new york, new york 10007-1866

12
SDMS Document 125 Maiden Lane, Stti Floor New York, New York 10038 tel: 212 785-9123 fax: 212 785-6114 111465 July 7, 2006 Mr. Michael Negrelli Remedial Project Manager U.S. Environmental Protection Agency 290 Broadway, 20th Floor New York, New York 10007-1866 PROJECT: DOC CONTROL NO.: SUBJECT: RAC II Contract No.: 68-W-98-210 Work Assignment No.: 151-RICO-02LT 3223-151-RA-ECRA 06209 Addendum to Final Screening Level Ecological Risk Assessment Report Consolidated Iron and Metal Superfund Site Remedial Investigation/Feasibility Study Newburgh, New York Dear Mr. Negrelli: CDM Federal Programs Corporation (CDM) is pleased to submit the Addendum to the Final Screening Level Ecological Risk Assessment. CDM performed the refinement of the contaminants of potential concem according to the methodologies discussed in conference calls with EPA on June 30 and July 3, 2006. The results are presented in the Addendum. If you have any questions regarding this submittal, please contact Ms. Susan Schofield at (203) 262-6633 or me at (212) 785-9123. Very truly wurs. Litwin, REM II Technical Operations Manager CDM Federal Programs Corporation Enclosure cc: D. Butler, EPA Region 2 (letter only) F. Rosado, EPA Region 2 R. Goltz/PSO File, CDM S. Schofield, CDM N. Luke, CDM RAC II Document Control 302581 consulting engineering construction operations

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Page 1: New York, New York 10007-1866

SDMS Document

125 Maiden Lane, Stti Floor

New York, New York 10038

tel: 212 785-9123

fax: 212 785-6114 111465

July 7, 2006

Mr. Michael Negrelli Remedial Project Manager U.S. Environmental Protection Agency 290 Broadway, 20th Floor New York, New York 10007-1866

PROJECT:

DOC CONTROL NO.: SUBJECT:

RAC II Contract No.: 68-W-98-210 Work Assignment No.: 151-RICO-02LT 3223-151-RA-ECRA 06209 Addendum to Final Screening Level Ecological Risk Assessment Report Consolidated Iron and Metal Superfund Site Remedial Investigation/Feasibility Study Newburgh, New York

Dear Mr. Negrelli:

CDM Federal Programs Corporation (CDM) is pleased to submit the Addendum to the Final Screening Level Ecological Risk Assessment. CDM performed the refinement of the contaminants of potential concem according to the methodologies discussed in conference calls with EPA on June 30 and July 3, 2006. The results are presented in the Addendum.

If you have any questions regarding this submittal, please contact Ms. Susan Schofield at (203) 262-6633 or me at (212) 785-9123.

Very truly w u r s .

Litwin, REM II Technical Operations Manager

CDM Federal Programs Corporation

Enclosure cc: D. Butler, EPA Region 2 (letter only)

F. Rosado, EPA Region 2 R. Goltz/PSO File, CDM

S. Schofield, CDM N. Luke, CDM RAC II Document Control

3 0 2 5 8 1 consulting • engineering • construction • operations

Page 2: New York, New York 10007-1866

Addendum Screening Level Ecological Risk Assessment

Refinement of Chemicals of Potential Concern Selection Consolidated Iron and Metals Superfund Site

Remedial Investigation/feasibility Study Work Assignment No.: 151-RICO-02LT

Prepared for: U.S. Environmental Protection Agency

290 Broadway New York, New York 10007-1866

Prepared by: CDM Federal Programs Corporation

125 Maiden Lane, 5* Floor New York, New York 10038

EPA Work Assignment No. EPA Region Contract No. CDM Federal Programs Corporation Document No. Prepared by

Site Manager Telephone Number EPA Remedial Project Managers Telephone Number Date Prepared

151-RICO-02LT II 68-W-98-210

: 3223-151-RA-ECRA-06201 : CDM FEDERAL PROGRAMS CORPORATION

Susan Schofield (203) 262-6633 Michael Negrelli (212) 637-4278 July 7, 2006

302582

Page 3: New York, New York 10007-1866

Contents Section 1 Introduction

Section 2 Modifications 2.1 Exposure Point Concentration 2-1 2.2 Total Organic Carbon in Sediment 2-1 2.3 Backgroimd Concentrations and Detection Frequencies 2-1

2.4 Screening Benchmarks 2-1

Section 3 Refined Chemicals of Potential Concem Selection

Section 4 Literature Cited

List of Tables Table 3-1 Refinement of Chemicals of Potential Concem - Sediment

302583

Page 4: New York, New York 10007-1866

Acronyms and Abbreviations BTAG COPC EPA ERA ERM HQ m g / k g mg /L MGP NYSDEC NOAA PAH PCB PRG RI SEL SLERA SMDP SVOC the site TOC VOC

Biological Technical Assistance Group contaminant of potential concem Environmental Protection Agency ecological risk assessment effect range - median hazard quotient milligrams per kilogram milligrams per liter manufactured gas plant New York State Department of Environmental Conservation National Oceanic and Atmospheric Administration polycyclic aromatic hydrocarbon polychlorinated biphenyl preliminary remediation goal remedial investigation severe effect level screening level ecological risk assessment scientific/management decision point semi volatile organic compoimd Consolidated Iron and Metals Superfund Site total organic content volatile organic compoimd

302584

Page 5: New York, New York 10007-1866

Section 1 Introduction This report serves as a supplemental document to the Final Screening-Level Ecological Risk Assessment (SLERA) Report (CDM 2006) conducted for the Consolidated Iron and Metals Superfund Site (the site). The final SLERA report indicated that there is a potential for ecological risk at the site. The purpose of this supplemental document is to proceed to the next step in the Ecological Risk Assessment process, which involves refinement of the contaminants of potential concem (COPCs) and further characterizing the potential for ecological effects.

Environmental Protection Agency (EPA) guidance recommends using the findings of a SLERA as the basis of a scientific/management decision point (SMDP) to determine the next steps in the ecological risk assessment process (EPA 1997). During a phone conversation with EPA and National Oceanic and Atmospheric Administration (NOAA) on June 27, 2006, the next steps in the ecological risk assessment process were discussed. It was decided that the next step, specifically Step 3, would be completed for sediment in the Hudson River adjacent to the site, as described in EPA (2001). This report provides the results of the refinement of the COPCs.

The approach used to refine the selection of COPCs for the site involved five basic modifications from the Final SLERA Report (CDM 2006a). The modificahons are listed below:

• Refinement of exposure point concentrations • Normalization of sediment screening values using average site-specific total organic

carbon (TOC) concentrations • Consideration of background concentrations • Consideration of site-related contaminants • Refinement of screening benchmarks

The COPCs identified for sediment following the refined evaluation for the site are summarized in Table 3-1.

CDM SLERA Addendum - Consolidated Iron and Metals Site

3 0 2 5 8 5

Page 6: New York, New York 10007-1866

Section 2 Modifications Details regarding the modifications made to the refined COPC selection process are presented below.

2.1 Exposure Point Concentration In the Final SLERA report, the maximum detected values of contaminants in sediment were compared to screening benchmarks. In the refined COPC selection, the mean concentration for each chemical was compared to its screening benchmark. The use of the mean concentrations for calculating exposure point concentrations is more representative than the use of maximum concentrations.

2.2 Total Organic Carbon in Sediment The bioavailability of organic compounds decreases as the organic content of sediment increases. In the Final SLERA, the lowest total organic carbon (TOC) concentration measured at the site (1.2 percent) was used to normalize screening benchmark concentrations for organic compoimds. In the refined COPC selection for sediment, the average, site-specific TOC concentration (3.73 percent) was used, providing a more realistic estimation of the potential risk from contaminants at the site.

2.3 Background Concentrations In the Final SLERA Report, background concentrations of contaminants were not considered. In the refined COPC selection, the mean background concentration for each contaminant was calculated and contaminants having a mean detected concentration lower than the background value were removed from consideration as COPCs. One half of detection limit was used for non-detects.

2.4 Site-Related Contaminants In the Final SLERA Report, whether the contaminants were site related was not considered. In the refined COPC selection, the non-site related contaminants were eliminated as COPCs (see Table 3-1). The site-related contaminants identified in the Final RI Report (CDM 2006b) are the following:

• Polycyclic Aromatic Hydrocarbons (PAHs): benzo(a)anthracene, benzo(b)fluoranthene, benzo(a)pyrene, indeno(l,2,3-c,d)pyrene, and dibenz(a,h)anthracene

• Polychlorinated Biphenyl (PCB): Aroclor-1254 • Metals: arsenic, cadmium, copper, iron, lead, mercury, vanadium, and zinc

2.5 Screening Benchmarks In the Final SLERA Report, conservative screening benchmarks among sources considered were used to calculate hazard quotients (HQs). In the refined COPC selection, the following widely accepted and used benchmark sources that contained screening values for the compound(s) of interest were considered:

CDM SLERA Addendum - Consolidated Iron and Metals Site

3 0 2 5 8 6

Page 7: New York, New York 10007-1866

Section 2 Modifications

Severe Effect Levels (SEL) from Persaud, D., R. Jaagumagi, and A. Hayton. 1993. Guidelines for the protection and management of aquatic sediment quality in Ontario Water Resources Branch, Ontario Ministry of the Environment, 27 pp.

Effect Range - median (ERM) from Long, E.R. and L.G. Morgan. 1991. The potential for biological effects of sediment-sorbed contaminants tested in the National Status and Trends Program, NOAA Technical Memorandum NOS OMA 52, National Oceanic and Atmospheric Administration, Seattle, WA

Preliminary Remedial Goals (PRGs) from Efroymson, R.A., G.W. Suter II, B.E. Sample, and D.S. Jones 1997. Preliminary remedial goals for ecological endpoints. ES/ER/TM-162/R2. Oak Ridge National Laboratory

New York State Department of Environmental Conservation (NYSDEC) Technical Guidance for Screening Contaminated Sediments 1999

Ingersoll, C.G. et al., 1996. Calculation and evaluation of sediment effect concentrations for the amphipod Hyallela azteca and the midge Chironomus riparius. International Association of Great Lakes Research 22:602-623.

Risk Assessment Information System, Oak Ridge National laboratory, online http://risk.lsd.oml.gov/homepage/benchmark.html

CDM SLERA Addendum - Consolidated Iron and Metals Site

302587

Page 8: New York, New York 10007-1866

Section 3 Refined Chemicals of Potential Concern Selection The refined list of COPCs, the reason for their selection/exclusion, contaminant concentrations, and background concentrations are discussed in this section.

Using a conservative approach, the Final SLERA Report indicated that the potential for ecological risk exists in sediments in the Hudson River adjacent to the site (CDM 2006a). A scientific and management decision was made during a conference call with EPA's Biological Technical Assistance Group (BTAG) to refine and re-evaluate COPCs identified in the SLERA using supplemental information and site-specific parameters, as discussed in EPA (2001). Modifications made from the Final SLERA Report are listed in Section 1.

Table 3-1 lists statistical information of COPCs identified in the SLERA, mean and background concentrations, HQs based on mean concentration of these contaminants, HQs based on the background concentrations, and justification and comments for selection or exclusion of each chemical or analyte as a COPC in this refinement.

As shown in Table 3-1,32 COPCs [1 volatile organic compound (VOC), 17 semi-volatile organic compounds (SVOCs), 4 pesticides/PCBs, and 10 inorganicsj identified in the SLERA have HQs equal to or less than one, indicating they are not considered COPCs in the refinement. Five contaminants (benzaldehyde, carbazole, endrin ketone, thallium, and vanadium) do not have screening values. The mean concentration of vanadium (25.5 mg/kg) was lower than the backgroimd concentration (26.1 mg/kg) . Thus, vanadium is eliminated as a COPC. Benzaldehyde, carbazole, endrin ketone, and thalliimi, are also excluded as COPCs because they are not associated with site operations and are not considered site-related contaminants.

Four contaminants (dibenzofuran, dimethylphthalate, 2-methylnaphthalene, and cyanide) having mean concentrations below their respective mean background concentrations. Therefore, they are excluded as COPCs.

Three contaminants (acetone, acenaphthylene, and 4-methylphenol) were present at concentrations exceeding their respective screening levels. However, these three compounds were detected very infrequently in soil samples at the site, indicating that these three contaminants in sediments in the Hudson River likely did not originate from site soils. Furthermore, the RI Report (CDM 2006b) indicates that these contaminants are not associated with site activities. Therefore, they are also eliminated as COPCs in this refinement.

One SVOC (butylbenzylphthalate) and four inorganics (manganese, seleniimn, silver, and zinc) are also excluded from the refined COPC list, because they are not considered site related in the RI Report. In addition, screening level exceendances for these five contaminants were low, with calculated HQs ranging from 2.3 to 1.1.

CDM SLERA Addendum - Consolidated Iron and Metals Site

302588

Page 9: New York, New York 10007-1866

Section 3 Refined Chemicals of Potential Concern Selection

Benzo(b)fluoranthene and copper may be considered COPCs in the refinement. The calculated HQs for these two contaminants are below 10 (8 and 3.2, respectively). In background samples, the mean backgroimd concentration of benzo(b)fluoranthene also exceeds its screening criterion (HQ = 5.3). Therefore, a calculated net H Q from this contaminant is low (2.7).

Two contaminants (benzo(b)fluoranthene and copper) have been determined to be site related and could be considered COPCs in this refinement. However, copper has a low HQ (3.2). For benzo(b)fluoranthene, the mean concentration and background concentrations are 3,094 and 2,061 Mg/kg, respectively, resulting in HQs of 8 and 5.3, respectively. The difference between these HQs is 2.7, which indicates the potential for risk is extremely low. Furthermore, previous investigations conducted at the Newburgh manufactured gas plant (MGP) hazardous waste site immediately down river of the Consolidated Iron site indicated that PAHs and inorganics were contaminants of concem (COCs). Benzo(b)fluoranthene and copper were generally detected in Hudson River sediment samples at much high levels adjacent to the MGP site. It is likely contaminants from the MGP site were transported upriver with the tidal flow and deposited near the Consolidated Iron site. Therefore, these two contaminants in sediment may have originated at the MGP site.

Using the approach described herein to refine the list of COPCs at the site, detected contaminants fall into several groupings, as shown on Table 3-1 and svunmarized below.

• Most contaminants present in sediment are at concentrations below screening values; their HQs are below 1, indicating no risk concems.

• Several contaminants (acetone, acenaphthylene, and 4-methyIphenol) have relatively high HQs, but are not site related contaminants, based on limited or no detections of these contaminants in site soils.

• Several contaminants (butylbenzylphthalate, aluminum, manganese, seleniimi, silver, and zinc) minimally exceed screening values, with HQs in the range of 1 to 3, which is indicative of very low potential for risk.

• Several contaminants (benzaldehyde, carbazole, endrin ketone and thallitun) lack screening values, but are not site related, based on limited or no detections of these contaminants in site soils.

• Two compounds (benzo(b)fluoranthene and copper) exceed screening criteria, with relatively low HQs (2.7 and 3.2, respectively), indicating low potential for risk.

Based on the refinement of COPCs described in this Addendtun to the SLERA, only two contaminants - benzo(b)fluoranthene and copper - are site-related COPCs. Both have low HQs and show low potential for risk to receptors in the Hudson River sediments. Therefore, CDM recommends that a Baseline Ecological Risk Assessment (BERA) should not be conducted for Hudson River sediments.

CDM SLERA Addendum - Consolidated Iron and Metals Site

3 0 2 5 8 9

Page 10: New York, New York 10007-1866

Section 4 Literature Cited CDM 2006a. Final Screening Level Ecological Risk Assessment, Consolidated Iron and Metals Superfund Site, Newburgh, New York. March 31.

CDM 2006b. Remedial Investigation Report, Consolidated Iron and Metals Superfund Site, Newburgh, New York. July 5.

Efroymson, R.A., G.W. Suter II, B.E. Sample, and D.S. Jones. 1997. Preliminary remediation goals for ecological endpoints. ES/ER/TM-162/R2. Oak Ridge National Laboratory, Oak Ridge, TN.

EPA 1997. Ecological Risk Assessment Guidance for Superfund: Process for Designing and Conducting Ecological Risk Assessments. EPA 540-R-97-006.

EPA 2001. ECO Update. The Role of Screening Level Risk Assessments and Refining Contaminants of Concem in Baseline Ecological Risk Assessments. EPA 540/F-01/014.

Long, E.R. and L.G. Morgan 1991. The potential for biological effects of sediment-sorbed contaminants tested in the National Status and Trends Program, NOAA Technical Memorandum NOS OMA 52, National Oceanic and Atmospheric Administration, Seattle, WA

New York State Department of Environmental Conservation (NYSDEC) Technical Guidance for Screening Contaminated Sediments 1999.

Persaud, D., R. Jaagumagi, and A. Hayton 1993. Guidelines for the protection and management of aquatic sediment quality in Ontario Water Resources Branch, Ontario Ministry of the Environment, 27 pp.

Risk Assessment Information System, Oak Ridge National laboratory, online http://risk.Isd.oml.gov/homepage/benchmark.shtml

CDM SLERA Addendum • Consolidated Iron and Metals Site

302590

Page 11: New York, New York 10007-1866

Table 3-1 Refinement of Chemicals of Potential Concem - Sediment

Consolidated Iron and Metal Site Newburgh. New York

302591

1 Chemica l Name M i n i m u m

Concent ra t ion

(Qual i f ier)

Max imum

Concentrat ion

(Quali f ier)

Unit

Locat ion of

M a x i m u m

Concen t ra t i on

Detect ion

Frequency B a c k g r o u n d '

1 Eco log ica l

[ Sc reen ing Level

V a l u e ' Source

Mean

Concentrat ion

HO based

on Mean COPC Just i f icat ion a n d c o m m e n t s

HQ based

on

B a c k g r o u n d

( H Q ) - ( H Q

Backg round

1 Volat i le Organic C o m p o u n d s I

[Ace tone

|2 -Butanone

21

8 J

120

26

j / g / k g

^ /g /Vg

SD-17

SD-17

8 / 1 0

4 / 1 0

40.5

8.6

0.3

10.1

c

o

44.5

1 10.6

131.1

1.0

No

No

not assoicated w i t h s i te operat ion

and not detected in soi l IHQSI

119.3 11.8 1

XSemi'Volati le Orqanic C o m p o u n d s 1

lAcenaph thene

1 Acenaphthy lene

{Anthracene

iBenza ldehyde

|Benzo(a)anthracene

lBen20(a)pyrene

18enzo(b) f luoranthene

Ben2o(g,h, i )perylene

BenzoOc)fluoranthene

bls(2-Ethylhexyl) ph tha la te

Buty lbenzy lphtha la te

[Carbazole

IChrysene

lDibenzo(a,h)anthracene

1 Dibenzofuran

iD imethy lphtha la te

p l -n -bu ty lph tha la te

D i -noc ty lph tha la te

F luoranthene

iF luorene

lndeno(1.2,3-cd)pyrene

2-Methy lnaphlhalene

4-Methylphenol

[Naphthalene

iPhenanthrene

iPyrene

94 J

110 J

220 J

91 J

160 J

190 J

270 J

95 J

96 J

1900

120 J

210 J

200 J

150 J

79 J

470 J

110 J

71 J

270 J

100 J

110 J

98 J

70 J

160 J

140 J

300 J

4700

240 J

8300

210 J

16000

12000

15000

4700

5900

7200 J

1200 J

2700 J

16000

2400 J

1900 J

470 J

11000 J

510 J

40000

4800

7700

770 J

70 J

1300 J

28000

40000

/ / g A g

vgr t ig

( /g/kg

; /g /kg

/ m / k g

( /gAg

; / g * g

/ / g * g

w * g / i g ^ g

/ / g / kg

/ /g /kg

wi<g pgm p g / ^ g * « / l t g

* / g * g ^/g/kg

</gAg

p g i ^ a

p g i ^ g pgn^g

v g i ^ g

w ^ g *^ / i<g / / g / k g

SO-19

SD-20

SD-19

SD-18

SD-19

SD-19

SD-19

SD-19

SD-19

SD-11

SD-19

SD-19

SD-19

SD-19

SD-19

SD-11

SD-20

SD-11

SD-19

SD-19

SD-19

SD-19

SD-11

SD-19

SD-19

SD-19

6 / 10

3 / 10

6 / 10

7 / 10

10 / 10

10 / 10

10 / 10

10 / 10

9 / 10

3 / 10

5 / 10

5 / 10

10 / 10

6 / 10

4 / 10

1 / 10

3 / 10

4 / 10

10 / 10

6 / 10

10 / 10

3 / 10

1 / 10

3 / 10

10 / 10

10 / 10

2.072.O

502.0

2,579.0

NO

2,431.2

1,814.9

2,061.0

918.4

951.5

5,591.0

774.5

494.5

2,649.0

616.0

1,247.0

780.5

616.5

ND

5,046.0

1,799.0

1,027.2

595.5

ND

B65.5

5,950.5

4,823.0

5,222.0

6.0

13,801.0

NV

55,204.0

53,712.0

387.9

11,936.0

49,982.0

7,441.4

408.6

NV

17,158.0

4,849.0

15.7

11.9

8,952.0

1,790.4

38,046.0

5,968.0

11,936.0

25.0

25.0

1,119.0

35,435.0

31,705.0

e

h

a

a

a

i

a

a

e

d

-

a

a

c

1

c

i a

a

a

b

i

e

a

a

775.4

523.5

1,315.0

410.4

2,843.0

2,463.0

3,094.0

1,117.5

1,225.6

1,715.0

564.0

623.5

3,044.0

696.0

425.4

629.5

1,567.5

518.6

6,527.0

793.0

1,838.0

441.3

589.5

510.5

4,214.0

6j253.0

0.1

87.7

0.1

0.1

0.05

8.0

0.1

0.02

0.2

1.4

~

0.2

0.1

27.2

53.1

0.2

0.3

0.2

0.1

0.2

17.7

23.6

0.5

0.1

0.2

No

No

No

No

No

No

Yes

No

No

No

No

No

No

No

No

No

No

No

No

No

No

No

No

No

No

No

HO SI

not assoicated w i t h s i te operat ion

and not detected in sol i

HQS1

not assoicated w i t h s i te operat ion

and not site related

HQ<1

HO SI

HQS1

HQS1

HO SI

not assoicated w i th s i te operat ion

and not s i te related

not assoicated w i th s i te operat ion

and not site related

HO SI

HO SI

below background

below background

HO SI

HO SI

HQS1

HQS1

HQS1

be low backg round

not assoicated w i t h s i te operat ion

and not detected in soi l

HO SI

H Q < 1

H Q S l

84.1

-..

5.3

--

~ 79.6

65.8

--

23.8

-

1 3.6

-

2.7

1

1 -52.4

-12.7

1

-6.2 j

1 Pest ic ides a n d Po l ych lo r i na ted b i pheny l s I

|4,4'-DDD 4.4'-ODE

Endr in a ldehyde

Endr in ketone

Aroclor-1248

3.3 J 3.5 J

3.2 J

6.2 JN

220 J

11 12 J

8.4 JN

6.2 JN

520.1

wAg //g/><g / / g A g

pgn^g

im^9\

SD-17

SD-11

SD-17

SD-20

SD-11

2 / 10 /

3 /

1 /

4 /

10 10

10

9

S

4.4 6.0

ND

6.3

223.3

223.8 708.7

17.9

NV

5.595.0

a a

i

a

4.8

6.7

4.9

4.4

219.5

0.02 0.01

0.3

-

0.04

No No

No

No

No

H Q S l H Q S l

H Q S l

not assoicated w i t h s i te operat ion

and not site related

HQ SI ' j

.-

-

1

COM Table 3-1 relinement 070606 xls

Page 12: New York, New York 10007-1866

Table 3-1 Refinement at Chemicals ot Potential Concern - Sediment

Consolidated Iron and Metal Site Newburgh, New York

302592

Chemical Name Minimum

Concentration (Oualifler)

Maximum Concentration

(Qualifier) Unit

Location of Maximum

Concentration

Detection Frequency

Background ^

Ecological Screening Level

Value' Source

Mean Concentration

HQ based on Mean

COPC Justification and comments HO based

on Background

(HQ) - (HO Background)

Inorganics j Aluminum Antimony Arsenic Barium Cadmium Chromium Cobalt Copper Cyanide jiron Lead iManganese

Mercury Nickel {Selenium

Silver

Thallium Vanadium

Zinc

8500 15 J 1.5 47

1.4 18

9.2 36

0.28 J 25000

60 J 370

0.17 21

8.9 J

2.3

6.4 J 15

160

18000 15 J 14

380 1.7 86 18 J

2600 0.66 J

69000 400

1900 J

0.54 86 8.9 J

7.2 J

6.4 J 31 J

1100

mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg

mg/kg mg/kg mg/kg

mg/kg

mg/kg mg/kg

mg/kg

SD-17 SD-12 SD-17 SD-20 SD-17 SD-17 SD-16 SD-17 SD-16 SD-17 SD-17 SD-16

SD-11 SD-17 SD-12

SD-16

SD-12 SD-16

SD-17

10 / 10 1 / 10

1 0 / 10 10 / 10 2 / 10

10 / 10 10 / 10 1 0 / 10 4 / 10

10 / 10 10 / 10 10 / 10

1 0 / 10 10 / 10 1 / 10

4 / 10

1 / 10 10 / 10

10 / 10

14,000.0 11.5 5.8

119.1 0.9

54.8 16.0 71.5 2.8

31,700.0 70.3

1,671.0

0.3245 33.1 6.6

ND

4.7 26.1

180.0

14,000.0 25.0 33.0 160.0 10.0

145.0 50.0 110.0 0.1

40,000.0 250.0

1,100.0

2.0 75.0 2.0

2.2

NV NV

270.0

g b a f a b i a d a a a

a a d

b

-b

13,950.0 7.8 5.5

124.0 0.9

53.5 14.0 350.7 2.2

35,400.0 160.5

1,302.0

0.4 38.2 4.5

2.5

3.3 25.5

333.0

1.0 0.3 0.2 0.8 0.1 0.4 0.3 3.2

22.0 0.9 0.6 1.2

0.2 0.5 2.3

1.1

_

1.2

No No No No No No No Yes No No No No

No No No

No

No No

No

HQSl HQSl HQSl HQSl HQSl HQS1 HQSl

below background HQSl HO SI not assoicated with site operation and not site related H0<1 HQSl not assoicated with site operation and not site related not assoicated with site operation and not site related not assoicated with site operation and not site related below background (25.5 vs. 26.1) not assoicated with site operation and not site related

-~ ~

_ --

0.7 27.9

---

-

-

-

-_ _ -

2.5 -5.9

-

..

-

' Background values were calculated by averaging the values from samples {SD-01 through SD-10), including one heilf detection limits for non-detects ^ for organics, screening criteria are based on a calculated site-specific average total wganic cartjon concentration of 3.73% Sources a Persaud D, R, Jaagumagi, and A. Hayton 1993. Guidelines for the protection and management of aquatic sediment quality in Ontario Water Resources Branch, Ontario Ministry of Ihe Emvironment. Toronto, 27 pp. b. Long ER and L.G Morgan 1991. The potenti^ for biological effects of sediment-swbed contaminants tested in the National Status and Trends Program. NOAA Technical Memorandum NOS OMA 52, Nation^ Oceanic and Atmospheric Adminstration. Seattle, WA, 175 c. Efroymson, RA., G.W Suter II, BE, Sample and OS. Jones. 1997. Pr^iminary remediation goals for ecological endpoints. ES/ER/TM-162/R2, Oak Ridge National Labortory, d. EPA Region 3. 2005. BTAG Freshwater Sediment Screening Benchmarks, March 2005 e. NYSDEC Technical Guidance lor Screening Contaminated Sediments. 1999 ( MHSPE (Ministry ot Housing, Spatial Planning, and Environment) 1994, Intervention vafues and target values - Soil Quality Standards. The Hague. The Netherlands. g. IngersotI, C G.. PS. Haverland. EL. Brunson, T.J. Canfield, F.J, Dwyer. C.E. Henke, N.E. Kemble, DR. Mount and R.G. Fox, 1966. Calculation and Evaluation of Sediment Effect Concentrations for the Amphipod Hyallela azteca and the Midge Chironomous riparius. Internationa] Association of Great lakes Research 22:602-623 h. NOAA Squirt 1999. i. EPA Region 5, 2003. RCI^ Ecological Screening Levds, July 17. 2003 j . Washington MAEL (minor adverse effect level), Washington Department of Ecology, Sediment Management Unit, Sediment Quality Chemical Criteria updated B/9/2001. http://www.ecy,wa gov/programs'tcp/smu/sed_chem htm

Definitions: - _ _ NV = No Value NA = Not Applicable

ND =: Not detected J = Estimated VaJue

JN = Tentativety Identified uQ^9 = microgram per kilogram mg/kg = milligram per kilogram

CfM Table 3-1 lefinement 070606 > Page 2 o( 2