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Grânulos de glicogênio Fibras de celulose

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Page 1: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Grânulos de glicogênio

Fibras de celulose

Page 2: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Monossacarídeos com 3 carbonos

Page 3: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Isomeria

Page 4: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Aldoses

Page 5: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 6: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

D-glucose em água: ciclização

Page 7: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 8: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 9: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Oxidação

Page 10: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Metilação

Page 11: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Monossacarídeos oligossacarídeos polissacarídeos

Page 12: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 13: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 14: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 15: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 16: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 17: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Ligações de hidrogênio em azul

Page 18: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Fibras de celulose

Page 19: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 20: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 21: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 22: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 23: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 24: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Amilose

Page 25: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 26: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Exemplos de dissacarídeos presentes em polissacarídeos

Page 27: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 28: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 29: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Page 30: Monossacarídeos com 3 carbonos - iq.usp.br · HO CH20H 1 3 o coo- OH H CH20H coo- OH H H OH o -03S0 H OH NHCOCH3 NHCOCH3 D-Glucuronate N-Acetyl-D-glucosamine Hyaluronate L-lduronate

Relenza (GSK) Tamiflu (Roche)

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