novel method gas separation(ingles)gym

Upload: geronimo-hugo-rojas-mamani

Post on 07-Jul-2018

217 views

Category:

Documents


0 download

TRANSCRIPT

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    1/34

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    2/34

    Overview

    Current process

    New process

    Economic comparison

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    3/34

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    4/34

    Natural Gas Processing  Everything Together

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    5/34

    Water removalRemoves &ree li'uid

    water andcondensate gas

    ends the gas to a

    re(nery

     The water goes towaste

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    6/34

    Natural Gas Processing  Everything Together

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    7/34

    Natural Gas Processing

    )cid Gas Removal*ydrogen sul(de

    +ercaptans

    Car$on dioxide

    )cid gas removal processes)mine treating

    ,en(eld processul(nol process

    others

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    8/34

    Natural Gas Processing

    )mine Treatment+ost common used

    amines

    +onoethanolamineDiethanolamine

    Diisopropylyamine

    +ethylethanolamine

    *ydrogen sul(de goesthrough a Claus process

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    9/34

    Natural Gas Processing)mine Treating

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    10/34

    Natural Gas Processing

    ul(nol Process-sed to reduce *.#

    CO.# and mercaptans&rom gases

    Great &or treating large'uantities o& gas

    olvent a$sor$s thesour gas

    ul&olane is used

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    11/34

    Natural Gas Processing

    ul(nol Process

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    12/34

    Natural Gas Processing  Everything Together

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    13/34

    Natural Gas Processing

    Glycol Dehydration+ethod &or removing the water vapor &rom the

    gas

    -sa$le glycols Triethylene glycol /

    most commonly used

    Diethylene glycol

    Ethylene glycol Tetraethylene glycol

    Wor0s $y having the glycol adsor$ the water

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    14/34

    Natural Gas ProcessingGlycol Dehydration

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    15/34

    Pressure wing )dsorption)dsor$ent material is

    used

    Gas and material go

    under high pressure+aterial adsor$s the

    gas " *.# mercaptans#CO.%

    DisadvantagesRe'uires high pressures

    low cycle times

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    16/34

    Natural Gas Processing

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    17/34

    +ercury removalCurrent Processes)ctivated car$on / through chemisorption1

    )ctivated has extremely high sur&ace area

    +ercury can damages aluminum heat

    exchangers Those used in cryogenic processing plants

     Those use in li'ue&action plants

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    18/34

    Natural Gas Processing

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    19/34

    Nitrogen Re2ectionProcesses that can

    re2ect nitrogenCryogenic process

    )$sorption process"using lean oil orsolvent%

    +em$rane separation

    )dsorption process"activated car$on%

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    20/34

    Natural Gas Processing

    Cryogenic ProcessCommon re&rigerants used

    +ost common method &or removal o&impurities such as nitrogen

    Disadvantages+ust reach extremely low temperatures

    Only use&ul &or large scale production

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    21/34

    Natural Gas Processing

    !ean Oil Removal

    !ean oil is &ed countercurrent with the wet gas

     Temperature and pressure are set to allow &orthe greatest a$sorption o& unwanted gases

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    22/34

    Natural Gas Processing

      +em$ranesDriving &orcePartial pressure

     Type o& materialdetermine permea$ility

    k  D P    ×=

    D = diffusion coefficient (cm2/s)

    k = Henry’s law sorption

    coefficient (cm3/cm3cmHg)

    2

    1

     P 

     P =α 

    P1 = Permeaility of component 1

    P2 = Permeaility of component 2

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    23/34

    Natural Gas ProcessingEconomics

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    24/34

    Demethani3er

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    25/34

    Demethani3er The next step is to

    recover the NG!4s

    ProcessCryogenics using a

    tur$o5expander can $eused This is the most

    common

    !ean oil adsorptioncan $e used here

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    26/34

    Natural Gas ProcessingCryogenic Process

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    27/34

    NG! recovery

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    28/34

    NG! recovery

    Now the rest o&the li'uid is &ed tothree unitsDeethani3er

    De$utani3er

    Depropani3er

    ProcessEach sent to a

    distillation column

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    29/34

    weetening NG!4s

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    30/34

    +erox Processes+ercaptan oxidation

    Removes mercaptans &romPropane

    ,utane

    !arger hydrocar$ons

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    31/34

    Natural Gas Processing  )nother Process

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    32/34

    Novel +ethod

     Technical in&ormationmomentarily not availa$ledue to 6P issues

    *owever economics will $ecompared

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    33/34

    Novel +ethod)dvantage+ore cost e7ective than any previous methods

    !ess environmental impacts than previousmethods

    eparates all contaminants

    eparates each component

    Everything is done using one process

  • 8/18/2019 Novel Method Gas Separation(Ingles)Gym

    34/34

    Novel +ethod