new tradewind and clipper™ aquatic herbicides of onsite... · products that work, from people who...
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Products That Work, From People Who Care®
New Tradewind™ and Clipper™ Aquatic Herbicides
Jim Petta, Mike Riffle, PhD. and Joe Chamberlin, PhD. May 2012 Aquatic Short Course
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Tradewind Specifications
Active Ingredient: bispyribac-sodium (Tradewind™) Chemical Family: pyrimidinyloxybenzoic acid Mode of Action: acetolactate synthase (ALS) inhibitor
− ALS is a plant specific enzyme − Similar MOA to imazamox, imazapyr, and penoxsulam − But unique family which leads to differential uptake and
selectivity Registered in Spring 2011 Formulation: 8 oz WSP No swimming, drinking, or fishing restrictions Applied to multiple lakes/sites in 2011-12 in Florida with
excellent results (efficacy and selectivity)
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Tradewind Toxicology and E-fate
No drinking, fishing or swimming restrictions Excellent toxicology profile (minimal PPE)
− Not acutely toxic to mammals − Not carcinogenic, teratogenic or mutagenic
Excellent environmental fate profile; 30 day HL
Non-Target Species Toxicity Birds Practically non-toxic
Freshwater Fish Practically non-toxic
Estuarine Fish Practically non-toxic
Freshwater Invertebrate Practically non-toxic
Estuarine Invertebrate Practically non-toxic
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80% SP formulation Unique WSP package
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Thomas Lake
75 acre lake near Lakeland, FL − Nine foot average depth with some deep “holes”
Target species: Hydrilla verticillata
45 ppb Tradewind subsurface July 22, 2011
ACOE evaluated treatment
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Native Species To Conserve
Southern naiad/bushy pondweed (Najas guadalupensis)
American Lotus (Nelumbo lutea)
Bladderwort (Utricularia spp.)*
Coontail(Ceratophyllum demersum)*
* Not observed until post treatment
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7 Application Day
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Naiad + Hydrilla (0 DAA)
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July 20, 2011 Pre-treatment Biomass 3 sample sites (3 transect lines) N=9 Hydrilla = 69 + 22 g dry wt. Naiad 18 + 7 g dry wt. Bio-volume = 61%
Dr. Mike Netherland, ACOE
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No “Bumps”
Concentration of bispyribac-sodium in Thomas Lake
0.0
5.0
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0
7/22/1
18/5
/11
8/19/1
19/2
/11
9/16/1
1
9/30/1
1
10/14
/11
10/28
/11
11/11
/11
11/25
/11
12/9/
11
12/23
/111/6
/12
1/20/1
22/3
/12
Date
Co
nce
ntr
atio
n (
pp
b)
Application Date: July 22nd, 2011 Dr. Mike Riffle and Walter Albeldano, Valent USA Corp.
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Oct 20, 2011
Post-treatment Biomass 3 sample sites (3 transect lines) N=9
Hydrilla 0.83 + 2.1 g dry wt - 99% biomass reduction
Naiad 13 + 9 g dry wt.
Bio-volume = 9 %
Dr. Mike Netherland, ACOE
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Minimal impact on floating @ emergent plants (October 27: 3 months after application)
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Minimal impact on Southern Naiad (October 27: 3 months after application)
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Conclusions
Tradewind in Thomas Lake − Very effective against Hydrilla at the target dose of
45 ppb
− Minimal impact on natives Southern Naiad, lotus, cattails
− 2-3 month residual in water, no “bumps” needed
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New Clipper Herbicide
New chemistry/MOA in PPO inhibitor
High efficacy against Cabomba, Hydrilla including rHydrilla, Duckweed, watermeal
Short contact time = fast uptake
There and gone within 2-3 days
No drinking, fishing, or swimming restrictions
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Clipper Specifications
Active Ingredient: flumioxazin
Mode of Action: Initiates cell membrane disruption
Low toxicity (minimal PPE)
Good environmental profile
51% WDG (water dispersible granule)
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Algae Control
Algae types include filamentous algae (Pithophora and Cladophora)
200 ppb target rate Some planktonic control observed Coverage Tank mix and rotate
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Non-Target Plant Selectivity
Good selectivity observed in operational applications to Eelgrass, maidencane, chara, pickeralweed
Water lily sensitivity in treatment zone
O 50 100 200 400 800 1600
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Cabomba, pre and 30 DAT at 200 ppb
Lake Josephine, near Sebring, FL 2011
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Target Cabomba and Limnophila
Lake Seminole, GA, FL
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14 DAT at 200 ppb
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Hydrilla Perimeter Treatment
Excellent control at 120 + days Clipper at 200 ppb + Reward at 200 ppb
Butler Chain , 2011
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Clipper
Submersed species (cabomba, Hydrilla, coontail, EWM, CLP, others):
Good to excellent results at 200 ppb (label is 100 to 400 ppb)
Hydrilla 200 ppb + Reward (diquat) at 200 ppb; 200 ppb alone in
low pH and high turbidity
pH plays a role in activity (lower = longer half life)
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Watermeal (Wolffia spp.)
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11 DAT at 200 ppb
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Watermeal and Duckweed 200 ppb at 14 DAT
Target filamentous
St. Petersburg, FL 2011
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Duckweed and Watermeal
Target 200 ppb
Apply subsurface or surface (not foliar per se)
Retreatment depends on budding rate, population, introductions, water fluctuations, etc.
Plan additional treatments under severe conditions
NIS or similar (MSO) Silicone?
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Hygrophila Control at 157-200 ppb
University of Florida, 2011
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Hygrophila
Broward County, 2011
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Hygrophila at 200 ppb 28 DAT
Broward County, 2011
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So What Have we learned?
For submersed plants…. − Apply before emergence/topping out − Target rate is 200 ppb − Second application may be necessary for re-growth if
any − Tank mix diquat for Hydrilla, Hygrophila
For floating plants……
− Apply 200 ppb rate − Surface application/reduced rate for deeper areas − Surfactant? − Duckweed and watermeal may require retreatment of
the area for new growth or introductions
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Questions?