morphisto gmbh safety data sheet · 2021. 1. 18. · citronensäure >0,5 - 3,0 mol/l 1.1....

according to Regulation (EC) No 1907/2006

Safety Data SheetMORPHISTO GmbH

Citronensäure >0,5 - 3,0 Mol/l

Revision date: 13.02.2020 Product code: 15207_collect of 9

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier

This MSDS covers the following products in all container sizes:

- REF 15207.xxxxx – Citronensäure 1,0 mol/l

- REF 17094.xxxxx – Citronensäure 3,0 mol/l

- REF 16827.xxxxx – Citronensäure 1 %

Further trade names

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

Use as laboratory reagent. The product is intended for research, analysis and scientific education.

Not known

Uses advised against

1.3. Details of the supplier of the safety data sheet

MORPHISTO GmbHCompany name:

Street: Weismüllerstr. 45

Place: D-60314 Frankfurt am Main

Telephone: Telefax:+49 (0) 69 / 400 3019-60 +49 (0) 69 / 400 3019-64

[email protected]:

http://www.morphisto.deInternet:

Poison Information Center Mainz, Germany, Tel: +49(0)6131/192401.4. Emergency telephone

number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No. 1272/2008

Hazard categories:

Serious eye damage/eye irritation: Eye Irrit. 2

Hazard Statements:

Causes serious eye irritation.

2.2. Label elements

Regulation (EC) No. 1272/2008

Signal word: Warning

Pictograms:

H319 Causes serious eye irritation.

Hazard statements

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

P337+P313 If eye irritation persists: Get medical advice/attention.

Precautionary statements

The mixture need not be classified as corrosive in spite of the extreme pH.

2.3. Other hazards

Print date: 17.02.2020GB - ENRevision No: 1,1

mailto:[email protected]

http://http://www.morphisto.de





SECTION 3: Composition/information on ingredients

3.2. Mixtures

in aqueous solutionChemical characterization

Hazardous components

QuantityChemical nameCAS No

EC No Index No REACH No

GHS Classification

35 - < 40 %77-92-9 citric acid

201-069-1

Eye Irrit. 2; H319

Full text of H and EUH statements: see section 16.

Further Information

Product does not contain listed SVHC substances > 0,1 % according to Regulation (EC) No. 1907/2006 Article

59 (REACH)

SECTION 4: First aid measures

4.1. Description of first aid measures

In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet

if possible).

General information

Remove casualty to fresh air and keep warm and at rest. In case of respiratory tract irritation, consult a

physician.

After inhalation

Wash with plenty of water/.?. In case of skin irritation, seek medical treatment.

After contact with skin

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue

rinsing. If eye irritation persists: Get medical advice/attention.

After contact with eyes

Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person or a person with

cramps. In all cases of doubt, or when symptoms persist, seek medical advice.

After ingestion

4.2. Most important symptoms and effects, both acute and delayed

refer to section 2 and 11.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Carbon dioxide (CO2). Foam. Dry extinguishing powder. Water spray.

Suitable extinguishing media

High power water jet.

Unsuitable extinguishing media

5.2. Special hazards arising from the substance or mixture

Can be released in case of fire: Carbon dioxide (CO2). Carbon monoxide






In case of fire: Wear self-contained breathing apparatus.

5.3. Advice for firefighters

Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

Additional information

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Avoid contact with skin, eyes and clothes. @1501.B015718

Wear personal protection equipment. (refer to chapter 8)

Do not allow to enter into surface water or drains.6.2. Environmental precautions

Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).

Collect in closed containers for disposal.

Clean contaminated objects and areas thoroughly observing environmental regulations.

6.3. Methods and material for containment and cleaning up

See section 8.

refer to chapter 13.

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Wear suitable protective clothing. (refer to chapter 8)

Advice on safe handling

No special measures are necessary.

Advice on protection against fire and explosion

Avoid contact with skin, eyes and clothes.

General protection and hygiene measures: refer to chapter 8

Further information on handling

7.2. Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a cool, well-ventilated place.

Requirements for storage rooms and vessels

Do not store together with: Explosives. Oxidizing solids. Oxidizing liquids. Radioactive substances. Infectious

substances.

Hints on joint storage

Protect against: UV-radiation/sunlight. heat. frost.

Further information on storage conditions

7.3. Specific end use(s)

See section 1.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

To date, no national critical limit values exist.

Additional advice on limit values

8.2. Exposure controls






Provide adequate ventilation. Use extractor hood (laboratory).

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice.

Always close containers tightly after the removal of product. Do not eat, drink, smoke or sneeze at the

workplace. Wash hands before breaks and after work. Take off contaminated clothing.

Protective and hygiene measures

Tightly sealed safety glasses. DIN EN 166

Eye/face protection

In case of prolonged or frequently repeated skin contact: Wear suitable gloves. EN ISO 374

Suitable material:

CR (polychloroprenes, Chloroprene rubber). (0,5 mm)

NBR (Nitrile rubber). (0,35 mm)

Butyl rubber. (0,5 mm)

FKM (fluororubber). (0,4 mm)

penetration time (maximum wearing period): >=480 min

Before using check leak tightness / impermeability. In the case of wanting to use the gloves again, clean them

before taking off and air them well.

For special purposes, it is recommended to check the resistance to chemicals of the protective gloves

mentioned above together with the supplier of these gloves.

Hand protection

Protective clothing.

Minimum standard for preventive measures while handling with working materials are specified in the TRGS 500

(D).

Skin protection

With correct and proper use, and under normal conditions, breathing protection is not required.

Respiratory protection necessary at:

generation/formation of aerosols

Generation/formation of mist

Suitable respiratory protective equipment:

Combination filtering device (EN 14387) Type : A / P2/P3

The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates)

that may arise when handling the product. If the concentration is exceeded, self-contained breathing apparatus

must be used.

Respiratory protection

Do not allow to enter into surface water or drains.

Environmental exposure controls

colourless

liquidPhysical state:

Colour:

9.1. Information on basic physical and chemical properties

SECTION 9: Physical and chemical properties

characteristicOdour:

Test method

pH-Value: 1-2 N/A

Changes in the physical state






~100 °C N/AInitial boiling point and boiling range:

>60 °C N/AFlash point:

none

Explosive properties

not determinedIgnition temperature:

none

Oxidizing properties

Density: not determined

Water solubility: completely miscible

Viscosity / dynamic: not determined

9.2. Other information

No information available.

SECTION 10: Stability and reactivity

10.1. Reactivity


10.2. Chemical stability

Stable under normal storage and handling conditions.

10.3. Possibility of hazardous reactions

Reacts with : Alkalis (alkalis).


10.4. Conditions to avoid

Oxidizing agents, strong. Alkalis (alkalis).

10.5. Incompatible materials

Can be released in case of fire: Carbon dioxide (CO2). Carbon monoxide

10.6. Hazardous decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicocinetics, metabolism and distribution


Acute toxicity

Based on available data, the classification criteria are not met.

Chemical nameCAS No

SourceSpeciesDoseExposure route Method

77-92-9 citric acid

Mouse.LD50 >5000

mg/kg

ECHA Dossieroral

RatLD50 >2000

mg/kg

ECHA Dossierdermal






Causes serious eye irritation.

Skin corrosion/irritation: Based on available data, the classification criteria are not met.

citric acid (CAS-No.: 77-92-9):

Irritant effect on the skin: Not an irritant. (Rabbit in aqueous solution, 50%)

literature infomation: ECHA Dossier

Irritation and corrosivity

Sensitising effects


Carcinogenic/mutagenic/toxic effects for reproduction


citric acid (CAS-No.: 77-92-9):

In-vivo mutagenicity: No experimental indications of mutagenicity in-vivo exist.

Literature information: ECHA Dossier

STOT-single exposure



STOT-repeated exposure

Aspiration hazard


SECTION 12: Ecological information

12.1. Toxicity

@1718.B017281

12.2. Persistence and degradability

@1718.B017281

12.3. Bioaccumulative potential

No indication of bioaccumulation potential.

@1718.B017281

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

The components in this formulation do not meet the criteria for classification as PBT or vPvB.

@1718.B017281

12.6. Other adverse effects

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal recommendations

Dispose of waste according to applicable legislation. Consult the local waste disposal expert about waste

disposal. Non-contaminated packages may be recycled.

Control report for waste code/ waste marking according to (EWC) European Waste Catalogue:

List of Wastes Code - residues/unused products

060106 WASTES FROM INORGANIC CHEMICAL PROCESSES; wastes from the manufacture, formulation,

supply and use (MFSU) of acids; other acids; hazardous waste

List of Wastes Code - used product

WASTES FROM INORGANIC CHEMICAL PROCESSES; wastes from the manufacture, formulation,

supply and use (MFSU) of acids; other acids; hazardous waste

060106

List of Wastes Code - contaminated packaging






WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE

CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal

packaging waste); packaging containing residues of or contaminated by hazardous substances;

hazardous waste

150110

Handle contaminated packages in the same way as the substance itself.

Contaminated packaging

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: Not restricted

Not restricted14.2. UN proper shipping name:

Not restricted14.3. Transport hazard class(es):

14.4. Packing group: Not restricted

Inland waterways transport (ADN)


14.2. UN proper shipping name: Not restricted

14.3. Transport hazard class(es): Not restricted


Marine transport (IMDG)



14.3. Transport hazard class(es): Not restricted


Air transport (ICAO-TI/IATA-DGR)



Not restricted14.3. Transport hazard class(es):

Not restricted14.4. Packing group:

14.5. Environmental hazards

noENVIRONMENTALLY HAZARDOUS:

14.6. Special precautions for user

Not restricted

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

Not restricted

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulatory information

Additional information

The preparation is dangerous in the sense of Directive 1999/45/EC.

This preparation is hazardous in the sense of regulation (EC) No 1272/2008 [GHS].

Not subject to regulation 96/82/EC.






REACH 1907/2006 Appendix XVII, No (mixture): 3

National regulatory information

Observe restrictions to employment for juvenils according to the 'juvenile

work protection guideline' (94/33/EC).

Employment restrictions:

1 - slightly water contaminatingWater contaminating class (D):

15.2. Chemical safety assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Changes

Rev. 1.00; 02.03.2015, Initial release

Abbreviations and acronyms

ADR: Accord européen sur le transport des marchandises dangereuses par Route

CAS Chemical Abstracts Service

DNEL: Derived No Effect Level

IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER

IMDG: International Maritime Code for Dangerous Goods

IATA: International Air Transport Association

IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)

ICAO: International Civil Aviation Organization

ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)

GHS: Globally Harmonized System of Classification and Labelling of Chemicals

GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)

LOAEL: Lowest observed adverse effect level

LOAEC: Lowest observed adverse effect concentration

LC50: Lethal concentration, 50 percent

LD50: Lethal dose, 50 percent

NOAEL: No observed adverse effect level

NOAEC: No observed adverse effect level

NTP: National Toxicology Program

N/A: not applicable

OSHA: Occupational Safety and Health Administration

PNEC: predicted no effect concentration

PBT: Persistent bioaccumulative toxic

RID: Règlement international concernant le transport des marchandises dangereuses par chemin de

fer (Regulations Concerning the International Transport of Dangerous Goods by Rail )

SARA: Superfund Amendments and Reauthorization Act

SVHC: substance of very high concern

TRGS Technische Regeln fuerGefahrstoffe

TSCA: Toxic Substances Control Act

VOC: Volatile Organic Compounds

VwVwS: Verwaltungsvorschrift wassergefaehrdender Stoffe

WGK: Wassergefaehrdungsklasse

H319 Causes serious eye irritation.

Relevant H and EUH statements (number and full text)

The above information describes exclusively the safety requirements of the product and is based on our

present-day knowledge. The information is intended to give you advice about the safe handling of the product

Further Information






named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be

transferred to other products. In the case of mixing the product with other products or in the case of processing,

the information on this safety data sheet is not necessarily valid for the new made-up material.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety

data sheet.)


morphisto gmbh safety data sheet · 2021. 1. 18. · citronensäure >0,5 - 3,0 mol/l 1.1....

Documents