national report on monitoring and assessment: ukraine
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National Report on Monitoring and Assessment: Ukraine. RAC PMA (UkrSCES). Sofia, 2008 Oct 9. Main goals. Ukrainian Regional Monitoring System of Black Sea Number/List of monitored parameters National institutions involved in 2007 Quality Assurance /Quality Control - PowerPoint PPT PresentationTRANSCRIPT
National Report on Monitoring and Assessment: Ukraine
RAC PMA (UkrSCES)
Sofia, 2008 Oct 9
2
Main goals Ukrainian Regional Monitoring
System of Black Sea Number/List of monitored
parameters National institutions involved in
2007 Quality Assurance /Quality Control Ukrainian Annual Assessment of
the Black Sea Environment International Projects Data processing resources of
UkrSCES Main Publications of the Monitoring
and Assessment Results Principal Document RAC PMA Proposals
3
Ukrainian Monitoring System
4
Sampling points 2007
5
Ukrainian Monitoring SystemNumber/List of monitored parameters (2007/2006)
ParameterSamples numbers
ParameterSamples numbers
ParameterSamples numbers
Hydrochemicals Metalls PAHs
Temperature 66/59 Fe 84/82 Naphthalene 5/0
Salinity 149/59 Mn 5/0 Acenaphthylene 5/0
pH 79/70 Zn 17/0 Acenaphthene 5/0
O2 150/82 Co 17/0 Acenaphthene 5/0
TSS 148/70 As 17/0 Fluorene 5/0
Transparency 10/0 Hg 17/0 Phenanthrene 5/0
BOD5 79/70 Cu 17/0 Anthracene 5/0
P (PO4) 150/71 Cd 17/0 Floranthene 5/0
Ptotal 69/0 Pb 17/0 Pyrene 5/0
6
Ukrainian Monitoring SystemNumber/List of monitored parameters (2007/2006)
ParameterSamples numbers
ParameterSamples numbers
ParameterSamples numbers
Hydrochemicals Metalls PAHs
N (NH4) 113/82 Ni 17/0 Benzo[a]antracene 5/0
N (NO2) 150/82 Cr 17/0 Chrysene 5/0
N (NO3) 150/82 Al 5/0Benzo(b)fluoranthene
5/0
Ntotal 70/0 V 5/0Benzo(k)fluoranthene
5/0
SiO4 42/0 Benzo[a]pyrene 5/0
Benzo(ghi)perilen 5/0
Dibenzo[a,h]anthracene
5/0
Indeno(1,2,3-c,d) piren
5/0
7
Ukrainian Monitoring SystemNumber/List of monitored parameters (2007/2006)
Chlororganic pesticides PCBs totalDibenzo[a,h]anthracene
5/0
DDT17/0
Ar1254 17/0Indeno(1,2,3-c,d)piren
5/0
DDD 17/0 Ar1260 17/0
DDE 17/0
Lindane 17/0
α-HCH 17/0
β-HCH 17/0 Other organic pollutants
HCB 17/0 Phenols volatile 79/42
Heptachlor 17/0 Detergents 79/65
Aldrin17/0 Total Petroleum
Hydrocarbons91/83
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Data were reported to the Ministry of Environment Protection of Ukraine. Results of Pilot monitoring were reported to the UNOPS.
Financing assured by Ministry of the Environment Protection of Ukraine, National Academy of Science of Ukraine and UNOPS.
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Ukrainian Annual Assessment of the Black Sea Environment
PO428%
NH424%NO2
6%
NO342%
PO416%
NH428%
NO221%
NO335%
PO415%
NH427%
NO220%
NO338%
PO419%
NH428%
NO221%
NO332%
PO422%
NH417%
NO230%
NO331%
PO425%
NH425%
NO225%
NO325%
0
20
40
60
80
100
120
2000 2001 2002 2003 2004 2005 2006 2007
O2PO4NH4NO2NO3
10
The researches were focused on the two main ecological problems of the Black Sea
1) Eutrophication of seawater and negative ecological effects of this phenomenon
2) Toxic pollution of marine environment.
Odessa region
0
100
200
300
400
1992
1994
1996
1999
2005
mg.kg -1
Tot.CH
mkg/kg
1990 2007
11
Ukrainian Monitoring System
Long term variability of the Water Samples Number during 2000 – 2007 years
0
20
40
60
80
100
120
2000 2001 2002 2003 2004 2005 2006 2007
O2PO4
NH4
NO2NO3
12
Range of variations of main chemical quality parameters in the surface (a) and bottom layer (b) of national waters in 2007
O2
μM
PO4
μM
Ptotal
μM
NO3
μM
NO2
μM
NH4
μM
Ntotal
μM
SiO4
μM
TSSμM
Secci
Min 164 0,04 0,04 0,00 0,01 0,00 23,9 13,0 0,50 3,0
Max 388 14,8 14,85 71,39 21,42 132,1 53,6 23,2 38,0 7,0
O2
μM
O2 (%)
PO4
μM
Ptotal
μM
NO3
μM
NO2
μM
NH4
μM
Ntotal
μM
SiO4
μM
TSSμM
Min 74 32 0,09 0,67 0,33 0,03 0,14 26,3 14,6 1,9
Max 340 75 0,32 7,55 10,98 1,98 1,47 36,6 16,8 4,8
a
b
13
Long term variability of the average annual concentrations of P(PO4), (µmol/l P)
2000 2001 2001 2003 2004 2005 2006 2007
Kerch
Port "Odessa"Port Illichivsk
Port UzhnyiWWTP "Pivdenna"
WWTP "Pivnichni"
0
5
10
15
20
25
30
35
14
Long term variability of the average annual concentrations of N(NO2), (µmol/l N)
2000 2001 2002 2003 2004 2005 2006 2007
Kerch
Port "Odessa"Port Illichivsk
Port UzhnyiWWTP "Pivdenna"
WWTP "Pivnichni"
0
2
4
6
8
10
12
14
16
15
Long term variability of the average annual concentrations of N (NO3), (µmol/l N)
2000 2001 2002 2003 2004 2005 2006 2007
Kerch
Port "Odessa"Port Illichivsk
Port UzhnyiWWTP "Pivdenna"
WWTP "Pivnichni"
0
10
20
30
40
50
60
70
80
90
16
Long term variability of the average annual concentrations of N(NH4), (µmol/l N)
2000 2001 2002 2003 2004 2005 2006 2007
Kerch
Port "Odessa"Port Illichivsk
Port UzhnyiWWTP "Pivdenna"
WWTP "Pivnichni"
0
10
20
30
40
50
60
70
80
90
100
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Toxic pollution of the marine environment
0%
10%
20%
30%
40%
50%
60%
70%
80%
90%
100%
7 8 9 10 11No of station
6-rings
5-rings
4-rings
3-rings
2-rings
2000 2001 2002 2003 2004 2005 2006 2007
Kerch
Port "Odessa"
Port Illichivsk
Port Uzhnyi
WWTP "Pivdenna"WWTP "Pivnichni"
0
5
10
15
20
25
18
Long term variability of the Water Samples Number of Total petroleum hydrocarbons during 2000 – 2007 years
2000 2001 2002 2003 2004 2005 2006 2007
Kerch
Port "Odessa"
Port Illichivsk
Port Uzhnyi
WWTP "Pivdenna"WWTP "Pivnichni"
0
5
10
15
20
25
19
Long term variability of the Water Samples Number of Detergents during 2000 – 2007 years
2000 2001 2002 2003 2004 2005 2006 2007
Kerch
Port "Odessa"
Port Illichivsk
Port Uzhnyi
WWTP "Pivdenna"WWTP "Pivnichni"
0
5
10
15
20
25
20
Long term variability of the average annual concentrations of Total petroleum hydrocarbons, (mg/dm3)
2000 2001 2002 2003 2004 2005 2006
Kerch
Port "Odessa"
Port Illichivsk
Port Uzhnyi
WWTP "Pivdenna"
WWTP "Pivnichni"
0,00
0,01
0,02
0,03
0,04
0,05
0,06
0,07
0,08
0,09
0,10
2007
21
PAHsNumberof ring
Concentrations of PAHs, µg/kg
No 7WWTP
Pivnichna
No 8Cape
“Large Fountain”
No 9Illichivsk
portMouth
No 10Damping
place
No 11Damping
place
Naphtalene 2 18,2 <0,1 3,3 24,1 2,3
Acenaphthylene 3 0 <0,1 3,2 7,1 2,5
Acenaphthene 3 <0,1 <0,1 2 7 2
Fluorene 3 22,7 <0,1 5,8 167,4 7,1
Phenanthrene 3 236 37,2 44,6 114 51,4
Anthracene 3 46,4 5,7 6,0 20,9 7,4
Fluoranthene 4 406 89,5 103 232 128
Pyrene 4 322 66,0 81,5 174 98,1
Benzo(a)anthracene 4 201 39,9 40,1 86,2 39,9
Chrysene 4 228 59,3 60,1 121 67,1
Benzo(b)fluoranthrene 5 244 87,0 99,1 172 118
Benzo(k)fluoranthrene 5 169 54,0 79,4 144 67,2
Benzo(a)pyrene 5 239 58,5 12,0 20,7 10,6
22
PAHsNumberof ring
Concentrations of PAHs, µg/kg
No 7WWTP
"Pivnichna"
No 8Cape
“Large Fountain”
No 9Illichivsk
portMouth
No 10Damping
place
No 11Damping
place
Benzo(g,h,i)perylene 6 138 48,0 62,7 108 62,6
Dibenzo(a,h)anthracene 5 31,8 5,8 12,0 20,7 10,6
Indeno(1,2,3cd)pyrene 174 62,6 83,8 144 82,9
Σ PAHs 2476 614 699 1563 758
ΣCarc. PAHs 1425 415 449 817 459
Σcarc./Σ PAHs * 100 58 68 64 52 61
Phenanthrene/Anthracene 5,1 6,5 7,4 5,4 6,9
Fluoranthene/Pyrene 1,3 1,4 1,3 1,3 1,3
23
Distribution of PAHs according numbers of ring in molecule
0%
10%
20%
30%
40%
50%
60%
70%
80%
90%
100%
7 8 9 10 11No of station
6-rings
5-rings
4-rings
3-rings
2-rings
24
Ukrainian Monitoring SystemNational institutions involved in 2007
• UkrSCES - the Ukrainian Scientific Center of Ecology of the Sea, Ministry of the Environment Protection;
• SEINWRBS - State Ecological Inspection of Environmental Protection of the Black sea's North-West region, Ministry of the Environment Protection.
25
Quality Assurance /Quality Control
The two laboratories of department of analytical research of UkrSCES and department of analytical control of SEINWRBS which involved into international marine monitoring system are accredited by the Ukrainian standardization organization.
26
Summary of quality control procedures routinely employed within the laboratory
Use of high quality analytical standards for instrument calibration.
Use of high quality glassware, acids and other reagent and equipment.
Routine calibration and adjustments of AAS and maintance of continuous records of these calibrations.
Routine performance tests including complete procedural blank analyses and spikes
Use of certified reference material and performance of quality control chart.
Use of replicate samples.
RAC PMA in 2007 takes part in the Black Sea intercomparison exercis: QUASIMEME and BSERP Intercalibration Exercise, Round 50 (nutrients in water, organic pollutants in bottom sediments).
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International Projects
http://www.cadses.net/projects/apprpro.html
UkrSCES
• “Spatial Planning in Coastal zones”: works concerning the analysis of the current policy, the legislative basis of procedures of the role of spatial planning within the frameworks of ІCZM and sea use planning in Ukraine are under development, the national report concerning these certain problems is being prepared.
• “Black Sea Scientific Network” within the framework of the specific research and technological development programme “Structuring the European Research Area”. Works on filling in the interactive DB “Scientists UkrSCES”, “Publications UkrSCES” and DB Socio-Economic – socio-economic data of Ukrainian coastal areas were fulfilled.
28
Data processing resources of UkrSCES at the moment (financial support EU PlanCoast)
Router
Windows 2003 Server UkrSCES LAN
Powerful FirewallWeb server
Switch
Windows 2003 Server Mirror 11 modernworkstations
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Resources of UkrSCES (planned)
Router
Windows 2003 Server
UkrSCES LAN
Powerful Firewall
Switch
Windows 2003 Server Mirror
+11 work stations
Database server
Web server
Workgroup server
+15 work stations
DMZ
DMZ
30
Current State
DATABASEon SQL server
IMSserver
WWWserver
Scientificvessels
Analyticlaboratories
31
Example of www.sea.gov.ua
32
Main Publications of the Monitoring and Assessment Results
I.G.Orlova, N.E.Pavlenko, V.V.Ukrainsky, J.I.Popov EUTROPHICATION STATE OF THE NORTH-WESTERN PART OF THE BLACK SEA BY RESULTS OF LONG-TERM
COMPLEX MONITORING //Collection " Ecological safety of coastal and shelf zones and complex use of resources of the shelf ", Release 15, Sevastopol, 2007
Yu. Denga, V. Michaylov M. Monashko, V. Piatakova Filophora field of the Black Sea, - Environment 2007: Actual problems of ecology and hydrometeorology, integration of education and
science. Odessa, 2007, 53 p. Kostylev Ed.F., Tretiak I.P. LET'S RESTORE ZERNOV’S PHYLLOPHORA FIELD // Ecological journal “Alive Ukraine”. №01-02, 2007. Rachinskaya A.V. PECULIARITY OF COASTAL MICROPHYTOBENTHOS COMMUNITY STRUCTURE IN AREA OF DRAINAGE WATERS
INFLUENCE // International scientific-practical conference “Ecological problems of the Black Sea” (31 May - 1 June 2007, Оdessa): - Оdessa, 2007. P. 276-280.
Kovalishina S.P., Dudnik D. S. THE CHARACTERISTIC OF A ZOOPLANKTON OF ESTUARY DNEPRO-BUGSKOGO AND ADJOINING WATER AREAS. //
The international scientifically-practical conference «Aktualne of a problem of ecology - 2007» (Belarus, Grodno, November 2007) Loeva I.D., Orlova I.G., Pavlenko N.E., Ukrainsky V.V., Komorin V.N. THE STATE OF EKOSYSTEM OF THE BLACK SEA ON RESULTS LONG PERIOD OF THE ECOLOGICAL
MONITORING. //Living Ukraine. Ecological magazine. № 01-02.2007 С. 13-15. Chervonyk V.V., Popov Y.I., Ukrainsky V.V. CHANGEABILITY OF TERMOKHALINNYKH DESCRIPTIONS OF THE OVERHEAD MIXED LAYER AND FRONTAL
SECTIONS IS IN WESTERN PART OF THE BLACK SEA. // Ecological problems of the Black sea. Odessa. on 31 May - 01 June 2007. ICSTI 2007 - page 374-377.
G.E. Shulman, V.N Nikolsky, T.V Yuneva, A.M. Shchepkina, A.E. Kideys. INFLUENCE OF GLOBAL CLIMATIC AND REGIONAL ANTHROPOGENIC FACTORS ON SMALL PELAGIC FISHES OF
BLACK SEA. // MARINE ECOLOGICAL JOURNAL, N4 Fomin V.V., Ivanov V.A.Coulping THERMODYNAMICS OF THE OCEAN. MODELING OF CURRENT AND WIND WAVES IN THE KERCH CANNEL //
MARINE HYDROPHYSICAL JOURNAL, N 5 Demyshev S.G., Dymova O.A., Cherkesov L.V. NUMERICAL SIMULATION OF THE FLOWS IN THE BASIN WITH TWO STRAITS// MARINE HYDROPHYSICAL
JOURNAL N4
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Principal Document Regional Activity Center for Pollution Monitoring and Assessment (RAC PMA),
Odessa, Ukraine DRAFT
34
Principal Document RAC PMA1.The Ukrainian Scientific Center of Ecology of the Sea
(UkrSCES) is a Regional Activity Center for Pollution Monitoring and Assessment (RAC PMA) in accordance to the “Strategic Action Plan for the Rehabilitation and Protection of the Black Sea ” (BS- SAP)
2. The purpose of the RAC PMA is to provide support to AG PMA and together with the AG PMA deals with organizational , scientific-methodical and technical functioning of the Regional Monitoring System and conducts the assessment of pollution of the Black Sea within the framework of the Black Sea Ecological Program (BSEP) and the support for implementation of the Bucharest Convention.
3. The Head of the RAC PMA is Director of UkrSCES.
35
Principal Document RAC PMA4. RAC PMA tasks: information and scientific-methodical support of the Permanent
Secretariat of the Black Sea Commission and Coordinating Council of the BSEP program on assessment, diagnosis and forecasting of the Black Sea environment;
scientific-methodical support of the activities of the Black Sea international monitoring system;
analyze the information obtained by Secretariat of the Black Sea Commission from the National Centers of Monitoring, preparation a review about the State of Environment of the Black Sea for AG PMA and the Permanent Secretariat;
organization of the interactive mapping service for customers via WWW standard through IMS processing.
36
Proposals to the decision of the 18-th Meeting of AG PMA
Permanent Secretariat Commission on the Protection of the Black Sea Against Pollution and RAC PMA :
to work out and approve the Concept Document (Terms of reference) for RAC PMA;
to make the most out of the data processing resources of RAC PMA for technical, information and programmatic support of AG PMA and Permanent Secretariat;
within the work plan of the Secretariat foresee organization and financing of the annual international expedition covering the Black Sea in the whole within the framework of fulfilling of the Regional monitoring
37
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