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Institute of Combustion Technology Laser Diagnostics for High-Pressure Gas Turbine Combustion Wolfgang Meier German Aerospace Center (DLR), Institute of Combustion Technology, Stuttgart, Germany Workshop on Techniques for High-Pressure Combustion Argonne National Laboratory, August 29 - September 1, 2011

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Institute of Combustion Technology

Laser Diagnostics for High-Pressure Gas Turbine Combustion

Wolfgang Meier

German Aerospace Center (DLR), Institute of Combustion Technology, Stuttgart, Germany

Workshop on Techniques for High-Pressure CombustionArgonne National Laboratory, August 29 - September 1, 2011

30.8.2011

Slide 2 Argonne Workshop 2011

Outline

- Introduction to DLR Institute of Combustion Technology

- Measurement techniques and test rigs

- Problems encountered in high-pressure combustion

- Examples and results

- Summary and conclusions

30.8.2011

Slide 3 Argonne Workshop 2011

Gas Turbine Combustion at DLR Stuttgart

Goals and research fields

• Reduction of Pollutants:NOx, soot, UHC

• Instationary combustion phenomena:Ignition, re-ignition, extinction, thermo-acoustic

• Fuel-flexibility:Kerosene, natural gas of different quality, syngases, alternative fuels

• Burners and combustion systems:FLOX®, hybrid power plant

30.8.2011

Slide 4 Argonne Workshop 2011

Laser Measuring Techniques for Different Quantities

Flow field velocity

Species (OH, CH, NO, CH2O, tracer), temperature, structures

Major species, mixing, temp..

Temperature

Soot

Atoms, Ions

Quantity Technique

Particle Image Velocimetry (PIV)

Laser induced fluorescence (LIF)

Laser Raman Scattering

Coherent anti-Stokes Raman scattering (CARS)

Laser induced incandescence (LII)

Laser Induced BreakdownSpectroscopy (LIBS)

Dim.

2D

2D

0D or 1D

0D

2D

0D

All methods applied as single-pulse techniques with repetition rates up to 10 kHz

30.8.2011

Slide 5 Argonne Workshop 2011

Mobile Laser Systems

Raman-LasersCARS-Lasersystem

- For measurement campaigns at test rigs, all over Europe.- Installation in containers: temperature stabilized, compact.

30.8.2011

Slide 6 Argonne Workshop 2011

High-Pressure Text Rigs

at DLR Stuttgart

30.8.2011

Slide 7 Argonne Workshop 2011

High-Pressure Combustion Test Rig at Stuttgart

Air supply:Pressure: max. 40 barFlow rate: max. 1.3 kg/sInlet temperature: max. 1000 K

Gaseous and liquids fuels

Thermal power: max. 2 MW

Not traversable

optical measurement section

supply section

30.8.2011

Slide 8 Argonne Workshop 2011

High-Pressure Combustion Test Rig – Stuttgart

Typical combustion chamber with optical access

Example of a low-emission flame

30.8.2011

Slide 9 Argonne Workshop 2011

Problems Encountered in High-Pressure Combustion

- Limited optical access, laser beams and signals must pass several windows.

- Window degradation by high thermal loads.- Line broadening → signal reduction in LIF.- Signal trapping (LIF, chemiluminescence imaging).- Beam degradation and steering (CARS, Raman, LII).- Depolarization in windows by stress-induced birefringence. - Non-traversable combustors → measurement technique must be

traversed.- Costs.

30.8.2011

Slide 10 Argonne Workshop 2011

Influence of Heat Load on Quartz Windows

Quartz window after extensive use at high pressure

30.8.2011

Slide 11 Argonne Workshop 2011

Window Cooling in Optical Combustion Chamber

plane quartz plates

Flow of cooling air

Exhaust165 mm

275 mm

30.8.2011

Slide 12 Argonne Workshop 2011

LIF: Effect of Line Broadening- NO was seeded as a tracer to the fuel or the combustion gases.- LIF of NO A-X ( bands at λ~226 nm) at 15 bar, T~1200 K.

225,48 225,50 225,52 225,54 225,56 225,58 225,60 225,620

10

20

30

40

50

60

70

80

90

100

NO O2 * 6000

inte

nsity

(a.u

.)

wavelength (nm) (vacuum)

Q1(23)

- Lines not well resolved and broader than exciting laser radiation.- Overlapp with (hot) O2 spectrum (Schumann-Runge band).- Different tracer available?

Sadanandan et al., Appl. Phys B 2011DOI 10.1007/s00340-011-4655-4

30.8.2011

Slide 13 Argonne Workshop 2011

Absorption of Laser Radiation and LIF Signal

Excitation of OH in A-X (1,0) band in CH4/air flames at 1 atm.

Averaged LIF signal from turb. flame at T≈1900 K

Absorption of laser from left to right ≈45%

Excitation of Q1(8) at λ≈283nm

30.8.2011

Slide 14 Argonne Workshop 2011

Absorption of Laser Radiation and LIF Signal

Excitation of OH in A-X (1,0) band in CH4/air flames at 1 atm.

Averaged LIF signal from turb. flame at T≈1900 K

Absorption of laser from left to right ≈45%

306 308 310 312 314 316 318 3200

20

40

60

80

100(1,1)(0,0)

inte

nsity

(a.u

.)

wavelength (nm)

no abs. with abs.

Emission spectrum after laser excitation

Absorption path: 54 mm through exhaust gas at T≈2100 K.

Excitation of Q1(8) at λ≈283nm

Sadanandan et al., Appl. Phys B 2011accepted for publication

30.8.2011

Slide 15 Argonne Workshop 2011

1D Laser Raman Scattering at the High-Pressure Rig

Goals- Application to lean premixed GT combustors.- Simultaneous single-shot measurement of major species

concentrations, mixture fraction and temperature along a line.- Identification of effects of unmixedness and finite-rate chemistry.- Data for model validation.

Challenges- Introduce high-power laser pulses with small beam waist into

combustion chamber.- Move laser and detection optics synchronously to change

measurement position.- Perform calibration measurements inside pressure housing.- Cope with window contamination, alignment shifts, ….

30.8.2011

Slide 16 Argonne Workshop 2011

Laser system + pulse stretcher

Spektrographf = 300 mm

Beam expansion3,3 : 1

ICCDcamera

Cylinder lensesconvex

f = 300 mm

Convex lens

Focus inside thecombustion chamber

Apochromatf ≈ 280 mm

Notchfilter

532 nm

Power meter

Measurement Setup

3 double pulse Nd:YAG lasersλ = 532 nm, 6 x 0.3 J / Pulsrepetition rate: 10 Hz

Stopper et al., Exp Thermal FluidSci. 34, 396-403 (2010)

30.8.2011

Slide 17 Argonne Workshop 2011

Laser system + pulse stretcher

Spektrographf = 300 mm

Beam expansion3,3 : 1

ICCDcamera

Cylinder lensesconvex

f = 300 mm

Convex lens

Focus inside thecombustion chamber

Apochromatf ≈ 280 mm

Notchfilter

532 nm

Power meter

Measurement Setup

3 double pulse Nd:YAG lasersλ = 532 nm, 6 x 0.3 J / Pulsrepetition rate: 10 Hz

30.8.2011

Slide 18 Argonne Workshop 2011

Pulse Stretcher for Laser Pulses

8 ns 6 single pulsesPeak power: ~ 35 MW

1 long pulsePeak power: ~ 7 MW350 ns

Beam is splitted by beam splitters and recombined after having travelled different distances.

30.8.2011

Slide 19 Argonne Workshop 2011

ChallengeOptical breakdown in focus

Reduced with smallbeam divergence

Damage of the combustor windows

Requires largebeam divergence

large beam waist

large cross section on windows

30.8.2011

Slide 20 Argonne Workshop 2011

Our Approach: Generate Astigmatism

astigmatic fosus

Use of 2 cylindrical lenses

Beam waist about 0.5 mm

F1 F2

30.8.2011

Slide 21 Argonne Workshop 2011

Raman Measurements in Scaled GT Combustor- Lean premixed natural gas /air flames (p=4 bar, Ptherm.=1.2 MW).- Staged combustion: 1 pilot burner, 8 main burners.- One goal: Interaction between pilot and main burners.

pilot burner

main burners

Lückerath et al., Proc. ASME Turbo Expo 2011, GT2011-45790

30.8.2011

Slide 22 Argonne Workshop 2011

Scatterplot of Temperature vs. Mixture Fraction

- Symbols represents results from single-shot measurements.- Different states of mixing and reaction progress.

adiab.equil.

non-reacted stoich. f

30.8.2011

Slide 23 Argonne Workshop 2011

Flame Shape from Chemiluminescence

cone of pilot burner.

OH* chemiluminescence, Abel-transformed

flow frommain burners

region of mixing and flame stabilization

30.8.2011

Slide 24 Argonne Workshop 2011

Mixing and Reaction Progress

ba

d

c

e

30.8.2011

Slide 25 Argonne Workshop 2011

Wish List for Raman Measurements

- Laser with ~1 μs pulse duration, pulse energy >1 J, good beam profile, wavelength close to 400 nm.

- Detection camera with high quantum efficiency, low noise, gateable.

- Window material with better heat resistance or improved cooling concept.

30.8.2011

Slide 26 Argonne Workshop 2011

Summary and Conclusions

- Laser measurements at high-pressure test rigs could be performed successfully.

- Window degradation is one of the most serious problems in our high-pressure combustion chambers.

- Effects of line broadening, beam steering, etc. reduce the quality of the results.

- Possible improvements: fs-CARS? Long pulse lasers for Raman?