international quality assurance programme (iqap) … · 2013. 10. 9. · o0lrtk heroin (dam) and...
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INTERNATIONAL QUALITY ASSURANCE PROGRAMME (IQAP)
INTERNATIONAL COLLABORATIVE EXERCISES (ICE)
Summary ReportSEIZED MATERIALS
2013/1
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This report contains the data received from laboratories participating in the current exercise. The results compiled in this report are not intended to be an overview of the quality of work and cannot be interpreted as such. These comments do not reflect the general state of the art within the profession.
Participant results are reported using a randomly assigned "WebCode". This code maintains participant's anonymity, provides linking of the various report sections, and will change with every report.
Samples Substances from the ICE Menu Concentrations Comments on substancesSample 1 Heroin 47.9 %
Caffeine N/A
Sample 2 Morphine 68.7 %
Sample 3 Lactose N/A
Nimetazepam 3.7 %
Sample 4 Amfetamine 10.3 %
Test Samples Information
Samples Comments on samplesSample 1 SM-1 was prepared from a seizure containing 47.9% Heroin base. The seizure also contained 6-
monoacetylmorphine, acetylcodeine, caffeine, papaverine, dextrometorphan and codeine. Trace amounts of morphine and noscapine could also be detected
Sample 2 SM-2 was prepared from a seizure containing 68.7% Morphine base. The seizure also contained codeine and trace amounts of 6-monoacetylmorphine and heroin.
Sample 3 SM-3 was prepared from a seizure containing 3.7% Nimetazepam. The seizure also contained lactose and glucose
Sample 4 SM-4 was prepared from a seizure containing 10.3% Amfetamine base. The seizure also contained sucrose and trace amounts of methamphetamine and diphenylisopropylamine
2013/1-SM Copyright (c) 2013 UNODC
INTERNATIONAL QUALITY ASSURANCE PROGRAMME (IQAP)INTERNATIONAL COLLABORATIVE EXERCISES (ICE)
Table of contents Introduction Page 3 Comments from the International Panel of Forensic Experts Page 3 Codes and Abbreviations Page 5 Sample 1 Analysis Page 6 Identified substances Page 6 Statement of findings Page 10 Identification methods Page 19 Summary Page 23 Z-Scores Page 24 Sample 2 Analysis Page 27 Identified substances Page 27 Statement of findings Page 30 Identification methods Page 38 Summary Page 42 Z-Scores Page 43 Sample 3 Analysis Page 45 Identified substances Page 45 Statement of findings Page 48 Identification methods Page 56 Summary Page 60 Z-Scores Page 61 Sample 4 Analysis Page 63 Identified substances Page 63 Statement of findings Page 66 Identification methods Page 74 Summary Page 78 Z-Scores Page 79
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Introduction An important element of the UNODC International Quality Assurance Programme (IQAP) is the implementation of the International Collaborative Exercises (ICE). The exercises allow laboratories, from both developing and developed countries, to continuously monitor their performance in drug testing on a truly global scale. This report provides information on analytical results of laboratories participating in the Seized Materials (SM) group. In order to maintain confidentiality, the participating laboratories have been assigned random “Web Codes”, which change every round. Two rounds are offered per year with each round presenting participants with four different test samples for analysis. The analytical results returned by laboratories participating in ICE are evaluated by UNODC and a confidential report is provided to each laboratory on its own performance. The overall analytical results are reviewed by the UNODC’s International Panel of Forensic Experts which oversees the implementation of these exercises, and offers guidance and support in addressing relevant quality issues. The exercises provide an overview of the performance and capacity of participating laboratories and enable UNODC to tailor technical support in the laboratory sector for greatest impact.
Comments from the International Panel of Forensic Experts Participation of Laboratories Samples within both the Seized materials (SM) and Biological Specimens (BS) test groups were sent to 165 laboratories in 57 countries. Within the SM test group, samples were sent to 139 laboratories and 132 laboratories (95%) submitted the results of their analysis in time for inclusion in the summary report, with 128 (97%) using the ICE portal for return of results. The almost universal usage of the ICE portal is a high endorsement of its utility. Some laboratories had difficulty in obtaining import authorization particularly for the new psychoactive substances included in the ICE menu and this resulted in an extension of the deadline for submission of results. It is hoped that these delays will be decreased in the future as both participants and competent authorities become more familiar with the international import/export requirements for these emerging substances. Qualitative Analysis The results for the qualitative identification of the controlled substances were good for all test samples in the SM group. In particular, with correct identification of the heroin in SM-1 and the morphine in SM-2 by 100% and 95% of participants respectively. SM-3 containing nimetazepam and SM-4 containing amphetamine were identified by 91% and 94% of participants respectively. Some 89.4% of participants overall used GC-MS for the qualitative analysis indicating access to this technique which is one of the most commonly used tandem techniques for the confirmation of controlled substances. It is encouraging to note that only six false positive results for controlled substances within the ICE menu were reported for the four test samples in the SM group, while there were a total of 24 false negative results. The seizure used for SM-1 contained at least nine components and 35 laboratories identified the trace amounts of morphine present. Participants who identified the morphine may have in error received a false positive result upon submission of results via the portal. As the amount of morphine present was low, those laboratories who did not identify it need not consider the result a false negative. For SM-4, five laboratories using GC/MS also identified trace amounts of methamphetamine present and similarly, this result need not be considered a false positive. The detection limits of the different analytical techniques shall be taken into consideration when ascribing false positive results in future ICE rounds. Quantitative Analysis A modified Z-score was used for the statistical examination of the quantitative results, as it is a robust method based on absolute deviations from the median of all participant values and is relatively insensitive to outliers. The proportion of participants who carried out quantitative analysis, 90 (68%) for SM-1, 54 (41%) for SM-2, 41 (31%) for SM-3 and 76 (58%) for SM-4 continues to be encouraging. The percentages of laboratories performing quantitative analysis for heroin has remained stable at 68% for ICE 2012/1, 70% for ICE 2012/2 and 68% for this current round. The percentages of laboratories performing quantitative analysis for morphine is also stable at 46% for ICE 2011/1 and 41% for the current round. Similarly, the percentages of laboratories performing quantitative analysis for amphetamine are comparable with 59% for
INTERNATIONAL QUALITY ASSURANCE PROGRAMME (IQAP)INTERNATIONAL COLLABORATIVE EXERCISES (ICE)
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both ICE 2011/2 and 2012/1, and 58% for the current round. Nimetazepam is a new substance on the ICE menu for this current round and it is encouraging to see 31% of laboratory already performing quantitative analysis for this drug. It is understood that quantitative analysis of controlled substances is often governed by local legislation and the prosecution requirements. Analysis of the Z-scores showed that 77 out of 90 (86%) of participants provided acceptable quantitative results with Z-scores within 3.5 for heroin in SM-1, 52 out of 54 (96%) for morphine in SM-2, 32 of 41 (78%) laboratories for nimetazepam in SM-3 and 68 of 76 (87%) for the amphetamine in SM-4. Participants with Z-scores outside acceptable limits should review their quantification procedures. 69% of participants in this round quantified at least one test sample and 30% quantified all four test samples. Z-score values obtained from quantitative analysis assist participating laboratories in evaluating their performance and Z-scores should be monitored over time as part of each laboratory’s quality assurance programme.
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Codes and Abbreviations
Tech Code Name140 Colorimetric reactions
141 Marquis reagent (sulphuric acid, formaldehyde)
142 Cobalt thiocyanate
150 Thin Layer Chromatography
160 High/Ultra High Performance Liquid Chromatography
161 High Performance Liquid Chromatography with diode array detection
170 Gas Chromatography NPD
171 Gas Chromatography FID
172 Gas Chromatography ECD
180 Gas Chromatography/Mass Spectrometry
190 Fourier Transform Infrared Spectrometry
200 Spectrophotometry (visible, UV)
210 Others (specify)
211 NMR
220 Microcrystal test
230 Liquid chromatography/mass spectrometry
231 Liquid chromatography/tandem mass spectrometry
(+) “positive”: Indicates that the analyte is identified; for presumptive tests (e.g. colour reactions), indicates that a positive reaction was obtained.
(-) “negative”: Indicates that the analyte is not identified.
(ANP): Analysis not performed.
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Identified substances for Test Sample 1
Code Identified Substances00H0DT heroin
0DAKSM Heroin
0SRDXD heroin
0T0BVS HEROINA
1HR18P Heroin, 6-Monoacetylmorphine, acetylcodeine
1R7FTA Heroin and Monoacetylmorphines
1SWNJJ heroin, caffeine
22JWSL Heroine
2ACHVO opiates
2FELET Heroin
2IOV6B héroine
2QK02D Heroína Clorhidrato
2SMWYX Herion,caffeine,6-monoacetylmorphine
3E3XE3 Heroin, 6-MAM, Acetylcodeine, Dextromethorphane, caffeine
400BTP Heroin
424NFI Heroin
4ED4U4 Diamorphine
4FLYLL HEROINE
4P9OST Heroin
4ZRH5B Heroine
5AL4YL Heroine and codeine
5ZSPFZ Heroin
6CS6GB Heroina
77H7IH Heroin
78CN24 morphine, héroïne, lidocaïne
7BREL7 Heroin, Monoacetylmorphine, Morphine
7H5WS7 heroine
88O8O8 heroin.morphine.
8KXYZQ Heroin
8LLTJE caffeine, dextromethorphane, morphine, 6-acetylcodeine, 6-monoacetylmorphine, diacethylmorphine
8QXEZ5 heroine
99WMWJ heroin,mprphine,codiene,papaverine
9EU3UC heroin
9WEC99 HEROIN; MORPHINE
AJWS6O Diamorphine
AMA50Q Heroin. Traces of dextromethorphan, codeine and morphine
APYADP we found heroin
B824TN Heroin and morphine
BBEBBB Heroin HCl
BPBBMB Heroin
Sample 1 Analysis
2013/1-SM Copyright (c) 2013 UNODC(6)
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Code Identified SubstancesBZBJBP Heroin
C2WUON Heroin,Morphine,Caffeine,Paracetamol
C5ZRZ2 HEROIN
CIIE5Y YES, MORPHINE Y CODEINE, ACETAMINOPHEN.)
CLW6JW Heroin
CQC6CC HEROIN
CSDDCC HEROIN CHLORHYDRATE
DDXKOD HEROIN. CAFFEINE
DVAVS7 heroin, caffeine
EIJIBE HEROIN
EK1BZR Heroin
EYBQOO Heroin, morphine
EYEEEV Heroin, codeine, papaverine, morphine, caffeine, 6-acetylmorphine, 6-acetylcodeine, dextromethorphan
F66RUS Heroin
FF11HE heroin
G9XDGK Heroine
GUEUUR Diamorphine
HPPPFP Héroin, probably morphine, 6MAM, acétylcodeine
HRHXY5 Heroin
HSJGXV Heroin
IBADDP Diamorphine, Caffeine, Dextromethorphan indicated
IQXIII heroin
IYZYBB opiates (heroin)
J9KZ5A Morphine, codeine, heroin
JBRMJJ Heroin
JCJPKW Diamorphine
JGOKP5 Heroin
JNYC8O Heroin, Morphine, Caffeine
JQIGMD HEROIN
JTSJJD Heroin, Caffeine
JUNUUU heroin, caffeine, acetylcodeine, 6-MAM
K7QIQW Heroin, Codeine, 6-monoacetylmorphine, Acetylcodeine, Dextromethorphan
KBTTYE heroin
KFTKVQ heroin, morphine
KW3BDH heroin (DAM) and monoacetylmorphine (MAM)
L1N1AS Heroin, Morphine
LACFSF Heroina, Cafeina
LLDWGL heroin
LTLGBL Heroin
LTXFMY Heroin; caffeine;Mephedrone
M5FWNJ heroin
MDPWHT heroin
MKND72 Heroin, Morphine, 6-monoacetylmorphine,Acetylcodeine
2013/1-SM Copyright (c) 2013 UNODC(7)
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Code Identified SubstancesMMHHSD Heroin
MRHASS Heroin
N0NNLS heroin
N1M8LG Heroin
N666MQ Heroin and Caffeine.
NA2AKJ Diamorphine HCL
NO9OBB Heroine HCl
NPDHYI heroin
O0LRTK heroin (DAM) and monoacetylmorphine (MAM)
OPBW2C Heroin
OVCNJF Heroin
PCIBIV dextromethorphan
PDGMFW Heroin, Morphine, O6-MAM, Codeine
PPHC9X heroin
PQLTDR heroin
PSOAIJ Heroin
PUS7H2 6-Monoacetilmorfina, Acetilcodeina, Morfina y Heroina
QJIQTJ Heroin
R8O18R Heroine
RIJOTJ heroin
RPGPEM heroin hydrochloride
RXGBPA heroine
S2O5GO Heroína
S6OORI heroine
SADCGQ Heroin, Morphine
SOQRQ9 HEROIN
SSOSVY Heroin
SSSCSJ heroin, morphine
T0QNTU Heroin
TBBUSK heroin, morphine
TDDURM DIACETIYL MORPHFINE (HEROIN) (MORPHINE)
TXQHJG heroin, caffeine, 6 Mono acetilmorphine and acetilcodeine.
UHMVSZ HEROINA, MORFINA, CODEINA, MONOACETILMORFINA Y CAFEINA
UT6VEX 6-Monoacetylmorphine and Diacetylmorphine
UTL3JI Heroin
VFLGQF Heroin,
VLZ8LL heroine, morphine
VMSX5E HEROIN HCL
W4SM4Y Heroin
WKJAI3 heroine
WPYVIW Base Heroin
XKGJ2G Diamorphine
XPE2VZ Heroin
YCSW1Z heroin
2013/1-SM Copyright (c) 2013 UNODC(8)
INTERNATIONAL QUALITY ASSURANCE PROGRAMME (IQAP)INTERNATIONAL COLLABORATIVE EXERCISES (ICE)
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Code Identified SubstancesYETFFI Heroin hydrochloride
YULAAJ heroin, caffeine
YYMCDP heroin
Z4FNNZ Heroin
2013/1-SM Copyright (c) 2013 UNODC(9)
INTERNATIONAL QUALITY ASSURANCE PROGRAMME (IQAP)INTERNATIONAL COLLABORATIVE EXERCISES (ICE)
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Code Caffeine Heroin00H0DT - +
Heroin is controlled by law (KB 31/12/1930 changed by KB 8/10/1963).
0DAKSM - +The sample contains the controlled drug heroin 47.36 %, m/m.
0SRDXD + +The powder is a mixture of heroin and caffeine. The concentration of heroin in the sample is 47.3% by weight
0T0BVS ANP +La sustancia analizada se trata de heroína
1HR18P + +Caffeine
1R7FTA + +Based on the above analysis, the sample was found to contain Heroin and Monoacetylmorphines
1SWNJJ + +
22JWSL + +The sample SM-1 contains a mixture of caffeine, heroine, 6-acetylcodeine and dextromethorphan.
2ACHVO + +heroinmorphinecafeineacetyl codeine
2FELET - +SM-1 was found to be contain Heroin. Monoacetyl Morphine and acetyl codeine also was detected in this sample
2IOV6B + +6 monoacetylmorphine , acetylcodéine, levometorphane, papvérine, noscapine
2QK02D + +Se detectan cafeína, 6-Monoacetilmorfina, Acetilcodeína y Codeína.
2SMWYX + +SM1 was prepared from a seizure containing 39.8% w/w herion base. The seizure also contained caffeine and 6-monoacetylmorphine.
3E3XE3 + +
400BTP + +In the dust sample analyzed was detected the presence of Heroin, Acetylcodeine,6 monoacetylmorphine and caffeine.
Statement of findings for Test Sample 1
2013/1-SM Copyright (c) 2013 UNODC(10)
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Code Caffeine Heroin424NFI + +
Sample 2013/1/SM-1 consists of light yellow powder. Heroin, a prohibited sudstance included in the National Law for Narcotics, is found to be present in this sample. The seizure also contains morphine, codeine, methadone, acetylcodeine and 6-mono-acetyl-morphine.
4ED4U4 + +0.228 grams of a powder containing 54% Diamorphine. Diamorphine is a Class A controlled drug subject to the provisions of the Misuse of Drugs Act 1971.
4FLYLL + +
4P9OST + +Sample 2013/1/SM-1 was found to contain controlled substance HEROIN, a Schedule I drug under the Single Convention on Narcotic Drugs.
4ZRH5B + +the sizure also contained heroine, acetylcodeine, 6-monoacetylmorphine, dextrometorphan, cofeine and trace amounds of codeine and morphine
5AL4YL + +
5ZSPFZ + +we found aswell in this sample caffeine and 6-acetyl morphineand acetyl codeine
6CS6GB + +Cafeina, Acetil Codeina, 6-Monoacetil Morfina
77H7IH + +We found Heroin in SM-1 as controlled drug
78CN24 - +l'analyse de l'échantillon 2013/1/SM-1 révèle la présence de la morphine, de l'héroïne et de la lidocaïne
7BREL7 + +On analysis, i found the substances to contain 47.59% of heroin, 1.31% of morphine and 16.09% of monoacetylmorphine
7H5WS7 ANP +The seizure contained heroine
88O8O8 ANP +
8KXYZQ + +Sample contain heroin. The sample contain also caffeine, acetyl-codeine, and 6-monoacetyl-morphine
8LLTJE + +heroin was as hydrochloride form
8QXEZ5 + +heroine, caffeine, dextromethorphane,6-monoacetylmorphine,morphine,codeine
2013/1-SM Copyright (c) 2013 UNODC(11)
INTERNATIONAL QUALITY ASSURANCE PROGRAMME (IQAP)INTERNATIONAL COLLABORATIVE EXERCISES (ICE)
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Code Caffeine Heroin99WMWJ + +
the sample conatins 41.2 % Heroin and 2.8 % Morphine
9EU3UC + +
9WEC99 + +/
AJWS6O ANP +One glass bottle labelled '2013/1/SM-1 containing 0.225g of beige coloured powder. This powder contained on average of 45% diamorphine which is commonly referred to as 'heroin'. Diamorphine is a class A controlled drug under the misuse of Drugs Act (1971)(as ammended).
AMA50Q + +Cream-coloured powder containing heroin. Also dected traces of dextromethorphan, codeine and morphine, as well as acetylcodeine, monoacetylmorphine and caffeine.
APYADP + +the sample also contains caffeine and 6MAM and acetylcodeine as metabolites
B824TN + +Heroin and morphine and caffeine
BBEBBB + +SM 1 contain also Coffeine and Dextromethorphan
BPBBMB + +SM-1 was identified as illicit Heroin
BZBJBP + +Heroin. The seizure also contained 6-monoacetylmorphine, acetylcodein, dextromethorphan and trace amounds of morphine, codeine and morphine-3-acetate
C2WUON + +-
C5ZRZ2 + +CAFFEINE, ACETYLCODEINE, MONOACETILMORPHINE
CIIE5Y + +IN THE SAMPLE RECEIVED IN BOTTLE AMBER LID GREEN LETTERING 2013/1/SM-1 WAS FOUND HEROIN, MORPHINE, CAFFEINE, CODEINE, PAPAVERINE AND NOSCAPINE.
CLW6JW + +Diluted with caffeine
CQC6CC + +HEROIN 48.2% AS BASE. CAFFEINE WAS IDENTIFIED AS ADULTERANT
CSDDCC + +caffein, glucose
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Code Caffeine HeroinDDXKOD + +
The sample 2013/1/SM-1 was found to contain and Caffeine.
DVAVS7 + +The sample contains heroin which is scheduled as illicit drug in XXXX. Caffeine is also present as cutting agent.
EIJIBE + +HEROIN CHLORIDRATE (45.4% as base) - CAFFEINE
EK1BZR + +The powder was analysed and found to contain heroin (diamorphine).
EYBQOO + +SM-1 contains heroin, 46% and trace quantity of morphine
EYEEEV + +*Results of screening tests were positive for opiates. *Retention time and fragmentation pattern obtained with the sample are equivalent to those obtained with heroin, codeine, papaverine, morphine, caffeine, 6-acetylmorphine, 6-acetylcodeine and dextromethorphan.
F66RUS + +Sample contain drug- Heroin
FF11HE + +mixture of heroin and coffeine
FNZI88 + +
G9XDGK + +The sample SM1 contained 44.1 % heroine calculated as a base.In this sample was identified caffenie, dextromethorphan, codeine, acethylcodeine, 6-monoacetylmorphine, diacetylmorphine (heroine), papaverine, noscapine
GUEUUR + +One glass vial with lid attached containing 218mg of pale brown powder containing an average of 46% diamorphine (heroin) together with the adulterant caffeine.
HPPPFP + +Morphine, 6MAM, acetylcodeine are not quantified routinely in our laboratory
HRHXY5 + +The saple contains heroin (47.2%), caffeine, acetylcodeine and 6-monoacetylmorphine.
HSJGXV + +Heroin (47.65% base), caffein, monoacetylmorphine and acetylcodeine.
IBADDP + +On analysis, the powder was found to contain diamorphine.
2013/1-SM Copyright (c) 2013 UNODC(13)
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Code Caffeine HeroinIQXIII + +
found heroin with 46.3% w/w , 6-monoacetylmorphine, 6-acetylcodeine, caffeine, levomethorphan and oleamide
IYZYBB + +we have not received standards
J9KZ5A + +Souble in Methanol, The Sample contains 47.5% Heroine, 1.7% Morphine as a base. In the sample was identified caffeine as adulterant .
JBRMJJ + +
JCJPKW + +Brown powder found to contain diamorphine at a concentration of 41 per cent
JGOKP5 + +Related compound: Morphine;Adulterant: Caffeine
JNYC8O + +50.71% +/- 5.58% Heroin detected in sample SM-1.Morphine detected in sample SM-1 but quantitation not performed.
JQIGMD + +THE SAMPLE ALSO CONTAINS CAFEIN AND d,l-methorphan
JTSJJD + +At first Screening Test was performed and confirmed by TLC method in two different solvent system.
JUNUUU + +color test : Marquis = purple violet , Mecke = deep green , Frohde = purple becoming green/purple TLC : TA = heroin or 6-MAM , system diehtylether :acetone: diethylamine (85:8:7) = heroin, acetylcodeine, 6-MAM, caffeine
GC : Heroin base = 46.13%, caffeine 9.81%GC/MS : Heroin, acetylcodeine, 6-MAM ,caffeine
K7QIQW + +Heroin was found and the purity was 53.41%. Other drugs found were Codeine, 6-monoacetylmorphine, Acetylcodeine, Dextromethorphan.
KBTTYE ANP +After analysis, the sample was found to contain heroin.
KFTKVQ + +On analysis, I found the substance to contain morphine and 46.99% Heroin.
KW3BDH + +powder containing 43.1% of heroin and 13.9% of 6-monoacetylmorphine. The sample contains also caffeine, methorphan and acetylcodeine not quantified
L1N1AS + +heroin and Morphine were identified by TLC and GC/MS. Caffeine and lactose were also identified by TLC and GC/MS
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Code Caffeine HeroinLACFSF + +
Las pruebas químicas y la coincidencia en los tiempos de retención y fragmentos de masas del material de referencia usado en las mismas condiciones que la muestra analizada, indican la presencia de heroina y cafeina.
LLDWGL + +Sample contains 49.4 ± 2.9 % heroin-base. Sample also contains caffeine, acetylcodeine, 6-monoacetylmorphine, papaverin and dextrometorphan.
LTLGBL + +
LTXFMY + +Marquis reagent, Scott reagent have been applied, the TLC and GC/FID
M5FWNJ + +caffeine, acetylcodeine, 6-monoacetylmorphine, papaverine, dextrometorphan
MDPWHT + +The sample is heroin.
MKND72 + +
MMHHSD + +Beige, fine powder with acrid smell, tested positive for Heroin, a substance listed in Table A of the Law on Addictive Substances.
MRHASS + +The sample contains heroin, 6-monoacetylmorphine, acetylcodeine and caffeine.
N0NNLS + +
N1M8LG + +We also found 6-acethyl-codeine, 6-acethyl-morphine, caffein, papaverine and noscapine and traces of dextrometrorphane, codeine and morphine and also traces of glucose and lactose.
N666MQ + +Applied chemical tests and instrumental chemical analysis, that sample 2013/1/SM1 contains Heroin and Caffeine.
NA2AKJ ANP +One brown glass bottle containing 222mg of a yellow powder. this yellow powdercontained an average of 58% of diamorphine hydrochloride (also known as heroin).
NO9OBB + +The power contained Heroine chlorhydrate with caféine.
NPDHYI + +Presence of heroin hydrochloride, acetylcodeine, monoacetylmorphine, papaverine, noscapine, methorphan, glucose and caffeine was detected in the sample.
O0LRTK + +white powder containing heroin (52.1%) and monoacetylmorphine (6.6%). It contains also acetylcodeine and caffeine
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Code Caffeine HeroinOPBW2C - +
OVCNJF + +Beige powder containing Heroin with a 37.99% as a base.
PCIBIV + +
PDGMFW + +Caffeine, Metorphan, Noscapine, Papaverine, Acetyl Codeine
PPHC9X + +powder contains heroin with caffeine
PQLTDR + +acetil-kodein, 6-MAM, koffein, dextromorphan
PSOAIJ ANP +Positive to heroin , contains morphine, 6- Monoacetylmorphine, Acetylcodein
PUS7H2 + +Cafeina y Dextromethorphan
QJIQTJ +
R8O18R + +Powder contains Heroine wich is a controlled substance
RIJOTJ + +yellow powder containing heroin (42.1%), 6-monoacetylmorphine, acetylcodeine, and caffeine.
RPGPEM + +sample contains also caffeine, O6-monoacetylmorphine and acetylcodeine
RXGBPA + +cafeine, dextromethorphane, morphine, acetylcodeine,6MAM,noscapine
S2O5GO ANP +Pruebas colorimétricas, Marquis, Lieberman, FT-IR, UV-visible y TLC
S6OORI + +acetyl-codein, 6-monoacetyl-morphine, dextromorphan,
SADCGQ + +
SOQRQ9 + +POWDER CONTAINING HEROIN. ADDITIONALLY IDENTIFIED CAFFEINE, ACETYLCODEINE, 6-MONOACETYLMORPHINE, METHORPHAW, STEREOCHEMICAL COMPOSITION NOT DETERMINED.
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Code Caffeine HeroinSSOSVY + +
The sample contains heroin which is listed as a controlled drug according to XXX order, appendix I of February 22nd 1990.
SSSCSJ - +
T0QNTU + +In the test sample 2013/1/SM-1 were detected heroin, acetylcodeine, 6-monoacetylmorphine, noscapine, dextromethorphan and caffeine
TBBUSK + +browny powder, other alkaloids - papaverine, morphine, noscapine, and 6-MAM, dextromethorphan, caffeine as diluent ingredient
TDDURM + +The sample correspond: Diacetyl (morphine) mixed with morphine, cafeine and dextrormetofano.
TXQHJG + +
UHMVSZ + +
UT6VEX - +Test sample 2013/1/SM-1 was found to contain the following controlled drugs 6-Monoacetylmorphine and Diacetylmorphine
UTL3JI - +The results of the tests of the SM 1 (20) received confirmed that the mentioned sample contains heroín with 56.3 percentage by weight (56.3%)
VFLGQF + +The sample was founf to contain Heroin, 6-MAM, acetylcodeine, Dextrometorphan and caffeine
VLZ8LL + +The sample SM-1 found to contain 47,5 % heroine, 2,2 % morphine. The seizure also contains caffeine, dextromethorphan, codeine, acetylcodeine, 6-monoacetylmorphine, papaverine, noscapine.
VMSX5E + +caffeine 10.84, acetylcodeine, 06 Monoacetylmorphine, noscapine, papaverine, glucose
W4SM4Y + +One glass bottle containing 0.22 grammes of a mixture containing 0.11 grammes of heroin hydrochloride (being a salt of heroin).
WKJAI3 + +CR, TLC, FTIR, GC, GC/MS
WPYVIW + +Base Heroin 47,2 +/-2,14% (w/w); Acetylcodeine, 6-Monoacetylmorphine, Morphine,Dextrometorphane, Caffeine
XKGJ2G + +The sample was found to contain 46.5% of diamorphine (as base).
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Code Caffeine HeroinXPE2VZ + +
In the 0,225 g unknown powder it is found 39% Heroin.
YCSW1Z + +This sample also contains 6-monoacetyl-morphine, acetyl-codeine, dextrometorphan and caffeine.
YETFFI + +This sample contains heroin HCl (44.9 % as base) cut with caffein (10.7%), dextromethorphan (
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Identification methods for Test Sample 1
Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
00H0DT I S
0DAKSM I SI
0SRDXD I I I SI I I XRD
0T0BVS SI I
1HR18P I SI
1R7FTA S I
1SWNJJ I SI SI
22JWSL S S I I
2ACHVO SI I
2FELET S S I I
2IOV6B SI I I I
2QK02D SI S I I SI I
2SMWYX SI
3E3XE3 SI
400BTP S S I I
424NFI S S I I I I
4ED4U4 S S I
4FLYLL I SI
4P9OST S I
4ZRH5B SI
5AL4YL S I
5ZSPFZ S I
6CS6GB S I
77H7IH S I I
78CN24 S I
7BREL7 S S S I
7H5WS7 I SI
88O8O8 SI S S I
8KXYZQ SI ASAP-TOF
8LLTJE S I
8QXEZ5 SI I I I I
99WMWJ SI
9EU3UC S I I
9WEC99 I SI SI
Analytical Technique Codes
Legend: S ... used for Screening I ... used for Identification SI ... used for both
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Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
AJWS6O S S I
AMA50Q S SI I SI
APYADP S S I
B824TN I I SI I
BBEBBB I S I I I
BPBBMB S SI I I
BZBJBP SI I
C2WUON SI
C5ZRZ2 S I I
CIIE5Y S S S I
CLW6JW S S S I I
CQC6CC I SI I
CSDDCC SI
DDXKOD S S S I I
DVAVS7 I SI
EIJIBE S S S I
EK1BZR S S I I
EYBQOO SI S S S I I I
EYEEEV S S I I
F66RUS I SI I I LCMS
FF11HE S I I I I
FNZI88 SI
G9XDGK I I
GUEUUR S S I I
HPPPFP S I I SI I
HRHXY5 S S I I
HSJGXV S I
IBADDP I
IQXIII SI
IYZYBB I I S IMMUNOCHEMICAL
J9KZ5A I I SI
JBRMJJ SI
JCJPKW S S I
JGOKP5 I SI
JNYC8O S S I I
JQIGMD S S I I
JTSJJD S S I S 210(Fast Blue B salt Test)
JUNUUU S I I I
K7QIQW S S S I
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Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
KBTTYE S I
KFTKVQ S S S I
KW3BDH SI
L1N1AS S S S I I
LACFSF S S I
LLDWGL SI SI
LTLGBL S S S I I
LTXFMY S SI S I
M5FWNJ S SI I
MDPWHT S I I
MKND72 S S SI SI
MMHHSD S S S I I
MRHASS SI
N0NNLS S I I
N1M8LG SI I
N666MQ S S I
NA2AKJ I I
NO9OBB I SI I
NPDHYI S S S S I I I
O0LRTK I I SI
OPBW2C I SI
OVCNJF S S S I I
PCIBIV I S S SI I SI I
PDGMFW I I SI
PPHC9X SI I
PQLTDR S SI I I
PSOAIJ S I I
PUS7H2 S I
QJIQTJ I
R8O18R SI I I
RIJOTJ SI
RPGPEM S I I I
RXGBPA SI I
S2O5GO I S I I SI I I I liberman
S6OORI I SI I
SADCGQ I SI
SOQRQ9 SI
SSOSVY I I
SSSCSJ I SI
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Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
T0QNTU I
TBBUSK SI I
TDDURM I SI
TXQHJG S I I
UHMVSZ S S I I
UT6VEX SI
UTL3JI S I
VFLGQF I S Immunochromatography
VLZ8LL S S S S I I
VMSX5E SI
W4SM4Y S S I SI I
WKJAI3 SI S SI I I
WPYVIW S S S I I I I XRD
XKGJ2G SI I UPHLC/ELSD
XPE2VZ S I I
YCSW1Z I SI I
YETFFI S S I I
YULAAJ S S I
YYMCDP S I
Z4FNNZ S I I I RAMAN
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Section
Response SummaryParticipants: 132
Caffeine: 114
Heroin: 132
Frequency of use of screening and identification techniques:
Summary for test sample 1The response summary of all 126 participating laboratories for the identification of SM-1, frequency of use of screening andidentification techniques and false positives and negatives:
Identification of test sample 1:
False positives for Test Sample 1 (controlled substances)
Code Name TechniqueLTXFMY Mephedrone 141, 150
Section 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
Screening 42 50 35 18 0 2 0 2 45 7 0 0 0 1 4
31.8% 37.9% 26.5% 13.6% 0.0% 1.5% 0.0% 1.5% 34.1% 5.3% 0.0% 0.0% 0.0% 0.8% 3.0%
Identification 10 5 2 32 9 15 1 21 118 45 2 2 2 3 7
7.6% 3.8% 1.5% 24.2% 6.8% 11.4% 0.8% 15.9% 89.4% 34.1% 1.5% 1.5% 1.5% 2.3% 5.3%
# labs using this technique
47 52 37 41 9 16 1 22 118 46 2 2 2 3 1035.6% 39.4% 28.0% 31.1% 6.8% 12.1% 0.8% 16.7% 89.4% 34.8% 1.5% 1.5% 1.5% 2.3% 7.6%
Response Summary Participants: 132
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Z-Scores for Test Sample 1
CODEHeroinMAD: 1.7
Conc. * AbsDev ZScore
00H0DT 47.2 0.0 0.0
0DAKSM 47.4 0.2 0.1
0SRDXD 47.3 0.1 0.0
1HR18P 49.6 2.4 0.9
1SWNJJ 47.0 0.2 0.1
22JWSL 46.0 1.2 0.5
2FELET 77.9 30.7 12.0
2IOV6B 47.4 0.2 0.1
2SMWYX 39.8 7.4 2.9
3E3XE3 44.3 2.9 1.1
4ED4U4 54.0 6.8 2.7
4FLYLL 63.0 15.8 6.2
4P9OST 50.0 2.8 1.1
4ZRH5B 49.3 2.1 0.8
5ZSPFZ 45.6 1.6 0.6
7BREL7 47.6 0.4 0.2
88O8O8 47.2 0.0 0.0
8LLTJE 65.2 18.0 7.0
8QXEZ5 43.0 4.2 1.6
99WMWJ 41.2 6.0 2.3
9EU3UC 47.9 0.7 0.3
9WEC99 46.5 0.7 0.3
AJWS6O 45.0 2.2 0.9
BBEBBB 45.5 1.7 0.7
BPBBMB 36.0 11.2 4.4
BZBJBP 52.5 5.3 2.1
C2WUON 50.1 2.9 1.1
C5ZRZ2 49.9 2.7 1.1
CQC6CC 48.2 0.9 0.4
CSDDCC 47.0 0.2 0.1
DVAVS7 46.0 1.2 0.5
EIJIBE 45.4 1.8 0.7
EYBQOO 46.0 1.2 0.5
FF11HE 22.0 25.2 9.8
FNZI88 48.9 1.7 0.7
G9XDGK 44.1 3.1 1.2
GUEUUR 46.0 1.2 0.5
HPPPFP 46.0 1.2 0.5
HRHXY5 47.2 0.0 0.0
HSJGXV 47.7 0.4 0.2
IBADDP 49.0 1.8 0.7
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CODEHeroinMAD: 1.7
Conc. * AbsDev ZScore
IQXIII 46.3 0.9 0.4
IYZYBB 61.3 14.1 5.5
J9KZ5A 47.5 0.3 0.1
JBRMJJ 56.3 9.1 3.6
JCJPKW 41.0 6.2 2.4
JGOKP5 45.7 1.5 0.6
JNYC8O 50.7 3.5 1.4
JQIGMD 46.7 0.5 0.2
JUNUUU 46.1 1.1 0.4
K7QIQW 53.4 6.2 2.4
KBTTYE 48.2 1.0 0.4
KFTKVQ 47.0 0.2 0.1
KW3BDH 43.1 4.1 1.6
L1N1AS 48.1 0.9 0.4
LLDWGL 49.4 2.2 0.9
MDPWHT 48.2 1.0 0.4
MKND72 52.5 5.3 2.1
MMHHSD 45.2 2.0 0.8
MRHASS 33.3 13.9 5.4
N1M8LG 64.9 17.7 6.9
NA2AKJ 51.0 3.8 1.5
NO9OBB 46.7 0.5 0.2
NPDHYI 45.0 2.2 0.9
O0LRTK 52.1 4.9 1.9
OPBW2C 45.2 2.0 0.8
OVCNJF 38.0 9.2 3.6
PDGMFW 47.8 0.6 0.2
PPHC9X 48.2 1.0 0.4
RIJOTJ 42.1 5.1 2.0
RPGPEM 48.0 0.8 0.3
RXGBPA 52.7 5.5 2.1
SADCGQ 52.6 5.4 2.1
SOQRQ9 47.4 0.2 0.1
SSOSVY 45.5 1.7 0.7
SSSCSJ 59.0 11.8 4.6
T0QNTU 48.0 0.8 0.3
TBBUSK 49.0 1.8 0.7
UHMVSZ 33.5 13.7 5.3
UTL3JI 56.3 9.1 3.6
VLZ8LL 47.5 0.3 0.1
VMSX5E 47.1 0.1 0.1
W4SM4Y 46.2 1.0 0.4
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CODEHeroinMAD: 1.7
Conc. * AbsDev ZScore
WKJAI3 46.0 1.2 0.5
WPYVIW 47.2 0.0 0.0
XKGJ2G 46.5 0.7 0.3
XPE2VZ 39.0 8.2 3.2
YETFFI 44.9 2.3 0.9
YULAAJ 47.6 0.4 0.2
YYMCDP 40.6 6.6 2.6
*) Concentration: w/w %
Z-Score has been calculated as modified Z-Score as it is a robust method and therefore relatively insensitive to outliers.Modified Z-Score = 0.6745 * AbsDev/MADAbsDev = Absolute value of the difference between a laboratory value and the median of all the laboratory values for the given drug;MAD = median absolute deviation about the median.Modified Z-scores with an absolute value of greater than 3.5 should be considered as potential outliers.Reference:Iglewicz, B. and Hoaglin, D. C.: 1993 How to Detect and Handle Outliers, American Society for Quality Control, Milwaukee, WI
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Substance: SM-1/Heroin 1.7MAD =Lab Median = 47.2
Round: 2013/1
Z-Score has been calculated as modified Z-Score as it is a robust method and therefore relatively insensitive to outliers.Modified Z-Score = 0.6745 * AbsDev/MADAbsDev = Absolute value of the difference between a laboratory value and the median of all the laboratory values for the given drug;MAD = median absolute deviation about the median.Modified Z-scores with an absolute value of greater than 3.5 should be considered as potential outliers.Reference:Iglewicz, B. and Hoaglin, D. C.: 1993 How to Detect and Handle Outliers, American Society for Quality Control, Milwaukee, WI
Z-Score Report per Sample per Substance
UNODC value = 47.9
(26)
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Identified substances for Test Sample 2
Code Identified Substances00H0DT morphine
0DAKSM Morphine
0SRDXD morphine, codeine
0T0BVS MORFINA
1HR18P Morphine, Codeine
1R7FTA Morphine and Codeine
1SWNJJ morphine
22JWSL Morphine
2ACHVO opiates
2FELET Morphine
2IOV6B morphine
2QK02D Morfina
2SMWYX Morphine,codeine.
3E3XE3 Morphine, Codeine
400BTP Morphine
424NFI Morphine
4ED4U4 Morphine & Codeine
4FLYLL MORPHINE
4P9OST Morphine
4ZRH5B morphine
5AL4YL Morphine
5ZSPFZ morphine, codeine
6CS6GB Morfina
77H7IH Morphine
78CN24 Morphine
7BREL7 Morphine
7H5WS7 morphine
88O8O8 morphine
8KXYZQ Morphine
8LLTJE codeine, morphine
8QXEZ5 morphine
99WMWJ Codeine and Morphine
9EU3UC Morphine
9WEC99 MORPHINE; CODEIN
AJWS6O Codeine and morphine
AMA50Q Morphine, as well as codeine
APYADP we found morphine
B824TN Morphine
BBEBBB Morphine HCL
BZBJBP codeine and morphine
Sample 2 Analysis
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Code Identified SubstancesC2WUON Morphine
C5ZRZ2 MORPHINE
CIIE5Y YES, MORPHINE Y CODEINE.
CLW6JW Morphine
CQC6CC MORPHINE
CSDDCC MORPHIN CHLORHYDRATE, CODEIN
DDXKOD MORPHINE
DVAVS7 morphine
EIJIBE MORPHINE
EK1BZR Morphine and codeine
EYBQOO Morphine
EYEEEV morphine, codeine
F66RUS Morphine
FF11HE morfphine
G9XDGK Morphine, codeine
GUEUUR Codeine and morphine
HPPPFP Morphine and codeine
HRHXY5 Morphine
HSJGXV Morfine
IBADDP Codeine, Morphine
IQXIII morphine
IYZYBB opiates (morphine)
J9KZ5A Morphine, codeine
JBRMJJ Heronin and morphine
JCJPKW Codeine and morphine
JGOKP5 Morphine
JNYC8O Morphine, Codeine
JQIGMD MORPHINE AND CODEINE
JTSJJD Morphine, Codeine
JUNUUU Morphine, codeine phosphate
K7QIQW Morphine
KBTTYE Morphine
KFTKVQ morphine
L1N1AS Morphine
LACFSF Morfina
LLDWGL morphine
LTLGBL Morphine
LTXFMY Morphine, m-CPP HCl
M5FWNJ codeine, morfin
MDPWHT morphine, codeine
MKND72 Morphine, Codeine
MMHHSD Morphine and Codeine
MRHASS Morphine
N0NNLS morphine, codeine
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Code Identified SubstancesN1M8LG Morphine
N666MQ Morphine and Codeine.
NA2AKJ Morphine hydrochloride and codeine
NO9OBB Morphine, codeine
NPDHYI morphine
O0LRTK morphine
OPBW2C Morphine
OVCNJF Morphine
PDGMFW Morphine, Codeine
PPHC9X morphine, codeine
PQLTDR morfin, kodein
PSOAIJ Morphine
PUS7H2 Codeina y Morfina
R8O18R Morphine
RIJOTJ morphine
RPGPEM morphine hydrochloride
RXGBPA morphine
S2O5GO Morfina
S6OORI morphine, codein
SADCGQ Morphine
SOQRQ9 MORPHINE AND CODEINE
SSOSVY Morphine
SSSCSJ morphine
T0QNTU Morphine
TBBUSK morphine
TDDURM MORPHINE and CODEINE
TXQHJG morphine and codeine
UHMVSZ MORFINA Y CODEINA
UT6VEX Morphine
UTL3JI morphine
VFLGQF codeine
VLZ8LL morphine
VMSX5E MORPHINE HCL
W4SM4Y Morphine
WKJAI3 morphine, codeine
WPYVIW Morphine hidrochlorhide
XKGJ2G Morphine and Codeine
XPE2VZ Morphine & Codeine
YCSW1Z morphine, codeine
YETFFI Morphine hydrochloride
YULAAJ codeine, morphine
YYMCDP morphine
Z4FNNZ Morphine and Codeine
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Code Morphine00H0DT +
Morphine is controlled by law (KB 31/12/1930 changed by KB 8/10/1963).
0DAKSM +The sample contains the controlled drug morphine 70.67 %, m/m and codeine 12.94 %, m/m.
0SRDXD +the powder is a mixture of morphine and codeine. The concentration of morphine in the sample is 90.3% by weight, codeine is 9% by weight.
0T0BVS +La sustancia analizada se trata de morfina
1HR18P +
1R7FTA +Based on the above analysis, the sample was found to contain Morphine and Codeine
1SWNJJ +
22JWSL +The sample SM-2 contains a mixture of morphine and codeine.
2ACHVO +codeinemorphine
2FELET +SM-1 was found to be contain Morphine. Codeine also was detected in this sample.
2IOV6B +codéine, 6 monoacetylmorphine
2QK02D +Ademas Codeína.
2SMWYX +SM2 was prepared from a seizure containing 60.6% w/w morphine base. The seizure also contained codeine.
3E3XE3 +
400BTP +In the powder sample analyzed was detected the presence of morphine and codeine.
424NFI +Sample 2013/1/SM-2 consists of white powder. Morphine, a prohibited sudstance included in the National Law for Narcotics, is found to be present in this sample. The seizure also contains codeine.
Statement of findings for Test Sample 2
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Code Morphine4ED4U4 +
0.225 grams of a powder containing Morphine. Morphine is a Class A controlled drug subject to the provisions of the Misuse of Drugs Act 1971.
4FLYLL +
4P9OST +Sample 2013/1/SM-2 was found to contain controlled substance MORPHINE, a Schedule I drug under the SingleConvention on Narcotic Drugs.
4ZRH5B +morphine and codeine
5AL4YL +
5ZSPFZ +
6CS6GB +Monomorfinan-6-ol
77H7IH +We found Morphine in SM-2 as controlled drug
78CN24 +L'analyse de l'échantilon 2013/1/SM-2 révèle la présence de la morphine
7BREL7 +On analysis, i found the substances to contain 63.14% of morphine.
7H5WS7 +The seizure contained morphine
88O8O8 +
8KXYZQ +sample contain Morphine.
8LLTJE +morphine was as hydrochloride form
8QXEZ5 +morphine, codeine
99WMWJ +The sample contains 8.3 % Morphine.
9EU3UC +
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Code Morphine9WEC99 +
/
AJWS6O +One glass bottle labelled '2013/1/SM-2' containing 0.221g of off-white powder. This powder contained codeine and morphine.Please see part 5 (4) for further comments.
AMA50Q +White powder containing morphine and codeine.
APYADP +the sample also contains codeine and acetylcodeine as metabolite
B824TN +Morphine
BBEBBB +SM 2 contain also Codeine
BPBBMB -Analysis of the Powder did not reveal the presence of any controlled drugs
BZBJBP +codeine and morphine
C2WUON +-
C5ZRZ2 +CODEINE
CIIE5Y +IN THE SAMPLE RECEIVED IN BOTTLE AMBER LID GREEN LETTERING 2013/1/SM-2 WAS FOUND MORPHINE Y CODEINE.
CLW6JW +With codeine also
CQC6CC +MORPHINE AND CODEINE WERE IDENTIFIED
CSDDCC +
DDXKOD +The sample 2013/1/SM-2 was found to contain Morphine.
DVAVS7 +The sample contains morphine which is scheduled as illicit drug in France.
EIJIBE +MORPHINE CHLORYDRATE (67.4% as base) - CODEINE CHLORYDRATE (11.6 as base)
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Code MorphineEK1BZR +
The powder was analysed and found to contain morphine and codeine.
EYBQOO +SM-2 contains morphine, 59%
EYEEEV +*Results of screening tests were positive for opiates. *Retention time and fragmentation pattern obtained with the sample are equivalent to those obtained with morphine and codeine.
F66RUS +Sample contain drug- Morphine
FF11HE +mixture of morphine and codeine
FNZI88 +
G9XDGK +The sample SM2 contained morphine and codeine. Quantification of morphine we do not performed.
GUEUUR +One glass vial with lid attached containing 217mg of off-white powder containing codeine and morphine.
HPPPFP +Morphine and codeine are not quantified routinely in our laboratory
HRHXY5 +The sample contains morphine and codeine.
HSJGXV +Morfine (not quantified) and codeine
IBADDP +On analysis, the powder was found to contain morphine.
IQXIII +found morphine with 59.0% w/w, 6-acetylcodeine, and oleamide (calibration curve performed with UNODC standard)
IYZYBB +we have not received standards
J9KZ5A +Souble in Methanol, The Sample contains 64.9% Morphine, 11.8% Codeine as a base.
JBRMJJ +
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Code MorphineJCJPKW +
Off-white powder found to contain codeine and morphine. I am satisfied that morphine is present at a concentration greater than 0.2%.
JGOKP5 +Also found Codeine
JNYC8O +Morphine and Codeine detected in sample SM-2 but quantitation not performed.
JQIGMD +MORPHINE 79.6%CODEINE 13.3%
JTSJJD +At first Screening Test was performed and confirmed by TLC method in two different solvent system.
JUNUUU +color test : Marquis = purple violet , Mecke = deep green , Frohde = purple becoming green/purple TLC : TA = Morphine or codeine, system diehtylether :acetone: diethylamine (85:8:7) = Morphine and codeine
GC : Morphine base = 78.66%, codeine base 13.33%GC/MS : Heroin, acetylcodeine, 6-MAM ,caffeine
K7QIQW +Morphine was found and the purity was 72.03%. Other drug found was codeine.
KBTTYE +After analysis, the sample was found to contain morphine.
KFTKVQ +The sample was found to contain morphine.
KW3BDH -
L1N1AS +Morphine was identified by TLC and GC/MS
LACFSF +Las pruebas químicas y la coincidencia en los tiempos de retención y fragmentos de masas del material de referencia usado en las mismas condiciones que la muestra analizada, indican la presencia de morfina.
LLDWGL +Sample contains 72,8 ± 3.2 % morphine-base. Sample also contains codeine.
LTLGBL +
LTXFMY +Marquis reagent and Scott reagent have been applied, the TLC and GC/FID
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Code MorphineM5FWNJ +
MDPWHT +The sample is a mixture of morphine and codeine.
MKND72 +
MMHHSD +White, odourless powder, tested positive for Morphine and Codeine, substances listed in Table B and C respectively of the Law on Addictive Substances.
MRHASS +The sample contains morphine and codeine.
N0NNLS +
N1M8LG +We also found codeine and traces of heroin.
N666MQ +Applied chemical tests and instrumental chemical analysis, that sample 2013/1/SM2 contains Morphine and Codeine.
NA2AKJ +One brown glass bottle containing 224mg of an off-white powder. This off-white powder contained morphine hydrochloride and codeine.
NO9OBB +The power contained morphine and codéine.
NPDHYI +Presence of morphine and codeine was detected in the sample.
O0LRTK +white powder containing morphine (69.4%). In addition is present codeine
OPBW2C +
OVCNJF +The analyze sample was identify as Morphine, however the quantification was not possible due to the degradation of the standard sample.
PCIBIV +
PDGMFW +
PPHC9X +powder contains morphine and codeine
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Code MorphinePQLTDR +
PSOAIJ +Positive to morphine, contains codeine sulfate.
PUS7H2 +
QJIQTJ ANP
R8O18R +Powder contains morphine wich is a controlled substance
RIJOTJ +white powder containing morphine (58.9%) and codeine
RPGPEM +
RXGBPA +codeine
S2O5GO +Pruebas colorimétricas, Marquis, Lieberman, FT-IR, UV-visible , TLC y microcristales
S6OORI +
SADCGQ +
SOQRQ9 +POWDER CONTAINING MORPHINE AND CODEINE
SSOSVY +The sample contains morphine which is listed as controlled drug according to french order, appendix I of February 22nd 1990.
SSSCSJ +
T0QNTU +In the test sample 2013/1/SM-2 were detected codeine and morphine
TBBUSK +white powder, mixture of the morphine and codeine
TDDURM +The sample correspond: MORPHINE mixed with CODEINE
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Code MorphineTXQHJG +
UHMVSZ +
UT6VEX +Test sample 2013/1/SM-2 was found to contain the following controlled drug Morphine
UTL3JI +The results of the tests of the SM 2 (29) received confirmed that the mentioned sample contains morphine but we are not able to give a cuantification result because we have not got the pattern of the mentioned controlled drug. The SM 2 also contains codein as not controlled drug
VFLGQF -the sample was found to contain codeine
VLZ8LL +The sample SM-2 found to contain 73,0 % morphine. The seizure also contains codeine.
VMSX5E +codéine
W4SM4Y +One glass bottle containing 0.22 grammes of a powder containing 0.15 grammes of morphine.
WKJAI3 +CR, TLC, FTIR, GC, GC/MS
WPYVIW +Morphine hidrochloride, Codeine
XKGJ2G +The sample was found to contain 68.4% of morphine (as base) and 12.5% of codeine (as base).
XPE2VZ +In the 0,230 g unknown powder it is found 50% Morphine and 10% Codeine.
YCSW1Z +
YETFFI +This sample contains morphine HCl (67.3% as base) and codein (13.8% as base)
YULAAJ +
YYMCDP +marquis reagent is positive (violet) ant Scott reagent is positive too. In the chromatogram the retention time is like morphine. So, the substance is morphine.
Z4FNNZ +Test Sample 2013/1/SM-2 contains Morphine and Codeine
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Identification methods for Test Sample 2
Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
00H0DT I S
0DAKSM I SI
0SRDXD I I I SI I I XRD
0T0BVS SI I
1HR18P I SI
1R7FTA S I
1SWNJJ I SI SI
22JWSL S S I I
2ACHVO SI I
2FELET S S I I
2IOV6B SI I I I
2QK02D SI S I I SI I
2SMWYX SI
3E3XE3 SI
400BTP S S I I
424NFI S S I I I I
4ED4U4 S S I
4FLYLL I SI
4P9OST S I
4ZRH5B SI
5AL4YL S I
5ZSPFZ S I
6CS6GB S I
77H7IH S I I
78CN24 S I
7BREL7 S S S I
7H5WS7 I SI
88O8O8 SI S S I
8KXYZQ SI ASAP-TOF
8LLTJE S I
8QXEZ5 SI I I I I
99WMWJ SI
9EU3UC S I I
9WEC99 I SI SI
Analytical Technique Codes
Legend: S ... used for Screening I ... used for Identification SI ... used for both
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Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
AJWS6O S S I
AMA50Q S SI I SI
APYADP S S I
B824TN I I SI I
BBEBBB I S I I I
BPBBMB S SI I I
BZBJBP SI I
C2WUON SI
C5ZRZ2 S I I
CIIE5Y S S S I
CLW6JW S S S I I
CQC6CC I SI I
CSDDCC SI
DDXKOD S S S I I
DVAVS7 I SI
EIJIBE S S S I
EK1BZR S S I I
EYBQOO SI S S S I I I
EYEEEV S S I I
F66RUS I SI I I LCMS
FF11HE S I I I I
FNZI88 SI
G9XDGK I I
GUEUUR S S I I
HPPPFP S I I SI I
HRHXY5 S S I I
HSJGXV S I
IBADDP I
IQXIII SI
IYZYBB I I S IMMUNOCHEMICAL
J9KZ5A I I SI
JBRMJJ SI
JCJPKW S S I
JGOKP5 I SI
JNYC8O S S I I
JQIGMD S S I I
JTSJJD S S I S 210(Fast Blue B salt Test)
JUNUUU S I I I
K7QIQW S S S I
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Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
KBTTYE S I
KFTKVQ S S S I
KW3BDH SI
L1N1AS S S S I I
LACFSF S S I
LLDWGL SI SI
LTLGBL S S S I I
LTXFMY S SI S I
M5FWNJ S SI I
MDPWHT S I I
MKND72 S S SI SI
MMHHSD S S S I I
MRHASS SI
N0NNLS S I I
N1M8LG SI I
N666MQ S S I
NA2AKJ I I
NO9OBB I SI I
NPDHYI S S S S I I I
O0LRTK I I SI
OPBW2C I SI
OVCNJF S S S I I
PCIBIV I S S SI I SI I
PDGMFW I I SI
PPHC9X SI I
PQLTDR S SI I I
PSOAIJ S I I
PUS7H2 S I
QJIQTJ I
R8O18R SI I I
RIJOTJ SI
RPGPEM S I I I
RXGBPA SI I
S2O5GO I S I I SI I I I liberman
S6OORI I SI I
SADCGQ I SI
SOQRQ9 SI
SSOSVY I I
SSSCSJ I SI
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Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
T0QNTU I
TBBUSK SI I
TDDURM I SI
TXQHJG S I I
UHMVSZ S S I I
UT6VEX SI
UTL3JI S I
VFLGQF I S Immunochromatography
VLZ8LL S S S S I I
VMSX5E SI
W4SM4Y S S I SI I
WKJAI3 SI S SI I I
WPYVIW S S S I I I I XRD
XKGJ2G SI I UPHLC/ELSD
XPE2VZ S I I
YCSW1Z I SI I
YETFFI S S I I
YULAAJ S S I
YYMCDP S I
Z4FNNZ S I I I RAMAN
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Response SummaryParticipants: 132
Morphine: 126
Frequency of use of screening and identification techniques:
Summary for test sample 2The response summary of all 126 participating laboratories for the identification of SM-2, frequency of use of screening andidentification techniques and false positives and negatives:
Identification of test sample 2:
False positives for Test Sample 2 (controlled substances)
Code Name TechniqueLTXFMY 1-(3-Chlorophenyl)piperazine 141, 150
False negatives for SM-2 (techinque(s) used or ANP) . Code - BPBBMB (180), VFLGQF (180), QJIQTJ (ANP),KW3BDH (ANP)
Section 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
Screening 42 50 35 18 0 2 0 2 45 7 0 0 0 1 4
31.8% 37.9% 26.5% 13.6% 0.0% 1.5% 0.0% 1.5% 34.1% 5.3% 0.0% 0.0% 0.0% 0.8% 3.0%
Identification 10 5 2 32 9 15 1 21 118 45 2 2 2 3 7
7.6% 3.8% 1.5% 24.2% 6.8% 11.4% 0.8% 15.9% 89.4% 34.1% 1.5% 1.5% 1.5% 2.3% 5.3%
# labs using this technique
47 52 37 41 9 16 1 22 118 46 2 2 2 3 1035.6% 39.4% 28.0% 31.1% 6.8% 12.1% 0.8% 16.7% 89.4% 34.8% 1.5% 1.5% 1.5% 2.3% 7.6%
Response Summary Participants: 132
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Z-Scores for Test Sample 2
CODEMorphineMAD: 5.4
Conc. * AbsDev ZScore
00H0DT 87.1 18.6 2.3
0DAKSM 70.7 2.2 0.3
0SRDXD 90.3 21.8 2.7
1HR18P 77.8 9.3 1.2
1SWNJJ 76.1 7.6 1.0
2FELET 65.8 2.7 0.3
2IOV6B 78.8 10.4 1.3
2SMWYX 60.6 7.9 1.0
3E3XE3 81.0 12.5 1.6
4P9OST 65.0 3.5 0.4
4ZRH5B 77.8 9.3 1.2
7BREL7 63.1 5.3 0.7
8LLTJE 81.5 13.0 1.6
8QXEZ5 35.0 33.5 4.2
99WMWJ 8.3 60.2 7.5
9EU3UC 51.8 16.7 2.1
BBEBBB 58.0 10.5 1.3
BZBJBP 75.5 7.0 0.9
C2WUON 71.6 3.1 0.4
CSDDCC 63.0 5.5 0.7
EIJIBE 67.4 1.1 0.1
EYBQOO 59.0 9.5 1.2
FF11HE 68.9 0.5 0.1
FNZI88 71.4 3.0 0.4
IQXIII 59.0 9.5 1.2
IYZYBB 80.3 11.8 1.5
J9KZ5A 64.9 3.6 0.4
JGOKP5 61.2 7.3 0.9
JQIGMD 79.6 11.1 1.4
JUNUUU 78.7 10.2 1.3
K7QIQW 72.0 3.6 0.4
L1N1AS 67.4 1.0 0.1
LLDWGL 72.8 4.3 0.5
MKND72 74.5 6.0 0.8
MRHASS 69.7 1.3 0.2
N1M8LG 76.9 8.4 1.1
NPDHYI 67.3 1.2 0.1
O0LRTK 69.4 0.9 0.1
OPBW2C 71.8 3.3 0.4
PDGMFW 67.2 1.3 0.2
RIJOTJ 58.9 9.6 1.2
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CODEMorphineMAD: 5.4
Conc. * AbsDev ZScore
RPGPEM 83.8 15.3 1.9
RXGBPA 81.0 12.5 1.6
SADCGQ 73.8 5.3 0.7
SOQRQ9 68.0 0.5 0.1
SSSCSJ 64.0 4.5 0.6
UHMVSZ 87.5 19.0 2.4
VLZ8LL 73.0 4.5 0.6
VMSX5E 81.0 12.5 1.6
W4SM4Y 66.9 1.6 0.2
WKJAI3 79.0 10.5 1.3
XKGJ2G 68.4 0.1 0.0
XPE2VZ 50.0 18.5 2.3
YETFFI 67.3 1.2 0.1
*) Concentration: w/w %
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Substance: SM-2/Morphine 5.4MAD =Median = 68.5
Round: 2013/1
Z-Score has been calculated as modified Z-Score as it is a robust method and therefore relatively insensitive to outliers.Modified Z-Score = 0.6745 * AbsDev/MADAbsDev = Absolute value of the difference between a laboratory value and the median of all the laboratory values for the given drug;MAD = median absolute deviation about the median.Modified Z-scores with an absolute value of greater than 3.5 should be considered as potential outliers.Reference:Iglewicz, B. and Hoaglin, D. C.: 1993 How to Detect and Handle Outliers, American Society for Quality Control, Milwaukee, WI
Z-Score Report per Sample per Substance
UNODC value = 68.8
(44)
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Identified substances for Test Sample 3
Code Identified Substances00H0DT nimetazepam
0DAKSM Nimetazepam
0SRDXD nimetazepam
0T0BVS NIMETAZEPAM
1HR18P Nimetazepam
1R7FTA Nimetazepam
1SWNJJ nimetazepam, lactose
22JWSL Nimetazepam
2ACHVO benzodiazepines
2FELET Nimetazepam
2IOV6B nimétazepam
2QK02D Nimetazepam
2SMWYX Nimetazepam
3E3XE3 Nimetazepam
400BTP Nimetazepam
4ED4U4 Nimetazepam
4P9OST NIMETAZEPAM
4ZRH5B nimetozepam
5AL4YL Nimetazepam
5ZSPFZ nimetazepam
6CS6GB Nimetazepam
77H7IH Nimetazepam
78CN24 Lidocaïne
7BREL7 Nimetazepam
8KXYZQ Nimetazepam
8QXEZ5 nimetazepam
99WMWJ Nimetazepam
9EU3UC Nimetazepam
9WEC99 NIMETAZEPAM
AJWS6O Nimetazepam
AMA50Q Nimetazepam
APYADP we found nimetazepam
B824TN Nimetazepam
BBEBBB Nimetazepam
BPBBMB Nimetazepam
BZBJBP Nimetazepam
C2WUON Nimetazepam
C5ZRZ2 NIMETAZEPAM
CIIE5Y YES, NIMETAZEPAM
CLW6JW Nimetazepam
Sample 3 Analysis
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Code Identified SubstancesCQC6CC NIMETAZEPAM
DDXKOD Nimetazepam
DVAVS7 nimetazepam, lactose
EIJIBE MIMETAZEPAM
EK1BZR Nimetazepam
EYBQOO Nimetazepam
EYEEEV Nimetazepam, lactose
F66RUS Nimetazepm
G9XDGK Nimetazepam
GUEUUR Nimetazepam
HPPPFP Nimetazepam
HRHXY5 Nimetazepam
HSJGXV Nimetazepam
IBADDP Nimetazepam
IQXIII nimetazepam
IYZYBB benzodiazepines (nimetazepam)
J9KZ5A Nimetazepam
JBRMJJ controlled substance
JCJPKW Nimetazepam
JGOKP5 Nimetazepam
JNYC8O Nimetazepam
JQIGMD NIMETAZEPAM
JTSJJD Nimetazepam
JUNUUU Nimetazepam
K7QIQW Nimetazepam
KBTTYE Nimetazepam
KFTKVQ Nimetazepam
KW3BDH nimetazepam
L1N1AS Nimetazepam
LACFSF Nimetazepam
LLDWGL Nimetazepam
LTLGBL Nimetazepam
LTXFMY Nimetazepam
M5FWNJ nimetazepam
MDPWHT nimetazepam
MKND72 Nimetazepam
MMHHSD Nimetazepame
MRHASS Nimetazepam
N0NNLS nimetazepam
N1M8LG Nimetazepam
N666MQ Nimetazepam.
NA2AKJ Nimetazepam
NO9OBB NIMETAZEPAM
NPDHYI nimetazepam
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Code Identified SubstancesO0LRTK nimetazepam
OPBW2C Nimetazepam and Lactose
OVCNJF Nimetazepam
PDGMFW Nimetazepam
PPHC9X nimetazepam
PSOAIJ Nimetazepam
PUS7H2 Nimetazepam
R8O18R Nimetazepam
RIJOTJ nimetazepam
RPGPEM nimetazepam
RXGBPA nimetazepam
SADCGQ Nimetazepam
SOQRQ9 NIMETAZEPAM
SSOSVY Nimetazepam
SSSCSJ nimetazepam
TDDURM Nimetazepam
TXQHJG nimetazepam
UTL3JI NONE
VFLGQF methamphetamine
VLZ8LL nimetazepam
VMSX5E NIMETAZEPAM
W4SM4Y Nimetazepam
WKJAI3 nimetazepam
WPYVIW Nimetazepam
XKGJ2G Nimetazepam
XPE2VZ Nimetazepam
YCSW1Z nimetazepam
YETFFI Nimetazepam
YULAAJ nimetazepam
Z4FNNZ Nimetazepam
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Code Lactose Nimetazepam00H0DT ANP +
Nimetazepam is controlled by law (KB 22/01/1998).
0DAKSM + +The sample contains the controlled drug nimetazepam 3.75 %, m/m and lactose.
0SRDXD + +The powder is a mixture of nimetazepam and lactose. The concentration of nimetazepam in the sample is 10% by weight.
0T0BVS ANP +La sustancia analizada se trata de una benzodiacepina, probablemente nimetazepam
1HR18P ANP +
1R7FTA ANP +Based on the above analysis, the sample was found to contain Nimetazepam
1SWNJJ + +
22JWSL + +The sample SM-3 contains a mixture of lactose and nimetazepam
2ACHVO ANP +nimetazepam
2FELET - +SM-1 was found to be contain Nimetazepam.
2IOV6B + +lactose
2QK02D + +Se detecto lactosa.
2SMWYX - +SM3 was prepared from a seizure containing 3.78% w/w nimetazepam.
3E3XE3 ANP +
400BTP + +In the powder sample analyzed was detected the presence of Nimetazepam and Lactose.
424NFI + ANPSample 2013/1/SM-3 consists of light pink powder. No prohibited sudstances are detected in this sample.
Statement of findings for Test Sample 3
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Code Lactose Nimetazepam4ED4U4 ANP +
0.220 grams of a powder containing Nimetazepam. Nimetazepam is a Class C controlled drug subject to the provisions of the Misuse of Drugs Act 1971.
4FLYLL + -
4P9OST ANP +Sample 2013/1/SM-3 was found to contain controlled substance NIMETAZEPAM, a Schedule IV drug under the international Convention on Psychotropic Substances.
4ZRH5B - +nimetozepam
5AL4YL ANP +lactose and Nimetazepam
5ZSPFZ ANP +
6CS6GB ANP +Fenil Alanina
77H7IH ANP +We found Nimetazepam in SM-3 as controlled drug
78CN24 - -Après analyse, l'échantillon 2013/1/SM-3 contient la Lidocaïne
7BREL7 + +On analysis, i found the substances to contain 3.58% of nimetazepam.
7H5WS7 ANP ANP
88O8O8 ANP ANP
8KXYZQ ANP +Sample contain Nimetazepam.
8LLTJE ANP +
8QXEZ5 - +nimetazepam
99WMWJ ANP +the sample contains Nimetazepam
9EU3UC + +
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Code Lactose Nimetazepam9WEC99 + +
/
AJWS6O ANP +One glass bottle labelled '2013/1/SM-3' containing 0.231g of pink powder. This powder contained Nimetazepam. Nimetazepam is a class C controlled drug under the misuse of Drugs Act (1971)(as ammended).
AMA50Q ANP +Pink powder containing nimetazepam.
APYADP ANP +the sample was confirmed by gc ms
B824TN + +Nimetazepam and lactose
BBEBBB + +SM 3 contain also Lactose
BPBBMB ANP +Analysis of the powder revealed the presence of Nimetazepam
BZBJBP + +Nimetazepam, lactose
C2WUON ANP +-
C5ZRZ2 + +LACTOSE, GLUCOSE
CIIE5Y - +IN THE SAMPLE RECEIVED IN BOTTLE AMBER LID GREEN LETTERING 2013/1/SM-3 WAS FOUND NIMETAZEPAM.
CLW6JW + +Diluted with lactose
CQC6CC + +NIMETAZEPAM IN LACTOSE POWDER
CSDDCC + +NIMETAZEPAM, LACTOSE, GLUCOSE
DDXKOD ANP +The Sample 2013/1/SM-3 was found to contain Nimetazepam.
DVAVS7 + +The sample contains nimetazepam which is scheduled as psychotrope in France. Lactose is also present as cutting agent.
EIJIBE ANP +NIMETAZEPAM CHLORYDRATE
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Code Lactose NimetazepamEK1BZR + +
The powder was analysed and found to contain nimetazepam.
EYBQOO - +SM-3 contains nimetazepam, 7,2%
EYEEEV + +*Retention time and fragmentation pattern obtained with the sample are equivalent to those obtained nimetazepam. *The spectroscopic parameters obtained with the sample are equivalent to those obtained lactose.
F66RUS + +Sample contain drug- Nimetazepam
FF11HE + +mixture of lactose and nimetazepam
FNZI88 - +
G9XDGK + +The sample SM3 contained nimetazepam and lactose.Pharmaceuticals with psychoactive compunds, we do not quantify.
GUEUUR + +One glass vial with lid attached containing 210mg of pink powder cotaining nimetazepam
HPPPFP + +Probably nimetazepam (We don't have the standard product in the laboratory). This product is not found en France.Lactose and probably glucose traces
HRHXY5 ANP +The sample contains nimetazepam.
HSJGXV - +Nimetazepam
IBADDP ANP +On analysis, the powder was found to contain nimetazepam.
IQXIII ANP +sample was found to contain nimetazepam but quantification was not performed
IYZYBB + +we have not received standards
J9KZ5A + +The sample contains 3.8% Nimetazepam and Lactose.
JBRMJJ - +Nimetazepam is a benzodiacepine drugs
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Code Lactose NimetazepamJCJPKW ANP +
Pink powder found to contain nimetazepam
JGOKP5 ANP +
JNYC8O + +3.33% +/- 0.30% Nimetazepam detected in sample SM-3.
JQIGMD - +
JTSJJD - +At first Screening Test was performed and confirmed by TLC method in two different solvent system.
JUNUUU ANP +TLC : TA and TE = nimetazepamGC : Nimetazepam 3.59%GC/MS : Nimetazepam
K7QIQW - +Nimetazepam was found and the purity was 2.75%.
KBTTYE ANP +After analysis, the sample was found to contain nimetazepam.
KFTKVQ - +On analysis, I found the substance to contain 3.07 % nimetazepam.
KW3BDH ANP +powder containing nimetazepam
L1N1AS + +Nimetazepam was identified by TLC and GC/MS
LACFSF ANP +El análisis cromatográfico realizado a la muestra produjo coincidencias significativas con la librería de compuestos del software, lo que indica la presencia de Nimetazepam en la muestra analizada.
LLDWGL + +Sample contains nimetazepam and lactose. According to the Hungarian low we not quantify nimetazepam routinely.
LTLGBL + +
LTXFMY ANP +Marquis reagent and Scott reagent have been applied, the TLC and GC/FID
M5FWNJ ANP +
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Code Lactose NimetazepamMDPWHT + +
The sample contains nimetazepam.
MKND72 ANP +
MMHHSD ANP +Pink, odourless powder, tested positive for Nimetazepam, a substance listed in Table D of the Law on Addictive Substances.
MRHASS + +The sample contains nimetazepam and lactose.
N0NNLS - +
N1M8LG + +We also found lactose
N666MQ ANP +Applied chemical tests and instrumental chemical analysis, that sample 2013/1/SM3 contains Nimetazepam.
NA2AKJ ANP +One brown glass bottle containing 231mg of a pink powder. this pink powder contained nimetazepam.
NO9OBB + +The power contained Nimetazepam with lactose. Nimetazepam is a psychotropic substance
NPDHYI + +Presence of nimetazepam and lactose was detected in the sample.
O0LRTK + +Pink powder containing nimetazepam. The amount of nimetazepam was not quantified. The sample contains also lactose and glucose (not quantified)
OPBW2C + +
OVCNJF + +Pink powder containing Nimetazepam with a 24.8% of base. Nimetazepam is clasify as a psychotropic by the Ministry of Health of Guatemala, it is not clasify as a seized material.
PCIBIV - +
PDGMFW + +Sugar
PPHC9X + +powder contains nimetazepam
PQLTDR + +nimetazepam, laktóz
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Code Lactose NimetazepamPSOAIJ + +
Positive to Nimetazepam and lactose
PUS7H2 ANP +
QJIQTJ ANP ANP
R8O18R ANP +Powder contains Nimetazepam wich is a controlled substance
RIJOTJ ANP +Pink powder containing nimetazepam. The amount of nimetazepam was not determined because there is not the righr standard reference material in the laboratory.
RPGPEM + +sample contains also lactose
RXGBPA + +suggar, fatty acids
S2O5GO + ANPPruebas colorimétricas, Marquis, Scott, Lieberman, Chen Cao,FT-IR.
S6OORI - +nimatazepam
SADCGQ - +
SOQRQ9 ANP +POWDER CONTAINING NOMETAZEPAM
SSOSVY + +The sample contains nimetazepam which is listed as a controlled psychotropic substance according to french order, 1st part of appendix of February 22nd 1990.
SSSCSJ ANP +
T0QNTU - +In the test sample 2013/1/SM-3 was detected nimetazepam
TBBUSK + +white powder, mixture of the nimetazepam and lactose
TDDURM - +The sample correspond: Nimetazepam mixed with lactoce
TXQHJG + +
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Code Lactose NimetazepamUHMVSZ - -
UT6VEX ANP -Test sample 2013/1/SM-3 was found to contain No controlled drugs .
UTL3JI - -we have not found any controlled drug in the SM 3 (36)
VFLGQF ANP ANPthe sample was found to contain methamphetamine
VLZ8LL + +The sample SM-3 found to contain 3,6 % nimetazepam. The seizure also contains lactose.
VMSX5E + +lactose, glucose
W4SM4Y + +One glass bottle containing 0.23 grammes of a powder containing 7 milligrammes of nimetazepam.
WKJAI3 + +TLC, FTIR, GC, GC/MS
WPYVIW + +Nimetazepam, Lactose
XKGJ2G + +The sample was found to contain nimetazepam.
XPE2VZ - +In the 0,230 g unknown powder it is found 10% Nimetazepam.
YCSW1Z + +This sample also contains lactose.
YETFFI + +This sample contains Nimetazepam (not quantified) with lactose.
YULAAJ ANP +
YYMCDP ANP ANPmarquis reagent is negative ant Scott reagent is positive. In the chromatogram the retention time does not like the retention time patterns we have. So, we can not know the drug.
Z4FNNZ + +Test Sample 2013/1/SM-3 contains Nimetazepam and Lactose
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Identification methods for Test Sample 3
Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
00H0DT I S
0DAKSM I SI
0SRDXD I I I SI I I XRD
0T0BVS SI I
1HR18P I SI
1R7FTA S I
1SWNJJ I SI SI
22JWSL S S I I
2ACHVO SI I
2FELET S S I I
2IOV6B SI I I I
2QK02D SI S I I SI I
2SMWYX SI
3E3XE3 SI
400BTP S S I I
424NFI S S I I I I
4ED4U4 S S I
4FLYLL I SI
4P9OST S I
4ZRH5B SI
5AL4YL S I
5ZSPFZ S I
6CS6GB S I
77H7IH S I I
78CN24 S I
7BREL7 S S S I
7H5WS7 I SI
88O8O8 SI S S I
8KXYZQ SI ASAP-TOF
8LLTJE S I
8QXEZ5 SI I I I I
99WMWJ SI
9EU3UC S I I
9WEC99 I SI SI
Analytical Technique Codes
Legend: S ... used for Screening I ... used for Identification SI ... used for both
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Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
AJWS6O S S I
AMA50Q S SI I SI
APYADP S S I
B824TN I I SI I
BBEBBB I S I I I
BPBBMB S SI I I
BZBJBP SI I
C2WUON SI
C5ZRZ2 S I I
CIIE5Y S S S I
CLW6JW S S S I I
CQC6CC I SI I
CSDDCC SI
DDXKOD S S S I I
DVAVS7 I SI
EIJIBE S S S I
EK1BZR S S I I
EYBQOO SI S S S I I I
EYEEEV S S I I
F66RUS I SI I I LCMS
FF11HE S I I I I
FNZI88 SI
G9XDGK I I
GUEUUR S S I I
HPPPFP S I I SI I
HRHXY5 S S I I
HSJGXV S I
IBADDP I
IQXIII SI
IYZYBB I I S IMMUNOCHEMICAL
J9KZ5A I I SI
JBRMJJ SI
JCJPKW S S I
JGOKP5 I SI
JNYC8O S S I I
JQIGMD S S I I
JTSJJD S S I S 210(Fast Blue B salt Test)
JUNUUU S I I I
K7QIQW S S S I
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Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
KBTTYE S I
KFTKVQ S S S I
KW3BDH SI
L1N1AS S S S I I
LACFSF S S I
LLDWGL SI SI
LTLGBL S S S I I
LTXFMY S SI S I
M5FWNJ S SI I
MDPWHT S I I
MKND72 S S SI SI
MMHHSD S S S I I
MRHASS SI
N0NNLS S I I
N1M8LG SI I
N666MQ S S I
NA2AKJ I I
NO9OBB I SI I
NPDHYI S S S S I I I
O0LRTK I I SI
OPBW2C I SI
OVCNJF S S S I I
PCIBIV I S S SI I SI I
PDGMFW I I SI
PPHC9X SI I
PQLTDR S SI I I
PSOAIJ S I I
PUS7H2 S I
QJIQTJ I
R8O18R SI I I
RIJOTJ SI
RPGPEM S I I I
RXGBPA SI I
S2O5GO I S I I SI I I I liberman
S6OORI I SI I
SADCGQ I SI
SOQRQ9 SI
SSOSVY I I
SSSCSJ I SI
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Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
T0QNTU I
TBBUSK SI I
TDDURM I SI
TXQHJG S I I
UHMVSZ S S I I
UT6VEX SI
UTL3JI S I
VFLGQF I S Immunochromatography
VLZ8LL S S S S I I
VMSX5E SI
W4SM4Y S S I SI I
WKJAI3 SI S SI I I
WPYVIW S S S I I I I XRD
XKGJ2G SI I UPHLC/ELSD
XPE2VZ S I I
YCSW1Z I SI I
YETFFI S S I I
YULAAJ S S I
YYMCDP S I
Z4FNNZ S I I I RAMAN
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Response SummaryParticipants: 132
Lactose: 60
Nimetazepam: 120
Response Summary Participants: 126
Frequency of use of screening and identification techniques:
Summary for test sample 3The response summary of all 126 participating laboratories for the identification of SM-3, frequency of use of screening andidentification techniques and false positives and negatives:
Identification of test sample 3:
False positives for Test Sample 3 (controlled substances)
False negatives for SM-3 (techinque(s) used or ANP) . Code - 4FLYLL (180), 78CN24 (150), UHNVSZ (171/180 ), UT6VEX ( 180)UTL3JI (180), 424NFI (ANP), 7H5W57 (ANP), 88O8O8 (ANP),QJIQTJ (ANP), S2O5GO (ANP), YYMCDP (ANP), VFLGQF (ANP)
Code Name Technique 1
Section 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210
Screening 42 50 35 18 0 2 0 2 45 7 0 0 0 1 4
31.8% 37.9% 26.5% 13.6% 0.0% 1.5% 0.0% 1.5% 34.1% 5.3% 0.0% 0.0% 0.0% 0.8% 3.0%
Identification 10 5 2 32 9 15 1 21 118 45 2 2 2 3 7
7.6% 3.8% 1.5% 24.2% 6.8% 11.4% 0.8% 15.9% 89.4% 34.1% 1.5% 1.5% 1.5% 2.3% 5.3%
# labs using this technique
47 52 37 41 9 16 1 22 118 46 2 2 2 3 1035.6% 39.4% 28.0% 31.1% 6.8% 12.1% 0.8% 16.7% 89.4% 34.8% 1.5% 1.5% 1.5% 2.3% 7.6%
Response Summary Participants: 132
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Z-Scores for Test Sample 3
CODENimetazepamMAD: 0.3
Conc. * AbsDev ZScore
0DAKSM 3.8 0.0 0.1
0SRDXD 10.0 6.3 15.2
1HR18P 4.1 0.4 1.0
1SWNJJ 3.6 0.1 0.2
2FELET 0.1 3.7 8.8
2SMWYX 3.8 0.1 0.2
4ZRH5B 3.5 0.2 0.5
7BREL7 3.6 0.1 0.3
8LLTJE 2.8 0.9 2.2
8QXEZ5 7.0 3.3 8.0
9EU3UC 8.2 4.5 10.8
BBEBBB 3.5 0.2 0.5
BZBJBP 3.1 0.6 1.4
C2WUON 3.8 0.1 0.3
EYBQOO 7.2 3.5 8.4
FNZI88 3.0 0.7 1.6
IYZYBB 13.6 9.9 23.9
J9KZ5A 3.8 0.1 0.2
JGOKP5 3.8 0.1 0.2
JNYC8O 3.3 0.4 0.9
JUNUUU 3.6 0.1 0.3
K7QIQW 2.7 1.0 2.3
KBTTYE 3.5 0.2 0.5
KFTKVQ 3.1 0.6 1.5
L1N1AS 3.2 0.5 1.1
MKND72 2.9 0.8 1.9
MRHASS 3.8 0.1 0.2
N1M8LG 2.9 0.9 2.0
NPDHYI 3.8 0.1 0.2
OPBW2C 3.2 0.5 1.3
OVCNJF 24.8 21.1 50.9
PDGMFW 2.7 1.0 2.4
RPGPEM 3.7 0.0 0.0
RXGBPA 15.5 11.8 28.4
SADCGQ 3.7 0.1 0.1
SOQRQ9 3.8 0.1 0.2
SSSCSJ 4.0 0.3 0.7
VLZ8LL 3.6 0.1 0.2
W4SM4Y 3.4 0.3 0.7
WKJAI3 3.8 0.1 0.2
XPE2VZ 10.0 6.3 15.2
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Substance: SM-3/Nimetazepam 0.3MAD =Median = 3.7
Round: 2013/1
Z-Score has been calculated as modified Z-Score as it is a robust method and therefore relatively insensitive to outliers.Modified Z-Score = 0.6745 * AbsDev/MADAbsDev = Absolute value of the difference between a laboratory value and the median of all the laboratory values for the given drug;MAD = median absolute deviation about the median.Modified Z-scores with an absolute value of greater than 3.5 should be considered as potential outliers.Reference:Iglewicz, B. and Hoaglin, D. C.: 1993 How to Detect and Handle Outliers, American Society for Quality Control, Milwaukee, WI
Z-Score Report per Sample per Substance
UNODC value = 3.7
(62)
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Identified substances for Test Sample 4
Code Identified Substances00H0DT amphetamine
0DAKSM Amfetamine
0SRDXD amphetamine
0T0BVS ANFETAMINA
1HR18P Amphetamine
1SWNJJ amfetamine
22JWSL Amfetamine
2ACHVO amphetamines
2FELET Amfetamine
2IOV6B metamphétamine
2QK02D Anfetamina
2SMWYX Amfetamine
3E3XE3 Amphetamine
400BTP Amphetamine
424NFI Amfetamine
4ED4U4 Amfetamine
4FLYLL AMFETAMINE
4P9OST Amphetamine
4ZRH5B amfetamine
5AL4YL amfetamine sulphate
5ZSPFZ anfetamine
6CS6GB Anfetamina
77H7IH Amphetamine
78CN24 Amphétamine
7BREL7 Amphetamine
88O8O8 amfetamine
8KXYZQ Amphetamine
8LLTJE amphetamine
8QXEZ5 amfetamine
99WMWJ Amfetamine
9EU3UC Amphetamine
9WEC99 AMFETAMINE
AJWS6O Amphetamine
AMA50Q Amphetamine
APYADP we found amphetamine
B824TN Amfetamine
BBEBBB Amphetamine Sulphate
BPBBMB Amphetamine
BZBJBP Amphetamine
C2WUON Amfetamine
Sample 4 Analysis
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Code Identified SubstancesC5ZRZ2 AMPHETAMINE
CIIE5Y NO
CLW6JW Amphetamine
CQC6CC AMPHETAMINE
CSDDCC AMFETAMIN SULFATE
DDXKOD Amphetamine
DVAVS7 amphetamine
EIJIBE AMPHETAMINE
EK1BZR Amphetamine
EYBQOO Amfetamine, metamfetamine
EYEEEV amfetamine
F66RUS Amphetamine
FF11HE amphetamine
G9XDGK Amfetamine
GUEUUR Amphetamine
HPPPFP amphetamine
HRHXY5 Amfetamine
HSJGXV Amphetamine
IBADDP Amphetamine
IQXIII amphetamine
IYZYBB amphetamines (amphetamine)
J9KZ5A Amphetamine
JBRMJJ Amphetamine
JCJPKW Amphetamine
JGOKP5 Amphetamine
JQIGMD AMFETAMINE
JTSJJD Amfetamine
JUNUUU Amphetamine
KBTTYE Amphetamine
KFTKVQ Amphetamine
L1N1AS Amphetamine
LACFSF Anfetamina
LLDWGL Amfetamine
LTLGBL Amfetamine
LTXFMY Amphetamine
M5FWNJ amfetamine
MDPWHT amfetamine, metamfetamine
MKND72 Amfetamine
MMHHSD Amphetamine
MRHASS Amfetamine
N0NNLS amfetamine
N1M8LG Amphetamine
N666MQ Amfetamine.
NA2AKJ amphetamine sulphate
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Code Identified SubstancesNO9OBB Amphetamine
NPDHYI amfetamine
O0LRTK amfetamine
OPBW2C Amphetamine and sucrose
OVCNJF Amfetamine
PCIBIV Isosorbide
PDGMFW Amphetamine
PPHC9X amfetamine
PQLTDR amfetamin
PSOAIJ Anfetamine
PUS7H2 Anfetamina
QJIQTJ amfetamine
R8O18R Amphetamine
RIJOTJ amphetamine
RPGPEM amphetamine sulphate
RXGBPA amfetamine
S2O5GO anfetamina
S6OORI amphetamine
SADCGQ Amfetamine
SOQRQ9 AMPHETAMINE
SSOSVY Amphetamine
SSSCSJ amfetamine
T0QNTU Amfetamine
TBBUSK amphetamine
TXQHJG amphetamine
UHMVSZ ANFETAMINA
UT6VEX Amfetamine
UTL3JI anphetamine
VFLGQF amphetamine
VLZ8LL amphetamine
VMSX5E AMFETAMINE SO4
W4SM4Y Amphetamine
WKJAI3 amphetamine
WPYVIW Amphetamine sulphate
XKGJ2G Amphetamine and Methamphetamine
XPE2VZ Amphetamine
YCSW1Z amfetamine
YETFFI Amfetamine sulphate
YULAAJ afetamine
YYMCDP amfetamine
Z4FNNZ Amphetamine
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Code Amfetamine00H0DT +
Amphetamine is controlled by law (KB 22/01/1998).
0DAKSM +The sample contains the controlled drug amfetamine 9.55 %, m/m.
0SRDXD +The powder is a mixture of sucrose and amphetamine. The concentration of amphetamine in the sample is 4.9% by weight.
0T0BVS +La sustancia analizada se trata de anfetamina
1HR18P +
1R7FTA -Based on the above analysis, dangerous drugs were not detected in the sample
1SWNJJ +
22JWSL +The sample SM-4 contains amfetamine.
2ACHVO +amphetaminealso trace of methamphetamine
2FELET +SM-1 was found to be contain Amfetamine
2IOV6B -sucrose
2QK02D +se identificó como D-Anfetamina
2SMWYX +SM4 was prepared from a seizure containing 8.34% w/w amfetamine base.
3E3XE3 +
400BTP +In the sample analyzed was detected the presence of amphetamine, piperidine 2-(phenyl methyl) and sucrose.
424NFI +Sample 2013/1/SM-4 consists of white powder. Amfetamine, a prohibited sudstance included in the National Law for Narcotics, is found to be present in this sample.
Statement of findings for Test Sample 4
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Code Amfetamine4ED4U4 +
0.229 grams of a powder containing 10% Amfetamine. Amfetamine is a Class B drug subject to the provisions of the Misuse of Drugs Act 1971.
4FLYLL +
4P9OST +Sample 2013/1/SM-4 was found to contain controlled substance AMPHETAMINE, a Schedule II drug under the Convention on Psychotropic Substances.
4ZRH5B +amfetamine
5AL4YL +
5ZSPFZ +we found in that sample many different sugars.
6CS6GB +Hexosa, 1,6 Anhidro-alfa-D-Galactosa
77H7IH +We found Amphetamine in SM-4 as controlled drug
78CN24 +Après analyse, l'échantillon 2013/1/SM-4 contient l'amphétamine
7BREL7 +On analysis, i found the substances to contain 10.83% of amphetamine.
7H5WS7 ANP
88O8O8 +
8KXYZQ +Sample contain Amphetamine.
8LLTJE +amphetamine was as sulfate form
8QXEZ5 +amfetamine,sorbitol, trimethyltriborate
99WMWJ +The sample contains 8.3 % amfetamine
9EU3UC +
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Code Amfetamine9WEC99 +
/
AJWS6O +One glass bottle labelled '2013/1/SM-4' containing 0.221g of off-white powder. This powder contained on average of 10% amphetamine. Amphetamine is a class B controlled drug under the misuse of Drugs Act (1971)(as ammended).
AMA50Q +White powder containing amphpetamine.
APYADP +the sample was confirmed by gc ms
B824TN +Amfetamine
BBEBBB +SM 4 contain also Sucrose
BPBBMB +Analysis of the powder revealed the presence of Amphetamine
BZBJBP +Amphetamine, sucrose
C2WUON +-
C5ZRZ2 +SORBITOL
CIIE5Y -IN THE SAMPLE RECEIVED IN COLOR AMBER GLASS BOTTLE WITH PLASTIC CAP STAMPED GREEN MISSING AS DRUGS 2013/1/SM-4.
CLW6JW +Diluted with sucrose
CQC6CC +AMPHETAMINE 10.3% AS BASE.
CSDDCC +saccharose, sorbitol or mannitol
DDXKOD +The sample 2013/1/SM-4 was found to contain Amphetamine.
DVAVS7 +The sample contains amphetamine which is scheduled as illicit drug in France.
EIJIBE +AMPHETAMINE SULFATE (15.5 as base)
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