methane production assessment by anaerobic codigestion from stem banana and cattle waste

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SERGIO ENRIQUE ARANGO OSORNO, Chemical Eng. Candidate to Master Science of Eng. (Environmental). [email protected] JORGE MONTOYA Biologist MSc GUSTAVO PEÑUELA Chemical. PhD Research Teams: INTEGRA & GDCON Tecnological of Antioquia - University of Antioquia Medellín - Colombia 2010 METHANE PRODUCTION ASSESSMENT BY ANAEROBIC CODIGESTION FROM STEM BANANA AND CATTLE WASTE IN ANTIOQUIA, COLOMBIA 15 th International Scientific Congress. CNIC 2010. CUBA 1th July.

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Page 1: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

SERGIO ENRIQUE ARANGO OSORNO,Chemical Eng. Candidate to Master Science of Eng. (Environmental).

[email protected]

JORGE MONTOYA Biologist MSc

GUSTAVO PEÑUELAChemical. PhD

Research Teams: INTEGRA & GDCONTecnological of Antioquia - University of Antioquia

Medellín - Colombia2010

METHANE PRODUCTION ASSESSMENT BY ANAEROBIC CODIGESTION FROM STEM BANANA AND

CATTLE WASTE IN ANTIOQUIA, COLOMBIA

15 th International Scientific Congress. CNIC 2010. CUBA 1th July.

Page 2: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

ANAEROBIC PROCESS

Page 3: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

RAW MATERIAL TYPE

SPECIES WEIGHT Kg manure/day L/kg.VS. %CH4

Pigs 50 4,5 - 6 340 - 550 65 - 70

Cattle 400 25 -40 90 - 310 65

Horses 450 12 - 16 200 - 300 65

Sheep 45 2,5 90 - 310 63

Poultry 1, 5 0,06 310 - 620 60

Vegetables Wholesale Central

13000 6 - 12 60

Codigestion Wholesale C. & Livestock C.

23000 212 - 268 60

Page 4: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

• Colombia generates 1`231.200 ton/y of waste stem banana and 14'700 000 ton/y in the world[1].

• CH4 production is equal to 738 600 ton/year.

• [1] SOTO, M. Banano cultivo y comercialización. San José de Costa Rica: Editorial LIL, 1995. 648p.

CH4 ESTIMATION

Page 5: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

STUDY AREASan Pedro de los MilagrosUrabá “Banana” Region

Page 6: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

• ¿How much will be affected kinetic and methane production by temperature in cattle anaerobic and banana stem vegetable wastes codigestion ?

OUR RESEARCH QUESTION

Page 7: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

GENERAL OBJECTIVE

To evaluate temperature effect in mesophilic and thermophilic conditions in methane production from cattle and banana stem vegetable waste co-digestion.

Page 8: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

SPECIFIC OBJECTIVES

• To assess the influence of livestock/vegetable wastes in methane production during co-digestion.

• To determine kinetics of methane production at different temperatures.

• To determine the COD, total solids, fixed solids, volatile solids and humidity, in livestock and vegetables waste co-digestion treatment.

Page 9: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

EXPERIMENTAL DESIGN

VARIABLE

TEMP.

VARIABLE: SUBSTRATE RATIO

X = vegetable m/ (vegetable m + animal m) (%)

X1 = 0 X 2 =1/3 X3=2/3

X4 =100 (33.3) (66.6)

T1 (25ºC) T1, X1 T1, X2 T1, X3 T1, X4 T2 (35ºC) T2, X1 T2, X2 T2, X3 T2, X4 T3 (45ºC) T3, X1 T3, X2 T3, X3 T3, X4

Total Treatms. 12

Total assays 36

Page 10: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

RESULTS

Page 11: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

METHODS

To take samples

Livestock C. O.M Animal

Wholesale CentralO.M vegetable

STEM BANANA

Mix and get Xi:X1, X2, X3, X4

Analyze each sample X1, X2, X3 y X4

Do 3 repetitionof each one to get Xij (12)

InicialAnalysis (SST y SSV),

COD, humIdity, pH, conduct.Upload biorxtors (12)

up to one third

Put stopper and valve, injection N2

Heat bath Mary a T cte

Analysis of CH4x chromatography

Analysis fin. (SST y SSV), DQO, humidity, pH, conduct.

Time = 40 days

Analysis microbiological

O.M. 40 day

Time= 4 days

TIME DURATION

PROCEDURE

LABORATORY ANALYSIS

Page 12: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

SAMPLE COLLECTIONS

Page 13: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

UPLOAD ANAEROBIC BIOREACTORS

Page 14: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

CH4 PRODUCTION KINETICS (25°C)

Page 15: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

CH4 PRODUCTION KINETICS (35°C)

Page 16: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

CH4 PRODUCTION KINETICS (45°C)

Page 17: Methane production assessment by anaerobic codigestion from stem banana and cattle waste
Page 18: Methane production assessment by anaerobic codigestion from stem banana and cattle waste
Page 19: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

CONCLUSION

• By increasing the temperature it can be obtained energy in methane structure from waste cattle and banana stem co-digestion, which are abundant in banana plantations and cattle areas in Colombia and other tropical countries, achieving a great reduction of greenhouse gases emissions.

Page 20: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

REFERENCES• ENERGIAS RENOVABLES 2004. ENERGIA BIOMASA. Dirección Nacional de

Promoción. Subsecretaría de Energía Eléctrica. Secretaría de Energía. República Argentina. 2006.

• Cartilla técnica biodigestores. 2003. Corantioquia.• ZAPATA, Alvaro. 2003. Utilización del biogás para generación de electricidad.

Fundación CIPAV. Colombia.• Políticas energéticas en Cuba: pasado y propuestas para el futuro. Programa de desarrollo

de las fuentes nacionales de energía. • http://usuarios.lycos.es/biodieseltr/hobbies4.html • Flotats, X.,Campos, E.. 1997. Aprovechamiento energéticos de residuos ganaderos.• HESSAMI, Mir - Akbar . Anaerobic digestion of household organic waste to produce

biogas. 1996.• FAN, Yao-Ting. 2005. Efficiente conversion of wheat straw into biohydrogen gas by cow

dung compost. • Lay JJ, Li YY, Noike T. 1998. A mathematical model for methane production from

landfill bioreactor. Journal of Environmental Engineering ASCE 1998;124:730–6.• Lixiviados en los vertederos de residuos sólidos: su incidencia en la extracción de biogás.

Tubkal Catalunya, S. L.. • Lin CY, Lay CH. Carbon/nitrogen-ratio effect on fermentative hydrogen • production by mixed microflora. International Journal of Hydrogen Energy 2004;29:41–

5.

Page 21: Methane production assessment by anaerobic codigestion from stem banana and cattle waste

THANKS

CONTACT

[email protected]