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1 1 1 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW NEET - II : 2016 CODE -AA/PP/WW PHYSICS Date : 24-07-2016 Time : 3 Hrs. Marks : 720 Medical - UG 1. 5 3 2 3 3 3 hG LT L L LT C Topic: _____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016 2. 2 p dx a bt dt 2 q dx f t dt 2 2 a bt f t 2 2 f a t b Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016 3. 0 1 tan 30 3 t r a a 2 2 15 t r a a 4/3 15 r a 2 2 15 3 r r a a 3 15 r a a 30 0 2 3 15 4 r v a r 3 15 2.5 5.7 / 4 v ms Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

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Page 1: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

111

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW

NEET - II : 2016CODE -AA/PP/WW

PHYSICSDate : 24-07-2016

Time : 3 Hrs.Marks : 720

Medical - UG

1.

5 32

3 3 3

hG L T L LL TC

Topic: _____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

2. 2pdxa bt

dt

2qdxf t

dt

2 2a bt f t

2 2f atb

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

3. 0 1tan 303

t

r

aa

2 2 15t ra a 4 / 3 15ra

22 15

3r

ra a

3 15ra

a300

23154r

var

315 2.5 5.7 /4

v m s

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

Page 2: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

22

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW

4.600

600

V

V cos(60 )0

I P

2 cos 60m V

mvTopic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

5. 212 0.1 22

g u

4 2

i fp p

0.01 400 0.01 2 2V

2 kg

5 m

10 cmu

v 4 2 4 2 1.4 1000.01

V

4 2.8 100

1.2 100 = 120

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

6. mm 0.5 0.3

A B

Velocity exchange due to same mass.Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

7. ˆ ˆ ˆ4 3 2 5D Displacement i k i j

ˆˆ ˆ2 3i j k

Work F D

ˆˆ ˆ ˆ ˆ4 3 2 3i j i j k

8 3 5 Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

Page 3: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

333

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW

8. (3)

2 22

1 12 2A A BI I

2 2A A B B

A B

I II I

2

A A

B B

L IL I

B A B AI I L L

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

9.

2 22

22 2

2152

12 2

SS SS

CC C C

MRIEMRE I

2

4 1 15 2 5

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

10. m1 m2

CM

2

1 2

m lm m

2 2

2 11 2

1 2 1 2

m l m lI m mm m m m

21 2

1 221 2

m m l m mm m

21 2

1 2

m m lm m

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

11. 3

GMrg r RR

2

GM r Rr

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

Page 4: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

44

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW

12. 2GMmTotal energyR h

2

22GM R m

R R h

2

0

2g mR

R h

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

13. 4

04

3 10 3 1 0.1252 20 8 10 24 8

P E SArea

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

14. 2 cosshfrg

cosconstant

1 2 3

1 2 3

cos cos cos

1 2 3

1 2 3cos cos cos

1 2 3

Rise means 090

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

15. 050For C

100releasedR mC T

gain 0mC T

100 0C C

050R gain T C

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

Page 5: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

555

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW

16. 3 2 3 2 .... 110 2

T T T TC T

2 ' ' 2 .... 210 2

T T T TC T

2 2 ' '/ 21 3 2 3 / 2

T T TT T T

3 2 ' 'T T T

6 4 'T T

6 3'4 2T TT

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

17. 3 3PV C K

0 1RC C

K

3 32 1 3 2 2

R R RR

= RTopic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

18. Heat delivered 1

Energy consumed W

1 1

2 21 2

1 1

1 12731 1273

tWt

1

1 2

273tt t

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

19. PV nRT

A

A

kN TRTPM mN

kTPm

mPkT

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

Page 6: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

66

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW

20. 2 mTk

T m

35 1

mm

9 9 25m m 925 1

mm

9 16m

916

m

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

21.0

3 32 4 C

V VL L

0 2L L

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

22. 1 sin 2y A nt

2 sin 2 1y A n t

3 sin 2 1y A n t

2sin 2 cos 2 sin 2y nt t A nt

1 2cos 2 sin 2A t nt

cos 2 1t

2 t n t n

1 30, ,1, ....2 2

t

so time interval = 12

s

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

23. sinPE

3 04 0.02 2 10 sin 30q

4 0.22 10

q

200q mcTopic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

Page 7: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

777

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW

24. 01 2 3 1

23

A K K K Cd

1 2 3, , are parallelk k k

04 2

2

A K Cd

1 2

1 1 1C C C

0 0 1 2 3 0 4

32 2

d d dAK A K K K AK

1 2 3 4

1 3 12K z K K K K

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

25. 1 2 3 2 2 9V Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

26.2 2100500

b

VPR R

20bR

3020

IR

2500 20I

2230500 2020 R

22302520 R

230 520 R

46 20 R

26R

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

Page 8: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

88

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW

27. one turn2

R

01 2

IB BR

2Rr

n n

20 02 2 2 R

n

nI n IB n Br

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

28. cos60oW MB MB

2MBW

sin 60oMB

32 32

W W

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

29. (1)

2mV qv Br

V e Br m

2 2V e Bf

r m

91.76 3.57 102 3.14

f

90.98 10f

1d GHz

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

Page 9: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

999

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW30. For a series circuit

1 LQR C

31

1 1.5 1020 35

Q

32

1 2.5 1025 45

Q

33

1 3.5 1015 30

Q

34

1 1.5 1025 45

Q

3rd circuit has maximum Q value & hence best suited for tuinng.Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

31. 21

dBrdt

2 0

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

32.

80 V

60

Veff

80V

100V

40

80cos 0.83600 6400

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

33.220100

t

i e

2.2t

i e

100 C

220 Vmax 2.2i A

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

Page 10: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

1010

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW

34. 1 3 1 112f R R

1 1f R

1 4 1 11' 3f R R

1 2 23 3R R

1 1 1 1 2 2 4' 3 3efff f f f R R R

34effff

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

35. 115 7.5

1.5t t cm

223 4.5

1.5t t cm

12t cm

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

36.1 1

2 2

I An nI A

1 2 max

1 2 min

11

A A A nA A A n

2

max2

min

1

1

nII n

max min

max min

21

I I nI I n

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

Page 11: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

111111

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW

37.1 1 144

v m Pd

0.25 diopterP

It is a concave lines.

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

38.5 2

2

5 10 10 0.60.02 10

D yd

415 10

0.15cm

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

39.h hv

mv m

22

2 2

hvm

22

2

12 2

hm vm

2

0 22hc h

m

2

02m C

h

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

40. In first case

max5 . 2pE eV K E eV

3eV

In second case

max. 6 3 3K E eV

Stopping voltage 3V

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

Page 12: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

1212

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW

41. 2 2

1 1 13

RdeR

1 536

Rd

1 1 1 7' 9 16 9 16

Rd Rd

9 155'736

20'7

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

42. 12

30mint

230n

10 00 6 tN N e

20 09 15 tN N e

2 14 t te

2 2n t

60mint

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

43. 100cII

1000BR

100 cII

0 4V V

o L

i B

V RV R

4 1000 0.02 20100 2000iV mv

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

Page 13: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

131313

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW

44.

II

R1 D1 D210V

3 2

Diode D1 is reversed biased. Then no current will flow through that link.

10 2.54

I A

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

45.O AO BO C

P O

OR 1

11 1 1 1 0

A B P C QO O O O

Topic:_____ ; Sub Topic: _____ ; L:_ ; Medical-UG ; NEET Exam - 2016

Page 14: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

111

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : PP / Chemistry

NEET - II : 2016CODE - PP

CHEMISTRYDate : 24-07-2016

Time : 3 Hrs.Marks : 720

Medical - UG

Q.46 A long chain of glucose units attached together by 1, 4 linkages. It is the ability of these chains to hydrogenbond together in to fibres that gives cellulose its unique properties of mechanical strength and chemicalstability.

Topic:Biomolecules; Sub Topic:Carbohydrates; L:2 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.4731000 cmMolar conductivity

0.5 molek

3

3 1 1000 cm5.76 10 Scm0.5 mole

2 11.152 10 Scm mol

2 111.52 Scm molTopic:Electrochemistry; Sub Topic:Conductance and conductivity; L:1 ; Medical-UG ; AIPMT / NEET Exam

- 2016

Q.48 Unimolecular surface reactions can be described by1 2

1( ) ( ) productsK Kg adsorbedK

A A

Rate of product formation is 2 AK (where A is surface coverage of A).

2 Ar K {i.e., rate of reaction is directly proportional to surface coverage}Topic:Surface chemistry; Sub Topic:Adsorption; L:2 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.49 Millimoles of an electrolyte that must be added to one litre of colloidal solution to bring complete coagulationis called coagulation value.

1Coagulation powerCoagulation value

Topic: Surface chemistry; Sub Topic: Colloids; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Page 15: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

22

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : PP / Chemistry

Q.50 NaCl Na Cl (Fused electrolyte)

Cathode : 2 2 2Na e Na

2Anode : 2 2Cl Cl e

To get 0.1 mole 2 0.2Cl F is required.

0.2 96500 3 (sec)t t is 110 minutes (approx).Topic: Electrochemistry; Sub Topic: Faraday’s laws; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.51 3; 1 3 no. of electron 2n p Topic:Atomic structure ; Sub Topic:Quantum number; L:2 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.52 2 2

1 1

ln lnVT VS nC n RT V

2 1

1 2

ln lnpT PS nC nRT P

Isothermal process; 2 1T T

1

2

ln PS nRP

Topic:Thermodynamics; Sub Topic:Entropy; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.53 22( ) ( ) ( )( ) 2s aq aqBa OH Ba OH

In dilution solutions; Assume complete ionisation

1 ( 1) ( 1)1

i n in

3i n Topic:Solution and colligative properties; Sub Topic:Vant Hoff factor; L:1 ; Medical-UG ; AIPMT / NEET

Exam - 2016

Q.54

N+ H O2

N

H

+ OH– ; K = 1.7 × 10b–9

t = 0 Ct = t C–Ceq

–C

–C

22 (1 1)

1b bCK K C

Page 16: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

333

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : PP / Chemistry

94

1

1.7 10 1.3 1010

bKC

2% ionisation 100 1.3 10 Topic:Equilibrium; Sub Topic:Ostald’s dilution law; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.55 In fluorite structure; F occupy tetrahedral voids and 2Ca occupy CCp lattice points.

i.e., each 2Ca is surrounded by 8 F ions C.N = 8

each F is surrounded by 4 2Ca ions C.N = 4Topic:Solid Shape; Sub Topic:Ionic crystals; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.56 oE is – ve 0oG

ln 1oeq eqG RT K K

Topic:Electrochemistry; Sub Topic: Gibbs free energy & Keq; L:1 ; Medical-UG ; AIPMT / NEET Exam -2016

Q.57 For ideal solutions;0; 0; 0; 0G S H V

Raoult’s law 0 0Total A A B BP P X P X

i.e. obs calculatedP P

incorrect statement is 0mixG

Topic: Solution and colligative properties; Sub Topic: Ideal solutions; L:1 ; Medical-UG ; AIPMT / NEETExam - 2016

Q.58 s aq aqAgCl Ag Cl

spK Ag Cl

101.6 10 0.1Ag 91.6 10Ag M

Topic: Ionic equilibrium; Sub Topic: Solubility product; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.59 Let atomic weight of X be : x and Y be : y

10 0.1 2 1x y

9 0.05 3 2 2 18 0.1 3 2x y x y

Page 17: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

44

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : PP / Chemistry

2 1003 2 180x yx y – – –

2 8040

xx

30y

Topic:Mole concept; Sub Topic:Atomic weights ; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.60 1 60 60Q C

192060 10no.of electrons 3.745 10

1.602

Topic:Electrochemistry; Sub Topic:Electrolytic cell; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.61 3 3 2 342H BO H O B OH H O

Topic:P-Block; Sub Topic:Boric acid; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.62 3 3 63AlF KF K Al F

Topic:P-Block; Sub Topic:Alluminium compounds; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.63 Zn is more electropositive than Fe.

20

/0.76

Zn ZnE V

2 20 0

/ /0.41 ; 0.04

Fe Fe Fe FeE V E V

zn act as sacrifying metal and protect FeTopic: Electrochemistry; Sub Topic:Prevention of corrosion; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.64 Suspension is called milk of lime.Topic:S-block; Sub Topic:Calcium compounds; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.652 3 4

2 3

NO NO NHsp sp sp

Topic:Chemical bonding; Sub Topic:Hybridisation; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.66

. .

PF

FF

3BF is lewis acid and electron deficient.

4 4,CF SiF have octet configuration and no lone pair to donateTopic: P-block ; Sub Topic:Basic nature; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Page 18: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

555

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : PP / Chemistry

Q.67 2 23 3 3 3

2 2 3 3

32 32 42 42

Trigonal planar Trigonal planar Tetrahedral Tetrahedral

CO NO SO ClOe e e e

sp sp sp sp

Topic:Chemical bonding; Sub Topic:Hybridisation; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.68 Beryllim salts readily hydrolyze.Topic:S-block; Sub Topic:Beryllium compounds; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.69 2 2 4 4 2CaF H SO CaSO HF

(a) 20

2Cu Cu

(b) 0 4

2S SO

(c) 0 4

2C CO

Topic:Atomic structure; Sub Topic: Shapes of orbitals ; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.70 2 2 2;x y zd d are along the axis.

Topic:__________ ; Sub Topic:________ ; L:_ ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.71 48 4no. of hybrid orbitals 6

2XeF

3 2sp d hybridisationoctahedral geometrysquare planar shape

Topic:Chemical bonding; Sub Topic:Hybridisation; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.72 4SeF have see-saw shape

4CH have Tetrahedral shape.

3I has bent shape.Trigonal bipyramidal geomentry.

Topic:Chemical bonding; Sub Topic:Hybridisation and geomentry; L:1 ; Medical-UG ; AIPMT / NEET Exam- 2016

Q.73 Trans effect is the labilzation (making more reactive) of ligands, that are trans to certain other ligands.

22 2 3 3 3 32, , , , , , ,Py Cl Br I SCN NO SC NH Ph SO PR AsR CH H

2 4, , ,NO CO CN C H

Page 19: Medical - UG - Careers360 · PDF file333 RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : AA / PP / WW 8. (3) 2 2 2 1 1 2 2A A B I I 2 2 A A B B

66

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : PP / ChemistryTopic:Co-ordination compounds; Sub Topic:Trans effect; L:2 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.74 (1) Eu shows + 2 state(2) From Pr to Lu due to lanthanoid contraction size decreases therefore basic nature decreases.

(4) 4( )aqCe is good oxidising agent.

(3) is wrong.Topic:__________ ; Sub Topic:________ ; L:_ ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.75 Low spin complexes with 3 6 8 10, , andd d d d electrons does not have John-Teller distortions.

High spin complexes with 3 5 8 10, , ,d d d d electrons does not show John-Teller distortions.Topic:__________ ; Sub Topic:________ ; L:_ ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.76 In friedel-crafts reaction

+ R – Cl Lewisacid

R

+ HCl

Cl

can form

remaining ; are not possible.

Topic:__________ ; Sub Topic:________ ; L:_ ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.77 Coplanar : all atoms must be in same plane.

(2) Puckered structure so no planarity

(3) C CH C3

H C3

C

N

CN

Hydrogens out of plane

(4) no planarity

Planarity is possible due to free rotation it may some time go out of plane.

Topic:__________ ; Sub Topic:________ ; L:_ ; Medical-UG ; AIPMT / NEET Exam - 2016

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777

RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : PP / Chemistry

Q.78 6–carbons and 6–carbons during the linkage

(CH )2 4

C

O||

C

O||

(CH )2 6

NH NH n

Topic:Polymers; Sub Topic:Co-polymerisation; L:1; Medical-UG ; AIPMT / NEET Exam - 2016

Q.79NH

5

4 3

21 N

H

NH

i.e., ether (2) (or) (5) carbon.Topic:GOC; Sub Topic: Resonance; L:1 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.80 (1) HBrBr

propeneelimination

(2) elimination3 2 2 3 2 2 3 2

Propene

HBrH C CH CH OH H C CH CH Br H C CH CH

(3) 2 No reactionH C C O

(4) elimination3 2 2 3 2

PropeneH C CH CH Br H C CH CH

Topic: Hydrocarbon ; Sub Topic:Alkane ; L:2 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.81 The compound with No H will not react with Nitrous acid.

Option 3 is not having ( )H Topic:Nitrogen and its compounds ; Sub Topic: Chemical properties; L:2 ; Medical-UG ; AIPMT / NEET

Exam - 2016

Q.82 DNA in copies as messenger RNA (mRNA) which in turn is the template for protein synthesis (uses r-RNAand t RNA)

Topic: Biomolecules ; Sub Topic: Proteins ; L:2 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.83 CHO

OHHOHH

CH OH2

CHO

HHOOHH

CH OH2

CHO

HHOHHO

CH OH2

CHO

OHHHHO

CH OH2

D-erythrose D-threose L-erythrose L-Threose

Topic: Biomolecules ; Sub Topic: Carbohydrate ; L:2 ; Medical-UG ; AIPMT / NEET Exam - 2016

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RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : PP / Chemistry

Q.84 (i) H+

(ii) H

Topic:Aromatic compounds; Sub Topic:Electrophilic substitution; L:2 ; Medical-UG ; AIPMT / NEET Exam -2016

Q.85NO2

Sn/HClStephensreduction

NH2

HNO2

Diazotisation

(N N)Cl–

(A)

(B)DiazoniumChloride

OH

N N

(azo compound)yellow orange solution

or ppt. is formed

OH

Topic:Nitrogen and its compounds ; Sub Topic: Chemical properties; L:2 ; Medical-UG ; AIPMT / NEETExam - 2016

Q.86 3 2 2 3 2 2H C CH CH Br NaCN H C CH CH CN NaBr

The above reaction follows 2SN mechanism, which is best in Polar Non Protic Solvent i.e., N,N-dimethylformamide (DMF).

Topic:Alkyl and Aryl halide; Sub Topic:ST: SN reaction ; L:2 ; Medical-UG ; AIPMT / NEET Exam - 2016

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RAO IIT ACADEMY / Medical - UG / NEET - II / 2016 / Solutions / Code : PP / Chemistry

Q.87

O O

H (1-atm)2(g)

Pd/C ethanol

Reduction take place at Non polar unsaturation. i.e., ( )C C Topic:Hydrocarbon ; Sub Topic: Chemical properties ; L:2 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.88 Tautomerism takes place with carbonyl compound having H atom.H which is at Bridge head C will not get involved in Tautomerism.

Structure (I): H are at bridge head so no Tautomerism.

Structure (II): H is at bridge head and another C is not having H so no Tautomerism.Structure (III): H is presents so can undergo Tautomerism. Only option III will show Tautomerism.

Topic:GOC; Sub Topic:Tautomerism; L:2 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.89 When an EWG is present close to –COOH due to (-I) effect losing H becomes very easy. (I effect isdistance dependent)Structure-II: –O- is present close to –COOH due to –I effect, after that structure III and then structure (–I) i.e., (II) > (III) > (I).

Topic:GOC ; Sub Topic:Inductive effect; L:2 ; Medical-UG ; AIPMT / NEET Exam - 2016

Q.90 Br Br Br Br

Alkene dissociating heterolytically will favour 2Br addition Reaction.

2 3 2

|Propene

|

Br

Br H C CH CHunsymmetrical

Br

Topic: Hydrocarbon ; Sub Topic:Addition reaction; L:2 ; Medical-UG ; AIPMT / NEET Exam - 2016