impairment assessment and conceptual model of legacy pesticides: ddt, chlordane, and dieldrin rmp...

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Impairment Assessment and Conceptual Model of Legacy Pesticides: DDT, Chlordane, and Dieldrin RMP Annual Meeting May 4, 2004 Jon Leatherbarrow, Chris Werme, Mike Connor, Jay Davis San Francisco Estuary Institute

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Page 1: Impairment Assessment and Conceptual Model of Legacy Pesticides: DDT, Chlordane, and Dieldrin RMP Annual Meeting May 4, 2004 Jon Leatherbarrow, Chris Werme,

Impairment Assessment and Conceptual Model of Legacy Pesticides:DDT, Chlordane, and Dieldrin

RMP Annual MeetingMay 4, 2004

Jon Leatherbarrow, Chris Werme, Mike Connor, Jay DavisSan Francisco Estuary Institute

Page 2: Impairment Assessment and Conceptual Model of Legacy Pesticides: DDT, Chlordane, and Dieldrin RMP Annual Meeting May 4, 2004 Jon Leatherbarrow, Chris Werme,

Regulatory Status

Restricted/Banned

• DDT in the 1960s/70s• Chlordane and Dieldrin

in the 1970s/80s

SanPabloBay

SuisunBay

CentralBay

SouthBay

LowerSouthBay

Delta

CWA 303(d) List• 1994 Fish Advisory

(OEHHA)• All segments of SF Bay

listed as impaired

Carquinez Strait

Page 3: Impairment Assessment and Conceptual Model of Legacy Pesticides: DDT, Chlordane, and Dieldrin RMP Annual Meeting May 4, 2004 Jon Leatherbarrow, Chris Werme,

Impairment Indicator – Fish2000 RMP Fish Monitoring Results

DDT

Pe

stic

ide

s in

Fis

h (

ng

/g)

0

20

40

60

80

100

120

Chlordane0

5

10

15

20

25

30

Dieldrin0

1

2

3

4

5

Fish Screening Value

POSSIBLEIMPAIRMENT

POSSIBLEIMPAIRMENT

IMPAIRMENTUNLIKELY

Page 4: Impairment Assessment and Conceptual Model of Legacy Pesticides: DDT, Chlordane, and Dieldrin RMP Annual Meeting May 4, 2004 Jon Leatherbarrow, Chris Werme,

Impairment Indicator – Water2002 RMP Water Monitoring Results

No 2002 samples exceeded CTR water quality criteria for:

p,p’-DDEp,p’-DDDp,p’-DDTTotal ChlordaneDieldrin

Page 5: Impairment Assessment and Conceptual Model of Legacy Pesticides: DDT, Chlordane, and Dieldrin RMP Annual Meeting May 4, 2004 Jon Leatherbarrow, Chris Werme,

0 10 20 30 40

Mas

s in

Bay

(kg

)

0

100

200

300

400

Years

60 kg

40 kg

20 kg

0 kg

DDT Forecast

1980 1990 2000

p,p'

-DD

E (

µg/

kg)

0

20

40

60

80

100

…and Historic Trends in Bivalves

Page 6: Impairment Assessment and Conceptual Model of Legacy Pesticides: DDT, Chlordane, and Dieldrin RMP Annual Meeting May 4, 2004 Jon Leatherbarrow, Chris Werme,
Page 7: Impairment Assessment and Conceptual Model of Legacy Pesticides: DDT, Chlordane, and Dieldrin RMP Annual Meeting May 4, 2004 Jon Leatherbarrow, Chris Werme,
Page 8: Impairment Assessment and Conceptual Model of Legacy Pesticides: DDT, Chlordane, and Dieldrin RMP Annual Meeting May 4, 2004 Jon Leatherbarrow, Chris Werme,
Page 9: Impairment Assessment and Conceptual Model of Legacy Pesticides: DDT, Chlordane, and Dieldrin RMP Annual Meeting May 4, 2004 Jon Leatherbarrow, Chris Werme,
Page 10: Impairment Assessment and Conceptual Model of Legacy Pesticides: DDT, Chlordane, and Dieldrin RMP Annual Meeting May 4, 2004 Jon Leatherbarrow, Chris Werme,
Page 11: Impairment Assessment and Conceptual Model of Legacy Pesticides: DDT, Chlordane, and Dieldrin RMP Annual Meeting May 4, 2004 Jon Leatherbarrow, Chris Werme,
Page 12: Impairment Assessment and Conceptual Model of Legacy Pesticides: DDT, Chlordane, and Dieldrin RMP Annual Meeting May 4, 2004 Jon Leatherbarrow, Chris Werme,

Data Gaps and Potential Next Steps

1. Current trends in contamination? Sediment cores and continued fish monitoring

3. Pesticide loading & fate from tributaries? Central Valley; storms with Delta Outflow > 150,000 cfs Local Watersheds; clean-up, loading & BMP studies

4. Loading & fate of remobilized sediment in Bay? Further investigation; field studies, clean-up, bathymetry, modeling

2. Benefits from activities focused on reducing PCB contamination in the Bay?