nuclear reactions nuclear reactions involve the nucleus of atoms when a nuclear reaction occurs, the...
TRANSCRIPT
Nuclear Reactions
• Nuclear Reactions involve the nucleus of atoms
• When a nuclear reaction occurs, the element is changed completely into another element
• As a result, nuclear reactions are also known as Transmutations
The Nucleus
d10-13 cm
(d10-8 cm for an atom)
The Nucleons
mass (AMU) charge (esu)
proton 1 +1
neutron 1 0
In case you forgot...
many elements have several isotopes
U23892
U23592
92 protons143 neutrons
92 protons146 neutrons
Identical chemistries, different nuclear reactions
Chemical vs. Nuclear Energies
CH4(g) + 2 O2(g) CO2(g) + 2 H2O(g)
H = -896 kJ/mol
= -56 kJ/g
235Unuclear fission
other nuclei
H = -8.2 x 107 kJ/g
Why do nuclear reactions occur?
• Naturally, some atoms are stable while others are unstable
• Usually, when the ratio of neutron:proton is greater than 1.3, the nucleus is unstable
• Examples, 236U, 209Po, 14C, 230Th
• An unstable nucleus is radioactive and naturally emits certain radiations and is converted to a more stable isotope
proton (p)
neutron (n) the nuclear force
Forces in the Nucleuselectrostatic repulsion
Nuclear Stability
protons (Z)
neut
rons
(N
)
0 900
140
N/Z=1
.
.
.
...... . .
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. ............. ....................
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............... .................. .. . ..
.......
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..
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“Island of Stability”
decay
EC decay
decay
neutronsneeded for stability
Determine if any of the following isotopes is stable or unstable
Isotope
Protons (P)
Neutrons (N)
N/P ratio Stable or unstable
218Po
14C
214Pb
206Pb
Types of RadiationThere are 4 main types of radiation:
Radiation Charge Mass Symbol
Alpha rays
(-particles)
+2 4 42He
Beta rays
(-particles)
-1 0 0-1
Gamma rays
(-rays)
0 0 00
Positrons +1 0 O+1
The Discovery of Radioactivity
U
-
+
+
Particles
positively charged
massive
accurate measurements 4He nuclei
2 protons2 neutrons
Emission of particles
• Some unstable nuclide decay by emitting only -particles
• Examples:• 226
88Ra → 22286Rn + 4
2He• 210
84Po → 20682Pb + 4
2He• 230
90Th → 22688Ra + 4
2He• Using Table N, identify 4 nuclide that
undergo alpha decay and write the nuclear equation
Decay
U238
92 He + 4
2
234
90 Th
nucleons are conserved (238)charge is conserved (92)
identities of atoms are not!
Emission of particles
• Some unstable nuclide decay by emitting only -particles
• Examples:• 239
92U → 23993Np + 0
-1• 239
93Np → 23994Pu + 0
-1• 14
6C → 147N + 0
-1• Using Table N, identify 4 nuclide that
undergo beta decay and write the nuclear equation
TABLE NSelected Radioisotopes
Particles
negatively charged small mass
accurate measurements electrons
Decay
234
90 Th e- + 0
-1234
91 Pa
i.e. a neutron is turned into a proton + an electron
90 p144 n
91 p143 n
Electron Capture
55
26 Fe + e-5525 Mn
26 p29 n
25 p30 n
i.e. a proton captures an electron and is turned into a neutron
Electron Capture (EC)++ ++
+++
+++
+ -
-
Decay Series
A B C D ... � non-radioactive nuclide
There are three such series:
A = 238U,A = 232Th,A = 235Uand
238U Decay Series
238U Ž 234Th Ž 234Pa Ž 234U Ž 230Th
226Ra
222Rn(g) Œ
218Po Œ
214Pb Œ
214Bi Ž 214Po Ž 210Pb Ž 210Bi
210Po206Pb Œ
non-radioactive
Nuclear Reactions
A + B Ž C
[mass (A) + mass (B)] mass (C)
e.g. Fe5626
26 p + 30 n Ž Fe5626
find mass before and after reaction
Nuclear Reactions
mass before = 26 mp + 30 mn
= 26(1.00728 amu) + 30(1.00866 amu)= 56.44908 amu
mass after = mass 56Fe atom - 26 me
= 55.9349 amu - 26(.0005486 amu)= 55.92070 amu
“mass defect” = 0.52838 amu
Nuclear Reactions
The mass is converted to
energy!
"It followed from the special theory of relativity that mass and energy are both but different manifestations of the same thing -- a somewhat unfamiliar conception for the average mind. Furthermore, the equation E is equal to m c-squared, in which energy is put
equal to mass, multiplied by the square of the velocity of light, showed that very small amounts of mass may be converted into a very large amount of energy and vice versa. The mass and energy were in fact equivalent, according to the formula mentioned before. This was demonstrated by Cockcroft and Walton in 1932, experimentally."
Nuclear Reactions
The mass is converted to energy!
E = mc2
m = 0.52838 amu / 56Fe nucleus = 0.52838 g/mol = 0.52838 x 10-3 kg/mol
c = 3.00 x 108 m/s
Nuclear Reactions
E = mc2
= 0.52838 x 10-3 kg/mol (3.00 x 108 m/s)2
= 4.75 x 1013 (kg m2 s-2) / mol
= 4.75 x 1013 J/mol
= 4.75 x 1010 kJ/mol
= the “binding energy” of 56Fe
Binding Energy
is a maximum at 56Fe
lighter elements become more stable upon fusion
heavier elements becomemore stable upon fission
Nuclear Fission
n
235Uunstable 236U
92Kr36
141Ba56
+ 3 1n0
Nuclear Fission
1n + 235U 141Ba + 92Kr + 3 1n
Many other fission “pathways” exist:
1n + 235U 137Te + 97Zr+ 2 1n
Exercises
• Page 814: questions 8, 9, 10, 11 and 12
Artificial Transmutations
Aim: What is Artificial Transmutation and how do Artificial Transmutations occur?
Do Now
Write Nuclear Equations for the following natural transmutations:
(a) U-235 → Th-234 (b) Th-230 → Ra-226
(c) Po-214 → Pb-210 (d) Pb-214 → Bi-214
(e) U-234 → Th-230 (e) Pa-234 → U-234
What is Artificial Transmutation?
• Artificial Transmutation is where a stable isotope is made to disintegrate
• This is usually done by bombardment with high speed particles
• Examples:
• 42He + 14
7N → 178O + 1
1p
• 2713Al + 4
2He → 3015P + 1
0n
• 3215P + 0
-1 → 3214Si
Individual Practice
• Page 816: Problems 15 and 16
• Page 837: Problems 73-76
Group Practice
• Examine the Figure on page 814. Write a series of nuclear equations showing the transmutations from U-238 to Po-214