installation name & address for inspection purposes only. · flare stack job number: cek-2280,...

ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland

Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL

DublinLusk

Fingal Timoney & Company

Flare Stack

70 Montrose Avenue, Hillington Park, Glasgow, G52 4LAT: 0800 328 1821 (or + 44 161 432 3286 from overseas)

E: [email protected] Exova Catalyst Ireland Contact: John Healey (07826 916 681)

Balleally Balleally Landfill Site

Fingal County Council

Stack Reference

Waste Licence: W0009-03

Stack Emissions Testing Report Commissioned by

Installation Name & Address

Flare Stack

TE1 TE2 TE3 TE4MM 03 476

MCERTS Level 2

John HealeyReport Approved by

MM 10 1061MCERTS Level 2

Version

Signature of Report Approver

Version 1

Team Leader

Regional Manager

19th October 2016

Job Reference NumberCEK-2280

Dates of the Monitoring Campaign

Report Written byStephen Dick

9th November 2016Report Date

TE1 TE2 TE3 TE4

CAT-RT (Version BP)CEK-2280 Fehily Timoney & Co (Balleally Landfill) - Flare Stack Report

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EPA Export 16-01-2017:14:57:28

TITLE PAGE

CONTENTS

Summary of Sampling Deviations

EXECUTIVE SUMMARY

Monitoring Objectives

Monitoring Results

Monitoring Dates & Times

Process Details

Monitoring & Analytical Methods

Sampling Location

Plant Photos / Sample Points

APPENDIX 1 - Monitoring Personnel & List of Equipment

APPENDIX 2 - Raw Data, Sampling Equations & Charts

Opinions and interpretations expressed herein are outside the scope of Exova Catalyst Ireland's ISO 17025 accreditation.

9

3

5

6

8

7

CONTENTS

4

2

This test report shall not be reproduced, except in full, without the written approval of Exova Catalyst Ireland.

The testing performed fully meets the technical requirements in Irish EPA Guidance Note, AG2.

CAT-RT (Version BP) of 35

Fingal County CouncilBalleallyFlare Stack

Job Number: CEK-2280, Version 1Sample Date/s: 19th October 2016


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EPA Export 16-01-2017:14:57:28

Overall Aim of the Monitoring Campaign

Special Requirements

Target Parameters

Hydrogen Fluoride | Hydrogen Chloride | Total VOCs (as Carbon) | Oxides of Nitrogen (as NO₂) | Carbon Monoxide |

(Page 1 of 7)

MONITORING OBJECTIVES

Executive Summary

Exova Catalyst Ireland were commissioned by Fingal Timoney & Company to carry out stack emissions testing for Fingal County Council on the Flare Stack at Balleally.

The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values (ELVs) as specified in the Site's Permit.

There were no special requirements.

Fingal County Council, BalleallyFlare Stack

19th October 2016





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EPA Export 16-01-2017:14:57:28

where MU = Measurement Uncertainty associated with the Result

Parameter

Hydrogen Fluoride ¹ < .Hydrogen Chloride ¹ - .Total VOCs (as Carbon) ¹ - .Oxides of Nitrogen (as NO₂) ¹ - .Carbon Monoxide ¹ - .Oxygen Dry

Water Vapour

¹ Reference Conditions (REF) are: 273K, 101.3kPa, dry gas, 3% oxygen.* The MU is calculated from values in LFTGN 05 [2010]. i.e. 20% of the Result for CO, 30% of the Result for NOx & 40% of the Result for TVOCs)

- --mg/m³

mg/m³-

1.48

% v/v 0.60.55

-

--

Concentration

-Limit **+/-

#--

0.151.88 -

** The result is considered to be an 'Approach to Limit' if it is above the Limit, but below the Limit once the MU is subtracted from it. The Result is considered to be Non-Compliant if, even after subtracting the MU from the Result, the Result is still above the Limit in LFTGN 05 [2010] or the calculated MU (See the Measurement Uncertainty Calculations in Appendix 2 of this Test Report) is above 6% for CO, 10% for NOx & 15% for TVOCs

11.0

23.7 150

-50

Executive Summary

-

MONITORING RESULTS

mg/m³

Flare Stack

mg/m³ 0.40 #--

-Result -

5

MU *

12.3

0.4379.0 #

(Page 2 of 7)

0.30 50

1.06

% v/v

-0.03 -

Fingal County Council, Balleally

`

-Units

#

#-

mg/m³ -10 -

-





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EPA Export 16-01-2017:14:57:28

Parameter

R1 < .R1 - .R1 - .R1 - .R1 - .R1 -

All results are expressed at the respective reference conditions.

Date(s)--

0.40

Flare Stack19th October 2016

Executive Summary

SamplingTimes-

(Page 3 of 7)

Units

mg/m³ - 19/10/2016

-


MONITORING DATE(S) & TIMES

mins

14:32 - 15:02

60

14:00 - 14:30

% v/v

mg/m³ 19/10/2016-

3019/10/2016

DurationConcentration Sampling

-Hydrogen Chloride

mg/m³1.88

-Hydrogen Fluoride30

Carbon Monoxide79.0

19/10/2016-

-19/10/2016mg/m³

1.06

1.48

14:02 - 15:02

14:02 - 15:02-

14:02 - 15:02

mg/m³-

14:02 - 15:02

Oxygen

60-

606019/10/2016

-

10.9

Total VOCs (as Carbon)Oxides of Nitrogen (as NO₂)





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EPA Export 16-01-2017:14:57:28

Standard Operating Conditions

Value


Feedstock (if applicable)

Capacity (of 100%) and Tonnes / HourContinuous or Batch Process

Landfill gasN/A

Continuous when Operational

Flare Process Status

Flare Stack19th October 2016

Abatement SystemAbatement System Running Status

Plume Appearance

N/AN/A

Fuel

Parameter

(Page 4 of 7)Executive Summary

PROCESS DETAILS

None Visible

N/A





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EPA Export 16-01-2017:14:57:28

0.1 % v/vCAT-TP-05 Yes

EN 15058

0.41 mg/m³CAT-TP-21

CATYes

EN 14790EN 12619:2013

CATDry Zirconia Cell by Horiba PG-250CATOxygen

CAT-TP-05Yes

YesEN 14789 CAT-TP-21 Yes 0.1 %

YesCarbon Monoxide

YesCAT-TP-20

CAT Yes

Yes

Yes

(with short name reference as appears in the table above)

Exova Catalyst (CAT)

CAT

ISO 17025 Accreditation Number: 4279ISO 17025 Accreditation Number: 0605

Oxides of Nitrogen (as NO₂)NDIR by Horiba PG-250

GravimetricWater Vapour

ANALYSIS LABORATORIES

CAT 0.32 mg/m³

0.62 mg/m³

Total VOCs (as Carbon)

EN 1911Yes IC

0.437 mg/m³CATYes

ICHydrogen ChlorideYesYes CATCAT-TP-11 Yes Yes

Flame Ionisation Detection by Sick 3006 FID

RPS Laboratories Ltd (RPS)

YesChemiluminescence by Horiba PG-250EN 14792

CAT-AP-01

MCERTS17025

Testing

Executive Summary

(Average)Analytical

TechniqueProcedure Testing

0.4 mg/m³CATCAT

LabISO

Lab

Hydrogen Fluoride

Standard

Monitoring

ParameterProcedure

Analytical

CAT-AP-01

Technical

ISO 15713 CAT-TP-10

Analysis

Analysis17025

Analysis

LOD

Flare Stack

(Page 5 of 7)

Testing ISO


MONITORING & ANALYTICAL METHODS

CAT-TP-21

19th October 2016

SUMMARY OF SAMPLING DEVIATIONS

Deviation

All Parameters All There are no deviations associated with the sampling employed.

Parameter Run





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EPA Export 16-01-2017:14:57:28

Duct Characteristics Location of Sampling Platform

Platform Details

Sampling Location / Platform Improvement Recommendations

Executive Summary

cm

-

MEWP

Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)

-

Sufficient working area to manipulate probe and operate the measuring instruments

Type-

Parameter

There are no obstructions present which hamper insertion of sampling equipment

Yes

-

(Page 6 of 7)

Units

Vertical

Yes

Platform has chains / self closing gates at top of ladders

All platforms should be designed in accordance with the requirements in EPA Guidance Note AG1 and EN 15259.

Yes

Width

YesSafe Access Available

General Platform Information

Permanent / Temporary Platform

N/A

20-

m²m

Sample Port Size

Circular

Value

Value

Platform has vertical base boards (approx. 0.25m high)N/AN/A

SUITABILITY OF SAMPLING LOCATION

OutsideInside / Outsidem

-

Orientation of Duct

Irish EPA Technical Guidance Note AG1 / EN 15259 Platform Requirements

Port DepthArea

Value

4" Flange

Easy Access Available

Depth

EN 15259 Homogeneity Test Requirements

All platforms should be designed in accordance with the requirements in EPA Guidance Note AG1 and EN 15259.

There is no requirement to perform a EN 15259 Homogeneity Test on this Stack.





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EPA Export 16-01-2017:14:57:28

Photo 2

PLANT PHOTOS

(Page 7 of 7)

Photo 1

Photo 3

Executive Summary

SAMPLE POINTS

Line A

where = isokinetic point sampled at

= isokinetic point not sampled at

= combustion gases sample point

A1

= non-isokinetic sample point





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EPA Export 16-01-2017:14:57:28

APPENDIX 1 - Stack Emissions Monitoring Personnel, List of Equipment & Methods and Technical Procedures Used

APPENDIX 2 - Summaries, Calculations, Raw Data and Charts

APPENDICES

APPENDIX CONTENTS





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EPA Export 16-01-2017:14:57:29

Bioaerosols Temperature Logger -Electronic Refrigerator -

CAT 9.10

Position

Box Thermocouples (2)Box Thermocouples (1)

LIST OF EQUIPMENT

StopwatchServomex 4900

-

CAT 25.4

MCERTS Number

Miscellaneous Items

CAT 7.38

-

CAT 3.57

Gasmet DX4000

Horiba PG-350E

MM 10 1061MCERTS Trainee MM 16 1385 None

Eco Physics CLD 822MhABB AO2020-URAS26

TE1 TE2 TE3 TE4Trainee Kyle Barbour

-

Stack Thermocouple (1)

Gasmet Sampling SystemCAT 5.4

Digital Temperature Meter

Heated Probe (3) -CAT 6.11

Bernath 3006 FID CAT 8.4-

CAT 5.8 1m Heated Line (2)Heated Probe (2)

Equipment Type

Control Box DGM (2)

-

Stephen Dick MCERTS Level 2

Mass Flow Controller (2) CAT 6.12CAT 21P.33

CAT 3.34 / 3.54-

-

Umbilical (1)

CAT 4.206

-

Umbilical (2) Servomex 5200MP

CAT 11.6 Easylogger EN-EL-12 Bit CAT 11.19

Dual Channel Heater Controller500g / 1Kg Check Weights CAT 17.4Last Impinger Arm CAT 4.22 / 4.44 / 4.643

CAT 3.15

Callipers

- 20m Heated Line (1)15m Heated Line (1)

CAT 14.4

CAT 5.11

Heated Probe (1)

--

CAT 12.963

CAT 3.57-

Mass View (2)

CAT 12.72

-

Tubes Kit Thermocouple -

20m Heated Line (2)

Single Channel Heater Controller

-

JCT JCC P1 Cooler

CAT 13.24

Mass Flow Controller (1)


Technical Endorsements

Team Leader

S-Pitot (2) CAT 21S.28 / 21S.4

CAT 3.34

CAT 14.53

-

S-Pitot (1)

L-Pitot-


Mass View (1) CAT 25.3

Barometer

Digital Manometer (2)

Oven Box (2)1m Heated Line (1)

CAT 3.54

Oven Box (1)

-Laboratory BalanceTape Measure CAT 16.3

Equipment I.D.Digital Manometer (1)Horiba PG-250

CAT 23.22

Equipment Type

Easylogger EN-EL-12 Bit

CAT 20.8

Equipment Type

CAT 4.934

5m Heated Line (1) CAT 20.4

Site Balance

-

Equipment I.D.Control Box DGM (1)

CAT 4.883

Extractive Sampling

MCERTS Accreditation

Equipment I.D.

STACK EMISSIONS MONITORING PERSONNEL

APPENDIX 1

Name

Instrumental Analysers

Ankersmid APP100 1m Heated Line (3)

Electronic Refrigerator -

METHODS & TECHNICAL PROCEDURES USED

EN 14792

Water Vapour

Parameter

CAT-TP-21

EN 14790Total VOCs (as Carbon)

Hydrogen Chloride

Oxides of Nitrogen (as NO₂)

CAT-TP-21CAT-TP-21

Technical ProcedureStandard

OxygenCarbon Monoxide

EN 14789EN 15058

Tubes Kit Thermocouple -

ISO 15713

Tape Measure CAT 16.3

CAT-TP-11CAT-TP-10

CAT-TP-20CAT-TP-05

EN 12619:2013

Hydrogen FluorideEN 1911





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EPA Export 16-01-2017:14:57:29

Sample Runs

- -

< <

- -

- -

- -

- -

Blank Runs

- -

APPENDIX 2

Mass Emission

Maximum

±% v/v

Mean


Parameter Units

g/hr

Units

Units

11.0

HYDROGEN FLUORIDE: RESULTS SUMMARY

Parameter

0.03

0.40

0.52

0.03±mg/m³

mg/m³

Uncertainty

Uncertainty ±g/hr

Run 1

Flare Stack

Mean

0.40Concentration

Parameter Blank 1

Run 1

11.0Water Vapour % v/v

0.52

Uncertainty

< <

General Sampling Information

FORMAT: Number Used / Number Required


Reference Conditions

Reference Conditions are: 273K, 101.3kPa, dry gas, 3% oxygen.

Standard

0.27

Number of Sampling Lines Used

A1

YesDate of Sample Analysis 02/11/2016

ISO 15713Technical Procedure

Number of Sampling Points Used

CAT-TP-10

Sample Point I.D.'s

Concentration mg/m³

1 / 1

Parameter

0.1μm Glass Fibre

CAT-AP-01Name of Analytical Laboratory CATAnalytical Laboratory's Procedure

Impinger Material PolyethyleneAbsorption Solution

1 / 1

0.27

ISO 17025 Accredited Analysis?

Value

Probe Material Stainless SteelFilter Housing Material Stainless Steel

0.1 mol/l Sodium Hydroxide

Positioning of Filter Out Stack Heated HeadFilter Size and Material





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EPA Export 16-01-2017:14:57:29

Sample Runs

<<--<<<<

APPENDIX 2

HYDROGEN FLUORIDE: SAMPLING DETAILS

Parameter Units Run 1

Duration

Total Mass Of Water Vapour g 9.9Calculated Water Vapour % v/v 11.02

- MFC / MV

Silica Trap End Mass g

Mass in Back Impinger µg

1541.1

7.1Total Mass Collected µg 22.5

1212.7Liquid Trap End Mass g

mins 30

m³

Sampling Times - 14:32 - 15:02

Sampling Device

0.1120

3.21

ml

0.05Laboratory Result for Back ImpingerVolume in Front ImpingersVolume in Back Impinger

µg/mlSample Flow Rate l/minLaboratory Result for Front Impingers

Silica Trap Start Mass g 1540.5

Volume Sampled (STP, Dry) m³ 0.0996

Mass in Front Impingers µg 15.4

Calculated Concentration mg/m³ 0.40

0.05307.8142.2

Liquid Trap Start Mass g 1203.4

Volume Sampled (REF) m³ 0.0563Volume Sampled (STP, Wet)

Sampling Dates - 19/10/2016

µg/mlml

Where: MFC stands for Mass Flow Controller, MV stands for Mass View Flowmeter

Blank Runs

<-<<

Parameter Units Blank 1

Calculated Concentration mg/m³

Calculated Water Vapour % v/v 11.02

Laboratory Result for Impingers µg/ml 0.05Volume in Impingers ml

Blank Dates - 19/10/2016Average Volume Sampled (REF) m³ 0.0563

Total Mass Collected µg 15.3305.9

0.27





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EPA Export 16-01-2017:14:57:29

Sample Runs

² The concentration is less than 30% of the ELV, therefore no assessment against an allowable efficiency is required. 1 7 0 8

APPENDIX 2

HYDROGEN FLUORIDE: QUALITY ASSURANCE

Leak Test Results Units Run 1

Leak Test Acceptable - Yes

- N/A ²

Water Droplets Units Run 1

Are Water Droplets Present

Less than 50% Faded % Yes

Absorption Efficiency Units Run 1

Absorption Efficiency % 100.0Allowable Absorption Efficiency % N/A ²Absorption Efficiency Acceptable

Run 1

Silica Gel (Concurrent Water Vapour)

MU Acceptable % Yes

Units Run 1

Test Conditions Units Run 1

Measurement Uncertainty (MU) % 4.7

Allowable MU % 20

MU (Concurrent Water Vapour) Units

Allowable Leak Rate l/min 0.06

3.21Pre-Sampling Leak Rate l/min 0.04

l/min

Post-Sampling Leak Rate l/min

- No

Mean Sampling Rate

0.06

Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

Leak Test Results Units Blank 1


Expected Sampling Rate l/min 3.00

Ambient Temperature Recorded? -

Leak Test Acceptable

Nature of Deviation

Pre-Sampling Leak Rate l/min 0.05

Blank AcceptableAllowable Blank

Validity of Blank vs ELV

(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)

There are no deviations associated with the sampling employed.

Run Number

Yes

mg/m³Yes-0.5

Units

Allowable Leak Rate l/min 0.06-

Yes

Post-Sampling Leak Rate l/min 0.04

Blank 1





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EPA Export 16-01-2017:14:57:29

Sampled Volume (STP)LeakLaboratory Result




≤2%

HYDROGEN FLUORIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

Measured Quantities Symbol Units Run 1

Value Standard uncertaintyMeasured Quantities

APPENDIX 2

%

Symbol

-0.0996

mg/m³ 0.0080

Lr

Vm

No Requirement

uVm

Units

2.65

Run 1

2.00

Measured Quantities

% 2.65

m³

Symbol Units Run 1

L 1.87% -

mg/m³ 0.0106

Measured Quantities

4.01

Uncertainty in Measurement Units

1.00L

Uncertainty in ResultUnits Run 1

0.011

m³ 0.002uL

Run 1

mg/m³ 0.004

Lr

0.0996

Vm

Sensitivity Coefficient

uLr

% 1.87

Uncertainty as a Percentage

1.00

Requirement of Standard

%≤2%

mg/m³ 0.0043

Run 1

mg/m³

O₂ Correction FactorStack Gas O₂ ContentMU for O₂ Correction

Combined uncertainty

Expanded uncertainty (95% confidence), without Oxygen CorrectionExpanded uncertainty (95% confidence), with Oxygen CorrectionExpanded uncertainty (95% confidence), estimated with Method DeviationsReported Uncertainty


mg/m³ 0.03

mg/m³ 0.03

mg/m³

- 1.77% v/v 10.83

% 4.92

% 6.8

0.09

Oxygen Correction Part of MU Budget

mg/m³ 0.03

Measured Quantities Units Run 1

Parameter

0.01

8.4

Units Run 1

% 8.4

% 8.4%

-Overall MU For O₂ Measurement

mg/m³ 0.03





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EPA Export 16-01-2017:14:57:29

Sample Runs

- -

- -

- -

- -

- -

- -

Blank Runs

- -

HYDROGEN CHLORIDE: RESULTS SUMMARY

Mean


Parameter

APPENDIX 2

Units Run 1

Concentration

0.15Uncertainty ±mg/m³ 0.15

Uncertainty ±% v/v

13.7

Parameter Run 1

mg/m³ 1.9 1.9

Mass Emission g/hr

Units Mean

Uncertainty ±g/hr

Water Vapour % v/v 13.7

0.61 0.61

Parameter Units Blank 1 Maximum

< <






Parameter

CAT

1 / 1

EN 1911Technical Procedure CAT-TP-11

Name of Analytical Laboratory

1 / 1Number of Sampling Points Used

Standard

Date of Sample Analysis 03/11/2016

CAT-AP-01ISO 17025 Accredited Analysis? Yes

Number of Sampling Lines Used

Sample Point I.D.'s A1

Value

Probe Material Stainless Steel

0.29Concentration mg/m³ 0.29

Filter Housing Material Stainless SteelImpinger Material Borosilicate GlassAbsorption Solution HPLC Grade Water

Positioning of Filter Out Stack Heated HeadFilter Size and Material 0.1μm Glass Fibre

Analytical Laboratory's Procedure





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EPA Export 16-01-2017:14:57:29

Sample Runs

-----<--

Sampling Device

Mass in Back Impinger µg 6.9

Total Mass Of Water Vapour

Silica Trap Start Mass g 1538.2g 1233.5

Volume Sampled (REF) m³ 0.0509Sample Flow Rate l/min 2.99

µg 95.9

13.67

-

Sampling Times

Total Mass Collected

Liquid Trap End Mass

Sampling Dates

Calculated Concentration

g 11.8Calculated Water Vapour % v/v

Liquid Trap Start Mass g 1224.0

Laboratory Result for Back Impinger

Volume in Back Impinger ml 138.5

minsVolume Sampled (STP, Dry)

APPENDIX 2

HYDROGEN CHLORIDE: SAMPLING DETAILS


Laboratory Result for Front Impingers µg/ml 0.29

m³ 0.0929

MFC / MV

Silica Trap End Mass g 1540.5

mg/m³ 1.88

Duration 30

Mass in Front Impingers µg 89.0

Volume in Front Impingers ml 306.8

- 14:00 - 14:30

Volume Sampled (STP, Wet) m³ 0.1076

- 19/10/2016

µg/ml 0.05

Where: MFC stands for Mass Flow Controller, MV stands for Mass View Flowmeter

Blank Runs

<-<<

Volume in Impingers mlµg/ml

299.8Laboratory Result for Impingers

Total Mass Collected µg 15.0

0.05

Blank Dates - 19/10/2016

Parameter Units Blank 1

13.67

Calculated Concentration mg/m³

Calculated Water Vapour % v/v

Average Volume Sampled (REF) m³ 0.0509

0.29





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EPA Export 16-01-2017:14:57:29

Sample Runs

¹ The concentration in the last absorber was less than 5 times the analytical detection limit. 1 7 11 19

Leak Test Results

Pre-Sampling Leak Rate l/min 0.032.99

Units Run 1

Post-Sampling Leak Rate l/min 0.04

MU (Concurrent Water Vapour) Units Run 1

%

Mean Sampling Rate l/min

Units Run 1

APPENDIX 2

HYDROGEN CHLORIDE: QUALITY ASSURANCE

Allowable Absorption Efficiency

Are Water Droplets Present - No

Absorption Efficiency % 100.0N/A ¹

Silica Gel (Concurrent Water Vapour)


Water Droplets

Units

Units Run 1

MU Acceptable % Yes

%

Run 1

N/A ¹

Allowable MUMeasurement Uncertainty (MU) % 4.4

Less than 50% Faded

Allowable Leak Rate l/min 0.06

Absorption Efficiency Units Run 1

Absorption Efficiency Acceptable -

Yes

% 20

Test Conditions

Blank Runs

Method Deviations

1

- - - - -

- - - - -

- - - - -

Expected Sampling Rate

-

Pre-Sampling Leak Rate

Blank 1

Units Run 1

mg/m³ 5.0

Yes

Leak Test Results

Nature of Deviation

Yes

l/min 0.06Allowable Leak Rate

Units Blank 1

Validity of Blank vs ELV Units

Post-Sampling Leak Rate

Ambient Temperature Recorded?

Allowable Blank

l/min 0.03

Test Conditions

l/min 3.00

Blank Acceptable -


Run Number

l/min 0.04

(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)






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%

Value Standard uncertainty

uVm m³

-

≤2%% 1.34

Requirement of StandardRun 1

Run 1

Lr mg/m³

2.00

Units Run 1

0.0471

0.0019

Symbol

HYDROGEN CHLORIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

uL % -

Vm

mg/m³

Uncertainty in Measurement Units Sensitivity Coefficient

Measured Quantities

%

Lr 2.50

m³

Uncertainty in Result

L

L 1.34

Measured Quantities Symbol Run 1

APPENDIX 2

uLr

Units

0.047

Vm

Measured Quantities

1.00

2.50

0.015mg/m³ 1.00

Run 1

0.0929

0.0377mg/m³

Symbol

Units Run 1

mg/m³ 0.0145

20.28

Units

0.0929

≤2%%

Measured QuantitiesUncertainty as a Percentage

No Requirement

O₂ Correction FactorStack Gas O₂ ContentMU for O₂ Correction

Combined uncertainty



% v/v

Run 1

% 8.2

UnitsParameter

8.2

0.06

%

-

Overall MU For O₂ Measurement 5.07- 0.09

mg/m³

Run 1

6.5

%

mg/m³ 0.150.15

mg/m³0.12

% 8.2

Oxygen Correction Part of MU BudgetMeasured Quantities Units

%

11.131.82

mg/m³

0.15mg/m³





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Sample Runs

- -

- -

- -


Span Gas Type

Heated Head Filter Used

Value

Parameter Units

Probe Material Stainless SteelFiltration Type / Size 0.1µm Glass Fibre

Propane in 7% O₂ in N₂ (5 Grade)

APPENDIX 2

Mass Emission

Concentration

g/hr

Parameter

Yes

1.1

CAT-TP-20

180°C

Span Gas Expiry Date

Heated Line Temperature

CYL 1.0137n in N₂ | CYL 1.0188a in AIR

1.0

TOTAL VOCs (as CARBON): RESULTS SUMMARY

Standard

23/12/2019 | 24/08/2020

Uncertainty

Flare Stack

mg/m³ 1.1

1.0

±g/hr

Uncertainty ±mg/m³

Mean

Span Gas Reference Number


EN 12619:2013Technical Procedure

Run 1

This is the blended concentration of both propane cylinders





Span Gas Set Point (ppm) 84.97

A1

2 | 2

86.91 | 81.1Span Gas Start Pressure (bar) 130 | 90Gas Cylinder Concentration (ppm)


Sample Point I.D.'s

Span Gas Uncertainty (%)

23/12/2019 | 24/08/2020

Number of Sampling Lines UsedNumber of Sampling Points Used 1 / 1

7% O₂ in N₂ (5 Grade)

1 / 1

Zero Gas Type





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Graphical Trend of Data

APPENDIX 2

TOTAL VOCs (as CARBON): DATA TREND

COVER ME WITH CHART/S

0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

9.0

10.0

13:0

2

13:0

4

13:0

6

13:0

8

13:1

0

13:1

2

13:1

4

13:1

6

13:1

8

13:2

0

13:2

2

13:2

4

13:2

6

13:2

8

13:3

0

13:3

2

13:3

4

13:3

6

13:3

8

13:4

0

13:4

2

13:4

4

13:4

6

13:4

8

13:5

0

13:5

2

13:5

4

13:5

6

13:5

8

14:0

0

14:0

2

Conc

entr

atio

n (m

g/m

³)

Total VOCs At Reference Conditions

- Run 1





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Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

-0.20ppm

APPENDIX 2

19/10/2016

- Yes

-

Zero Down Sampling Line (Pre)

Span Down Sampling Line (Post)

Units

ppm

Sampling Times -

ppm

84.10

CAL

1

14:02 - 15:02

Instrument Range ppm 100

0.00

ppm -0.60

Span Down Sampling Line (Pre)

Units

-0.20

Zero Drift AcceptableAllowable Zero Drift ± ppm

Run 1

ppm

4.25

Span Drift

Zero Down Sampling Line (Post) ppm

°C

Test Conditions

Run Ambient Temperature Range 12.5 - 12

ppm 83.50

-

Units

Span Drift AcceptableAllowable Span Drift ± ppm

CAL

1

4.25Yes

Run 1

Run 1

TOTAL VOCs (as CARBON): SAMPLING DETAILS & QUALITY ASSURANCE

Span Gas Value

Zero Drift

85.0

Sampling Dates

Units Run 1

Parameter

Method Deviations

1

- - -

- - -

- - -

- - -

- - -

Nature of Deviation

(x = deviation applies to the associated run)

°C

Run Number


Run Ambient Temperature Range 12.5 - 12





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Combined interference

Lower of [A] or [B]

RUN 1 UnitsStandard deviation of repeatability at zero

2.00

15.0 mg/m³Cal gas conc. 136.5 mg/m³

% of value/kPa

Performance characteristics

% of valueZero drift -0.24

60

use rep at span

Lack of fit 0.01

0.45

Performance characteristic

0.00mg/m³

mg/m³ (REF)15.010.0

RUN 1 UnitsResponse time 45

mg/m³

ppm to mg/m³MCERTS Range [B] 15.0

% range0.50 % full scale/10V

Losses in the line (leak) 1.06 % of valueUncertainty of calibration gas 2.83

Measured concentrationTGN M2 Allowable MULimit value

% full scale

Conversion 1.61

Dependence on voltage

Standard deviation of repeatability at span level

% full scaleDeviation from linearity 0.08

%0.60 mg/m³ (STP, dry)

% of value

mg/m³Cal gas conc. 85.0

TOTAL VOCs (as CARBON): MEASUREMENT UNCERTAINTY CALCULATIONS

1.40

mg/m³

Repeatability at span level 0.00

-

ppm

Performance characteristics RUN 1 Units

Ambient temperature dependence

Range Used 100.0160.6

Repeatability at zero

APPENDIX 2

ppm

% full scaleSpan drift -0.71

% of full scale

Range Used [A]

mg/m³

secondsNumber of readings in measurement

Atmospheric pressure dependence 0.30% full scale/10K

% full scaleVolume or pressure flow dependence 1.60

k =

mg/m³

% at ELVResult of Compliance with Uncertainty Requirement in M2 COMPLIANT

Expanded uncertainty (with O₂) - at 95% Confidence 11.28 % at ELVOverall Allowable uncertainty (with O ₂) - at 95% Confidence 15.8

mg/m³

mg/m³Losses in the line (leak) 0.00

mg/m³

Expanded uncertainty (with O₂) - at 95% Confidence

Result 0.60 mg/m³Combined uncertainty 0.29

RUN 1

0.20

Units

Dependence on voltage 0.06

-0.19

Measurement uncertainty

mg/m³Uncertainty of calibration gas 0.01

Atmospheric pressure dependence 0.01 mg/m³

Lack of fit 0.01

Volume or pressure flow dependence 0.00

mg/m³Drift

mg/m³

Requirement for SRM is that Uncertainty should be <15% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 15% + the uncertainty associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.

-

95.33

-

Result of Compliance with Uncertainty Requirement in M2 N/A

Units% of Value

RUN 1

mg/m³ (REF)

RUN 1 UnitsExpanded uncertainty (no O₂) - at 95% Confidence 95.20 % of Value

Uncertainty corrected to std conds. (O ₂)

Expanded uncertainty (no O₂) - at 95% Confidence 5.67 % at ELVOverall Allowable uncertainty (no O ₂) - at 95% Confidence 15.0

mg/m³Combined interference (from MCERTS Certificate) 0.04

mg/m³

% at ELV


Expanded uncertainty 1.96 0.57 mg/m³1.01





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Sample Runs

- -

- -

- -


OXIDES OF NITROGEN (as NO₂): RESULTS SUMMARY

Value

Span Gas Type Nitrogen Monoxide

0.1µm Glass Fibre

Uncertainty

Heated Head Filter UsedFiltration Type / Size

CAT-TP-21

APPENDIX 2

Run 1

EN 14792

g/hr

79.0

Uncertainty ±mg/m³


Yes

Flare Stack

Parameter Units Mean

79.0

Probe Material Stainless Steel

Mass Emission

5.1

Concentration mg/m³

180°C

Parameter

±g/hr

Span Gas Reference Number CYL 4.0154

5.1

StandardTechnical Procedure

Heated Line TemperatureDate & Result of Last Converter Check 15/04/2016 - 95%

NOTE: Dilution performed to achieve correct span value





Span Gas Uncertainty (%)

Sample Point I.D.'s

418.45

Number of Sampling Lines Used1 / 1

Span Gas Start Pressure (bar) 40Gas Cylinder Concentration (ppm)

Zero Gas Type Nitrogen (5 Grade)2

A1

Span Gas Reference Number CYL 4.0154Span Gas Expiry Date

1 / 1Number of Sampling Points Used

15/07/2019





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APPENDIX 2

OXIDES OF NITROGEN (as NO₂): DATA TREND

0.0

20.0

40.0

60.0

80.0

100.0

120.0

140.0

14:0

2

14:0

4

14:0

6

14:0

8

14:1

0

14:1

2

14:1

4

14:1

6

14:1

8

14:2

0

14:2

2

14:2

4

14:2

6

14:2

8

14:3

0

14:3

2

14:3

4

14:3

6

14:3

8

14:4

0

14:4

2

14:4

4

14:4

6

14:4

8

14:5

0

14:5

2

14:5

4

14:5

6

14:5

8

15:0

0

15:0

2

Conc

entr

atio

n (m

g/m

³)

Oxides of Nitrogen (as NO₂) At Reference Conditions

- Run 1





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Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

Instrument Range

Units

Span Down Sampling Line (Post) ppm 76.20ppm 2.10

Span Gas Value ppm

Span Down Sampling Line (Pre) ppm 74.10

Run 1

Allowable Zero Drift

ppm

Average Temperature °C

CAL

1

Sampling Times - 14:02 - 15:02


APPENDIX 2

OXIDES OF NITROGEN (as NO₂): SAMPLING DETAILS & QUALITY ASSURANCE

Parameter

Sampling Dates

Temperature Acceptable

ppm 0.20

250

Allowable Temperature

0.00

Allowable Span Drift

- Yes

-

-

4.0

± ppm 3.65

< °C

Zero Drift

Span Drift Acceptable - Yes

19/10/2016

Units

Span Drift

73.1

CAL

1

Run 1

2.1

Units

3.65

Yes

Zero Down Sampling Line (Post) ppm 0.20

Zero Drift Acceptable

ppm

Conditioning Unit Temperature Units

Run 1

Run 1

± ppm

Method Deviations

1

x

- - -

- - -

- - -

Units Run 1

°C



12.5 - 12Run Ambient Temperature Range

Test Conditions

Nature of Deviation


Run Number





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0.60

% of value

Performance characteristics RUN 1

Range Used

Lower of [A] or [B]

Converter efficiency

Number of readings in measurement 60 -Repeatability at zero 0.40 % full scale

% of valueRepeatability at span level 0.40

Performance characteristic RUN 1 Units

0.40 % full scale/10V95.0 %

% range

% of value/kPa

Cal gas conc. 73.1 ppmConversion 2.05 ppm to mg/m³

UnitsResponse time 60

mg/m³ (REF)10.0

150.0

mg/m³

OXIDES OF NITROGEN (as NO₂): MEASUREMENT UNCERTAINTY CALCULATIONS

mg/m³ (STP, dry)10 %

125.0

ppmRange Used [A] 513.1


mg/m³

Losses in the line (leak)

% full scale

Atmospheric pressure dependence

%44.21

250.0

0.30

Uncertainty of calibration gas 2.00

Ambient temperature dependence 0.18

0.28

Span drift 0.00 % full scaleVolume or pressure flow dependence 0.40

% of value% of value

0.00

mg/m³

% of full scale

seconds

MCERTS Range [B] 125.0 mg/m³

% full scale/10K

% full scaleDeviation from linearityZero drift 0.27

Cal gas conc. 150.0

Performance characteristics RUN 1

Ration NO / NO₂Measured concentrationTGN M2 Allowable MULimit value

Combined interference

Uncertainty of calibration gas blending 1.40

APPENDIX 2

Units

k =

Expanded uncertainty (no O₂) - at 95% Confidence 4.19

% at ELVResult of Compliance with Uncertainty Requirement in M2 N/A -

RUN 1

mg/m³ (REF)

mg/m³0.13

mg/m³

Uncertainty corrected to std conds. (O ₂) 3.31

mg/m³

RUN 1 UnitsMeasurement uncertainty Result 44.21

mg/m³

Combined interference (from MCERTS Certificate) 0.43

Performance characteristic RUN 1 UnitsStandard deviation of repeatability at zero use rep at span

mg/m³

% of ValueExpanded uncertainty (with O₂) - at 95% Confidence

mg/m³Standard deviation of repeatability at span level

0.20 mg/m³Drift 0.23

-


Result of Compliance with Uncertainty Requirement in M2

mg/m³

COMPLIANT

% of ValueExpanded uncertainty (no O₂) - at 95% Confidence 1.23 % at ELVOverall Allowable uncertainty (no O ₂) - at 95% Confidence 10.0

% at ELV

UnitsExpanded uncertainty (with O₂) - at 95% Confidence 6.51

0.51

Overall Allowable uncertainty (with O ₂) - at 95% Confidence 11.2 % at ELV

0.05

RUN 1

1.85

Uncertainty of calibration gas

Units

mg/m³

Volume or pressure flow dependence 0.00

mg/m³Combined uncertainty 0.94

mg/m³Lack of fit


mg/m³Converter efficiencyLosses in the line (leak) 0.00

0.05mg/m³


0.03 mg/m³

Expanded uncertainty 1.96

Uncertainty of calibration gas blending 0.36

mg/m³Atmospheric pressure dependence 0.11 mg/m³

5.45





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Sample Runs

- -

- -

- -


YesHeated Line Temperature 180°C

2.1

Span Gas Type Carbon Monoxide

Heated Head Filter Used

±mg/m³ 2.1

1.5

Parameter

Uncertainty

Technical Procedure CAT-TP-21Standard EN 15058

Span Gas Reference Number CYL 2.0093

Run 1

0.1µm Glass Fibre


APPENDIX 2

Flare Stack

Parameter Units


Uncertainty

Concentration

Value

mg/m³ 1.5

Mean

±g/hr

19/04/2019

Mass Emission

Probe Material Stainless SteelFiltration Type / Size

CARBON MONOXIDE: RESULTS SUMMARY

g/hr






A1

Zero Gas TypeSpan Gas Uncertainty (%) 2

1 / 1

Nitrogen (5 Grade)


Number of Sampling Points Used

Gas Cylinder Concentration (ppm) 405.62

Number of Sampling Lines Used 1 / 1

Sample Point I.D.'s

19/04/2019Span Gas Start Pressure (bar) 50





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APPENDIX 2

CARBON MONOXIDE: DATA TREND

0.0

5.0

10.0

15.0

20.0

25.0

30.0

35.0

40.0

45.0

50.0

14:0

2

14:0

4

14:0

6

14:0

8

14:1

0

14:1

2

14:1

4

14:1

6

14:1

8

14:2

0

14:2

2

14:2

4

14:2

6

14:2

8

14:3

0

14:3

2

14:3

4

14:3

6

14:3

8

14:4

0

14:4

2

14:4

4

14:4

6

14:4

8

14:5

0

14:5

2

14:5

4

14:5

6

14:5

8

15:0

0

15:0

2

Conc

entr

atio

n (m

g/m

³)

Carbon Monoxide At Reference Conditions

- Run 1





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Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0

Zero Drift Acceptable -

ppm

CAL

1

Units Run 1


ppmSpan Gas Value

40.50

Span Drift

Allowable Span Drift ± ppm

Span Down Sampling Line (Post)

1.00

CARBON MONOXIDE: SAMPLING DETAILS & QUALITY ASSURANCE

Parameter

ppm 1.00

Yes

Sampling Times

ppm

Run 1

Run 1

Average TemperatureAllowable Temperature < °C 4.0

ppm 0.20

Sampling Dates - 19/10/2016Instrument Range ppm 200

°C 2.1

ppm0.80

-

Yes

Units

40.3

Span Down Sampling Line (Pre)

Units

2.01

APPENDIX 2

Units

CAL

1


Zero Drift

Allowable Zero Drift ± ppm

-

14:02 - 15:02

Run 1

2.01

Zero Down Sampling Line (Post)

Conditioning Unit Temperature

ppm 39.50

Method Deviations

1

x

- - -

- - -

- - -



Run Ambient Temperature Range

Units Run 1

Run Number

Test Conditions

Nature of Deviation

YesSpan Drift Acceptable -

°C 12.5 - 12





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%0.83 mg/m³ (STP, dry)Measured concentration

Performance characteristic RUN 1 UnitsStandard deviation of repeatability at zero use rep at span mg/m³Standard deviation of repeatability at span level 0.05 mg/m³

Dependence on voltage 0.40 % full scale/10VLosses in the line (leak) 1.99 % of valueUncertainty of calibration gas blending 1.40 % of valueUncertainty of calibration gas 2.00 % of value

% of full scaleAtmospheric pressure dependence 0.30 % of value/kPaAmbient temperature dependence 0.05 % full scale/10KCombined interference 0.73 % range

% full scaleDeviation from linearity 0.37 % of value

Number of readings in measurement 60

APPENDIX 2

CARBON MONOXIDE: MEASUREMENT UNCERTAINTY CALCULATIONS

mg/m³Cal gas conc. 50.3 mg/m³

% full scale

UnitsResponse time 60

0.40

Zero drift 0.00

0.40

% full scaleRepeatability at span level

50.0 mg/m³ (REF)6.0

Conversion 1.25 ppm to mg/m³

RUN 1

-Repeatability at zero

Performance characteristics

Span drift 0.00 % full scaleVolume or pressure flow dependence

Range Used 200.0 ppmRange Used [A] 249.8 mg/m³Cal gas conc. 40.3 ppm

TGN M2 Allowable MULimit valuePerformance characteristics RUN 1 Units

MCERTS Range [B] 95.0

seconds

mg/m³Lower of [A] or [B] 95.0

0.40

k =

RUN 1 UnitsExpanded uncertainty (no O₂) - at 95% Confidence 144.25

Expanded uncertainty (with O₂) - at 95% Confidence 6.55 % at ELVOverall Allowable uncertainty (with O ₂) - at 95% Confidence 7.8 % at ELVResult of Compliance with Uncertainty Requirement in M2 COMPLIANT -


1.19 mg/m³Uncertainty corrected to std conds. (O ₂) 2.13 mg/m³ (REF)

RUN 1 UnitsExpanded uncertainty (with O₂) - at 95% Confidence 144.34 % of Value

Expanded uncertainty 1.96

Uncertainty of calibration gas 0.01 mg/m³

RUN 1 UnitsMeasurement uncertainty Result 0.83 mg/m³Combined uncertainty 0.61 mg/m³

% of ValueExpanded uncertainty (no O₂) - at 95% Confidence 2.38 % at ELVOverall Allowable uncertainty (no O ₂) - at 95% Confidence 6.0 % at ELVResult of Compliance with Uncertainty Requirement in M2 N/A -

Combined interference (from MCERTS Certificate) 0.40 mg/m³Dependence on voltage 0.05 mg/m³Losses in the line (leak) 0.01 mg/m³Uncertainty of calibration gas blending 0.01 mg/m³

Drift 0.00 mg/m³Volume or pressure flow dependence 0.00 mg/m³Atmospheric pressure dependence 0.08 mg/m³Ambient temperature dependence 0.01 mg/m³

Standard deviation of repeatability at span level 0.05 mg/m³Lack of fit 0.20 mg/m³





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Sample Runs

- -

- -

- -



Span Gas Type Synthetic Air (5 Grade)Span Gas Reference Number

Units Run 1

180°C

Value

Standard

Parameter

Span Gas Expiry Date 10/01/2021Span Gas Start Pressure (bar) 130Gas Cylinder Concentration (% v/v) 21.13

Mean

Parameter

EN 14789Technical Procedure CAT-TP-21

Probe Material Stainless SteelFiltration Type / Size

Span Gas Uncertainty (%) 2

Uncertainty ±% v/v

CYL 11.0241

0.1µm Glass FibreHeated Head Filter Used YesHeated Line Temperature

0.54 0.54


Concentration % v/v 10.92 10.92

OXYGEN: RESULTS SUMMARY

APPENDIX 2



Sample Point I.D.'s A1

Nitrogen (5 Grade)

Number of Sampling Points Used 1 / 1Number of Sampling Lines Used 1 / 1

Span Gas Uncertainty (%) 2Zero Gas Type





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OXYGEN: DATA TREND

APPENDIX 2


0.0

5.0

10.0

15.0

20.0

14:0

2

14:0

4

14:0

6

14:0

8

14:1

0

14:1

2

14:1

4

14:1

6

14:1

8

14:2

0

14:2

2

14:2

4

14:2

6

14:2

8

14:3

0

14:3

2

14:3

4

14:3

6

14:3

8

14:4

0

14:4

2

14:4

4

14:4

6

14:4

8

14:5

0

14:5

2

14:5

4

14:5

6

14:5

8

15:0

0

15:0

2

Conc

entr

atio

n (%

v/v

)

Oxygen Oxygen

- Run 1





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Sampling Details

Quality Assurance

Zero Drift 0 0 0

Span Drift 0 0 0


- Yes4.0

0.10

14:02 - 15:02


Sampling Times

Average Temperature

-

Conditioning Unit Temperature Units Run 1

Allowable Span Drift

Span Gas Value

Run 1

Allowable Temperature < °C

0.02Zero Down Sampling Line (Post) % v/v 0.12

CAL

1 Zero Down Sampling Line (Pre) % v/v

% v/v 25

Zero Drift Acceptable

Instrument Range

-

Span Drift Units

Span Down Sampling Line (Post) % v/v

APPENDIX 2

OXYGEN: SAMPLING DETAILS & QUALITY ASSURANCE


± % v/v 0.35

°C 2.1

Yes

Units Run 1

% v/v7.107.05

% v/v 7.00

% v/v 0.05

Allowable Zero Drift ± % v/v 0.35

Zero Drift

CAL

1 Span Down Sampling Line (Pre)

Sampling Dates - 19/10/2016

% v/v

Method Deviations

1

x

- - -

- - -

- - -



Run Ambient Temperature Range °C 12.5 - 12

Nature of Deviation Run Number







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Volume or pressure flow dependence 0.00 %volAtmospheric pressure dependence

Combined interference 0.56

%volAmbient temperature dependence -0.01 %vol

Standard deviation of repeatability at span level 0.01 %volLack of fit 0.01 %volDrift 0.22

Standard deviation of repeatability at zero use rep at span %vol

-0.07 % full scale/10KAtmospheric pressure dependence 0.30 % of value/kPaAmbient temperature dependence

Volume or pressure flow dependence 0.20 % of full scale

N/A %vol6.0 %

0.02

Units

Repeatability at zero 0.04

% rangeDependence on voltage 0.02 % full scale/10VLosses in the line (leak) 0.00 % of valueUncertainty of calibration gas

10.92 %volRange Used 25.0 %volCal gas conc. 21.1 %vol

Performance characteristics RUN 1Response time 60 seconds

2.00

%vol

Span drift 0.71 % full scale

Combined interference (from MCERTS Certificate) 0.08 %vol

% of value

Performance characteristic RUN 1 Units

0.08 % of valueZero drift 1.42

Number of readings in measurement 60 -% full scale

Repeatability at span level 0.04 % full scaleDeviation from linearity

% full scale

Performance characteristics RUN 1 Units

Measured concentrationTGN M2 Allowable MULimit value

APPENDIX 2

OXYGEN: MEASUREMENT UNCERTAINTY CALCULATIONS

k =

Result of Compliance with Uncertainty Requirement in M2 COMPLIANT -

Expanded uncertainty 1.96 0.54 %vol

RUN 1 Units

Uncertainty of calibration gas 0.13 %vol

RUN 1 UnitsMeasurement uncertainty Result 10.92 %vol

Requirement for SRM is that Uncertainty should be 0.5%vol absolute or 6% relative whichever is the lower, on a dry gas basis. Ref EA TGN M2.

Combined interference (from MCERTS Certificate) 0.08 %volDependence on voltage 0.00 %volLosses in the line (leak) 0.00 %vol

Combined uncertainty 0.28 %vol

Expanded uncertainty (no O₂) - at 95% Confidence 4.98 % of Value





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installation name & address for inspection purposes only. · flare stack job number: cek-2280,...

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