{\rtf1{\fonttbl{\f2 Times New Roman;}{\f3 Times New Roman Bold;}{\f4 Times New Roman;}{\f5 Times New Roman;}{\f6 Times New Roman;}{\f7 Times New Roman Italic;}{\f8 Times New Roman Bold;}{\f9 Times New Roman;}{\f10 Times New Roman;}{\f11 Times New Roman;}{\f12 Times New Roman Bold;}{\f13 Times New Roman;}{\f14 Times New Roman Italic;}{\f15 Times New Roman;}{\f16 Times New Roman;}{\f17 Times New Roman Bold;}{\f1000000 Times New Roman;}}{\colortbl;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;\red0\green0\blue0;}\viewkind1\viewscale100\margl0\margr0\margt0\margb0\deftab80\dntblnsbdb\expshrtn\paperw11900\paperh16840\pard\sb0\sl-240{\bkmkstart Pg1}{\bkmkend Pg1}\par\pard\ql \li3177\sb0\sl-414\slmult0 \par\pard\ql\li3177\sb204\sl-414\slmult0 \up0 \expndtw0\charscalex95 \ul0\nosupersub\cf2\f3\fs36 THE MANUFACTURE OF STEEL \par\pard\qj \li1740\sb0\sl-280\slmult0 \par\pard\qj\li1740\ri1481\sb197\sl-280\slmult0 \up0 \expndtw-2\charscalex100 \ul0\nosupersub\cf3\f4\fs24 Steel refers to any iron-carbon alloy, although steels usually contain other elements as \up0 \expndtw-3\charscalex100 well. In New Zealand steel is made by BHP NZ at Glenbrook, where about 90% of New \up0 \expndtw-4\charscalex100 Zealand's annual steel requirements are produced. \par\pard\qj \li1740\sb0\sl-280\slmult0 \par\pard\qj\li1740\ri1481\sb1\sl-280\slmult0 \up0 \expndtw-5\charscalex100 Iron occurs mainly as oxide ores, though it is also found in smaller quantities as its sulfide \line \up0 \expndtw-4\charscalex100 and carbonate. These other ores are usually first roasted to convert them into the oxide. \line \up0 \expndtw-2\charscalex100 On a world scale the most important ore is haematite (Fe\ul0\sub\cf4\f5\fs24 2\ul0\nosupersub\cf3\f4\fs24 O\ul0\sub\cf4\f5\fs24 3\ul0\nosupersub\cf3\f4\fs24 ), but in New Zealand the \line \up0 \expndtw-3\charscalex100 starting materials are magnetite (Fe\ul0\sub\cf4\f5\fs24 3\ul0\nosupersub\cf3\f4\fs24 O\ul0\sub\cf4\f5\fs24 4\ul0\nosupersub\cf3\f4\fs24 ) and titanomagnetite (Fe\ul0\sub\cf4\f5\fs24 2\ul0\nosupersub\cf3\f4\fs24 TiO\ul0\sub\cf4\f5\fs24 4\ul0\nosupersub\cf3\f4\fs24 ). The oxides are \line \up0 \expndtw-3\charscalex100 reduced with carbon from coal, through the intermediate production of carbon monoxide. \par\pard\qj \li1740\sb0\sl-280\slmult0 \par\pard\qj\li1740\ri1480\sb1\sl-280\slmult0 \up0 \expndtw-6\charscalex100 The carbon initially burns in air to give carbon dioxide and the heat, which is necessary for \up0 \expndtw0\charscalex100 the process. The carbon dioxide then undergoes an endothermic reaction with more \up0 \expndtw-5\charscalex100 carbon to yield carbon monoxide: \par\pard\li1740\sb29\sl-322\slmult0\fi3300\tx7920 \up0 \expndtw-4\charscalex100 C + O\ul0\sub\cf4\f5\fs24 2\ul0\nosupersub\cf3\f4\fs24 \ul0\nosupersub\cf5\f6\fs28 \u8594?\ul0\nosupersub\cf3\f4\fs24 CO\ul0\sub\cf4\f5\fs24 2\tab \up0 \expndtw-4\charscalex100 \ul0\nosupersub\cf3\f4\fs24 \u8710?\ul0\nosupersub\cf6\f7\fs24 H\ul0\nosupersub\cf3\f4\fs24 = -393 kJ mol\ul0\super\cf4\f5\fs23 -1\par\pard\li1740\sb22\sl-322\slmult0\fi3240\tx7920 \up0 \expndtw-4\charscalex100 \ul0\nosupersub\cf3\f4\fs24 C + CO\ul0\sub\cf4\f5\fs24 2\ul0\nosupersub\cf3\f4\fs24 \ul0\nosupersub\cf5\f6\fs28 \u8594?\ul0\nosupersub\cf3\f4\fs24 2CO\tab \up0 \expndtw-4\charscalex100 \u8710?\ul0\nosupersub\cf6\f7\fs24 H\ul0\nosupersub\cf3\f4\fs24 = +171 kJ mol\ul0\super\cf4\f5\fs23 -1\par\pard\li1740\sb0\sl-276\slmult0\par\pard\li1740\sb7\sl-276\slmult0\fi0 \up0 \expndtw-3\charscalex100 \ul0\nosupersub\cf3\f4\fs24 The oxide ores are then principally reduced by the carbon monoxide produced in this\par\pard\li1740\sb4\sl-276\slmult0\fi0 \up0 \expndtw-4\charscalex100 reaction, the reactions involving very small enthalpy changes:\par\pard\li4260\sb59\sl-276\slmult0\fi0\tx5013\tx5328\tx8045 \up0 \expndtw-7\charscalex100 Fe\ul0\sub\cf4\f5\fs24 2\ul0\nosupersub\cf3\f4\fs24 O\ul0\sub\cf4\f5\fs24 3\tab \up0 \expndtw-8\charscalex100 \ul0\nosupersub\cf3\f4\fs24 +\tab \up0 \expndtw-8\charscalex100 3CO \ul0\nosupersub\cf5\f6\fs28 \u8594?\ul0\nosupersub\cf3\f4\fs24 2Fe + 3CO\ul0\sub\cf4\f5\fs24 2\tab \up0 \expndtw-8\charscalex100 \ul0\nosupersub\cf3\f4\fs24 \u8710?\ul0\nosupersub\cf6\f7\fs24 H\ul0\nosupersub\cf3\f4\fs24 = -22 kJ mol\ul0\super\cf4\f5\fs23 -1\par\pard\li4260\sb67\sl-276\slmult0\fi0\tx5013\tx5328\tx8045 \up0 \expndtw-7\charscalex100 \ul0\nosupersub\cf3\f4\fs24 Fe\ul0\sub\cf4\f5\fs24 3\ul0\nosupersub\cf3\f4\fs24 O\ul0\sub\cf4\f5\fs24 4\tab \up0 \expndtw-8\charscalex100 \ul0\nosupersub\cf3\f4\fs24 +\tab \up0 \expndtw-8\charscalex100 4CO \ul0\nosupersub\cf5\f6\fs28 \u8594?\ul0\nosupersub\cf3\f4\fs24 3Fe + 4CO\ul0\sub\cf4\f5\fs24 2\tab \up0 \expndtw-8\charscalex100 \ul0\nosupersub\cf3\f4\fs24 \u8710?\ul0\nosupersub\cf6\f7\fs24 H\ul0\nosupersub\cf3\f4\fs24 = -10 kJ mol\ul0\super\cf4\f5\fs23 -1\par\pard\qj \li1740\ri1480\sb269\sl-280\slmult0 \up0 \expndtw0\charscalex100 \ul0\nosupersub\cf3\f4\fs24 In conventional ironmaking this reduction occurs in a blast furnace, whereas in New \line \up0 \expndtw-5\charscalex100 Zealand a rotary kiln is employed for direct reduction, followed by indirect reduction in an \line \up0 \expndtw-3\charscalex100 electric melter. This technology is used because the titanium dioxide present in the ore \line \up0 \expndtw-3\charscalex100 produces a slag which blocks conventional blast furnaces as it has a high melting point. \par\pard\qj \li1740\sb0\sl-280\slmult0 \par\pard\qj\li1740\ri1480\sb1\sl-280\slmult0 \up0 \expndtw-3\charscalex100 The iron produced in this way always contains high levels of impurities making it very \line \up0 \expndtw-3\charscalex100 brittle. Steel making is mainly concerned with the removal of these impurities. This is \line \up0 \expndtw0\charscalex102 done by oxidising the elements concerned by blowing pure oxygen through a lance \line \up0 \expndtw-4\charscalex100 inserted into the molten alloy. The KOBM (Klockner Oxygen Blown Maxhutte) used for \line \up0 \expndtw-4\charscalex100 this in New Zealand is unusual because oxygen is also blown through holes in the base of \line \up0 \expndtw0\charscalex104 the converter. The oxides produced are either evolved as gases, or combine with \line \up0 \expndtw-5\charscalex100 limestone to form an immiscible slag which floats on the surface of the liquid metal and so \line \up0 \expndtw-6\charscalex100 is easily separated. \par\pard\ql \li1440\sb0\sl-276\slmult0 \par\pard\ql\li1440\sb208\sl-276\slmult0 \up0 \expndtw-3\charscalex100 \ul0\nosupersub\cf7\f8\fs24 INTRODUCTION \par\pard\ql \li1440\sb0\sl-280\slmult0 \par\pard\ql\li1440\ri1420\sb1\sl-280\slmult0 \up0 \expndtw-4\charscalex100 \ul0\nosupersub\cf3\f4\fs24 Steel is a term given to alloys containing a high proportion of iron with some carbon. Other \line \up0 \expndtw-4\charscalex100 alloying elements may also be present in varying proportions. The properties of steel are \line \up0 \expndtw-4\charscalex100 highly dependent on the proportions of alloying elements, so that their levels are closely \line \up0 \expndtw-4\charscalex100 controlled during its manufacture. The properties of steel also depend on the heat treatment \line \up0 \expndtw-5\charscalex100 of the metal. \par\pard\ql \li1440\sb0\sl-276\slmult0 \par\pard\ql\li1440\sb8\sl-276\slmult0 \up0 \expndtw-4\charscalex100 Steel is by far the most important metal, in tonnage terms, in the modern world, with the \par\pard\qj \li1440\ri1425\sb1\sl-280\slmult0 \up0 \expndtw-4\charscalex100 annual global production of over 700 million tonnes dwarfing the approximately 17 million \line \up0 \expndtw-4\charscalex100 tonnes of the next most prolific, aluminium. 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