metamorphic fabric chapter 13a. solid-state crystal growth nucleation –crystallization of new...

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Metamorphic Fabric Metamorphic Fabric Chapter 13A

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Page 1: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Metamorphic FabricMetamorphic Fabric

Chapter 13A

Page 2: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Solid-state Crystal GrowthSolid-state Crystal Growth

• Nucleation

– Crystallization of new phases

• Crystal growth

– Modification of existing grain boundaries

Page 3: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

NucleationNucleation

• Homogeneous nucleation

• Heterogeneous nucleation

Page 4: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Homogeneous NucleationHomogeneous Nucleation

• Formation of new minerals within another mineral

• Free energy of new phase is greater than

its surface energy

• Rate of homogeneous nucleation is very

slow

Page 5: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Heterogeneous NucleationHeterogeneous Nucleation

• New minerals form along existing grain

boundaries or other discontinuities

• This mechanism is common

Page 6: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Crystal GrowthCrystal Growth

• Nucleation

• Independent growth

• Some contacts

• Granoblastic texture

Page 7: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Granoblastic TextureGranoblastic Texture

• Triple points

• Straight grain boundaries

• Interfacial angle controlled by surface energy of crystals in contact

Page 8: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Interfacial AnglesInterfacial Angles

• Dihedral angles ()

• Controlled by facial

energy

• Sine relationship

applies

Page 9: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Stress CategoriesStress Categories

• Tension

• Compression

• Shear

Page 10: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Hydrostatic PressureHydrostatic Pressure

• Defined as a uniform stress on a point regardless of direction

• Hydrostatic pressure increases with

depth in the earth

• Its value equals gz

Page 11: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries
Page 12: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Pressure SolutionPressure Solution

• Areas under high stress dissolve

• Material moves to regions of low stress

• Migration facilitated by an intergranular fluid

• Driving mechanism is a chemical potential

• Evidenced by growth into pressure shadows

Page 13: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries
Page 14: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Formation of PorphyroblastsFormation of Porphyroblasts

• Controlled by nucleation phenomena

• Megacrysts have a high surface energy

– If only a few nuclei may form

– They may grow to a very large size

Page 15: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

StressStress

• Stress is measured by F/A

• Units are Newtons/m2, MPa, bars, etc.

is the symbol for stress

= lim F/ A as A becomes infinitely

small

Page 16: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Directed StressDirected Stress

• Tectonism produces non-uniform stress

• This causes:

– Rock deformation

– Preferred orientation of mineral grains

– Development of large-scale structures

Page 17: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

StrainStrain

• Strain is the response to stress

is the symbol for strain

= lim l/lo as l approaches zero

l is the change in length in a line element

l0 is the original length of the same line

element

Page 18: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Strain MeasurementsStrain Measurements

• Units of strain are given as a fraction of the initial dimension

• Length strain

l = l/lo

• Volume strain

v = V/Vo

Page 19: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Timing of Porphyroblast Timing of Porphyroblast GrowthGrowth

Pre-tectonic, Syn-tectonic, Post-tectonic

Page 20: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Pre-tectonic Textures

Page 21: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Post-tectonic Textures

Page 22: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Types of Rock BehaviorTypes of Rock Behavior

• Elastic (like a spring)

– All deformation recoverable

– Linear deformation with applied stress

• Viscous (honey)

– No deformation recoverable

– No threshold for deformation

Page 23: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Types of Rock BehaviorTypes of Rock Behavior• Plastic (clay)

– Some deformation recoverable

– Yield strength must be overcome

• Brittle (halite)

– Yields by fracturing

– Generally elastic behavior prior to

rupture

Page 24: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

RheologyRheology

• The study of the flow of materials

• Strength describes the condition of materials

when they fail

• Soft materials begin to yield at their yield

strength

• Brittle materials will rupture at their

fracture strength

Page 25: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Linear Rheological ModelsLinear Rheological Models

• Hookean model elastic

• Newtonian model viscous

• Saint Venant model plastic

Page 26: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Elastic ModelElastic Model

Page 27: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Viscous ModelViscous Model

Page 28: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Sliding Block ModelSliding Block Model

Page 29: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Complex Rheological ModelsComplex Rheological Models

• Bingham model

• Has both a yield strength (kb)and

a viscosity (b)

• Common behavior of natural materials

Page 30: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Plastic ModelPlastic Model

Page 31: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Metamorphic TectonitesMetamorphic Tectonites

• Undulatory extinction

– Wavy extinction in quartz

– Bent twin planes in crystals

• Deformation bands

• Deformation lamellae

Page 32: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Low Temperatures Low Temperatures & High Strain Rates& High Strain Rates

• Undulatory extinction

• Kink bands

• Deformation lamellae

Page 33: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

High TemperaturesHigh Temperatures& Slow Strain Rates& Slow Strain Rates

• Recovery and recrystallization occur

• Sutured grain boundaries

• Small new grains form

Page 34: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Diffusive FlowDiffusive Flow

• Thermally activated

• Stress induced

• Diffusive recrystallization

• Sometimes called pressure solution

Page 35: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Role of Fluids in DeformationRole of Fluids in Deformation

• Hydraulic weakening of non-hydrous

silicates

• Prograde dehydration reduces ductility

• High pore PH20 may cause rock to be

brittle

Page 36: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Anisotropic FabricAnisotropic Fabric

• Results from syntectonic flow under stress

• Causes include:– Applied nonhydrostatic stress– Magnitude of strain– Strain rate– T & P

Page 37: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Fabric GeometryFabric Geometry

• Very complicated

• Non-homogeneous rock

bodies

• Linked chain of events

• Unambiguous answers

Page 38: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Grain OrientationGrain Orientation

• Foliation commonly parallel to axial

plane of folds

– Noted by orientation of platy minerals

• Lineation commonly parallels hinge line

– Given by alignment of elongate minerals

Page 39: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Orientation MechanismOrientation Mechanism

• Not easy to determine

• Nucleation and growth?

• Rotation of grains?

• Pressure solution?

Page 40: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

Segregation LayeringSegregation Layering

• Alternating bands of different minerals

– Relict beds?

– Mechanical transportation processes?

• Easier to determine in lower grade rocks

• Uncertain origin in higher grade rocks

Page 41: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

a. type of cleavage?a. type of cleavage?b. how many S?b. how many S?

Page 42: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

c. texture?c. texture?

Page 43: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

d. rock name?d. rock name?

Page 44: Metamorphic Fabric Chapter 13A. Solid-state Crystal Growth Nucleation –Crystallization of new phases Crystal growth –Modification of existing grain boundaries

e. names? (1=L, 2=R)e. names? (1=L, 2=R)