johnson seminar project
TRANSCRIPT
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GAS HYDRATE FORMATION ANDGAS HYDRATE FORMATION AND
PREVENTIONPREVENTION
MARCH, 2014MARCH, 2014
IN THE DEPARTMENT OF PETROLEUM ENGINEERING, FACULTY OFIN THE DEPARTMENT OF PETROLEUM ENGINEERING, FACULTY OF
ENGINEERING, RIVERS STATE UNIVERSITY OF SCIENCE ANDENGINEERING, RIVERS STATE UNIVERSITY OF SCIENCE AND
TECHNOLOGY NKPOLU-OROWORUKWO, PORT HARCOURT.TECHNOLOGY NKPOLU-OROWORUKWO, PORT HARCOURT.
Presented ByPresented By
COURSE TITLE:
SEMINAR/RESEARCH METHODOLOGYIN PETROLEUM ENGINEERING
COURSE CODE
PTE 511
SEMINAR CO-ORDIANTOR
ENGR. NMEGU
AMADI !OHNSONAMADI !OHNSON
DE" 200#/1125DE" 200#/1125
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TALE OF CONTENTTALE OF CONTENT
Abstract
Introduction
Definition of Gas Hydrate
Condition Necessary for the Formation of gas Hydrate
Major effect of gas hydrate
Importance of gas hydrate to the energy industry andsociety
Removing Gas Hydrate !oc"age in a #ystem
$reventing Gas Hydrate Formation
Conc!usion
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ASTRACTASTRACT
Gas hydrate is a so!id substances composed of %ater
and gas mo!ecu!es &main!y methane' and is a!so "no%
as c!athrate it occur %or!d%ide in the oceanic and po!ar
sediments %here temperate is !o% enough and pressure
is sufficient!y high to crysta!!i(e the methane into gas)
hydrates* #ince it discovery+ gas hydrate have attracted
interest as a potentia! energy resources
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INTRODUCTIONINTRODUCTION
Gas hydrate deposits a!ong ocean margin are estimated toe,ceed "no%n petro!eum reserves by a factor of three*-hese hydrate bed !ea" gases into the %ater forming co!dsee page %hich is common on continenta! marginsaround the %or!d* hydrate inf!uence ocean carbon cyc!ing+c!imate change+ and coasta! sediment stabi!ity*
.oca!i(ed me!t do%n can caused geo!ogica! ha(ard forshe!f oi! and gas production faci!ities*
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F$%. 1" S&'( H)*+ '% $ N3+ GF$%. 1" S&'( H)*+ '% $ N3+ G
P+'*3$' F$$$P+'*3$' F$$$
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WHAT ARE GAS HYDRATEWHAT ARE GAS HYDRATE
Gas hydrate is a so!id ice)!i"e form of %ater thatcontain gas mo!ecu!es in its mo!ecu!ar cavities in
nature+ this gas is most!y methane+
-hey are formed as a resu!t of physica!
combination of %ater and gas mo!ecu!es*
/n!i"e inorganic Hydrate &e*g C/#01* 2H30' the
ratio bet%een %ater and gas is not constant*
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F$% 2 S&'( & G H)*+ S+33+ ' D$+ GF$% 2 S&'( & G H)*+ S+33+ ' D$+ G
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CONDITION NECESSARY FOR THECONDITION NECESSARY FOR THE
FORMATION OF GAS HYDRATEFORMATION OF GAS HYDRATE
Four condition for the hydrate formation
Ade4uate gas mo!ecu!es to stabi!i(e most of the
hydrate cavities
#ufficient %ater mo!ecu!e to form the cavityA temperature %ithin the hydrate phase
e4ui!ibrium region*
A pressure %ithin the hydrate phase e4ui!ibriumregion*
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GEOLOGICAL SETTING WHERE GASGEOLOGICAL SETTING WHERE GAS
HYDRATE OCCURHYDRATE OCCUR
Gas hydrate occur in t%o discrete geo!ogica!
situation
5 Marine she!f sediment
5 $ermafrost region
Hydrate occur in these types of setting
because the pressure+ temperature condition
are %ithin the hydrate stabi!ity fie!d*
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F$% 6 S&'( G H)*+ $ M+$ S*$7F$% 6 S&'( G H)*+ $ M+$ S*$7
F$% 4 S&'( G H)*+ $ P+7+' 8'F$% 4 S&'( G H)*+ $ P+7+' 8'..
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MA!OR EFFECT OF GAS HYDRATE IN THE OILMA!OR EFFECT OF GAS HYDRATE IN THE OIL
AND GAS SECTOR.AND GAS SECTOR.
Gas hydrate cause !ot of damage to the oi! andgas sector and a!so to our environment %hich
inc!ude6
$ipe!ine b!oc"ageG!oba! c!imate change
#ubsea !and s!ides
Deep %ater dri!!ing and production
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F$% 5" S&'( & D7% ' D9 (+ 9+'*3$'.
F$% :" S&'( & 3; L*$*
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F$%
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IMPORTANCE OF GAS HYDRATE TO THEIMPORTANCE OF GAS HYDRATE TO THE
ENERGY INDUSTRY AND SOCIETYENERGY INDUSTRY AND SOCIETY
1= G H)*+ A+ P'$ E+%)R'3+.
the 4uantity of natura! gas in sedimentary gas hydratee,ceeds the conventiona! natura! gas resources* As aresu!t numerous studies have discussed the energypotentia! of gas hydrate &Co!!ett+ 7889+ 3003+ #assenand Mi!"ov+ 3009'+ /ti!i(ation of gas hydrate as anenergy resource has been hinder by !ac" of economic
method for producing the hydrate
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2=2= G H)*+ ' P) R' $ P * F33+G H)*+ ' P) R' $ P * F33+
C$7 C&%C$7 C&%
If these marine gas hydrate begin to rapid!y dissociate
into gas : %ater+ then the methane trapped in the
gas hydrate can be re!eased to the atmosphere* If
the inf!u, of methane to the atmosphere from
dissociating hydrate is sufficient in 4uantity+ this
methane can cause g!oba!+ %arming* -his process is
be!ieved to have inf!uence past c!imate changes*
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REMOVING GAS HYDRATE LOCKAGE IN AREMOVING GAS HYDRATE LOCKAGE IN A
SYSTEMSYSTEM
T&+'3%& H$%"Heat must be supp!ied %ith caution
beginning from the end and progressing to%ard the
midd!e of the p!ug* If hydrate p!ug is dissociated in the
midd!e+ the pressure might increase sudden!yT&+'3%& $&$;$'+ I>$'" Inhibitor injection %i!!shift the hydrate phase boundary to the !eft+ %hichcou!d resu!t in gas hydrate dissociation*
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PREVENTING GAS HYDRATEPREVENTING GAS HYDRATE
FOUR METHODS OF HYDRATE PREVENTION
5 Reducing the pressure be!o% that of the hydrate
formation for the given temperature;5 Maintaining the temperature of the gas f!o% above the
hydrate formation temperature for the given pressure;5 Reducing the de% point of %ater vapor in the gas f!o%
be!o% the operating temperature &drying the gas'5 Introducing various substance &a!coho!s+ e!ectro!ytes'
into gas f!o%+ %hich !o%er the hydrate formationpressure*
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CONCLUSIONCONCLUSION
Gas hydrates are formed as a resu!t of physica!combination of %ater and suitab!y si(ed
mo!ecu!es*
-here are huge amount of methane hydrates in
subsea sediments and permafrost regions*
-hey have very interesting properties+ %ith many
potentia! industria! app!ications*
-hey had significant impact on the past c!imate
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THANK YOU