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    GAS HYDRATE FORMATION ANDGAS HYDRATE FORMATION AND

    PREVENTIONPREVENTION

    MARCH, 2014MARCH, 2014

    IN THE DEPARTMENT OF PETROLEUM ENGINEERING, FACULTY OFIN THE DEPARTMENT OF PETROLEUM ENGINEERING, FACULTY OF

    ENGINEERING, RIVERS STATE UNIVERSITY OF SCIENCE ANDENGINEERING, RIVERS STATE UNIVERSITY OF SCIENCE AND

    TECHNOLOGY NKPOLU-OROWORUKWO, PORT HARCOURT.TECHNOLOGY NKPOLU-OROWORUKWO, PORT HARCOURT.

    Presented ByPresented By

    COURSE TITLE:

    SEMINAR/RESEARCH METHODOLOGYIN PETROLEUM ENGINEERING

    COURSE CODE

    PTE 511

    SEMINAR CO-ORDIANTOR

    ENGR. NMEGU

    AMADI !OHNSONAMADI !OHNSON

    DE" 200#/1125DE" 200#/1125

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    TALE OF CONTENTTALE OF CONTENT

    Abstract

    Introduction

    Definition of Gas Hydrate

    Condition Necessary for the Formation of gas Hydrate

    Major effect of gas hydrate

    Importance of gas hydrate to the energy industry andsociety

    Removing Gas Hydrate !oc"age in a #ystem

    $reventing Gas Hydrate Formation

    Conc!usion

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    ASTRACTASTRACT

    Gas hydrate is a so!id substances composed of %ater

    and gas mo!ecu!es &main!y methane' and is a!so "no%

    as c!athrate it occur %or!d%ide in the oceanic and po!ar

    sediments %here temperate is !o% enough and pressure

    is sufficient!y high to crysta!!i(e the methane into gas)

    hydrates* #ince it discovery+ gas hydrate have attracted

    interest as a potentia! energy resources

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    INTRODUCTIONINTRODUCTION

    Gas hydrate deposits a!ong ocean margin are estimated toe,ceed "no%n petro!eum reserves by a factor of three*-hese hydrate bed !ea" gases into the %ater forming co!dsee page %hich is common on continenta! marginsaround the %or!d* hydrate inf!uence ocean carbon cyc!ing+c!imate change+ and coasta! sediment stabi!ity*

    .oca!i(ed me!t do%n can caused geo!ogica! ha(ard forshe!f oi! and gas production faci!ities*

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    F$%. 1" S&'( H)*+ '% $ N3+ GF$%. 1" S&'( H)*+ '% $ N3+ G

    P+'*3$' F$$$P+'*3$' F$$$

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    WHAT ARE GAS HYDRATEWHAT ARE GAS HYDRATE

    Gas hydrate is a so!id ice)!i"e form of %ater thatcontain gas mo!ecu!es in its mo!ecu!ar cavities in

    nature+ this gas is most!y methane+

    -hey are formed as a resu!t of physica!

    combination of %ater and gas mo!ecu!es*

    /n!i"e inorganic Hydrate &e*g C/#01* 2H30' the

    ratio bet%een %ater and gas is not constant*

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    F$% 2 S&'( & G H)*+ S+33+ ' D$+ GF$% 2 S&'( & G H)*+ S+33+ ' D$+ G

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    CONDITION NECESSARY FOR THECONDITION NECESSARY FOR THE

    FORMATION OF GAS HYDRATEFORMATION OF GAS HYDRATE

    Four condition for the hydrate formation

    Ade4uate gas mo!ecu!es to stabi!i(e most of the

    hydrate cavities

    #ufficient %ater mo!ecu!e to form the cavityA temperature %ithin the hydrate phase

    e4ui!ibrium region*

    A pressure %ithin the hydrate phase e4ui!ibriumregion*

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    GEOLOGICAL SETTING WHERE GASGEOLOGICAL SETTING WHERE GAS

    HYDRATE OCCURHYDRATE OCCUR

    Gas hydrate occur in t%o discrete geo!ogica!

    situation

    5 Marine she!f sediment

    5 $ermafrost region

    Hydrate occur in these types of setting

    because the pressure+ temperature condition

    are %ithin the hydrate stabi!ity fie!d*

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    F$% 6 S&'( G H)*+ $ M+$ S*$7F$% 6 S&'( G H)*+ $ M+$ S*$7

    F$% 4 S&'( G H)*+ $ P+7+' 8'F$% 4 S&'( G H)*+ $ P+7+' 8'..

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    MA!OR EFFECT OF GAS HYDRATE IN THE OILMA!OR EFFECT OF GAS HYDRATE IN THE OIL

    AND GAS SECTOR.AND GAS SECTOR.

    Gas hydrate cause !ot of damage to the oi! andgas sector and a!so to our environment %hich

    inc!ude6

    $ipe!ine b!oc"ageG!oba! c!imate change

    #ubsea !and s!ides

    Deep %ater dri!!ing and production

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    F$% 5" S&'( & D7% ' D9 (+ 9+'*3$'.

    F$% :" S&'( & 3; L*$*

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    F$%

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    IMPORTANCE OF GAS HYDRATE TO THEIMPORTANCE OF GAS HYDRATE TO THE

    ENERGY INDUSTRY AND SOCIETYENERGY INDUSTRY AND SOCIETY

    1= G H)*+ A+ P'$ E+%)R'3+.

    the 4uantity of natura! gas in sedimentary gas hydratee,ceeds the conventiona! natura! gas resources* As aresu!t numerous studies have discussed the energypotentia! of gas hydrate &Co!!ett+ 7889+ 3003+ #assenand Mi!"ov+ 3009'+ /ti!i(ation of gas hydrate as anenergy resource has been hinder by !ac" of economic

    method for producing the hydrate

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    2=2= G H)*+ ' P) R' $ P * F33+G H)*+ ' P) R' $ P * F33+

    C$7 C&%C$7 C&%

    If these marine gas hydrate begin to rapid!y dissociate

    into gas : %ater+ then the methane trapped in the

    gas hydrate can be re!eased to the atmosphere* If

    the inf!u, of methane to the atmosphere from

    dissociating hydrate is sufficient in 4uantity+ this

    methane can cause g!oba!+ %arming* -his process is

    be!ieved to have inf!uence past c!imate changes*

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    REMOVING GAS HYDRATE LOCKAGE IN AREMOVING GAS HYDRATE LOCKAGE IN A

    SYSTEMSYSTEM

    T&+'3%& H$%"Heat must be supp!ied %ith caution

    beginning from the end and progressing to%ard the

    midd!e of the p!ug* If hydrate p!ug is dissociated in the

    midd!e+ the pressure might increase sudden!yT&+'3%& $&$;$'+ I>$'" Inhibitor injection %i!!shift the hydrate phase boundary to the !eft+ %hichcou!d resu!t in gas hydrate dissociation*

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    PREVENTING GAS HYDRATEPREVENTING GAS HYDRATE

    FOUR METHODS OF HYDRATE PREVENTION

    5 Reducing the pressure be!o% that of the hydrate

    formation for the given temperature;5 Maintaining the temperature of the gas f!o% above the

    hydrate formation temperature for the given pressure;5 Reducing the de% point of %ater vapor in the gas f!o%

    be!o% the operating temperature &drying the gas'5 Introducing various substance &a!coho!s+ e!ectro!ytes'

    into gas f!o%+ %hich !o%er the hydrate formationpressure*

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    CONCLUSIONCONCLUSION

    Gas hydrates are formed as a resu!t of physica!combination of %ater and suitab!y si(ed

    mo!ecu!es*

    -here are huge amount of methane hydrates in

    subsea sediments and permafrost regions*

    -hey have very interesting properties+ %ith many

    potentia! industria! app!ications*

    -hey had significant impact on the past c!imate

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    THANK YOU