ksa environmental laboratory inc. info/appendix iv...ksaenvironmental laboratory inc. february 26,...

KSA Environmental Laboratory Inc.February 26, 2007

KSA Workorder: Q001202

Miami, FL 33176

Dear Brad Waller,

Enclosed is a copy of your laboratory report for test samples received by our laboratory on

02/16/07 13:55.

Unless otherwise noted in an attached project narrative, all samples were received in acceptable

condition and processed in accordance with the referenced methods/procedures. Results for

these procedures apply only to the samples as submitted.

This data has been produced in accordance with NELAC standards. This report shall not be

reproduced except in full, without the written approval of the Laboratory.

If you have any questions or require further information, please do not hesitate to contact me.

Sincerely,

Enclosure(s)

RE: Parkland

Attn: Brad Waller

Hydrologic Associates - Miami

8925 S.W. 148th Street Suite 212

Emerson Perez

Project Manager

Florida Certifications: E86349 & E86616 (Microbiology)

of 23 KSA Environmental Laboratory Inc. - 10200 USA Today Way - Miramar, FL 33025 - (954) 431-4550

CASE NARRATIVE

______________________________________________________________________________

KSA Work Order #: Q001202

Project Name: Parkland

______________________________________________________________________________

I. Sample Receiving Notes

All samples listed on the Chain of Custody identified with KSA Work Order # Q001202 were received

with containers intact, correctly preserved, and at the proper temperature for the requested analyses.

II. Analytical Data Notes

The analyses were performed in accordance with KSA Environmental Laboratory SOP's and

industry-standard methodologies in compliance with FDEP/NELAC criteria. There were no notable

problems encountered in the analytical process.

III. Quality Control Notes

EPA 8081: The LCS/LCSD RPD for batch 7020498 exceeded laboratory guidelines for delta-BHC,

Endosulfan sulfate, and Endrin aldehyde; however, the LCS and LCSD percent recoveries were within

control limits. The associated samples are flagged with the FDEP "J" qualifier.

EPA 8260: The LCS/LCSD RPD for batch 7020583 exceeded laboratory guidelines for

1,1,1-Trichloroethane; however, the LCS and LCSD percent recoveries were within control limits. The

associated samples are flagged with the FDEP "J" qualifier.

EPA 300.0: The LCS/LCSD recovered slightly above the control limits for Nitrite; however, since this

analyte was detected below PQL in the samples and the high recovery would yield a high bias, no further

corrective action was necessary.



SAMPLE SUMMARY

Client ID ReceivedSampledMatrix

Q001202-01 MW-East 02/15/07 00:00 02/16/07 13:55Groundwater

Q001202-02 MW-West 02/15/07 00:00 02/16/07 13:55Groundwater



ANALYTICAL REPORT

Sample ID: MW-East

Lab #: Q001202-01

Project:

Work Order #:

Parkland

Q001202

GroundwaterMatrix:02/15/07 0:00Sampled:

Priority Pollutant Volatiles

Parameter

Analytical

Results MDL PQLAnalytical

Batch

Analysis

Method

Analysis

Date/Time

Prep

Date/TimeDFQ

70205480.18 ug/L 0.18 1.0 8260U 02/20/07 19:0202/20/07 9:081,1,1-Trichloroethane 1

70205480.36 ug/L 0.36 1.0 8260U 02/20/07 19:0202/20/07 9:081,1,2,2-Tetrachloroethane 1


70205480.31 ug/L 0.31 1.0 8260U 02/20/07 19:0202/20/07 9:081,1-Dichloroethane 1

70205480.25 ug/L 0.25 1.0 8260U 02/20/07 19:0202/20/07 9:081,1-Dichloroethene 1


70205480.41 ug/L 0.41 1.0 8260U 02/20/07 19:0202/20/07 9:081,2-Dichloropropane 1

70205482.2 ug/L 2.2 5.0 8260U 02/20/07 19:0202/20/07 9:082-Chloroethylvinyl ether 1

70205482.0 ug/L 2.0 10 8260U 02/20/07 19:0202/20/07 9:08Acrolein 1

70205485.2 ug/L 5.2 10 8260U 02/20/07 19:0202/20/07 9:08Acrylonitrile 1

70205480.36 ug/L 0.36 1.0 8260U 02/20/07 19:0202/20/07 9:08Benzene 1

70205480.26 ug/L 0.26 1.0 8260U 02/20/07 19:0202/20/07 9:08Bromodichloromethane 1

70205480.41 ug/L 0.41 1.0 8260U 02/20/07 19:0202/20/07 9:08Bromoform 1

70205480.77 ug/L 0.77 1.0 8260U 02/20/07 19:0202/20/07 9:08Bromomethane 1

70205480.15 ug/L 0.15 1.0 8260U 02/20/07 19:0202/20/07 9:08Carbon tetrachloride 1

70205480.23 ug/L 0.23 1.0 8260U 02/20/07 19:0202/20/07 9:08Chlorobenzene 1

70205480.30 ug/L 0.30 1.0 8260U 02/20/07 19:0202/20/07 9:08Chlorodibromomethane 1

70205480.66 ug/L 0.66 1.0 8260U 02/20/07 19:0202/20/07 9:08Chloroethane 1

70205480.30 ug/L 0.30 1.0 8260U 02/20/07 19:0202/20/07 9:08Chloroform 1

70205480.72 ug/L 0.72 1.0 8260U 02/20/07 19:0202/20/07 9:08Chloromethane 1

70205480.32 ug/L 0.32 1.0 8260U 02/20/07 19:0202/20/07 9:08cis-1,3-Dichloropropene 1

70205480.33 ug/L 0.33 1.0 8260U 02/20/07 19:0202/20/07 9:08Ethylbenzene 1

70205480.42 ug/L 0.42 5.0 8260U 02/20/07 19:0202/20/07 9:08Methylene chloride 1

70205480.34 ug/L 0.34 1.0 8260U 02/20/07 19:0202/20/07 9:08Tetrachloroethene 1

70205480.31 ug/L 0.31 1.0 8260U 02/20/07 19:0202/20/07 9:08Toluene 1

70205480.38 ug/L 0.38 1.0 8260U 02/20/07 19:0202/20/07 9:08trans-1,2-Dichloroethene 1

70205480.34 ug/L 0.34 1.0 8260U 02/20/07 19:0202/20/07 9:08trans-1,3-Dichloropropene 1

70205480.42 ug/L 0.42 1.0 8260U 02/20/07 19:0202/20/07 9:08Trichloroethene 1

70205480.31 ug/L 0.31 1.0 8260U 02/20/07 19:0202/20/07 9:08Vinyl chloride 1

Surrogate Recovery % Recovery % Recovery Limits

1,2-Dichloroethane-d4 106 % 72-136 7020548

4-Bromofluorobenzene 96.5 % 79-117 7020548

Dibromofluoromethane 106 % 77-131 7020548

Toluene-d8 90.8 % 78-125 7020548

Organochlorine Pesticides

Parameter

Analytical


Batch

Analysis

Method

Analysis

Date/Time

Prep

Date/TimeDFQ

70204980.0021 ug/L 0.0021 0.0047 8081U 02/22/07 8:3002/19/07 8:504,4'-DDD 1



ANALYTICAL REPORT

Sample ID: MW-East

Lab #: Q001202-01

Project:

Work Order #:

Parkland

Q001202



Parameter

Analytical


Batch

Analysis

Method

Analysis

Date/Time

Prep

Date/TimeDFQ

70204980.0039 ug/L 0.0039 0.0047 8081U 02/22/07 8:3002/19/07 8:504,4'-DDE 1

70204980.0032 ug/L 0.0032 0.0047 8081U 02/22/07 8:3002/19/07 8:504,4'-DDT 1

70204980.0041 ug/L 0.0041 0.0047 8081U 02/22/07 8:3002/19/07 8:50Aldrin 1

70204980.0038 ug/L 0.0038 0.0047 8081U 02/22/07 8:3002/19/07 8:50alpha-BHC 1

70204980.0041 ug/L 0.0041 0.0047 8081U 02/22/07 8:3002/19/07 8:50beta-BHC 1

70204980.16 ug/L 0.16 0.24 8081U 02/22/07 8:3002/19/07 8:50Chlordane (tech) 1

70204980.0040 ug/L 0.0040 0.0047 8081J, U 02/22/07 8:3002/19/07 8:50delta-BHC 1

70204980.0028 ug/L 0.0028 0.0047 8081U 02/22/07 8:3002/19/07 8:50Dieldrin 1

70204980.0028 ug/L 0.0028 0.0057 8081U 02/22/07 8:3002/19/07 8:50Endosulfan I 1

70204980.0013 ug/L 0.0013 0.0047 8081U 02/22/07 8:3002/19/07 8:50Endosulfan II 1

70204980.0073 ug/L 0.0073 0.0094 8081J, U 02/22/07 8:3002/19/07 8:50Endosulfan sulfate 1

70204980.014 ug/L 0.014 0.094 8081U 02/22/07 8:3002/19/07 8:50Endrin 1

70204980.0036 ug/L 0.0036 0.0047 8081J, U 02/22/07 8:3002/19/07 8:50Endrin aldehyde 1

70204980.013 ug/L 0.013 0.094 8081U 02/22/07 8:3002/19/07 8:50gamma-BHC (Lindane) 1

70204980.0098 ug/L 0.0098 0.094 8081U 02/22/07 8:3002/19/07 8:50Heptachlor 1

70204980.016 ug/L 0.016 0.094 8081U 02/22/07 8:3002/19/07 8:50Heptachlor epoxide 1

70204980.018 ug/L 0.018 0.094 8081U 02/22/07 8:3002/19/07 8:50Methoxychlor 1

70204980.45 ug/L 0.45 0.47 8081U 02/22/07 8:3002/19/07 8:50Toxaphene 1


Decachlorobiphenyl 111 % 41-129 7020498

Tetrachloro-meta-xylene 83.1 % 42-129 7020498

Polychlorinated Biphenyls

Parameter

Analytical


Batch

Analysis

Method

Analysis

Date/Time

Prep

Date/TimeDFQ

70204990.12 ug/L 0.12 0.24 8082U 02/19/07 17:0202/19/07 8:52PCB-1016 1

70204990.066 ug/L 0.066 0.24 8082U 02/19/07 17:0202/19/07 8:52PCB-1221 1

70204990.017 ug/L 0.017 0.24 8082U 02/19/07 17:0202/19/07 8:52PCB-1232 1

70204990.066 ug/L 0.066 0.24 8082U 02/19/07 17:0202/19/07 8:52PCB-1242 1

70204990.066 ug/L 0.066 0.24 8082U 02/19/07 17:0202/19/07 8:52PCB-1248 1

70204990.066 ug/L 0.066 0.24 8082U 02/19/07 17:0202/19/07 8:52PCB-1254 1

70204990.16 ug/L 0.16 0.24 8082U 02/19/07 17:0202/19/07 8:52PCB-1260 1



Tetrachloro-meta-xylene 73.3 % 10-166 7020499



ANALYTICAL REPORT

Sample ID: MW-East

Lab #: Q001202-01

Project:

Work Order #:

Parkland

Q001202


Metals

Parameter

Analytical


Batch

Analysis

Method

Analysis

Date/Time

Prep

Date/TimeDFQ

70205170.0028 mg/L 0.0028 0.0060 6010U 02/20/07 12:0302/19/07 14:47Antimony, Total 1

70205170.0043 mg/L 0.0043 0.010 6010U 02/20/07 12:0302/19/07 14:47Arsenic, Total 1

70205170.0013 mg/L 0.0013 0.0040 6010U 02/20/07 12:0302/19/07 14:47Beryllium, Total 1

70205170.0013 mg/L 0.0013 0.0050 6010U 02/20/07 12:0302/19/07 14:47Cadmium, Total 1

70205170.0012 mg/L 0.0012 0.0050 6010U 02/20/07 12:0302/19/07 14:47Chromium, Total 1

70205170.0043 mg/L 0.0043 0.010 6010U 02/20/07 12:0302/19/07 14:47Copper, Total 1

70205170.0044 mg/L 0.0044 0.015 6010U 02/20/07 12:0302/19/07 14:47Lead, Total 1

70205150.000060 mg/L 0.000060 0.00020 7470U 02/19/07 14:0102/19/07 13:55Mercury, Total 1

70205170.0016 mg/L 0.0016 0.0050 6010U 02/20/07 12:0302/19/07 14:47Nickel, Total 1

70205170.0037 mg/L 0.0037 0.010 6010U 02/20/07 12:0302/19/07 14:47Selenium, Total 1

70205170.00057 mg/L 0.00057 0.0050 6010U 02/20/07 12:0302/19/07 14:47Silver, Total 1

70205170.0047 mg/L 0.0047 0.010 6010U 02/20/07 12:0302/19/07 14:47Thallium, Total 1

70205170.0054 mg/L 0.0054 0.020 6010U 02/20/07 12:0302/19/07 14:47Zinc, Total 1

Wet Chemistry

Parameter

Analytical


Batch

Analysis

Method

Analysis

Date/Time

Prep

Date/TimeDFQ

0.021 mg/L 0.0040 0.0050 335.3 702058802/21/07 16:2402/21/07 9:00Cyanide, Total 1

0.082 mg/L 0.015 0.020 350.1 702065602/23/07 15:3902/23/07 13:13Nitrogen, Ammonia (as N) 1

0.41 mg/L 0.091 0.25 351.2 702055502/20/07 15:2602/20/07 9:00Nitrogen, Kjeldahl, Total 1

3.3 mg/L 0.062 0.50 300.0 702050502/16/07 16:0002/16/07 16:00Nitrogen, Nitrate (as N) 1

0.29 mg/L 0.021 0.50 300.0 7020505I 02/16/07 16:0002/16/07 16:00Nitrogen, Nitrite (as N) 1

0.33 mg/L 0.091 0.25 Calc [CALC]02/23/07 15:3902/23/07 13:13Nitrogen, Organic 1

0.0090 mg/L 0.0080 0.010 365.2 7020621I 02/17/07 14:3002/17/07 14:30Orthophosphate as P 1

0.059 mg/L 0.018 0.020 420.2 7020671V 02/25/07 15:0002/23/07 15:56Phenols, Total 1

70205590.047 mg/L 0.047 0.10 365.4U 02/20/07 17:4602/19/07 9:00Phosphorus, Total 1



ANALYTICAL REPORT

Sample ID: MW-West

Lab #: Q001202-02

Project:

Work Order #:

Parkland

Q001202


Priority Pollutant Volatiles

Parameter

Analytical


Batch

Analysis

Method

Analysis

Date/Time

Prep

Date/TimeDFQ

70205830.18 ug/L 0.18 1.0 8260J, U 02/21/07 14:0402/21/07 11:121,1,1-Trichloroethane 1

70205830.36 ug/L 0.36 1.0 8260U 02/21/07 14:0402/21/07 11:121,1,2,2-Tetrachloroethane 1



70205830.25 ug/L 0.25 1.0 8260U 02/21/07 14:0402/21/07 11:121,1-Dichloroethene 1


70205830.41 ug/L 0.41 1.0 8260U 02/21/07 14:0402/21/07 11:121,2-Dichloropropane 1

70205832.2 ug/L 2.2 5.0 8260U 02/21/07 14:0402/21/07 11:122-Chloroethylvinyl ether 1

70205832.0 ug/L 2.0 10 8260U 02/21/07 14:0402/21/07 11:12Acrolein 1

70205835.2 ug/L 5.2 10 8260U 02/21/07 14:0402/21/07 11:12Acrylonitrile 1

70205830.36 ug/L 0.36 1.0 8260U 02/21/07 14:0402/21/07 11:12Benzene 1

70205830.26 ug/L 0.26 1.0 8260U 02/21/07 14:0402/21/07 11:12Bromodichloromethane 1

70205830.41 ug/L 0.41 1.0 8260U 02/21/07 14:0402/21/07 11:12Bromoform 1

70205830.77 ug/L 0.77 1.0 8260U 02/21/07 14:0402/21/07 11:12Bromomethane 1

70205830.15 ug/L 0.15 1.0 8260U 02/21/07 14:0402/21/07 11:12Carbon tetrachloride 1

70205830.23 ug/L 0.23 1.0 8260U 02/21/07 14:0402/21/07 11:12Chlorobenzene 1

70205830.30 ug/L 0.30 1.0 8260U 02/21/07 14:0402/21/07 11:12Chlorodibromomethane 1

70205830.66 ug/L 0.66 1.0 8260U 02/21/07 14:0402/21/07 11:12Chloroethane 1

70205830.30 ug/L 0.30 1.0 8260U 02/21/07 14:0402/21/07 11:12Chloroform 1

70205830.72 ug/L 0.72 1.0 8260U 02/21/07 14:0402/21/07 11:12Chloromethane 1

70205830.32 ug/L 0.32 1.0 8260U 02/21/07 14:0402/21/07 11:12cis-1,3-Dichloropropene 1

70205830.33 ug/L 0.33 1.0 8260U 02/21/07 14:0402/21/07 11:12Ethylbenzene 1

70205830.42 ug/L 0.42 5.0 8260U 02/21/07 14:0402/21/07 11:12Methylene chloride 1

70205830.34 ug/L 0.34 1.0 8260U 02/21/07 14:0402/21/07 11:12Tetrachloroethene 1

70205830.31 ug/L 0.31 1.0 8260U 02/21/07 14:0402/21/07 11:12Toluene 1

70205830.38 ug/L 0.38 1.0 8260U 02/21/07 14:0402/21/07 11:12trans-1,2-Dichloroethene 1

70205830.34 ug/L 0.34 1.0 8260U 02/21/07 14:0402/21/07 11:12trans-1,3-Dichloropropene 1

70205830.42 ug/L 0.42 1.0 8260U 02/21/07 14:0402/21/07 11:12Trichloroethene 1

70205830.31 ug/L 0.31 1.0 8260U 02/21/07 14:0402/21/07 11:12Vinyl chloride 1


1,2-Dichloroethane-d4 111 % 72-136 7020583

4-Bromofluorobenzene 96.2 % 79-117 7020583

Dibromofluoromethane 115 % 77-131 7020583

Toluene-d8 116 % 78-125 7020583


Parameter

Analytical


Batch

Analysis

Method

Analysis

Date/Time

Prep

Date/TimeDFQ

70204980.0020 ug/L 0.0020 0.0046 8081U 02/22/07 8:5002/19/07 8:504,4'-DDD 1



ANALYTICAL REPORT

Sample ID: MW-West

Lab #: Q001202-02

Project:

Work Order #:

Parkland

Q001202



Parameter

Analytical


Batch

Analysis

Method

Analysis

Date/Time

Prep

Date/TimeDFQ

70204980.0038 ug/L 0.0038 0.0046 8081U 02/22/07 8:5002/19/07 8:504,4'-DDE 1

70204980.0031 ug/L 0.0031 0.0046 8081U 02/22/07 8:5002/19/07 8:504,4'-DDT 1

70204980.0040 ug/L 0.0040 0.0046 8081U 02/22/07 8:5002/19/07 8:50Aldrin 1

70204980.0037 ug/L 0.0037 0.0046 8081U 02/22/07 8:5002/19/07 8:50alpha-BHC 1

70204980.0040 ug/L 0.0040 0.0046 8081U 02/22/07 8:5002/19/07 8:50beta-BHC 1

70204980.16 ug/L 0.16 0.23 8081U 02/22/07 8:5002/19/07 8:50Chlordane (tech) 1

70204980.0039 ug/L 0.0039 0.0046 8081J, U 02/22/07 8:5002/19/07 8:50delta-BHC 1

70204980.0028 ug/L 0.0028 0.0046 8081U 02/22/07 8:5002/19/07 8:50Dieldrin 1

70204980.0028 ug/L 0.0028 0.0056 8081U 02/22/07 8:5002/19/07 8:50Endosulfan I 1

70204980.0013 ug/L 0.0013 0.0046 8081U 02/22/07 8:5002/19/07 8:50Endosulfan II 1

70204980.0071 ug/L 0.0071 0.0093 8081J, U 02/22/07 8:5002/19/07 8:50Endosulfan sulfate 1

70204980.014 ug/L 0.014 0.093 8081U 02/22/07 8:5002/19/07 8:50Endrin 1

70204980.0035 ug/L 0.0035 0.0046 8081J, U 02/22/07 8:5002/19/07 8:50Endrin aldehyde 1

70204980.013 ug/L 0.013 0.093 8081U 02/22/07 8:5002/19/07 8:50gamma-BHC (Lindane) 1

70204980.0096 ug/L 0.0096 0.093 8081U 02/22/07 8:5002/19/07 8:50Heptachlor 1

70204980.016 ug/L 0.016 0.093 8081U 02/22/07 8:5002/19/07 8:50Heptachlor epoxide 1

70204980.018 ug/L 0.018 0.093 8081U 02/22/07 8:5002/19/07 8:50Methoxychlor 1

70204980.44 ug/L 0.44 0.46 8081U 02/22/07 8:5002/19/07 8:50Toxaphene 1



Tetrachloro-meta-xylene 117 % 42-129 7020498

Polychlorinated Biphenyls

Parameter

Analytical


Batch

Analysis

Method

Analysis

Date/Time

Prep

Date/TimeDFQ

70204990.11 ug/L 0.11 0.23 8082U 02/19/07 17:2202/19/07 8:52PCB-1016 1

70204990.065 ug/L 0.065 0.23 8082U 02/19/07 17:2202/19/07 8:52PCB-1221 1

70204990.017 ug/L 0.017 0.23 8082U 02/19/07 17:2202/19/07 8:52PCB-1232 1

70204990.065 ug/L 0.065 0.23 8082U 02/19/07 17:2202/19/07 8:52PCB-1242 1

70204990.065 ug/L 0.065 0.23 8082U 02/19/07 17:2202/19/07 8:52PCB-1248 1

70204990.065 ug/L 0.065 0.23 8082U 02/19/07 17:2202/19/07 8:52PCB-1254 1

70204990.16 ug/L 0.16 0.23 8082U 02/19/07 17:2202/19/07 8:52PCB-1260 1



Tetrachloro-meta-xylene 108 % 10-166 7020499



ANALYTICAL REPORT

Sample ID: MW-West

Lab #: Q001202-02

Project:

Work Order #:

Parkland

Q001202


Metals

Parameter

Analytical


Batch

Analysis

Method

Analysis

Date/Time

Prep

Date/TimeDFQ

70205170.0028 mg/L 0.0028 0.0060 6010U 02/20/07 12:0302/19/07 14:47Antimony, Total 1

70205170.0043 mg/L 0.0043 0.010 6010U 02/20/07 12:0302/19/07 14:47Arsenic, Total 1

70205170.0013 mg/L 0.0013 0.0040 6010U 02/20/07 12:0302/19/07 14:47Beryllium, Total 1

70205170.0013 mg/L 0.0013 0.0050 6010U 02/20/07 12:0302/19/07 14:47Cadmium, Total 1

70205170.0012 mg/L 0.0012 0.0050 6010U 02/20/07 12:0302/19/07 14:47Chromium, Total 1

70205170.0043 mg/L 0.0043 0.010 6010U 02/20/07 12:0302/19/07 14:47Copper, Total 1

70205170.0044 mg/L 0.0044 0.015 6010U 02/20/07 12:0302/19/07 14:47Lead, Total 1

70205150.000060 mg/L 0.000060 0.00020 7470U 02/19/07 14:0102/19/07 13:55Mercury, Total 1

0.0020 mg/L 0.0016 0.0050 6010 7020517I 02/20/07 12:0302/19/07 14:47Nickel, Total 1

70205170.0037 mg/L 0.0037 0.010 6010U 02/20/07 12:0302/19/07 14:47Selenium, Total 1

70205170.00057 mg/L 0.00057 0.0050 6010U 02/20/07 12:0302/19/07 14:47Silver, Total 1

0.0048 mg/L 0.0047 0.010 6010 7020517I 02/20/07 12:0302/19/07 14:47Thallium, Total 1

70205170.0054 mg/L 0.0054 0.020 6010U 02/20/07 12:0302/19/07 14:47Zinc, Total 1

Wet Chemistry

Parameter

Analytical


Batch

Analysis

Method

Analysis

Date/Time

Prep

Date/TimeDFQ

0.018 mg/L 0.0040 0.0050 335.3 702058802/21/07 16:2502/21/07 9:00Cyanide, Total 1

70206560.015 mg/L 0.015 0.020 350.1U 02/23/07 15:4002/23/07 13:13Nitrogen, Ammonia (as N) 1

0.39 mg/L 0.091 0.25 351.2 702055502/20/07 15:2802/20/07 9:00Nitrogen, Kjeldahl, Total 1

4.0 mg/L 0.062 0.50 300.0 702050502/16/07 16:0002/16/07 16:00Nitrogen, Nitrate (as N) 1

0.30 mg/L 0.021 0.50 300.0 7020505I 02/16/07 16:0002/16/07 16:00Nitrogen, Nitrite (as N) 1

0.39 mg/L 0.091 0.25 Calc [CALC]02/23/07 15:4002/23/07 13:13Nitrogen, Organic 1

0.010 mg/L 0.0080 0.010 365.2 702062102/17/07 14:3002/17/07 14:30Orthophosphate as P 1

70206710.018 mg/L 0.018 0.020 420.2U 02/25/07 15:0002/23/07 15:56Phenols, Total 1

70205590.047 mg/L 0.047 0.10 365.4U 02/20/07 17:4702/19/07 9:00Phosphorus, Total 1



QUALITY CONTROL FOR :Q001202

RPD%RECPQL Analyte LimitRPDLimits%RECUnitsResult MDL

Prepared & Analyzed: 20-Feb-07Blank (7020548-BLK1)

Priority Pollutant Volatiles - Quality Control

1,1,1-Trichloroethane ug/L1.00.18 0.18U

1,1,2,2-Tetrachloroethane ug/L1.00.36 0.36U


1,1-Dichloroethane ug/L1.00.31 0.31U

1,1-Dichloroethene ug/L1.00.25 0.25U


1,2-Dichloropropane ug/L1.00.41 0.41U

2-Chloroethylvinyl ether ug/L5.02.2 2.2U

Acrolein ug/L102.0 2.0U

Acrylonitrile ug/L105.2 5.2U

Benzene ug/L1.00.36 0.36U

Bromodichloromethane ug/L1.00.26 0.26U

Bromoform ug/L1.00.41 0.41U

Bromomethane ug/L1.00.77 0.77U

Carbon tetrachloride ug/L1.00.15 0.15U

Chlorobenzene ug/L1.00.23 0.23U

Chlorodibromomethane ug/L1.00.30 0.30U

Chloroethane ug/L1.00.66 0.66U

Chloroform ug/L1.00.30 0.30U

Chloromethane ug/L1.00.72 0.72U

cis-1,3-Dichloropropene ug/L1.00.32 0.32U

Ethylbenzene ug/L1.00.33 0.33U

Methylene chloride ug/L5.00.42 0.42U

Tetrachloroethene ug/L1.00.34 0.34U

Toluene ug/L1.00.31 0.31U

trans-1,2-Dichloroethene ug/L1.00.38 0.38U

trans-1,3-Dichloropropene ug/L1.00.34 0.34U

Trichloroethene ug/L1.00.42 0.42U

Vinyl chloride ug/L1.00.31 0.31U

72-136Surrogate: 1,2-Dichloroethane-d4 112

79-117Surrogate: 4-Bromofluorobenzene 97.2

77-131Surrogate: Dibromofluoromethane 106

78-125Surrogate: Toluene-d8 88.0





Prepared & Analyzed: 20-Feb-07LCS (7020548-BS1)


79-1331051,1,1-Trichloroethane

78-1271171,1,2,2-Tetrachloroethane

77-12393.51,1,2-Trichloroethane

76-1271041,1-Dichloroethane

73-1421081,1-Dichloroethene

77-1251001,2-Dichloropropane

80-126104Benzene

82-118102Chlorobenzene

78-126112Chloroform

83-122104Ethylbenzene

76-12682.5Tetrachloroethene

77-12390.0Toluene

77-126112trans-1,2-Dichloroethene

79-12698.5Trichloroethene

67-12790.0Vinyl chloride


79-117Surrogate: 4-Bromofluorobenzene 102



Prepared & Analyzed: 20-Feb-07LCS Dup (7020548-BSD1)


2079-133112 6.451,1,1-Trichloroethane

2078-127116 0.8581,1,2,2-Tetrachloroethane

2077-12395.5 2.121,1,2-Trichloroethane

2076-127110 5.611,1-Dichloroethane

2073-142115 6.281,1-Dichloroethene

2077-125104 3.921,2-Dichloropropane

2080-126108 3.77Benzene

2082-118106 3.85Chlorobenzene

2078-126119 6.06Chloroform

2083-122108 3.77Ethylbenzene

2076-12688.5 7.02Tetrachloroethene

2077-12395.5 5.93Toluene

2077-126118 5.22trans-1,2-Dichloroethene

2079-126106 7.33Trichloroethene

2067-12795.0 5.41Vinyl chloride









Prepared & Analyzed: 20-Feb-07Matrix Spike (7020548-MS1) Source: Q001155-02







70-13099.51,2-Dichloropropane

70-130104Benzene


70-130113Chloroform

70-13093.5Ethylbenzene

70-13080.2Tetrachloroethene

70-13075.5Toluene















1,1,2,2-Tetrachloroethane ug/L1.00.36 0.36U



1,1-Dichloroethene ug/L1.00.25 0.25U


1,2-Dichloropropane ug/L1.00.41 0.41U

2-Chloroethylvinyl ether ug/L5.02.2 2.2U

Acrolein ug/L102.0 2.0U

Acrylonitrile ug/L105.2 5.2U

Benzene ug/L1.00.36 0.36U

Bromodichloromethane ug/L1.00.26 0.26U

Bromoform ug/L1.00.41 0.41U

Bromomethane ug/L1.00.77 0.77U

Carbon tetrachloride ug/L1.00.15 0.15U

Chlorobenzene ug/L1.00.23 0.23U

Chlorodibromomethane ug/L1.00.30 0.30U

Chloroethane ug/L1.00.66 0.66U

Chloroform ug/L1.00.30 0.30U

Chloromethane ug/L1.00.72 0.72U

cis-1,3-Dichloropropene ug/L1.00.32 0.32U

Ethylbenzene ug/L1.00.33 0.33U

Methylene chloride ug/L5.00.42 0.42U

Tetrachloroethene ug/L1.00.34 0.34U

Toluene ug/L1.00.31 0.31U

trans-1,2-Dichloroethene ug/L1.00.38 0.38U

trans-1,3-Dichloropropene ug/L1.00.34 0.34U

Trichloroethene ug/L1.00.42 0.42U

Vinyl chloride ug/L1.00.31 0.31U




78-125Surrogate: Toluene-d8 116








78-12795.61,1,2,2-Tetrachloroethane


76-12794.11,1-Dichloroethane

73-14299.01,1-Dichloroethene

77-12596.91,2-Dichloropropane

80-126108Benzene


78-12696.6Chloroform


76-126105Tetrachloroethene

77-12395.8Toluene

77-12692.9trans-1,2-Dichloroethene





77-131Surrogate: Dibromofluoromethane 96.8





2078-127103 7.451,1,2,2-Tetrachloroethane


2076-12784.5 10.81,1-Dichloroethane

2073-14285.0 15.21,1-Dichloroethene

2077-12588.5 9.061,2-Dichloropropane

2080-12693.5 14.4Benzene

2082-11894.0 7.18Chlorobenzene

2078-12684.5 13.4Chloroform

2083-12293.5 8.70Ethylbenzene

2076-12688.5 17.1Tetrachloroethene

2077-12385.5 11.4Toluene

2077-12682.5 11.9trans-1,2-Dichloroethene

2079-12683.0 17.7Trichloroethene

2067-12772.5 0.687Vinyl chloride

72-136Surrogate: 1,2-Dichloroethane-d4 98.5


77-131Surrogate: Dibromofluoromethane 90.0













70-1301221,2-Dichloropropane

70-130102Benzene

70-13099.5Chlorobenzene

70-130125Chloroform


70-130126Tetrachloroethene

70-130118Toluene


70-130116Trichloroethene





78-125Surrogate: Toluene-d8 118

Prepared: 19-Feb-07 Analyzed: 22-Feb-07Blank (7020498-BLK1)

Organochlorine Pesticides - Quality Control

4,4'-DDD ug/L0.00500.0022 0.0022U

4,4'-DDE ug/L0.00500.0041 0.0041U

4,4'-DDT ug/L0.00500.0034 0.0034U

Aldrin ug/L0.00500.0043 0.0043U

alpha-BHC ug/L0.00500.0040 0.0040U

beta-BHC ug/L0.00500.0043 0.0043U

Chlordane (tech) ug/L0.250.17 0.17U

delta-BHC ug/L0.00500.0042 0.0042U

Dieldrin ug/L0.00500.0030 0.0030U

Endosulfan I ug/L0.00600.0030 0.0030U

Endosulfan II ug/L0.00500.0014 0.0014U

Endosulfan sulfate ug/L0.0100.0077 0.0077U

Endrin ug/L0.100.015 0.015U

Endrin aldehyde ug/L0.00500.0038 0.0038U

gamma-BHC (Lindane) ug/L0.100.014 0.014U

Heptachlor ug/L0.100.010 0.010U

Heptachlor epoxide ug/L0.100.017 0.017U

Methoxychlor ug/L0.100.019 0.019U

Toxaphene ug/L0.500.48 0.48U

41-129Surrogate: Decachlorobiphenyl 114

42-129Surrogate: Tetrachloro-meta-xylene 115





Prepared: 19-Feb-07 Analyzed: 22-Feb-07LCS (7020498-BS1)


55-1311194,4'-DDD

57-1291104,4'-DDE

40-1791184,4'-DDT

56-120102Aldrin

59-13392.0alpha-BHC

41-113111beta-BHC

32-141113delta-BHC

51-133120Dieldrin

53-132103Endosulfan I

17-130106Endosulfan II

10-13470.4Endosulfan sulfate

45-13697.6Endrin

11-11691.6Endrin aldehyde

52-13493.2gamma-BHC (Lindane)

58-13181.2Heptachlor

49-131113Heptachlor epoxide

32-162117Methoxychlor

41-129Surrogate: Decachlorobiphenyl 52.0

42-129Surrogate: Tetrachloro-meta-xylene 79.6

Prepared: 19-Feb-07 Analyzed: 22-Feb-07LCS Dup (7020498-BSD1)


2055-131111 6.964,4'-DDD

2057-129104 5.614,4'-DDE

2040-17996.8 19.74,4'-DDT

2056-120108 5.71Aldrin

2059-13398.4 6.72alpha-BHC

2041-113110 0.905beta-BHC

2032-14190.8 21.8delta-BHC

2051-133116 3.39Dieldrin

2053-132106 2.87Endosulfan I

2017-13088.0 18.6Endosulfan II

2010-13449.6 34.7Endosulfan sulfate

2045-136100 2.43Endrin

2011-11669.2 27.9Endrin aldehyde

2052-13497.2 4.20gamma-BHC (Lindane)

2058-13180.4 0.990Heptachlor

2049-131115 1.75Heptachlor epoxide

2032-162105 10.8Methoxychlor




Polychlorinated Biphenyls - Quality Control

PCB-1016 ug/L0.250.12 0.12U

PCB-1221 ug/L0.250.070 0.070U

PCB-1232 ug/L0.250.018 0.018U

PCB-1242 ug/L0.250.070 0.070U

PCB-1248 ug/L0.250.070 0.070U

PCB-1254 ug/L0.250.070 0.070U

PCB-1260 ug/L0.250.17 0.17U









70-130102PCB-1248





2070-130102 0.00PCB-1248




Metals - Quality Control

Mercury, Total mg/L0.000200.000060 0.000060U



85-11590.5Mercury, Total



75-12593.7Mercury, Total

Prepared & Analyzed: 19-Feb-07Matrix Spike Dup (7020515-MSD1) Source: Q001202-02


2075-12595.8 2.22Mercury, Total



Antimony, Total mg/L0.00600.0028 0.0028U

Arsenic, Total mg/L0.0100.0043 0.0043U

Beryllium, Total mg/L0.00400.0013 0.0013U

Cadmium, Total mg/L0.00500.0013 0.0013U

Chromium, Total mg/L0.00500.0012 0.0012U

Copper, Total mg/L0.0100.0043 0.0043U

Lead, Total mg/L0.0150.0044 0.0044U

Nickel, Total mg/L0.00500.0016 0.0016U

Selenium, Total mg/L0.0100.0037 0.0037U

Silver, Total mg/L0.00500.00057 0.00057U

Thallium, Total mg/L0.0100.0047 0.0047U

Zinc, Total mg/L0.0200.045 0.0054







80-120102Antimony, Total

80-120102Arsenic, Total

80-120102Beryllium, Total

80-120102Cadmium, Total

80-120104Chromium, Total

80-120102Copper, Total

80-120103Lead, Total

80-120101Nickel, Total

80-120100Selenium, Total

80-120100Silver, Total

80-120103Thallium, Total

80-120102Zinc, Total

Prepared: 19-Feb-07 Analyzed: 20-Feb-07Matrix Spike (7020517-MS1) Source: Q001172-01


75-125105Antimony, Total

75-125107Arsenic, Total

75-125102Beryllium, Total

75-12599.0Cadmium, Total

75-125102Chromium, Total

75-125103Copper, Total

75-125101Lead, Total

75-12599.3Nickel, Total

75-125102Selenium, Total

75-125100Silver, Total

75-125101Thallium, Total

75-125101Zinc, Total

Prepared: 19-Feb-07 Analyzed: 20-Feb-07Matrix Spike Dup (7020517-MSD1) Source: Q001172-01


2075-125105 0.00Antimony, Total

2075-125108 0.930Arsenic, Total

2075-125103 0.976Beryllium, Total

2075-125100 1.01Cadmium, Total

2075-125103 0.976Chromium, Total

2075-125104 0.966Copper, Total

2075-125102 0.985Lead, Total

2075-125100 0.702Nickel, Total

2075-125103 0.976Selenium, Total

2075-125101 0.995Silver, Total

2075-125103 1.96Thallium, Total

2075-125102 0.985Zinc, Total


Wet Chemistry - Quality Control

Nitrogen, Nitrate (as N) mg/L0.500.062 0.062U

Nitrogen, Nitrite (as N) mg/L0.500.021 0.021U



80-110106Nitrogen, Nitrate (as N)

90-110116Nitrogen, Nitrite (as N)







2080-110105 0.948Nitrogen, Nitrate (as N)

2090-110114 1.74Nitrogen, Nitrite (as N)



Nitrogen, Kjeldahl, Total mg/L0.250.091 0.091U



90-110107Nitrogen, Kjeldahl, Total



2090-11088.5 18.9Nitrogen, Kjeldahl, Total



90-110121Nitrogen, Kjeldahl, Total



2090-110130 7.17Nitrogen, Kjeldahl, Total



Phosphorus, Total mg/L0.100.047 0.047U



80-120103Phosphorus, Total



2080-120103 0.00Phosphorus, Total



80-12073.0Phosphorus, Total



2080-12084.6 14.7Phosphorus, Total



Cyanide, Total mg/L0.00500.0040 0.0040U



80-120106Cyanide, Total







2080-120103 2.87Cyanide, Total



80-12090.5Cyanide, Total



2080-12089.8 0.776Cyanide, Total



Orthophosphate as P mg/L0.0100.0080 0.0080U



80-120107Orthophosphate as P



2080-120107 0.00Orthophosphate as P



80-120105Orthophosphate as P



2080-120107 1.89Orthophosphate as P



Nitrogen, Ammonia (as N) mg/L0.0200.015 0.015U



90-110106Nitrogen, Ammonia (as N)



2090-110106 0.00Nitrogen, Ammonia (as N)



90-110104Nitrogen, Ammonia (as N)



2090-11095.2 8.84Nitrogen, Ammonia (as N)







Phenols, Total mg/L0.0200.019 0.018I



80-12093.8Phenols, Total

Prepared: 23-Feb-07 Analyzed: 25-Feb-07LCS Dup (7020671-BSD1)


2080-12090.2 3.91Phenols, Total

Prepared: 23-Feb-07 Analyzed: 25-Feb-07Matrix Spike (7020671-MS1) Source: Q001132-03


80-120104Phenols, Total

Prepared: 23-Feb-07 Analyzed: 25-Feb-07Matrix Spike Dup (7020671-MSD1) Source: Q001132-03


2080-120106 1.90Phenols, Total



NOTES AND DEFINITIONS

Indicates the analyte was detected in both the sample and the associated method blank. The value in the method blank is

not subtracted from the associated samples.

V

Indicates the compound was analyzed for but not detected.U

Estimated value. See accompanying case narrative for a complete description.J

The reported value is between the laboratory method detection limit and the reporting limit.I

Quality control recovered outside acceptance criteria.#

Method Detection LimitMDL

Practical Quantitation LimitPQL

Dilution FactorDF

Percent Recovery%REC

Relative Percent DifferenceRPD



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