may 24, 2019 u.s. environmental protection agency, region 5 re · may 24, 2019 . ms. lauren bumba...

May 24, 2019 Ms. Lauren Bumba – Remedial Project Manager U.S. Environmental Protection Agency, Region 5 Superfund Division, Remedial Response Branch 77 West Jackson Boulevard Mailcode: SR-6J Chicago, Illinois 60604-3507 RE:

Summary of April 2019 Groundwater Sampling Activities, Remedial Investigation/Feasibility Study (RI/FS) - Ottawa Township Flat Glass Site, Ottawa, LaSalle County, Illinois, PNA168.0016.

Dear Ms. Bumba: On behalf of Pilkington North America, Inc. (PNA), Hull & Associates, Inc. (Hull) hereby submits a summary of the results from the April 2019 semi-annual site-wide groundwater sampling event, undertaken in support of the RI/FS at the Ottawa Township Flat Glass Site (Site). The groundwater monitoring wells and piezometers that were sampled during the April 2019 sampling event are included on Table 1 and Figure 1. Groundwater sampling procedures and laboratory results are summarized below:

1. Groundwater sampling was conducted from April 24 through April 26 at monitoring wells

and piezometers using low-flow techniques, with the exception of MW-5, which was sampled using a disposable bailer due to insufficient water volume for low-flow sampling. Where low-flow techniques were used, groundwater was extracted at a rate of approximately 100 to 400 milliliters per minute and the following field parameters were measured: pH, temperature, conductivity, oxidation-reduction (redox) potential, dissolved oxygen and turbidity. When field parameters stabilized per Hull’s Standard Operating Procedure (SOP), samples were collected in laboratory-prepared containers and immediately placed on ice in a cooler. The Village of Naplate Main and Auxiliary Production Well samples were collected through faucets or spigots at each wellhead, prior to any treatment being conducted. All samples were submitted to TestAmerica, Inc. under chain-of-custody for analyses described below.

2. Samples collected from the monitoring wells and piezometers were analyzed for total

arsenic using U.S. EPA Method 6020 and total dissolved solids (TDS). Field parameters and analytical results for monitoring wells are summarized in Table 1. The laboratory analytical results are located in Attachment A.

3. Water level measurements were collected at all groundwater monitoring wells prior to

sample collection activities. Water levels are summarized on Table 2. Water levels could not be obtained from several monitoring wells located within OU4, including P-15, P-30, P-31 and MW-3, as the access road could not be traversed due to the presence of standing water.

Ms. Lauren Bumba PNA168.0016 May 24, 2019

A discussion of the analytical results associated with the Central Plume, originating from the Plaster Pit in Operable Unit 4 (OU4) follows:

1. Arsenic concentrations within the core area of the plume were 1,800 micrograms per liter (ug/L) at MW-6L, 760 ug/L at MW-14, 1,900 ug/L at P-23, and 530 ug/L at PZ-2 (duplicate result 630 ug/L).

2. The detected arsenic concentrations at MW-15 was 36 ug/L, which was substantially lower than the concentration detected during the September 2019 sampling event (1,200 ug/l) and more in line with historical observations which have ranged from 20.4 ug/L to 179 ug/L.

3. Arsenic was also detected in samples collected from monitoring wells MW-16 (260 ug/L),

P-22 (19 ug/L), the upper and middle wells of the MW-6 cluster (17 ug/L and 5.4 ug/L, respectively), and the middle and lower wells of the MW-18 cluster (6.3 ug/L and 14 ug/L, respectively).

4. Arsenic was not detected in samples collected from monitoring wells MW-18U or P-9. 5. TDS in groundwater samples ranged from 230 milligrams per liter (mg/L) at sample location

P-9 to 2,600 mg/L at MW-18M. 6. The concentration of arsenic in the leachate collected from piezometer HP-7 was 54,000

ug/L. The TDS concentration was 29,000 mg/L. 7. Arsenic was not detected in the parent or duplicate sample collected from the Village of

Naplate Main Well (reporting limit of 1 ug/L). The reported concentration of arsenic in the Village of Naplate Auxiliary Well was 1.4 ug/L

A discussion of the analytical results associated with the West Plume, originating from the Original Sand Pond in OU4 follows:

1. Detectable total arsenic concentrations in groundwater ranged from 53 ug/L at MW-4U to 2,000 ug/L at MW-2U. The detected concentration of 2,000 ug/L at MW-2U is substantively lower than the reported concentration of 23,000 ug/L in the October 2017 event and the concentration of 8,200 during the October 2018 events and falls within the historical range of detected concentrations of 440 ug/L to 6,540 ug/L.

2. Arsenic in leachate piezometer HP-5, which is located in the Original Sand Pond, was 16,000 ug/L.

3. TDS concentrations in groundwater ranged from 520 mg/L at sample location P-5 to 3,000 mg/L at MW-2U. The TDS concentration at leachate piezometer HP-5 was 16,000 mg/L.

4. P-30 was not sampled as the access road could not be safely traversed due to the presence

of standing water. A discussion of the analytical results associated with the South Plume, originating from Quarry 1 in Operable Unit 3 (OU3) follows:

Ms. Lauren Bumba PNA168.0016 May 22, 2019

HULL & ASSOCIATES, INC. MAY 2019 DUBLIN, OHIO PNA168.0016

1. A substantial number of the monitoring wells reported results as below the detection limit of

<5.0 ug/L, including samples collected from the upper and lower wells of the MW-11 and MW-12 clusters, MW-13L, MW-21, S-2, S-3, S-5, S-6R and S-8.

2. Arsenic was detected in samples collected from monitoring wells MW-11M (5.4 ug/L), MW-

12M (14 ug/L), the upper and middle wells of the MW-13 cluster (17 and 29 ug/L, respectively with a detection of 30 ug/L in the MW-13M duplicate), MW-20 (16 ug/L), MW-22 (310 ug/L), MW-23 (7.5 ug/L) and S-1 (130 ug/L).

3. TDS ranged from 530 mg/L at sample locations S-3 to 3,200 mg/L at S-8.

As discussed in previous correspondence, PNA will continue to sample the Village of Naplate wells for arsenic on a quarterly basis; the next quarterly sampling event is tentatively scheduled for June 2019. The next semi-annual Site-wide groundwater sampling event is tentatively scheduled for October 2019. If you have any questions, please contact me at (513) 460-8632.

Sincerely, W. Lance Turley Senior Consultant ct: Jim Lavrich, PNA Kent Purcell, PNA

AnnMarie Sanford, Pepper Hamilton Tom Wilczak, Pepper Hamilton David Richards, Hull

Hull Project File PNA168


TABLES

PILKINGTON NORTH AMERICA, INC.OTTAWA TOWNSHIP FLAT GLASS SUPERFUND SITE

TABLE 1

RESULTS OF THE APRIL 2019 GROUNDWATER SAMPLING EVENT

ArsenicTotal Dissolved

SolidsTemperature pH

Specific Conductance

ORP TurbidityDissolved Oxygen

ug/L mg/LoC s.u. uS/cm mV NTUs mg/L

HP-7 (leachate) 4/26/2019 PNA168:HP-7:G042619 54,000 29,000 11.5 11.36 14,700 -343 <1 0.54

MW-6L 4/24/2019 PNA168:MW-6L:G042419 1,800 1,100 14.7 7.59 1,420 -57 10 0.92MW-6M 4/24/2019 PNA168:MW-6M:G042419 5.4 1,100 14.7 7.04 1790 43 9 1.08MW-6U 4/24/2019 PNA168:MW-6U:G042419 17 470 15.0 7.29 848 -48 226 1.94MW-14 4/24/2019 PNA168:MW-14:G042419 760 870 13.8 7.88 1,470 -49 29 5.18MW-15 4/24/2019 PNA168:MW-15:G042419 36 610 13.6 8.70 902 -165 9 0.90MW-16 4/24/2019 PNA168:MW-16:G042419 260 1,000 16.3 7.49 1,470 -16 8 0.89MW-18L 4/24/2019 PNA168:MW-18L:G042419 14 1,300 15.2 7.52 2,130 -295 1 1.72MW18M 4/24/2019 PNA168:MW-18M:G042419 6.3 2,600 13.4 11.11 2,570 -299 8 5.26MW-18U 4/24/2019 PNA168:MW-18U:G042419 <5 600 13.0 8.53 947 -209 18 1.51

P-22 4/24/2019 PNA168:P-22:G042419 19 460 14.0 7.59 774 10 6 1.23P-23 4/24/2019 PNA168:P-23:G042419 1,900 860 13.6 7.74 1,440 -135 26 2.20P-9 4/26/2019 PNA168:P-9:G042619 <5 230 12.4 6.39 351 161 <1 8.61

PNA168:PZ-2:G042419 530 550PNA168:PZ-2:G042419A 630 570

HP-5 (leachate) 4/26/2019 PNA168:HP-5:G042619 16,000 7,30012.2 10.81 5,150 -261 3 1.73

MW-2U 4/24/2019 PNA168:MW-2U:G042419 2,000 3,000 12.3 3.48 4,100 482 >1,000 4.32MW-4U 4/24/2019 PNA168:MW-4U:G042419 53 710 13.0 6.94 1,060 -100 68 1.29MW-5 4/25/2019 PNA168:MW-5:G042519 150 950 13.1 6.91 1,280 -99 400 2.23

P-5 4/24/2019 PNA168:P-5:G042419 320 520 10.2 7.64 879 106 5 7.41P-30

MW-11L 4/25/2019 PNA168:MW-11L:G042519 <5 1,600 11.07 7.30 2,490 -53 9.2 0.52MW-11M 4/25/2019 PNA168:MW-11M:G042519 5.4 570 10.88 7.10 847 -80 7.7 0.21MW-11U 4/25/2019 PNA168:MW-11U:G042519 <5 600 11.15 7.20 927 157 259 6.31MW-12L 4/25/2019 PNA168:MW-12L:G042519 <5 760 14.41 8.60 1,080 -37 100 0.58MW-12M 4/25/2019 PNA168:MW-12M:G042519 14 750 13.77 7.50 964 103 108 0.77MW-12U 4/25/2019 PNA168:MW-12U:G042519 <5 670 11.73 6.30 1,000 76 151 1.95MW-13L 4/25/2019 PNA168:MW-13L:G042519 <5 610 11.6 7.81 970 -149 1 6.51

PNA168:MW-13M:G042519 29 540PNA168:MW-13M:G042519A 30 540

MW-13U 4/25/2019 PNA168:MW-13U:G042519 17 540 11.7 7.87 872 -179 4 0.88MW-20 4/25/2019 PNA168:MW-20:G042519 16 810 14.5 7.12 1,190 -81 2 1.72MW-21 4/25/2019 PNA168:MW-21:G042519 <5 570 16.0 7.20 1,080 75 >1,000 6.80MW-22 4/25/2019 PNA168:MW-22:G042519 310 2,600 13.3 8.52 3,200 -233 <1 1.59MW-23 4/26/2019 PNA168:MW-23:G042619 7.5 640 6.3 7.54 999 59 7 8.21

S-1 4/25/2019 PNA168:S-1:G042519 130 1,600 11.9 10.27 1,950 -191 1 6.86S-2 4/25/2019 PNA168:S-2:G042519 <5 1,800 13.90 7.92 2,510 75 3 9.40S-3 4/25/2019 PNA168:S-3:G042519 <5 530 12.8 6.46 852 118 56 9.12S-5 4/25/2019 PNA168:S-5:G042519 <5 620 10.0 7.62 1,030 34 1 10.57S-6R 4/25/2019 PNA168:S-6R:G042519 <5 960 9.92 6.60 1,260 265 31 8.53S-8 4/25/2019 PNA168:S-8:G042519 <5 3,200 17.8 7.53 3,840 -70 3 4.41

PNA168:VON-1:W042519 <1 NT

PNA168:VON-1:W042519A <1 NT

VON-2 4/25/2019 PNA168:VON-2:W042519 1.4 NT 13.2 7.46 838 -56 <1 4.41

P-25 4/25/2019 PNA168:P-25:G042519 <5 420 11.0 6.75 610 117 42 8.34

Notes:a. NT - Not Testedb. Duplicate sample

865 -162 6

Field Parameters

811 -37 36 0.82

Monitored Location

Sample Location

Sample Date Field Sample ID

Groundwater

NA

South

West

P-Z2

Central

VON-1 <1 4.51

MW-13M

4/24/2019

4/25/2019

Not sampled - Inaccessible

1.40

13.1

4/25/2019 14.0 7.34 908 -42.0

7.72

11.9 8.13

HULL & ASSOCIATES, INC.DUBLIN, OHIO 1 of 1

NOVEMBER 2018PNA168.0002.xlsx


FIGURE

HP-5

PZ-2

MW-5

MW-23

MW-22

MW-21MW-20

MW-6UMW-6MMW-6L

MW-4U

MW-2U

MW-16

MW-15MW-14

MW-18UMW-18M MW-18L

MW-13U

MW-13MMW-13L

MW-12U

MW-11UMW-11M

MW-11L

MW-12L

MW-12MS-8

S-5

S-3S-2

S-1

P-9

P-5

S-6R

P-32

P-30

P-25

P-23

P-22

Naplate Village Well

Ottawa Avenue Cemetery Well

Naplate Auxiliary Well

HP-7

HP-6

HP-3

HP-2

HP-1

HP-4

PZ-3

PZ-1

MW-8

MW-3

EX-1MW-9L

MW-7UMW-7M

MW-7L

MW-4L

MW-2L

MW-1UMW-1L

MW-9M

MW-17L

MW-17MMW-17U

S-7

S-4

P-8P-7

P-6

P-4

P-3

P-2

P-1

P-37

P-34

P-33

P-31

P-29P-28

P-27P-26

P-21

P-20P-19

P-18

P-17

P-15

P-13

P-24

P-12P-11

Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS User CommunityProduced using ArcGIS 10.5

PNA PropertyOrange Wells Part of September 2016 Sampling EventMunicipal / IndustrialHull Leachate PiezometerHull Monitoring PiezometerHull Monitoring Well or Nests (MW-)Monitoring Well (P-, S-)Abandoned WellDecommissioned Well

0 520 1,040260Feet

1:6,000

© 2018, Hull & Associates, Inc.

Edited: 5/24/2019 By: mopel

Figure

File Name: PNA168_02_Fig01_QtrSamp0419.mxd

Site-Wide GroundwaterSampling Results (April 2019)

Ottawa Township Flat Glass SiteQuarterly Sampling Report

Pilkington North America, Inc.Village of Naplate, La Salle County, Illinois

1May 2019DISCLAIMER

Hull & Associates, Inc. (Hull) has furnished this map tothe company identified in the title block (Client) for itssole and exclusive use as a preliminary planning andscreening tool and field verification is necessary toconfirm these data. This map is reproduced fromgeospatial information compiled from third-partysources which may change over time. Areas depictedby the map are approximate and may not be accurateto mapping, surveying or engineering standards. Hullmakes no representation or guarantee as to thecontent, accuracy, timeliness or completeness of anyinformation or spatial location depicted on this map.This map is provided without warranty of any kind,including but not limited to, the implied warranties ofmerchantability or fitness for a particular purpose. Inno event will Hull, its owners, officers, employees oragents, be liable for damages of any kind arising out ofthe use of this map by Client or any other party.

6397 Emerald PkwySuite 200Dublin, Ohio 43016

Phone: (614) 793-8777Fax: (614) 793-9070www.hullinc.com

MW-6M 4/24/2019Arsenic ug/L 5.4

MW-6U 4/24/2019Arsenic ug/L 17

MW18M 4/24/2019Arsenic ug/L 6.3

MW-18U 4/24/2019Arsenic ug/L <5

MW-11M 4/25/2019Arsenic ug/L 5.4


MW-12L 4/25/2019Arsenic ug/L <5

MW-12M 4/25/2019Arsenic ug/L 14


P-25 4/25/2019Arsenic ug/L <5


MW-18L 4/24/2019Arsenic ug/L 14

MW-22 4/25/2019Arsenic ug/L 310

S-5 4/25/2019Arsenic ug/L <5

S-6R 4/25/2019Arsenic ug/L <5



S-3 4/25/2019Arsenic ug/L <5

MW-21 4/25/2019Arsenic ug/L <5

S-8 4/25/2019Arsenic ug/L <5

S-2 4/25/2019Arsenic ug/L <5

MW-20 4/25/2019Arsenic ug/L 16

S-1 4/25/2019Arsenic ug/L 130

HP-7 (leachate) 4/26/2019

Arsenic (ug/L) 54,000

P-5 4/24/2019Arsenic ug/L 320


HP-5 (leachate) 4/26/2019

Arsenic ug/L 16,000

MW-2U 4/24/2019Arsenic ug/L 2,000

P-30 Not SampledArsenic ug/L Inaccessible


MW-16 4/24/2019Arsenic ug/L 260

P-23 4/24/2019Arsenic ug/L 1,900

P-22 4/24/2019Arsenic ug/L 19

P-9 4/26/2019Arsenic ug/L <5

MW-14 4/24/2019Arsenic ug/L 760


MW-6L 4/24/2019Arsenic ug/L 1,800

MW-23 4/26/2019Arsenic ug/L 7.5

MW-13M 4/25/2019Arsenic ug/L 29Arsenic ug/L 30

P-Z2 4/24/2019Arsenic ug/L 530Arsenic ug/L 630


ATTACHMENT A

Laboratory Analytical Report

ANALYTICAL REPORTEurofins TestAmerica, Chicago2417 Bond StreetUniversity Park, IL 60484Tel: (708)534-5200

Laboratory Job ID: 500-162329-1Client Project/Site: PNA Pilkington - Ottawa

For:Hull & Associates, Inc.6397 Emerald ParkwaySuite 200Dublin, Ohio 43016-2231

Attn: Ms. Monica Williamson

Authorized for release by:5/2/2019 12:26:34 PM

Opal Johnson, Project Manager II(330)[email protected]

The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced except in full,and with written approval from the laboratory. For questions please contact the Project Managerat the e-mail address or telephone number listed on this page.

This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

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https://secure.testamericainc.com/TotalAccess/login.aspx

http://www.testamericainc.com/services-we-offer/ask-the-expert

http://www.testamericainc.com

mailto:[email protected]

Table of Contents

Client: Hull & Associates, Inc.Project/Site: PNA Pilkington - Ottawa

Laboratory Job ID: 500-162329-1

Page 2 of 16Eurofins TestAmerica, Chicago

5/2/2019

Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

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Case NarrativeClient: Hull & Associates, Inc. Job ID: 500-162329-1Project/Site: PNA Pilkington - Ottawa

Job ID: 500-162329-1

Laboratory: Eurofins TestAmerica, Chicago

Narrative

CASE NARRATIVE

Client: Hull & Associates, Inc.

Project: PNA Pilkington - Ottawa

Report Number: 500-162329-1

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of

the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

Eurofins TestAmerica, Chicago attests to the validity of the laboratory data generated by Eurofins TestAmerica facilities reported herein. All analyses performed by Eurofins TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures

described in the application methods. Eurofins TestAmerica’s operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written

approval of the laboratory.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the

individual sections below.

This laboratory report is confidential and is intended for the sole use of Eurofins TestAmerica and its client.

RECEIPT

The samples were received on 4/26/2019 11:55 AM; the samples arrived in good condition, properly preserved and, where required, on ice. The temperature of the cooler at receipt was 2.3º C.

TOTAL RECOVERABLE METALS (ICPMS)Samples PNA168:VON-1:W042519 (500-162329-1), PNA168:VON-1:W042519A (500-162329-2) and PNA168:VON-2:W042519

(500-162329-3) were analyzed for total recoverable metals (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 04/30/2019 and analyzed on 05/01/2019.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

Eurofins TestAmerica, ChicagoPage 3 of 16 5/2/2019

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Detection SummaryJob ID: 500-162329-1Client: Hull & Associates, Inc.

Project/Site: PNA Pilkington - Ottawa

Client Sample ID: PNA168:VON-1:W042519 Lab Sample ID: 500-162329-1

No Detections.

Client Sample ID: PNA168:VON-1:W042519A Lab Sample ID: 500-162329-2

No Detections.

Client Sample ID: PNA168:VON-2:W042519 Lab Sample ID: 500-162329-3

Arsenic

RL

1.0 ug/L

MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type

Total

Recoverable

11.4 6020A

Eurofins TestAmerica, Chicago

This Detection Summary does not include radiochemical test results.

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Method SummaryJob ID: 500-162329-1Client: Hull & Associates, Inc.


Method Method Description LaboratoryProtocol

SW8466020A Metals (ICP/MS) TAL CHI

SW8463005A Preparation, Total Recoverable or Dissolved Metals TAL CHI

Protocol References:

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

TAL CHI = Eurofins TestAmerica, Chicago, 2417 Bond Street, University Park, IL 60484, TEL (708)534-5200


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Sample SummaryJob ID: 500-162329-1Client: Hull & Associates, Inc.


Lab Sample ID Client Sample ID ReceivedCollectedMatrix

500-162329-1 PNA168:VON-1:W042519 Water 04/25/19 09:30 04/26/19 11:55

500-162329-2 PNA168:VON-1:W042519A Water 04/25/19 09:30 04/26/19 11:55

500-162329-3 PNA168:VON-2:W042519 Water 04/25/19 09:45 04/26/19 11:55


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Client Sample ResultsJob ID: 500-162329-1Client: Hull & Associates, Inc.


Lab Sample ID: 500-162329-1Client Sample ID: PNA168:VON-1:W042519Matrix: WaterDate Collected: 04/25/19 09:30

Date Received: 04/26/19 11:55

Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL

Arsenic <1.0 1.0 ug/L 04/30/19 08:11 05/01/19 20:49 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier


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Lab Sample ID: 500-162329-2Client Sample ID: PNA168:VON-1:W042519AMatrix: WaterDate Collected: 04/25/19 09:30



Arsenic <1.0 1.0 ug/L 04/30/19 08:11 05/01/19 20:52 1



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Lab Sample ID: 500-162329-3Client Sample ID: PNA168:VON-2:W042519Matrix: WaterDate Collected: 04/25/19 09:45



Arsenic 1.4 1.0 ug/L 04/30/19 08:11 05/01/19 20:56 1



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Definitions/GlossaryJob ID: 500-162329-1Client: Hull & Associates, Inc.


GlossaryThese commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CNF Contains No Free Liquid

DER Duplicate Error Ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL Detection Limit (DoD/DOE)

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision Level Concentration (Radiochemistry)

EDL Estimated Detection Limit (Dioxin)

LOD Limit of Detection (DoD/DOE)

LOQ Limit of Quantitation (DoD/DOE)

MDA Minimum Detectable Activity (Radiochemistry)

MDC Minimum Detectable Concentration (Radiochemistry)

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not Detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative Error Ratio (Radiochemistry)

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)


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QC Association SummaryJob ID: 500-162329-1Client: Hull & Associates, Inc.


Metals

Prep Batch: 482789

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Water 3005A500-162329-1 PNA168:VON-1:W042519 Total Recoverable

Water 3005A500-162329-2 PNA168:VON-1:W042519A Total Recoverable

Water 3005A500-162329-3 PNA168:VON-2:W042519 Total Recoverable

Water 3005AMB 500-482789/1-A Method Blank Total Recoverable

Water 3005ALCS 500-482789/2-A Lab Control Sample Total Recoverable

Analysis Batch: 483261


Water 6020A 482789500-162329-1 PNA168:VON-1:W042519 Total Recoverable

Water 6020A 482789500-162329-2 PNA168:VON-1:W042519A Total Recoverable

Water 6020A 482789500-162329-3 PNA168:VON-2:W042519 Total Recoverable

Water 6020A 482789MB 500-482789/1-A Method Blank Total Recoverable

Water 6020A 482789LCS 500-482789/2-A Lab Control Sample Total Recoverable


Page 11 of 16 5/2/2019

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QC Sample ResultsJob ID: 500-162329-1Client: Hull & Associates, Inc.


Method: 6020A - Metals (ICP/MS)

Client Sample ID: Method BlankLab Sample ID: MB 500-482789/1-AMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483261 Prep Batch: 482789

RL MDL

Arsenic <1.0 1.0 ug/L 04/30/19 08:11 05/01/19 19:30 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

Client Sample ID: Lab Control SampleLab Sample ID: LCS 500-482789/2-AMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483261 Prep Batch: 482789

Arsenic 100 102 ug/L 102 80 - 120

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits


Page 12 of 16 5/2/2019

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Lab ChronicleClient: Hull & Associates, Inc. Job ID: 500-162329-1Project/Site: PNA Pilkington - Ottawa

Client Sample ID: PNA168:VON-1:W042519 Lab Sample ID: 500-162329-1Matrix: WaterDate Collected: 04/25/19 09:30


Prep 3005A 04/30/19 08:11 SAH482789 TAL CHI

Type

Batch Batch

MethodPrep Type LabAnalystRun

Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable

Analysis 6020A 1 483261 05/01/19 20:49 FXG TAL CHITotal Recoverable

Client Sample ID: PNA168:VON-1:W042519A Lab Sample ID: 500-162329-2Matrix: WaterDate Collected: 04/25/19 09:30


Prep 3005A 04/30/19 08:11 SAH482789 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable


Client Sample ID: PNA168:VON-2:W042519 Lab Sample ID: 500-162329-3Matrix: WaterDate Collected: 04/25/19 09:45


Prep 3005A 04/30/19 08:11 SAH482789 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Page 13 of 16 5/2/2019

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Accreditation/Certification SummaryClient: Hull & Associates, Inc. Job ID: 500-162329-1Project/Site: PNA Pilkington - Ottawa

Laboratory: Eurofins TestAmerica, ChicagoAll accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.

Authority Program EPA Region Identification Number Expiration Date

California 29039State Program 04-30-19 *

Georgia State Program 4 N/A 04-30-19 *

Georgia State Program 4 939 04-30-19 *

Hawaii State Program 9 N/A 04-30-19 *

Illinois NELAP 5 100201 04-30-19 *

Indiana State Program 5 C-IL-02 04-30-19 *

Iowa State Program 7 82 05-01-20

Kansas NELAP 7 E-10161 10-31-19

Kentucky (UST) State Program 4 66 04-30-19 *

Kentucky (WW) State Program 4 KY90023 12-31-19

Louisiana NELAP 6 30720 06-30-19

Mississippi State Program 4 N/A 04-30-19 *

New York NELAP 2 12019 04-01-20

North Carolina (WW/SW) State Program 4 291 12-31-19

North Dakota State Program 8 R-194 04-30-19 *

Oklahoma State Program 6 8908 08-31-19

South Carolina State Program 4 77001 04-30-19 *

Wisconsin State Program 5 999580010 08-31-19

Wyoming State Program 8 8TMS-Q 04-30-19 *

Laboratory: Eurofins TestAmerica, CantonAll accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.


California 29279State Program 02-23-20

Connecticut State Program 1 PH-0590 12-31-19

Florida NELAP 4 E87225 06-30-19

Illinois NELAP 5 200004 07-31-19

Kansas NELAP 7 E-10336 04-30-19 *

Kentucky (UST) State Program 4 58 02-23-20

Kentucky (WW) State Program 4 98016 12-31-19

Minnesota NELAP 5 039-999-348 12-31-19 *

Minnesota (Petrofund) State Program 1 3506 07-31-19

Nevada State Program 9 OH00048 07-31-19

New Jersey NELAP 2 OH001 06-30-19

New York NELAP 2 10975 03-31-20

Ohio VAP State Program 5 CL0024 09-06-19

Oregon NELAP 10 4062 02-23-20

Pennsylvania NELAP 3 68-00340 08-31-19 *

Texas NELAP 6 T104704517-18-10 08-31-19

USDA Federal P330-16-00404 12-28-19

Virginia NELAP 3 460175 09-14-19

Washington State Program 10 C971 01-12-20 *

West Virginia DEP State Program 3 210 12-31-19


* Accreditation/Certification renewal pending - accreditation/certification considered valid.

Page 14 of 16 5/2/2019

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of 16 5/2/2019

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Login Sample Receipt Checklist

Client: Hull & Associates, Inc. Job Number: 500-162329-1

Login Number: 162329

Question Answer Comment

Creator: Scott, Sherri L

List Source: Eurofins TestAmerica, Chicago

List Number: 1

TrueRadioactivity wasn't checked or is </= background as measured by a survey meter.

TrueThe cooler's custody seal, if present, is intact.

TrueSample custody seals, if present, are intact.

TrueThe cooler or samples do not appear to have been compromised or tampered with.

TrueSamples were received on ice.

TrueCooler Temperature is acceptable.

TrueCooler Temperature is recorded. 2.3

TrueCOC is present.

TrueCOC is filled out in ink and legible.

TrueCOC is filled out with all pertinent information.

TrueIs the Field Sampler's name present on COC?

TrueThere are no discrepancies between the containers received and the COC.

TrueSamples are received within Holding Time (excluding tests with immediate HTs)

TrueSample containers have legible labels.

TrueContainers are not broken or leaking.

TrueSample collection date/times are provided.

TrueAppropriate sample containers are used.

TrueSample bottles are completely filled.

TrueSample Preservation Verified.

TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs

N/AContainers requiring zero headspace have no headspace or bubble is <6mm (1/4").

TrueMultiphasic samples are not present.

TrueSamples do not require splitting or compositing.

N/AResidual Chlorine Checked.


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ANALYTICAL REPORTEurofins TestAmerica, Chicago2417 Bond StreetUniversity Park, IL 60484Tel: (708)534-5200

Laboratory Job ID: 500-162331-1Client Project/Site: PNA Pilkington - Ottawa

For:Hull & Associates, Inc.6397 Emerald ParkwaySuite 200Dublin, Ohio 43016-2231

Attn: Ms. Monica Williamson

Authorized for release by:5/9/2019 8:58:11 AM

Opal Johnson, Project Manager II(330)[email protected]

The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced except in full,and with written approval from the laboratory. For questions please contact the Project Managerat the e-mail address or telephone number listed on this page.

This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

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https://secure.testamericainc.com/TotalAccess/login.aspx

http://www.testamericainc.com/services-we-offer/ask-the-expert

http://www.testamericainc.com

mailto:[email protected]

Table of Contents

Client: Hull & Associates, Inc.Project/Site: PNA Pilkington - Ottawa

Laboratory Job ID: 500-162331-1

Page 2 of 79Eurofins TestAmerica, Chicago

5/9/2019

Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56

QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57

QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61

Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65

Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74

Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75

Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79

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Job ID: 500-162331-1

Laboratory: Eurofins TestAmerica, Chicago

Narrative

CASE NARRATIVE

Client: Hull & Associates, Inc.

Project: PNA Pilkington - Ottawa

Report Number: 500-162331-1

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of

the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

Eurofins TestAmerica, Chicago attests to the validity of the laboratory data generated by Eurofins TestAmerica facilities reported herein. All analyses performed by Eurofins TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures

described in the application methods. Eurofins TestAmerica’s operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written

approval of the laboratory.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the

individual sections below.

This laboratory report is confidential and is intended for the sole use of Eurofins TestAmerica and its client.

RECEIPT

The samples were received on 4/26/2019 11:55 AM; the samples arrived in good condition, properly preserved and, where required, on ice. The temperatures of the 3 coolers at receipt time were 2.3º C, 3.3º C and 3.6º C.

Receipt Exceptions

Received both bottles for samples 18-20 with date of 042519 and it's in the sample ID. COC has 4/24/19, logged in as 4/25/19. Received both bottles for sample 23 with ID of MW-5, logged per COC.

TOTAL RECOVERABLE METALS (ICPMS)Samples PNA168:P-23:G042419 (500-162331-1), PNA168:P-22:G042419 (500-162331-2), PNA168:P-5:G042419 (500-162331-3),

PNA168:MW-2U:G042419 (500-162331-4), PNA168:MW-4U:G042419 (500-162331-5), PNA168:MW-16:G042419 (500-162331-6), PNA168:MW-6L:G042419 (500-162331-7), PNA168:MW-6M:G042419 (500-162331-8), PNA168:MW-6U:G042419 (500-162331-9),

PNA168:MW-18L:G042419 (500-162331-10), PNA168:MW-18M:G042419 (500-162331-11), PNA168:MW-18U:G042419 (500-162331-12),

PNA168:MW-15:G042419 (500-162331-13), PNA168:MW-14:G042419 (500-162331-14), PNA168:FB-1:G042419 (500-162331-15), PNA168:PZ-2:G042419 (500-162331-16), PNA168:PZ-2:G042419A (500-162331-17), PNA168:MW-13M:G042519 (500-162331-18),

PNA168:MW-13L:G042519 (500-162331-19), PNA168:MW-13U:G042519 (500-162331-20), PNA168:MW-13M:G042519A

(500-162331-21), PNA168:S-5:G042519 (500-162331-22), PNA168:MW-5:G042519 (500-162331-23), PNA168:MW-21:G042519 (500-162331-24), PNA168:MW-22:G042519 (500-162331-25), PNA168:S-1:G042519 (500-162331-26), PNA168:S-2:G042519

(500-162331-27), PNA168:S-8:G042519 (500-162331-28), PNA168:MW-20:G042519 (500-162331-29), PNA168:S-3:G042519 (500-162331-30), PNA168:P-25:G042519 (500-162331-31), PNA168:P-9:G042619 (500-162331-32), PNA168:HP-5:G042619


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Job ID: 500-162331-1 (Continued)

Laboratory: Eurofins TestAmerica, Chicago (Continued)

(500-162331-33), PNA168:HP-7:G042619 (500-162331-34), PNA168:MW-23:G042619 (500-162331-35), PNA168:S-6R:G042519

(500-162331-36), PNA168:MW-12U:G042519 (500-162331-37), PNA168:MW-12M:G042519 (500-162331-38), PNA168:MW-12L:G042519 (500-162331-39), PNA168:MW-11U:G042519 (500-162331-40), PNA168:MW-11M:G042519 (500-162331-41), PNA168:MW-11L:G042519

(500-162331-42), PNA168:FB-2:G042519 (500-162331-43) and PNA168:FB-3:G042619 (500-162331-44) were analyzed for total

recoverable metals (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 04/30/2019 and analyzed on 05/02/2019, 05/03/2019 and 05/08/2019.

Samples PNA168:HP-5:G042619 (500-162331-33)[20X] and PNA168:HP-7:G042619 (500-162331-34)[20X] required dilution prior to

analysis. The reporting limits have been adjusted accordingly.

Arsenic failed the recovery criteria high for the MS and the MSD of sample PNA168:P-23:G042419MSD (500-162331-1) in batch

500-484297.

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

TOTAL DISSOLVED SOLIDSSamples PNA168:P-23:G042419 (500-162331-1), PNA168:P-22:G042419 (500-162331-2), PNA168:P-5:G042419 (500-162331-3),

PNA168:MW-2U:G042419 (500-162331-4), PNA168:MW-4U:G042419 (500-162331-5), PNA168:MW-16:G042419 (500-162331-6), PNA168:MW-6L:G042419 (500-162331-7), PNA168:MW-6M:G042419 (500-162331-8), PNA168:MW-6U:G042419 (500-162331-9), PNA168:MW-18L:G042419 (500-162331-10), PNA168:MW-18M:G042419 (500-162331-11), PNA168:MW-18U:G042419 (500-162331-12), PNA168:MW-15:G042419 (500-162331-13), PNA168:MW-14:G042419 (500-162331-14), PNA168:FB-1:G042419 (500-162331-15), PNA168:PZ-2:G042419 (500-162331-16), PNA168:PZ-2:G042419A (500-162331-17), PNA168:MW-13M:G042519 (500-162331-18),

PNA168:MW-13L:G042519 (500-162331-19), PNA168:MW-13U:G042519 (500-162331-20), PNA168:MW-13M:G042519A (500-162331-21), PNA168:S-5:G042519 (500-162331-22), PNA168:MW-5:G042519 (500-162331-23), PNA168:MW-21:G042519 (500-162331-24), PNA168:MW-22:G042519 (500-162331-25), PNA168:S-1:G042519 (500-162331-26), PNA168:S-2:G042519 (500-162331-27), PNA168:S-8:G042519 (500-162331-28), PNA168:MW-20:G042519 (500-162331-29), PNA168:S-3:G042519 (500-162331-30), PNA168:P-25:G042519 (500-162331-31), PNA168:P-9:G042619 (500-162331-32), PNA168:HP-5:G042619

(500-162331-33), PNA168:HP-7:G042619 (500-162331-34), PNA168:MW-23:G042619 (500-162331-35), PNA168:S-6R:G042519 (500-162331-36), PNA168:MW-12U:G042519 (500-162331-37), PNA168:MW-12M:G042519 (500-162331-38), PNA168:MW-12L:G042519 (500-162331-39), PNA168:MW-11U:G042519 (500-162331-40), PNA168:MW-11M:G042519 (500-162331-41), PNA168:MW-11L:G042519 (500-162331-42), PNA168:FB-2:G042519 (500-162331-43) and PNA168:FB-3:G042619 (500-162331-44) were analyzed for total dissolved solids in accordance with SM 2540C. The samples were analyzed on 04/27/2019, 04/29/2019, 04/30/2019 and 05/01/2019.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.


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Client Sample ID: PNA168:P-23:G042419 Lab Sample ID: 500-162331-1

Arsenic

RL

5.0 ug/L


Total

Recoverable

11900 6020A

Total Dissolved Solids 10 mg/L Total/NA1860 SM 2540C


Arsenic

RL

5.0 ug/L


Total

Recoverable

119 6020A



Arsenic

RL

5.0 ug/L


Total

Recoverable

1320 6020A


Client Sample ID: PNA168:MW-2U:G042419 Lab Sample ID: 500-162331-4

Arsenic

RL

5.0 ug/L


Total

Recoverable

12000 6020A



Arsenic

RL

5.0 ug/L


Total

Recoverable

153 6020A


Client Sample ID: PNA168:MW-16:G042419 Lab Sample ID: 500-162331-6

Arsenic

RL

5.0 ug/L


Total

Recoverable

1260 6020A


Client Sample ID: PNA168:MW-6L:G042419 Lab Sample ID: 500-162331-7

Arsenic

RL

5.0 ug/L


Total

Recoverable

11800 6020A


Client Sample ID: PNA168:MW-6M:G042419 Lab Sample ID: 500-162331-8

Arsenic

RL

5.0 ug/L


Total

Recoverable

15.4 6020A




Page 5 of 79 5/9/2019

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Arsenic

RL

5.0 ug/L


Total

Recoverable

117 6020A



Arsenic

RL

5.0 ug/L


Total

Recoverable

114 6020A



Arsenic

RL

5.0 ug/L


Total

Recoverable

16.3 6020A



Total Dissolved Solids

RL

10 mg/L


Total/NA1600 SM 2540C


Arsenic

RL

5.0 ug/L


Total

Recoverable

136 6020A



Arsenic

RL

5.0 ug/L


Total

Recoverable

1760 6020A


Client Sample ID: PNA168:FB-1:G042419 Lab Sample ID: 500-162331-15


RL

10 mg/L



Client Sample ID: PNA168:PZ-2:G042419 Lab Sample ID: 500-162331-16

Arsenic

RL

5.0 ug/L


Total

Recoverable

1530 6020A


Client Sample ID: PNA168:PZ-2:G042419A Lab Sample ID: 500-162331-17

Arsenic

RL

5.0 ug/L


Total

Recoverable

1630 6020A




Page 6 of 79 5/9/2019

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Arsenic

RL

5.0 ug/L


Total

Recoverable

129 6020A




RL

10 mg/L




Arsenic

RL

5.0 ug/L


Total

Recoverable

117 6020A


Client Sample ID: PNA168:MW-13M:G042519A Lab Sample ID: 500-162331-21

Arsenic

RL

5.0 ug/L


Total

Recoverable

130 6020A


Client Sample ID: PNA168:S-5:G042519 Lab Sample ID: 500-162331-22


RL

10 mg/L




Arsenic

RL

5.0 ug/L


Total

Recoverable

1150 6020A




RL

10 mg/L




Arsenic

RL

5.0 ug/L


Total

Recoverable

1310 6020A



Arsenic

RL

5.0 ug/L


Total

Recoverable

1130 6020A




Page 7 of 79 5/9/2019

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RL

10 mg/L





RL

10 mg/L




Arsenic

RL

5.0 ug/L


Total

Recoverable

116 6020A




RL

10 mg/L





RL

10 mg/L





RL

10 mg/L



Client Sample ID: PNA168:HP-5:G042619 Lab Sample ID: 500-162331-33

Arsenic

RL

5.0 ug/L


Total

Recoverable

2016000 6020A


Client Sample ID: PNA168:HP-7:G042619 Lab Sample ID: 500-162331-34

Arsenic

RL

5.0 ug/L


Total

Recoverable

2054000 6020A



Arsenic

RL

5.0 ug/L


Total

Recoverable

17.5 6020A


Client Sample ID: PNA168:S-6R:G042519 Lab Sample ID: 500-162331-36


RL

10 mg/L





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RL

10 mg/L




Arsenic

RL

5.0 ug/L


Total

Recoverable

114 6020A




RL

10 mg/L





RL

10 mg/L




Arsenic

RL

5.0 ug/L


Total

Recoverable

15.4 6020A




RL

10 mg/L





RL

10 mg/L





RL

10 mg/L





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Method SummaryJob ID: 500-162331-1Client: Hull & Associates, Inc.


Method Method Description LaboratoryProtocol

SW8466020A Metals (ICP/MS) TAL CHI

SMSM 2540C Solids, Total Dissolved (TDS) TAL CHI

SW8463005A Preparation, Total Recoverable or Dissolved Metals TAL CHI

Protocol References:

SM = "Standard Methods For The Examination Of Water And Wastewater"

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.




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Sample SummaryJob ID: 500-162331-1Client: Hull & Associates, Inc.


Lab Sample ID Client Sample ID ReceivedCollectedMatrix

500-162331-1 PNA168:P-23:G042419 Water 04/24/19 08:28 04/26/19 11:55

500-162331-2 PNA168:P-22:G042419 Water 04/24/19 08:56 04/26/19 11:55

500-162331-3 PNA168:P-5:G042419 Water 04/24/19 09:25 04/26/19 11:55

500-162331-4 PNA168:MW-2U:G042419 Water 04/24/19 10:02 04/26/19 11:55

500-162331-5 PNA168:MW-4U:G042419 Water 04/24/19 10:34 04/26/19 11:55

500-162331-6 PNA168:MW-16:G042419 Water 04/24/19 11:15 04/26/19 11:55

500-162331-7 PNA168:MW-6L:G042419 Water 04/24/19 11:54 04/26/19 11:55

500-162331-8 PNA168:MW-6M:G042419 Water 04/24/19 12:20 04/26/19 11:55

500-162331-9 PNA168:MW-6U:G042419 Water 04/24/19 12:51 04/26/19 11:55

500-162331-10 PNA168:MW-18L:G042419 Water 04/24/19 13:29 04/26/19 11:55

500-162331-11 PNA168:MW-18M:G042419 Water 04/24/19 13:58 04/26/19 11:55

500-162331-12 PNA168:MW-18U:G042419 Water 04/24/19 14:27 04/26/19 11:55

500-162331-13 PNA168:MW-15:G042419 Water 04/24/19 15:01 04/26/19 11:55

500-162331-14 PNA168:MW-14:G042419 Water 04/24/19 15:35 04/26/19 11:55

500-162331-15 PNA168:FB-1:G042419 Water 04/24/19 12:35 04/26/19 11:55

500-162331-16 PNA168:PZ-2:G042419 Water 04/24/19 16:15 04/26/19 11:55

500-162331-17 PNA168:PZ-2:G042419A Water 04/24/19 16:15 04/26/19 11:55

500-162331-18 PNA168:MW-13M:G042519 Water 04/25/19 05:44 04/26/19 11:55

500-162331-19 PNA168:MW-13L:G042519 Water 04/25/19 06:12 04/26/19 11:55

500-162331-20 PNA168:MW-13U:G042519 Water 04/25/19 06:37 04/26/19 11:55

500-162331-21 PNA168:MW-13M:G042519A Water 04/25/19 05:44 04/26/19 11:55

500-162331-22 PNA168:S-5:G042519 Water 04/25/19 07:10 04/26/19 11:55

500-162331-23 PNA168:MW-5:G042519 Water 04/25/19 11:00 04/26/19 11:55

500-162331-24 PNA168:MW-21:G042519 Water 04/25/19 12:35 04/26/19 11:55

500-162331-25 PNA168:MW-22:G042519 Water 04/25/19 13:19 04/26/19 11:55

500-162331-26 PNA168:S-1:G042519 Water 04/25/19 13:48 04/26/19 11:55

500-162331-27 PNA168:S-2:G042519 Water 04/25/19 14:23 04/26/19 11:55

500-162331-28 PNA168:S-8:G042519 Water 04/25/19 14:49 04/26/19 11:55

500-162331-29 PNA168:MW-20:G042519 Water 04/25/19 15:24 04/26/19 11:55

500-162331-30 PNA168:S-3:G042519 Water 04/25/19 15:55 04/26/19 11:55

500-162331-31 PNA168:P-25:G042519 Water 04/25/19 16:35 04/26/19 11:55

500-162331-32 PNA168:P-9:G042619 Water 04/26/19 06:13 04/26/19 11:55

500-162331-33 PNA168:HP-5:G042619 Water 04/26/19 06:50 04/26/19 11:55

500-162331-34 PNA168:HP-7:G042619 Water 04/26/19 07:22 04/26/19 11:55

500-162331-35 PNA168:MW-23:G042619 Water 04/26/19 08:11 04/26/19 11:55

500-162331-36 PNA168:S-6R:G042519 Water 04/25/19 08:35 04/26/19 11:55

500-162331-37 PNA168:MW-12U:G042519 Water 04/25/19 10:28 04/26/19 11:55

500-162331-38 PNA168:MW-12M:G042519 Water 04/25/19 11:31 04/26/19 11:55

500-162331-39 PNA168:MW-12L:G042519 Water 04/25/19 13:35 04/26/19 11:55

500-162331-40 PNA168:MW-11U:G042519 Water 04/25/19 15:46 04/26/19 11:55

500-162331-41 PNA168:MW-11M:G042519 Water 04/25/19 16:50 04/26/19 11:55

500-162331-42 PNA168:MW-11L:G042519 Water 04/25/19 17:46 04/26/19 11:55

500-162331-43 PNA168:FB-2:G042519 Water 04/25/19 17:40 04/26/19 11:55

500-162331-44 PNA168:FB-3:G042619 Water 04/26/19 07:10 04/26/19 11:55


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Lab Sample ID: 500-162331-1Client Sample ID: PNA168:P-23:G042419Matrix: WaterDate Collected: 04/24/19 08:28



Arsenic 1900 5.0 ug/L 04/30/19 16:04 05/08/19 11:58 1


General ChemistryRL MDL

Total Dissolved Solids 860 10 mg/L 04/27/19 02:28 1



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Arsenic 19 5.0 ug/L 04/30/19 16:04 05/08/19 12:06 1






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Arsenic 320 5.0 ug/L 04/30/19 16:04 05/08/19 12:08 1






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Lab Sample ID: 500-162331-4Client Sample ID: PNA168:MW-2U:G042419Matrix: WaterDate Collected: 04/24/19 10:02



Arsenic 2000 5.0 ug/L 04/30/19 16:04 05/08/19 12:10 1






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Arsenic 53 5.0 ug/L 04/30/19 16:04 05/08/19 12:20 1






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Lab Sample ID: 500-162331-6Client Sample ID: PNA168:MW-16:G042419Matrix: WaterDate Collected: 04/24/19 11:15



Arsenic 260 5.0 ug/L 04/30/19 16:04 05/08/19 12:22 1






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Lab Sample ID: 500-162331-7Client Sample ID: PNA168:MW-6L:G042419Matrix: WaterDate Collected: 04/24/19 11:54



Arsenic 1800 5.0 ug/L 04/30/19 16:04 05/08/19 12:24 1






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Lab Sample ID: 500-162331-8Client Sample ID: PNA168:MW-6M:G042419Matrix: WaterDate Collected: 04/24/19 12:20



Arsenic 5.4 5.0 ug/L 04/30/19 16:04 05/08/19 12:26 1






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Arsenic 17 5.0 ug/L 04/30/19 16:04 05/08/19 12:27 1






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Arsenic 14 5.0 ug/L 04/30/19 16:04 05/08/19 12:29 1






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Arsenic 6.3 5.0 ug/L 04/30/19 16:04 05/08/19 12:31 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:04 05/08/19 12:36 1






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Arsenic 36 5.0 ug/L 04/30/19 16:04 05/08/19 12:38 1






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Arsenic 760 5.0 ug/L 04/30/19 16:04 05/08/19 12:39 1






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Lab Sample ID: 500-162331-15Client Sample ID: PNA168:FB-1:G042419Matrix: WaterDate Collected: 04/24/19 12:35



Arsenic <5.0 5.0 ug/L 04/30/19 16:04 05/08/19 12:41 1






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Lab Sample ID: 500-162331-16Client Sample ID: PNA168:PZ-2:G042419Matrix: WaterDate Collected: 04/24/19 16:15



Arsenic 530 5.0 ug/L 04/30/19 16:04 05/08/19 12:43 1






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Lab Sample ID: 500-162331-17Client Sample ID: PNA168:PZ-2:G042419AMatrix: WaterDate Collected: 04/24/19 16:15



Arsenic 630 5.0 ug/L 04/30/19 16:04 05/08/19 12:45 1






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Arsenic 29 5.0 ug/L 04/30/19 16:04 05/08/19 12:46 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:04 05/08/19 12:48 1






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Arsenic 17 5.0 ug/L 04/30/19 16:04 05/08/19 12:50 1






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Lab Sample ID: 500-162331-21Client Sample ID: PNA168:MW-13M:G042519AMatrix: WaterDate Collected: 04/25/19 05:44



Arsenic 30 5.0 ug/L 04/30/19 16:06 05/03/19 02:49 1






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Lab Sample ID: 500-162331-22Client Sample ID: PNA168:S-5:G042519Matrix: WaterDate Collected: 04/25/19 07:10



Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/03/19 03:08 1






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Arsenic 150 5.0 ug/L 04/30/19 16:06 05/03/19 03:12 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/03/19 03:16 1






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Arsenic 310 5.0 ug/L 04/30/19 16:06 05/08/19 12:57 1






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Arsenic 130 5.0 ug/L 04/30/19 16:06 05/08/19 13:06 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:08 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:10 1






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Arsenic 16 5.0 ug/L 04/30/19 16:06 05/08/19 13:11 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:13 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:18 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:20 1






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Lab Sample ID: 500-162331-33Client Sample ID: PNA168:HP-5:G042619Matrix: WaterDate Collected: 04/26/19 06:50



Arsenic 16000 5.0 ug/L 04/30/19 16:06 05/08/19 13:22 20






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Lab Sample ID: 500-162331-34Client Sample ID: PNA168:HP-7:G042619Matrix: WaterDate Collected: 04/26/19 07:22



Arsenic 54000 5.0 ug/L 04/30/19 16:06 05/08/19 13:24 20






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Arsenic 7.5 5.0 ug/L 04/30/19 16:06 05/08/19 13:25 1






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Lab Sample ID: 500-162331-36Client Sample ID: PNA168:S-6R:G042519Matrix: WaterDate Collected: 04/25/19 08:35



Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:27 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:29 1






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Arsenic 14 5.0 ug/L 04/30/19 16:06 05/08/19 13:31 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:32 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:34 1






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Arsenic 5.4 5.0 ug/L 04/30/19 16:07 05/02/19 19:25 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:07 05/02/19 19:29 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:07 05/02/19 19:32 1






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Arsenic <5.0 5.0 ug/L 04/30/19 16:07 05/02/19 19:36 1






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Definitions/GlossaryJob ID: 500-162331-1Client: Hull & Associates, Inc.


Qualifiers

MetalsQualifier Description

4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not

applicable.

Qualifier

GlossaryThese commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CNF Contains No Free Liquid

DER Duplicate Error Ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL Detection Limit (DoD/DOE)

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision Level Concentration (Radiochemistry)

EDL Estimated Detection Limit (Dioxin)

LOD Limit of Detection (DoD/DOE)

LOQ Limit of Quantitation (DoD/DOE)

MDA Minimum Detectable Activity (Radiochemistry)

MDC Minimum Detectable Concentration (Radiochemistry)

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not Detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative Error Ratio (Radiochemistry)

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)


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Metals

Prep Batch: 482913


Water 3005A500-162331-1 PNA168:P-23:G042419 Total Recoverable



Water 3005A500-162331-4 PNA168:MW-2U:G042419 Total Recoverable


Water 3005A500-162331-6 PNA168:MW-16:G042419 Total Recoverable

Water 3005A500-162331-7 PNA168:MW-6L:G042419 Total Recoverable

Water 3005A500-162331-8 PNA168:MW-6M:G042419 Total Recoverable







Water 3005A500-162331-15 PNA168:FB-1:G042419 Total Recoverable

Water 3005A500-162331-16 PNA168:PZ-2:G042419 Total Recoverable

Water 3005A500-162331-17 PNA168:PZ-2:G042419A Total Recoverable






Water 3005A500-162331-1 MS PNA168:P-23:G042419 Total Recoverable

Water 3005A500-162331-1 MSD PNA168:P-23:G042419 Total Recoverable

Water 3005A500-162331-1 DU PNA168:P-23:G042419 Total Recoverable

Prep Batch: 482914


Water 3005A500-162331-21 PNA168:MW-13M:G042519A Total Recoverable

Water 3005A500-162331-22 PNA168:S-5:G042519 Total Recoverable











Water 3005A500-162331-33 PNA168:HP-5:G042619 Total Recoverable

Water 3005A500-162331-34 PNA168:HP-7:G042619 Total Recoverable


Water 3005A500-162331-36 PNA168:S-6R:G042519 Total Recoverable







Water 3005A500-162331-21 MS PNA168:MW-13M:G042519A Total Recoverable


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Metals (Continued)

Prep Batch: 482914 (Continued)


Water 3005A500-162331-21 MSD PNA168:MW-13M:G042519A Total Recoverable

Water 3005A500-162331-21 DU PNA168:MW-13M:G042519A Total Recoverable

Prep Batch: 482915










Water 6020A 482914500-162331-21 PNA168:MW-13M:G042519A Total Recoverable

Water 6020A 482914500-162331-22 PNA168:S-5:G042519 Total Recoverable

Water 6020A 482914500-162331-23 PNA168:MW-5:G042519 Total Recoverable


Water 6020A 482915500-162331-41 PNA168:MW-11M:G042519 Total Recoverable

Water 6020A 482915500-162331-42 PNA168:MW-11L:G042519 Total Recoverable

Water 6020A 482915500-162331-43 PNA168:FB-2:G042519 Total Recoverable






Water 6020A 482914500-162331-21 MS PNA168:MW-13M:G042519A Total Recoverable

Water 6020A 482914500-162331-21 MSD PNA168:MW-13M:G042519A Total Recoverable

Water 6020A 482914500-162331-21 DU PNA168:MW-13M:G042519A Total Recoverable



Water 6020A 482913500-162331-1 PNA168:P-23:G042419 Total Recoverable



Water 6020A 482913500-162331-4 PNA168:MW-2U:G042419 Total Recoverable












Water 6020A 482913500-162331-16 PNA168:PZ-2:G042419 Total Recoverable

Water 6020A 482913500-162331-17 PNA168:PZ-2:G042419A Total Recoverable




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Metals (Continued)

Analysis Batch: 484297 (Continued)











Water 6020A 482914500-162331-33 PNA168:HP-5:G042619 Total Recoverable

Water 6020A 482914500-162331-34 PNA168:HP-7:G042619 Total Recoverable


Water 6020A 482914500-162331-36 PNA168:S-6R:G042519 Total Recoverable







Water 6020A 482913500-162331-1 MS PNA168:P-23:G042419 Total Recoverable

Water 6020A 482913500-162331-1 MSD PNA168:P-23:G042419 Total Recoverable

Water 6020A 482913500-162331-1 DU PNA168:P-23:G042419 Total Recoverable

General Chemistry



Water SM 2540C500-162331-1 PNA168:P-23:G042419 Total/NA


Water SM 2540CMB 500-482507/1 Method Blank Total/NA

Water SM 2540CLCS 500-482507/2 Lab Control Sample Total/NA




Water SM 2540C500-162331-4 PNA168:MW-2U:G042419 Total/NA


Water SM 2540C500-162331-6 PNA168:MW-16:G042419 Total/NA

Water SM 2540C500-162331-7 PNA168:MW-6L:G042419 Total/NA

Water SM 2540C500-162331-8 PNA168:MW-6M:G042419 Total/NA







Water SM 2540C500-162331-15 PNA168:FB-1:G042419 Total/NA

Water SM 2540C500-162331-16 PNA168:PZ-2:G042419 Total/NA

Water SM 2540C500-162331-17 PNA168:PZ-2:G042419A Total/NA




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General Chemistry






Water SM 2540C500-162331-21 PNA168:MW-13M:G042519A Total/NA

Water SM 2540C500-162331-22 PNA168:S-5:G042519 Total/NA












Water SM 2540C500-162331-36 PNA168:S-6R:G042519 Total/NA



Water SM 2540C500-162331-18 MS PNA168:MW-13M:G042519 Total/NA

Water SM 2540C500-162331-18 DU PNA168:MW-13M:G042519 Total/NA

Water SM 2540C500-162331-19 DU PNA168:MW-13L:G042519 Total/NA















Water SM 2540C500-162331-33 PNA168:HP-5:G042619 Total/NA

Water SM 2540C500-162331-34 PNA168:HP-7:G042619 Total/NA




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RL MDL

Arsenic <5.0 5.0 ug/L 04/30/19 16:04 05/08/19 11:54 1

MB MB



Arsenic 100 93.2 ug/L 93 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Client Sample ID: PNA168:P-23:G042419Lab Sample ID: 500-162331-1 MSMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 484297 Prep Batch: 482913

Arsenic 1900 100 2070 4 ug/L 214 75 - 125

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: PNA168:P-23:G042419Lab Sample ID: 500-162331-1 MSDMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 484297 Prep Batch: 482913

Arsenic 1900 100 2070 4 ug/L 211 75 - 125 0 20

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Client Sample ID: PNA168:P-23:G042419Lab Sample ID: 500-162331-1 DUMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 484297 Prep Batch: 482913

Arsenic 1900 1870 ug/L 0.9 20

Analyte

DU DU

DUnitResult Qualifier

Sample

Result

Sample

Qualifier LimitRPD

RPD


RL MDL

Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/03/19 02:42 1

MB MB



Arsenic 100 95.9 ug/L 96 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Client Sample ID: PNA168:MW-13M:G042519ALab Sample ID: 500-162331-21 MSMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483476 Prep Batch: 482914

Arsenic 30 100 127 ug/L 97 75 - 125

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits


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Client Sample ID: PNA168:MW-13M:G042519ALab Sample ID: 500-162331-21 MSDMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483476 Prep Batch: 482914

Arsenic 30 100 126 ug/L 96 75 - 125 0 20

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Client Sample ID: PNA168:MW-13M:G042519ALab Sample ID: 500-162331-21 DUMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483476 Prep Batch: 482914

Arsenic 30 29.1 ug/L 3 20

Analyte

DU DU


Sample

Result

Sample

Qualifier LimitRPD

RPD


RL MDL

Arsenic <5.0 5.0 ug/L 04/30/19 16:07 05/02/19 19:17 1

MB MB



Arsenic 100 97.5 ug/L 97 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Method: SM 2540C - Solids, Total Dissolved (TDS)

Client Sample ID: Method BlankLab Sample ID: MB 500-482507/1Matrix: Water Prep Type: Total/NAAnalysis Batch: 482507

RL MDL

Total Dissolved Solids <10 10 mg/L 04/27/19 01:32 1

MB MB


Client Sample ID: Lab Control SampleLab Sample ID: LCS 500-482507/2Matrix: Water Prep Type: Total/NAAnalysis Batch: 482507

Total Dissolved Solids 250 298 mg/L 119 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits


RL MDL


MB MB



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Method: SM 2540C - Solids, Total Dissolved (TDS) (Continued)



Analyte

LCS LCS


Spike

Added

%Rec.

Limits


RL MDL


MB MB




Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Client Sample ID: PNA168:MW-13M:G042519Lab Sample ID: 500-162331-18 MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 482758

Total Dissolved Solids 540 250 824 mg/L 112 75 - 125

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: PNA168:MW-13M:G042519Lab Sample ID: 500-162331-18 DUMatrix: Water Prep Type: Total/NAAnalysis Batch: 482758

Total Dissolved Solids 540 546 mg/L 0.4 5

Analyte

DU DU


Sample

Result

Sample

Qualifier LimitRPD

RPD

Client Sample ID: PNA168:MW-13L:G042519Lab Sample ID: 500-162331-19 DUMatrix: Water Prep Type: Total/NAAnalysis Batch: 482758

Total Dissolved Solids 610 618 mg/L 2 5

Analyte

DU DU


Sample

Result

Sample

Qualifier LimitRPD

RPD


RL MDL


MB MB




Analyte

LCS LCS


Spike

Added

%Rec.

Limits


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Method: SM 2540C - Solids, Total Dissolved (TDS)


RL MDL


MB MB




Analyte

LCS LCS


Spike

Added

%Rec.

Limits


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Client Sample ID: PNA168:P-23:G042419 Lab Sample ID: 500-162331-1Matrix: WaterDate Collected: 04/24/19 08:28


Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable


Analysis SM 2540C 1 482507 04/27/19 02:28 CLB TAL CHITotal/NA



Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable



Client Sample ID: PNA168:MW-2U:G042419 Lab Sample ID: 500-162331-4Matrix: WaterDate Collected: 04/24/19 10:02


Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable




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Client Sample ID: PNA168:MW-16:G042419 Lab Sample ID: 500-162331-6Matrix: WaterDate Collected: 04/24/19 11:15


Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable



Client Sample ID: PNA168:MW-6L:G042419 Lab Sample ID: 500-162331-7Matrix: WaterDate Collected: 04/24/19 11:54


Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable



Client Sample ID: PNA168:MW-6M:G042419 Lab Sample ID: 500-162331-8Matrix: WaterDate Collected: 04/24/19 12:20


Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable




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Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable



Client Sample ID: PNA168:FB-1:G042419 Lab Sample ID: 500-162331-15Matrix: WaterDate Collected: 04/24/19 12:35


Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable




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Client Sample ID: PNA168:PZ-2:G042419 Lab Sample ID: 500-162331-16Matrix: WaterDate Collected: 04/24/19 16:15


Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable



Client Sample ID: PNA168:PZ-2:G042419A Lab Sample ID: 500-162331-17Matrix: WaterDate Collected: 04/24/19 16:15


Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable




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Client Sample ID: PNA168:MW-13M:G042519A Lab Sample ID: 500-162331-21Matrix: WaterDate Collected: 04/25/19 05:44


Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable



Client Sample ID: PNA168:S-5:G042519 Lab Sample ID: 500-162331-22Matrix: WaterDate Collected: 04/25/19 07:10


Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable




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Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable




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Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable



Client Sample ID: PNA168:HP-5:G042619 Lab Sample ID: 500-162331-33Matrix: WaterDate Collected: 04/26/19 06:50


Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable



Client Sample ID: PNA168:HP-7:G042619 Lab Sample ID: 500-162331-34Matrix: WaterDate Collected: 04/26/19 07:22


Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable




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Client Sample ID: PNA168:S-6R:G042519 Lab Sample ID: 500-162331-36Matrix: WaterDate Collected: 04/25/19 08:35


Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable




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Prep 3005A 04/30/19 16:07 BDE482915 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:07 BDE482915 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:07 BDE482915 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable





Prep 3005A 04/30/19 16:07 BDE482915 TAL CHI

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total Recoverable






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Accreditation/Certification SummaryClient: Hull & Associates, Inc. Job ID: 500-162331-1Project/Site: PNA Pilkington - Ottawa

Laboratory: Eurofins TestAmerica, ChicagoAll accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.


California 29039State Program 04-30-19 *

Georgia State Program 4 N/A 04-30-19 *

Georgia State Program 4 939 04-30-19 *

Hawaii State Program 9 N/A 04-30-19 *

Illinois NELAP 5 100201 05-30-19 *

Indiana State Program 5 C-IL-02 05-30-19 *

Iowa State Program 7 82 05-01-20

Kansas NELAP 7 E-10161 10-31-19

Kentucky (UST) State Program 4 66 05-30-19 *

Kentucky (WW) State Program 4 KY90023 12-31-19

Louisiana NELAP 6 30720 06-30-19 *

Mississippi State Program 4 N/A 04-30-19 *

New York NELAP 2 12019 04-01-20

North Carolina (WW/SW) State Program 4 291 12-31-19

North Dakota State Program 8 R-194 05-30-19 *

Oklahoma State Program 6 8908 08-31-19 *

South Carolina State Program 4 77001 05-30-19 *

Wisconsin State Program 5 999580010 08-31-19 *

Wyoming State Program 8 8TMS-Q 04-30-19 *

Laboratory: Eurofins TestAmerica, CantonAll accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.


California 29279State Program 02-23-20

Connecticut State Program 1 PH-0590 12-31-19

Florida NELAP 4 E87225 06-30-19

Illinois NELAP 5 200004 07-31-19

Kansas NELAP 7 E-10336 04-30-19 *

Kentucky (UST) State Program 4 58 02-23-20

Kentucky (WW) State Program 4 98016 12-31-19

Minnesota NELAP 5 039-999-348 12-31-19 *

Minnesota (Petrofund) State Program 1 3506 07-31-19

Nevada State Program 9 OH00048 07-31-19

New Jersey NELAP 2 OH001 06-30-19

New York NELAP 2 10975 03-31-20

Ohio VAP State Program 5 CL0024 09-06-19

Oregon NELAP 10 4062 02-23-20

Pennsylvania NELAP 3 68-00340 08-31-19 *

Texas NELAP 6 T104704517-18-10 08-31-19

USDA Federal P330-16-00404 12-28-19

Virginia NELAP 3 460175 09-14-19

Washington State Program 10 C971 01-12-20 *

West Virginia DEP State Program 3 210 12-31-19


* Accreditation/Certification renewal pending - accreditation/certification considered valid.

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Login Sample Receipt Checklist

Client: Hull & Associates, Inc. Job Number: 500-162331-1

Login Number: 162331

Question Answer Comment

Creator: Scott, Sherri L

List Source: Eurofins TestAmerica, Chicago

List Number: 1

TrueRadioactivity wasn't checked or is </= background as measured by a survey meter.

TrueThe cooler's custody seal, if present, is intact.

TrueSample custody seals, if present, are intact.

TrueThe cooler or samples do not appear to have been compromised or tampered with.

TrueSamples were received on ice.

TrueCooler Temperature is acceptable.

TrueCooler Temperature is recorded. 2.3,3.6,3.6

TrueCOC is present.

TrueCOC is filled out in ink and legible.

TrueCOC is filled out with all pertinent information.

TrueIs the Field Sampler's name present on COC?

FalseThere are no discrepancies between the containers received and the COC.

TrueSamples are received within Holding Time (excluding tests with immediate HTs)

TrueSample containers have legible labels.

TrueContainers are not broken or leaking.

TrueSample collection date/times are provided.

TrueAppropriate sample containers are used.

TrueSample bottles are completely filled.

TrueSample Preservation Verified.

TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs

N/AContainers requiring zero headspace have no headspace or bubble is <6mm (1/4").

TrueMultiphasic samples are not present.

TrueSamples do not require splitting or compositing.

N/AResidual Chlorine Checked.


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may 24, 2019 u.s. environmental protection agency, region 5 re · may 24, 2019 . ms. lauren bumba...

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