memorandum from terri white, usepa to jon … · project: 13-0162, aberdeen groundwater - reported...
TRANSCRIPT
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division:
980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
4SESD-ASB
MEMORANDUM
February 22,2013
SUBJECT: FINAL Analytical Report
Project: 13-0162, Aberdeen Groundwater
Superfund Remedial
FROM: Terri White
ICS Chemist
THRU: Mike Wasko, Chief
ASB Inorganic Chemistry Section
T O : Jon Bomholm
Attached are the final results for the analytical groups listed below. These analyses were perfonned in accordance with the Analytical Support Branch's (ASB) Laboratory Operations and Quality Assurance Manual (ASB LOQAM) found at www.epa.gov/region4/sesd/asbsop. Any unique project data quality objectives specified in writing by the data requestor have also been incorporated into the data unless otherwise noted in the Report Narrative. Chemistry data have been verified based on the ASB LOQ/\M specifications and have been qualified by this laboratory if the applicable quality control criteria were not met. Verification is defined in Section 5.2 of the ASB LOQAM. For a listing of specific data qualifiers and explanations, please refer to the Data Qualifier Definitions included in this report. The reported results are accurate within the limits of the method(s) and are representative only of the samples as received by the laboratory.
Analyses Included in ihis report: Method Used: Accreditations:
Total Metals (TMTL)
Tolal Metals Tolal Metals
EPA 200.8 (Water) EPA 6010 (Water)
ISO ISO
Page 1 of 18 E130310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
Sample Disposal Policy
Because of the laboratory's limited space for long term sample storage, our policy is to dispose of samples on a periodic schedule. Please note that within 60 days of this memo, the original samples and all sample extracts and/or sample digestates will be disposed of in accordance with applicable regulations. The 60-day sample disposal policy does not apply to criminal samples which are held until the laboratory is notified by the criminal investigators that case development and litigation are complete.
These samples may be held in the laboratory's custody for a longer period of time if you have a special project need. If you wish for the laboratory to hold samples beyond the 60-day period, please contact our Sample Control Coordinator, Debbie Colquitt, by e-mail at Colquitt.Debbie(a)epa.gov, and provide a reason for holding samples beyond 60 days
cc: Nardina Turner
Page 2 of 18 EI30310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
SAMPLES INCLUDED IN THIS REPORT
Project: 13-0162, Aberdeen Groundwater
Sample ID
ACGMW26
ACGM\V27
ACGMW29
ACGMW929
GEIMW29D
CE1MW29L
Laboratory ID
El 30310-02
El 30310-03
El 30310-04
El 30310-05
El 30310-06
El 30310-07
Matrix
Groundwater
Ground waler
Groundwater
Groundwater
Groundwater
Groundwater
Date Collected Date Received
1/17/13 16:15
1/17/13 17:55
1/16/13 16:40
1/16/13 16:40
1/17/13 11:30
1/17/13 11:20
1/18/13 11:32
1/18/13 11:32
1/18/13 11:32
1/18/13 11:32
1/18/13 11:32
1/18/13 11:32
Page 3 of 18 E130310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
DATA Q U A L I F I E R D E F I N I T I O N S
U The analyte was not detected at or above the reporting limit.
J The identification of Ihe analyte is acceptable; the reported value is an estimate.
OL-2 Laboratory Control Spike Recovery greater than method control limits
QM-1 Matrix Spike Recovery less than method control limits
A C R O N Y M S A N D A B B R E V I A T I O N S
C A S Chemical Abstracts Service
Note; Anaiytes with no known CAS identitlers have been assigned codes beginning with "E". the EPA ID as assigned by the EPA Substance Registry System (ww\v.epa.gov/srs), or beginning with "R4-", a unique identifier assigned by the EPA Region 4 laboratory.
ISO The tesL if analyzed after June 26. 2012, is accredited under the EPA Region 4 ASB's ISO/IEC 17025 accreditation
issued by /VNSI-ASQ National Accreditation Board/ACLASS. Refer to certificate and scope of accreditation AT-1691.
M D L Method Detection Limit - The minimum concentration of a substance (an analyte) that can be measured and reported with a 99% confidence that the analyte concentration is greater than zero.
M R L Minimum Reporting Limit - Analyte concentration that corresponds to the lowest demonstrated level of acceptable quantitation. The MRL is sample-specific and accounts for preparation weights and volumes, dilutions, and moisture content of soil/sediments.
TIC Tentatively Identified Compound - An analyte identified based on a match wilh the instrument software's mass spectral library. A calibration standard has not been analyzed to confinn the compound's identification or the estimated concentration reported.
Page 4 of 18 E1303I0TMTLFINAL02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
P r o j e c t : 13-0162, A b e r d e e n G r o u n d w a t e r
Total Metals
Sample ID: ACGMW26
Station ID: ACGMW26
L a b ID : E l 3 0 3 1 0 - 0 2
Matrix: Groundwater
Date Collected: 1/17/13 16:15
< 4.V'J:'^-:-;„»-;!/.!; • - ^ ^ K ^ - ^ : - - . m. : '•v:.W4A-/f:i ' " ^ A i ' :
-.-•'A.'A%.--,'}.'ie. «i-.Wi/r.v> Qtwl i f ie rs ' . f 4 i % . A - : : U i i i t s . ^ ^ h £ < M R L : - . . •Pivp'arcdii.Analy:ed.".Meihfld'j.- ' l - ' : • f - ' - . -XJC^y" , j ^ ' ^ - ' - ^ - ° ^ S ; . ^ » : . - ^ ^ ^ ^ g ^ > Q " T ^ ^ : . : - K i ^ m A t ' - > - : i - f i r % f - i i ^ - i ! A - - - ^ A . . : s ' i ^ . - A ' ' - - : : A r •
. : « 'm-^^u : !,»-
-'Alumihu'ni^S^
Antimony
'"Arsenic
Barium "-?=- X" ' —
'Beryllium ...U3Si.<;i.si
Cadmium
-:7->".raTYyfpyrp;.- .-*'.'.'..' ^ 'K- ' '-*t
'^•"A-A'T^,- . ' - ' ' i ^ ^v .
-=:8W«^rr- • -- . - f . . . , ; - . -
ug/L 1,0 P P P P P P EPA 200 8
--r:r«-"37''rEg'
Ug/L '
13 3fi
" L W B " ' i.''36.-:
1/24/13 Ll 13
:.C^^3;0-U.
: ' ' ^ ^ • : 1-0
ug/L 5.0
'PWZ "" iM3l ."^^Po^".'^^ilfe"
2/13/13 • 111.32
1/29/13 ;U2S
EPA 200.8
EPAOOIO
0.50 Ll ug/L 0.50 1/24/13
13 36 :/13/l3 1832 EPA 200 8
•"-x:aiAP^AA-...A'PPP.::rr.. -••• . - ^ S S l:^;,?»^i^oo•^••;:^• ¥^?vi- : ' .? . - :^S7^' '$^^":250' ** EPA6010:. -.V -i-1/24/l3^y.' "•'M-Vtr^
i^: -=•:• l Magnfesiuffi AApAii^' c : •^:^ |^ ' :* ' '~K!i; 4 j 7()0 'rf \ f i f a « s f j--vK,:, ;iiigA^:j ••;i;s~ Q: sc i :Z ' ' ?^A§^^&^A eoio' Manganese ug/L
ug/L
ug/L
ug/L
II I im^r. ."j j«i*tfjUi., 1 I • .I.,,. .^,n.i.,r.,A
5.0
10
10
ILOOO-
2.0
1/24/13 13 33
^•M/24'/13' • '•13J3^
I 34/13 13 33
2/01/13 c D A A n i o |g -iq hPA60I0
';o'28'' '-l-EPA*Olo
1/24/13?irj,-': 2/01/13
1/24/13 II 2b
2/13/13 18 32
EPA 6010
EPA60iq;-;S
EPA 200 8
"^f^M's;'V--Stj-'^'<:--ni"''-'':i/2^7fFJ^-i7:9/i3'j-Vp-o^^
ug/L 1000
iTl i^irftri.wftrt<
7440-65-5
7440-66-6:.
Yttrium
• Zinc ',rfr:
ug/L 5 0
ug/L 3.0 P P P 'S'^l,-' EPA 6010 3.0
fo
i/:4/i3 13 33
V\?i4i'l3'~, : 13 33..
i/:'3/i3 20::
' T o ' o ' / r r T T ^ ^ ^ ^ ? ^ ! ^ ^ : ^ '
Page 5 of 18 El30310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
Project: 13-0162, Aberdeen Groundwater
Total Metals
.Sample ID: ACGMW27
Station ID: ACGMW27
L a b I D : E l 3 0 3 1 0 - 0 3
Matrix: Groundwater
Date Collected: 1/17/13 17:55
Page 6 of 18 El30310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
Project: 13-0162, Aberdeen Groundwater
Total Metals
Sample ID: ACGMW29
Station ID: ACGMW29
Lab ID: E130310-04
Mat r i x : Groundwater
Dale Collected: 1/16/13 16:40
Page 7 of 18 E130310 TMTL FINAL 02 22 13 1349 2/22/13 .:49
U N I T E D STATES E N V I R O N M E N T A L P R O T E C T I O N A G E N C Y
Region 4 Science and Ecosystem Support Division
980 Col lege Station Road, Athens , Georgia 30605-2700
D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
P r o j e c t : 13-0162, A b e r d e e n G r o u n d w a t e r
Total Metals
Sample ID: ACGMW929
Station ID: ACGMW29
L a b ID : E l 3 0 3 1 0 - 0 5
Matrix: Groundwater
Date Collected: 1/16/13 16:40
Number.- . A'n:i^4iialyle • . ' ^-• : l -#4ir^ •••r-.^ISl^f^;,--* •Re.mt^fiUlifii^rs',>h-f.w, : - P i A ^ W & W ^ i ^ '•. '. '(/hiis^ '•' "
' ' 'Jf t •- - '-•••Ai H -'• '. ,''J:k:i 3;i';-A'':'.--'As'--.-A. :• '.''.P'M.-^A -AlMRI:••fPrepared."'-AnalyreiipMeih'od "- '^Sv^^ '
7429-90;5r;j ja^rtif i ir; I - ^ . ^ 2 ' ' 3 .
7440-36-0
.Aluminum
7782-49-2
7440-22-4
7440-23-5
744lf24-6" ;: Ahz: -..
7440-28-0
744oSl-5
7440-32-6
7440-,62-2
7440-65-5
EPA 6010
Strontium.'^ - .• ,f(pp>;:7'-,:~ "4^^?^^^ •
Thallium
' ZMj^zziZllS^z ' '" '^ Titanium
Vanadium
Yttrium 744p;6'626i:-jV^|Zinc ~. - ' ^ M ^ . - V >*i»':fl!.5.p
Page 8 of 18 E130310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162
Project 13-0162, Aberdeen Groundwater - Reported by Terri White
Project: 13-0162, Aberdeen Groundwater
Total Metals
Sample ID: GEIMW29D
Station ID: GEIMW29D
Lab ID: El30310-06
Matrix: Groundwater
Date Collected: 1/17/13 11:30
Nu'mHcr- '••''--, '^ -iiiatvte. 'A.-:-.. -•.Sf,?-..^. -r ':.V-;p-?-' -s"" -; -'A' ^Resultsc:QuiilifiikrAi'A-.-: •. •.•tfUifits' ---.'^y'Ai^lRIAS Prepar'ed:.'-W>alx-'icdr'ifethi,d^>AAii':,TfA -*:•;- • - ^ w ; . '-' - . - n i i - . . :---V^Mi::tA •• ••-.• •••iy:t'A, •• ' •• ' •• • "fe-.' • •:->':--:tA^-t.-
7429-90^5'.'fi-'S-4:'.Aluminum'sfl
7440-36-0
7440-38r2?j
7440-39-3
Antimony . . . - . . — j . . p ^ . .
Arsenic, '-^st:' Barium
7440-4l--7jWjy-BVryllm f 'J " •^^WlyZ'^' Cadmium 7440-43-9
7440-70-2''tii-^Calcium Liji2« U,.2^?iA<w . •,., :'.-.,s • J i L -
ug/L
ui/L?'
ug/L
1.0
"Z 5.0
1/24/13 13 36
~i/Un-i ,.13-36
1/24/13 13 33
2/01/13 -
I.JS.'SAB 2/13/13
11 01
; EP.A 6 0 1 0
ug/L >mAkZ^zoZ"^^p
0.50 1/24/13 13 36
2/13/13 t l 09 j^
I/2W13 21 00
'.rjriTw/iT
2/13/13 II O'l
9313 i^.=. ft,VfV,V
EPA 2 0 0 8
E P A 2 6 0 . ' 8 '
EPA 6 0 1 0
•eepmp EPA 200 8
' '^$iS^-^''^~iip/i~'AAS^^^Pn^^'2*'>i^'A'.~^SS\'i]^^ i g ! f e :3^ in : t b "%v^- ; j . - ; ; jB^y^ ' y^ l3 33----'':.'';.-:20 00 ,= ' ;^^^
7440-47-3
S40-48-4, l^^^^.h ;,.;..^'j;d
7440-50-8
7439,-89-6^
7439-92-1 7439:954^.'
7439-96-5
Chromium EPA 5010
Page 9 of 18 EI3O310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162
Project 13-0162, Aberdeen Groundwater - Reported by Terri White
Project: 13-0162, Aberdeen Groundwater
Total Metals
Sample ID: GEIMW29L
Station ID: GEIMW29L
Lab ID: El30310-07
Matrix: Groundwater
Date Collected: 1/17/13 11:20
Page 10 of 18 EI30310TMTLFrNAL02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
Total Metals (TMTL) - Quality Control
US-EPA, Region 4, SESD
EPA 6010
Silver
Barium
Beryllium
Cobalt
Chromium
Copper
Molybdenum
Nickel
Tin
Strontium
Titanium
Vanadium
^'ttrium
Zinc
u
u
u
u
u
u
u
u
LI
U
Ll
U
U
U
5.0
5.0
3.0
5,0
5,0
10
10
10
15
5,0
5,0
5.0
3,0
10
ug
Analyte Result
Reporting
Limit Units
Spike Soiu-ce %REC
Level Result %REC Limits RPD
RPD
Limit Notes
Batch 1301092 - M 200.2 Metals Water
Rlank(130l092-BLKI) Prepared: 01/24/13 Analyzed: 01/29/13
Blank (I30I092-BLK2) Prepared: 01/24/13 Analyzed: 02/01/13
EPABOIO
Aluininuin
Manganese
Calcium
Magnesium
Iron
Sodium
Potassium
u
u
u
u
u
u
u
too
5,0
250
250
100
1000
1000
" t
LCS(I30I092-BSI) Prepared: 01/24/13 Analyzed: 01/29/13
EPA 6010
Silver
Barium
Beryllium
Cobalt
Chromium
Copper
Molybdenum
Nickel
Tin
Strontium
Titanium
99,897
195,07
49,550
99,151
199,75
102.74
100 35
199.80
103,18
98,877
101,93
5.0
5,0
3,0
5,0
5,0
10
10
10
15
5,0
5,0
"t 7L 100,00
200.00
50 000
100,00
200,00
100,00
100,00
200,00
100,00
100,00
100,00
99.9
97.5
991
9 9 2
9 9 9
103
IOO
99,9
103
98,9
102
85-115
85-115
85-115
85-115
85-115
85-115
85-115
85-115
85-115
85-115
85-115
Page II of 18 E130310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Divis ion
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
Total Metals (TMTL) - Quality Control
US-EPA, Region 4, SESD
Analyte Result
Reporting
Limit Units
Spike Source ?-iREC
Level Result %REC Li)nits RPD
RPD
Limit Notes
Batch 1301092 - M 200.2 Metals Water
LCS(130I092-BSI) Prepared; 01/24/13 Analyzed: 01/29/13 Vanadium
\'ttriuin
Zinc,
100.54
101.33
200.69
5,0
3,0
10
ug/L 100,00
100.00
200,00
101
101
100
85-115
85-115
85-115
LCS (1301092-BS2) Prepared: 01/24/13 Analyzed; 02/01/13
EPA 6010 Aluminum
Manganese
Calcium
.Magnesium
Iron
Sodium
Potassium
5028,3
513,59
5267.4
5105.5
6059,1
10068
9o93,7
IOO
5,0
250
250
IOO
1000
1000
"t / L 5000.0
500.00
5000.0
5000,0
5000,0
IOOOO
IOOOO
lOI
103
105
102
121
101
96,9
85-115
85-115
85-115
85-115
85-115
85-115
85-115
OL-2
Matrix Splke(130l092-MSI) Source: El30307-02 Prepared: 01/24/13 Analyzed: 01/29/13
EPA 6010 Silver
Barium
Beryllium
Cobalt
Chromium
Copper
Molybdenum
Nickel
Tin
Strontium
Titanium
Vanadium
^'ttrium
Zinc
98,522
209.72
49.479
99385
198.10
103.35
99.617
196.61
102.82
106.36
103.52
100.44
101.45
199.61
5 0
5.0
3.0
5.0
5.0
10
10
10
15
5.0
5.0
5.0
3.0
10
"t 7L 100.00
200.00
50.000
100.00
200.00
100.00
100.00
200.00
100.00
100.00
100.00
100.00
100.00
200.00
u 13.465
u 0.61717
u u u u u
6.3462
U
U
0.83376
3.5654
98.5
98.1
99.0
98.8
99.1
103
99.6
98.3
103
IOO
104
IOO
101
98.0
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
Page 12 of 18 E130310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T Id: 13-0162 Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
Total Metals (TMTL) - Quality Control
US-EPA, Region 4, SESD
Analyte
Reporting
Result Limit Units
Spike Source "'oREC
Level Result %REC Limits RPD
RPD
Limit Notes
Batch 1301092 - M 200.2 Metals Water
M a t r i x S p i k e ( I 3 0 I 0 9 2 - M S 2 ) S o u r c e : E l 3 0 3 1 0 - 0 2 Prepared: 01 /24/13 Analyzed: 01 /29/13
EPA 6010 Silver
Barium
Ber\'llium
Cobalt
Chromium
Copper
Molybdenum
Nickel
Tin
Strontium
Titanium
Vanadium
N'ttrium
Zinc
97.595
282.81
49759
101.19
222.09
105.51
103.27
204.59
79.514
152.41
109.03
II0.5I
108.89
222.72
5.0
5.0
3.0
5.0
5.0
10
10
10
15
5.0
5.0
5.0
3.0
10
ug/L
" " -" " " "
"
" "
100.00
200.00
50.000
100.00
200.00
100.00
100.00
200.00
100.00
100.00
100.00
100.00
100.00
200.00
, U
88,812
0,59388
2,0584
27.507
5.6140
9.7858
13.983
U
53.637
38.694
11.020.
8.6528
27.335
97.6
97.0
98.3
99.1
97.3
9 9 9
93.5
95.3
79.5
98.8
70.3
99.5
IOO
9 7 7
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
Matrix Spike (1301092-MS3) Source: E130307-02 Prepared: 01/24/13 Analyzed: 02/01/13 EPABOIO Aluminum
Manganese
Calcium
Magnesium
Iron
Sodium
Potassium
5037.9
531.53
5663.9
5574.6
5789.1
12551
11078
100
5.0
250
250
IOO
1000
1000
nil. 5 0 0 0 . 0
5 0 0 . 0 0
5 0 0 0 . 0
5 0 0 0 . 0
5 0 0 0 . 0
IOOOO
IOOOO
U
18.521
1295.1
4 7 2 . 3 1
4 2 6 . 2 1
2646 .1
I 4 I 3 . 6
101
103
107
104
107
9 9 . 0
9 6 . 6
7.5-125
7 5 - 1 2 5
7 5 - 1 2 5
7 5 - 1 2 5
7.5-125
7 5 - 1 2 5
7 5 - 1 2 5
M a t r i x S p i k e ( 1 3 0 l 0 9 2 - M S 4 ) S o u r c e : E l 3 0 3 1 0 - 0 2 Prepared; 01 /24 /13 Analyzed; 02 /01/13
EPA 6010 Aluminum
Manganese
Calcium
Magnesium
Iron
Sodium
Potassium
12212
764.45
10379
7006.0
13085
3934S
10940
100
5.0
250
250
IOO
1000
1000
"t 7L
'
5000.0
500.00
5000.0
5000.0
5000.0
IOOOO
IOOOO
6958.6
235.71
5041.1
1725.9
7523.5
29469
936.69
105
106
107
106
III
98.8
IOO
75-125
75-125
75-125
75-125
75-125
75-125
75-125
Page 13 of 18 EI30310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
Total Metals (TMTL) - Quality Control
US-EPA, Region 4, SESD
EPA 6010 Silver
Barium
Beryllium
Cobalt
Chromium
Copper
Molybdenum
Nickel
Tin
Strontium
Titanium
Vanadium
Yttrium
Zinc
98.214
210.36
49.815
99.019
200.06
100.71
99353
198.28
101.63
106.71
100.61
99.551
101.68
200.71
5.0
5.0
3.0
5.0
5.0
10
10
10
15
5.0
5.0
5.0
3.0
10
"t yL 100.00
200.00
50.000
100.00
200.00
100.00
100.00
200.00
100.00
100.00
100.00
100.00
100.00
200.00
U
13.455
u 0.61717
U
U
, u u u
5,3462
u U
0,83376
3,5654
98.2
98.4
99,5
98,4
100
101
99,4
99.1
102
100
101
99.5
101
98.5
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
0.313
0.302
0.677
0.369
0.984
2.59
0.265
0,844
1,16
0,328
2,95
0,889
0,231
0.552
20
20
20
20
20
20
20
20
20
20
20
20
20
20
Analyte
Reporting
Result Limit Units
Spike Source '!i,REC
Level Result ^oREC Limits RPD
RPD
Limit Notes
Batch 1301092 - M 200.2 Metals Water
M a t r i x S p i k e O u p ( 1 3 0 1 0 9 2 - M S D I ) Source: EI30307-02 Prepared; 01/24/13 Analyzed: 01/29/13
Matrix Spike Dup (I30I09Z-MSD2) Source: El30310-02 Prepared: 01/24/13 Analyzed; 01/29/13
EPABOIO Silver
Barium
Ber>'llium
Cobalt
Chromium
Copper
Molybdenum
Nickel
Tin
Strontium
Titanium
Vanadium
Yttrium
Zinc
97,559
284,34
49,354
99,356
220,87
108.52
101,80
206.03
82,412
152.05
113.12
109.54
108,54
219.12
5,0
5,0
3,0
5,0
5,0
10
10
10
15
5.0
5,0
5,0
3,0
10
"t yL 100.00
200.00
50.000
100,00 .
200.00
100.00
100.00
200.00
100.00
100.00
100.00
100.00
100.00
200.00
u 88.812
0.59388
2.0584
27.507
5.6140
9.7858
13.983
U
53.637
38.694
11.020
8.6528
27.335
97.7
97.8
97.5
97.3
96.7
103
92.0
96.0
82.4
98.4
74.4
98.5
99.9
95.9
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
0.0651
0.540
0.797
1.82
0.554
2.81
1.44
0.701
3.58
0.242
3.68
0.793
0.321
1.63
20
20
20
20
20
20
20
20
20
20
20
20
20
20
QM-1
Page 14 of 18 El30310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
Total Metals (TMTL) - Quality Control
US-EPA, Region 4, SESD
EPA 6010
Aluminum
•Manganese
Calcium
Magnesium
Iron
Sodium
Potassium
5058.4
540.09
6823.5
5728.4
5892.3
12662
II 160
100
5.0
250
250
IOO
1000
1000
ug/L
" -" " " -
5000.0
500.00
5000.0
5000.0
5000.0
IOOOO
IOOOO
U
18.521
1295.1
472.31
426.21
2646.1
I4I3.6 /
101
104
III
105
109
100
97.5
75-125
75-125
75-125
75-125
75-125
75-125
75-125
0.407
1.58
2.37
0.942
1.77
0.881
0.745
20
20
20
20
20
20
20
Analyte
Reporting
Result Limit Units
Spike Source '/oREC
Level Result ".iREC Limits RPD
RPD
Limit Notes
Batch 1301092 - M 200.2 Metals Water
M a t r i x Spike D u p ( l 3 O I 0 9 2 - M S D 3 ) Source: EI30307-02 Prepared: 01/24/13 Analyzed; 02/01/13
Matrix Spike Dup (130I092-MSD4) Source: El30310-02 Prepared; 01/24/13 Analyzed; 02/01/13
EPA 6010
Aluminum
Manganese
Calcium
Magnesium
Iron
Sodium
Potassium
I 2 I 3 2
7 4 0 . 7 0
10088
6 7 7 5 . 0
12798
3 8 3 2 9
10582
IOO
5.0
250
250
IOO
1000
1000
u g / L
"
5 0 0 0 . 0
5 0 0 . 0 0
5 0 0 0 . 0
5 0 0 0 . 0
5 0 0 0 . 0
IOOOO
IOOOO
5968.5
235.71
5041.1
1726.9
. 7523.5
29469
936.69
103
101
lOI
101
105
88.6
96.5
75-125
75-125
75-125
75-125
75-125
75-125
75-125
0.655
3.15
2.85
3.35
2.21 •
2.62
3.33
20
20
20
20
20
20
20
MRL Verification (li01092-PSl) Prepared: 01/24/13 Analyzed: 01/2^/13
EPA 6010
Silver
Barium
Ber\llium
Cobalt
Chromium
Copper
Molybdenum
Nickel
Tin
Strontium
Titanium
Vanadium
Yttrium
Zinc
5.3386
5.3336
3.0781
5.0200
5.7409
9.9564
10.997
10.675
15.891
4.9962
5.4825
4.6900
2.9708
11.662
5.0
5.0
3.0
5.0
.5.0
10
10
10
15
5.0
5.0
5.0
3.0
10
ug/L
" "
--" "
" "
"
-
5.0000
5.0000
3.0000
5.0000
5.0000
10.000
10.000
10.000
15.000
5.0000
5.0000
5.0000
3.0000
10.000
107
107
103
IOO
115
99,6
no 107
106
99.9
no 93.8
99.0
117
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
MRL-2
MRL-2
MRL-2
MRL-2
MRL-2
MRL-2.
U
MRL-2
MRL-2
MRL-2
MRL-2.
U
MRL-2
MRL-2.
U
MRL-2.
u
MRL-2
Page 15 of 18 El30310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
Total Metals (TMTL) - Quality Control
US-EPA, Region 4, SESD
.Analyte Result
Reporting
Limit Units
Spike Source ^oREC
Level Result '^iREC Limits RPD
RPD
Limit Notes
Batch 1301092 - iM 200.2 Metals Water
MRL Verincation (I30I092-PS2) Prepared: 01 /24/13 Analyzed; 02 /01/13
EPA 6010
Aluminum
Manganese
Calcium
Magnesium
Iron
Sodium
Potassium
110.70
5.4963
271.42
250.64
109.00
1174.5
1001.9
IOO
5.0
250
250
IOO
1000
1000
" l yL 100.00
5.0000
250.00
250.00
100.00
1000.0
1000.0
in
no
109
100
109
117
100
70-130
70-130
70-130
70-130
70-130
70-130
70-130
MRL-2
MRL-2
MRL-2
MRL-2
MRL-2
MRL-2
MRL-2
Batch 1301093 - M 200.2 Metals Water
Blank (1301093-BLKl) Prepared: 01/24/13 Analyzed: 02/13/13
EPA 200.8
Arsenic
Selenium
Cadmium
Antimony
Thallium
Lead
u u u u u u
1-0
2.0
0.50
1.0
1.0
I.O
ug/
' ' ' •
'
LCS(130I093-BSI) Prepared: 01/24/13 Analyzed; 02/13/13
EPA 200.8
Arsenic
Selenium
Cadmium
Antimony
Thallium
Lead
221.10
224.70
55.218
196.83
212.79
220.08
5.0
10
2.5
5.0
5.0
5.0
ug/L 200.00
200.00
50.000
200.00
200.00
200.00
111
112
110
98:4
106
no
85-115
85-115
85-115
85-115
85-115
85-115
Matrix Spike (I30I093-MSI) Source: El30307-02 Prepared: 01/24/13 Analyzed: 02/13/13
EPA 200.8
•Arsenic
Selenium
Cadmium
Antimony
Thallium
Lead
220.31
232.63
54.710
199.60
218.31
223.25
5.0
10
2.5
5.0
5.0
5.0
ug/L
" -" " "
200.00
200.00
50.000
200.00
200.00
200.00
U
U
U
0.016066
u
0.24975
no
116
109
99.8
109
III
70-130
70-130
70-130
70-130
70-130
• 70-130
Page 16 of 18 E130310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road. Athens, Georgia 30605-2700
D.A.R.T Id: 13-0162
Project: 13-0162, Aberdeen Groundwater - Reported by Terri White
Total Metals (TMTL) - Quality Control
US-EPA, Region 4, SESD
EPA 200.8
Arsenic
Selenium
Cadinium
.Antimony
Thalliuin
Lead
218.23
225.49
55.819
100.58
215.76
236.04
5.0
10
2 5
5 0
5.0
5.0
ug/L
"
"
"
"
200.00
200.00
50.000
200.00
200.00
200.00
1.9337
1.5894
0.058284
0.10713
U
11.526
108
112
112
50.2
108
112
70-130
70-130
70-130
70-130
70-130
70-130
.Analyte
Reporting
Result Limit Units
Spike Source %REC
Level Reside ».'oREC Limits RPD
RPD
Limit Notes
B a t c h 1301093 - M 200.2 M e t a l s W a t e r
M a t r i x Sp ike (130 l093-MS2) Source: El30310-02 Prepared: 01/24/13 Analyzed: 02/13/13
QM-I
Matrix Spike Dup (1301093-MSDI) Source: El30307-02 Prepared: 01/24/13 Analyzed; 02/13/13
EPA 200.8
Arsenic
Selenium
Cadmium
Antimony
Thallium
Lead
220.85
215.89
54.928
195.91
211.79
223.38
5.0
10
2.5
5.0
5.0
5.0
ug/L
"
-
"
"
"
200.00
200.00
50.000
200.00
200.00
200.00
U
U
U
0.016055
U
0.24975
no
108
no
98.4
106
112
70-
70-
70-
70-
70-
70-
30
30
130
30
30
30
0.244
7.00
0.398
1.36
3.03
0.0569
20
20
20
20
20
20
Matrix Spike Dup (1301093-MSD2) Source: El30310-02 Prepared: 01/24/13 Atialyzed: 02/13/13
EPA 200.8
Arsenic
Selenium
Cadinium
Antimony
Thallium
Lead
217.35
216.57
54.999
101.80
221.47
239.92
SO
10
2.5
5.0
5-P
5.0
ug/L
"
"
"
"
"
200.00
200.00
50.000
200.00
200.00
200.00
1.9337
1.5894
0.058284
0.I07I3
U
11.526
108
107
no
50.8
111
114
70-130
70-130
70-130
70-130
70-130
70-130
0.402
4.04
148
1.20
2.61
1.53
20
20
20
20
20
20
QM-1
MRL Verification (I30I093-PSI) Prepared: 01/24/13 Analyzed: 02/13/13
EPA 200.8
Arsenic
Selenium
Cadmium
Antimony
Thallium
1.1288
2.2018
0.55980
0.52760
0.64800
1.1454
I.O
2.0
0.50
1.0
I.O
LO
ug/L
"
"
LOOOO
2.0000
0.50000
0.50000
0.50000
I OOOO
113
no
114
106
130
115
65-135
65-135
65-135
65-135
55-135
65-135
MRL-2
MRL-2
MRL-2
MRL-2.
U
MRL-2.
U
MRL-2
Page 17 of 18 El30310 TMTL FINAL 02 22 13 1349 2/22/13 13:49
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T Id: 13-0162
Project 13-0162, Abertdeen Groundwater - Reported by Terri White
Notes and Definitions for Q C Samples
u MRL-2
QC-6
QL-2
( M-1
The analyte was not detected at or above the reporting limit.
MRL verillcation for Non-Potable Water matrix
Calibration check standard greater than mediod control limits.
Laboratory Control Spike Recovery greater than method control limits
Matrix Spike Recovery less than method control limits
Page 18 of 18 El30310 TMTL FINAL 02 22 13 1349 2/22/13 13:49