i

南京大学固体微结构物理

国家重点实验室

主 任 王 牧

副主任 王强华

桑 海

刘 辉

殷 江

实验室

办公室主任

实验室

主任助理

张文俊

郝西萍

吴 军

地 址： 南京市汉口路 22 号

邮 编： 210093

电 话： 86-25-83592756

传 真： 86-25-83595535

Email： lssms@nju.edu.cn

网 址： https://vlssm.nju.edu.cn

目 次

实验室概况………………………………………………………………………………………………….. 1

第八届学术委员会委员名单…………………………………....................................... 2

2013年实验室工作总结…………………………………………………………………………… 3

2013 年优秀论文精选 (Selected papers published in 2013)………. 18

1 Qiu H, Xu T, Wang ZL, Ren W, Nan HY, Ni ZH, Chen Q, Yuan SJ, Miao

F, Song FQ, Long G, Shi Y, Sun LT, Wang JL, Wang XR, Hopping

transport through defect-induced localized states in molybdenum

disulphide, Nature Communications 4, 2642(2013).............................

19

2 Yang H, Wang ZY, Fang DL, Deng Q, Wang QH, Xiang YY, Yang Y,

Wen HH, In-gap quasiparticle excitations induced by non-magnetic Cu

impurities in Na(Fe0.96Co0.03Cu0.01)As revealed by scanning tunnelling

spectroscopy, Nature Communications 4, 2749(2013)….....................

25

3 Wen Z, Li C, Wu D, Li AD, Ming NB, Ferroelectric-field-effect-

enhanced electroresistance in metal/ferroelectric/semiconductor tunnel

junctions, Nature Materials 12, 617-621(2013)……………………….

32

4 Sheng C, Liu H, Wang Y, Zhu SN, Genov DA, Trapping light by

mimicking gravitational lensing, Nature Photonics 7, 902-906(2013)...

37

5 Wang ZY, Yang H, Fang DL, Shen B, Wang QH, Shan L, Zhang CL,

Dai PC, Wen HH, Close relationship between superconductivity and the

bosonic mode in Ba0.6K0.4Fe2As2 and Na(Fe0.975Co0.025)As, Nature

Physics 9, 42-48(2013)…………………………………………………

49

6 Li L, Li T, Wang SM, Zhu SN, Collimated plasmon beam:

Nondiffracting versus linearly focused, Physical Review Letters 110,

046807(2013)…………………………………………………………...

56

7 Jin H, Xu P, Luo XW, Leng HY, Gong YX, Yu WJ, Zhong ML, Zhao G,

Zhu SN, Compact engineering of path-entangled sources from a

monolithic quadratic nonlinear photonic crystal, Physical Review

Letters 111, 023603(2013)………………..……………………………

61

8 Sun L, Cao RX, Miao BF, Feng Z, You B, Wu D, Zhang W, Hu A, Ding

HF, Creating an artificial two-dimensional Skyrmion crystal by

nanopatterning, Physical Review Letters 110, 167201(2013)………...

66

9 Wu S, Zhang Z, Zhang Y, Zhang KY, Zhou L, Zhang XJ, Zhu YY,

Enhanced rotation of the polarization of a light beam transmitted

through a silver film with an array of perforated S-shaped holes,

Physical Review Letters 110, 207401(2013)…………………………..

71

10 Li HC, Sheng L, Shen R, Shao LB, Wang BG, Sheng DN, Xing DY,

Stabilization of the quantum spin Hall effect by designed removal of

time-reversal symmetry of edge states, Physical Review Letters 110,

266802(2013)…………………………………………………………...

76

National Lab of Solid State Microstructures

ii

National Lab of Solid State

Microstructures

Nanjing University

Director Mu WANG

Deputy

Director

Qianghua WANG

Hai SANG

Hui LIU

Jiang YIN

Director of

the Office

Assistant to

the Director

Wenjun ZHANG

Xiping HAO

Jun WU

Address: 22 Hankou Road

Nanjing, China

Zip Code： 210093

Tel: 86-25-83592756

Fax: 86-25-83595535

Email: lssms@nju.edu.cn

Web

Address:

http://vlssm.nju.edu.cn

11 Sun J, Martinez-Canales M, Klug DD, Pickard CJ, Needs RJ, Stable

all-nitrogen metallic salt at terapascal pressures, Physical Review

Letters 111, 175502(2013)……………………………………………..

81

12 Zhu SL, Wang ZD, Chan YH, Duan LM, Topological Bose-Mott

insulators in a one-dimensional optical superlattice, Physical Review

Letters 110, 075303(2013)……………………………………………..

86

13 Liu YL, Zhang CF, Zhang HC, Wang R, Hua Z, Wang XY, Zhang JY,

Xiao M, Broadband optical non-linearity induced by charge-transfer

excitons in type-II CdSe/ZnTe nanocrystals, Advanced Materials 25,

4397-4402(2013)……………………………………………………….

91

14 Sun M, Xiong SJ, Wu XL, He CY, Li TH, Chu PK, Enhanced

photocatalytic oxygen evolution by crystal cutting, Advanced

Materials 25, 2035-2039(2013)………………………………………..

97

15 Xiong X, Jiang SC, Hu YH, Peng RW, Wang M,Structured metal film as

a perfect absorber, Advanced Materials 25, 3994-4000(2013)………

116

2013 年发表论文摘要(Abstract list of publications in 2013)………. 123

I Science and Engineering of Artificial

Microstructures

124

1 Friction and wear performance of the 0.5Ba(Ti0.8Zr0.2)O-3-

0.5(Ba0.7Ca0.3)TiO3 piezoelectric film, Zhang Y, Wang ZM, Chen YF,

Guo XL, Sun W, Yuan GL, Yin J, Liu ZG, Acta Physica Sinica 62,

066802(2013)…………………………………………………………...

124

2 Structured metal film as a perfect absorber, Xiong X, Jiang SC, Hu YH,

Peng RW, Wang M, Advanced Materials 25, 3994-4000(2013)………

124

3 A new type of artificial structure to achieve broadband omnidirectional

acoustic absorption, Zheng LY, Wu Y, Zhang XL, Ni X, Chen ZG, Lu

MH, Chen YF, AIP Advances 3, 102122(2013)………………………..

124

4 Kinetics of linear domains in LiNbO3 single crystals polarized by

scanning probe microscopy, Bo HF, Jin YM, Xu TT, Du YC, Kan Y, Lu

XM, Zhu JS, Applied Physics Letters 103, 252903(2013)…………….

124

5 Subwavelength imaging through spoof surface acoustic waves on a

two-dimensional structured rigid surface, Jia H, Lu MH, Wang QC,

Bao M, Li XD, Applied Physics Letters 103, 103505(2013)………….

125

6 Electric field control of magnetic properties in CoPt/Pb(Mg1/3Nb2/3)O-

3-PbTiO3 heterostructure at room temperature, Yang YT, Zhang QM,

Wang DH, Song YQ, Wang LY, Lv LY, Cao QQ, Du YW, Applied

Physics Letters 103, 082404(2013)……………………………………

125

7 In-situ observation of nanomechanical behavior arising from critical-

temperature-induced phase transformation in Ba(Zr0.2Ti0.8)O-3-

0.5(Ba0.7Ca0.3)TiO3 thin film, Wang ZM, Cai ZL, Zhao K, Guo XL,

Chen J, Sun W, Cheng ZX, Kimura H, Li BW, Yuan GL, Yin J, Liu ZG,

Applied Physics Letters 103, 071902(2013)…………………………..

125

8 Core-shell magnetic exchange model for Co3O4 nanowires, Chen L,

Yang YR, Meng XK, Applied Physics Letters 102, 203102(2013)……

125

9 Oblique metal gratings transparent for broadband terahertz waves, Fan

RH, Li J, Peng RW, Huang XR, Qi DX, Xu DH, Ren XP, Wang M,

Applied Physics Letters 102, 171904(2013)……..................................

125

Annual Report 2013——Content

iii

10 Significant ferrimagnetisms observed in superlattice composed of antiferromagnetic LaFeO3 and YMnO3, Chen YB,

Zhou J, Zhang ST, Wu FX, Yao SH, Gu ZB, Wu D, Chen YF, Applied Physics Letters 102, 042403(2013)…………...

126

11 Detecting p-type conduction in Ba-doped InN, Xie QY, Xie WM, Wang JL, Zhu HP, Yang JH, Sun L, Wu XS, Applied

Physics Letters 102, 042109(2013)…………………………………………………………………………....……….

126

12 Peculiarity of magnetoresistance in high pressure annealed Ni43Mn41Co5Sn11 alloy, Ma SC, Wang DH, Zhong ZC, Luo

JM, Xu JL, Du YW, Applied Physics Letters 102, 032407(2013)……………………………………………………...

126

13 Fabrication of stereo metallic resonant structures with polymer droplets as template, Chen XC, Wu YW, Hu YH, Li

HM, Peng RW, Hao XP, Wang M, Applied Physics Letters 102, 021904(2013)…………………………....................

126

14 Electrical behaviors of c-axis textured 0.975Bi(0.5)Na(0.5)TiO(3)-0.025BiCoO(3) thin films grown by pulsed laser

deposition, Guo FF, Yang B, Zhang ST, Liu DQ, Wu FM, Wang DL, Cao WW, Applied Surface Science 283, 759-763

(2013).…………………………………………………………………………………………………………………...

127

15 TEM study of SrIrO3 thin films with various thicknesses grown on (001) SrTiO3 substrates synthesized by pulsed laser

deposition, Zhang LY, Wu HY, Zhou J, Wu FX, Chen YB, Yao SH, Zhang ST, Chen YF, Applied Surface Science

280, 282-286(2013)……………………………………………………………………………………………………...

127

16 Surface-roughness-assisted formation of large-scale vertically aligned CdS nanorod arrays via solvothermal method,

Zhou MM, Yan SC, Shi Y, Yang M, Sun HB, Wang JY, Yin Y, Gao F, Applied Surface Science 273, 89-93(2013)……

127

17 The structures and positive magnetoresistance of metallic Sr2CrWO6 epitaxial thin film, Ji WJ, Xu J, Jiao L, Wang

JF, Gu ZB, Chen YB, Zhou J, Yao SH, Zhang ST, Ceramics International 39, 9305-9308(2013)……………………

128

18 Phase transition, microstructure and electrical properties of Fe doped Ba0.70Ca0.30TiO3 lead-free piezoelectric

ceramics, Li CX, Yang B, Zhang ST, Zhang R, Sun Y, Wang JJ, Wang RX, Cao WW, Ceramics International 39,

8701-8708(2013)………………………………………………………………………………………………………...

128

19 Effects of 5d Ir-substitution on structures, transport and magnetic properties of Sr2FeMoO6, Wang JF, Li Z, Zhang ST,

Zhou J, Gu ZB, Yao SH, Chen YB, Chen YF, Ceramics International 39, 5863-5868(2013)…………………………

128

20 Effects of sintering temperature and poling conditions on the electrical properties of Ba0.70Ca0.30TiO3 diphasic

piezoelectric ceramics, Li CX, Yang B, Zhang ST, Zhang R, Cao WW, Ceramics International 39, 2967-2973(2013).

129

21 Optical study of Ba(MnxTi(1-x)O3) thin films by spectroscopic ellipsometry, Zhang T, Yin J, Ding LH, Zhang WF,

Chinese Physics B 22, 117801(2013)…………...………………………………………………………………………

129

22 Martensitic transformation and related magnetic effects in Ni-Mn-based ferromagnetic shape memory alloys, Wang

DH, Han ZD, Xuan HC, Ma SC, Chen SY, Zhang CL, Du YW, Chinese Physics B 22, 077506(2013)…………..……

129

23 Optical isolation by time-dependent sinusoidal-shaped structures, Xu YL, Feng L, Lu MH, Chen YF, Chinese

Physics Letters 30, 094202(2013) ……………………………………………………………………………………..

129

24 Variable cell nudged elastic band method for studying solid-solid structural phase transitions, Qian GR, Dong X,

Zhou XF, Tian YJ, Oganov AR, Wang HT, Computer Physics Communications 184, 2111-2118(2013)….………….

130

25 The microstructure and magnetic property of TiO2-terminated SrTiO3 substrate selected growth cubic phase CaRuO3

film, Zhang LY, Zhou J, Zhang ST, Chen YB, Chen YF, Crystal Research and Technology 48, 546-554(2013)……..

130

26 Shape-controlled hydrothermal synthesis of ferroelectric Bi4Ti3O12 nanostructures, Wang F, Wang JB, Zhong XL, Li

B, Liu J, Wu D, Mo D, Guo DY, Yuan SG, Zhang KD, Zhou YC, Crystengcomm 15, 1397-1403(2013)……………..

130

27 Quantitative control of Fe/Mo anti-site defect and its effects on the properties of Sr2FeMoO6, Wang JF, Xu XJ, Ji WJ,

Zhang ST, Zhou J, Gu ZB, Chen YB, Yuan GL, Yao SH, Chen YF, Crystengcomm 15, 4601-4605(2013)……………

131

28 High temperature solution growth, chemical depotassiation and growth mechanism of KxRhO2 crystals, Zhang BB,

Dong ST, Chen YB, Zhang LY, Zhou J, Yao H, Gu ZB, Zhang ST, Chen YF, Crystengcomm 15, 5050-5056(2013)…...

131

29 Electrochemical study of Ni deposition on carbon microfiber, Song SQ, Liu Z, Ortega CM, Wu XS, Sun L,

Electrochimica Acta 94, 252-258(2013)………………………………………………………………………………..

131

30 Lattice dynamics and electron-phonon interaction in Bi/Bi2Te3 (111) heteroepitaxial film, Huang GQ, Li B, EPL 104,

57003(2013)…………………................................................................................................................................... .......

131

31 Multi-tip nano-prisms: Controlled growth and emission enhancement properties, Liu M, Meng C, Xue ZH, Xiong X,

Shu DJ, Peng RW, Wu Q, Hu Z, Wang M, EPL 104, 18004(2013)……………………………………………………..

132

32 Temperature dependent exchange bias effect in polycrystalline BiFeO3/FM (FM = NiFe, Co) bilayers, Xue XB, Yuan

XY, Rui WB, Xu QY, You B, Zhang W, Zhou SM, Du J, European Physical Journal B 86, 121(2013)……………..

132

National Lab of Solid State Microstructures

iv

33 Dipole polarizabilities of Pd-N (N=2-25) clusters, Ma L, Wang JG, Wang GH, European Physical Journal D 67, 6

(2013)……………………………………………………………………………………………………………………

132

34 Ferroelectric behavior and magnetocapacitance effect caused by Fe2+ in Ho3Fe5O12 ceramics, Su J, Guo YF, Zhang

JT, Sun H, He J, Lu XM, Lu CJ, Zhu JS, Ferroelectrics 448, 71-76(2013)……………………………………………..

132

35 A novel co-templating method for hierarchical mesoporous alumina monoliths replica, Tang SK, Cui XL, Gu L, Zhou

H, Zhang XW, Functional Materials Letters 6, 1350059(2013)………….....................................................................

133

36 Metallic grating on a D-shaped fiber for refractive index sensing, Yan HT, Liu Q, Ming Y, Luo W, Chen Y, Lu YQ,

IEEE Photonics Journal 5, 4800706(2013)……………………………………………………………………………

133

37 Intrinsically modified thermoelectric performance of alkaline-earth isovalently substituted [Bi(2)AE(2)O(4)][CoO2](y)

single crystals, Sun N, Dong ST, Zhang BB, Chen YB, Zhou J, Zhang ST, Gu ZB, Yao SH, Chen YF, Journal of

Applied Physics 114, 043705(2013)……………………….……………………………………………………………

133

38 Room temperature ferromagnetism in triple perovskite Sr3CrFeMoO9, Jiao L, Xu J, Li Z, Wang JF, Zhou J, Gu ZB,

Zhang ST, Journal of Materials Science-Materials in Electronics 24, 4970-4973(2013)……………………………

134

39 Morphotropic phase boundary and electric properties in (1-x)Bi0.5Na0.5TiO3-xBaSnO(3) lead-free piezoelectric

ceramics, Jiao L, Guo FF, Wang JF, Gu ZB, Zhang ST, Yang B, Journal of Materials Science-Materials in

Electronics 24, 4080-4084(2013)……………………………………………………………………………………….

134

40 Tunable multimode and narrowband in a photonic quasicrystal waveguide, Hu Q, Sun LY, Xu DH, Zhou Y, Peng RW,

Wang M, Journal of Nanoscience and Nanotechnology 13, 873-877(2013)………………………………………….

134

41 Magnetic vortex core dynamics in correlated double plates of permalloy, Li J, Hu Q, Zhang RL, Peng RW, Wang M,

Journal of Nanoscience and Nanotechnology 13, 1043-1046(2013)…...…………………………………………….

134

42 Influence of the interlayer on coupling of surface plasmons in a sandwiched structure with periodic array of

nanoapertures, Sun LY, Qin L, Zhu LH, Fan RH, Li D, Peng RW, Journal of Nanoscience and Nanotechnology 13,

1237-1240(2013)………………………………………………………………………………………………………..

135

43 A detector of an invisible carpet cloaking structure, Wang DL, Hu Q, Dong YQ, Peng RW, Journal of Nanoscience

and Nanotechnology 13, 984-988(2013)……..………………………………………………………………………...

135

44 Metal-insulator transition in SrIrO3 with strong spin-orbit interaction, Wu FX, Zhou J, Zhang LY, Chen YB, Zhang

ST, Gu ZB, Yao SH, Chen YF, Journal of Physics-Condensed Matter 25, 125604(2013)……....................................

135

45 Hybridized effects of plasmonic quadrupolar and dipolar resonances on the perforated planar metallic film, Wu S,

Zhou L, Wang QJ, Zhang XJ, Zhu YY, Journal of Physics D-Applied Physics 46, 065302(2013)…………………….

135

46 Structures, chemical states and properties of Sr2Fe1+xMo1-xO6 ceramics sintered in N-2, Ji WJ, Wang JF, Xu J, Jiao L,

Zhou J, Chen YB, Gu ZB, Yao SH, Zhang ST, Chen YF, Journal of Physics D-Applied Physics 46, 015001(2013).....

136

47 Structural evolving sequence and porous Ba6Zr2Nb8O30 ferroelectric ceramics with ultrahigh breakdown field and

zero strain, Zhang ST, Yuan GL, Chen J, Gu ZB, Yang B, Yin J, Cao WW, Journal of The American Ceramic

Society 96, 555-560(2013)………………………………………………………………………………………………

136

48 Coupled magnetic resonator optical waveguides, Liu H, Zhu SN, Laser & Photonics Reviews 7, 882-900(2013)…... 136

49 2.95 mu m luminescence from a Ho3+, Pr3+ double-doped LiLuF4 optical crystal, Zhang PX, Hang Y, Zhao CC, Zhang

LH, Zhu YY, Laser Physics 23, 115802(2013)………………………………………………………………………….

136

50 Optical spectroscopy of Nd3+/Mg2+ co-doped LiTaO3 laser crystal, Zhang PX, Hang Y, Gong J, Zhao CC, Yin JG,

Zhang LH, Zhu YY, Laser Physics 23, 015803(2013)………………………………………………………………….

137

51 Ordering of gold nanorods in confined spaces by directed assembly, Li WK, Zhang P, Dai M, He J, Babu T, Xu YL,

Deng RH, Liang RJ, Lu MH, Nie ZH, Zhu JT, Macromolecules 46, 2241-2248(2013)………………………………..

137

52 Modification of spontaneous emission from fluorescent spheres by partially disordered photonic crystals, Liu ZQ, Liu

GQ, Chen YH, Huang K, Hu Y, Zhang XN, Cai ZJ, Liu XS, Fu GL, Materials Letter 101, 44-46(2013)……………....

137

53 Highly effective and reproducible surface-enhanced Raman scattering substrates based on Ag pyramidal arrays,

Wang YD, Lu N, Wang WT, Liu LX, Feng L, Zeng ZF, Li HB, Xu WQ, Wu ZJ, Hu W, Lu YQ, Chi LF, Nano

Research 6, 159-166(2013)...…………………………………………………………………………………………...

138

54 Experimental demonstration of a unidirectional reflectionless parity-time metamaterial at optical frequencies, Feng L,

Xu YL, Fegadolli WS, Lu MH, Oliveira JEB, Almeida VR, Chen YF, Scherer A, Nature Materials 12, 108-113

(2013)……………………………………………………………………………………………………………………

138

Annual Report 2013——Content

v

55 Trapping light by mimicking gravitational lensing, Sheng C, Liu H, Wang Y, Zhu SN, Genov DA, Nature Photonics

7, 902-906(2013)…………………………………...........................................................................................................

138

56 Low-voltage-modulated laser based on dye-doped polymer stabilized cholesteric liquid crystal, Liu BW, Zheng ZG,

Chen XC, Shen D, Optical Materials Express 3, 519-526(2013)……………………………………………………..

139

57 Controlled disorder effect on the structure, bandgap and emission modification of three-dimensional photonic

crystals, Liu ZQ, Liu GQ, Chen YH, Huang K, Zhang XN, Cai ZJ, Hu Y, Optics Communications 301, 34-38(2013)..

139

58 Subwavelength multiple focal spots produced by tight focusing the patterned vector optical fields, Cai MQ, Tu CH,

Zhang HH, Qian SX, Lou K, Li YN, Wang HT, Optics Express 21, 31469-31482(2013)……………………………...

139

59 Nonreciprocal resonant transmission/reflection based on a one-dimensional photonic crystal adjacent to the magneto-

optical metal film, He C, Sun XC, Zhang Z, Yuan CS, Lu MH, Chen YF, Sun C, Optics Express 21, 28933-28940

(2013)…………….……………………………………………………………………………………………………...

139

60 Vector optical fields with polarization distributions similar to electric and magnetic field lines, Pan Y, Li SM, Mao L,

Kong LJ, Li YN, Tu CH, Wang P, Wang HT, Optics Express 21, 16200-16209(2013)………………………………..

140

61 Optical forces in twisted split-ring-resonator dimer stereometamaterials, Tang CJ, Wang QG, Liu FX, Chen Z, Wang

ZL, Optics Express 21, 11783-11793(2013)……………………………………………………………………………

140

62 Broadband absorption and efficiency enhancement of an ultra-thin silicon solar cell with a plasmonic fractal, Zhu LH,

Shao MR, Peng RW, Fan RH, Huang XR, Wang M, Optics Express 21, A313-A323(2013)………………………….

140

63 Heralded generation of multipartite entanglement for one photon by using a single two-dimensional nonlinear

photonic crystal, Shi J, Xu P, Zhong ML, Gong YX, Bai YF, Yu WJ, Li QW, Jin H, Zhu SN, Optics Express 21,

7875-7881(2013)………………………………………………………………………………………………………..

141

64 Dual broadband near-infrared perfect absorber based on a hybrid plasmonic-photonic microstructure, Liu ZQ, Zhan

P, Chen J, Tang CJ, Yan ZD, Chen Z, Wang ZL, Optics Express 21, 3021-3030(2013)…………………………….…

141

65 Surface-enhanced fluorescence of a dye-doped polymer layer with plasmonic band edge tuning, Jiang JJ, Xu F, Xie

YB, Tang XM, Liu ZY, Zhang XJ, Zhu YY, Optics Letters 38, 4570-4573(2013)……………………………………..

141

66 Sharper focal spot generated by 4 pi tight focusing of higher-order Laguerre-Gaussian radially polarized beam, Chen

GY, Song F, Wang HT, Optics Letters 38, 3937-3940(2013)………………...................................................................

141

67 Vector optical fields with bipolar symmetry of linear polarization, Pan Y, Li YN, Li SM, Ren ZC, Si Y, Tu CH, Wang

HT, Optics Letters 38, 3700-3703(2013)…………………………….............................................................................

142

68 Controllable polarization coupled dual-focused second-harmonic generations in a two-dimensional optical

superlattice,Hong XH, Yang B, Zhu D, Zhang Z, Zhang C, Huang H, Qin YQ, Zhu YY, Optics Letters 38, 1793-1795

(2013)………………………………………………………………………………………………………....................

142

69 High-performance cavity-phase matching by pump reflection, Lin HB, Li SF, Sun YW, Zhao G, Hu XP, Lv XJ, Zhu

SN, Optics Letters 38, 1957-1959(2013)……………………………………………………………………………….

142

70 Converting surface plasmon to spatial Airy beam by graded grating on metal surface, Tang XM, Li L, Li T, Wang QJ,

Zhang XJ, Zhu SN, Zhu YY, Optics Letters 38, 1733-1735(2013)…………………………………………………….

142

71 Surface plasmon polaritons mediated by surface modes in a metal-based photonic crystal complex structure, Liu GQ,

Liu ZQ, Chen YH, Gong LX, Tang FL, Li L, Zhang XN, Hu Y, Huang K, Optik 124, 5135-5138(2013)…………….

142

72 The glass transition and crystallization of propylene carbonate investigated by mechanical spectroscopy, Ying XN,

Physica Scripta 88, 025603(2013)…………………………………………………………………………………….

143

73 Mechanical stress effect on the crystallization behavior of Ge2Sb2Te5 films studied by electrical resistance

measurement, Du YC, Kan Y, Lu XM, Liu YF, Bo HF, Cai W, Hu DZ, Huang FZ, Zhu JS, Physica Status Solidi-

Rapid Research Letters 7, 506-509(2013)…………………………………………………………………………….

143

74 Observing electronic structures on ex-situ grown topological insulator thin films, Yao SH, Zhou B, Lu MH, Liu ZK,

Chen YB, Analytis JG, Brune C, Dang WH, Mo SK, Shen ZX, Physica Status Solidi-Rapid Research Letters 7,

130-132(2013)…………………………………………………………………………………………………………..

143

75 How does the boron concentration affect hydrogen storage in lithium decorated zero- and two-dimensional boron-

carbon compounds? Ye XJ, Liu CS, Jia R, Zeng Z, Zhong W, Physical Chemistry Chemical Physics 15, 2507-2513

(2013)……………………………………………………………………………………………………………………

143

76 Cubic-quintic condensate solitons in four-wave mixing, Wu ZK, Zhang YQ, Yuan CZ, Wen F, Zheng HB, Zhang YP,

National Lab of Solid State Microstructures

vi

Xiao M, Physical Review A 88, 063828(2013)………………………………………………………………..………. 144

77 Nonlinear frequency conversion of fields with orbital angular momentum using quasi-phase-matching, Shao GH, Wu

ZJ, Chen JH, Xu F, Lu YQ, Physical Review A 88, 063827(2013)……………………………………………………..

144

78 Managing orbital angular momentum in second-harmonic generation, Li SM, Kong LJ, Ren ZC, Li YN, Tu CH,

Wang HT, Physical Review A 88, 035801(2013)……………………………………………..........................................

144

79 Fourier coupled-wave diffraction theory of periodic structures and crystals, Huang XR, Peng RW, Honnicke MG, Gog

T, Physical Review A 87, 063828(2013)………………………………………………………………………………..

145

80 Tuning the polarization state of light via time retardation with a microstructured surface, Jiang SC, Xiong X,

Sarriugarte P, Jiang SW, Yin XB, Wang Y, Peng RW, Wu D, Hillenbrand R, Zhang X, Physical Review B 88, 161104

(2013) ………..………………………………………………………………………………………………………….

145

81 Polarization-dependent perfect absorbers/reflectors based on a three-dimensional metamaterial, Xiong X, Xue ZH,

Meng C, Jiang SC, Hu YH, Peng RW, Wang M, Physical Review B 88, 115105(2013)………………………………

145

82 Topological phase transition in a graphene system with a coexistence of Coulomb interaction, staggered potential, and

intrinsic spin-orbit coupling, Cao J, Xiong SJ, Physical Review B 88, 085409(2013)…………………………………

145

83 Broadband antireflection and light-trapping enhancement of plasmonic solar cells, Fan RH, Zhu LH, Peng RW,

Huang XR, Qi DX, Ren XP, Hu Q, Wang M, Physical Review B 87, 195444(2013)…………………………………..

146

84 Optical-magnetism-induced transparency in a metamaterial, Qin L, Zhang K, Peng RW, Xiong X, Zhang W, Huang

XR, Wang M, Physical Review B 87, 125136(2013)..………………………………………………………………….

146

85 Microscopic view of the role of repeated polytypism in self-organization of hierarchical nanostructures, Liu M, Ma

GB, Xiong X, Wang ZW, Peng RW, Zheng JG, Shu DJ, Zhang ZY, Wang M, Physical Review B 87, 085306(2013)….

146

86 Compact engineering of path-entangled sources from a monolithic quadratic nonlinear photonic crystal, Jin H, Xu P,

Luo XW, Leng HY, Gong YX, Yu WJ, Zhong ML, Zhao G, Zhu SN, Physical Review Letters 111, 023603(2013)……

147

87 4-Methoxyanilinium perrhenate 18-crown-6: A new ferroelectric with order originating in swinglike motion slowing

down, Fu DW, Cai HL, Li SH, Ye Q, Zhou L, Zhang W, Zhang Y, Deng F, Xiong RG, Physical Review Letters 110,

257601(2013) ………………………….………………………………………………………………………………..

147

88 Enhanced rotation of the polarization of a light beam transmitted through a silver film with an array of perforated

S-shaped holes, Wu S, Zhang Z, Zhang Y, Zhang KY, Zhou L, Zhang XJ, Zhu YY, Physical Review Letters 110,

207401(2013)……………………………………………………………………………………………………………

147

89 Observation of temperature-induced crossover to an orbital-selective Mott phase in A(x)Fe(2-y)Se(2) (A = K, Rb)

superconductors, Yi M, Lu DH, Yu R, Riggs SC, Chu JH, Lv B, Liu ZK, Lu M, Cui YT, Hashimoto M, Mo SK,

Hussain Z, Chu CW, Fisher IR, Si Q, Shen ZX, Physical Review Letters 110, 067003(2013)………………………..

147

90 Collimated plasmon beam: Nondiffracting versus linearly focused, Li L, Li T, Wang SM, Zhu SN, Physical Review

Letters 110, 046807(2013)……………………………………………………………………………………………...

148

91 All-optical strong coupling switches based on a coupled meta-atom and MIM nanocavity configuration, Chen S, Liu

JQ, Lu HY, Zhu YY, Plasmonics 8, 1439-1434(2013)…………………………………………………………………..

148

92 Tunable plasmon-induced transparency of double continuous metal films sandwiched with a plasmonic array, Liu ZQ,

Liu GQ, Liu XS, Huang K, Chen YH, Hu Y, Fu GL, Plasmonics 8, 1285-1292(2013)………………………………..

148

93 Synthesis of epoxy resin based on biphenyl structure for application in carbon fiber-reinforced composites, Zhou YZ,

Ren H, Lu HB, Meng XK, Polymer-Plastics Technology and Engineering 52, 581-585(2013)…………...………….

149

94 The two-photon interference mediated by the magnetic resonance in two-dimensional metamaterial, Wang SM, Mu

SY, Zhu C, Gong YX, Xu P, Liu H, Zhu SN, Zhang X, Quantum Information Processing 12, 825-830(2013)……….

149

95 Making structured metals transparent for broadband electromagnetic waves, Meng C, Peng RW, Fan RH, Huang XR,

Wang M, Science China-Information Sciences 56, 120404(2013)…………………………………………………….

149

96 Excitation of coherent plasmon modes in a polymer structure with side resonators, Zhu C, Liu H, Sheng C, Gao F,

Wang Q, Zhu SN, Science China-Information Sciences 56, 120409(2013)…………………………………………..

149

97 Large-area surface-enhanced Raman scattering-active substrates fabricated by femtosecond laser ablation, Zhu ZQ,

Yan ZD, Zhan P, Wang ZL, Science China-Physics Mechanics & Astronomy 56, 1806-1809(2013)………………...

150

98 Sodium guide star laser generation by single-pass frequency doubling in a periodically poled near-stoichiometric

LiTaO3 crystal, Yuan Y, Zhang L, Liu YH, Lu XJ, Zhao G, Feng Y, Zhu SN, Science China-Technological Sciences

Annual Report 2013——Content

vii

56, 125-128(2013)………………………………………………………………………………………………………. 150

99 Active display and encoding by integrated plasmonic polarizer on light-emitting-diode, Wang L, Li T, Guo RY, Xia W,

Xu XG, Zhu SN, Scientific Reports 3, 2603(2013)…………………………………………………………………….

150

100 Femtosecond laser processing by using patterned vector optical fields, Lou K, Qian SX, Ren ZC, Tu CH, Li YN,

Wang HT, Scientific Reports 3, 2281(2013)……………………………………………………………………………

150

101 Triple perovskite Sr3CrFeMoO9 ultrathin films with ferromagnetism above room temperature, Li Z, Jiao L, Ji WJ, Xu

J, Wang JF, Gu ZB, Zhou J, Yao SH, Chen YB, Zhang ST, Chen YF, Scripta Materialia 69, 590-593(2013)………….

150

102 Charge order suppression in oxygen nonstoichiometric La1/3Sr2/3FeO3-delta, Ying XN, Solid State Communications

169, 20-23(2013)………………………………………………………………………………………………………..

151

103 Thickness dependent microstructures and properties of Sr2Fe10/9Mo8/9O6 films grown in N-2, Ji WJ, Xu J, Zhang ST,

Chen YB, Zhou J, Gu ZB, Yao SH, Chen YF, Solid State Communications 163, 28-32(2013)………………………

151

104 Polarization tuning of third-harmonic generation by coupling of two types of quasi-phase-matched quadratic

processes, Zhu D, Zhang C, Qin YQ, Lv XJ, Zhu YY, Solid State Communications 163, 37-40(2013)………………

151

105 Macrotribological behavior of the graphene surface structured in a cylinder array, Wu HY, Gu ZB, Gong Q, Lei Y,

Mo D, Zhang ST, Chen YB, Chen YF, Surface & Coatings Technology 236, 296-302(2013)………………………..

152

106 Si seed layer thickness effect on the structure of ultrathin tetrahedral amorphous carbon films, Liu FX, Ma HT, Tang

CJ, Surface & Coatings Technology 235, 117-120(2013)…………………………………………………………….

152

II Electronics Based on Quantum Physics 152

107 Phase transition of ultrathin Bi2Se3 film sandwiched between ferromagnetic insulators, Wang HQ, Yang YY, Ju Y,

Sheng L, Xing DY, Acta Physica Sinica 62, 037202(2013)…….....................................................................................

152

108 Quantum entanglement based on surface phonon polaritons in condensed matter systems, Ming Y, Wu ZJ, Tan AH,

Hu XK, Xu F, Lu YQ, AIP Advances 3, 042122(2013)………………………………………………………………..

153

109 Exploring inequality violations by classical hidden variables numerically, Vongehr S, Annals of Physics 339, 51-58

(2013)……………………………………………………………………………………………………………………

153

110 Spin transport in molecules studied by Fe3O4/molecule nanoparticles, Yue FJ, Wang S, Wu D, Applied Physics

A-Materials Science & Processing 111, 347-354(2013)………………………………………………………………

153

111 High-field critical current enhancement by irradiation induced correlated and random defects in (Ba0.6K0.4)Fe2As2,

Kihlstrom KJ, Fang L, Jia Y, Shen B, Koshelev AE, Welp U, Crabtree GW, Kwok WK, Kayani A, Zhu SF, Wen HH,

Applied Physics Letters 103, 202601(2013)…………………………………………………………………………..

153

112 Multiple Dirac points and perfect transmission in graphene with a dimerlike potential, Zhang RL, Gao HT, Zhou Y,

Fan RH, Qi DX, Peng RW, Huang RS, Wang M, Applied Physics Letters 103, 121605(2013)……………………….

154

113 Spectroscopy of self-assembled one-dimensional atomic string: The role of step edge, Cao RX, Zhong ZF, Hu J, Zhang

XP, Miao BF, Sun L, You B, Wu D, Hu A, Zhang WY, Ding HF, Applied Physics Letters 103, 081608(2013)………

154

114 Giant magnetoresistance enhancement at room-temperature in organic spin valves based on La0.67Sr0.33MnO3

electrodes, Chen BB, Zhou Y, Wang S, Shi YJ, Ding HF, Wu D, Applied Physics Letters 103, 072402(2013)………

154

115 Magnetic properties and magnetoresistance effect of Pb2FeMoO6, Yuan XP, Xu MX, Chen YB, Applied Physics

Letters 103, 052411(2013)……………………………………………………………………………………………..

154

116 Distinguishing spin pumping from spin rectification in a Pt/Py bilayer through angle dependent line shape analysis,

Bai LH, Feng Z, Hyde P, Ding HF, Hu CM, Applied Physics Letters 102, 242402(2013)……………………………

155

117 Tuning the carrier density of LaAlO3SrTiO3 interfaces by capping La1-xSrxMnO3, Shi YJ, Wang S, Zhou Y, Ding HF,

Wu D, Applied Physics Letters 102, 071605(2013)……………………………………………………………………

155

118 Gate voltage induced topological phase transition in hexagonal boron-nitride bilayers, Zhai XC, Jin GJ, Applied

Physics Letters 102, 023104(2013)................................................................................................................................ ..

155

119 Improving the spin entropy by suppressing Co4+ concentration in thermoelectric Ca3Co4O9+delta, Tang GD, Xu F,

Zhang DW, Wang ZH, Ceramics International 39, 1341-1344(2013)…………………………………………………

155

120 Graphene-like physics in optical lattices, Mei F, Zhang DW, Zhu SL, Chinese Physics B 22, 116106(2013)…………. 156

121 Coupling-matrix approach to the Chern number calculation in disordered systems, Zhang YF, Yang YY, Ju Y, Sheng

L, Shen R, Sheng DN, Xing DY, Chinese Physics B 22, 117312(2013)………………………………………………..

156

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122 Structural distortions and magnetisms in Fe-doped LaMn1-xFexO3 (0 < x <= 0.6), Zheng L, Wu XS, Chinese Physics

B 22, 107806(2013)……………………………………………………………………………………………………..

156

123 Spin fluctuations and unconventional superconducting pairing in iron-based superconductors, Yu SL, Li JX, Chinese

Physics B 22, 087411(2013)…………………………………………………………………………………………….

156

124 Spin Chern numbers and time-reversal-symmetry-broken quantum spin Hall effect, Sheng L, Li HC, Yang YY, Sheng

DN, Xing DY, Chinese Physics B 22, 067201(2013)…………………………………………………………………..

156

125 Controlled remote implementation of quantum operations with high-dimensional systems, Zhan YB, Li XW, Ma PC,

Shi J, Chinese Physics B 22, 040306(2013)…………………………………………………………………………..

157

126 Optimal entanglement concentration for three-photon W states with parity check measurement, Zhou L, Sheng YB,

Zhao SM, Chinese Physics B 22, 020307(2013)……………………………………………………………………….

157

127 The finite temperature effect on Josephson junction between an s-wave superconductor and an s(+/-)-wave

superconductor, Wang D, Lu HY, Wang QH, Chinese Physics Letters 30, 077404(2013)……………………………

157

128 Efficient excitation of a symmetric collective atomic state with a single-photon through dipole blockade, Hong FY,

Xiong SJ, Fu JL, Zhu ZY, Communications in Theoretical Physics 59, 365-369(2013)……………………………..

157

129 Density functional theory study of FePdn (n=2-14) clusters and interactions with small molecules, Ma L, Wang JG,

Hao YY, Wang GH, Computational Materials Science 68, 166-173(2013)…………………………………………..

158

130 Spin-valve giant magnetoresistance in scandium-benzene sandwich cluster, Yang Z, Zhang BL, Liu XG, Yang YZ, Li

XY, Xiong SJ, Xu BS, EPL 104, 50006(2013)………………………………………………………………………….

158

131 Doping effect of Cu and Ni impurities on the Fe-based superconductor Ba0.6K0.4Fe2As2, Cheng P, Shen B, Han F, Wen

HH, EPL 104, 37007(2013)……………………………………………………………………………………………..

158

132 Optical conductivity of Ba0.6K0.4Fe2As2: The effect of in-plane and out-of-plane doping in the superconducting gap,

Dai YM, Xu B, Shen B, Wen HH, Qiu XG, Lobo RPSM, EPL 104, 47006(2013)…………………………………….

159

133 Long-range triplet Josephson current modulated by the interface magnetization texture, Meng H, Wu XQ, Zheng ZM,

EPL 104, 37003(2013)………………………………………………………………………………………………….

159

134 Specular Andreev reflection in inversion-symmetric Weyl semimetals, Chen W, Jiang L, Shen R, Sheng L, Wang BG,

Xing DY, EPL 103, 27006(2013)…................................................................................................................................ ..

159

135 Phonon spectra and superconductivity of the BiS2-based compounds LaO1-xFxBiS2, Li B, Xing ZW, Huang GQ, EPL

101, 47002(2013)………………………………………………………………………………………………………..

159

136 Appearance and disappearance of edge states in topological insulators, Yang Y, Zhang YF, Sheng L, Xing DY,

European Physical Journal B 86, 281(2013)…………………………………………………………………………

160

137 Shubnikov de Haas quantum oscillation of the surface states in the metallic Bismuth Telluride sheets, Chen TS, Han

JH, Li ZG, Song FQ, Zhao B, Wang XF, Wang BG, Wan JG, Han M, Zhang R, Wang GH, European Physical Journal

D 67, 75(2013)…………………………………………………………………………………………………………..

160

138 Oxygen-vacancy-related dielectric relaxation in BiFeO3 ceramics, Min KL, Huang FZ, Jin YM, Zhu WL, Zhu JS,

Ferroelectrics 450, 42-48(2013)………..........................................................................................................................

160

139 Coherent control of dressed images of four-wave mixing, Wu ZK, Zhang YQ, Liu TK, Zhang ZY, Li C, Zhang YP,

Xiao M, Frontiers of Physics 8, 228-235(2013)……………………………………………………………………….

160

140 Transmission properties of a qubit-coupled-two-resonator system, Zhao J, Yu Y, Jin BB, IEEE Transactions on

Applied Superconductivity 23, 1701705(2013)……………………………………………………………………….

160

141 Enhanced electrical properties of novel Pb(Ni1/3Nb2/3)O-3-BiScO3-PbTiO3 ternary system near morphotropic phase

boundary, Wang DL, Jiang ZH, Yang B, Zhang ST, Zhang MF, Guo FF, Cao WW, Japanese Journal of Applied

Physics 52, 101101(2013)……………………………………………………………………………………………….

161

142 Structural phase transition and thermal expansion in Bi1-2.5xPr1.5xBaxFeO3 ceramics, Cheng GF, Ruan YJ, Huang YH,

Wu XS, Journal of Alloys and Compound 566, 235-238(2013)………………………………………………………

161

143 Electric-field-controlled magnetic responses in Metglas and lead zirconate titanate laminated composite, Xuan HC,

Wang DH, Du YW, Journal of Alloys and Compound 550, 446-450(2013)…………………………………………..

161

144 Room-temperature observations of the weak localization in low-mobility graphene films, Han JH, Wang SY, Qian D,

Song FQ, Wang XR, Wang XF, Wang BG, Han M, Zhou JF, Journal of Applied Physics 114, 214502(2013)………..

162

145 Strain sensing and far-infrared absorption in strained graphene quantum dots, Qi FH, Jin GJ, Journal of Applied

Annual Report 2013——Content

ix

Physics 114, 073509(2013)……………………………………………………………………………………………... 162

146 Mechanical stress modified ferroelectric aging behavior, Xu TT, Kan Y, Jin YM, Sun H, Du YC, Wu XM, Bo HF, Cai

W, Huang FZ, Lu XM, Zhu JS, Journal of Applied Physics 113, 187204(2013)……………………………………….

162

147 Effect of Y-doping on spin entropy in Ca3-xYxCo4O9+delta, Zhang DW, Wang ZH, Tang GD, Xu XB, Xu XN, Qiu L,

Zhang DX, Du YW, Journal of Applied Physics 113, 17E113(2013)………………………………………………….

162

148 Width dependent edge distribution of graphene nanoribbons unzipped from multiwall carbon nanotubes, Zhong ZF,

Shen HL, Cao RX, Sun L, Li KP, Wang XR, Ding HF, Journal of Applied Physics 113, 174307(2013)………………

163

149 Mn induced ferromagnetism spin fluctuation enhancement in Sr2Ru1-xMnxO4, Zheng L, Cai JZ, Xie QY, Lv B, Mao

ZQ, Wu XS, Journal of Magnetism and Magnetic Materials 342, 115-119(2013)………………………………….

163

150 Spin-dependent energy bands and spin polarization in two-dimensional spin-orbit lateral superlattices, Zhang RL, Qi

DX, Wang DL, Li J, Peng RW, Huang RS, Wang M, Journal of Nanoscience and Nanotechnology 13, 1246-1250

(2013)……………………………………………………………………………………………………………………

163

151 Spin fluctuations and pairing symmetry in A(x)Fe(2-y)Se(2): dual effect of the itinerant and the localized nature of

electrons, Yu SL, Guo J, Li JX, Journal of Physics-Condensed Matter 25, 445702(2013)…………………………..

163

152 Universal scheme to generate metal-insulator transition in disordered systems, Guo AM, Xiong SJ, Xie XC, Sun QF,

Journal of Physics-Condensed Matter 25, 415501(2013)…………………………………………………………….

164

153 Kosterlitz-Thouless transition in disordered two-dimensional topological insulators, Xu Z, Sheng L, Shen R, Wang

BG, Xing DY, Journal of Physics-Condensed Matter 25, 065501(2013)……………………………………………..

164

154 Three-dimensional anisotropic fluctuation diamagnetism around the superconducting transition of Ba1-xKxFe2As2

single crystals in the finite-field (or prange) regime, Mosqueira J, Dancausa JD, Carballeira C, Salem-Sugui S,

Alvarenga AD, Luo HQ, Wang ZS, Wen HH, Vidal F, Journal of Superconductivity and Novel Magnetism 26,

1217-1220(2013)………………………………………………………………………………………………………...

164

155 Implementation of bright two-color quadripartite continuous-variable entanglement by the quantum optical dimer,

Wang JF, Sheng JT, Zhu SN, Xiao M, Journal of The Optical Society of America B-Optical Physics 30, 2130-2135

(2013)……………………………………………………………………………………………………………………

164

156 A field-directional specific heat study on the gap structure of overdoped Ba(Fe1-xCox)(2)As-2, Mu G, Tang J, Tanabe Y,

Xu J, Zeng B, Shen B, Han F, Wen HH, Heguri S, Tanigaki K, Journal of The Physical Society of Japan 82, 054714

(2013)……………………………………………………………………………………………………………………

165

157 Surface solitons of four-wave mixing in an electromagnetically induced lattice, Zhang YP, Yuan CZ, Zhang YQ,

Zheng HB, Chen HX, Li CB, Wang ZG, Xiao M, Laser Physics Letters 10, 055406(2013)………………………….

165

158 Low-frequency Landau-Zener-Stuckelberg interference in dissipative superconducting qubits, Du LJ, Lan D, Yu Y,

Low Temperature Physics 39, 665-679(2013)…………………………………………………………………………

165

159 Electromagnetically induced interference in a superconducting flux qubit, Du LJ, Yu Y, Lan D, Low Temperature

Physics 39, 503-514(2013)……………………………………………………………………………………………...

166

160 Optimal cooling of a driven artificial atom in dissipative environment, Du LJ, Yu Y, Lan D, Low Temperature

Physics 39, 111-119(2013)………………………………………………………………………………………………

166

161 Structural and optical properties of (Al, K)-co-doped ZnO thin films deposited by a sol-gel technique, Xu JP, Shi SB,

Zhang XS, Wang YW, Zhu MX, Li L, Materials Science in Semiconductor Processing 16, 732-737(2013)………..

166

162 Observation of possible topological in-gap surface states in the Kondo insulator SmB6 by photoemission, Jiang J, Li S,

Zhang T, Sun Z, Chen F, Ye ZR, Xu M, Ge QQ, Tan SY, Niu XH, Xia M, Xie BP, Li YF, Chen XH, Wen HH, Feng DL,

Nature Communications 4, 3010(2013)……………………………………………………………………………….

166

163 In-gap quasiparticle excitations induced by non-magnetic Cu impurities in Na(Fe0.96Co0.03Cu0.01)As revealed by

scanning tunnelling spectroscopy, Yang H, Wang ZY, Fang DL, Deng Q, Wang QH, Xiang YY, Yang Y, Wen HH,

Nature Communications 4, 2749(2013)……………………………………………………………………………….

167

164 Sign-reversal of the in-plane resistivity anisotropy in hole-doped iron pnictides, Blomberg EC, Tanatar MA, Fernandes

RM, Mazin II, Shen B, Wen HH, Johannes MD, Schmalian J, Prozorov R, Nature Communications 4, 1914(2013)…

167

165 Influence of microstructure on superconductivity in KxFe2 (-) Se-y(2) and evidence for a new parent phase K2Fe7Se8,

Ding XX, Fang DL, Wang ZY, Yang H, Liu JZ, Deng Q, Ma GB, Meng C, Hu YH, Wen HH, Nature

Communications 4, 1897(2013)………………………………………………………………………………………..

168

National Lab of Solid State Microstructures

x

166 Close relationship between superconductivity and the bosonic mode in Ba0.6K0.4Fe2As2 and Na(Fe0.975Co0.025)As,

Wang ZY, Yang H, Fang DL, Shen B, Wang QH, Shan L, Zhang CL, Dai PC, Wen HH, Nature Physics 9, 42-48

(2013)……………………………………………………………………………………………………………………

168

167 Topological phase transitions with and without energy gap closing, Yang YY, Li HC, Sheng L, Shen R, Sheng DN,

Xing DY, New Journal of Physics 15, 083402(2013)………………………………………………………………....

168

168 Synchronous control of dual-channel all-optical multistate switching, Sheng JT, Wang JF, Xiao M, Optics Letters 38,

5369-5372(2013)………………………………………………………………………………………………………..

169

169 Magnetoresistive properties of the La0.7Ce0.3MnO3 bulks and epitaxial thin films, Wu ZF, Wang ZH, Optoelectronics

and Advanced Materials-Rapid Communications 7, 683-687(2013)………………………………………………..

169

170 High temperature thermoelectric and magnetic properties of InxNdyCo4Sb12 skutterudites, Tang GD, Zhang DW, Chen

G, Xu F, Wang ZH, Physica B-Condensed Matter 408, 79-82(2013)………………………………………………….

169

171 Evidence for giant spin entropy contribution in thermoelectric Ca3Co4O9+delta, Tang GD, Xu F, He Y, Wang LY, Qiu L,

Wang ZH, Physica Status Solidi B-Basic Solid State Physics 250, 1327-1330(2013)………………………………..

169

172 PT-symmetric optical potentials in a coherent atomic medium, Sheng JT, Miri MA, Christodoulides DN, Xiao M,

Physical Review A 88, 041803(2013)…………………………………………………………………………………..

169

173 Tunable interfaces for realizing universal quantum computation with topological qubits, Xue ZY, Shao LB, Hu Y, Zhu

SL, Wang ZD, Physical Review A 88, 024303(2013)………………………………………………………………….

170

174 Processing quantum information in a hybrid topological qubit and superconducting flux qubit system, Zhang ZT, Yu

Y, Physical Review A 87, 032327(2013)……………………………………………………………………………….

170

175 Enhanced low-energy magnetic excitations via suppression of the itinerancy in Fe0.98-zCuzTe0.5Se0.5, Wen JS, Li SC, Xu

ZJ, Zhang C, Matsuda M, Sobolev O, Park JT, Christianson AD, Bourret-Courchesne E, Li Q, Physical Review B 88,

144509(2013)……………………………………………………………………………………………………………

170

176 Probing active/passive bands by quasiparticle interference in Sr2RuO4, Gao Y, Zhou T, Huang HX, Ting CS, Tong PQ,

Wang QH, Physical Review B 88, 094514(2013)………………………………………………………………………

171

177 Coulomb blockade effect of molecularly suspended graphene nanoribbons investigated with scanning tunneling

microscopy, Zhong ZF, Shen HL, Cao RX, Sun L, Li KP, Hu J, Liu Z, Wu D, Wang XR, Ding HF, Physical Review

B 88, 125408(2013)……………………………………………………………………………………………………..

171

178 Electronic Raman spectra in superconducting graphene: A probe of the pairing symmetry, Lu HY, Chen S, Xu YH,

Zhang LQ, Wang D, Wang WS, Physical Review B 88, 085416(2013)………………………………………………..

171

179 Electron-phonon coupling and electronic properties of electron-doped grapheme, Kang GZ, Zhang DS, Li J, Physical

Review B 88, 045113(2013)…………………………………………………………………………………………….

171

180 Hybrid magnetoresistance in the proximity of a ferromagnet, Lu YM, Cai JW, Huang SY, Qu D, Miao BF, Chien CL,

Physical Review B 87, 220409(2013)………………………………………………………………………………….

172

181 Effect of heavy-ion irradiation on superconductivity in Ba0.6K0.4Fe2As2, Salovich NW, Kim H, Ghosh AK, Giannetta

RW, Kwok W, Welp U, Shen B, Zhu S, Wen HH, Tanatar MA, Physical Review B 87, 180502(2013)……………….

172

182 Quantitatively probing two-electron entanglement with a spintronic quantum eraser, Chen W, Shen R, Wang ZD,

Sheng L, Wang BG, Xing DY, Physical Review B 87, 155308(2013)…………………………………………………

172

183 Angle-resolved photoemission observation of isotropic superconducting gaps in isovalent Ru-substituted

Ba(Fe0.75Ru0.25)(2)As-2, Xu N, Richard P, Wang XP, Shi X, van Roekeghem A, Qian T, Ieki E, Nakayama K, Sato T,

Rienks E, Thirupathaiah S, Xing J, Wen HH, Shi M, Takahashi T, Ding H, Physical Review B 87, 094513(2013)…….

172

184 From quasi-two-dimensional metal with ferromagnetic bilayers to Mott insulator with G-type antiferromagnetic order

in Ca-3(Ru1-xTix)(2)O-7, Peng J, Ke X, Wang GC, Ortmann JE, Fobes D, Hong T, Tian W, Wu XS, Mao ZQ, Physical

Review B 87, 085125(2013)…………………………………………………………………………………………….

173

185 Magnetic properties and origins of ferroelectric polarization in multiferroic CaMn7O12, Zhang JT, Lu XM, Zhou J,

Sun H, Huang FZ, Zhu JS, Physical Review B 87, 075127(2013)……………………………………………………..

173

186 Two-dimensional quantum diffusion of Gd adatoms in nano-size Fe corrals, Cao RX, Miao BF, Zhong ZF, Sun L, You

B, Zhang W, Wu D, Hu A, Bader SD, Ding HF, Physical Review B 87, 085415(2013)……………………………….

173

187 Spatial domain interactions between ultraweak optical beams, Khadka U, Sheng JT, Xiao M, Physical Review

Letters 111, 223601(2013)………………………………………………………………………………………………

174

Annual Report 2013——Content

xi

188 Hidden T-linear scattering rate in Ba0.6K0.4Fe2As2 revealed by optical spectroscopy, Dai YM, Xu B, Shen B, Xiao H,

Wen HH, Qiu XG, Homes CC, Lobo RPSM, Physical Review Letters 111, 117001(2013)……………………………

174

189 Stabilization of the quantum spin Hall effect by designed removal of time-reversal symmetry of edge states, Li HC,

Sheng L, Shen R, Shao LB, Wang BG, Sheng DN, Xing DY, Physical Review Letters 110, 266802(2013)…………..

174

190 Raman-scattering detection of nearly degenerate s-wave and d-wave pairing channels in iron-based Ba0.6K0.4Fe2As2

and Rb0.8Fe1.6Se2 superconductors, Kretzschmar F, Muschler B, Bohm T, Baum A, Hackl R, Wen HH, Tsurkan V,

Deisenhofer J, Loidl A, Physical Review Letters 110, 187002(2013)………………………………………………….

174

191 Optical properties for topological insulators with metamaterials, Zuo ZW, Ling DB, Sheng L, Xing DY, Physics

Letters A 377, 2909-2915(2013)………………………………………………………………………………………..

175

192 Tunneling through two single molecular magnets in series arrangement junction in parallel/antiparallel situations,

Jiang L, Ju Y, Liu X, Zhang ZZ, Shen R, Wang BG, Physics Letters A 377, 997-1002(2013)…………………………

175

193 Effect of Dy-doping on the microstructure and magnetic properties of Y1-xDyxMnO3, Zhang AM, Zhou GT, Sun J, Xu

T, Guo LL, Wu XS, Powder Diffraction 28, S45-S49(2013)…………………………………………………………..

175

194 Strong coupling superconductivity and prominent superconducting fluctuations in the new superconductor Bi4O4S3, Li

S, Yang H, Fang DL, Wang ZY, Tao J, Ding XX, Wen HH, Science China-Physics Mechanics & Astronomy 56,

2019-2025(2013)………………………………………………………………………………………………………...

175

195 Effect of the V/III ratio during buffer layer growth on the yellow and blue luminescence in undoped GaN epilayer,

Chai XZ, Zhang Y, Liu B, Xie ZL, Han P, Ye JD, Hu LQ, Xiu XQ, Zhang R, Zheng YD, Science China-Physics

Mechanics & Astronomy 56, 1694-1698(2013)………………………………………………………………………..

176

196 Recent advances in spin transport in organic semiconductors, Jiang SW, Yue FJ, Wang S, Wu D, Science China-

Physics Mechanics & Astronomy 56, 142-150(2013)…………………………………………………………………

176

197 Entangler via electromagnetically induced transparency with an atomic ensemble, Yang XH, Zhou YY, Xiao M,

Scientific Reports 3, 3479(2013)……………………………………………………………………………………….

176

198 Peculiar magnetism of BiFeO3 nanoparticles with size approaching the period of the spiral spin structure, Huang FZ,

Wang ZJ, Lu XM, Zhang JT, Min KL, Lin WW, Ti RX, Xu TT, He J, Yue C, Zhu JS, Scientific Reports 3, 2907(2013).

176

199 Exchange bias in polycrystalline Bi1-xLaxFeO3/NiFe bilayers, Yuan XY, Xue XB, Du J, Huang FZ, Xu QY, Solid State

Communications 161, 9-12(2013)……………………………………………………………………………………..

177

200 Magnetic entropy change in perovskite manganites La(0.7)A(0.3)MnO(3) La(0.7)A(0.3)Mn(0.9)Cr(0.1)O(3) (A = Sr, Ba, Pb) and

Banerjee criteria on phase transition, Wang ZM, Jiang JJ, Solid State Sciences 18, 36-41(2013)……………………

177

201 Size-dependent quantum diffusion of Gd atoms within Fe nano-corrals, Hu J, Cao RX, Miao BF, Liu Z, Zhong ZF, Sun

L, You B, Wu D, Zhang W, Hu A, Bader SD, Ding HF, Surface Science 618, 148-153(2013)…………………………

177

202 Self-organized Gd atomic superlattice on Ag(111): Scanning tunneling microscopy and kinetic Monte Carlo

simulations, Cao RX, Zhang XP, Miao BF, Zhong ZF, Sun L, You B, Hu A, Ding HF, Surface Science 610, 65-69

(2013)……………………………………………………………………………………………………………………

178

203 Probing the dead layer thickness and its effect on the structure and magnetic properties in La2/3Ca1/3MnO3 thin films,

Xie QY, Wu XS, Li J, Lv B, Gao J, Thin Solid Films 545, 89-93(2013)………………………………………………

178

III Nanostructures and Nanodevices 178

204 Single-particle spectroscopic measurements of fluorescent graphene quantum dots, Xu QF, Zhou Q, Hua Z, Xue Q,

Zhang CF, Wang XY, Pan DY, Xiao M, ACS Nano 7, 10654-10661(2013)……………………………………………

178

205 Increasing specific surface area of (110)-oriented ZnO nanosheets by sulfuration-oxidization treatment for

photoelectrode applications, Wei YL, Bao CX, Gao H, Huang H, Yu T, Zou ZG, Acta Physico-Chimica Sinica 29,

1975-1980(2013)………………………………………………………………………………………………………..

178

206 Versatile graphene-promoting photocatalytic performance of semiconductors: basic principles, synthesis, solar

energy conversion, and environmental applications, Tu WG, Zhou Y, Zou ZG, Advanced Functional Materials 23,

4996-5008(2013)………………………………………………………………………………………………………...

179

207 Broadband optical non-linearity induced by charge-transfer excitons in type-II CdSe/ZnTe nanocrystals, Liu YL,

Zhang CF, Zhang HC, Wang R, Hua Z, Wang XY, Zhang JY, Xiao M, Advanced Materials 25, 4397-4402(2013)….

179

208 Fabrication of silver nanoparticle decorated AFM tips for tip-enhanced Raman scattering applications, Li YH, Xu

National Lab of Solid State Microstructures

xii

CH, Han M, Advanced Research on Biochemical Materials and Nanotechnology Application 643, 195-198(2013) 179

209 The Talbot effect: recent advances in classical optics, nonlinear optics, and quantum optics, Wen LM, Zhang Y, Xiao

M, Advances in Optics and Photonics 5, 83-130(2013)………………………………………………………………

179

210 The effects of Co-Ti co-doping on the magnetic, electrical, and magnetodielectric behaviors of M-type barium

hexaferrites, Guan YJ, Lin YB, Zou LY, Miao Q, Zeng M, Liu ZW, Gao XS, Liu JM, AIP Advances 3, 122115(2013)..

180

211 Upward ferroelectric self-poling in (001) oriented PbZr0.2Ti0.8O3 epitaxial films with compressive strain, Luo Y, Li XY,

Chang L, Gao WX, Yuan GL, Yin J, Liu ZG, AIP Advances 3, 122101(2013)…………………………………………

180

212 Influence of cycling electric polarization on multiferroic behaviors in heterostructural films composed of ferroelectric

and ferromagnetic oxides, Li ZW, Zhou MX, Chen B, Wan JG, Liu JM, Wang GH, Applied Physics A-Materials

Science & Processing 113, 477-482(2013)……………………………………………………………………………..

180

213 Conductive Atomic Force Microscopy (C-AFM) observation of conducting nanofilaments formation in GeSbTe phase

change materials, Yang F, Xu L, Fang L, Jiang YF, Xu J, Su WN, Yu Y, Ma ZY, Chen KJ, Applied Physics A-

Materials Science & Processing 112, 663-667(2013)………………………………………………………………….

181

214 The metallic interface between insulating NdGaO3 and SrTiO3 perovskites, Li C, Xu QF, Wen Z, Zhang ST, Li AD, Wu

D, Applied Physics Letters 103, 201602(2013)………………………………………………………………………..

181

215 Thermal transport through an exciton-condensate Josephson junction based on graphene double layers, Zhang CY,

Jin GJ, Applied Physics Letters 103, 202111(2013)……………………………………………………………………

181

216 The interface inter-diffusion induced enhancement of the charge-trapping capability in HfO2/Al2O3 multilayered

memory devices, Lan XX, Ou X, Lei Y, Gong CJ, Yin QN, Xu B, Xia YD, Yin J, Liu ZG, Applied Physics Letters

103, 192905(2013)………………………………………………………………………………………………………

181

217 Enhanced pyroelectric property in (1-x)(Bi0.5Na0.5) TiO3-xBa(Zr0.055Ti0.945)O-3: Role of morphotropic phase boundary

and ferroelectric-antiferroelectric phase transition, Guo FF, Yang B, Zhang ST, Wu FM, Liu DQ, Hu PA, Sun Y, Wang

DL, Cao WW, Applied Physics Letters 103, 182906(2013)……………………………………………………………

182

218 Strong energy-transfer-induced enhancement of Er3+ luminescence in In2O3 nanocrystal codoped silica films, Lin T,

Zhang XW, Xu J, Liu X, Swihart MT, Xu L, Chen KJ, Applied Physics Letters 103, 181906(2013)…………………..

182

219 Magnetic phase separation and exchange bias in off-stoichiometric Ni-Mn-Ga alloys, Han ZD, Qian B, Wang DH,

Zhang P, Jiang XF, Zhang CL, Du YW, Applied Physics Letters 103, 172403(2013)…………………………………

182

220 Temperature-dependent tunneling electroresistance in Pt/BaTiO3/SrRuO3 ferroelectric tunnel junctions, Wen Z, You

L, Wang JL, Li AD, Wu D, Applied Physics Letters 103, 132913(2013)………………………………………………

182

221 The tunable magnetostructural transition in MnNiSi-FeNiGe system, Zhang CL, Wang DH, Han ZD, Qian B, Shi HF,

Zhu C, Chen J, Wang TZ, Applied Physics Letters 103, 132411(2013)……………………………………………….

183

222 Defect recombination induced by density-activated carrier diffusion in nonpolar InGaN quantum wells, Yang F, Zhang

CF, Shi CT, Park MJ, Kwak JS, Jung S, Choi YH, Wu XW, Wang XY, Xiao M, Applied Physics Letters 103, 123506

(2013)……………………………………………………………………………………………………………………

183

223 Complete set of material constants of 0.95(Na0.5Bi0.5)TiO3-0.05BaTiO(3) lead-free piezoelectric single crystal and the

delineation of extrinsic contributions, Zheng LM, Yi XJ, Zhang ST, Jiang WH, Yang B, Zhang R, Cao WW, Applied

Physics Letters 103, 122905(2013)…………………………………………………………………………………….

183

224 Low-temperature synthesis of K0.5FeF3 with tunable exchange bias, Xu QR, Liu Y, Zheng YD, Rui WB, Sheng Y, Shen

X, Du J, Xu MX, Dong S, Wu D, Xu QY, Applied Physics Letters 103, 102405(2013)………………………………

183

225 Phase transition characteristics of Al-Sb phase change materials for phase change memory application, Zhou XL, Wu

LC, Song ZT, Rao F, Ren K, Peng C, Song SN, Liu B, Xu L, Feng SL, Applied Physics Letters 103, 072114(2013)…

184

226 Nanomechanical actuation from phase transitions in individual VO2 micro-beams, Guo H, Wang KV, Deng Y, Oh Y,

Asif SAS, Warren OL, Shan ZW, Wu J, Minor AM, Applied Physics Letters 102, 231909(2013)……………………

184

227 Resistive switching mechanism in silicon highly rich SiOx (x < 0.75) films based on silicon dangling bonds percolation

model, Wang YF, Qian XY, Chen KJ, Fang ZH, Li W, Xu J, Applied Physics Letters 102, 042103(2013)……………..

184

228 Optical absorption and charging effect in nano-crystalline Ge/SiNx multilayers, Li C, Xu J, Xu L, Li W, Jiang XF, Sun

SH, Chen KJ, Applied Surface Science 269, 129-133(2013)………………………………………………………….

185

229 Hydrothermal synthesis of CdS nanoparticleffunctionalized graphene sheet nanocomposites for visible-light

photocatalytic degradation of methyl orange, Yan SC, Wang BJ, Shi Y, Yang F, Hu D, Xu X, Wu JS, Applied Surface

Annual Report 2013——Content

xiii

Science 285, 840-845(2013)……………………………………………………………………………………………. 185

230 Hydrogenated amorphous silicon-carbide thin films with high photo-sensitivity prepared by layer-by-layer hydrogen

annealing technique, Li SX, Cao YQ, Xu J, Rui YJ, Li W, Chen KJ, Applied Surface Science 270, 287-291(2013)…

185

231 Structural and electroluminescent properties of Si quantum dots/SiC multilayers, Rui YJ, Li SX, Cao YQ, Xu J, Li W,

Chen KJ, Applied Surface Science 269, 37-40(2013)…………………………………………………………………..

185

232 An impedance spectroscopy study of the rotation and reorientation of water molecules in hydrated graphite oxide, Yu

J, Gu M, Bian C, Xu XB, Tang TB, Carbon 61, 367-372(2013)……………………………………………………….

186

233 Room temperature ferromagnetism in hydrothermally grown Ni and Cu co-doped ZnO nanorods, Tang GD, Shi XQ,

Huo C, Wang ZH, Ceramics International 39, 4825-4829(2013)……………………………………………………..

186

234 Size-controlled nanoporous TiO2 spheres with high dye-loading: facile synthesis and application as scattering layers

in dye-sensitized solar cells, Huang H, Wei YL, Bao CX, Gao H, Yu T, Zou ZG, Chinese Journal of Inorganic

Chemistry 29, 2169-2175(2013)……………………………………………………………………………………….

186

235 Magnetic properties and magnetostriction of PrxNd1-xFe1.9 (0 <= x <= 1.0) alloys at low temperature, Wang Y, Tang

SL, Li YL, Xie R, Du YW, Chinese Physics B 22, 037503(2013)……………………………………………………..

186

236 Transformation behaviors, structural and magnetic characteristics of Ni-Mn-Ga films on MgO (001), Xie R, Tang SL,

Tang YM, Liu XC, Tang T, Du YW, Chinese Physics B 22, 107502(2013)……………………………………………

187

237 Controllable synthesis, characterization, and growth mechanism of hollow ZnxCd1-xS spheres generated by a one-step

thermal evaporation method, Yang ZX, Zhong W, Au CT, Du YW, Chinese Physics B 22, 108101(2013)……………

187

238 Field-effect transistors based on two-dimensional materials for logic applications, Wang XR, Shi Y, Zhang R,

Chinese Physics B 22, 098505(2013)…………………………………………………………………………………..

187

239 Anisotropic localization behavior of graphene in the presence of diagonal and off-diagonal disorders, Wang LM, Shi

SC, Zhang WY, Chinese Physics B 22, 127201(2013)………………………………………………………………….

187

240 Structural and electrical properties of laser-crystallized nanocrystalline Ge films and nanocrystalline Ge/SiNx

multilayers, Li C, Xu J, Li W, Jiang XF, Sun SH, Xu L, Chen KJ, Chinese Physics B 22, 107201(2013)…………….

188

241 Electron beam evaporation deposition of cadmium sulphide and cadmium telluride thin films Solar cell applications,

Fang L, Chen J, Xu L, Su WN, Yu Y, Xu J, Ma ZY, Chinese Physics B 22, 098802(2013)……………………………

188

242 Performance improvement of charge trap flash memory by using a composition-modulated high-k trapping layer, Tang

ZJ, Li R, Yin J, Chinese Physics B 22, 097701(2013)………………………………………………………………….

188

243 Improvement on the magneto-optical Kerr effect of cobalt film with a quadrilayer structure, Zhang SY, Tang SL, Gao

JL, Luo XJ, Xia WB, Du YW, Chinese Physics B 22, 087802(2013)………………………………………………….

188

244 The charge storage characteristics of ZrO2 nanocrystallite-based charge trap nonvolatile memory, Tang ZJ, Li R, Yin

J, Chinese Physics B 22, 067702(2013)………………………………………………………………………………..

189

245 Review of magnetocaloric effect in perovskite-type oxides, Zhong W, Au CT, Du YW, Chinese Physics B 22, 057501

(2013)…………………………………………………………………………………………………………………….

189

246 Impact of Au nanocrystal size and inter-nanocrystal distance on the storage characteristics of memory devices, Lan

XX, Ou X, Xu B, Gong CJ, Li R, Yin QN, Xia YD, Yin J, Liu ZG, Li AD, Yan F, Chinese Physics Letters 30, 128102

(2013)…………………………………………………………………………………………………………………….

189

247 The anomalous temperature effect on the ductility of nanocrystalline Cu films adhered to flexible substrates, Hu K, Cao

ZH, Wang L, She QW, Meng XK, Chinese Physics Letters 30, 076201(2013)……………………………………….

190

248 Room-temperature multi-peak NDR in nc-Si quantum-dot stacking MOS structures for multiple value memory and

logic, Qian XY, Chen KJ, Huang J, Wang YF, Fang ZH, Xu J, Huang XF, Chinese Physics Letters 30, 077303(2013)

190

249 The effect of multiple interface states and nc-Si dots in a Nc-Si Floating gate MOS structure measured by their G-V

characteristics, Shi Y, Ma ZY, Chen KJ, Jiang XF, Li W, Huang XF, Xu L, Xu J, Feng D, Chinese Physics Letters 30,

077307(2013)……………………………………………………………………………………………………………

190

250 GeTe4 as a candidate for phase change memory application, Li R, Tang SY, Bai G, Yin QN, Lan XX, Xia YD, Yin J,

Liu ZG, Chinese Physics Letters 30, 058101(2013)……………………………………………………………………

190

251 Electric field modulated dispersion and aggregation of Ti atoms on graphene for hydrogen storage, Guo YH, Cao JX,

Xu B, Xia YD, Yin J, Liu ZG, Computational Materials Science 68, 61-65(2013)……………………………………

191

252 The in situ TEM observation of rapid lithium encapsulation and release in LiCl nanoshells and nanotubes, Neng W,

National Lab of Solid State Microstructures

xiv

Martini M, Su WN, Ling X, Sun LT, Shen YT, Crystengcomm 15, 7872-7878(2013)……………………………….. 191

253 ITO bi-crystal nanowires follow a grain boundary assistant growth mode, Wan N, Xu J, Sun LT, Lin T,

Crystengcomm 15, 3925-3931(2013)………………………………………………………………………………….

191

254 Quantum interference effects induced by multiple magnetic impurities on a triangular lattice f-wave superconductor,

Zuo XJ, Zhou Y, European Physical Journal B 86, 386(2013)……………………………………………………….

191

255 Structures and properties of AunScm (n + m=6) clusters, Ge GX, Yan HX, Jing Q, Huang XM, Wan JG, Wang GH,

European Physical Journal D 67, 116(2013)………………………………………………………………………….

192

256 Systemically tuning the surface plasmon resonance of high-density silver nanoparticle films, Gong YC, Zhou Y, He

LB, Xie B, Song FQ, Han M, Wang GH, European Physical Journal D 67, 87(2013)……………………………….

192

257 Improved photovoltaic properties of Si quantum dots/SiC multilayers-based heterojunction solar cells by reducing

tunneling barrier thickness, Cao YQ, Xu X, Li SX, Li W, Xu J, Chen KJ, Frontiers of Optoelectronics 6, 228-233

(2013)……………………………………………………………………………………………………………………

192

258 Light extraction enhancement of GaN LEDs by Hybrid ZnO micro-cylinders and nanorods array, Yin ZM, Liu XY,

Yao HC, Wu YZ, Hao XP, Han M, Xu XG, IEEE Photonics Technology Letters 25, 1989-1992(2013)……………..

192

259 A comparative study of the reversible hydrogen storage behavior in several metal decorated graphyne, Guo YH, Lan

XX, Cao JX, Xu B, Xia YD, Yin J, Liu ZG, International Journal of Hydrogen Energy 38, 3987-3993(2013)……...

193

260 Structural, spectroscopic, and dielectric characterizations of Mn-doped 0.67BiFeO3-0.33BaTiO3 multiferroic

ceramics, Hang QM, Zhou WK, Zhu XH, Zhu JM, Liu ZG, Talaat Al-Kassab, Journal of Advanced Ceramics 2,

252-259(2013)…………………………………………………………………………………………………………..

193

261 Hydrothermal synthesis of CdS/functionalized graphene sheets nanocomposites, Yan SC, Shi Y, Zhao B, Lu T, Hu D,

Xu X, Wu JS, Chen JS, Journal of Alloys and Compound 570, 65-69(2013)………………………………..………

193

262 Giant low-temperature magnetostriction and spin-reorientation of polycrystalline alloy PrFe1.9, Tang YM, Xie R,

Zhang L, Gao JL, Chen LY, Xia WB, Wang Y, Tang SL, Du YW, Journal of Applied Physics 113, 233902(2013)….

194

263 Thermally assisted manipulation of magnetic domain structures in amorphous rare-earth-Fe-B film, Gao JL, Zhang

SY, Luo XJ, Xia WB, Li YL, Tang SL, Du YW, Journal of Applied Physics 114, 033902(2013)…………………….

194

264 Enhanced magnetic performance of metal-organic nanowire arrays by FeCo/polypyrrole co-electrodeposition, Luo

XJ, Xia WB, Gao JL, Zhang SY, Li YL, Tang SL, Du YW, Journal of Applied Physics 113, 17B908(2013)…….........

194

265 Tunneling magnetoresistance tuned by a vertical electric field in an AA-stacked graphene bilayer with double

magnetic barriers, Wang DL, Jin GJ, Journal of Applied Physics 114, 233701(2013)………………………………..

194

266 Conduction mechanism of resistance switching in fully transparent MgO-based memory devices, Zhang T, Yin J, Xia

YD, Zhang WF, Liu ZG, Journal of Applied Physics 114, 134301(2013)..………………….........................................

195

267 Double-walled ice nanotubes grown in carbon nanotubes: Molecular dynamics simulations, Chang X, Li HC, Fa W,

Journal of Applied Physics 114, 074314(2013)……………………………………………………………………….

195

268 Giant magneto-optical Kerr effect in HfO2/Co/HfO2/Al/silicon structure, Zhang SY, Gao JL, Xia WB, Luo XJ , Tang

SL, Du YW, Journal of Applied Physics 114, 064308(2013)….………………………………………………………

195

269 The effect of thermal treatment induced inter-diffusion at the interfaces on the charge trapping performance of

HfO2/Al2O3 nanolaminate-based memory devices, Lan XX, Ou X, Cao YQ, Tang SY, Gong CJ, Xu B, Xia YD, Yin J,

Li AD, Yan F, Liu ZG, Journal of Applied Physics 114, 044104(2013)…………………………………………….....

196

270 Stress-modulated exciton polariton Josephson effect in a semiconductor microcavity, Zhang CY, Jin GJ, Journal of

Applied Physics 113, 183513(2013)……………………………………………………………………………………

196

271 Ultrafast pump-probe spectroscopic signatures of superconducting and pseudogap phases in YBa2Cu3O7-delta films,

Zhang CF, Li W, Gray B, He B, Wang Y, Yang F, Wang XY, Chakhalian J, Xiao M, Journal of Applied Physics 113,

083901(2013)……………………………………………………………………………………………………………

196

272 A Datta-Das transistor and conductance switch based on a zigzag graphene nanoribbon, Cao J, Tang CP, Xiong SJ,

Journal of Applied Physics 113, 054304(2013)……………………………………………………………………….

196

273 Effects of germanium and nitrogen incorporation on crystallization of N-doped Ge2+xSb2Te5 (x=0,1) thin films for

phase-change memory, Cheng LM, Wu LC, Song ZT, Rao F, Peng C, Yao DN, Liu B, Xu L, Journal of Applied

Physics 113, 044514(2013)……………………………………………………………………………………………...

197

274 Crystal polymorphism and enhanced dielectric performance of composite nanofibers of poly(vinylidene fluoride) with

Annual Report 2013——Content

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silver nanoparticles, Shi NE, Duan JJ, Su J, Huang FZ, Xue W, Zheng C, Qian Y, Chen SF, Xie LH, Huang W, Journal

of Applied Polymer Science 128, 1004-1010(2013)……………….…………………………………….…………….

197

275 Evidence for a Neolithic Age fire-irrigation paddy cultivation system in the lower Yangtze River Delta, China, Hu LC,

Chao ZH, Gu M, Li FC, Chen LN, Liu BD, Li X, Huang ZQ, Li YY, Xing BS, Dai JY, Journal of Archaeological

Science 40, 72-28(2013)…………………………………………………………………………………………………

197

276 First-principles prediction of magnetic superatoms in 4d-transition-metal-doped magnesium clusters, Ge GX, Han Y,

Wan JG, Zhao JJ, Wang GH, Journal of Chemical Physics 139, 174309(2013)……………………………………….

198

277 Non-hexagonal symmetry-induced functional T graphene for the detection of carbon monoxide, Liu CS, Jia R, Ye XJ,

Zeng Z, Journal of Chemical Physics 139, 034704(2013)…………………………………………………………….

198

278 Site-specific analysis of dipole polarizabilities of heterogeneous systems: Iron-doped Si-n (n=1-14) clusters, Ma L,

Wang JG, Wang GH, Journal of Chemical Physics 138, 094304(2013)……………………………………………….

198

279 Facile synthesis of polymer core@silver shell hybrid nanoparticles with super surface enhanced Raman scattering

capability, Huo D, He J, Yang SW, Zhou ZY, Hu Y, Epple M, Journal of Colloid and Interface Science 393, 119-125

(2013)………………………………………....................................................................................................................

198

280 In situ study of copper electrodeposition on a single carbon fiber, Song SQ, Ortega CM, Liu Z, Du J, Wu XS, Cai ZH,

Sun L, Journal of Electroanalytical Chemistry 690, 53-59(2013)……………………………………………………

199

281 Sandwich-like LiFePO4/graphene hybrid nanosheets: in situ catalytic graphitization and their high-rate performance

for lithium ion batteries, Guo XK, Fan Q, Yu L, Liang JY, Ji WX, Peng LM, Guo XF, Ding WP, Chen YF, Journal of

Materials Chemistry A 1, 11534-11538(2013)…………………………………............................................................

199

282 Facile hydrothermal synthesis of hydrotropic Cu2ZnSnS4 nanocrystal quantum dots: band-gap engineering and

phonon confinement effect, Liu WC, Guo BL, Wu XS, Zhang FM, Mak CL, Wong KH, Journal of Materials

Chemistry A 1, 3182-3186(2013)………………………………………………………………………………………

199

283 Dichroic-dye-doped polymer stabilized optically isotropic chiral liquid crystals, Zheng ZG, Wang C, Shen D, Journal

of Materials Chemistry C 1, 6471-6478(2013)………………………………………………………………………..

200

284 Theoretical study on aluminum carbide endohedral fullerene-Al4C@C-80, Lu QL, Song WJ, Meng JW, Wan JG,

Journal of Molecular Modeling 19, 1205-1209(2013)…………………….. …………………..………..……………

200

285 The magnetic properties and spin-filter effects of manganese-borazine sandwich clusters, Li PW, Yang Z, Zhang WD,

Xiong SJ, Journal of Molecular Structure 1038, 1-7(2013)…………………………………………………………..

200

286 Growth behavior and electronic properties of NiAln (n=1-14) clusters, Sun HQ, Bai YJ, Cheng HY, Xu N, Wang BL,

Wang GH, Journal of Molecular Structure 1031, 22-29(2013)………………………………………………………

200

287 Investigation of 1D siliver nanoparticle arrays for use as molecule concentration-specific SERS substrates, Gao J,

Qian H, Xu S, Han M, Journal of Nanomaterials 989803(2013)………………………………………………………

201

288 Atomic-scale microstructural characterization and dielectric properties of crystalline cubic pyrochlore

Bi1.5MgNb1.5O7 nanoparticles synthesized by sol-gel method, Zhang Y, Zhu XH, Zhou SH, Zhu JM, Liu ZG, Al-Kassab

T, Journal of Nanoparticle Research 16, 2208(2013)…………………………………………………………………

201

289 Fast response characteristics of hydrogen sensors based on Pd nanoparticle films with controlled coverage, Xie B,

Zheng MY, Liu F, Peng X, Wang GH, Han M, Journal of Nanoparticle Research 15, 1746(2013)……………..……

201

290 Scalable alignment of CdS nanowires based on efficient roll-on transfer technique, Yan SC, Shi Y, Xiao ZD, Wang JZ,

Hu D, Xu X, Lu T, Liu A, Gao F, Journal of Nanoscience and Nanotechnology 13, 4242-4246(2013)…………….

202

291 Coupling of surface plasmons and excited optical modes in metal/dielectric grating stacks, Fan RH, Qi DX, Hu Q, Qin

L, Peng RW, Wang M, Journal of Nanoscience and Nanotechnology 13, 1017-1021(2013)………………………..

202

292 Size-dependent eutectic temperature of Ag-Pb alloy nanoparticles, Lu HM, Shuai J, Meng XK, Journal of

Nanoscience and Nanotechnology 13, 1480-1483(2013)……………………………………………………………..

202

293 The periodicity effect on the charge storage characteristic of multistacked nc-Si floating gate, Ma ZY, Liu GY, Jiang

XF, Xia GY, Yan MY, Li W, Chen KJ, Xu L, Xu J, Feng D, Journal of Nanoscience and Nanotechnology 13,

997-1000(2013)…………………………………………………………………………………………………………

202

294 Development and applications of the heterostructures synthesis based on CdS nanowires, Yan SC, Shi Y, Sun LT, Yan

WF, Zhou MM, Hu D, Wu JS, Wang JY, Shi BJ, Lan XK, Journal of Nanoscience and Nanotechnology 13,

23-32(2013)……………....……………...........................................................................................................................

203

National Lab of Solid State Microstructures

xvi

295 Controllable synthesis of tetragonal and cubic phase Cu2Se nanowires assembled by small nanocubes and their

electrocatalytic performance for oxygen reduction reaction, Liu SL, Zhang ZS, Bao JC, Lan YQ, Tu WW, Han M, Dai

ZH, Journal of Physical Chemistry C 117, 15164-15173(2013)………………………………………………………

203

296 Stuffing enhances the stability of medium-sized (GaAs)(n) clusters, Lu QL, Meng JW, Song WJ, Mu YW, Wan JG,

Journal of Physical Chemistry C 117, 12835-12840(2013)…………………………………………………………..

203

297 The structural and optical properties of the CpTMC60 (TM = Sc-Fe) sandwich cluster, Yang Z, Zhang BL, Liu XG,

Yang YZ, Li XY, Xiong SJ, Xu BS, Journal of Physics B-Atomic Molecular and Optical Physics 46, 035101

(2013)…………….……................................................................................................................................ ..................

204

298 Electron-hole pair condensation and Coulomb drag effect in a graphene double layer, Zhang CY, Jin GJ, Journal of

Physics-Condensed Matter 25, 425604(2013)………………………………………………………………………..

204

299 Topological phase transition induced by spin-orbit coupling in bilayer grapheme, Xu L, Zhou Y, Gong CD, Journal

of Physics-Condensed Matter 25, 335503(2013)……………………………………………………………………...

204

300 Topological quantum phase transitions on the kagome and square-octagon lattices, Liu XP, Chen WC, Wang YF,

Gong CD, Journal of Physics-Condensed Matter 25, 305602(2013)…………….......................................................

205

301 Exotic electronic properties in Thue-Morse graphene superlattices, Xu YF, Zou JF, Jin GJ, Journal of Physics-

Condensed Matter 25, 245301(2013)…………..……………………………………………………………………..

205

302 Commensurate magnetic excitations induced by band splitting and Fermi surface topology in n-type cuprates, Zhang

HY, Zhou Y, Lin HQ, Gong CD, Journal of Physics-Condensed Matter 25, 155603(2013)…………………..….…

205

303 Adsorption behavior and electronic properties of Pd-n (n <= 10) clusters on silicon carbide nanotubes: a

first-principles study, Wang JG, Ma L, Wang GH, Journal of Physics-Condensed Matter 25, 085302(2013)……….

205

304 Tunable resistive switching behaviour in ferroelectric-ZnO bilayer films, Zhou MX, Li ZW, Chen B, Wan JG, Liu JM,

Journal of Physics D-Applied Physics 46, 165304(2013)…………………………………………………………….

206

305 Bipolar resistive switching based on SrTiO3/YBa2Cu3O7 epi-layers, Li K, Wen Z, Wu D, Zhai H, Li AD, Journal of

Physics D-Applied Physics 46, 035308(2013)…………………………………………………………………………

206

306 Synthesis of sandwich-like TiO2@C composite hollow spheres with high rate capability and stability for lithium-ion

batteries, Liu LC, Fan Q, Sun CZ, Gu XR, Li H, Gao F, Chen YF, Dong L, Journal of Power Sources 221, 141-148

(2013)…………………………………………………………………………………………………………………...

206

307 Pure face-centered-cubic (fcc) and hexagonal-close-packed (hcp) nickel phases obtained in air atmosphere sol-gel

process and fcc nickel phase obtained in N-2 protected sol-gel process, Li PY, Zhang P, Li FS, Jiang W, Cao ZH,

Journal of Sol-Gel Science and Technology 68, 261-269(2013)……………………………………………………

207

308 Fabrication of (La1-xGdx)(2/3)Sr1/3MnO3 manganite perovskite nanorods by sonication-assisted coprecipation, Jiang

XL, Yao YJ, Lai M, Jacob DS, Gedanken A, Du YW, Journal of Superconductivity and Novel Magnetism 26,

1385-1390(2013)……………………………….………………………………………………………………………

207

309 Temperature gradient introduced ferroelectric self-poling in BiFeO3 ceramics, Chen XM, Zou YH, Yuan GL, Zeng

M, Liu JM, Yin J, Liu ZG, Journal of The American Ceramic Society 96, 3788-3792(2013)………………….…….

207

310 Effect of annealing on the microstructures and the magnetic properties of [Fe/Pt] (16) multilayers on MgO (001)

substrates, Zhang AM, Zhu WH, Wu XS, Journal of The Korean Physical Society 63, 521-524(2013)…….………

207

311 Non-d-wave superconductivity driven magnetic excitations features in underdoped cuprates, Zhang HY, Zhou Y,

Gong CD, Journal of The Physical Society of Japan 82, 094715(2013)……………………………………………..

208

312 Origin of the pseudogap and its influence on superconducting state, Zhou Y, Lin HQ, Gong CD, Journal of The

Physical Society of Japan 82, 034702(2013)………………………………………………………………………….

208

313 Demonstration of an erbium-doped microsphere laser on a silicon chip, Fan HB, Hua SY, Jiang XS, Xiao M, Laser

Physics Letters 10, 105809(2013)……………………………………………………………………………………..

208

314 Rapid synthesis of pentagonal silver nanowires with diameter-dependent tensile yield strength, Tang SC, Vongehr S,

Wan N, Meng XK, Materials Chemistry and Physics 142, 17-26(2013)……………………………………………..

208

315 Large-scale synthesis, electromagnetic and enhanced microwave absorption properties of low helicity carbon

nanotubes/Fe nanoparticles hybrid, Qi XS, Zhong W, Deng CY, Au C, Du YW, Materials Letter 107, 374-377

(2013)……….…………………………………………………………………………………………………………..

209

316 Modulating individual thickness for optimized combination of strength and ductility in Cu/Ru multilayer films, Hu K,

Annual Report 2013——Content

xvii

Xu LJ, Cao YQ, Pan GJ, Cao ZH, Meng XK, Materials Letter 107, 303-306(2013)………………………………….. 209

317 A promising hybrid scaffold material: Bacterial cellulose in-situ assembling biomimetic lamellar CaCO3, Liu X, Ma

YJ, Zhou Y, Pei CH, Yin GF, Materials Letter 102, 91-93(2013)……..…………………………..…………………...

209

318 Mesoporous alumina materials synthesized in different gel templates, Cui XL, Tang SK, Zhou H, Materials Letter

98, 116-119(2013)………………………………………………………………………………………………………

210

319 Modified spontaneous emission from CdSe/ZnS core-shell quantum dots in plasmonic-photonic crystals, Liu GQ, Liu

ZQ, Huang K, Chen YH, Li L, Tang FL, Gong LX, Materials Letter 93, 42-44(2013) ……………………………..

210

320 Impact of the interfaces in the charge trap layer on the storage characteristics of ZrO2/Al2O3 nanolaminate-based

charge trap flash memory cells, Tang ZJ, Zhu XH, Xu HN, Xia YD, Yin J, Liu ZG, Li AD, Yan F, Materials Letter

92, 21-24(2013)…………………………………………………………………………………………………………

210

321 Facile fabrication of three-dimensional mesoporous Si/SiC composites via one-step magnesiothermic reduction at

relative low temperature, Jiang ZH, Ma YJ, Zhou Y, Hu SL, Han CJ, Pei CH, Materials Research Bulletin 48,

4139-4145(2013)…………………………..……………………………………………………………………………

210

322 Preparation and dielectric properties of SiC nanowires self-sacrificially templated by carbonated bacterial cellulose,

Wen LX, Ma YJ, Dai B, Zhou Y, Liu JS, Pei CH, Materials Research Bulletin 48, 687-690(2013)…..……………..

211

323 Long-persistent luminescence in neon:ultraviolet from silicon nanowires, Zhao YL, Zhou JF, Zheng LQ, Zhong CG,

Wrensford LV, Chan K, Materials Research Bulletin 48, 89-91(2013)……………………………………………….

211

324 Controlled synthesis of NiS nanoparticle/CdS nanowire heterostructures via solution route and their optical

properties, Yan SC, Shi Y, Sun LT, Xiao ZD, Sun B, Xu X, Materials Science and Engineering B-Advanced

Functional Solid-State Materials 178, 109-116(2013)………………………………………………………………..

211

325 Microscopical and physical characterization of microwave and microwave-hydrothermal synthesis products, Zhu

XH, Hang QM, Micron 44, 21-44(2013)……………………………………………………………………………….

211

326 Spin-frustrated effect and the magnetic properties in YMn1-xAlxO3, Zhang AM, Zhu WH, Wu XS, Bian Q, Modern

Physics Letters B 27, 1350163(2013)……………………………………………………………………….................

212

327 Ordered Ag/Si nanowires array: Wide-range surface-enhanced raman spectroscopy for reproducible biomolecule

detection, Huang JA, Zhao YQ, Zhang XJ, He LF, Wong TL, Chui YS, Zhang WJ, Lee ST, Nano Letters 13,

5039-5045(2013)………………………………………………………………………………………………………..

212

328 Electrical performance and scalability of Pt dispersed SiO2 nanometallic resistance switch, Choi BJ, Torrezan AC,

Norris KJ, Miao F, Strachan JP, Zhang MX, Ohlberg DAA, Kobayashi NP, Yang JJ, Williams RS, Nano Letters 13,

3213-3217(2013)………………………………………………………………………………………………………..

212

329 On-demand hydrogen generation using nanosilicon: Splitting water without light, heat, or electricity, Erogbogbo F,

Lin T, Tucciarone PM, LaJoie KM, Lai L, Patki GD, Prasad PN, Swihart MT, Nano Letters 13, 451-456(2013)……

213

330 Fabrication of anti-reflecting Si nano-structures with low aspect ratio by nano-sphere lithography technique, Sun SH,

Lu P, Xu J, Xu L, Chen KJ, Wang QM, Zuo YH, Nano-Micro Letters 5, 18-25(2013)……………………………….

213

331 Size dependence of the magnetic properties of Ni nanoparticles prepared by thermal decomposition method, He XM,

Zhong W, Au Chak-Tong, Du YW, Nanoscale Research Letters 8, 446(2013)……………………………………….

213

332 Direct observation of rotatable uncompensated spins in the exchange bias system Co/CoO-MgO, Ge CN, Wan XG,

Pellegrin E, Hu ZW, Valvidares SM, Barla A, Liang WI, Chu YH, Zou WQ, Du YW, Nanoscale 5, 10236-10241

(2013)……………………………………………………………………………………………………………………

214

333 Nanoscale quantification of charge injection and transportation process in Si-nanocrystal based sandwiched

structure, Xu J, Xu J, Zhang PZ, Li W, Chen KJ, Nanoscale 5, 9971-9977(2013)………………..……………………..

214

334 Influence of geometric nanoparticle rotation on cellular internalization process, Yang K, Yuan B, Ma YQ, Nanoscale

5, 7998-8006(2013)……………………………………………………………………………………………………...

214

335 High yield CdS nanowires synthesized by solvothermal routes and novel diauxic growth mechanism, Yan SC, Xiao

ZD, Shi Y, Hu D, Xu X, Wu JS, Zhou MM, Nanoscience and Nanotechnology Letters 5, 213-221(2013)……………

214

336 Double transfer UV-curing nanoimprint lithography, Shen YM, Yao L, Li ZW, Kou JL, Cui YS, Bian J, Yuan CS, Ge

HX, Li WD, Wu W, Chen YF, Nanotechnology 24, 465304(2013)…………………………………………………….

215

337 Local electrical conduction in polycrystalline La-doped BiFeO3 thin films, Zhou MX, Chen B, Sun HB, Wan JG, Li

ZW, Liu JM, Song FQ, Wang GH, Nanotechnology 24, 225702(2013)……………………………………………….

215

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338 Near-unity transparency of a continuous metal film via cooperative effects of double plasmonic arrays, Liu ZQ, Liu

GQ, Zhou HQ, Liu XS, Huang K, Chen YH, Fu GL, Nanotechnology 24, 155203(2013)……………………..……..

215

339 Hopping transport through defect-induced localized states in molybdenum disulphide, Qiu H, Xu T, Wang ZL, Ren W,

Nan HY, Ni ZH, Chen Q, Yuan SJ, Miao F, Song FQ, Long G, Shi Y, Sun LT, Wang JL, Wang XR, Nature

Communications 4, 2642(2013)…………………………………..................................................................................

216

340 Ferroelectric-field-effect-enhanced electroresistance in metal/ferroelectric/semiconductor tunnel junctions, Wen Z, Li

C, Wu D, Li AD, Ming NB, Nature Materials 12, 617-621(2013)…………………………………………………….

216

341 Fabrication and infrared-transmission properties of monolayer hexagonal-close-packed metallic nanoshells, Chen J,

Xu RQ, Liu ZQ, Tang CJ, Chen Z, Wang ZL, Optics Communications 297, 194-197(2013)……………....................

216

342 Quasi-phase-matched second-harmonic Talbot self-imaging in a 2D periodically-poled LiTaO3 crystal, Liu DM, Wei

DZ, Zhang Y, Zou J, Hu XP, Zhu SN, Xiao M, Optics Express 21, 13969-13974(2013)……………………………….

217

343 Reversal of optical binding force by Fano resonance in plasmonic nanorod heterodimer, Zhang Q, Xiao JJ, Zhang

XM, Yao Y, Liu H, Optics Express 21, 6601-6608(2013)………...……………………………………………………

217

344 Surface-enhanced Raman scattering effect of gold nanoparticle arrays: The influence of annealing temperature,

excitation power and array thickness, Liu GQ, Liu ZQ, Chen YH, Huang K, Li L, Tang FL, Gong LX, Hu Y, Zhang

XN, Optik 124, 5124-5126(2013)………………………………………………………………………………………

217

345 Component-controlled synthesis of small-sized Pd-Ag bimetallic alloy nanocrystals and their application in a

non-enzymatic glucose biosensor, Liu SL, Zhang C, Yuan L, Bao JC, Tu WW, Han M, Dai ZH, Particle & Particle

Systems Characterization 30, 549-556(2013)…………………………………………………………………………

217

346 Giant Hall effect of (Ni90Co10) (x) (SiO2)(1-x) nanogranular films at percolation threshold, Wang ZM, Xu QY, Zhao Q,

Che YL, Phase Transitions 86, 561-569(2013)…………...............................................................................................

218

347 Phase change behavior and critical size of Ge2Sb2Te5 nanowires and nanotubes, Bai G, Liu ZG, Li R, Xia YD, Yin J,

Physica B-Condensed Matter 411, 68-71(2013)………………………………………………………………………

218

348 Highly stable FeCo/carbon composites: Magnetic properties and microwave response, Xu MH, Zhong W, Wang ZH,

Au CT, Du YW, Physica E-Low-Dimensional Systems & Nanostructures 52, 14-20(2013)………………………..

218

349 Raman spectra of carbon nanotubes with monovacancy, Chang X, Feng CD, Fa W, Chen WC, Physica Scripta 88,

065705(2013)……................................................................................. ...........................................................................

219

350 Enhanced threshold voltage of Zn-doped Ge2Sb2Te5 phase-change memory deposited by electron-beam evaporation,

Li R, Jiang YF, Xu L, Ma ZY, Yang F, Xu J, Su WN, Physica Status Solidi A-Applications and Materials Science

210, 2650-2655(2013)…………..…………………………………………………………………………….................

219

351 Silicon doping effect on the crystallization behavior of Ge2Sb2Te5 film, Jiang YF, Xu L, Chen J, Zhang R, Su WN, Yu

Y, Ma ZY, Xu J, Physica Status Solidi A-Applications and Materials Science 210, 2231-2237(2013)……………..

219

352 Magnetic critical behavior of Mn5Ge3 ribbons, Zheng TF, Shi YG, Li JB, Fan JY, Shi DN, Lv LY, Tang SL, Physica

Status Solidi B-Basic Solid State Physics 250, 1445-1448(2013)……...........................................................................

219

353 Quantum limits for cascaded optical parametric amplifiers, Wang D, Zhang Y, Xiao M, Physical Review A 87,

023834(2013)……………………………………………………………………………………………………………

220

354 Vortex competition in a rotating two-component dipolar Bose-Einstein condensate, Zhao Y, An J, Gong CD, Physical

Review A 87, 013605(2013)…………………………………………………………………………………………….

220

355 Edge excitations in fractional Chern insulators, Luo WW, Chen WC, Wang YF, Gong CD, Physical Review B 88,

161109(2013)…..……………………………………………………………………………………………………….

220

356 Fluctuant magnetism in metal oxide nanocrystals capped with surfactants, Zhang JH, Xiong SJ, Wu XL, Thurber A,

Jones M, Gu M, Pan ZD, Tenne DA, Hanna CB, Du YW, Physical Review B 88, 085437(2013)…………………….

220

357 Corrugation-induced metal-semiconductor transition in single-wall carbon nanotubes with a small radius, Lu HX,

Wu JB, Zhang WY, Physical Review B 88, 035423(2013)…………………………………………………………….

221

358 Predicted giant magnetic anisotropy energy of highly stable Ir dimer on single-vacancy grapheme, Han Y, Ge GX,

Wan JG, Zhao JJ, Song FQ, Wang GH, Physical Review B 87, 155408(2013)…………………………………………

221

359 Fast deterministic single-exposure coherent diffractive imaging at sub-Angstrom resolution, Morgan AJ, D'Alfonso

AJ, Wang P, Sawada H, Kirkland AI, Allen LJ, Physical Review B 87, 094115(2013)………………………………..

221

360 Inverse spin Hall effect in a ferromagnetic metal, Miao BF, Huang SY, Qu D, Chien CL, Physical Review Letters

Annual Report 2013——Content

xix

111, 066602(2013)……………………………………………………………………………………………................ 222

361 Creating an artificial two-dimensional Skyrmion crystal by nanopatterning, Sun L, Cao RX, Miao BF, Feng Z, You B,

Wu D, Zhang W, Hu A, Ding HF, Physical Review Letters 110, 167201(2013)……………………………………….

222

362 Effect of a nonuniform magnetic field on the Landau states in a biased AA-stacked graphene bilayer, Wang DL, Jin

GJ, Physics Letters A 377, 2901-2904(2013)…………………………………………………………………………..

222

363 Effect of polar distortion on electronic structures of (001) LaGaO3/SrTiO3 interface, Xu QF, Wu D, Li AD, Physics

Letters A 377, 577-581(2013)…………………………………………………………………………………………..

222

364 Silver nanoshells as tri-mode bactericidal agents integrating long term antibacterial, photohyperthermia and

triggered Ag+ release capabilities, Huo D, Gao J, Guo BL, Ding Y, He J, Yu HP, Zhou ZY, Hu Y, RSC Advances 3,

10632-10638(2013)……………………………………………………………………………………………………..

223

365 Surface energy guided sub-10 nm hierarchy structures fabrication by direct e-beam etching, Wan N, Xu J, Xu T,

Martini M, Sun LT, Sun J, Zhou YL, RSC Advances 3, 17860-17865(2013)…………………………………………..

223

366 Thickness-driven spin reorientation transition in ultrathin films, Miao BF, Millev Y, Sun L, You B, Zhang W, Ding

HF, Science China-Physics Mechanics & Astronomy 56, 70-84(2013)………………………………………………

223

367 Controlled synthesis of magnetic iron oxide nanoparticles within a supramolecular organogel fiber network, Wang

LP, Tang SK, Zhou H, Science of Advanced Materials 5, 822-829(2013)…………………………………………….

223

368 Position-sensitive spectral splitting with a plasmonic nanowire on silicon chip, Hu Q, Xu DH, Zhou Y, Peng RW, Fan

RH, Fang NX, Wang QJ, Huang XR, Wang M, Scientific Reports 3, 3095(2013)…………………………………….

224

369 Enhanced hot-carrier luminescence in multilayer reduced graphene oxide nanospheres, Chen Q, Zhang CF, Xue F,

Zhou Y, Li W, Wang Y, Tu WG, Zou ZG, Wang XY, Xiao M, Scientific Reports 3, 2315(2013)………………………

224

370 The chemically driven phase transformation in a memristive abacus capable of calculating decimal fractions, Xu HN,

Xia YD, Yin KB, Lu JX, Yin QN, Yin J, Sun LT, Liu ZG, Scientific Reports 3, 1230(2013)………………………….

224

371 A promising method for fabricating Ag nanoparticle modified nonenzyme hydrogen peroxide sensors, Liao KM, Mao

P, Li YH, Nan YL, Song FQ, Wang GH, Han M, Sensors and Actuators B-Chemical 181, 125-129(2013)………….

225

372 Bright far-red/near-infrared conjugated polymer nanoparticles for in vivo bioimaging, Ding D, Liu J, Feng GX, Li K,

Hu Y, Liu B, Small 9, 3093-3102(2013)………………………………………………………………………………...

225

373 Theoretical calculation of magneto-optical properties in cobalt nanotube array with hexagonal symmetry, Zhang SY,

Tang SL, Gao JL, Luo XJ, Xia WB, Du YW, Solid State Communications 170, 19-23(2013)………………………..

225

374 Facile synthesis of ultrafine Cu2ZnSnS4 nanocrystals by hydrothermal method for use in solar cells, Liu WC, Guo BL,

Mak C, Li AD, Wu XS, Zhang FM, Thin Solid Films 535, 39-43(2013)……………………………………………….

225

375 Contrast in atomically resolved EF-SCEM imaging, Wang P, D'Alfonso AJ, Hashimoto A, Morgan AJ, Takeguchi M,

Mitsuishi K, Shimojo M, Kirkland AI, Allen LJ, Nellist PD, Ultramicroscopy 134, 185-192(2013)…………………..

226

IV Structure and Functionality of Soft Condensed Matter 226

376 Nonspecific adsorption of charged mesoporous nanoparticles on supported thiol/lipid hybrid bilayers, Lu NY, Yuan

B, Yang K, Acta Physica Sinica 62, 178701(2013)……………………………………………………………………..

226

377 Application of reed-vibration mechanical spectroscopy of liquids for studying dehydration denaturation of protein

hydrogel, Zhou HW, Liu J, Lei T, Huang YN, Acta Physica Sinica 62, 076203(2013)………………………………..

226

378 Nano-imprinted ferroelectric polymer nanodot arrays for high density data storage, Chen XZ, Li Q, Chen X, Guo X,

Ge HX, Liu Y, Shen QD, Advanced Functional Materials 23, 3124-3129(2013)……………………………………..

227

379 One-step photo synthesis of protein-drug nanoassemblies for drug delivery, Xie JB, Cao Y, Xia M, Gao X, Qin M, Wei

JW, Wang W, Advanced Healthcare Materials 2, 795-799(2013)…………………………………………………….

227

380 Conjugated polymer amplified far-red/near-infrared fluorescence from nanoparticles with aggregation-induced

emission characteristics for targeted in vivo imaging, Ding D, Li K, Qin W, Zhan RY, Hu Y, Liu JZ, Tang BZ, Liu B,

Advanced Healthcare Materials 2, 500-507(2013)……………………………………………………………………

227

381 Adsorption of nanoparticles and nanoparticle aggregates on membrane under gravity, Zhu T, Jiang ZY, Ma YQ,

Applied Physics Letters 102, 153109(2013)…………………………………………………………………………..

228

382 Vesicle deposition and subsequent membrane-melittin interactions on different substrates: A QCM-D experiment, Lu

NY, Yang K, Li JL, Yuan B, Ma YQ, Biochimica et Biophysica Acta-Biomembranes 1828, 1918-1925(2013)…….

228

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383 Design maps for cellular uptake of gene nanovectors by computer simulation, Ding HM, Ma YQ, Biomaterials 34,

8401-8407(2013)………………………………………………………………………………………………………..

228

384 A single-molecule view on the disassembly of tobacco mosaic virus, Cao Y, Biophysical Journal 105, 2615-2616

(2013)……………………………………………………………………………………………………………………

229

385 A yellow fluorescent protein with reduced chloride sensitivity engineered by loop-insertion, Liang JY, Yang Y, Yin PG,

Ding Y, Shen Y, Qin M, Wang J, Xu Q, Cao Y, Wang W, Chembiochem 14, 1423-1426(2013)………………………..

229

386 An enzyme-assisted nanoparticle crosslinking approach to enhance the mechanical strength of peptide-based

supramolecular hydrogels, Li Y, Ding Y, Qin M, Cao Y, Wang W, Chemical Communications 49, 8653-8655(2013)..

229

387 Theoretical and computational studies of dendrimers as delivery vectors, Tian WD, Ma YQ, Chemical Society

Reviews 42, 705-727(2013)…………………………………………………………………………………………….

229

388 Organic dots with aggregation-induced emission (AIE Dots) characteristics for dual-color cell tracing, Li K, Zhu ZS,

Cai PQ, Liu RR, Tomczak N, Ding D, Liu J, Qin W, Zhao ZJ, Hu Y, Chen XD, Tang BZ, Liu B, Chemistry of

Materials 25, 4181-4187(2013)………………………………………………………………………………………...

229

389 Brief review of recent research on blue phase liquid crystal materials and devices, Zheng ZG, Hu W, Zhu G, Sun M,

Shen D, Lu YQ, Chinese Optics Letters 11, 011601(2013)…………………………………………………………….

230

390 The application of reed-vibration mechanical spectroscopy for liquids to detect chemical reactions of an acrylic

structural adhesive, Wei L, Zhou HW, Zhang L, Huang YN, Chinese Physics B 22, 096201(2013)…..........................

230

391 Osmolyte effects on the unfolding pathway of beta-lactoglobulin, Meng W, Pan H, Qin M, Cao Y, Wang W, Chinese

Physics Letters 30, 108701(2013)……………………………………………………………………………………...

230

392 Thermodynamical properties of protein kinase with adenine inhibitors, Wu LZ, Hu D, Tang LH, Hu XF, Qin M,

Chinese Science Bulletin 58, 68-73(2013)……………………………………………………………………………..

231

393 The mechanical response of liquids depositing on a reed, Ying XN, European Physical Journal E 36, 35(2013)…… 231

394 Macromolecular crowding modulates the kinetics and morphology of amyloid self-assembly by beta-lactoglobulin,

Ma BL, Xie JB, Wei LS, Li W, International Journal of Biological Macromolecules 53, 82-87(2013)…………….

231

395 High capacity hydrogen storage in closo-hexaborate dianion B6H62-, Lu QL, Meng JW, Song WJ, Wan JG,

International Journal of Hydrogen Energy 38, 13328-13334(2013)…………………………………………………

232

396 Bacterial cellulose-assisted hydrothermal synthesis and catalytic performance of La2CuO4 nanofiber for methanol

steam reforming, Yang JZ, Tang WH, Liu XL, Chao C, Liu JG, Sun DP, International Journal of Hydrogen Energy

38, 10813-10818(2013)………………………………………………………………………………………………….

232

397 Thermally tunable random laser in dye-doped liquid crystals, Ye LH, Yin ZL, Zhao C, Hou C, Wang Y, Cui YP, Lu

YQ, Journal of Modern Optics 60, 1607-1611(2013)....................................................................................................

232

398 Localized frustration and binding-induced conformational change in recognition of 5S RNA by TFIIIA zinc finger, Tan

C, Li WF, Wang W, Journal of Physical Chemistry B 117, 15917-15925(2013)………………………………………

233

399 Controlled drug loading and release of a stimuli-responsive lipogel consisting of poly(N-isopropylacrylamide)

particles and lipids, Lu NY, Yang K, Li JL, Weng YY, Yuan B, Ma YQ, Journal of Physical Chemistry B 117,

9677-9682(2013)………………………………………………………………………………………………………..

233

400 Molecular mechanism of the inhibition of EGCG on the alzheimer A beta(1-42) dimer, Zhang T, Zhang J, Derreumaux

P, Mu YG, Journal of Physical Chemistry B 117, 3993-4002(2013)………………………………………………….

233

401 Specific binding of a short mirna sequence by zinc knuckles of Lin28: A molecular dynamics simulation study, Tan C,

Li WF, Wang W, Journal of Theoretical & Computational Chemistry 12, 1341015(2013)…………………………

234

402 Photo-cross-linking approach to engineering small tyrosine-containing peptide hydrogels with enhanced mechanical

stability, Ding Y, Li Y, Qin M, Cao Y, Wang W, Langmuir 29, 13299-13306(2013)…………………………………..

234

403 Hydrodynamic force depends not only on the viscosity of solution but also on the molecular weights of viscogens, Lv

CM, Zou DW, Qin M, Meng W, Cao Y, Wang W, Langmuir 29, 10624-10629(2013)………………………………….

234

404 Influence of surface chemistry on particle internalization into giant unilamellar vesicles, Liu JJ, Lu NY, Li JL, Weng

YY, Yuan B, Yang K, Ma YQ, Langmuir 29, 8039-8045(2013)……………………………………………………….

235

405 Fabrication of large two-dimensional colloidal crystals via self-assembly in an attractive force gradient, Sun XY, Li

Y, Zhang TH, Ma YQ, Zhang ZX, Langmuir 29, 7216-7220(2013)……………………………………………………

235

406 Effect of osmotic stress on membrane fusion on solid substrate, Zhu T, Jiang ZY, Nurlybaeva EMR, Sheng J, Ma YQ,

Annual Report 2013——Content

xxi

Langmuir 29, 6377-6385(2013)……………………………………………………………………………………….. 235

407 Computational investigations of a peptide-modified dendrimer interacting with lipid membranes, Tu CK, Chen K,

Tian WD, Ma YQ, Macromolecular Rapid Communications 34, 1237-1242(2013)…………………………………

235

408 Topological structure dynamics revealing collective evolution in active nematics, Shi XQ, Ma YQ, Nature

Communications 4, 3013(2013)………………………………………………………………………………………..

236

409 Complex liquid crystal alignments accomplished by Talbot self-imaging, Hu XK, Wei BY, Lin XW, Hu W, Zhu G,

Chigrinov V, Lu YQ, Optics Express 21, 7608-7613(2013)……………………………………………………………

236

410 A fast response variable optical attenuator based on blue phase liquid crystal, Zhu G, Wei BY, Shi LY, Lin XW, Hu W,

Huang ZD, Lu YQ, Optics Express 21, 5332-5337(2013)……………………………………………………………..

236

411 Regulation of charged reverse micelles on particle charging in nonpolar media, Cao HY, Lu NY, Ding BY, Qi M,

Physical Chemistry Chemical Physics 15, 12227-12234(2013)………………………………………………………

237

412 Correlation of reorientational jumps of water molecules in bulk water, Liu C, Li WF, Wang W, Physical Review B 87,

052309(2013)……………………………………………………………………………………………………………

237

413 Coordination between p21 and DDB2 in the cellular response to UV radiation, Li H, Zhang XP, Liu F, Plos One 8,

e80111(2013)……………………………………………………………………………………………………………

237

414 Deciphering structural and functional roles of disulfide bonds in decorsin, Wu LZ, Li Y, Yang Y, Qin M, Science

China-Chemistry 56, 1485-1492(2013)………………………………………………………………………………..

237

415 Controlling cellular uptake of nanoparticles with pH-sensitive polymers, Ding HM, Ma YQ, Scientific Reports 3,

2804(2013)………………………………………………………………………………………………………………

238

416 Syntheses and applications of concave and convex colloids with precisely controlled shapes, Cheng ZF, Luo FH,

Zhang ZX, Ma YQ, Soft Matter 9, 11392-11397(2013)……………………………………………………………….

238

417 Two approaches for the engineering of homogeneous small-molecule hydrogels, Ding BY, Li Y, Qin M, Ding Y, Cao

Y, Wang W, Soft Matter 9, 4672-4680(2013)…………………………………………………………………………..

238

418 Translocation of polyarginines and conjugated nanoparticles across asymmetric membranes, Li ZL, Ding HM, Ma

YQ, Soft Matter 9, 1281-1286(2013)…………………………………………………………………………………..

239

419 Computer simulations of the interactions of high-generation polyamidoamine dendrimers with electronegative

membranes, Xie LQ, Tian WD, Ma YQ, Soft Matter 9, 9319-9325(2013)…………………………………………….

239

Ⅴ Designing and Calculation on Microstructured Materials 239

420 N-doped SnO2 nanocrystals with green emission dependent upon mutual effects of nitrogen dopant and oxygen

vacancy, Zhou GX, Xiong SJ, Wu XL, Liu LZ, Li TH, Chu PK, Acta Materialia 61, 7342-7347(2013)……………..

239

421 Nanowires array designed by means of two-dimension closed-form solution for antireflection, Zhu ZP, Qin YQ, Acta

Physica Sinica 62, 157801(2013)……………………………………………………………………………………….

240

422 Enhanced photocatalytic oxygen evolution by crystal cutting, Sun M, Xiong SJ, Wu XL, He CY, Li TH, Chu PK,

Advanced Materials 25, 2035-2039(2013)…………………………………………………………………………….

240

423 Long-wavelength optical properties of a plasmonic crystal composed of end-to-end nanorod dimers, Yu XQ, Zhou L,

Dong ZG, Bai YF, Zhu SN, AIP Advances 3, 062122(2013)……………………………………………………………

240

424 Light-induced ferroelectricity in bioinspired self-assembled diphenylalanine nanotubes/microtubes, Gan ZX, Wu XL,

Zhu XB, Shen JC, Angewandte Chemie-International Edition 52, 2055-2059(2013)……………………………….

240

425 Broadband and wide-angle antireflection realized by multireflection effect in a micro-Lambda-shape array, Zheng

BW, Huang SS, Zhai CW, Wang C, Zhu MW, Chen YF, Applied Optics 52, 5585-5590(2013)……………………….

240

426 Ferroelectricity of polycrystalline GdMnO3 and multifold magnetoelectric responses, Lin L, Li L, Yan ZB, Tao YM,

Dong S, Liu JM, Applied Physics A-Materials Science & Processing 112, 947-954(2013)…………………………

241

427 A sandwiched flexible polymer mold for control of particle-induced defects in nanoimprint lithography, Li B, Zhang

JZ, Ge HX, Applied Physics A-Materials Science & Processing 110, 123-128(2013)…..............................................

241

428 Resonant Raman scattering from CdS nanocrystals enhanced by interstitial Mn, Zhao PQ, Liu LZ, Xue HT, Wu XL,

Shen JC, Chu PK, Applied Physics Letters 102, 061910(2013)………….....................................................................

241

429 Ferroelectric domain evolution with temperature in BaTiO3 film on (001) SrTiO3 substrate, Yuan GL, Chen JP, Xia H,

Liu JM, Yin J, Liu ZG, Applied Physics Letters 103, 062903(2013)………………………………………………….

242

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430 Optical identification of oxygen vacancy types in SnO2 nanocrystals, Liu LZ, Xu JQ, Wu XL, Li TH, Shen JC, Chu

PK, Applied Physics Letters 102, 031916(2013)………………………………………………………………………

242

431 In situ thermal imaging and absolute temperature monitoring by luminescent diphenylalanine nanotubes, Gan ZX,

Wu XL, Zhang JL, Zhu XB, Chu PK, Biomacromolecules 14, 2112-2116(2013)……………………………………..

242

432 Ferroelectric transition in the inorganic supramolecular complex (Hg6P4)(CuCl3)(2), Jiang XM, Yan ZB, Liu D, Wang

JX, Liu MF, Guo GC, Jin BB, Li XG, Liu JM, Chemistry-An Asian Journal 8, 2925-2931(2013)…………………..

242

433 Critical exponents of ferroelectric transitions in modulated SrTiO3: Consequences of quantum fluctuations and

quenched disorder, Wang JX, Liu MF, Yan ZB, Liu JM, Chinese Physics B 22, 077701(2013)……………………….

242

434 Strong coupling of a meta-diatom to a plasmonic nanocavity, Chen S, Lu HY, Liu JQ, Zhu YY, Chinese Physics

Letters 30, 087301(2013)……………………………………………………………………………………………….

243

435 Theory of superconductivity in a three-orbital model of Sr2RuO4, Wang QH, Platt C, Yang Y, Honerkamp C, Zhang

FC, Hanke W, Rice TM, Thomale R, EPL 104, 17013(2013)…………………………………………………………..

243

436 Dynamic magnetization process in the frustrated Shastry-Sutherland system TmB4, Huang WC, Huo L, Feng JJ, Yan

ZB, Jia XT, Gao XS, Qin MH, Liu JM, EPL 102, 37005(2013)……………………………………………………….

243

437 Theoretical investigation on the electronic and thermoelectric properties of RuSb2Te compound, Kong S, Zhang WY,

Shi DN, European Physical Journal B 86, 452(2013)…………………………………………………………………

244

438 Enhanced optical transmission of a continuous metal film with double metal cylinder arrays, Liu ZQ, Liu GQ, Huang

K, Chen YH, Hu Y, Zhang XN, Cai ZJ, IEEE Photonics Technology Letters 25, 1157-1160(2013)………………….

244

439 Multiferroic domain structure in orthorhombic multiferroics of cycloidal spin order: three-dimensional phase field

simulations, Chu P, Wang YL, Lin L, Dong S, Liu JM, IEEE Transactions on Magnetics 49, 3117-3120(2013).........

244

440 Application of reed-vibration mechanical spectroscopy for liquids in studying liquid crystallization, Zhou HW, Wang

LN, Zhang LL, Huang YN, International Journal of Modern Physics B 27, 1350080(2013)……………………….

244

441 Magnetostrictive properties of Tb-x(Pr0.5Nd0.5)(1-x)Fe1.93 cubic Laves alloys, Shi YG, Zhou XG, Hu CC, Shi DN, Lv

LY, Tang SL, Journal of Alloys and Compound 581, 753-756(2013)……....................................................................

245

442 Magnetocaloric behavior in perovskite manganites La(0.7)A(0.3)Mn(0.9)Fe(0.1)O(3) (A = Sr, Pb, Ba), Wang ZM, Huang J,

Journal of Alloys and Compound 576, 54-58(2013)………………………………………………………………….

245

443 Structure, magnetic properties and magnetostriction in NdFe1.9 bulk nanocrystalline alloys, Shi YG, Hu CC, Zhou

XG, Fan JY, Shi DN, Lv LY, Tang SL, Journal of Alloys and Compound 563, 289-292(2013).....................................

245

444 Investigation of activated oxygen molecules on the surface of Y2O3 nanocrystals by Raman scattering, Xu JQ, Xiong

SJ, Wu XL, Li TH, Shen JC, Chu PK, Journal of Applied Physics 114, 093512(2013)……………………………….

246

445 Negative magnetodielectric effect in CaCu3Ti4O12, Chen K, Huang CX, Zhang XR, Yu YL, Lau K, Hu WB, Li Q,

Wang J, Lin WW, Liu JM, Qiu L, Zhu JS, Withers RL, Journal of Applied Physics 114, 234104(2013)…..................

246

446 First-principles study on the magnetic properties in Mg doped BiFeO3 with and without oxygen vacancies, Yang RP,

Lin SX, Fang XG, Gao XS, Zeng M, Liu JM, Journal of Applied Physics 114, 233912(2013)……………………….

246

447 Optimization on magnetic transitions and magnetostriction in TbxDyyNdz(Fe0.9Co0.1)(1.93) compounds, Hu CC, Shi YG,

Shi DN, Zhou XG, Fan JY, Lv LY, Tang SL, Journal of Applied Physics 114, 143906(2013)………………………..

246

448 Electric-field-assisted magnetization switching in FePd/Pb(Mg1/3Nb2/3)O-3-PbTiO3 heterostructure at room

temperature, Yang YT, Wang DH, Song YQ, Gao JL, Lv LY, Cao QQ, Du YW, Journal of Applied Physics 114,

144902(2013)……………………………………………………………………………………………………………

247

449 The effect of titanium doping on the structure and phase change characteristics of Sb4Te, Zhu M, Wu LC, Rao F, Song

ZT, Ji XL, Yao DN, Cheng Y, Lv SL, Song SN, Liu B, Xu L, Journal of Applied Physics 114, 124302(2013)…..……

247

450 Dielectric and magnetic properties of BiFe1-4x/3TixO3 ceramics with iron vacancies: Experimental and first-principles

studies, Zou LY, Yang RP, Lin YB, Qin MH, Gao XS, Zeng M, Liu JM, Journal of Applied Physics 114, 034105

(2013)................................................................................................................................................................................

247

451 Multiferroicity in Mn-deficient Ca3CoMnO6: The consequence of Fe substitution, Lin L, Xie YL, Liu MF, Guo YJ,

Yan ZB, Liu JM, Journal of Applied Physics 114, 027006(2013)…………………………………………………….

247

452 Growth of single-walled Ag and Cu nanotubes confined in carbon nanotubes, studied by molecular dynamics

simulations, Han Y, Li R, Ge Y, Dong JM, Journal of Applied Physics 113, 234303(2013)…………………………..

248

453 Upward ferroelectric self-polarization induced by compressive epitaxial strain in (001) BaTiO3 films, Chen JP, Luo Y,

Annual Report 2013——Content

xxiii

Ou X, Yuan GL, Wang YP, Yang Y, Yin J, Liu ZG, Journal of Applied Physics 113, 204105(2013)…………………. 248

454 Anisotropy compensation and magnetostrictive properties in Tb-x Dy1-x(Fe0.9Mn0.1)(1.93) Laves compounds:

Experimental and theoretical analysis, Hu CC, Shi YG, Shi DN, Tang SL, Fan JY, Du YW, Journal of Applied

Physics 113, 203906(2013)…..…………………………………………………………………………………………

248

455 Electric field modulation of magnetism and electric properties in La-Ca-MnO3/Pb(Zr0.52Ti0.48)O-3 magnetoelectric

laminate, Chen SY, Zhang HQ, Liu FJ, Ye QY, Tang L, Huang ZG, Wang DH, Journal of Applied Physics 113,

17C712(2013)…………………………………………………………………………………………………………...

249

456 Strain-engineered A-type antiferromagnetic order in YTiO3: A first-principles calculation, Huang X, Tang YK, Dong

S, Journal of Applied Physics 113, 17E108(2013)…………………………………………………………………….

249

457 Large E-field tunability of microwave ferromagnetic properties in Fe50Co50-Hf/lead zinc niobate-lead titanate

multiferroic laminates, Li SD, Liu M, Shao WQ, Xu J, Chen SO, Zhou ZY, Nan TX, Sun NAX, Duh JG, Journal of

Applied Physics 113, 17C727(2013)…………………………………………………………………………………...

249

458 Stress competition and vortex magnetic anisotropy in FeCoAlO high-frequency soft magnetic films with gradient Al-O

contents, Li SD, Du HL, Xue Q, Xie SM, Liu M, Shao WQ, Xu J, Nan TX, Sun NX, Duh JG, Journal of Applied

Physics 113, 17A332(2013)…………………………………………………………………………………………….

249

459 Chemically modulated multiferroicity in Dy-doped Gd2Ti2O7, Lin L, Zhao ZY, Liu D, Xie YL, Dong S, Yan ZB, Liu

JM, Journal of Applied Physics 113, 17D903(2013)…………………………………………………………………..

250

460 Multiferroicity in spin ice Ho2Ti2O7: An investigation on single crystals, Liu D, Lin L, Liu MF, Yan ZB, Dong S, Liu

JM, Journal of Applied Physics 113, 17D901(2013)………………………………………………………………….

250

461 Magnetic orders and electronic structure in LaMnO3/SrTiO3 superlattices, Liu HM, Ma CY, Zhou PX, Dong S, Liu

JM, Journal of Applied Physics 113, 17D902(2013)…………………………………………………………………..

250

462 The competing spin orders and fractional magnetization plateaus of the classical Heisenberg model on Shastry-

Sutherland lattice: Consequence of long-range interactions, Huo L, Huang WC, Yan ZB, Jia XT, Gao XS, Qin MH,

Liu JM, Journal of Applied Physics 113, 073908(2013)………………………………………………………………

250

463 Stripe-vortex transitions in ultrathin magnetic nanostructures, Chen JP, Wang ZQ, Gong JJ, Qin MH, Zeng M, Gao

XS, Liu JM, Journal of Applied Physics 113, 054312(2013)………………………………………………………….

251

464 A new (2 x 1) dimerized structure of monolayer 1T-molybdenum disulfide, studied from first principles calculations,

Hu T, Li R, Dong JM, Journal of Chemical Physics 139, 174702(2013)………………………………………………

251

465 A new (2 x 1) reconstructed edge structure of zigzag Si nanoribbon: First principles study, Li R, Zhou J, Han Y, Dong

JM, Kawazoe Y, Journal of Chemical Physics 139, 104703(2013)……………………………………………………

251

466 Luminescence properties of cobalt-doped ZnO films prepared by sol-gel method, Xu JP, Shi SB, Li L, Zhang XS,

Wang YW, Shi QL, Li SB, Wang H, Journal of Electronic Materials 42, 3438-3444(2013)…………………………

251

467 Phase diagram of ferromagnetic XY model with nematic coupling on a triangular lattice, Qi K, Qin MH, Jia XT, Liu

JM, Journal of Magnetism and Magnetic Materials 340, 127-130(2013)……………………………………………

252

468 Exchange bias effect in Tb0.4Dy0.6MnO3, Xu MH, Wang ZH, Zhang DW, Du YW, Journal of Magnetism and

Magnetic Materials 340, 1-4(2013)……………………………………………………………………………………

252

469 Magnetic anisotropy of L1(0)-FePt film on (001) LaAlO3, Zhang AM, Zhu WH, Zheng L, Huang L, Gao JL, Tang SL,

Wu XS, Journal of Magnetism and Magnetic Materials 332, 89-92(2013)………………………………………….

252

470 Crystallization, phase evolution and ferroelectric properties of sol-gel-synthesized Ba(Ti0.8Zr0.2)O-3-

x(Ba0.7Ca0.3)TiO3 thin films, Wang ZM, Zhao K, Guo XL, Sun W, Jiang HL, Han XQ, Tao XT, Cheng ZX, Zhao HY,

Kimura H, Yuan GL, Yin J, Liu ZG, Journal of Materials Chemistry C 1, 522-530(2013)………………………….

253

471 Epitaxial strain induced magnetic transitions and phonon instabilities in tetragonal SrRuO3, He H, Ding HC, Gao

YC, Gong SJ, Wan XG, Duan CG, Journal of Physics-Condensed Matter 25, 165504(2013)……………………….

253

472 An ab initio study on the transition paths from graphite to diamond under pressure, Dong X, Zhou XF, Qian GR, Zhao

ZS, Tian YJ, Wang HT, Journal of Physics-Condensed Matter 25, 145402(2013)…………………………………...

253

473 Significant enhancements of dielectric and magnetic properties in Bi(Fe1-xMgx)O3-x/2 induced by oxygen vacancies,

Wu H, Lin YB, Gong JJ, Zhang F, Zeng M, Qin MH, Zhang Z, Ru Q, Liu ZW, Gao XS, Liu JM, Journal of Physics

D-Applied Physics 46, 145001(2013)………………………………………………………………………………….

254

474 Silver macro-texture substrates fabricated by plasma selective etching for surface-enhanced Raman scattering, Liu

National Lab of Solid State Microstructures

xxiv

FX, Ye XH, Tang CJ, Ma HT, Journal of Raman Spectroscopy 44, 393-400(2013)……………………………….. 254

475 Effect of A-site Bi-doping on the magnetic and electrical properties in TbMnO3, Zhang C, Yan HT, Wang XF, Kang

DW, Li LB, Lu XM, Zhu JS, Materials Letter 111, 147-149(2013)……………………………………………………

254

476 Dielectric properties of Ca2CuO3-CaCu2O3-CuO composite ceramics, Li QS, Zhang YQ, Li LB, Zang GZ, Modern

Physics Letters B 27, 1350042(2013)………………………………………………………………………………….

254

477 Noncollinear magnetism and half-metallicity in biased bilayer zigzag graphene nanoribbons, Pan LH, An J, Liu YJ,

New Journal of Physics 15, 043016(2013)…………………………………………………………………………….

255

478 Control the dispersive properties of compound plasmonic lenses, Wan WW, Ma CB, Liu ZW, Optics

Communications 291, 390-394(2013)…………………………………………………………………………………

255

479 The spin-filter capability and giant magnetoresistance effect in vanadium-naphthalene sandwich cluster, Yang Z,

Zhang BL, Liu XG, Yang YZ, Li XY, Xiong SJ, Xu BS, Organic Electronics 14, 2916-2924(2013)…………………

255

480 Two types of meta-crystals for IV group elements: Density functional theory calculations, Wu JB, Zhang WY, Mi YM,

Zhang CM, Physica B-Condensed Matter 410, 17-21(2013)…………………………………………………………

255

481 Influences of surface barrier on AC loss in Ag-Bi2223 tapes by simulation, Liu GH, Zhang L, Li YB, Yu JY, Deng Y,

Tang Z, Ding SY, Physica C-Superconductivity and Its Applications 495, 1-4(2013)………………………………

256

482 Quantum and classical correlations in the anisotropic XY Model with a single defect, Cheng WW, Shan CJ, Sheng

YB, Gong LY, Zhao SM, Liu JM, Physica E-Low-Dimensional Systems & Nanostructures 54, 72-77(2013)………

256

483 Edge reconstructions of hexagonal boron nitride nanoribbons: A first-principles study, Hu T, Han Y, Dong JM,

Physica E-Low-Dimensional Systems & Nanostructures 54, 191-196(2013)……………………………………….

256

484 Geometric and electronic structures of sulfur-edge-terminated zigzag edge graphene nanoribbons, Li R, Hu T, Dong

JM, Physica E-Low-Dimensional Systems & Nanostructures 49, 76-82(2013)……………………………………..

256

485 Growth of single-walled gold nanotubes confined in carbon nanotubes, studied by molecular dynamics simulations,

Han Y, Hu T, Dong JM, Physica E-Low-Dimensional Systems & Nanostructures 47, 122-127(2013)……………...

257

486 First-principles simulations on suspended coinage-metal nanotubes composed of different atomic species, Fa W,

Zhou J, Dong JM, Physical Chemistry Chemical Physics 15, 4610-4615(2013)……………………………………..

257

487 Formation of single-walled bimetallic coinage alloy nanotubes in confined carbon nanotubes: molecular dynamics

simulations, Han Y, Zhou J, Dong JM, Yoshiyuki K, Physical Chemistry Chemical Physics 15, 17171-17178(2013).

257

488 Theoretical study of water adsorption and dissociation on Ta3N5(100) surfaces, Wang JJ, Luo WJ, Feng JY, Zhang L,

Li ZS, Zou ZG, Physical Chemistry Chemical Physics 15, 16054-16064(2013)……………………………………..

258

489 Superfluid and magnetic states of an ultracold Bose gas with synthetic three-dimensional spin-orbit coupling in an

optical lattice, Zhang DW, Chen JP, Shan CJ, Wang ZD, Zhu SL, Physical Review A 88, 013612(2013)…………….

258

490 Functional renormalization group study of pairing symmetry and pairing mechanism in iron-selenide

superconductors, Xiang YY, Yang Y, Wang WS, Li ZZ, Wang QH, Physical Review B 88, 104516(2013)……………

258

491 Triplet pairing and possible weak topological superconductivity in BiS2-based superconductors, Yang Y, Wang WS,

Xiang YY, Li ZZ, Wang QH, Physical Review B 88, 094519(2013)…………………………………………………..

259

492 Competing electronic orders on kagome lattices at van Hove filling, Wang WS, Li ZZ, Xiang YY, Wang QH, Physical

Review B 87, 115135(2013)…………………………………………………………………………………………….

259

493 Electron-phonon superconductivity near charge-density-wave instability in LaO0.5F0.5BiS2: Density-functional

calculations, Wan XG, Ding HC, Savrasov SY, Duan CG, Physical Review B 87, 115124(2013)…………………….

259

494 Stabilized helical spin order and multiferroic phase coexistence in MnWO4: Consequence of 4d Ru substitution of Mn,

Yu HW, Liu MF, Li X, Li L, Lin L, Yan ZB, Liu JM, Physical Review B 87, 104404(2013)………………………….

259

495 Thermoelectric transport in thin films of three-dimensional topological insulators, Ma R, Sheng L, Liu M, Sheng DN,

Physical Review B 87, 115304(2013)…………………………………………………………………………………..

260

496 Stable all-nitrogen metallic salt at terapascal pressures, Sun J, Martinez-Canales M, Klug DD, Pickard CJ, Needs RJ,

Physical Review Letters 111, 175502(2013)…………………………………………………………………………..

260

497 Topological Bose-Mott insulators in a one-dimensional optical superlattice, Zhu SL, Wang ZD, Chan YH, Duan LM,

Physical Review Letters 110, 075303(2013)…………………………………………………………………………..

260

498 Vibrational properties and Raman spectra of different edge graphene nanoribbons, studied by first-principles

calculations, Hu T, Zhou J, Dong JM, Physics Letters A 377, 399-404(2013)………………………………………..

261

Annual Report 2013——Content

xxv

499 Polarization enhancement and ferroelectric switching enabled by interacting magnetic structures in DyMnO3 thin

films, Lu CL, Dong S, Xia ZC, Luo H, Yan ZB, Wang HW, Tian ZM, Yuan, SL, Wu T, Liu JM, Scientific Reports 3,

3374(2013)………………………………………………………………………………………………………………

261

500 Interaction-induced localization of mobile impurities in ultracold systems, Li J, An J, Ting CS, Scientific Reports 3,

3147(2013)………………………………………………………………………………………………………………

261

501 Coexistence of high performance resistance and capacitance memory based on multilayered metal-oxide structures,

Yan ZB, Liu JM, Scientific Reports 3, 2482(2013)…………………………………………………………………….

262

502 Interplay between point-group symmetries and the choice of the bloch basis in multiband models, Maier SA,

Honerkamp C, Wang QH, Symmetry-Basel 5, 313-343(2013)………………………………………………………...

262

Ⅵ Technological Applications in Material and Information Sciences 262

503 Band structure engineering of carbon nitride: In search of a polymer photocatalyst with high photooxidation property,

Chu S, Wang Y, Guo Y, Feng JY, Wang CC, Luo WJ, Fan XX, Zou ZG, ACS Catalysis 3, 912-919(2013)…………..

262

504 High-coercivity FePt nanoparticle assemblies embedded in oxide-matrix by atomic layer deposition, Kong JZ, Li AD,

Gao MY, Yan QY, Wu D, Acta Physica Polonica A 123, 173-176(2013)………............................................................

262

505 An in situ simultaneous reduction-hydrolysis technique for fabrication of TiO2-graphene 2D sandwich-like hybrid

nanosheets: graphene-promoted selectivity of photocatalytic-driven hydrogenation and coupling of CO2 into methane

and ethane, Tu WG, Zhou Y, Liu Q, Yan SC, Bao SS, Wang XY, Xiao M, Zou ZG, Advanced Functional Materials

23, 1743-1749(2013)……................................................................................................................................ .................

263

506 Zinc gallogermanate solid solution a novel photocatalyst for efficiently converting CO2 into solar fuels, Yan SC, Wang

JJ, Gao HL, Wang NY, Yu H, Li ZS, Zhou Y, Zou ZG, Advanced Functional Materials 23, 1839-1845(2013)………

263

507 An ion-exchange phase transformation to ZnGa2O4 nanocube towards efficient solar fuel synthesis, Yan SC, Wang JJ,

Gao HL, Wang NY, Yu H, Li ZS, Zhou Y, Zou ZG, Advanced Functional Materials 23, 758-763 (2013)…………...

263

508 A Co-catalyst-loaded Ta3N5 photoanode with a high solar photocurrent for water splitting upon facile removal of the

surface layer, Li MX, Luo WJ, Cao DP, Zhao X, Li ZS, Yu T, Zou ZG, Angewandte Chemie-International Edition

52, 11016-11020(2013)………………………………………………………………………………………………….

264

509 Na adsorption on SrTiO3 (001) surface and its interaction with water: A DFT calculation, Wang JJ, Li ZS, Zou ZG,

Applied Surface Science 270, 359-363(2013)…………………………………………………………………………

264

510 Improved interfacial and electrical properties of atomic layer deposition HfO2 films on Ge with La2O3 passivation, Li

XF, Liu XJ, Cao YQ, Li AD, Li H, Wu D, Applied Surface Science 264, 783-786(2013)……………………………

264

511 Novel visible light driven Mg-Zn-In ternary layered materials for photocatalytic degradation of methylene blue,

Huang L, Chu S, Wang JQ, Kong F, Luo LL, Wang Y, Zou ZG, Catalysis Todaycarbon 212, 81-88(2013)………….

264

512 In situ grown vertically oriented CuInS2 nanosheets and their high catalytic activity as counter electrodes in

dye-sensitized solar cells, Yang J, Bao CX, Zhang JY, Yu T, Huang H, Wei YL, Gao H, Fu G, Liu JG, Zou ZG,

Chemical Communications 49, 2028-2030(2013)…………………………………………………………………….

265

513 Atomic layer deposition of Al-doped ZnO films using aluminum isopropoxide as the Al precursor, Qian X, Cao YQ,

Guo BL, Zhai HF, Li AD, Chemical Vapor Deposition 19, 180-185(2013)…………………………………………..

265

514 Tricyclometalated iridium complexes as highly stable photosensitizers for light-induced hydrogen evolution, Yuan YJ,

Yu ZT, Gao HL, Zou ZG, Zheng C, Huang W, Chemistry-A European Journal 19, 6340-6349(2013)…....................

265

515 Charge-neutral amidinate-containing iridium complexes capable of efficient photocatalytic water reduction, Yu

ZT, Yuan YJ, Cai JG, Zou ZG, Chemistry-A European Journal 19, 1303-1310(2013)………......................................

265

516 Direct growth of Fe2V4O13 nanoribbons on a stainless-steel mesh for visible-light photoreduction of CO2 into

renewable hydrocarbon fuel and degradation of gaseous isopropyl alcohol, Li P, Zhou Y, Tu WG, Liu Q, Yan SC, Zou

ZG, Chempluschem 3, 274-278(2013)………………………………………………………………………………….

266

517 Water reduction systems associated with homoleptic cyclometalated iridium complexes of various 2-phenylpyridines,

Yuan YJ, Yu ZT, Cai JG, Zheng C, Huang W, Zou ZG, Chemsuschem 6, 1357-1365(2013)…………………………..

266

518 Highly efficient visible light photocatalytic activity of Cr-La codoped SrTiO3 with surface alkalinization: An insight

from DFT calculation, Wang JJ, Fang T, Yan SC, Li ZS, Yu T, Zou ZG, Computational Materials Science 79, 87-94

(2013)……………………………………………………………………………………………………………………

267

National Lab of Solid State Microstructures

xxvi

519 A transparent Ti4+ doped hematite photoanode protectively grown by a facile hydrothermal method, Cao DP, Luo WJ,

Li MX, Feng JY, Li ZS, Zou ZG, Crystengcomm 15, 2386-2391(2013)………………………………………………..

267

520 Synthesis of Bi6Mo2O15 sub-microwires via a molten salt method and enhancing the photocatalytic reduction of CO2

into solar fuel through tuning the surface oxide vacancies by simple post-heating treatment, Li P, Zhou Y, Tu WG,

Wang R, Zhang CF, Liu Q, Li HJ, Li ZD, Dai H, Wang JJ, Yan SC, Zou ZG, Crystengcomm 15, 9855-9858(2013)…..

267

521 Photoreduction of CO2 into Hydrocarbons Catalysed by ZnGa2O4/Ga2O3 Heterojunction, Wang NY, Yan SC, Zou ZG,

Current Organic Chemistry 17, 2454-2458(2013)………............................................................................................

267

522 An anion-controlled crystal growth route to Zn2GeO4 nanorods for efficient photocatalytic conversion of CO2 into

CH4, Yan SC, Wang JJ, Zou ZG, Dalton Transactions 42, 12975-12979(2013)……………………………………….

268

523 Efficient red phosphor double-perovskite Ca3WO6 with A-site substitution of Eu3+, Zhao X, Wang JJ, Fan L, Ding YF,

Li ZS, Yu T, Zou ZG, Dalton Transactions 42, 13502-13508(2013)……………………………………………………

268

524 The pursuit of rechargeable solid-state Li-air batteries, Li FJ, Kitaura H, Zhou HS, Energy & Environmental

Science 6, 2302-2311(2013)…………………………………………………………………………………………….

268

525 Towards sustainable and versatile energy storage devices: an overview of organic electrode materials, Song ZP, Zhou

HS, Energy & Environmental Science 6, 2280-2301(2013)………………………………………………………….

269

526 Challenges of non-aqueous Li-O-2 batteries: electrolytes, catalysts, and anodes, Li FJ, Zhang T, Zhou HS, Energy &

Environmental Science 6, 1125-1141(2013)……...........................................................................................................

269

527 Photoelectrochemical cells for solar hydrogen production: current state of promising photoelectrodes, methods to

improve their properties, and outlook, Li ZS, Luo WJ, Zhang ML, Feng JY, Zou ZG, Energy & Environmental

Science 6, 347-370(2013).................................................................................................................................................

269

528 Nearly monodispersed LiNbO3 nanocrystals synthesized by a nonaqueous Sol-Gel process and their photocatalytic

H-2 evolution activities, Feng JY, Wang ZQ, Wang JJ, Wan LJ, Yan SC, Li ZS, Zou ZG, European Journal of

Inorganic Chemistry 2013, 4142-4145(2013)………………………………………………………………………….

270

529 Tunable microwave photonic filter with a narrow and flat-top passband, Gao L, Chen XF, Yao JP, IEEE Microwave

and Wireless Components Letters 23, 362-364(2013)………………………………………………………………..

270

530 Photonic generation of a phase-coded microwave waveform with ultrawide frequency tunable range, Gao L, Chen XF,

Yao JP, IEEE Photonics Technology Letters 25, 899-902(2013)……………………………………………………..

270

531 Dual wavelength semiconductor laser based on reconstruction-equivalent-chirp technique, Li SM, Li RM, Li LY, Liu

R, Gao L, Chen XF, IEEE Photonics Technology Letters 25, 299-302(2013)…...........................................................

270

532 Bandgap modulation of polyimide photocatalyst for optimum H-2 production activity under visible light irradiation,

Chu S, Wang Y, Wang CC, Yang JC, Zou ZG, International Journal of Hydrogen Energy 38, 10768-10772(2013)…

271

533 Direct NaBH4-H2O2 fuel cell based on nanoporous gold leaves, Jin W, Liu JG, Wang YT, Yao YF, Gu J, Zou ZG,

International Journal of Hydrogen Energy 38, 10992-10997(2013)……....................................................................

271

534 The performance improvement of membrane and electrode assembly in open-cathode proton exchange membrane fuel

cell, Wu BB, Li B, Liu WM, Liu JG, Zhao M, Yao YF, Gu J, Zou ZG, International Journal of Hydrogen Energy 38,

10978-10984(2013)……………………………………………………………………………………………………..

271

535 Synthesis and electrochemical properties of Li-excess Li1+x [Ni0.5Co0.2Mn0.3]O-2 cathode materials using ammonia-

free chelating agent, Kong JZ, Yang XY, Zhai HF, Ren C, Li H, Li JX, Tang Z, Zhou F, Journal of Alloys and

Compound 580, 491-496(2013)………………………………………………………………………………………..

271

536 Enhanced luminescence intensity of Sr3B2O6:Eu2+ phosphor prepared by sol-gel method, Fan L, Zhao X, Zhang S,

Ding YF, Li ZS, Zou ZG, Journal of Alloys and Compound 579, 432-437(2013)……………………………………

272

537 The different electron transport of two nanotubes incorporated in working electrode of dye-sensitized solar cells,

Zhang XB, Tian HM, Wang XY, Xue GG, Tian ZP, Zhang JY, Yuan SK, Yu T, Zou ZG, Journal of Alloys and

Compound 578, 309-313(2013)………………………………………………………………………………………...

272

538 Synthesis and electrochemical performance of macroporous LiNi0.5Co0.2Mn0.3O2 by a modified sol-gel method, Kong

JZ, Zhai HF, Ren C, Gao MY, Zhang X, Li H, Li JX, Tang Z, Zhou F, Journal of Alloys and Compound 577, 507-510

(2013)……………………………………………………………………………………………………………………

272

539 Effects of Li source and calcination temperature on the electrochemical properties of LiNi0.5Co0.2Mn0.3O2 lithium-ion

cathode materials, Kong JZ, Zhou F, Wang CB, Yang XY, Zhai HF, Li H, Li JX, Tang Z, Zhang SQ, Journal of Alloys

Annual Report 2013——Content

xxvii

and Compound 554, 221-226(2013)…………………………………………………………………………………… 273

540 An efficient charge compensated red phosphor Sr3WO6: K+, Eu3+ - For white LEDs, Zhao X, Ding YF, Li ZS, Yu T,

Zou ZG, Journal of Alloys and Compound 553, 221-224(2013)………………………………………………………

273

541 Critical behavior and the universal curve for magnetocaloric effect in textured Mn5Ge3-xAlx ribbons, Zheng TF, Shi

YG, Fan JY, Shi DN, Tang SL, Lv LY, Zhong W, Journal of Applied Physics 113, 17A944(2013)…………………..

273

542 Achromatic waveplates for liquid crystal displays, Qi Z, Yeh PC, Zhu SN, Zhu YY, Journal of Display Technology 9,

586-591(2013)…………………………………………………………………………………………………………..

273

543 Study of the multiwavelength DFB Semiconductor laser array based on the reconstruction-equivalent-chirp technique,

Shi YC, Li SM, Li LY, Guo RJ, Zhang TT, Rui L, Li WC, Lu LL, Song T, Zhou YT, Li JS, Chen XF, Journal of

Lightwave Technology 31, 3243-2350(2013)………………………………………………………………………….

274

544 Fabrication and magnetic properties of FePt/Al2O3 composite film by atomic-layer-deposition, Kong JZ, Gao MY,

Zhai HF, Yan QY, Li AD, Li H, Wu D, Journal of Magnetism and Magnetic Materials 343, 1-5(2013)……………

274

545 Molecule-induced gradient electronic potential distribution on a polymeric photocatalyst surface and improved

photocatalytic performance, Guo Y, Kong F, Wang CC, Chu S, Yang JC, Wang Y, Zou ZG, Journal of Materials

Chemistry A 1, 5142-5147(2013)………………………………………………………………………………………

274

546 Versatile nanobead-scaffolded N-SnO2 mesoporous microspheres: one-step synthesis and superb performance in

dye-sensitized solar cell, gas sensor, and photocatalytic degradation of dye, Li ZD, Zhou Y, Song JC, Yu T, Liu JG,

Zou ZG, Journal of Materials Chemistry A 1, 524-531(2013)………………………………………………………..

275

547 Generalized synthesis of a family of multishelled metal oxide hollow microspheres, Tian ZP, Zhou Y, Li ZD, Liu Q,

Zou ZG, Journal of Materials Chemistry A 1, 3575-3579(2013)……………………………………………………

275

548 Photocurrent improvement in nanocrystalline Cu2ZnSnS4 photocathodes by introducing porous structures, Wen X,

Luo WJ, Zou ZG, Journal of Materials Chemistry A 1, 15479-15485(2013)…………………………………………

275

549 Lead silicate fiber-based, refractive index-independent temperature sensor, Qiu SJ, Zhou F, Feng X, Xu F, Lu YQ,

Journal of Modern Optics 60, 851-853(2013)…………………………………………………………………………

275

550 Water adsorption and decomposition on N/V-doped anatase TiO2 (101) Surfaces, Zhao ZY, Li ZS, Zou ZG, Journal of

Physical Chemistry C 117, 6172-6184(2013)………………………………………………………………………….

276

551 High-energy cathode materials (Li2MnO3-LiMO2) for lithium-ion batteries, Yu HJ, Zhou HS, Journal of Physical

Chemistry Letters 4, 1268-1280(2013)………………………………………………………………………………...

276

552 An efficient In0.30Ga0.70N photoelectrode by decreasing the surface recombination centres in a H2SO4 aqueous

solution, Li MX, Luo WJ, Liu Q, Zhuang Z, Li ZS, Liu B, Chen DJ, Zhang R, Yu T, Zou ZG, Journal of Physics

D-Applied Physics 46, 345103(2013)………………………………………………………………………………….

276

553 Band positions and photoelectrochemical properties of Cu2ZnSnS4 thin films by the ultrasonic spray pyrolysis method,

Huang S, Luo WJ, Zou ZG, Journal of Physics D-Applied Physics 46, 235108(2013)………………………………..

277

554 Biotemplated synthesis of LiFePO4/C matrixes for the conductive agent-free cathode of lithium ion batteries, Fan Q,

Lei LX, Chen YF, Sun YM, Journal of Power Sources 244, 702-706(2013)………………………………………….

277

555 A hybrid phase-transition model of olivine LiFePO4 for the charge and discharge processes, Li D, Zhang T, Liu XZ,

He P, Peng RW, Wang M, Han M, Zhou HS, Journal of Power Sources 233, 299-303(2013)………………………..

277

556 Preparation and visible-light photocatalytic properties of BiNbO4 and BiTaO4 by a citrate method, Zhai HF, Li AD,

Kong JZ, Li XF, Zhao J, Guo BL, Yin J, Li ZS, Wu D, Journal of Solid State Chemistry 202, 6-14(2013)………….

277

557 Preparation and phase structures of Zn-Ti-O ternary compounds by atomic layer deposition, Qian X, Gao MY, Cao

YQ, Guo BL, Li AD, Journal of Vacuum Science & Technology A 31, 01A133(2013)………………………………

278

558 The maximum limiting performance improved counter electrode based on a porous fluorine doped tin oxide

conductive framework for dye-sensitized solar cells, Bao CX, Huang H, Yang J, Gao H, Yu T, Liu JG, Zhou Y, Li ZS,

Zou ZG, Nanoscale 5, 4951-4957(2013)………………………………………………………………………………..

278

559 Enhanced photovoltaic performance of a dye-sensitized solar cell using graphene-TiO2 photoanode prepared by a

novel in situ simultaneous reduction-hydrolysis technique, Chen L, Zhou Y, Tu WG, Li ZD, Bao CX, Dai H, Yu T, Liu

JG, Zou ZG, Nanoscale 5, 3481-3485(2013)……………………………………………………………………………

278

560 Porous ZnO nanosheet arrays constructed on weaved metal wire for flexible dye-sensitized solar cells, Dai H, Zhou Y,

Chen L, Guo BL, Li AD, Liu JG, Yu T, Zou ZG, Nanoscale 5, 5102-5108(2013)………………………………………

279

National Lab of Solid State Microstructures

xxviii

561 Rational and scalable fabrication of high-quality WO3/CdS core/shell nanowire arrays for photoanodes toward

enhanced charge separation and transport under visible light, Li HJ, Zhou Y, Chen L, Luo WJ, Xu QF, Wang XY,

Xiao M, Zou ZG, Nanoscale 5, 11933-11939(2013)…………………………………………………………………….

279

562 Dispersion-compensating en/decoder for a time-spreading/wavelength-hopping optical code-division multiplexing

(OCDM) system, Zheng JL, Wang R, Pu T, Lu L, Fang T, Su Y, Li L, Yang Q, Chen XF, Optica Applicata 43, 485-495

(2013)……………………………………………………………………………………………………………………

279

563 Study on fiber ring laser in sensing application with beat frequency demodulation, Gao L, Huang L, Chen L, Chen XF,

Optics and Laser Technology 45, 137-141(2013)……………………………………………………………………..

280

564 Simultaneous measurement of strain and temperature with a multi-longitudinal mode erbium-doped fiber laser, Gao

L, Huang L, Chen L, Chen XF, Optics Communications 297, 98-101(2013)…………………………………………

280

565 High efficient blue emission of Ce3+ activated Ca4P2O9 phosphor for white LEDs, Zhao X, Fan L, Yu T, Li ZS, Zou ZG,

Optics Express 21, 31660-31667(2013)………………………………………………………………………………..

280

566 A novel concavely apodized DFB semiconductor laser using common holographic exposure, Shi YC, Li SM, Guo RJ,

Liu R, Zhou YT, Chen XF, Optics Express 21, 16022-16028(2013)…………………………………………………..

280

567 Efficient surface second-harmonic generation in slot micro/nano-fibers, Luo W, Guo W, Xu F, Lu YQ, Optics

Express 21, 11554-11561(2013)………………………………………………………………………………………..

281

568 Photonic-assisted microwave frequency multiplication with a tunable multiplication factor, Gao L, Liu WL, Chen XF,

Yao JP, Optics Letters 38, 4487-4490(2013)……………………………………………………………………………

281

569 Towards efficient solar hydrogen production by intercalated carbon nitride photocatalyst, Gao HL, Yan SC, Wang JJ,

Huang YA, Wang P, Li ZS, Zou ZG, Physical Chemistry Chemical Physics 15, 18077-18084(2013)……………….

281

570 Formation energy and photoelectrochemical properties of BiVO4 after doping at Bi3+ or V5+ sites with higher valence

metal ions, Luo WJ, Wang JJ, Zhao X, Zhao ZY, Li ZS, Zou ZG, Physical Chemistry Chemical Physics 15,

1006-1013(2013)………………………………………………………………………………………………………..

281

571 Simple method for the fluorinated functionalization of graphene oxide, Pu LY, Ma YJ, Zhang W, Hu HL, Zhou Y,

Wang QL, Pei CH, RSC Advances 3, 3881-3884(2013)……………………………………………………………….

282

572 Tunable orange red phosphors: S2--doped high temperature phase Ca3SiO4Cl2:Eu2+ for solid-state lighting, Zhao X,

Li ZS, Yu T, Zou ZG, RSC Advances 3, 1965-1969(2013)…………………………………………………………….

282

573 First demonstration of 1.3 mu m quarter-wavelength shift distributed feedback (DFB) semiconductor laser based on

conventional photolithography, Lu LL, Shi YC, Chen XF, Science China-Technological Sciences 56, 554-557(2013)

282

Annual Report 2013

1

实验室概况

固体微结构物理国家重点实验室成立于

1984 年，是国家首批成立的国家重点实验室之

一。实验室以凝聚态物理学、材料科学和信息科

学等多学科交叉融合为基础，面向量子调控等重

大前沿科学问题和国民经济发展的重大需求，围

绕微结构材料的设计、制备、性质及其应用等重

大科学问题与技术关键，以人工纳米结构材料与

器件、量子调控研究等为主要研究方向，设计、

制备微米、亚微米、纳米尺度的新结构，揭示新

的量子效应，发展量子调控科学，进而发展新一

代的光电器件及其应用，以期为技术创新提供科

学积累，促成我国新一代信息技术的跨越式发展。

实验室现有固定人员 72 人，其中中科院院士

8 位：冯端教授、王业宁教授、闵乃本教授、龚昌

德教授、都有为教授、邢定钰教授、祝世宁教授、

王广厚教授；长江奖励计划特聘教授 17 位，国家

自然科学基金委“杰出青年基金”获得者 19 位。

目前实验室主要研究方向包括人工微结构科

学与工程、量子调控的电子学、纳米结构物理及

器件、软物质的结构与功能、微结构材料设计和

理论计算、基于微结构的高新技术及其应用等 6

个研究方向。作为首席科学家主持的国家级重大

研究计划项目有 9 项，分别是吴迪教授主持的国

家重大科学研究计划项目“若干关联系统中多重

量子序的共存、竞争与调控研究”（2009-2013）；

丁海峰教授主持的国家重大科学研究计划项目

“ 低 维 自 旋 体 系 的 量 子 效 应 及 其 调 控 ”

（2010-2014）；邢定钰教授主持的国家重大科

学研究计划项目“固体微结构的量子效应、调控

及其应用研究”（2011-2015）；肖敏教授主持的

国家重大科学研究计划项目“全固态量子信息处

理 关 键 器 件 的 物 理 原 理 及 技 术 实 现 ”

（2012-2016）；彭茹雯教授主持的国家重大科

学研究计划项目“人工微结构材料中光、声以及

其它元激发的调控”（2012-2016）；王牧教授主

持的国家重点基础研究发展计划项目（973 项目）

“光电功能晶体的结构、性能和制备过程研究”

（2010-2014）；陈延峰教授主持的国家重点基

础研究发展计划项目（973 项目）“人工微结构红

外光电耦合材料及深空目标探测应用研究”

（2013-2017）；王炜教授主持的国家重点基础

研究发展计划项目（973 项目）“与激光聚变、自

然灾害和深空探测相关的非线性动力学斑图和轨

道稳定性研究”（2013-2017）；邹志刚教授主持

的国家重点基础研究发展计划项目（973 项目）

“高效光催化材料及其应用的基础研究”

（2013-2017）。目前各类科研项目进展顺利。

固体微结构物理国家重点实验室期望通过若

干年的努力，将实验室建设成为从事高水平科学

研究、拥有高层次实验研究平台和高素质的科学

技术队伍、具有学科交叉、人才汇聚、管理科学、

流动开放等特征的有重要国际影响的微结构研究

基地和国家科技现代化的创新平台。

National Lab of Solid State Microstructures

2

第八届学术委员会委员名单

学术委员会主任：邢定钰 中科院院士、教授 南京大学

学术委员会成员：龚旗煌 中科院院士、教授 北京大学

龚新高 教授 复旦大学

郭光灿 中科院院士、教授 中国科学技术大学

解思深 中科院院士、研究员 中国科学院物理研究所

金晓峰 教授 复旦大学

李树深 中科院院士、研究员 中国科学院半导体研究所

柳百新 中科院院士、教授 清华大学

闵乃本 中科院院士、教授 南京大学

欧阳钟灿 中科院院士、研究员 中国科学院理论物理研究所

潘建伟 中科院院士、教授 中国科学技术大学

秦金贵 教授 武汉大学

沈学础 中科院院士、研究员 中国科学院上海技术物理研究所

王 牧 教授 南京大学

闻海虎 教授 南京大学

向 涛 中科院院士、研究员 中国科学院物理研究所

肖 敏 教授 南京大学

谢心澄 研究员 北京大学

徐至展 中科院院士、研究员 中国科学院上海光学精密机械研究所

薛其坤 中科院院士、教授 清华大学

叶朝辉 中科院院士、研究员 中国科学院武汉物理与数学研究所

张 泽 中科院院士、教授 浙江大学

张守著 研究员 国家自然科学基金委

张裕恒 中科院院士、教授 中国科学技术大学

朱邦芬 中科院院士、教授 清华大学

祝世宁 中科院院士、教授 南京大学

Annual Report 2013

3

2013 年研究工作总结

固体微结构物理国家重点实验室以凝聚态物

理学、材料科学和信息科学等多学科交叉融合为

基础，面向量子调控等重大前沿科学问题和国民

经济发展的重大需求，围绕微结构材料的设计、

制备、性质及其应用等重大科学问题与技术关键，

以人工纳米结构材料与器件、量子调控研究等为

主要研究方向，设计、制备微米、亚微米、纳米

尺度的新结构，揭示新的量子效应，发展量子调

控科学，进而发展新一代的光电器件及其应用，

以期为技术创新提供科学积累，促成我国新一代

信息技术的跨越式发展。

实验室 2013 年发表 SCI 论文 573 篇，其中

以第一单位完成的论文 334 篇，包括 Nature

Communications 2 篇、Nature Materials 1

篇、Nature Photonics 1 篇、Nature Physics 1

篇、Phys. Rev. Lett. 7 篇、Adv. Mater. 3 篇、

Phys. Rev. 系列 25 篇、Appl. Phys. Lett. 21

篇；以非第一单位完成的论文 239 篇，包括

Nature Communications 3 篇 、 Nature

Materials 1 篇、Phys. Rev. Lett. 6 篇、Phys.

Rev. 系列 15 篇、Appl. Phys. Lett. 15 篇。各

研究方向的具体研究进展如下：

1. 人工微结构科学与工程

从理论和实验上研究超构材料中时空对称性

质，（a）计算分析方法上：发展关于磁电材料、

旋磁材料、时空超构材料等新颖结构材料的本征

值问题和谐波模拟的计算方法；发展了动力学含

时系统的本征值问题计算和谐波计算方法，并建

立相应的紧束缚计算模型来分析电磁超构材料和

声结构材料的能带色散问题和计算相应的拓扑相

位。（b）新型时空对称超材料的设计：结合时空

对称调控原理，引入材料的实部调制和虚部调制，

设计了新型的 parity-time（PT）单向衍射光栅，

PT 单向反射的 Si 波导，基于 PT 对称阈值点的单

向完美吸收器等新型器件，独立发展了新型的基

于 Passive 介质的耦合波理论和散射矩阵理论，

分析时空对称的相变规律。这些新的微结构波调

控原理将为新型光电探测器设计提供新的思路。

（c）物理效应和原型器件上：系统地研究了基于

时间反演的对称性破缺系统下旋磁介质光子晶体

奇异物理效应，研究光子晶体中的边界态单通效

应，并以此单向隐身等关键性的问题；系统地研

究了时空对称电磁超构材料和CMOS工艺兼容的

Si 基的光子芯片技术，同时调制光子芯片的 Si

的折射率的实部和虚部，在量子力学的时空对称

性破缺临界点上实现了对波单向传输的控制，实

现了波的单向反射传输。

研究金属表面等离激元（SPP）的传播与激发

性质，对之前利用面内衍射对 SPP 调控进行拓展，

设计了对称相位设计完成了多种准直且无衍射的

SPP 波束，并且针对 SPP 的传播损耗设计特殊的

相位分布实现了一定区域内“无衰减”的 SPP 波

束。实现了 SPP 波与空间光束之间的转换，利用

National Lab of Solid State Microstructures

4

特殊设计的非周期光栅将表面传播的 SPP 有效地

耦合成空间辐射的聚焦光束及 Airy 光束。实验上

清晰地观察到了 Airy 光束的无衍射自弯曲的特

性，理论模拟证实了这类光束的自修复性质。基

于电激励的 LED 实现了偏振调控的动态显示与偏

振复用器件。将电激励 LED 芯片作为衬底制备了

具有特殊小孔取向的金属微纳结构，根据偏振取

向的异常透射效应设计了二位偏振编码和灰度图

形显示以及动画显示的结构，并在实验上成功实

现。建立了 SPP 干涉检测系统，设计了针对面内

SPP传播的透反射结构，完成了 SPP 的 MZ干涉，

实现了具有面内光开光功能的 SPP 器件，并进一

步拓展到 SPP 波导中，不仅完成了更紧凑性的

SPP 开关（器件尺寸小于 66 m2）而且发现了

一种特殊的复合干涉机制。

在光波段超构材料实验中，在一块微小的光

子芯片上，采用简单而巧妙的旋涂加热工艺，利

用微球表面与聚合物薄膜接触的表面张力，在一

块微小的光子芯片上，实现了折射率具有类似中

心引力场分布的光学微腔。光子在这种微腔中的

传播特性可以模拟出光子在天体引力场中传播受

引力场吸引所产生的弯曲。理论上采用广义相对

论的爱因斯坦方程，计算了不同入射光子的传播

路径，实验中利用量子点荧光激发，测量了不同

入射距离的光束在弯曲波导中的传播路径。结果

证明，与黑洞周围引力场“视界”类似，这种微

腔也存在一种临界半径，当光子的传播路径通过

临界半径包围的区域，光子就会被微腔捕获，而

当光子的传播路径远离临界半径区域，光子不会

被捕获，只是路径发生弯曲，实验结果与理论很

好的符合。与以前的大多数共振光学微腔相比，

所得到的非共振光学微腔具有宽波段特性，可以

捕获较宽的连续波段内的光子，这也发展了光学

微腔一种新的功能，可以应用于光子芯片上的宽

波段激光器，光电探测，光伏器件等。《自然》杂

志主页“NEWS&COMMENTS”专栏对这个工作

进行了评述，国际著名超构材料专家 Leonhardt

教授评价这个工作是“第一次在光子芯片上，用

简单的实验，精确而漂亮地演绎了爱因斯坦广义

相对论所描述的部分思想”。

在蓝相液晶材料及其光学器件研究方面，利

用相干光照射倾斜放置的简单光栅，基于塔尔博

特效应和液晶光控取向技术制备了复杂图形的液

晶微结构，利用蓝相液晶制备了通讯波段的可调

光衰减器，在全波段范围内实现了 30dB 的动态

调制。从理论上证明在微纳光纤表面引入槽型结

构，利用表面非线性效应，可以实现二次谐波激

发效率数量级的提高，通过在单模光纤中接入一

段软玻璃光纤，制备出一种对折射率不敏感的光

纤温度传感器，有效消除了环境折射率的干扰，

利用 FIB 技术，在 D 型光纤表面制备出微米尺度

的金属光栅，实现通讯波段表面等离激元模式的

激发，并在液体折射率传感的应用中获得了很高

的线性度和灵敏度。

在新型微结构光学器件和效应研究方面，首

次从理论和实验两方面证实，当白光通过具有微

结构的银纳米线时，不同颜色的光可以在空间和

时间上分离开来；从而发现微结构的银纳米线可

以充当同时具有纳米级空间分辨以及飞秒级时间

分辨的波分复用器件，可应用于高性能光子芯片

的研制。在前期工作基础上首次实验证实亚波长

金属光栅对于太赫兹宽波段具有极好的透明性

质；接着设计和制备出倾斜金属光栅结构，实现

了垂直入射情况下金属结构对横磁模电磁波的宽

带透明，并且利用太赫兹成像技术直观地展示金

属微结构宽带透明效应；接着设计和制备出二维

金属阵列结构，实现了可见光波段的宽带透明金

属，并展示其在高性能太阳能薄膜电池中的应用，

Annual Report 2013

5

同时这种透明金属在光信息处理和光集成等方面

也具有诱人的应用前景。首次将银纳米等离激元

分形结构引入薄膜硅太阳能电池，揭示其对超薄

硅电池具有宽带吸收和效率增强的效应，为设计

新型薄膜太阳能光伏器件提供了新的科学思路。

从理论和实验两方面研究了电磁感应透明效应在

超构材料中的实现，发现和证实超构材料中光学

磁性诱导的电磁感应透明现象，并揭示出该系统

中的慢光特性，该研究结果在量子信息存储等方

面具有潜在的应用。

发展了精确制备亚波长尺度金属表面微纳结

构，采用特殊的无支撑的二维胶体晶体作为模板，

通过在胶体晶体模板上下表面两次物理沉积金属

的方法，成功获得了由介质-金属核壳结构构成的

表面等离激元微腔，这种表面等离激元微腔中存

在着丰富的模式耦合特性，为有效调控等离激元

模式激发特性提供了新的手段；完成了这种金属

纳米球壳阵列的 Fano 共振的调谐特性的理论和

实验研究；通过在平整金属膜层上生长二维胶体

晶体，然后再沉积不同厚度金属膜层，得到一种

新型的可应用于光全吸收的等离激元结构，其存

在两个宽带近完美的全吸收，在长波段和短波段

的最大吸收分别超过 99%和 97%；从理论上研

究等离激元微腔的存在对单个纳米发光体的影

响，如对单个纳米发光体的荧光增强和定向辐射

特性，采用一个电偶极子来描述单个纳米发光体，

通过调整等离激元微腔的尺寸，来调谐等离激元

微腔所支持的不同阶数的腔模共振频率，发现当

腔模共振频率与偶极子振荡频率相近时，偶极子

的辐射明显增强，同时通过在核壳结构构成的等

离激元微腔中引入对称性破缺，偶极子的辐射将

表现一种高定向的辐射。

从金属表面等离激元共振出发，设计了一种

单层的金属纳米结构，在零阶透射实现了极大地

光学旋转率（在实验中获得光的旋转率为

4.1×105度/毫米，远大于任何一种自然材料的，

如石英晶体，旋转率仅仅为 17 度/毫米）。其物理

机制如下：通过微结构的精确设计，实现 SPP 和

LSP 共振同时激发。利用 LSP 共振，实现偏振与

入射偏振方向垂直的电磁辐射输出。利用 SPP 波

穿过样品结构时带来的相位延迟效应，通过调制

样品厚度使SPP和LSP产生的偏振平行于入射偏

振方向的电磁辐射相消叠加，从而实现对单层零

阶透射光学偏振旋转的有效控制。随着样品厚度

的增加，光学旋转角度也得到非线性的增加。尤

其是当厚度为 245nm 时，在零阶透射中实现了

接近于线偏振的 90°光学旋转。该结构的设计对

于未来集成光子器件有潜在的应用可能，在物理、

生物、化学等方面都有重要的应用价值。

2．量子调控电子学

在关联电子系统和超导电性方面，测量了不

同铁基超导体系的电子隧道谱，发现了一种普遍

存在的电子集体激发模 Ω，这个电子激发模与磁

激发谱的共振峰能量相近，并且发现该模的能量

与超导转变温度Tc成近似正比关系Ω4.3kBTc。

该共振模的一个可能解释是来自于磁性配对导致

超导态以后，电子系统发生自旋为 1 的拆对激发

的后果，因此该工作说明了铁基超导的磁性配对

起源。

在铁基超导体中人为引入非磁性铜杂质散射

中心，用磁化手段证明它是无磁性的，并用扫描

隧道谱手段，观测到该无磁杂质所产生的能隙内

的单粒子态密度，从而判明了目前国际上争论较

多的 s 和 s++中两大模型中前者是唯一正确

的。

National Lab of Solid State Microstructures

6

制备了BiS2基的超导材料Bi4O4S3多晶样品

并首次制备了 NdO1-xFxBi1-yS2的单晶样品，通过

系列手段的测量，发现该类样品有很大的超导能

隙和超导涨落温度，涨落超导温度可以达到 20K

以上。

综合考虑反映电子巡游特怔的在点库仑相互

作用和局域的次近邻反铁磁交换耦合作用，利用

涨落-交换近似研究了铁基超导 AxFe2-ySe2 中的

自旋涨落性质与超导配对对称性。结果表明，次

近邻反铁磁耦合显著影响其自旋激发和超导配对

对称性。微小的次近邻反铁磁耦合将使系统的超

导配对从 d-波过渡至扩展的 s-波。此扩展的 s-

波在费米面上无节点，因而与最近的角分辩光电

子谱实验相符。另一方面，巡游自旋涨落和局域

自旋的综合作用导致自旋激发的特征峰位置与中

子散射实验结果相符。这些理论结果表明：电子

的 巡 游 特 怔 和 局 域 磁 性 在 描 写 铁 基 超 导

AxFe2-ySe2 中的自旋激发和超导配对中都起重要

的作用。

在拓扑绝缘体及 Dirac 体系输运性质方面，

提出了一个较为实际的方法来实现无需对称性保

护的、稳定的量子自旋霍尔效应。在一个量子自

旋霍尔样品边缘上可以通过磁性原子掺杂制造一

个铁磁区域，在铁磁区域中将产生一个交换场。

利用自旋陈数，研究了交换场对原先的量子自旋

霍尔态的影响，发现当交换场强度超过体系原先

的带隙时，将导致铁磁区域发生一个从量子自旋

霍尔态到量子反常霍尔的拓扑量子相变。这个相

变将把原来处于条形样品边缘上的两个相向运动

的边缘态之一推到磁性区域内侧，而另外一个仍

然留在样品的外侧。在此过程中，边缘态的自旋

极化方向的传播方向几乎不发生改变，因此这个

系统仍然表现量子自旋霍尔效应的性质。这个工

作为通过人为消除体系时间反演对称性从而实现

无需对称性保护的量子自旋霍尔效应，为寻找更

加稳定的量子自旋霍尔效应指出了一个新的方

向。

观测到金属性 Bi2Te3 中的拓扑表面态的

SDH 振荡。用熔融法制备拓扑绝缘体 Bi2Te3。系

统的测量发现大部分的样品表现出 p 型的金属输

运行为和来自于体相的三维 SDH 震荡。然而，在

金属样品 M 中，通过转角的磁输运第一次发现了

来自于二维拓扑表面态的 SDH 震荡。分析表明，

样品 M 和其他的样品有着明显的不同，高电阻率

高达10mΩ/cm，表面迁移率达到7000cm2/Vs，

几乎是体相迁移率的三倍，这些性质有利于呈现

表面态 SDH 震荡。分析表明样品 M 的表面态电

导占整体输运电导的比例为 0.3%。

观测到低迁移率石墨烯室温弱局域化效应。

作为一种量子修正，弱局域化效应都在低温或者

高迁移率的样品表现出来。分析了石墨烯中电子

输运量子修正的物理机制，发现石墨烯中存在大

量“锐利”的缺陷，这一缺陷使得电子自由程、

电子的谷间散射长度、谷内散射长度在低温下几

乎相等，而电子相干长度则不受影响，最终表现

出室温下可见的弱局域化修正。

在量子光学及非线性光学等方面，将时间标

签、时间分辨超快光学技术应用于由单个 CdSe

量子点和系综染料分子组成的能量转移体系，通

过荧光强度和荧光寿命的关联测量，首次实现了

教科书中定义的染料荧光量子产率标定，并揭示

了通过单个胶体量子点的单激子能量转移将体材

料转化成单光子发射源的可行性。

发现 InGaN 量子阱中横向的载流子扩对于

氮化物 LED 中效率衰变起到很大作用；着重探究

了热电子过程以及超快时间尺度量子相干性，发

现石墨烯在弯曲成纳米小球后，热电子发光会得

到极大的增强；在二型量子点中，发现超快尺度

Annual Report 2013

7

下电荷转移激子可产生很强的光学非线性响应。

成功观测到超导体相变的光激发准粒子的动力学

标志，在铁基超导体中观测到轨道相关的 Mott

相变特征。

在非线性自成像效应的人工调控研究中取得

了进展，首次在实验上实现了非线性光子晶体中

的准相位匹配二次谐波自成像效应，成像的强度

和质量大大提高。

在芯片上制备出了稀土掺杂的高品质因子氧

化硅光学微球腔。利用 1480nm 波长的连续激光

泵浦，实现了阈值低于 5μW的通信波段的微型激

光器。另外，还制备出了品质因子大于 107 的光

学微腔的耦合系统，在芯片上实现了 20 MHz 超

窄带宽的类电磁感应透明。

在固体量子计算方面，提出检测超导位相比

特和微观两能级耦合系统中微观两能级系统的新

方案。在超导位相量子比特中利用 Landau-

Zener 干涉实现了几何相的量子调控，首次观测

到几何相的 Landau-Zener 干涉，并发现几何相

的 Landau- Zener 干涉比相应动力学相的干涉

振幅更大，对实现容错量子计算有重要作用。

在多铁材料方面，理论研究了新型多铁性材

料 CaMn7O12 的磁性及铁电来源。发现自旋失措

结构与 Mn1 离子之间的反铁磁耦合有关，铁电极

化的来源包括非共线的交换伸缩机制和计入自旋

轨道耦合的p-d杂化机制，其中发生在Mn2-Mn3

电荷序链的交换伸缩机制是铁电的主要来源。

研究了 BiFeO3纳米颗粒的反常尺寸效应。发

现当颗粒尺寸接近其螺旋自旋周期时，颗粒表现

异常增强的铁磁性和大的磁介电效应。认为氧八

面的旋转扭曲在颗粒接近 62nm 自旋周期时会有

所增强，进而增强 DM 相互作用，提高铁磁性及

磁电耦合。

另外开展了液体表面波的衰减研究，将有孔

衬底与待测液体组成一个复合系统，通过研究复

合系统随时间液体逐渐挥发的力学响应，发现在

液体的挥发后期，液体表面波对复合系统的力学

损耗有明显的贡献。该研究为液体表面波的研究

提供了一种新颖简便的实验表征方法。

在有机自旋阀方面及异质界面等方面，研究

La0.67Sr0.33MnO3（LSMO）电极磁性对有机自旋

阀磁电阻的影响和自旋在 Alq3中弛豫的机制。用

PLD 生长原子级平整的 LSMO 薄膜，通过氧气退

火 Tc 达 360 K，由此制备的有机自旋阀（OSV）

磁电阻得到了很大提高，室温有 2.2%的磁电阻。

100K 以下磁电阻下降，其原因为 Alq3的自旋弛

豫。

研究 LaAlO3/SrTiO3异质界面的导电机制。

在绝缘的 LaAlO3（3 uc）/SrTiO3（001）界面

上生长La1-xSrxMnO3覆盖层，当Sr浓度低于2/3

时，LaAlO3/SrTiO3 界面显出金属性，载流子的

迁移率几乎与 Sr 的浓度无关，说明外加覆盖层没

有改变界面氧空位浓度和界面互扩散，但是载流

子密度随 Sr 浓度的增加单调的下降，这个现象被

归结于 La1-xSrxMnO3中Sr 电极化率的降低而导

致，该结果强烈的支持界面导电机制中的极化不

连续机制。

在氧化物材料方面。氧化物单晶材料的研究

集中于拓扑绝缘体晶体（拓扑 Kondo 绝缘体，拓

扑半金属晶体）以及过渡金属硫化物晶体的生长

及基本的输运工作；开展了氧化物畴界导电性的

理论计算，并初步开展了氧化物拓扑绝缘体的理

论计算工作；在氧化物薄膜方面，继续开展具有

高铁磁居里点的双钙钛矿氧化物和多种单元氧化

物薄膜、超晶格的研究工作，设计、制备完成了

一系列样品并表征了相关的微结构和磁性、输运

性质。

National Lab of Solid State Microstructures

8

3．纳米结构物理与器件

基于对掺杂空穴在反铁磁背景中运动的认

识，提出了一个适用于欠掺杂铜氧化合物赝能隙

态的有效哈密顿，有效模型很好地描述了赝能隙、

超导能隙的掺杂依赖以及动量空间的分布，对输

运特性的研究也与实验定性一致。基于有效模型

进一步研究了空穴掺杂铜氧化合物的磁激发特

性，很好地建立了磁激发谱的结构相变，沙漏型

色散，特别是指出了这些行为是正常态特性，与

超导没有直接关系，提供了一个不同于以往理论

的新观点。研究了电子掺杂铜氧化合物低能公度

磁激发行为，提出了能带劈裂和费米面的拓扑行

为是低能公度的起源，并且这种低能公度也是正

常态的性质，与超导没有直接关系。

通过固体 NMR，FTIR，BET 以及 XRD 等手

段发现氧化石墨中存在着两种不同的纳米级受限

空间，一种是氧化石墨片之间的二维结构，另外

一种是氧化石墨片状颗粒堆砌产生的裂缝状孔

道。考察了含水氧化石墨 100 K－300 K 温度范

围内的介电性质，通过在电极和样品之间增加极

薄聚四氟乙烯层的方法，避免了电极极化，使掩

盖在极大导电背景下的弛豫得以显示。清楚的揭

示了受限在氧化石墨体系中水分子存在两种不同

的弛豫行为。两种弛豫来源于氧化石墨中不同的

水分子，高温的 P1 过程为氧化石墨层间受限的水

分子运动产生，P1 过程的活化能接近断裂三个氢

键的键能，表明氧化石墨中的水分子所形成的四

个氢键，在转动过程中断裂三个氢键。在低含水

量的氧化石墨样品中，P1 过程满足 Arrhenius

关系，描述了水分子的局域运动。随着含水量的

增加，P1 过程运动速率变快，并且 P1 过程温度

依赖形式偏离了 Arrhenius 关系，说明水分子的

运动形式由不均匀的局域运动向集体运动转变。

研究了表面活性剂包裹对纳米粒子氧化物粒子的

磁性影响。不同的表面活性剂会导致不同的表面

磁性，并且氧化物纳米粒子核的磁性随表面活性

剂溶度的变化会产生震荡。

基于银锗硒（AGS）材料构建了一类具有电

突触功能的忆阻器，验证了其突触峰时依赖可塑

性。基于突触权重的长时程增强 LTP 和长时程抑

制 LTD 特性，发展了一种忆阻运算方法，以

5÷4=1.25 为例实现了小数运算，为发展忆阻智

能运算提供了一条新途径。为了进一步理解 AGS

忆阻器的工作原理，基于原位 TEM 观测研究了

LTP 和 LTD 过程中 AGS 微结构的动态演化，发

展了一种针对固体电解质忆阻材料原位TEM观测

的样品制备技术，避免了在使用 FIB 和离子减薄

等环节对固体电解质材料带来的不必要的损伤。

研究发现不同于经典固体电解质电化学理论的导

电通道形成规律：导电通道形成于反应电极，而

不是传统理论认为的惰性电极处。证实了构成导

电网络的是正交相 Ag2Se，而不是之前普遍认为

的由电化学沉积所形成的 Ag。据此，从 Ag2Se

非均匀成核与生长出发，提出了一种化学诱导忆

阻相变的新理论。

通过高压方法合成了立方 Laves 相 PrFe1.9

合金，用低温高精度 X 射线衍射（XRD）扫描和

强磁场方法研究了该合金的磁致伸缩效应。低温

测试发现合金具有相当大的磁致伸缩值：在 15 K

温度、外加磁场 90 kOe 时，合金的磁致伸缩值

达到了 7000 ppm。为了研究合金的内禀磁致伸

缩（λ111）随温度的变化，采用 XRD，从 300 K

到 15 K 之间分别对合金的{440}和{222}XRD

特征峰进行了精度扫描。发现在 300 K 到 70 K

温度范围内合金的易磁化方向为[111]。对于易磁

化方向为[111]的立方 Laves 相合金，根据{440}

Annual Report 2013

9

衍射峰的劈裂计算出了合金在[111]方向上的自

发磁致伸缩值 λ111。算出合金在 70 K 温度下 λ111

为 6700 ppm，这个值甚至比根据 Steven’s等

价操作算符所预测出来的 0 K 下的理论值 5600

ppm 还要大。根据单粒子模型理论，随着温度的

降低，合金中的稀土金属-过渡金属以及过渡金属

-过渡金属的交换作用会增强，这个增强的交换作

用将会导致磁致伸缩会随着温度的降低而升高。

因此预测在 0 K 下，具有[111]易磁化方向的

PrFe1.9合金将具有更大的磁致伸缩效应。这表明，

PrFe1.9合金作为磁致伸缩材料有可能在低温下有

潜在的应用。

研究了金属纳米粒子的局域等离激元（LSP）

之间的近场耦合机制以及金属纳米粒子的局域等

离激元（LSP）与金属纳米薄膜中的等离极化激元

（SPP）的近场耦合机制。探讨了金属纳米粒子点

阵与多孔介质纳米粒子点阵对介质内全内反射光

的引出机理，以及金属纳米结构引出介质内全反

射光的消逝波等离激元共振增强散射机制。在

GaN 基 LED 典型发光波长 450 nm，实现全内

反射光引出 4%，LED 光致发光增强 92%，电致

发光增强 26%。研究了基于密集排列金属纳米点

阵的传感机理，构建了 Ag 纳米粒子修饰的玻碳

电极，在 H2O2 非酶生物传感中灵敏度达到 63

A/mM、响应速度＜1s、检测限达 1μM，实现了

基于 Pd 纳米粒子点阵的超快氢气传感，基于 Cr

纳米粒子点阵的高灵敏度宽响应范围的应变传

感，以及基于一维 Ag 纳米粒子链的表面增强拉曼

分子痕量检测。

通 过 微 区 探 针 实 验 技 术 ， 揭 示 出

Bi0.9La0.1FeO3 多晶薄膜中晶界和晶粒内部的电

导特征及其随着外电场的变化规律，阐明了局域

电导的物理机制，即：在低电压下电导由晶界主

导，并与氧空位在电场下的重新分部相关；在高

电压下电导则由晶界和铁电畴的翻转共同控制。

基于第一性原理方法，预测了在含有单空位缺陷

的石墨烯表面沉积 Ir2 可使体系的稳定性和磁各

向异性能大幅度提高，揭示出该体系具有巨大磁

各向异性能的机制是源于 Ir2 在缺陷中心处的特

殊对称性导致的沿不同磁化方向的局域电子态密

度的差别；还发现了一种新型磁性超原子团簇：

TcMg8，揭示出该超原子团簇的形成机制主要与

体系中大的交换耦合作用和适中的晶体场效应密

切相关。

系统研究了 Pt/BaTiO3/SrRuO3铁电隧道结

电致电阻的温度依赖特性，发现除直接隧穿外，

以势垒层中的声子辅助隧穿是结电流的另一个贡

献。这种非弹性隧穿电流强烈依赖于温度但对势

垒形状，也就是势垒中极化方向不敏感，导致了

随温度升高，极化翻转对结电流调制的下降。研

究揭示了铁电隧道结中缺陷对其电致电阻特性的

影响，指出降低缺陷密度是提高隧道结存储特性，

特别是室温下数据成功写入和读出的重要前提。

常见的铁电隧道结采用金属电极，极化翻转仅能

调控势垒高度。但是量子隧穿几率同时依赖于势

垒高度和宽度。研究了基于金属/超薄铁电薄膜/

半导体结构的新型铁电隧道结。通过铁电场效应

可以使半导体表面在积累和耗尽之间翻转，从而

实现极化翻转对势垒高度和宽度的同时调控，获

得增强的电阻开关比。在 Nb:SrTiO3半导体衬底

上外延了厚度仅为 7 个晶胞高度（约 3 nm）的

高质量 BaTiO3 铁电薄膜，在 Pt/BaTiO3/

Nb:SrTiO3隧穿结构中实现了高达 104的电阻开

关比，比文献报道的最好结果提高了两个数量级，

并且表现出可靠的阻态翻转重复性和长时间的数

据保持性。这些突出的性能表明这一新型铁电隧

穿结构在非挥发阻性铁电存储方面具有极大的应

用潜力。

National Lab of Solid State Microstructures

10

对石墨烯等材料在各种形貌下的特殊性质和

可能的应用进行了较深入的理论研究，提出一些

可能的材料和器件结构，从理论上研究了沿着

zigzag 方向的石墨烯纳米条带的电子导电性质，

提出了采用这种条带的Datta-Das效应来构造纳

米晶体管和电导开关的可能性。研究了石墨烯在

具有电子间库伦互作用、错列势能以及内禀的自

旋-轨道互作用的情况下的电子性质，研究了各种

条件下系统的拓扑对称性和拓扑相变，并得到了

拓扑相变的相图。与实验工作结合，对 In2O3 的

截角八面体的电子性质进行理论研究，通过第一

性原理的计算，表明在截角面上确实存在能够加

速光催化作用的电子态，较好地解释了实验中所

发现的新效应。

针对纳米硅量子点在新型光电子器件中的应

用，系统研究了载流子在纳米硅中的注入和输运

过程，提出了一种利用 AFM/KFM 联合测量定量

分析载流子注入的模型和方法，并制备了纳米硅/

碳化硅多层结构电致发光器件；针对掺氧非晶氮

化硅薄膜发光稳定性的问题，通过探索制备和后

处理的手段和参数，明显改进了材料的发光稳定

性，获得了量子效率为 62%的发光掺氧非晶氮化

硅薄膜，为进一步研究和提高光增益打下了良好

基础。利用纳米小球刻蚀技术制备了纳米图形衬

底，结合纳米硅量子点/二氧化硅多层结构制备了

硅量子点/单晶硅异质结电池结构，从实验上发现

图形衬底明显地在宽光谱范围内提高了光吸收，

使得电池的短路电流密度有了明显地增加。

在新型存储器的研究方面，在 SMIC 工艺线

上得到了单分散性为 10% 左右、密度为

2×1011cm-2 的纳米硅量子点阵列，设计了 8

kbits NOR 结构存储矩阵的操作偏置接入方式和

相应结构存储矩阵的外围电路，仿真的结果达到

了预先设计的参数。在 Pt/SiO0.73/Pt 三明治结构

中观测到了不同于国际上报导的单极型阻变现

象，表现为其具有更低的操作电压，同时其 Reset

电压小于 set 电压。提出了“硅悬挂键渗流理论

模型”，认为在 Forming 操作时，通过电场诱导

的 Si-O 键的断裂生成新的硅悬挂键，进而形成悬

挂键渗流通道，器件显示低阻特性。Reset 操作

时，由于低阻态可以允许大电流通过，产生高的

焦耳热对悬挂键起到钝化作用，从而使器件回到

高阻状态。对具有不同 x 值的 Pt/SiOx/Pt 结构阻

变特性的进一步研究证实了我们提出的模型。通

过电子束蒸发的方法制备了 GST 和 Si-GST 薄

膜，并通过原位电阻测试的方法研究了薄膜的热

致相变动力学过程并将不同薄膜的所得结果进行

了对比。通过原位变温电阻测试的方法可知相比

于纯 GST 薄膜，Si-GST 薄膜有着更高的结晶温

度和晶态电阻率，并且这些物理量会随着 Si 掺杂

浓度的增加而进一步提高，这表明 Si-GST 薄膜

有着更好的非晶态热稳定性且可有效降低

PCRAM 器件的功耗。

在硅基纳米线结构的光电特性和光伏器件应

用方面，基于以往的工作系统地提出了“低熔点

金属”催化的纳米线生长模型。在实验上验证了

VLS 生长纳米线表面的液态金属超薄层的存在，

及其在此类金属催化纳米线过程中的普遍性。首

次深入研究了此现象对于稳定纳米线生长的重要

作用，并提出了一套相应的理论模型和框架，解

释了一直以来对于“低熔点”金属诱导纳米线生

长的理论难题。同时，利用 Sn，In 等金属生长的

洁净纳米线结构，在 PECVD 系统中成功制备了高

效径向结薄膜太阳能电池，其效率达到 8.14%

（保持为目前同类结构的世界记录），并大幅提高

了器件稳定性（光至衰减小于<6%，相比于通常

平面结构的 15%衰减）。进一步研究了三维纳米

结构中的光吸收、光电转换和独特的共振耦合等

Annual Report 2013

11

新奇特性。建立起一套可靠的模拟系统和模型体

系，为下一步的器件实现和性能爬升奠定基础。

在横向纳米线生长调控方面，继续专注于“自组

装-自定位”纳米线生长技术的理论基础和器件应

用。逐步完善了其引导生长的技术框架和相关模

型体系。并在实验上逐步实现了纳米线生长空间

调控的可靠性。

在非磁性半导体中引入磁性而制成的稀释磁

性半导体，因其既有半导体又有磁性的特性，从

而在自旋电子学方面的具有重要的应用前景。通

过表面修饰有机高分子可以有效地诱使非磁性半

导体出现铁磁性，这已成为该领域广泛采用的方

法。然而不同的研究组经常发现不同的研究结果，

即使在同一种系统中，如胺修饰的ZnO纳米粒子，

有研究组发现铁磁性，也有研究组发现没有铁磁

性。为澄清这种困惑，我们系统地研究了多种不

同浓度的有机分子（如 SDS、TOPO、PAA、PVP）

对 ZnO、TiO2、CeO2 等多种半导体纳米粒子的

修饰结果，揭示了纳米粒子的磁性会随着表面修

饰的有机分子的浓度增加而呈内秉性涨落变化，

这不仅有效地解释了以前各种貌似矛盾的结果，

而且为调控纳米粒子的磁性提供了一种新方法。

简单的布里渊区折叠模型预言扶手型碳纳米

管具有金属性，这种金属性不应随曲率而改变。

对小管径的扶手型碳纳米管的实验测量却发现了

小的能隙，且这种能隙即使在外场下依然存在。

缺乏合理的能带理论的解释，莫特绝缘体的概念

被作为可能的原因。然而纳米体系的充电效应无

法确认碳纳米管中的强关联电子效应。利用局域

泛函理论近似，证明褶皱效应在单管纳米碳管中

普遍存在，理想的圆筒形碳管甚至不是暂稳态。

褶皱结构总是比圆桶结构稳定，而褶皱幅度最管

径变小而快速上升。褶皱破坏了两类碳原子的格

点对称性，而绝对能隙的出现时这种对称性破缺

的结果。在扶手型碳纳米管从头计算的基础上，

将褶皱效应推广到一般碳纳米管，具体研究了各

种碳纳米管中绝对能隙和一般能隙与二位电子能

谱与一维电子能谱之间的关系，以及能隙与管径

间的依赖关系。

采用转移矩阵方法研究了石墨烯中狄拉克费

米子在电荷中性点附近的各向异性行为。在非对

角无序情况下 x-轴（锯齿形）的输运存在双参数

的标度行为，y-轴(扶手型)的输运存在退局域态，

并且满足单参数标度理论。进一步的研究表明衬

底导致的二聚化减弱了 x-轴方向的双参数标度行

为，但是保存了 y-轴方向的退局域态。研究同时

演示石墨烯在对角无序情况下的局域化各向异性

可以通过而据换来调节。

方钴矿是热电材料的优异候选者，可以用于

非机械热泵和发电机。利用局域泛函近似理论计

算了方钴矿 RuSb2Te 材料的电子能带结构和热

电性质。RuSb2Te 材料属于间接能隙半导体。局

域态密度在导带底部有快速上升沿。这种性质说

明 n-型半导体要比 p-型半导体具有更高的

Seebeck 系数。计算得到的 Seebeck 系数证实

了这种猜测。在 500K 温度之下，理论结果与实

验结果定性符合。

近年来，一维碳纳米材料（如碳纳米管、纳

米纤维、纳米螺旋等）受到了人们广泛的关注。

这些碳纳米材料可能应用于储氢材料、电磁波吸

收、电极材料、场发射器件、燃料电池等。最近

有很多报道采用过渡金属纳米颗粒为催化剂，可

以在较低的温度下催化裂解乙炔气体合成出螺旋

碳纳米纤维或螺旋碳纳米管等纳米材料，但过渡

金属纳米颗粒会包裹在碳纳米材料中很难去除。

为了除去这些催化剂，经常采用浓酸热处理等方

法，不仅耗费大量人力物力和大量时间，而且会

损坏碳纳米材料的结构，影响碳纳米材料的性能，

National Lab of Solid State Microstructures

12

严重制约了碳纳米材料的应用。创新性地采用水

溶性的碱金属碳酸盐为催化剂合成出螺旋碳纳米

材料，由于催化剂可溶于水，因此可以很方便地

从螺旋碳纳米材料中把催化剂去除，得到纯净的

碳纳米材料。既节省了纯化的成本，又不会对碳

纳米材料的结构和性能产生影响。为进一步研究

碳纳米材料的本征磁性创造了物质条件。

MoS2是一种二维半导体材料，具有 1.8 eV

直接带隙，在电子、光电器件方面有着广泛的应

用前景，是后硅时代的一种新型纳米电子材料，

近年来得到了学术界和工业界的广泛关注。在

MoS2进一步走向应用化的道路上，实际器件迁移

率远低于理论值一直困扰着学术界。结合实验与

理论计算，阐明了 MoS2 中的电子输运机制。利

用高分辨透射电子显微镜对 MoS2 表面原子结构

进行精细表征，结果显示大量 S 空位缺陷存在于

材料中。S 空位对 MoS2 能带结构有非常显著的

影响。基于密度泛函理论的第一性原理计算表明

本征 S 空位缺陷在能隙中引入缺陷态，在低载流

子浓度下，电子由 Bloch 波变为局域在缺陷态附

近的局域化电子，电子输运只能通过局域态之间

的跃迁实现，该输运机制限制了二硫化钼的本征

迁移率，这一结果得到了变温输运测试的证实。

随着载流子浓度的提高（通过场效应在 MoS2 体

系中引入高载流子浓度），电子传输将由跃迁传输

转变为扩展态传输，这一模型也解释了在二硫化

钼体系中金属态、甚至超导态的发现。该研究对

MoS2 输运领域的一个关键问题进行了较为系统

地解释，揭示了 MoS2 中的缺陷对电子输运和器

件应用的影响，并且为进一步提高二硫化钼器件

性能给出了理论指导。

由于 Skyrmion 晶体的特殊磁结构，通常认

为它需要 Dzyaloshinskii-Moriya（DM）相互作

用诱导才能产生，而大多数材料中的 DM 相互作

用都比较弱，仅有很少的几种材料可以形成

Skyrmion 晶体。此外，实验上观测到的

Skyrmion 晶体只存在于很窄的温度和磁场区

域，到目前为止还没有室温下的报导。这些严重

地阻碍了对 Skyrmion 晶体的深入研究和应用

探索。从理论上提出了一种构建人工二维

Skyrmion 晶体的方法。该方法将具有垂直各向

异性的磁性薄膜和具有磁涡旋态的纳米盘阵列有

机地结合起来，通过特殊的磁场处理即能产生人

工二维 Skyrmion 晶体，并且进一步通过微磁学

模拟验证了该方法的可行性。研究表明，通过这

种方法构建的 Skyrmion 晶体不仅可以稳定在

较宽的温度和磁场区域，甚至包括室温和零磁场。

同时该方法还不需要材料具有内禀的 DM 相互作

用。该方法的提出对于未来 Skyrmion 晶体的深

入研究和实际应用提供了一种全新的途径，同时

也指出了 DM 相互作用并不是形成 Skyrmion

在纳米微加工技术方面：发展了一种新型的

双转移紫外光固化纳米压印技术，利用这种技术，

不仅在平面衬底上，而且在高曲率衬底表面成功

实现了残余层厚度均匀的高分辨率紫外光固化纳

米压印。在石墨烯表面生长 Pt 微结构阵列，该复

合结构具有优良的摩擦性能。

4．软物质结构与功能

通过结合模拟和理论成功实现了活力物质的

液晶态结构：与对应的平衡态液晶体系缺陷的束

缚态和热扩散不同，研究发现这类非平衡活力体

系中拓扑结构的奇异性质。进一步，定量地刻划

了体系中拓扑缺陷的异常扩散动力学以及缺陷间

新颖的相互作用过程。由于拓扑缺陷对激发分离

后不能通过局域调整来去除系统中的旋错荷，预

Annual Report 2013

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测这一异常特性会导致拓扑结构动力学在宏观大

尺度向列相演化中起到重要作用。通过跟踪大量

缺陷的集体运动特性，并与系统大时空尺度的涨

落和弛豫行为对比，定量地证实了这一猜想。通

过计算机模拟，对基因载体与细胞之间相互作用

机理进行了详细研究。研究发现当纳米载体表面

带电高分子配体比较短时，所载运的 DNA 分子在

内吞过程中会显著地阻止基因载体的进一步吸

收；而当带电高分子配体长度增加时，DNA 分子

则会有效地促进细胞的内吞作用。此外，研究还

发现基因（DNA）自身的性质也能够对细胞内吞

基因载体产生重要影响，而这在此前的基因转染

实验中往往被忽略。通过比较正常细胞与癌细胞

对基因载体的吸收效率，还发现癌细胞所处的低

pH 环境及其细胞膜的负电性均有利细胞内吞基

因载体，这意味着对基因载体的高效吸收有可能

是癌细胞的一个固有属性。研究了一种新型的 pH

响应性药物输运系统。在这个新系统中，除了包

含需要被转运的纳米粒子（药物分子或团簇）之

外，还存在着一些 pH 敏感性高分子。由于这种

pH 敏感性高分子材料在不同 pH 环境中能够自发

地在纳米粒子表面吸附和解吸付，所以它们能够

有效地调节纳米粒子与细胞之间的特异性相互作

用，从而可以很好的控制纳米粒子在不同 pH 环境

中被细胞吸收的效率。发现纳米粒子的吸收效率

对外界 pH 值存在着三种不同的响应：在 pH 比较

高和比较低时，纳米粒子能够被细胞所吸收，而

在 pH 处于中间值的时候，纳米粒子内吞则被阻

止。

蛋白质或多肽的自组装聚集是生命科学研究

领域中的热点前沿问题，对其进行深入研究不仅

可以了解蛋白质淀粉装纤维相关的重大疾病的致

病机理，还可以探究蛋白质载药体系等新型的生

物材料。利用紫外光照的办法，通过对蛋白质分

子和抗癌药物共组装的物理机制研究，一步合成

蛋白质载药纳米粒子，并通过对纳米粒子表面进

行癌细胞表面因子特异性抗体的修饰，成功实现

了载药纳米粒子对肿瘤的靶向输运。利用化学交

联的办法合成高强度的水凝胶，可以作为高性能

的生物材料。通过前期对荧光蛋白质折叠的物理

机制研究，利用基因工程的办法对绿源荧光蛋白

序列进行修饰，制备出对氯离子高度敏感的生物

分子传感器。利用双苯丙氨酸侧链苯环的共轭特

性，制备出有着对高转化效率的管状纤维体。同

时利用分子动力学的方法系统研究了水分子大幅

度跳跃转动的关联性质以及转动和平动的关联。

此外还对细胞内蛋白质相互作用网络，含硫键蛋

白质折叠等方面做了大量工作。

5. 微结构材料设计与理论计算

运用分子动力学数值模拟方法研究了受限空

间下贵金属（金、银、铜）管状纳米结构材料的

生长特性。数值模拟结果表明，碳纳米管约束条

件可以有效地克服“自净化”效应，在任何合金

成分下可以生长出三种不同的混合贵金属（金-

银、金-铜和银-铜）纳米管。当约束碳管的直径

足够大时，还可以生长出一种新型的管状纳米合

金链，即在 Au-Ag 合金管中心会出现一根几乎是

纯金的链，而在 Au-Cu 和和 Ag-Cu 合金管中心

则会出现一根纯铜的链。

运用第一性原理数值计算方法研究了锯齿形

边界带状硅烯的边界重构行为，发现了一种新的

（2x1）边界重构结构（edge-4）：一对三角形-

五边形对拓扑缺陷，其总能量低于已经发现的两

种边界重构结构（edge-2 和 edge-3），因而更

加稳定。更重要的是，在外加应变下，前两种边

National Lab of Solid State Microstructures

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界重构结构（edge-2 和 edge-3）与新发现的基

态边界重构结构（edge-4）可以互相转化。

通过理论计算预测了具有面心立方结构并且

极易形成纳米颗粒的半导体材料 --氧化铟

（In2O3，带隙宽度 2.8eV）的{100}晶面在可

见光激发下相比较其它如（110），（111）晶面及

其体内更能够聚集光生空穴，进而能够在电场驱

动下高效地分解水产生氧气。在实验上首次大面

积地成功生长出截角的氧化铟微米级八面体颗

粒，光电化学的测试结果很好地符合了理论预测，

意味着可通过对半导体微纳结构材料的表面切割

来获得增强的光催化性能。

研究了 BaKFeAs 等超导体中的玻色模式，发

现其能量与超导临界温度之间有线性依赖关系，

从而表明该模式与超导机理紧密关联。通过与中

子散射之结果比较，确认该玻色模式为一种共振

自旋涨落模式；用泛函重正化群方法研究了

KFe2Se2 等一类超导体的超导机理和配对对称

性，发现尽管该类超导体只有电子型费米面，但

费米能级以下的赝空穴带可以作为 Cooper 对散

射的中转站而导致电子口袋上的吸引型 Cooper

对散射而实现配对和超导，并提出了进一步实验

验证有关结论的实验方案；用泛函重正化群方法

研究了新近发现的BiS2超导体的超导机理和配对

对称性，发现该超导体的能隙函数中以三态配对

分量为主导，而自旋轨道耦合导致一些次要的单

态配对分量，同时使整个能隙函数在时间反演下

不变。在自旋-晶格联合旋转操作下能隙函数具有

d-波对称性。在低载流子浓度下能隙没有节点，

此时超导态是一类弱拓扑超导体；用泛函重正化

群方法研究了Kagome格子在 van Hove填充情

况下的相图，发现了一系列有趣的电子态，如铁

磁、元胞内 120 度反铁磁、David-star 型电荷

型/自旋型共振价键固体、d-波 Permoranchuk

相、手征 d-波超导态等。

FF 生物分子是 β-淀粉样多肽的核心识别基

序，其通过简单的自主装可以形成稳定的 FF 纳米

结构。在前期研究的基础上，立足于 FF 纳米管的

结构，首次在分子层面上分析了 FF 纳米管中自发

极化的起源，并预测了铁电性的存在。以前的研

究发现 FF 纳米管需要很强的矫顽电场才能实现

自发极化的反转，而过大的外加电场会破坏纳米

管的结构。通过荧光光谱的分析发现，在紫外光

的辐照下，FF 纳米管中产生的光生电子－空穴对

会形成内建电场，有效抵消其铁电自发极化场。

根据这一结果，在光照的条件下测试了 FF 纳米管

的铁电性，发现电滞回线出现了明显的饱和趋势，

并首次通过实验的方法证实了 FF 纳米管沿轴向

的铁电性。

首次成功制备了外延的 DyMnO3薄膜，并令

人信服地将DyMnO3单晶块体多铁性性质完整地

复制到外延薄膜中。通过在 WMnO4 体系的 Mn

位替代掺杂 4d 的 Ru 离子，不但使得原有很窄的

铁电区域被大大拓宽，低温非铁电相被完全抑制，

而且铁电极化也被显著提高 20 倍以上。通过单晶

生长与多晶制备获取了高质量的具有非共线自旋

结构的自旋冰体系 Ho2Ti2O7和 Dy2Ti2O7样品，

揭示了这两个体系中存在本征的磁致铁电性，还

合 成 了 具 有 新 颖 铁 性 的 有 机 铁 电 体

(Hg6P4)(CuCl3)2。

6．基于微结构的高新技术与应用

在基于 REC 技术的激光器阵列、模拟直调激

光器、有源无源集成和光子集成芯片混合封装取

得阶段性成果。利用自主创新的重构-等效啁啾技

术（REC）成功制造了高单模成品率波长精准的

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激 光 器 阵 列 。 90% 以 上 的 波 长 偏 差 只 有

±0.3nm。随机挑选了若干具有 60 个波长（目前

据文献报道制作波长数最多的激光器阵列）的激

光器阵列，只有 7 个激光器出现双模现象，单模

成品率是 88.3%。研制了基于 REC 技术的双 λ8

相移单管模拟直调激光器。该激光器 SMSR 为

40dB，阈值电流小于 10mA，相对强度噪声

<-135 dB/Hz，测得的动态范围为 83dB/

Hz2/3，已经接近或达到模拟链路的传输要求。

有源无源集成是实现单片集成必须克服的技

术难题，针对 InP基材料的特点，提出了利用QWI

技术（量子阱混搭）和 Offset 技术实现有源无源

集成的技术方案，并取得一定的技术突破。利用

MLA+PLC 混合封装结构，完成了 4x10GHz、

8x10GHz 激光器阵列的封装及符合 ITU 标准的

可 调 谐 半 导 体 激 光 器 模 块 。 该 模 块 将 在

WDM-PON、分布式基站、未来通信网络建设中

发挥及其重要的作用。

探索ALD方法在复合无机－有机杂化薄膜的

制备及其表征，原位研究了其生长特性与机制。

将ALD技术应用到新型纳米晶存储器和阻变存储

器的制备中，深入研究了金属纳米晶存储器的沉

积工艺与存储特性，发展与产业化进程兼容的

ALD 关键工艺。开展了 ALD 在孔道型衬底里面沉

积金属薄膜的研究。

在锂离子二次电池正、负极和隔膜材料方面，

研究了 LiFePO4、NiCoMn 三元材料、Si 和可调

孔径隔膜材料，对其进行结构设计，并系统研究

其结构和性能的关系。在太阳能电池研究方面，

数值模拟和实验研究了尖劈微结构的陷光效应及

机理和机制，提出了氧化物球形级联结构的制备

方法，获得了电池性能的提高。

在人工光合成将二氧化碳转化为碳氢燃料研

究方面和高效光电化学太阳能分解水制氢方面取

得新的进展。迄今为止，利用太阳能主要依靠太

阳能电池将太阳能转化成电能来完成。但电能不

仅存储困难，不方便使用，另外太阳能电池本身

制造成本高居不下。太阳能分解水制氢不仅成本

低，而且由于氢能能量密度高、清洁环保、使用

方便，被认为是一种理想的能源载体。发展高效

光电极材料是这种技术能否实现大规模应用的关

键。针对 Ta3N5 光电极的特殊性质，巧妙地设计

出一种透明胶带剥离表面复合中心的方法，可以

有效减少表面光生电子空穴复合，大幅度提高其

太阳能转换效率，使得经过表面剥离后的 Ta3N5

光电极具有同类材料中最高的太阳能分解水制氢

效率。这种简单方法为消除其他半导体材料表面

复合中心提供了重要参考。

7. 学术交流及实验室建设

学术交流与合作

首届凝聚态物理前沿FUN研讨会——人工微

结构与光电物理性能调控研讨会于 2 月 25 日－

27 日在宁举行。来自南京大学（N）、复旦大学（F）、

中国科学技术大学(U)的相关课题组老师 40 余人

参加了此次会议。凝聚态物理前沿研讨会的口号

是 Physics is FUN (FUN 同时又是复旦科大和南

大的缩写)。它由中国科学技术大学张振宇教授、

复旦大学沈健教授和南京大学王牧教授等发起，

旨在促进各高校相关课题组的学术交流，进而寻

求长期有效实质性合作。本次会议邀请了复旦大

学的沈健教授、张远波教授、周磊教授、张童副

教授、中国科学技术大学的陆亚林教授、杨金龙

教授、曾长淦教授、张振宇教授、南京大学的万

贤纲教授、吴兴龙教授、李涛副教授、梁彬副教

授、卢明辉副教授、宋凤麒副教授作报告。该论

National Lab of Solid State Microstructures

16

坛准备办成系列会议，定期举行，每次设立不同

专题。

2013 年 6 月 21-23 日，实验室举行了 2nd

Workshop on Condensed Matter Physics

between NJU and UCD。王牧教授、李建新教

授、刘俊明教授、宋凤麒教授、闻海虎教授、丁

海峰教授、王欣然教授、王强华教授、彭茹雯教

授作为实验室代表参与了此次学术交流；

Winston Ko 教授、Alex Navrotsky 教授、

Shirley Chiang 教授、Ching Yao Fong 教授、

Kai Liu 教授、Sergey Savrasov 教授、Dong Yu

教授、Xiangdong Zhu 教授一行 8 人作为加州

大学戴维斯分校方面的代表参与了此次学术交

流。双方就学术合作、仪器共享、研究生培养等

方面进行了细致、深入的探讨。

2013 年，实验室接待国（境）内外专家来访

近 60 人次，还成功的承办了包括第 14 届超导磁

通物质国际研讨会、第十二届国际材联亚洲材料

大会、2013 国际压电原子力显微技术及纳米尺度

极性材料和力学高级研讨会在内的多个重要的学

术会议，取得了良好的效果，扩大了实验室在国

内外的学术影响。

2013 年，实验室有 170 人次出席包括 APS

March Meeting、中国物理学会在内的多个学术

会议，做了 142 次会议报告，其中邀请报告 56

次、口头报告 86 次、墙报 18 次，提交 20 余篇

会议论文。

实验技术队伍建设与人才培养

实验室引进高学历的实验技术人才，建立一

支相对稳定的高水平实验队伍，保障实验室新型、

大型精密设备的完善运行。通过提供学习、进修

机会，有计划派往国内外高校和著名实验室参观、

学习、交流，拓宽实验技术人员的视野，培养实

验技术人员的业务能力，提高实验技术人员的综

合素质。

研究生是固体微结构物理实验室科学研究的

重要力量。为激发研究生的科研热情，鼓励做深

入细致的原创性工作，实验室拨出专门经费设立

了研究生成果奖/优秀毕业研究生奖，用于表彰在

过去年度的工作中取得优异成绩的学生。2013 年

4 月，经研究生优秀成果奖/优秀毕业研究生奖评

审委员会严格审议，授予陈伟、顾铭强、贾兰、

李会超、李林 5 位同学 2012 年度研究生优秀成

果奖，授予陈昌东、王万胜、张俊廷 3 位同学优

秀毕业研究生奖。

实验室仪器设备建设

2013 年，实验室获得仪器设备专项经费

1142 万元。实验室购置了如超高真空多功能磁控

溅射系统、飞安级半自动集成电路测试平台、稳

态/瞬态荧光光谱仪、微波矢量网络分析仪等精密

实验仪器，建设了超高真空强磁环境团簇束流在

线检测与修饰室。大部分仪器设备已安装调试完

毕，性能参数良好，可正常稳定运行。

专项经费使用与管理

2013 年，实验室的专项运行经费 997.5 万，

主要用于自主研究课题、开放课题、访问学者与

实验室日常运行等方面。

自主研究课题的设置原则是以国家需求为根

本，以国际前沿为主导，以现有基础为背景，大

力促进和发展学科交叉。为遴选自主研究课题，

实验室成立工作委员会，对自主研究课题进行评

议并提供咨询意见，并征求部分学术委员会成员

的意见，最终由重点实验室主任办公会议决定，

力争做到课题决策过程公开透明。

2013 年，实验室批准目标导向性研究课题、

Annual Report 2013

17

自主探索性研究课题、青年基金课题 3 类课题 21

个项目。