international journal of photochemistry - vol 2_issue 2
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International Journal of
Photochemistry
Jul–Dec 2016
Mechanical Engineering
Electronics and Telecommunication Chemical Engineering
Architecture
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¬ International Journal of Thermal Energy andApplications
¬ International Journal of Production Engineering¬ International Journal of Industrial Engineering
and Design¬ International Journal of Manufacturing and
Materials Processing¬ International Journal of Mechanical Handling and
Automation
« International Journal of Radio Frequency Design« International Journal of VLSI Design and Technology« International Journal of Embedded Systems and Emerging
Technologies« International Journal of Digital Electronics« International Journal of Digital Communication and Analog
Signals
« International Journal of Housing and Human SettlementPlanning
« International Journal of Architecture and Infrastructure Planning
« International Journal of Rural and Regional Planning Development
« International Journal of Town Planning and Management
Applied Mechanics
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Computer Science and Engineering « International Journal of Wireless Network Security« International Journal of Algorithms Design and Analysis« International Journal of Mobile Computing Devices« International Journal of Software Computing and Testing« International Journal of Data Structures and Algorithms
Nanotechnology« International Journal of Applied Nanotechnology« International Journal of Nanomaterials and Nanostructures« International Journals of Nanobiotechnology
« International Journal of Solid State Materials« International Journal of Optical Sciences
Physics
« International Journal of Renewable Energy and itsCommercialization
« International Journal of Environmental Chemistry« International Journal of Agrochemistry« International Journal of Prevention and Control of Industrial
Pollution
Civil Engineering« International Journal of Water Resources Engineering« International Journal of Concrete Technology« International Journal of Structural Engineering and Analysis« International Journal of Construction Engineering and
Planning
Electrical Engineering« International Journal of Analog Integrated Circuits« International Journal of Automatic Control System« International Journal of Electrical Machines & Drives« International Journal of Electrical Communication
Engineering« International Journal of Integrated Electronics Systems and
Circuits
Material Sciences and Engineering « International Journal of Energetic Materials« International Journal of Bionics and Bio-Materials« International Journal of Ceramics and Ceramic Technology« International Journal of Bio-Materials and Biomedical
Engineering
Chemistry « International Journal of Photochemistry« International Journal of Analytical and Applied Chemistry« International Journal of Green Chemistry« International Journal of Chemical and Molecular
Engineering
« International Journal of Electro Mechanics andMechanical Behaviour
« International Journal of Machine Design andManufacturing
« International Journal of Mechanical Dynamicsand Analysis
« International Journal of Fracture and damageMechanics
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Biomaterials« International Journal of Plant Biotechnology« International Journal of Molecular Biotechnology« International Journal of Biochemistry and Biomolecules« International Journal of Animal Biotechnology and
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International Journal
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Photochemical logic gate
Photoreceptor systems in plants
Blue light systems
Etiolated and de-etiolated growth pattern of plants
Blue light photoreceptors
Phytochromobilin
Photomorphogenetic mutants
Chloroplast development
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Hidam Renubala
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EDITORIAL BOARD MEMBERS
Dr. Yee-Wen YenProfessor/Vice Dean of College of Engineering
Department of Materials Science and Engineering National Taiwan University of
Science and Technology, Taiwan
Dr. Lakhwinder SinghAssociate Professor and Head Department of
Applied Science, CGC College of Engineering Punjab, India
Dr.Rajesh Kumar SahuAssociate Professor Department of Chemistry
Vishwavidyalaya Engineering CollegeLakhanpur Sarguja University Ambikapur
Chattisgarh, India
Dr. Kakali PurkayasthaAll India Institute of medical Sciences,
India
Dr. Tanveer AlamM.Sc., Ph.D. Techno commercial DirectorUoN Chair of Oman's Medicinal Plants &
Marine Natural Products University of Nizwa, Nizwa Sultanate of Oman, Oman
Dr Yogesh Kumar SharmaSwami Shraddhanand College, Dept. of
Chemistry University of Delhi, Alipur, New Delhi, India
Dr. Sharad M SontakkeInstitute of Chemical Technology, Mumbai,
Maharashtra, India
Dr. Pradipta Kumar BeheraSambhalpur University, India
Dr. Shubha JainSchool of Studies in Chemistry & Biochemistry,
Vikram University, Ujjain, Madhya Pradesh, India
Ramakrishna RaoDepartment of Chemistry, GITAM School of Technology, GITAM University, Bangalore,
Karnataka, India
Dr. G Vijaya LakshmiDepartment of Chemistry, University College of
Technology, Osmania University, Hyderabad,Andhra Pradesh, India
Dr. Satyabrata MohapatraEmami Ltd., India
Dr. Dinesh Nivrutti NavaleDepartment of Chemistry, Vivekanand Education
Society's College of Arts, Science and Commerce, Mumbai, Maharashtra, India
Dr. Purav M. BadaniDepartment of Chemistry, University of Mumbai, Vidyanagari, Santacruz (East),
Mumbai, Maharashtra, India
Dr. J John Peter PaulDepartment of Botany, St.Xavier's College
Palayamkottai, Tamil Nadu, India
Dr. Rajib Ghosh ChaudhuriDepartment of Chemical Engineering, Birla Institute of Technology & Science, Pilani,
Dubai Campus, Dubai International Academic City, Dubai, UAE
From the Editor's Desk
Dear Readers,
We would like to present, with great pleasure, the inaugural volume of a new scholarly
journal, International Journal of Photochemistry. This journal is part of the Applied
Sciences, and is devoted to the scope of present Photochemistry issues, from theoretical
aspects to application-dependent studies and the validation of emerging technologies.
This new journal was planned and established to represent the growing needs of Photochemistry as an
emerging and increasingly vital field, now widely recognized as an integral part of scientific and technical
investigations. Its mission is to become a voice of Photochemistry, addressing researchers and practitioners
in this area.
The core vision of International Journal of Photochemistry in JournalsPub is to propagate novel awareness
and know-how for the profit of mankind ranging from the academic and professional research societies to
industry practitioners in a range of topics in Photochemistry in general. JournalsPub acts as a pathfinder
for the scientific community to publish their papers at excellently, well-timed & successfully. International
Journal of Photochemistry focuses on original high-quality research in the realm of Atmospheric
thermodynamics, Biological thermodynamics, Chemical thermodynamics, Equilibrium thermodynamics,
Maximum entropy thermodynamics, Non-equilibrium thermodynamics, Maximum entropy
thermodynamics, Non-equilibrium thermodynamics, Reaction's mechanism, Gas phase kinetics, Solution
kinetics etc.
The Journal is intended as a forum for practitioners and researchers to share the techniques of
Photochemistry and solutions in the area. Many scientists and researchers have contributed to the creation
and the success of Photochemistry. We are very thankful to everybody within that community who supported
the idea of creating an innovative platform. We are certain that this issue will be followed by many others,
reporting new developments in the field of Photochemistry.
This issue would not have been possible without the great support of the Editorial Board members, and we
would like to express our sincere thanks to all of them. We would also like to express our gratitude to the
editorial staff of JournalsPub, who supported us at every stage of the project.
It is our hope that this fine collection of articles will be a valuable resource for Photochemistry readers and
will stimulate further research into the vibrant area of Photochemistry.
Puneet Mehrotra
Managing Director
1. Development of Continuous Photocatalytic Reactor: Effect of Various Parameters Sharad M. Sontakke, Priyanka H. Kamble 1
2. Light Sensing PhotoreceptorsZeanut Akoijam 9
3. Plant Responses to Light StressAmit Agnihotri 11
4. Gibberellin and Seed GerminationVishal Jain 13
5. Light Dependent Processes in PlantsAmit Agnihotri 16
Contents
IJP (2016) 1-8 © JournalsPub 2016. All Rights Reserved Page 1
International Journal of Photochemistry Vol. 2: Issue 2
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Development of Continuous Photocatalytic Reactor: Effect of
Various Parameters
Sharad M. Sontakke*, Priyanka H. Kamble Department of Chemical Engineering, Institute of Chemical Technology, Mumbai, India
ABSTRACT
Water purification by heterogeneous photocatalysis is one of the rapidly growing areas of
interest amongst the researchers. For mass application of the technology, efficient and
economic reactor design is necessary which should address two important parameters,
namely, light distribution inside the reactor and high surface area of irradiated catalyst per
unit volume of reactor. The present study reports design of a continuous photocatalytic
reactor using an easy-to-apply and economic TiO2 paste. TiO2 obtained by four different
sources were studied and based on photoactivity as well as economy a suitable material was
shortlisted. A paste of TiO2 was synthesized using the shortlisted material and coated on two
different substrates, namely, glass and acrylic. Effect of various parameters such as choice of
substrate, number of layers and number of coated slides on the photocatalytic degradation of
Methylene blue was investigated in a batch photocatalytic reactor. The optimum conditions
from the batch studies were used to design a continuous photocatalytic reactor. Degradation
of Methylene blue was investigated in the continuous mode and it was observed that the
reactor displayed same degradation efficiency for at least three cycles. Keywords: continuous reactor, Methylene blue, photocatalysis, titanium dioxide
INTRODUCTION
Advanced oxidation processes (AOPs), such as photocatalysis, have shown a great promise as an alternative to the conventional water treatment technologies. TiO2, due to its superior properties, is a preferred material in the photocatalytic degradation studies.[1] The catalyst can be used in two ways namely, suspended and immobilized. The advantage of suspended catalyst is the availability of large surface area for the reaction, however, the separation and reuse of the catalyst are the serious disadvantages associated with it.[1] On the other hand, the available surface area for the reaction in case of immobilized catalyst is less compared to the equivalent amount of slurry catalyst. Suspended catalyst (or in slurry form) is extensively studied in the literature however, a very
limited attention is given to the immobilized (or supported) catalyst. Several substrates have been used for immobilization of catalyst which includes glass beads, glass tubes, glass fiber, semipermeable membranes, ceramic membranes, porous filter pipes, stainless steel, etc.[1–3] The immobilization of the catalyst is reported by various techniques such as spray coating, dip coating, chemical vapor deposition, sol–gel and electrophoretic deposition.[3] However, most of the immobilization techniques reported in literature are costly and require use of a sophisticated instrument.
IJP (2016) 9-10 © JournalsPub 2016. All Rights Reserved Page 9
International Journal of Photochemistry Vol. 2: Issue 2
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Light Sensing Photoreceptors
Zeanut Akoijam* Department of Chemistry, Manipur University, Manipur, India
ABSTRACT
Light is a vital factor for plant growth and development. Plant responds to light in different
ways. Plants consist of special receptors that perform various mechanisms in multi-steps to
regulate different aspects of plant growth and development. Here, in this short article, an
overview of these light harvesting photoreceptors is given.
Keywords: COP1, phytochrome, photoreceptors, phototropin BACKGROUND
Light is undoubtedly a vital abiotic factor regulating plant growth and development throughout their life-cycle. Several light sensing mechanisms have been developed in plants for regulating their responses towards light quality, intensity, duration of exposure or periodicity, direction or movement, etc.[1] Plants contain several photoreceptors that play important role in mediating different developmental processes in response to light. These photoreceptors consist of multiple steps of transduction chains that regulate different aspects such as gene expression, interaction among the plant hormones, developmental changes in plant cell membrane etc. Some of the plant photoreceptors involved in regulation of these activities is briefed here. Phytochrome
It is a protein molecule consisting of covalently attached chromophore. Phytochrome may exist in two different based on absorption spectra from light. The active form is the Pfr that absorbs red light of the spectra. The other form, Pr absorbs red light. These two forms are interconvertible, i.e., absorbtion of red light converts Pr to Pfr while absorbtion of
far red converts Pfr to Pr.[2] Since, these forms of the phytochrome are interconvertible; the plant response is largely regulated by this red/far red reversibility. A typical example is the phenomenon of germination in lettuce. Germination is induced when the lettuce seeds are exposed to red light. However, if the red light is followed by even a short pulse of far red light, germination is inhibited. Since, phytochrome can exist in two forms depending on red or far-red light; this photoreceptor is often used as an indicator of light quality.[2–4] Besides germination, phytochrome also mediates other photomorphogenic phenomena such as leaf expansion and inhibition of stem elongation. Phytochrome also undergoes autophosphorylation, owing to the presence of protein kinase receptors. Phototropin
Phototropin is the blue light receptor of plants. Phototropism is controlled mainly by blue/UVA light. It brings directional growth of the stem. In other words, it causes shoots to grow towards light, referred as positively phototropic. Roots on the other show negative phototropism
IJP (2016) 11-12 © JournalsPub 2016. All Rights Reserved Page 11
International Journal of Photochemistry Vol. 2: Issue 2
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Plant Responses to Light Stress
Amit Agnihotri* Department of Chemical Engineering, ITM Institute of Technology and Management, Gwalior,
Madhya Pradesh, India
ABSTRACT
Light is crucial for several physiological processes that control growth and development in
plants. However, though crucial, excessive light can be harmful and detrimental for the plant
causing photo-damage. Plants have adapted several mechanisms in order to respond against
the light stress. Such protective response adapted by the plant depends upon the intensity and
duration of the light stress.
Keywords: light stress, photo-inhibition, photosynthetic quantum conversion
Light is considered to be an essential ingredient for good plant growth. Inspite of being crucial for growth, exposure to excess levels of light can cause detrimental effects on plant function and development. Light is primarily required by plants to carry out photosynthesis, a process whereby plants turn the energy of light into their own building materials i.e., sugars. More the light is available, more energy is absorbed and consequently more sugars are formed. This enhances the overall plant growth including flowers growing bigger, fruits becoming sweeter, crops flourishing rapidly, etc. If plants are exposed to light intensities beyond their photosynthetic capacity, there is potential for photo-damage.[1–4] Light stress has been the least characterized and studied among the various types of abiotic stresses encountered by the plants. Plants being immobile cannot escape and have to face the light stress. In order to overcome the detrimental consequences of such hostile circumstances, plants have developed certain protective and adaptive stress responses such as[5]:
(1) Lowering the cross-sectional area of plant surface exposed to light, thereby reducing the amount of light absorbed.
(2) Increasing the rate of photosynthetic quantum conversion in chloroplasts.
(3) Increasing heat emission such as by de-epoxidation of violaxanthin to zeaxanthin.
(4) Rise of non-photochemical de-excitation of absorbed light quantum.
(5) Photo-inhibition of the photosynthetic pigment apparatus.
During stress exposure, plants undergo through different phases which have been categorized into 4 parts viz. (1) Response phase (alarm reaction) (2) Resistance phase (3) Exhaustion stage
(4) Regeneration phase, in which the physiological function is gradually restored once the source of stress is removed
The length (hours, days) of the regeneration phase to take the plant back to a normal physiological function depends on the strength and duration of the stress. The light stress either directly or
IJP (2016) 13-15 © JournalsPub 2016. All Rights Reserved Page 13
International Journal of Photochemistry Vol. 2: Issue 2
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Gibberellin and Seed Germination
Vishal Jain MM College, Modinagar, Uttar Pradesh, India
Plants undergo several developmental processes throughout their life-cycle. Several plant hormones participate in these growth and developmental processes. Plant hormones are chemical signals that are produced by cells in one area such as leaves, stems or root, and transported to a different area of the plant, where it generates a specific response. In this way, hormones co-ordinate different parts of the plant and regulate various physiological activities. Five major plant hormones are known: auxin, ethylene, cytokinin, abscisic acid and gibberellin. Though required in very small quantities, all of these play countless important functions in plants. This review describes the importance of gibberellin hormone in plants with main emphasis on its role in seed germination. Gibberellin was first isolated in 1938 from the metabolite product of rice pathogenic fungus Gibberella fujikuroi; the causal agent of the ‘foolish-seedling’ disease of rice.[1,2] Gibberellins are synthesized from geranyldiphosphate by a specific pathway including several enzymes. Gibberellins regulate diverse developmental processes throughout the plant life cycle such as stem elongation, leaf expansion, influence transition from juvenile to mature stage, pollen maturation, induction of flowering, fruit ripening, trichome development, sex determination and various aspects of seed germination such as breaking dormancy, mobilization of endosperm reserves.[3–5] Seed germination, an important step in the plant life cycle, is a complex mechanism wherein physiological and morphological alterations take place resulting in activation of the embryo. The pathways
leading to seed germination is initiated with the release of coat dormancy, ‘weakening of endosperm’, and ‘expansion of embryo cell’. Many researchers have evaluated the processes involved in seed germination, and how they are affected by plant hormones in different plant families like Brassicaceae.[6,7] It has been indicated that there is an intimate interaction between gibberellins metabolism and gibberellins response pathways. This kind of interaction, along with other pathways in the plant, results in the regulation of plant growth and development. Some reports suggest that gibberellins stimulate the synthesis and production of hydrolases particularly α-amylase that leads to the germination of seeds. While there are some others that though confirms the role of gibberellin in seed germination, rule out the opinion that gibberellin promotes seed germination via amylase production.[8] Using proteomic analysis, Gallardo et al. (2002) indicated the way via which the germination of Arabidopsis seeds is regulated by gibberellins.[9] In a view to identify the proteins whose abundance depends on the action of gibberellin during different stages of seed germination, Gallardo et al. pointed out that the gibberellin do not directly participates in the processes leading to seed germination. Instead, the hormone is involved in controlling the accumulation level of proteins associated with radicle protrusion and post-germination processes. An example of such protein being the cytoskeleton component, α-2,4 tubulin.[9]
IJP (2016) 16-18 © JournalsPub 2016. All Rights Reserved Page 16
International Journal of Photochemistry Vol. 2: Issue 2
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Light Dependent Processes in Plants
Amit Agnihotri Department of Chemical Engineering, ITM Institute of Technology and Management,
Gwalior, Madhya Pradesh, India
Light is vital for the survival of all living organisms on Earth. It is hard to imagine life without light. The source of light, the Sun, is the universal source of energy for all life on Earth. It helps the human beings to carry out daily routine work very easily. It is also required for growth and development of plants; bacteria such as cyanobacteria, green sulfur bacteria. In plants, the solar energy or light is absorbed and converted into another useful form, i.e., chemical energy. This review gives a brief insight into the various growth and developmental processes in plant that are controlled or regulated by light. Plants show different responses in presence to light. This phenomenon is called phototropism. A classic example is the bending of a plant stem towards light. Anyone who has grown a plant near a window would have observed that the plant usually bends toward the window where the light is stronger than inside the room. Another commonly experienced example of tropic response is gravitropism, where the plant grows in such a way so as to stay oriented relative to the source of gravity (the earth). Thus, in case a plant is knocked down, the shoot will grow faster on the lower side until the shoot is more-or-less standing up again. Such phototropic responses are regulated by specific blue-light photoreceptors called phototropins. Gravitropism is dependent on the presence of starch-filled plastids called amyloplasts in specialized cells. When the orientation of cells change, the mass of amyloplasts causes them to sink and tumble towards lower end of the
cell. As a result, differential growth occurs causing curvature in the plant. Several reports are available in literature that have described in detail how light effects the movement and/or functioning of different plant parts/cellular organelles. Light-dependent changes in the leaflet movement rhythm of Desmodium gyrans, the Indian telegraph plant was studied in detail by Sharma et al.[1] The movements and oscillations of the lateral leaflets of this plant were analyzed in response to different chemicals, DC currents, and static magnetic fields. It showed that the frequency of oscillations was more and rapid in presence of bright light, while low light intensity slowed down the oscillations. short period oscillations of the lateral leaflets actually was an adaptive response of the plant in order to optimize the amount of light falling on the leaflets thereby facilitating transpiration of water through stomata. Mimosa pudica is a highly sensitive and unique plant that shows rapid leaf movement. In response to any physical disturbance, this species folds its leaves in a fraction of seconds. Under conditions of high light, the plant immediately closes its leaves. This action is opposite of what is expected from the principle of energetics, according to which, the plant in high light, having abundant energy available to them should more rapidly open its leaves to allow capturing of more and more solar energy.
International Journal of
Photochemistry
Jul–Dec 2016
Mechanical Engineering
Electronics and Telecommunication Chemical Engineering
Architecture
Office No-4, 1 Floor, CSC, Pocket-E,Mayur Vihar, Phase-2, New Delhi-110091, India
E-mail: [email protected]
¬ International Journal of Thermal Energy andApplications
¬ International Journal of Production Engineering¬ International Journal of Industrial Engineering
and Design¬ International Journal of Manufacturing and
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« International Journal of Radio Frequency Design« International Journal of VLSI Design and Technology« International Journal of Embedded Systems and Emerging
Technologies« International Journal of Digital Electronics« International Journal of Digital Communication and Analog
Signals
« International Journal of Housing and Human SettlementPlanning
« International Journal of Architecture and Infrastructure Planning
« International Journal of Rural and Regional Planning Development
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Applied Mechanics
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Computer Science and Engineering « International Journal of Wireless Network Security« International Journal of Algorithms Design and Analysis« International Journal of Mobile Computing Devices« International Journal of Software Computing and Testing« International Journal of Data Structures and Algorithms
Nanotechnology« International Journal of Applied Nanotechnology« International Journal of Nanomaterials and Nanostructures« International Journals of Nanobiotechnology
« International Journal of Solid State Materials« International Journal of Optical Sciences
Physics
« International Journal of Renewable Energy and itsCommercialization
« International Journal of Environmental Chemistry« International Journal of Agrochemistry« International Journal of Prevention and Control of Industrial
Pollution
Civil Engineering« International Journal of Water Resources Engineering« International Journal of Concrete Technology« International Journal of Structural Engineering and Analysis« International Journal of Construction Engineering and
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Electrical Engineering« International Journal of Analog Integrated Circuits« International Journal of Automatic Control System« International Journal of Electrical Machines & Drives« International Journal of Electrical Communication
Engineering« International Journal of Integrated Electronics Systems and
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Material Sciences and Engineering « International Journal of Energetic Materials« International Journal of Bionics and Bio-Materials« International Journal of Ceramics and Ceramic Technology« International Journal of Bio-Materials and Biomedical
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Chemistry « International Journal of Photochemistry« International Journal of Analytical and Applied Chemistry« International Journal of Green Chemistry« International Journal of Chemical and Molecular
Engineering
« International Journal of Electro Mechanics andMechanical Behaviour
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Biomaterials« International Journal of Plant Biotechnology« International Journal of Molecular Biotechnology« International Journal of Biochemistry and Biomolecules« International Journal of Animal Biotechnology and
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