nhc–pd(ii) complex–cu(i) co-catalyzed homocoupling reaction of terminal alkynes

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NHC–Pd(II) complex–Cu(I) co-ca talyzed homocoupling reaction of termi nal alkynes Appl. Organometal. Chem. 2006; 20: 771–774

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NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes. Appl. Organometal. Chem. 2006; 20 : 771–774. N -benzylethanolamine. Suzuki and Heck reaction. tetramethylethylenediamine. Suzuki reaction. - PowerPoint PPT Presentation

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Page 1: NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes

NHC–Pd(II) complex–Cu(I) co-catalyzedhomocoupling reaction of terminal alkynes

Appl. Organometal. Chem. 2006; 20: 771–774

Page 2: NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes

N-benzylethanolamineSuzuki and Heck reaction

Page 3: NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes

tetramethylethylenediamineSuzuki reaction

Page 4: NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes

Chiral Bidentate Bis(N-Heterocyclic Carbene)-Based Palladium Complexes

Bearing Carboxylate Ligands: Highly Effective Catalysts for the

Enantioselective Conjugate Addition of Aryl boronic Acids to Cyclic Enones

Chem. Eur. J. 2008, 14, 3759 – 3764

Page 5: NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes

Air and moisture stable

Page 6: NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes
Page 7: NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes
Page 8: NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes

2-cycloheptenone (4b)

benzyl 2,3-dihydro-4-oxo-1Hpyridinecaboxylate(4c)

5,6-dihydropyran-2-one (4d)

2-cyclopentenone (4e)

Page 9: NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes

Bis(NHC)ePd(II) complexes as highly efficient catalysts

for allylation of aldehydes with allyltributyltin

Tetrahedron 64 (2008) 2412-2418

Page 10: NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes
Page 11: NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes
Page 12: NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes
Page 13: NHC–Pd(II) complex–Cu(I) co-catalyzed homocoupling reaction of terminal alkynes