mitsunobu - status of kek studies of superconducting thin films by pulsed laser deposition
DESCRIPTION
http://www.surfacetreatments.it/thinfilms Status of KEK studies on MgB2 (Shinji Mitsunobu - 20') Speaker: Shinji Mitsunobu - KEK | Duration: 20 min. Abstract We have been engaged in fabrication of high-Tc or MgB thin films on metallic substrates. At the international workshop on thin films in Padova, we showed our basic idea to make an accelerating-mode cavity. In the last of this paper, we report a subsequent development, mainly a partial success in fabricating superconducting film on a quadrant cavity of an accelerator structure. In the beginning, we describe some results concerning fabrication of films on Niobium and Titanium surfaces. Studies of Nb and Nb3Sn thin films by PLD will be shown.TRANSCRIPT
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STATUS OF KEK STUDIES OF SUPERCONDUCTING THIN FILMS BY PULSED LASER DEPOSITION
S. Mitsunobu , S. Inagaki, H. Nakanishi, K. Saito, T. Takatomi, M. Wake, and M. Yoshida
High Energy Accelerator Research Organization (KEK), Tsukuba, Ibaraki, Japan
M. Fukutomi, National Institute for Material Science (NIMS) , Tsukuba, Ibaraki, Japan
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PLD Thin Film Superconductor at KEK
TE011 Mode Cavity
• Nb Thin Film on Nb, Sapphire
• Nb3Sn Thin Film on Nb
• MgB2 Thin Film on Nb, Ti, Cu
TM010 Mode Cavity
• MgB2 Thin Film on Nb, Cu and Cu Quadrant Cavity
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Conceptual Drawing of Pulse Laser Deposition
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Laser system of PLD
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Vacuum Chamber of PLD
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PLD Processing
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TE011 Mode Cavity
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Nb3Sn on Nb Nb on Nb Nb on Sapphire
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Nb film on Sapphire
Al2O3
NbNb2O5
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Nb thin film on sapphire have low Q value of less than 100.TE011 peak was not observed.
TE011
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Nb thin film on Nb substrata
Nb
Nb2O5
NbNb2O5
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Surface resistance of Nb thin film on Nb
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Nb3Sn thin film show no superconducting transition around 18K.
104
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MgB2
• We have been engaged in fabrication of high-Tc or MgB thin films on metallic substrates. At the international workshop on thin films in Padova, we showed our basic idea to make an accelerating-mode cavity. In the last of this paper, we report a subsequent development, mainly a partial success in fabricating superconducting film on a quadrant cavity of an accelerator structure. In the beginning, we describe some results concerning fabrication of films on Niobium and Titanium surfaces.
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PRECURSOR POST-ANNEALING METHOD
After assembling the cavity with the component parts, we deposit MgB on the inner surface by pulsed laser deposition (PLD) and heat up to temperatures around 600 oC.This procedure is called precursor post-annealing method.
This method consists of two steps.
(i) The target is a pellet with a mixture of MgB2 and Mgpowder with the stoichiometry ofMg:B=2:1. Excimer laser with λ=248 nm (KrF), 400 mJ,
and 5–10 Hz is irrradiatedon the target in 6x10-5 Torr Ar atmosphere at room temperature for 2 hr. The thickness of the
fabricated film is around 1 µm.
(ii) Typically, the precursors are heated in 1 atm Ar gas at 550–650 oC for 10 min. This process must be optimized so that magnesium evaporation should be well controlled to become MgB2 in the phase diagram .
In the preceding experiments, we deposited chromium on the copper surface, then yttria-stabilized-zirconia (YSZ), and MgB2 . However, we now know that if the copper oxide is completely removed from the surface, the chromium buffer layer can be omissible.
Two parts machined vertical to the axis are assembled to make a cavity. The inside surface
is to be covered with MgB2 films.
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RF Measurments of MgB2 ON Nb and Ti
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TM010 mode cavity
• Nb TM010 cavity made from Nb rod.• Each half cell inner surfaces were formed
MgB2 precursor films by PLD.• The half cell joint by bolts.• The equator part was formed by conical
target.• The cavity was heated by cylindrical heater
upto 620 digC.
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TM010 cavity
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LaserMover
Camera
MirrorVacuumChamber
Side View Top View
Mover
Mirror
Camera
Laser
PC(python+PyVISA+Tkinter)
GPIB
Target
Cone Shape MgB2 TargetDisc Shape MgB2 Target
Rotation
Horizontal Vertical
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Q-value of the cavity fabricated with process (pi).
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Microwave surface resistance of a quadrant.
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SUMMARY
We are making MgB2 films by a precursor post-annealingmethod on copper and Nb cavities of an accelerator structure.Some of them have already showed superconductingproperties.We concentrate our effort to find the better conditionto get films of better quality. We hope we can make a high
power test in future.MgB2 thin films on Nb disks show partial shielding effect
which is important for high field cavity.Nb and Nb3Sn PLD films study started.