ii ftatm i - us environmental protection agency · ii i ftatm tom sttt i subject: tos utora i...
TRANSCRIPT
IIIfTATM
TOM
sttt
I Subject:
TosUtora
Kaltfc Ira41«y, Hazardous Vattt ScctfM} ICS-SNIIII
A rcvtttf of ttio laboratory n* tfata for tho rtforonco tfto tes• oeflters of tftt Uborttory Soctfon« Sa»1os w»r«sIKBGMIIC*
00o
O
7
CK&AMIC:
I The was found:
; »s« ofC )
eautlm.not N u$*d. ^ro^ltas artcan te addrmtd to oe«
art In
IIIII
UNITED STATES ENVlftONMCNTAi. PROTECTION ACCNCY .RCOIG* w
HOUSTON K3A1*CH*«ee HOKNWOOO move
TOCA9 77674
acacusr
Mo. .L Contractor
oJO
CgjjEliTS (To.be coopleted byCompleteness
ZlnstruoentjjInterference Check
><gpatr1x $>ik*s
UJOther
Accu-Labs Research, Inc.
III
-OOP?-°003
MA- £-0015° -0006
IIIII
-£ -0007
- £ -0009_- 6-0010
-0012~l> -0013- ^-0014
Nft - -0017- ^-0018
. M A . - -0019_M.ft ' -0020
-L -0021"°022
- ^-0023
-0026
* "°023
6-0029l> -°030
*0032- ^ -0033
This number is recorded
DOCUMENT INVENTORYDocument TypeCase fi le document inventory /Transnittal Letter (F 7033 ) /Case Uarratfve
' 'Sh ipp ing air or bi l l of laden /Sample tags •/SMO forms (SAS samples)Chain-of-Custody Forms /Sample traffic reports 2,Sample log-in sheets (F 7005) /Weekly progress reoorts /Analys is data summaries { B6 -B 18 } £Work Orders '(F 7017 and F 7002) A-Flame AA data sheets (F 7008) ^Furnace AA data sheets (F 7006) 1Mercury data sheets (F 7009) /Cyanide data sheets (F 7007 ) /Percent so l ids data sheets (F 7016 )Diges t ion sheets (F 701 1 and F 700 1 )Redigest ion sheets (F 7004 }Analyst logbook pagesHGA injection logs (F 7014} >YpH extremes log (F 7010 )Internal Chain-of-Custody (F 7003 } 2Spiking data (3807200 pages 5 & 6} /AA printer readouts /OMercury strip charts YComputer pr intoutsQua l i ty ControlAA strip charts'Analytical sp ikes - HGA (F 7019) 7QC Report Number (F 7024 ) /Case Log (F 7023 } IReporting Schedule (F 7026 )on each set of documents.
7022 Rev. 0- 6 -0001
Case
OoCMr-oo
IIIIIIIIII
• ~ -A../——- - _" ._
F 7033
Transmfttal Letter
Ca;se
Date Rece ived:
Date Reported:
Approval :Cathy/QairnsProject Manager
CMr-~oo
I
21? ®2ip Code Hequirod Fw Con»ci Jnvoieinfj , ;' ' " • "J i
rpaa aittme atffstftce in/oKUATtomfitisT 24 CHAMCWIS HIU APPEAR on mvoicej
I DEUVtRYANO SPECIAL HAHDLUtfCHICK SHMCfS RfgUIRfO , -HOtOKUIHC*-tll>&*iS*f*in>[jmu
o.' f; '; .' -, |t?ale ''T T,' : .-^V.
o 3 : >%i ^Oft iHTbiBW ,5 iOAfifAa JA>p!mSJIUCJMDJHIJlCttSSMinClv.1**
Snipper's Door, *jt,r}i*«pr)EJ ti,D Regular Stop: ''.-i' QOn:CallSropt1—•u,a,;i-OFedExLoc JaP'vi*
6 D Mr/Cf'-^^AL^i ..4.01" L' no-D
. . v, . iajHfJispfciAt stfwct._;r nm MKfHni t nn wn *" « ™• o/KHOJ pnnvy !•««• Dudnrflotr tin win « <• nw>*
Month/Day/Vear I "^
Proioci Code
'bozi
''- v » . • : , > • . -„ ; - * : c;
'(M
III
Project CodeCnrtP <:,„„„„ ».,„ "onth/Day/Year *"" '°~""-^—-'-~~—'-^^
OS^63WStation No
oCMh~OO
i
\ ' . / . .-•«"
ENVIRONMENTAL PROTECTION AGENCYOffice of Enforcement
0 REGJON 6First Internationa! BIdg., 120J Elm St.
Dailgs, Texas 75270CHAIN OF CUSTODY
__Relinquished by: l$i$n»njr*&
(Date /Time
Wrkrt /tooReceived by; (Signature) Relinquished by: (Signature) Dale /Time Received by; JS/snatu/e}
"Relinquished by: (Signature) •' ,j'Jl; '*. Date /Time Received by: (Signature) Relinquished by: (Signature? Date /Time Received by: (Signature)
Relinquished by: (Signature) .\' Date /Time Received for Laboratory by: : Date /Time
ion: Original Accornpanigj Shipment; Copy lo Coordinator field Fites;$- , . : . .
Rernarks
£07 &&
, i ."•', '*. ' 'I1-'
US! EONHmiONMENTAL PROTECTION AGENCY «WI Sample Management Ofijce.PO.Bdx8jaAlexcWfrid,VA:£313^ . . . • " • " • • • ' , • ' ' ' " "'•"•, •••:'.'•'' ' " ' ;INORGANICS TRAFHC REPORT
Sample Number
0 CAfiflNnmhar; (" '& /.' Sample Site Name/Code:
ii-ri'i^'tui : < i i : i i-. • . , ! • -
, ; - ; • • • • . 1 - ; • • • : •j . * '-wf-r(^ : '- i . if" • ;
(a) SAMPLE CONCENTRATIONi_j - (Check One)' • • • ~" Low CojicejilidlJuji
————— Medium Concentration0 SAMPLE MATRIX(Check One)—— Water————— Soil/Sediment
/7> SamjpHna Oiiice: JZ^ 9 \.) S /N_>^
Sampling Personnel:(Nam^ -V' X ''1 /. f v / ") ' / -•" , 0(Phone) V£ ^>' ^ (' '.?' SSampling Date: ) •• (f/4/$(y
• • ' : ' , ' f . '{Beainl (End!
. vft^JShipping Information: •Name Oi Cairier:f.~c.
i v
nat*ShirP«H: ' /'-- /^(•'
AirVrill Nnmhorr ^'V \ ' V- <V-X-dLS-. '' '
^/. C'/^/ r>os"- , , . - . ,© Sample Description: ; : t•" tCheckOn©)
——— Suiiace Water—— ^X^Giound Water t , ,. , Leachate M* ' ' ' " ' 'Mixed Media ••_ _ _ -SoHds'M- 1 '•- ; ' ' r ivOfhor . ] ; • • • • (speciiy)MATCHES ORGANIC SAMPLE NO' - > v
(e) Mark Volume Level I • , i *On Sample BottleCheck Analysis lequired
^*fotal M6ta3s/^"v ^ -7 / j/i/£?>)^Q,anide ^^^ ^' ' ' ' ' ' i
0 Ship To: sk&V£J3SJti*3 */. /o:/- d*nt i/// : . -/ - -'..> .-, L-CiO.
&Q033Atto:?X/")u^ A'/V/TransferShip To:
©ANALYSIS LAB: - '.•^"* /7R^H fcy- ££ -X- ^
•a— «DatpRArH- &* -&'?&>
•^
©'Sample ConditionOn Receipt:
^(eg. broken, leakage, chain oi custody, eta). 0JL\\
LfiBEILECOFi*• » • J... . . - * .
• - ' • ; . • )&$: ; • #?•;, , - :*- " • » ' s J. . . . . .v-w . . . . . . , , »
• -#*'
? .•
I-
•>;•?-
1
*,v'f-if:'•* :
,v-tfi •
Sample Number
INORGANICS TRAFFIC REPORT(?) CaHft Niimfcpr; &<: ? /
Sample Site Name/Code:in-'&Xqroaiu rN- . -\ ><T-3 e*.« J- '• i"; '•»Tr;,;""'f , . , ,
j * >"t t n1' r ' *' '*' .
gj Samplina Office: ,,\C^ ' Q T7 JSampling Personnel:
. ,,, (>, , , __(Nam«) vJ_T >? fsf'V £>//£/- .•C*iPhonel ,5/2 5^ tf'tf??/
' &(f/d$J $ip{Beain) ' ' ' 'fend)
- , . . . - ./T\ . Sample Description: j;- . - .;? .^-^ ' . . (Check Onej——— Sriiace Water—— 1£ Ground Water
_ _ _ ^Solids^""UT • ' • ' - ;
(specify)MATCHES ORGANIC SAMPLE NO/ ty(<4
@ SAMPLE CONCENTRATION,/ ^Check One)
————— Low Concentration————— Medium Concentration0 SAMPLE MATRIX
(Check One)——— Water————— Soil/Sediment
(Kejjn Shipping Information:Name Oi Carrier:
/" /~ (L4
n»t*qhi PPH- C^/^\/d(f/Airbill Nnmb°T* i Z \si$ s ^'S
g) Mark Volume LeveJOn Sample BottleCheck Analysis required
JsTTbtal Metals t "r/jV < 2 * /v>/*' ? J-t-^yanide , /j ^^ {j/A0#)
,• / -^. ' . . ' . . ' ' ' ' • ' 1 ' i ' ; " ; . ' , '
(4) Ship To:/h'£vlsj£3 ^ -,//•S*S )™ ^ ^"f^TU/ !tf *
M///^V?'~ ^/i>ar" *^^-**y' ^ "^ ii
Attn: />; (/ ; /r^ -,> , " -— 'TransferShip To:
® ANALYSIS LAB:\ . •
'- /_ / . -vv< /&'/!•?
^^^ i© ' 'Sample Condition • - -On Receipt:
(eg. broken, leakage, chain of custodyj-etc.)
^
//x
LABHLECOFY
i
SJ.
:"l
80 S L00Accu-Laks Research, Inc.
SAMPLECUSTODIAN SIGNATURE:
SAMPLE LOG-IN SHEETF 7005" Rev. A
DATE:DOCUMENT CONTROL # ^ 2 -
CIRCLE THE APPROPRIATE RESPONSE:1. Custody Seals on Shipping CASE NUMBER
Conta iner s2. Chain-of-Custody3. Sample Tags
Sample Tag Numbers4. SMO Forms5. B i l l s of Lading6. Custody Sea l s on
Sample Containers
in tact/not intactfTesent? absentesen
AIRBILL NUMBERbsent tie- on/ adhes ivel isted on cha1n-of-custody
intact
£$"7 &&$*
OATE«CCEIV£0
^^-s%—— 4^ ——
TIMERECEIVED
21& .-^_
CHAIH-OF-CUSTOOYRECORDNUMBER
^-^^/^
SMO SAMPLENUMBERS
MFC 373ftFC J-)^
CORRESPONDINGSAMPLE TAG
NUMBERS£-t?vyfcP>-#4^t,-&ffiif. &.-&&&y
ASSIGNED LABNUMBERS
^-^^/-pP-/-<3
DOES INFORMATION OSCUSTODY RECORDS,
TRAFFIC REPORTS, ANDSAMPLE TAGS AGREE?
t*~ ^\^ <*
•
RLMAWS:CONDIT ION OF
SAMPLESHIPMENT, ETC .
f
- mm
IIIILABORATORY WEEKLY REPORTINORCANICS Report No.
Laboratory Name ACCU- LABS RESEARCHEPA Contract No. _Jjg_-pl-7066uuvw ^_y./ _y-1 G <& _ it
(Monday)
of Samples Received this Week: _$-(#
IIIIIIII
cCMr-oo
Narrative: When necessary, note problems In corduon of sample,sample, sample identilication, etc. (Us« additional pages, if necessary.)
IIIIIIIIIIII
U .S . £?A Contract laboratory PrograaSample Manageaenc Off iceP .O . 8ox 8ia - Alexandria, VA 2 2 3 1 3703/557-2-190 FTS: 8-557-2490
NaaeSOW Mo si"
COVER PAGEINORGANIC ANALYSES DATA PACKAGECas e No.Q . C . Report No .
Samole N'utabersUb ID No. EPA No. Lab ID No
Connaents:
o«r~CMr-oo
ICP Intereieaent and background corrections applied? YesIf yes, corrections applied before or after
___ No ___.generation of raw data.
Footnote s :NU - not required by contract at this timeForm I:Value - If the result is a value greater than or equaX to the instrument
detection liait but leas than the contract required detection limit,report the value in brackets ( i . e . , ( 10 ) ) . Indicate the analyticalaethod used uith P (for ICP/Flame AA) or F (for furnace) .
- Indicates element was analyzed foe but not detected. Report uith thedetection Unit value ( e . g . , IOU) .
- Indicates a value estimated or not repotted due to the presence ofinterference. Explanatory note included on cover page.
- Indicated value determined by Method ot Standard Addition.- Indicated spike sample recovery is not within control limits.- Indicates duplicate analysis Is not within control limits.- Indicates the correlation coefficient for method of standard addition Isleas than 0 .995
U
B - 6
I1iiiiiiiiiiii
Forn I
U .S . E-PA Contrac t Laboratory ProgramSample Management Off i c eP .O . &ojc 818 - Alexandria. VA 2 2 3 1 37 0 3 / 5 5 7 - 2 4 9 0 KTS: t t -557-Z*90
INORGANIC ANALYSIS DATA SHEETLAB iwiE ACCU-LABS RESEARCH CASE N0i
SOW KC. 784LAB SAMPLE ID. NO. &5-6?o a/ - ^ -/ QC REPORT
| £PA Sanple No. |
Sate -?/3/^6
£**iNO. fa ^L
Elements Identif ied and MeasuredConcentration: Low XMatrix: Water A Soil
^jp<**>2. Ar.tiiaony ^DUF' K3. Arsenic JO U- /"""4. Barium' <30O UP5. Bervlliua ^^P6. Caasiun £ 97. Calcium T100 P8* O.roolua f?3 P5. Cobalt ^10U P10. Cooler 5 U. P11. Iron (5/j? 3OO 12. Lead 5U^/r
Cyanide * *T^~t£- /O W—
MediuoSludge
'kg dry weight (Circle13. Maznesiua1 4* Haneanese15 . Mercury16. Nickel17. Potassiua18. Selenioa19. 'Si lver20. Sodiua21. Thalliun22. Tin23 . Vanadium24. ZincPercent Solids C)
Other
One)r^ovol P/zjo p'/e 1
JOUP
saf '5UP
_ l$l 00 P_ /ouf__ _ .V_00 UF l £ '
50UF '^'^O '? Pi ) n i l
|
Foocnotes : For reporting results to EPA, standard resulc qualifiers are usedas defined on Cover Page, Additional flags or foctnotes explainingresults are encouraged. Definit ion of such flags oust be explicitand con.UJ.ned on Cove r , .Pag e , however.
CMr-oo
Lab Manager
*• *J
111U.S * EPA Contract Laboratory Progran
( S a m p l e Management Off i c eP .O . Box 818 - Alexandria. VA 2 2 3 1 37Q3/557-2490 KTS: f c -557-2< .90
| INORGAXIC ANLAB SAME ACCU-LABS RESEARCH
• sou NO. 7^4LAB SAHPLE ID. NO. {$$ -(jOSl'J '3-
Fora I
It.i'A Saaple tio. 1| |
-..,., :.dj:-:, :l!l. ]. f ,,. ; M3,te *^ J / j? (*ALVSIS DATA SHEET
CASE NO, &<93 /
QC REPORT NO. /,£,
1" Elements Identified and Measuredm ConcentrsCion: Low Vg Matrix: Water Y. Soil
I xig/T)or Eg/leg"*w=<r1. Aluminum O^/^O P *
1 2. Antiiaony 6OU F f£ '• 3. Arsenic /OU F
<!. Bariua ^OO U_PI 5. Beryllium 5U P
6. Cadnium £> /-*
1 7. Calcium 5?/VO P—— —————————— u- —— _«£ ———————8. Chrocduo -V7 P
15. Cobalt ^OUP10. Copper r/'3T PH. Iron HI 00 P
1 12. Lead % -f^p™ Cyanide " /6^
Mediuc!Sludge other
dry ueighc (Circle One)13. Maenesiun /^V?70l P14. Manganese W9 P'P*15. Mercury /V 3 /V
17. Potassium I^OO P18. Seleniuci <fj£"19- 'Si lver 5lt P20. Sodium ^^ /-p^i /-^21. Thallium /£) tV/r*22. Tin ^o /y /^ l/? i23. Vanadium ^y 0 U f- *>? '24. Zinc 91 PPercent. Solids (*)
CM
OO
Footnotes
Comments ;
For reporting results to EPA. standard result qualifiers arc usedas defined on Cover Page. Additional flags or footnotes explainingresults are encouraged. Definit ion of such flags oust be explicitand contained on Cover Page , however „
Lab Manager 77^I^- 7
IIIIIIIIII
Fqrg UQ, C. Report No.
INITIAL AND CONTINUING CALIBRATION VERIFICATION3
LAB NAfti ACCU-LABS RESEARCH CASE NO. L>O&\SOU NO. 784
DATE * 7 / 3 / £ ( /Compound Initial Calib.Metals:1. Aluminum2. Antimony3* Arsenic4. Barius5. Bervlliue6. Caesium7. Calcium£. Chromium9. Cobalt:
10. Coooer11. Iron12. . lead13. Hacnesiu=14. Mar.esnese15. Mercury16. Nickel17. Potass ium13. Selenium
- 1 9 . Silver20. Sodium21. Thallium22. Tin23* Vanadium24. ZincOther:
Cyanide
True Value"|00lb\
3713.00
Found
9tf..,^-7 -/^?oc> _
335 ja rcH -70
UNITS M\lL ' "^ Continuing Calibration^
/<!>t)9T-^2l2»/O6>?V
5300 WOO 1 /0A<2MCr- (^ (— *•j 3 G
#00x/3/£DO3//£3oo5/0310050
$300.35 „_50
...„«?•V/,?
/oo _
^6^9-bO32J-/T90.,3? .3-yy3J<//90
3000j 533S'^oo
0?&>
*/9/3^.^5
io4
9^/^c)
7 U?QC3CLL97Q Q
/ / /o/^959^
97/od/<?V9^/0377
/oi
True Value70D/ < ? ( -„
130O4353?5300
£6>O_ . 339 . .
S'OOV3
_ . ./too .300£/d3/06&P3V
^•500«25
_ . 50 . . .
-<//<?
/Od
Found
__/^5^5
7,3^0
ZR
/O^?3Wd
< P 3 7 l <?7V > 1 .353005V93bO^^5gib
__33___MLO.3V 733V£00c?/^0Vdc36
J>IOQ_3(*<£/<?(*yob
10$
/Of)95;oo94,/o/?/?5/^><?//^95W^,/c>^9^/oV?v
9?97
/^)3
Found
9<?< ^5
-V/
3/0
-&
c?7^c)
/JO
sa
9793
'
^ethod*P
FP \i*£'f
f i PII P
P93
10$
90
toSA20JOI
•
-p/=_ f•*"-"r ,.t- — .i PPpp
_ £?PipFP
* Initial Calibration Source j&vft S * Continuing Calibration Soucca pfi *
&TIL./&,
J3II
/a-/5/ *)it**5^./5
/y/5/39
r 3^-^
oo
Control Units: Mercury and Tin 80-120; All Othcc Compounds 90*1 10Indieace Analytical Method Used: P - ICP/Flarae AA; F - Furnace
B - a
1I1LAJB NJtt£ ACCU-LASS RESEARCH
• DATE "7/3 /^1
Preparation
I Co'330'j''*-- r'" ———— ~Meta l s :
m I. Alusinua| 2. Antisany
3, Arser. ic• 4. Bariua
5, Beryllium
1 6 . Ca i —i \:c7. Calriua
9. Cobalt10. Cocrsr
I »• '«-=™ 12. Leadu 13. Ha^esiuia1 14. Mar.zar.ese
15. Mercarv
1 " " ' ''-16. Kickel— — = ———— „17, Foc^ss iua
1 18. Seleniua——— - "- -19. Silver
120. Sodiua21. Thallium22. Tin
• 23. Vanadium24. Zinc
1 Other:-
_ Cyanide
InitialCalibrationBlank Value
300 Ut
Tors l itC. Rspo r c No, (0&L.
CASE MO. 6^ /
H«rix^ttJlITS /^ /U
•"Continuing C^l ibraciot i
1
^oo a
Blank Value2 3
5li 5U 5Ui-J C^ 1 ! ^ CX^ j *^*5oou ll 2oou5U
U
-/ o
Preoaration Blank1 2
30 U5LL
. _. 60.300 U.
5U. II 56i^u II u 1 sa/oo^ /ooa II joou.6 a^ou5U.20 a5U
50 U"5U6'<3a^oaloomsm6m/DO aSu$O6usm
\sou
_.5u _ _ II - r/ j .,3oa5U
o?oUSOU
I I 5UM 30^u ^a II ^a *5o a.
5 LL0.3-tt.joa/ooU5U5U/o^a^u.
.5U. _5 a ...5U
1 /06£
£>^Uj
. 166
5CC. . : »n-.,™
1
•""'
1. . . 1 . . . 1
tSotC50.
J06t/oott^_1^L.. SLU. .
IOOLL^U.
5U. ._6"ti
/OIL
CMr-oo
I
III
Form,VI IQ . C . Repor t No .
I
III
INSTRUMENT DETECTION' LIMITS ANDLABORATORY CONTROL SAMPLE
LAB KAMS ACCU-LA8S RESEARCH CASK NO.DATE "7 l5/ £ < /
I
Coaoo^r.c
Mecals:1. Aluminum2 . ^_ -Ar.tisony3. Arsenic4. Sasiua5. Bervlliunb . Ca."*.~'-tim7 r1 - i -- » i".
Required Detec t ionLiaits (CRDL)-ue/!
200
u
LCS UNITS
Instrument Detec t ionLicits ( IDL)-UE/!ICP/AA Furnace
60 || .10
20055
1i 5001 5i 5
5000 1 1 /OO
55
/^/L) ^/kg(Circle One)
tab Contro l SacnleTrue Found
yoL_^7
..-no<?v
/^oo /^/o< P35^9
,1^no5/9VO
5/70
•• • \m^mf^
to**tnlO 2
X/).2,
inC\!
oo
8. Chrcnium 10 | 1 $9. Ccb^lt10, CoDt>er1 1 . Iran12. Lead13, Magnesium• 14. Maneanese15. Mercurv16. Kickel17 . Pociss iutn18. Selenium19. Silver20. Sod i us.21, Thallium22, Tin23. Vanadium24. 2lncOther:
Cvmlde
5025
1005
500015
0 . 240
50005
105000
10405020
10
I50 f>5_30 .
! 55O>3~30/d&
5/OO „
5
10
• - 5
555
A(o\Ziob53°)£00V3
75*00
3ooAlb3/06£0$<f
# <5OD3550
/o *?"V/J?
s o o \
<2^/a^o^^ /#90
3 p
/wo35/3^6)ZIOWZbi»65#Y703.1V9/^9*U&,
W
97/OO9?
///§>g93/^//^?/oo
^//>fyd, i/03j^>£.9??£L
-2£L
9-/1B - 13
II
I
II
LAB
DATEK-
Forta VtQ. C. Report No .
DUPLICATES6O A.CASE NO.
EPA Sample NoLab Sample ID No.
Matrix
* Out of Control1 To be added at a later date .NC - Noa calculable RPD due Co valufl(j»)
7%I -J '/
Compo*-nd-^:-v^_.5L.:™\-. .'.- •-:— *Metals:1 . Aluninua2. Ar.tisony3. Arsenic4. 3-srium5. Beryllium6. Cadmium7. Calcium8. Chrorj.um9- Ccbalc10e Cooper11. Iron12. Lead13. HagnesiiHfl14. Manganese15. Mercury16. Nickel17. Potaislura18. Selenium19. Silver20. Sodium21. Thallium22. Tin23. Vanadium24. ZincOtheif; _____
Cyanid«—— J_ —— . .... . ^ —— .r.n-iii
Control Limit *
-nr- r rrrT ——— - ————— — inr in.. 1 11.11 II
Saaule(S) |
...1jf..O. . . _ .< kO< /0OoO<5_..g_ .770.0_. _
. _^1< ao^5
.5^3.00<5, ikey^l
/c?^0< o > 2<3iO£nkQ\<5 .<5
™_1£ZOO_< ^/o<voo^ao*?5? 7.. ...O.d J._
</o
Duplicace(D)
. . _ . ./ ./ . o < ) . . . . . . . .<r^o
_ .... .< /o_. . . . .<aoo<5
___!_„_.-., . 7700__ . fal
<20< 5
. . . . . . . ..aiA&fl i^5r^o^oi/^56>^o-a<30
, CllbQ]< 5
_ .. <_5 . . . .ntood<IO
„ <^>c<5O
$31*i»
<*/£)
RPD^
«35A)Oyoc/oc.A)C-0
O/1)CAJCA>0 |
, -/ ,A;C- A)C-
c^/vcA)O
,- fr)C./ifc/fc..^_ .
•/UC«J^24,™-
/U6_ .^ —/UC-
CMr-oo
RPD [ |S - D | / ( ( S * D ) / 2 ) J x 100
B - 12
IIII
IIII
LAB f
DATE
fora VQ. C. Reporc No. _J£^jSPIK£ SAMPLE RECOVERY
Matrix
CASE NO. _EPA Saaple No.Lab Sample ID No.Units jLtq/L*
iCoapoundHecals :1. Aluminum2. Antiaony3. Arsenic4. Barium5. Beryllium6. Cadmium7. Calcium8. Chromium9. Cobalt10* CoDDfir11. Iron12. Lead13. Magnesium14. Manganese15. Mercury16. Nickel17. Potassium18. Selenium19. Silver20. Sodium21. Thallium22. Tin23* Vanadium24. ZincOther :
Cyanide j
[Contro l Licdtf %R1
75- 125"«H
w
«
' «
-
-
-
"
„
H
H
-
-*4
H
-
-
M
Spiked SampleResult (SSK)
9YkO£bK*
4bL>*l
/0900D J^ 535^0
.5^ 5 J/5$OQ
rt2 3*15^^0.0
7,3?V60
4/600/oK056OQ
V//5^70
O L/ /
cu /f\-f\ Q/\
SampleResult (SR)
™*6<hO<* IQ<aoo<5u?
9 /•<//)x/700^
.. _/V/£0g
/V^703vy?60
1^00
<5IZbOO•<fO<</o
Z/3l*?7
</o
SpikedAdded (SA)
^oo
5OJ ___ £0L «?oooL 50j __ 50. ./ '00,066
3006003S£>
. JOO 6JO
S600O "J. 0?0rf
A6>•^00
O'OOOO/^ _ |50
/doooo50<30050
t^OO -Q^/gQ |
U !
995a?o9V_9^lib10!/<?$/M/o5
L / 7 0/OS/od/ys/ao/oolb%/at>WS5^&b/'JO/OS. ., .19D
CMh-OO
i :R - USSR - SR)/SAi x too"R"-* out of conctolCoiHisents:
. B - It
• Accu-Labs Research. Inc. F 7017 Rev. 8EPA Work OrderCyanide and Percent Solids
1 location ^ ALR * ^>j3 - d&J?/-<3• f Sample Type / t Case # &#<£*•/
Preservation 5 Volume <£-t-/y#.#tf Date Received &~&^/&iAnalysisi
• J^yanideB due £/<ao/^6i• _percent Solids
i
In Progress
/i-/3-yCo CP* * -^
Completed
6 .?0 .86 A
ConnientsCO^_CJr-oo
1 Chain of CustodyCyanide Extracts >
1 Sam nip ill <1*i ! Ipd £ n — - - • - - ' • - -oaiiipic ut^ id i i i cvi uSampleNumbers, I #2-
1*^-^*?/-^
SamplePH>12?7tJ>
d/A
DistTlletrffRefrigerated"bate /TimejQtjSbi*b-i?~nfttr (*<*&$$tf/ % A-fl
Analyst;/ ^-
' • • •>••'
ColorationDate /time
i^,- -Otf-^^ f!^
Analyst
/»- '
Removed toStorage
bate /Time Analyst
'"•
111101I1111•IIII1Hi
Accu-lats Research, Inc. F 7002 Rev. AERA Metals Work Order
Date Rece ived ^"^"^^ ALR » ^$L - £*?£l/ ~ 3Location ' ^^~ ""/ ' Case » ^K?^/Sample Type xf£>^ Extracts to AA Room: Analyst 0??Preservation and Volune -/-//Tt^^ Date/Time &//&/&(<> y'-lOti^.Digestion in progress tt/itt/gfo Extracts to Storage: AnalystDate Digest ion completed (j/r?/8£> Date/Time '
Element Completed In Progress CommentsJ- iinum^ARtitnony
iXBariun~™~ist^Bepyl 1 1 urntxca^mium\xi^cal ci ym
CobaltM~i\4^t^J PQO
tx^V 0 An/ vrf*'^« .* *
ManganeseMercury
dye-i^ficjcel/J^fotassium
^f^ver^Sodium^xh^l 1 i imL^ iT * _•*
• • »•*• /
_gjjwdii»J>ginc
t*i*
lf»t'&I'td4-S$
^
(>'<2&C^^"*Y,/^/^c
tS&~f<?~&&
(j>'f<r~ >
&-£Y111il3v/^o
-
^
,, .. . i- .Redigestions
^T-C\Jr-oo
Extracts to AA Room Extracts to StorageDate Time Analyst Date Time AnalystI
II111
III
Accu-Labs Research, Inc.
Element:__Wavelength:_Matrix:Water
Flame Atomic Absorption
nmProcedure No.BG.__. _V PE~ 560 No. 82040 Analyst^
P_ I .D .L . :
F 7008 Rev.
Tfcne
Soil . Other #age 4 06
Date Prepared:STfrNPftRPS C^,-» )
___ Prepared
Calibration BlankStandard 1Standard 2Standard 3
Initiala -&/. & abs a &'OO <-~J^-0
/O ,&
Recalibration/? •&/- &j< #
/&
No. Samole NumberDilution
Al iquot^^ F ac to r Re a din g^Concentration
OCM
rn ?%> v^5 ? im PE> */3<i *m/^-D -</fcd)/>} fc 5 ?.'i/nrC d i7V
/rj /= r> W9
Initial Calib.Calib. VerificationCalib. BlankReadent BlankLCSSg-Joi-'J- 3-v-5
-5^^5 - 6c?^/ - /
-/^-^"5^
Calib. VerificationCalib. Blank63 -6O^"3 - /
- /#_-^ i
RecalibrationCalib. VerificationCalib. Blank
/.of///I
IV
X(,0/•*
X/•o/.(j
/. // • /L///{>1 /
I(|jji"
1-0,. 0/.I1.1-
X/, o/.^
XO-^r, &o.o0-7-/•f~kr* fC4 A<)>?-/.0t>yf't*0 T' '0.0J.iO't/, f
X<?. £6.O
————— .______^-/*0?6 7V&^0,2. {£<$»/a 2 <JOVs/j;* 770/ 6. 5t.C//6$so.V 770/./ no o?.<: -7^0^^ 3*jbC)/64?A
^/j? 2-^6,2.^a.3-Wf*
X/OfffosU.JL,
LCS and Calibration Verification^CKDL: o3OO f o nO
True Value:
Spike - _ ml. ofComments:
mg/L std. in final volume of _ _,Analyst Checked tQ.C. Approved:
mL = V ,< spike
1I
Accu-Lahs Research, Inc. F 7008 Rev. EFlame Atomic Absorption
3& OElement: $3 Procedure No. 3 fa ?•<%$£ V ate i^-~ •?&'#'£ Time $1 Wavelength: j~3*2>'£ nm BG
Matrix i . /f&Water */ Soif . OtherI STA
PE 560 No. 82040 Analyst: ^^i^I.Pa
NDARDS (jjjrJ
D.L. : 0,2- ( .A?'*ge ,£. of iL
.1 ' j^ ' /// '
Date Prepared: ('*&*$-'& Prepared by: ^U= <y** . Initial
Calibration Blank _£_.O( Standard 1 /. O abs - # <?/_r""
Standard 2 f •#Standard 3 /#'&
Recalibration0 , &/• &j~,<?
s<2< & • T-
I CVIDilution Concentration CM
EPA No. Samnle Number Aliauot Factor Reading ( ^/>*»1 *t&J/I1
Initial Calib.Calib. VerificationCalib. BlankReaaent BlankLCS
5?->?o/V- 3mPt) "V-59 ! - HI
?Y) /-,£> •** 1 0-^ft} FC 3
I frlrC £7Y...
^r?^D VV9,-
I•
1.—————————
-5-5.5
X/.o X/. o/•#/•f
/ /./// /
t /- /€
**?
-i>3Calib. VerificationCalib. Blank63 - o^3 - /
* /^.-/ i
RecalibrationCalib. VerificationCalib. Blank
V
1-4—/•6/'&A //
X X/-O i /. /.^ / . e/
X/,A0.00.01 ' /_ . . * * ,/ _ . .c> . <^//l i£ > . < ?^.^d?.^/ 7V.2n.&0,0<f ,<?/, 5*-
X/^^,<^
// x ' °/#<??6 I3&*-^/.^ <^GO
^a ' 3~ <<?0 c )
fff/% /^/O^c/.^
,s/
/i'Z,^<j.^ <^OD( 4, .tR)
V" <oiOO9*i%#63<i &^i t$ 1 °/dd0?*
<t~0.^^tf.a^tf.,2.
•9 V%
X/^bif!jx.^.^
B LCS and Calibration Verification; >fo/*'i ~77T^ True Value: //A ( ^^" )« CRDL: 2r> .O_ (or tU )
Spike » ^.A tnL of /OOO mg/L std
1 -Comments :. in final volume of _/0O mL = c-7. <^ mg/L spike
Analyst Checked: ^</ Date: £"£&**<r<*. . .Q.C- Approved: JCe FT Date: 7/5 /S t>
1_ Accu-Labs Research, Inc.B Flame Atomic Absorption
Element: /?<£-- Procedure No. Sa&^tftf?*
1 Wavelengr.hr ^3f. 5* nm BG f/Matrix: JWater './^ Soil • Otherl• . . ._... _.._ STA. , . , . . . . • i - . ! -. , - i " • • * i s l Jfr
Date Prepared: "3^"^
PE 560 No. 82040J *T_k*
F 7008 Rev. £
Analyst: /&2&JI.D.L . : &t&0S^ (tfj-^T,\Page <^t of ^L 7*
M^ s (. ^i, - . . „ . . • y/J>repared by
• InitialCalibration Blank ^ .00 &
( Standard 1 Q .J'vC/ abs = ff.f-Standard 2 j.eadStandard 3 £ 0"°
>¥h
*oRecalibration
y, 0 & t/#'?° <* _ . . ' _ . (\l
I ooDilution Concentration ,,.EPA No. Samole Number Aliquot Factor Reading (,?,-, -*-*) ,^/L
1————————————————— --• ——— ;y- ———fVl *^ "Ts **J *•* KF ' f ' *L-* ' ^ J O
Initial Calib.Calib. VerificationCalib. BlankReagent BlankLCS
«5£-£0/V- -3•j°=*-*-3?~; — viv"""-"! ————————— ; ——————— iFf) t*~ L> -*o T 1 - /mp£> c)^7^C P ?-}
I MrC .dJ^-V
1- ————— ....-.-^rtO i f) jt^jJQ
,
1B ,_-.•ID
*
'f)tr-'*'(a(.S-J-l~* 1" i£~ z*J v5
Calib* VerificationCalib. Blank£3 - 60^/3 - /
- //^,-/3
RecalibrationCalib. VerificationCalib. Blank
X/.O
X X 1 pi/ X Vi//• 0
f(j 4,/' ^
——— ——— 1 ——— '
rf, A /0 .0 f<3^ /> tf<^
^•^ /?d .c) <^ c>5 t/ / od a.°°~.$.0 <{**6-0 °&6 .O<J^o .c^o^1
•V/ &/. 0/ o
V .ir~
X X/. i /. /,^/ ; , £?
fl LCS and Calibration Verification: £ tffy - J. 4CRDL: 5 (a^b )
B Spike ** 0. 1 mL of y^ tnq/L Std
1 —• •. in final volume c
Analyst ChecQ .C * Approve
(),&(/ 6f). A * 7-o ,vo "f').0<jO
.._ tf .0 00.Q O V v
XJ > Z 2 t fddov
^^r JJ<P^Li/.^Ci" <^5
^o .otf/' < 59 3^> 5 1 S^£.£3 , >d^~
o-o /o^0.06 f30 %
>" / t.^(? .O <f ) S. J
/ <5J- < 5•^ Vt><?-^>
^i> ^5^
-i —————£.2 J^>
X<9J-9s,
^&.00<S~
True Value: #,23J f^**"* )
if ^
W
0 mL ss d,&*j& mg/L spike
;ked: ^^•t^) Date: t'^^'r *sd: „ JilJ- Date: lM?^._
1_ Accu-La,bs Research/ Inc
Element: /*,*?*
F 7008 Rev. EFlame Atomic Absorption
Procedure No. >.Y^f^^o Date: £ ' "J3*yC time //^^
1 Wavelength; rf*1 j'. ^ run BG I/'Matrix: _Water t/ Soil iOther
PE 560 No. 82040 Analyst: _^^c^I, D.L . : #, &'<?J~ ( iPage 4 of 4. ^
• STANDARDS (^ ~)
Date Pre1
Calibration Blank
•
Standard 1Standard 2Standard 3
aared: ^^3^C- Prepared bys x^^t/
Initial&, tfatftf'j'v^ abs » 4.063/.&&&ft- .0(/O
Recalibrationc> .<?#&a j'W/• jv^J ,&0C/ - lria CM
• Dilution Concentration CM• EPA No. Sample Number Aliauot Factor Reading ( ^JL n&J.
I• - „. - .„.„„. . .
1 - , . _™. ._„ ,_pi }- 1> *A5<5Pn PE> */5</w^ „
• /n^c 3?a
I frirC £?•*/
Initial Calib.Calib. VerificationCalib. BlankReaoent BlankLCS
•S&'JO/-^- 3
x x x/.<3J/
/
X*. ^//
- V-5
^ &<<O0 -o.oJ .0 JOO-1-0 0*-/(jO £^O^
// x ^ i./a 3^ ^^
*£~0 .06 S~ < 5~*^Q .OOl" < 5
/ a 3 v 40- d oo\"
A t> ?*2-\ 6.0 Z 1-/ 1 /i .0 ^ V
- 5S \ta3i - (ffOZl - /
- /€-,3. , . , "3$
Calib. VerificationCalib. Blank
• mrt> vy 9•
_.Hu
1•
^>3 - bOjZ - I- 1 %.*/ i
RecalibrationCalib. VerificationCalib. Blank
I
1 1 tV V
'
X XA£ * / • <?t.U \ /*O
_d_v^&o &# jo-^c' J?r) 0O<*0.& t, Yf) oW<? o-^l0 oof 1e?^^S^,tf»^ o
X£ > . £? V^
fi-o $u
// * /$y£0.CM $ $
fl Qg \1 %
A A t.*C <£»
//^^ &V
| __ /o 5^',T ^ t7-OaJ^"«^£).1?OJ'i c/ rf" c S^
/3L <7 * ^ ,
X/v, 3 < !/;<? o f
£ LCS and Calibration Verification: <&£'9'~*£ ^ ^ True Value: 0.03$ ( ,^^^-J
ffl CRDL: 5™ Spike a <^./i? mL of t
IGomments s
(O^?o );T ^? mq/L std . in final volume o£ /V^v mL *» ^,^f^ raq/I> spike
Analyst Checked \_^^/ Date: 6*33~J%Q.C . Approved: uO> rT Date: 7'^/^^
1Accu^Lafas Research/ Inc.. F 7008 Rev. E
• * Flarte Atomic Absorption
Element: C_ 6- Procedure No. OCO/°O/ Date: 6"<£7'~£& Time a?tS~S~
I Wavelenq-h: ^33. 7 nm BG PE 560 No. 82040 Analyst: \J/2Matrix: LauC£ .Water \^ soil . Other
1 .' ' - - STANDARDS (,vk« )
I .D.L . : & / f A iPage A of i. T
^ ...... __,.... ............. ................. • #Date Prepared: u?"" O( > Prepared byi ^Ji
InitialCalibration Blank <5-O
g. Standard 1 /-O abs ~ 0,639• Standard 2 ,5-C™ Standard 3 J G - Q
E| EPA Hs. Samnle Number Aliauot1 Initial Calib. X
II Caiib. Verification /.Oi Calib. BlankReaaent BlankLCS
1...,., „- -..^.. - —— j-—^- ——— =^— . —— ,-, ——— ^^ . —^ —————/^1 /^7> *^J5o i«5o ' $o W - J /
fn 1-D **3 7 1 - V 1m^t> 'fri> -5 (
1 . -5.s ... fni^c » ^^i 1 ^ - o^/ - /1 -/€
/rirC ^ 7V 1 - ,?I - ,™,,- . -__ , . _ , ™ *5^• Calib. Verification
Calib. Blank
1 ^ p r> vy9 | ^3 - 6,033 - f-/« . < _ ._ i v w
1 ._.._. . . . . . . . .
1
I Recalibration XCalib. Verification I.OCalib. Blank I-U
B LCS and Calibration Verification: 3c?M'<5-
CRDL; *5(OOO (-j^pb )
Reealibration•3-O/-O
,5.0/(?-O
Dilution Concentration ^Factor Readina ^/^>M ) *U.<Clt
X X I ' x f ^ .I.O *Sy- f^, 1/- /Ct?^- £i£kf'O Q*O ^O,l <! IvO/. / <2-Q <:o- / </6^/•/ i */-7 Is,^ 9/5?. 5/70II y.ZL }^h-3-u o J-7 i 2.^ 7// c?.c" i-^?.5
! //£> ASL I I33L /05%_ _ _ / - / _ . 7*^ 7-7 770C
A/ 7-0 (7-7 O^o 9700/./ 7-V 1 8 - 1 mo// 9-4 1 to^ ioi^ JO^QO^.. _./._0 . . _ . _ . 5: . .^ ' _J5.3 toc^
/./ 0-0 <U>//./ c5-o l"^- / £^// *?'3 /o3-3 icd%
X X X/-O 5^3 53 /oo-^ _ ___/'C? O • O *O- /True Value: O-3 ( /v)*^? )rr
H Spike M -§/() "*• of IOO$ mg/L std. in final volume of /#£> mL » /5O tng/L spike
H Comments: AnalystQ.C * Ap
Checked: <$sr Date: ©"^'..^r*.proved: «-<"o n Date: Mlt?/ok?
1Accu-Labs Research, Inc.
1 Flame Atomic Absorption
Element: ^V" Procedure No. 3£/&?'*2F
( Wavelength: Zj'?*-. 9 na BGMatrix:Water t/ Soil - Other
1 . . . . . . . . . . . . . . . . . , . „ . - . „ . . . . .-..STA
PE 560 No. 82040
F 7008 Rev. E
Analyst; /£«*^I. D.L. i 0.0&S" f \Page ^J of a. S '
NDAR0S C«* K ) .: • , - - - . - , . , .- , . .- - /f '
Date Prepared: <^ .? "V^ Prepared byt^ l-^yf Initial
Calibration Blank d , O o <~<>^ Standard 1 $ tfa & abs *• Standard 2 /, oo &• Standard 3 £.,&& <j
1 -EPA No. Samnle Number AliquotInitial Calib.
1Calib. Verification
I Calib. BlankReaoent BlankLCS
I m fb V,5<? t£&'3OJ't/- 3
RecalibrationO .0&od^J~f<S
__ __
v o d.^^^- ,~ „ ,— .. .-. - . . ^_ — „__ ^O O U
C^JDilution Concentration CMFactor Readincr (/*/fvi} u^4-»
X 1 X60 |/ i——— f——— T
( •OI- - - - - - - \ 1
/Y) PE> 4 - Y 1r/op_DVkt) -5
1 1 , . , - . , „ , . ,r£A..,. . . .-,- .- ,tofC 37-i >j$- (aO~l - t- /£
Hi! 11I
B AnrC ^"7^ -^ !1 *^^• Calib. Verification
Calib. Elank
I mFT> VV9 1 ^3-^oV3 - /[ -IP.... . . ii^-
*/^t
1 —— , —————I Recalibration
Calib. VerificationCalib. Blank
X^.^^*f
/J O tJ £s_2M °V/!.i^l_.fj (J$ Vf} 1 3 &
I/) U f * i(^)-ri '^
. . . . . . y^ ^ .^) (y^i-'1^ <^y?-d-j-fjo.^^ 7
1 (J .tf^*-^\ \* •/
X o-\
/ . 6 i /. ^•o /-&
1Lt
LCS and Calibration Verifications ^/^''"X ^~—————^~ "CRDL: _ ./O ' ... __ < pnb )
1™.^,,^,, . . . fnW-, . , r , , . , r , , , .nm . , ^\'
Spike « AO taL of ^ <y mg/L std
•1 Comments :
^/ X ' ""T^C^f i *?5I~^.o. &o r ^^
^0.&&}f' <•* 5^/-^ ^tsvS-.0.cfO$d J3o<LJ' i
t*S%yO-Ootf $tf . Oc/tf 5?/),£/*{ ^— ^/''i
/t/3 $0 «55 9yi<<£?*& #¥'
0 ,t>c; ,1 ^ ,3 .<?o?d.jtd? /(/*•' ?A
\
X0 -^^O-^d ^
X^-*^
-^d ^yf^True Value : J><3£ / ( X/-?? )
. in final volume <Analyst Che<Q .C . Approve
>£ /<^ mL s= &,,3&et mg/L spike
:ked : AL>£\£^/ Datfi: /f ~fK\f^y(^.d : Li) W- Date : ^ ^ '? lo-
IIIIIIII
Accu-Labs Research, inc.Flame Atomic Absorption
Procedure Ho.
T 7008 Rev. E
_Wave length i_^j/Q •*?_._Matrix i '.
BG l&b _ PE 560 No. 82040
Water L/' Soil . otherAnalyst:I .D.I , . :JPage 4
::. STANDARDS
Date Prepared; Prepared
Calibration BlankStandard 1Standard 2Standard 3
Initial000Cj-'oO abs » O-O/4/• <^Q<9-CO
Recalibration<O£O£3. <TO/«OO<3 -CO
Dilution ConcentrationEPA Mo. Samnle Number Alicuot Factor Reading Gw-vO f
f Initial Calib. II Calib. Verificationj Calib. BlankI Reaaent Blankt LCS
Zr?f£> V,5# I-555- ^/V- 3/Y)P£> V.5S1 i - VmF-Jb-tffcd i -5i -5^/^^C 5?^ 4,5 - 6O^ / - /
' * */ * ./nrC £'?'t/ 1 ~^
x/.O-
x 1 x ) r' x XC/
^ ———I !1 t1 !1i ii f
1I *-3^ i )1 Calib. Verificationi Calib. Blank
/r? £ D VV9«.
k 3 - O^3 - /. -..//I . .
(
RecalibrationCalib. VerificationCalib. Blank
1111w
Q>3<<>O-&Ob-OI0>Sl_(0
O-S^= (00*% C-O-CSt. ^
O.5(o /cO% *O-btf- b-o</Q,/_a . _b-/a1 . 0-OY b.O^1 0.5/ h-S/ 9" %
O-OI1 c^-eo
\J
O.5&0.3(0&*oOo-c^o
_ .0% .. -<V'' ^
O'SP- /OM7rt tO-S-^ l&a^b^O-Oi-
-5-0 / i ^ 0%<5 -^i'") trt^C) /( ^i
tiiX X
/•6 i /)."c> '
X# . £ >6c?-^^
Xo. s> /&?*%A 6.00^
-CMC\j
tCS and Calibration Verification^CRD! . :„ _ _ _ ^Q _ '_
Spike *= /'O at. of
Comments:
True value:
std spikeAnalyst checked^Q.C* Approved:^^_ Date:
IIII
I
Accu-Labs Research, Inc.
Element:
F 7008 Rev, EAtomic Absorption
Procedure Ho*Wavelength: _J^f/./ _ _nm BG i/ PE 560 No. 82040Matrix:Water \/ Soil 0^• Other
STANDARDS (»„-*&
Anal y s t : jZ^<£.<JX .D . L . : d . &&J- ( . \. -7—- ———— - - I... —./?-? -<>^VPaqe <A o£ ^. X/
'• ' //Date Prepared: /-v?^^/ Prepared by: ^-^-^J
Calibration BlankStandard **Standard 2
Initial& /?£/ <ry^ r~# <^ abs =/. & & &
Star.card 3 ( A . a & &
Recalibration0 . t/e? (?a . J~<; O
/. <? ^ c>J.&&V
OJCM
EFA ^G. Samole NumberDilution
Aliauot Factor ReadinaConcentration.
t Initial Calib.( Calib. Verificationi11Calib. BlankReacrent BlankLCS
m.rt> ^.5tf !5S* - i3o/V- dm^ £ > */59Mpj> -^feC)m^C 37 :1
_ftLrC_^^_
r.y-5-5.^
X;.0
1
X/- o
1 t' 1 f
/ 1!
1i11 i'-— - t - —i
•^5 - loOii - i 1 !. _ . . . -/£ 1
-.-?|_ -551 Calib. Verification, ^ . ...__J
yr?rE> VV9Calib. Blank63-^0^3 - /
- //I-/ i "
RecalibrationCalib. VerificationCalib. Blank
11
V
^0 . 3 * 7^ ,6> £/2-f? O0l~
' ^ X ^~^1_^^.^ . . . . . . . 3^-o o<J{ 4;<}&**>" <
ft .?> 5 / ! ? /A, ^d.dod t <^ ^J"/^ <y ft-ft.d&Va^J?d o&3o.o &^o& /3tf £63! ) .3 ^-^6-00'
iI / - 1 1 ,9 -&0-2*O.O&2-<y .y,s~>
0 Ol~h0 .00 V
//*%^v,w? <^-(/.Oof <t>,O/3toott, J^^
xi 0 . 0W j "_i(? ^(?r^£) ^c'5''/d /&
1 ' 1
X X/ • ( ^ i /- O/*& i /.^
11
III
Accu-Labs Research, Inc.
Element:_ LJ^_£-^__^_^__^^,^_Wa ve le i\g th -_^^^-^_ ^_ninMatrix: ____Water L/' Soil - other
Flame Atomic Absorptirtn
Procedure Ko.BG._ !/ PE 560 No. 82040
F 7008 Rev.
Time _/
I-D.I * .Page of i //
- STANDARDS
Date Prepared; Prepared by:
Calibration BlankStandard 1Standard 2
Initial0,0V
/, a o abs - 0.0$(cj',& v
Standard 3 | /<? , £///
Kecalibration3. O&/. 0 &
/& i CS*J ' u-/
SPA Mo. Samnle Number
' CMDilution Concentration CM
Aliauot Factor ReadingInitial Calib.Calib. VerificationCalib. Blank?.«*.=» Gent BlankLCS
rnrl> V,5^ '5^-Jo/V- J
X X 1 X /' X ^/.O / "^ 1 o . }<j 0.79 ?*$,
1 / i o.vo \ *zo .v 3, <' I ' ' / i , . t - ) *. . .. ../.. .„. / . \,.o,o2> . . _ / > . £ 3 . _„/ 7 I c). yf ///^/ /, ^ \ 3^ ^> 5. *
/Y)P.D^5^ - V /o^ 1 ^ " . fV 2^?m^^V^O -5 I /^7 1 }•', -/ ^,1- 5,5 ! /e) 1 /tf^6 //
MrC 57^ ^ 2 - 6 c > ^ / - ' / ' ^-^J -?^ o" / l^i ?^ « ?- J : *
^i /^C dlT-*/ J,2 1 / | /, tj / y^ /<]1 "^^ ) 1 ^ 1 /. J"^ /^^; /51 Calib. Verification I /-<^ 1 i).^/ /0/?61 Calib. Blank
/r? ^t) VV9 ( 63 - 6£)^3 - /I - f &.1 -/ <
RecalibrationCalib. Verification
I Calib. Blank
1 y.^ 1 o>&° ^a.0%\ ' \ 'tt.o y 6 c^y1 / ] ^^ 0 f ,} #qv J^ 1 /. 6v3 tS*i %,(Ii ii . iiiix i x x x ^/ O i /• <^ /#<?&/. ^/ \ /. CJ * oO J~O & 2 ,., _ ...
^*sLCS and Calibration Verification: . ^r "*/ ^ ^ • True Value: ^, frO _ (^^^^\ )CRDL: /00 («rth )\"\Spike •» /-^ B\L o£ /^CV mq/L std
Comments:
//* in final volume o£ /& O m[> /• c* mg/L spik
Analyst Checked: ^4-^e^. Date: ^ •*•*• ^-'r '*?..Q . C * Approved ; , ffri Datei 'j^'SJs.... .„
290
11
Accu-Labs Research, Inc. ^ 7008 Rev, EFlame Atoraic Absorption
Element: Av&L Procedure No. 3oO /coSL Date: 6'^?-&^ iHnip f:£f)1 Wavelength; 3&8P.£^ nm BG Bj) PE 560 No. 32040 Analyst: c^
Matrix: Lett 's I iD-L . : O-O$~ ( \^ }Water \S Soil . Other Paqe ^? nf * '
I -.^-:v: ;
1" " " - ' " • : „ ; • - „ ' - . STANDARDS (rvi^.)
Date Prepared: G?"ci7 "o^ Prepared by: \J#*
. , , . . i . , .
• Initial t RecalibrationCalibration Blank O-GC> I &-OO
( Standard 1 hOO abs - d.VTQ j /-CO " ""' 'Standard 2 5"-OO ( <5-GS>Standard 3 /<2-OO ! /£>-<5t^>
• IM• ' Dilution Concentration CM. EPA Mo. Samole Number Aliauot Factor Readincr (/\rt^. ) tec. If^
I Initial Calib.
1 . . .. .,,. ,.,-
Calib, VerificationCalib. BlankReaoent BlankLCS
M.^7> ^6% \58~3ot+f- 3trtp£> ^3cj-_ ^l^iJ'V^C)1
- V-5
-5:5
X ! X ! X I " X £ 3. .- — /-^ ! _.f*0._ ...! /•?*' ll."7S,' 97^, /7^(7T
_[ i /-O I 0-c?0/ i /./ 1 ^oo' A/ t /.-T3
! // i 3.9^_ . . - _ . _ J //O. 1 /6-31 /«' 1 9-^B; // i ^ 35L
• An^c 37-i l ^ 5 - 6 o ^ / - / 1 ' A/ f /-fis"
I /nrC ^'?- £/- -1 . , . . „„ , - , . _ -
- /€- ,1~33
Calib. VerificationCalib. Blank
m r D W9 1 &3 - o^f3 - /1 - //?_1 */i
.
1H RecalibrationCalib. VerificationCalib. Blank
i /•? * /.&1i /. / V.<V^* / ' V.5&>I /-o i /-7/ •! '- O <0tioI /./ &Ot
I . . ! . ' . / o-o/
49.cC' ^5*^^-^.CC* <50AfrS *?</*?•: /^^^^3 5-77*?/O(3,53-c*^- 3.O$°P.o6 /^; ,50 6- V-87 ^70
tQO<T/f?.O^'^o-C£T c^ov f A I -^t,)^ IV^-^ S^^ffi !i i Ift
X t X XAO i AO \ /.1b'•c) 1 / -O &*&&
X/• 7k 9S*^^0-OS "
• tCS and Calibration Verification: O<PY'^* ^rue Value: /-SO ( AI^CRDL: 50 00 (-aab )
W Spike = 5 mL of /£>pO mq/L std
H Comrnents:
. . . . . . . r r
. in final voluae of /pQ™, »L w ^^ mg/t* spikeAnalyst Checked: ^Jl Date: (c?~&/~C&Q.C * Apfwoved; fpkr Date: 7'^/.^fc
IIIIIIIIIIII
II
A.ceu-La..bs Research, Inc.
Element: _ _ _ ' _Wavelervgth^Matrix:Water
Flarae Atomic AbsorptionProcedure Mo.
F 7008 Rev. E
nat BG B2>
Soil . Other560 No. 92040 Analyst:^
Page __^i of ^STANDARDS (
Date Prepared; Prepared by \__\JP__ _:
Calibration BlankStandard 1Standard 2Standard 3
Initial
i3£O™™l-OOO
Recalibration
/. OOO
ES*A Ko- Samnle NumberDilution Concentration CV
Aliouot Factor ReadinaInitial Calib.Calib. VerificationCalib. Blank
I Reaaent BlankLCS
5- 1*02 / - _/-/-e
Calib. VerificationCalib. Blank
IRecalibration
o-ooo <: 5
0.3V/o-cooTo eg I J4Q;oS
Calib. VerificationCalib. Blank
/.O A^SaLCS and Calibration Verification: ^p True Value:
Spike 0 •£- mL ofCommentai
std. in final volume o£ JGQ_ _ ml, = 6/-3QO mg/L spikeAnalyst Checked: _*^JP_Q.C. Approved! __ , . .r?JL(Z
IIIII
III
Accu-Labs Research, Inc.
Element:Flame Atomic Absorption
Procedure No.ths. <?33.Q _nm
F 7008 Rev. E
tima56 ° N °4 * 2040 Analyst;Matrix:Water Soil Other
Date Prepared Prepared
Calibration BlankStandard 1Standard 2Standard 3
InitialC>'OO
(5-S~O abs « £>-Ol(/'d>Q
<2? <3Q
Recaiibrationfr,r^_£>'£>oy 'Cx3ci -OO
Dilution Concentration c\jEPA Mo. Samnie Number Aliauot Factor Reading <£if)hA.) tjA^
ffl ^3> V5#fr) P £> •**£ 9
Initial Calib.Calib. VerificationCalib. BlankReagent BlankLCS6&^3o/^* 3- Vm^j> '^d ..'.•$..
tnfc 5 a -5.54»5 - 6O -3/ - /
- /€/TlrC ^ 7 - ^ 1 -«?
m rl) W9..
"^^Calib. VerificationCalib. Blank63 - 6>o%3 - f
_ _.._-_/._&1 -/3
RecalibrationCalib. VerificationCalib. Blank
Xj .O— H-i
1
———— 1
111
V
X'-0. -l.O
X 1/
V
Xa/9O OOO'OOQ.&L&<>lO-45ao3O-</3^xdOO£OO-<^fe0^(0£>,<££>O<X)CLOO
1 O^O/
HJ -
<3,39
X<5'^3(?c^^O
1 - x -y jQ. /9 <-}£.% 7?^^^>^ <3&><^o.cO- <^^^O-<3| /o/% J10
<^O'CO^(C5'3^*003o^3. iccft*^o -dsX* ^ j t^^O-O^- #2- xr^oO.^)^ fo^0.^/6? '• /&y$* ^DO-3O 91%^-ao>/
\l/ &Zoa.??) 96?^ ..
XO-3.Q *?7^•^^-O?-
LCS and Calibration Verification;
CRDL: 5/0 _. _ __.
True Valus;
Spike - mL of mg/L std. in final volume of tnL ^= O,*jQ_0_ mg/L spike
Gorarnentss 'Analyst Checked^Q.C. Approved:
1« Accu-Labs Research, Xnc* F 7008 Rev. ED flame Atomic Absorption^^B i J
Element: /\ Procedure No. >3c& f<x*33 Date: ~°t1~&£> Time //'OD^^t.( Wavelength: "fdrtf'S" nm BG
Matrix: L&jLsWater \S Soil . Other
PE 560 No. 82040 Analyst: OV3
I .D .L . : O./ ( .. , 1-» ————— - — -= ——— — x/)/3-t*^- 'Page A o£ a. ' '
1 ..-. .. . . . _^. .-.. -. ., ^ i-. .. • . , _ STANDARDS (/y>»^t)
Date Prepared: &~&l~'Cj(& Prepared by: **rf°Initial
Calibration Blank O-O
( Standard 1 / -Cl> abs » <D-/O^Standard 2 6-OStandard 3 /O. O
Recalibration<^-OAC?<5"-o/o-a " CM
IK-.
Dilution Concentration (\jEPA Wo. Samnle Number Alicuot Factor fceadincr Oyv*?) Pfd*
I Initial Calib. I X X X f ;/X ' G
I Galib. VerificationCalib. BlankReacrent Blank
ILCS
J"Vl f^ "f\ -*J *% V 1 **\ Y -* *) f~t t f / K/ * * .' J? * * v O * *J n ***/ L/ /"^ ^.JfrtP-D^^ 1 -V• r!L^ . -5,H /M f*C. 5 / J ' ^ " / r t * 1 / - /
- /£
I /r>_rC_^?V ! . _ _ _-^ . . . . . . . . . . . ."5^
/.of1 ""•
A^ ^O 9.O £¥0 «?fAO <3-o \*-O'/ <G&-/. / C?-O U^, / </CA>
! /./ <P.<2 *<3>tf itf% ^Y^CA/ 1 A *7 /-s"// F <£>-? 1 ^OA? 9'^> 9-9// 6.3 &? //0%
! A/ A6> ^^© /g /7&C/i/ /-^ (A^'^^O /T6OA/ 7-O f7.7 77<36// .S6 165 /^>?fo fo/tO (
Calib. Verification 1 / • £ > «?. / * !p. / IC&toCalib. Blank
• ffl f1 1) ^/V9 63 " &o%3 •" /• , - / j o .-/i
1 _ _ _ . . . . . . _ . . . _ . _ .-1I uecalibration
Calib. VerificationCalib. Blank
/.^ ^.-CJ f^<3.
V
X/.oAO
/.y O-O l-^o, //,/ <7-O <A //A/) -y-7 »^5^- /03%1
iI 1f
1X X I X
/.O o?'/ f^'f *OC??*/•O <?-O J^O./ 1
1 . ,*._.«, . . .. .^ . . . . . ^2r"5// *) ^7 / *LCS and Calibration Verification: t^oV *<>«. True Value: «*'' _ t,/v?^ '
j- CRDL: 5000 ( f3p^ )
^ Spike - £ tnL of /QQ& Big/L std
1 Comments:'
/ ' /
. in final volume of /OO mL - 5^ mgA* spike
AnalystQ.C * Apt
Checked: ^JP Date: ~7~'£&^>roved: cX^ W~ Date: / /d*-i j (a
1Accu-1-ahs Research, Inc. F 7008 Rev. E
1 Flame Atomic AbsorptionAElemer.t:: /<> Procedure Ho. 3&Q'733$~' Date: 6'3&8fc Time /Q'ZS'oxn
1Wavelength: t/33&- / ™ BG "f?T>Matrix:Water \^ Soil . Other
1 - - - - "-••;"•' -*. ;:,., - "-. STA
PE 560 No. 62040 Analyst: ^/PI.Pa
HOARDS I'm* )pi-
Date Prepared: fr£LQ ~Q(? Prepared by: OP
D.L. : d'OO^ (^^._ Ige ^ oe JL
Initial UecalibrationCalibration Blank £>*££O «^> OoO
Standard 1 <3-'Gc) abs s 0-&f^ &-t£XT)( Standard 2 o". 35O O-§'CO *r\
Standard 3 /'<3OC> / ' O&Q, . . , _ „ , _ _ _ _ ,„,__ ,__ —— „ „„„ , , . _ . -_ —— _i .__,„ ,._ .v^" • — —————————— \
( Dilution Concentration ^EPA Ho. Sample Number Aliquot Factor Heading (a/frri ) $&\
I Initial Calib._ J Calib. Verification• I Calib. Blank• I Reaoent Blank\ tcsI m /L3> *A5$ !i5^a^o,/.V- -3/T>P£> v^^ 1 - Vrrtpj) *.'b$ f -5• 1 - 5 ^
X X;.'3 '
>/ 1
1i
X0-^*3^^)^X>OC?-<^3O
. .0-0,35c?-co^.
, , , ,„„. . " x r r t(9.(933 "YT^ 3£-^o-C'cU" < Dt-O-ttfT' < 5^><>^' /^3^ J542.CDV
O.O/3 \Q-Oi31 C^ l ~C^e£r^ (i j O.Ofrtf'
XO/O o&toQ-c&a J&&PCI />i^C 37J. l i i a - 4 0 5 / - / 1 f l<3-oo^ Uo.<9o5" ^5™ 1 -/€
/r)rC v^M \ ~31 1 -5j
1 Calib. Verificationi Calib* Blank
1 ' ^?rr> vv9 63- ^ ^3 -/> , .„ __ _ -^-
I -"1 ™ "•"" " m r 1 1 - " " - —————————————————
IfcecalibrationCalib. VerificationCalib. Blank
1 f1
_ i L : . , :1 -
&><=&<3uO/CO30-05*7£>.o36>O-<X?DCJ.CC'X^I i V 1 o^coow., , . r 1
i < 5"^ <^0.0^"? //8% ^9(5-o3fo /Ofe??tf/0. (33^
jvix0-OS"5" vtBtd?^c^ >/<5%
1f1x i x
J-O i //o' | )x
<5-03<^i^ -^coX
&&3b lob??'~O*8fi~
1^1^—^^* f ^*J . ^^ fj- , /LCS and Calibration Verification: O/O ' ^ True Value: Q>QCst- (/&**. )
CRDL: /O _(fip b )P Spike - 0.) mL of 5^ mq/L std
— Comments :
. in final volume of /O() mL * £>.£>6?L wg/1* spike
Afl iyst Ch<3fi&e4.{ *s3r Date: »*<3S *V<^
0-C . Approved: ^?/r Date: 7/f^/?r -
1Aeeu-Labs Research, IncIElement: j/#
Flame Atomic
Procedure No.
( Wavelength: _^/^ run BGMatrix: /Ci / 63Water \/ Saill
; Date PreI _____Calibration Blank
(Standard 1Standard 2Standard 3
. Other
F 7008 Rev. £Absorption3#07*3Sy Date: -W!/' Time /# "d
PE 560 No. 82040 Analyst; ^/f^/I.D.L. : ^. / ( ,,-APaqe ^ of j_ /^
STANDARDS tftyrO
aared: /^ ^^~ Prepared by: T^/'*Initial
^- #/.^ abs =* 0 .06 "2*•=- — * - -~ — -• • - ——— — .-._ ——— —— . —— - .. —— .v:. —— . —r", <>
/tf , O
Recalibration^. /i &^- &
/s * 0 '
( Dilution ConcentrationEPA Ko. Samnle Number Aliauot Factor Readino (^ )
Initial Calib. I X
II Calib. VerificationCalib. BlankReagent BlankLCS
I F* FT) V,5£ \5$^_3O_Lyhi P D -*/5 9mf*£) -4<~0 I
I _
'- 3, - -Y,-5
/.<31
i
X X > X /
/ . /, #1 / .///
y/<?//c?<^
-5.5/»fC 5^2 4,5 - .60_2 ./- . . ../. _ .._
IFYJ f*C, y> i
- /€i //oO! ////
-4~^^
Calib. VerificationCalib. Blank
I /r? r £> */V9 &3 - 6tO*/3 - /— 1 jt)
' /51 - - • • — —I Recalibration
Calib. VerificationCalib. Blank
1V
r
//I/O/• &/. c/
y /_//
iV V
I '6 i /• <?..../-.«'. ... /•&
H LC3 and Calibration Verification: 3f<f •" £
GKDL: 3_Q&&
pi Spike «* /^ mC ofm Comments:
. t^pb )/OOO mq/L std
/• 4rf.tf^.•"_^..^_.. ...
p. J5/> / 3A 7/.^£>£
/i *fy-f '#,o.... ' - -o /9-^
Xc •/#.o
/<?& t& J-*-*** / <'/-^^•/ /6
/O ? > ^'^r7 J
V^-i/3^(?^3«s //0f6I* ' II
,IL.^.~.^^UL*3 13<??%*
sZ.0,1o ./6 .'
/*&&
X??•%
^ o ./
True Value: /*'^ (0/0 -^- Jft
- in Sinai volume of / &O tnL « Jvo wg/L spikeAnalyst Checked: ddf,*S Date: ^''^ '''TVQ.C . Approved: <Jfj> <Pr Date: / / P / ? ^
/s
1I
Accu-Uabs Research, Inc. F 7333 ReV| EFlame Atomic Absorption
Element: %_-f) Procedure Mo. <$&O/^'^j Daterfe"^^1"""^^ Time -.2"??2/v)/( Wavelength: £13.9 fun EG <8r> PE 560 Mo. 82040 Analyst: ^Jp
Matrix : I .D.L. : 0.<jOS~ ( Lj" "VWater \y Soil • Other Paqe £ of -j *P~
1 - , . .STANDARDS Gj 7 )
_ Date Prepared; lv~<££~~$(& Prepared by: \JrI• _ _ _ _ _ . . _ _ . , Initial P.ecalibration
Calibration Blank O-&OO <J'&33( Standard 1 0&Q_ abs - &.O93 0 &Q
Standard 2 hCCQ /. &£& \T\Standard 3 ^) *&CQ s-p>(~y*r*) t<~*
1 ' . • Dilution Concentration ..— E?"A Mo. Samole Number Aliauot Factor Reading f^-?-j-i ,P7^Initial Calib.
1 Calib. VerificationCalib. BlankReacrent Blank
ILCS
M}-£> ^$8 $$~ 3OJ-*/- .3/Y) f— • L) * * } i — f
1 -5.5M *"C 5 7-!? 'a 5 ~ la O -3 / -* t
X X X ) X """/^D/.O / ^.^^'
O-oaOO CG>IO'*T//£L(3-O )\* o. 3/*y
/< O O-/VO/O ^ . 37 '
f I o. s^87~/e O'5"%I /r}rC ?"?V -.?
"^^Calib. Verification
— Calib. BlankI sn rt> ^V9 1 6 3 - &Oy/3 - /• . . _ . . _ . . _ .. . . -/«...* /51 , _ _( „ - „ - ——————————.. _ _ _ _
I fcecalibrationCalib.' VerificationCalib. Blank
0-0770-3J7^•vbt>0.COO
1 O.C&4-' 1 _£?-CQ3
V \/X _a --. J\x Q, ,3 3 /
X X 1 X._._ _ ' „ . . . . _ . _ _ _ ./.. . . . . ..e^tft.
^-VO^ ^7^ yifi^Lcc6 <5^> c^r-S < 5C'^i^L §9$ 4i^O-onQ*3nH.d^^1__I.L.O-S'96 P^, ^9 la0-0^7 9 70^307_ JO?4?'O.}5«/O.<905^O-<^>5 tft-0-33i ~uy$+
X6-V04/ ^7^.^O'COS"
1 . . • - • • • • " " ^r™"'LCS and Calibration Verification: o^^f-^T "0- True Value; O**4/Q ( vvi *
ffl CRDL: cs?O ( <4tyb }
™ Spike fe 0*3 . -aL of /f/0 mg/L stdH Comments :
ii. in final volume oC /fn> mL a 0<3(Jti mg/L spike
Analyst Checked* \jp Date: &~&£*Ci6
Q.C. Approved: Yt JA' Date: (/•^-/^S^
IIIIIIIIIIII
Accu-Lahs Research/ Inc.HGA Atomic Absorption
Element: _Wavelength:_ _ ____Matrix Hodi£ier:_Water ^ Soil
nm^_m Procedure Mo*
BGJ^1)__ PE 5000 NO. S206?____________ PE 603 NO. 82034_Other PE 50002 No. 8 2 1 4 3
Date:Analyst:^X .D . L . :_£>.Page __/
7006 Rev* F
fine ./4i'/£for^
ofSTANDARDS
Date Prepared: Prepared bys__^_ff_
Calibration BlankStandard 1Standard 2
Standard 3: ( ^> »O7& ^
Initialo.ooo _ ... .0.^50 abs -.j utftfO./oOO.OkS % « 33
Recalibrauion£>'OOOo-o^oO./oo0 Ob*/ % = 9i
Final
4 S=
EPA No. Sample Number. JD3.1ution .Reading Reading Cone
Aliauot Factor 1 2 (1i
*-l'V* f^ 1 ^ T 0
^ *ii /J
"V^F D **/V^ t
Initial Calib*Calib. VerificationCalib. BlankReaaent Blank ILCS 1
kP- f c >O <?/ ' '-le ___ l-<£Calib. Verification 1Calib, Blank 1
/i>3- (#O<3f • 3-3 !
- f bRecalibrationCalib. VerificationCalib. Blank
Calib. VerificationCalib. Blank
Final CalibrationCalib. VerificationCalib. Blank
X/ •
4xM/ •
X
o
L>
X,„/•<?,._
, /.o/•oy-D/•O(•OJ-O/•o/•o
,. _/.:A,, „»/ -o
X_ _ .7-0
/ •O
X
X 1O-o?)?O-OOO^OJSD.O.-.a/03o. oooO-eooO oooO-/O6o-cooO'O^^O.oCOO-0(POO-03D
XO-lOOQ'Ood
X
X~£L£L22-JO'Ooc? 10*000 1O-/O5 \O-OOO 1O-LTC>U
o ./oVO'OUcJo.o<i5O'OOOo.oooD.o I/ _ _
XO-OJ7Q-OOO
X
X l
^•09^ 9 ?"^o<O.OG$&&Q3L-— "0./i)V /^3^<O'OD5" ^<0*OO!>' <<Q..<X>5. . <<O.Oa5"O.0A6 5^*55<0*00&*< 0,0050-O3/ 6^^
XA&$ ?7<y°<o>oo5'
X
/C
LGS and Calibration Verification; ,5 iP/?..//#3L"2I....-#ol.-. _ True Value; __Q_.__ 4>O_ - _ .( 9^)6 )0;g_ mL of _o?_^_ mg/L std. in final volume of J_(2Q_
CKDL: _ __Spike =comments:
_ _ t n L *Analyst checked i L J? // _
1Aecu-Labs Research, Inc. F 7006 Rev. E
• KGA Atomic Absorption
Elements £OO Procedure No. ^fiOltlOt? Date: la /tJ7/?(a Time <9/o£> d>v^
(Wavelength: 1 ^3- 1 nm BG ^ (Matrix Modifier: J0 ( . /OO*
^_ PE 5000 No.PE 603 No*
62067 i^* Analyst: J& M-92034 I .D.L . : O-Oo£ ( GA^W)
Water ,/• S"oil Other Page / of |
Date Prepared: h 1 &'STANDARDS (pAv^
3 IS t> Pr epa red by : -£• Ir•
( Initial 1 Recalibration I FinalCalibration Blank ti'OOO 0 .OOO
Standard 1 ' 0-O&~Q abs = 0-«2/5 Q'GSbStandard 2 Q,fOO Q.IOO
• Standard 3: ( &-O7Q J O-O72- * = /i>3 O-O7V * - ^t>k 1 * sH Avg .
Dilution Reading Reading Cone.I E P A No . Samole Number Alicmot Factor 1 2 fa&r*^)
I Initial Calib. 1 XCalib. Verification
— Calib. Blank• t P.eacent Blank™ LCS
IrtPC. 572- ! &«3 - AOP-/- /
/.OX I X X
hO O.O&1 O-QAII.O O.OOO O'OOO
' ' XO,01~I /oo%<O>OO<3
i *\ <w 1 1 j- -1
iLO O-QaZ. O'O&6 \ 0-02*4 $9%I'O O.r&b O>OO*} d-Oob
I I * /€ , /.o ' o.ooi o-ool3"?V -A /-O O'OOl 0-OO3.
Calib. Verification /*O l / p « ^ 3 t ? &' 0 3.3
0.001<o±0o£O>Q$-5 ?3*^
1Calib. Blank / • < ) 1 O-OOd O.OOO \<O.OoS
6 ? ^ - 6 O O / - 5i f-O \ O'Otl 0-QI& ^O-Qid 80%Yrt ^2> w9 i ?3 - f e > oV3 - y-/£
1 - /5
Recalibraticn
1 Calib. VerificationCalib. Blank
/ • t > O'OOO O-ddd <Q.o&5I'd t o-t)0^ O'Ooo <o>cctf/•O j O-OI*/ O-Q<bfI 1
X/-oJ.c »
|H™
1 Calib. Verification! Calib. Blank
B Final calibration• Calib. Verification
1 Calib. Blank
X
X 1 X " Xl-O 1 O- O2£ <5-O<36/.O 1 O-OQO Q'&Od
\11
X X X
0-0/3. 6(3%X
0.^5 93%<O'Oa6
X
| LCS and Calibration Verifications JkPfl 3,?V-T & ] True Value: Q.O31 . . (££w-»rOCRDL: /O ( fLf?Jb )
a Spike - £ ) •/ RiL of .30 mq/L• Comments:
std. in final volume of /&V raL = O-O^O mg/L spikeAnalQ .C .
vst Checked: £>/i Date: b / J I W b .Aoprovedt f~n rr Datet V/ir 1^ '
f1**
1 Accu-Labs Research, inc. F 7006 Rev. Em HGA Atomic Absorption••H f\ 1* Element: *r O Procedure Ho. 3#£ l £/3 Date: 6>/e?y/^G Time /O-'&va^
Wavelength: <?#3'3 run BG f$'D
( Matrix ModificWater \s~ £
Iir 1 nsHi/fff Kfiy t- A(<^ kil)i
_ PE 5000 No.PE 603 No.
oil Othei^ ^
Date Prepared: 6/JSTANDARDS (pp^
82067 <x Analyst: ^S /-/8 2 0 3 4 l .D.L. : f).OC>£ (£U>v^ )
Page,)
I of ' I
y/5>6 Prepared by: ofeH"Initial Recaiibration . Final
• Calibration Blank 0.OOO O-OOO• Standard 1 • O-OSO abs ** Q.a.l$ O'O.^O
Standard 2 Q.ioO O-/OO
( Standard 3: ( O-O^O ) O'O^O * - /t^) O-CTlS- % - /0J I * ^Avg.
Dilution Reading Reading Cone._ EPA No. Samole Number Aliauot Factor 1 2 (fiJbv*J)I•
vr/£C - 372.^V.-. ,m ,
Initial Calib. XCalib. Verification) /.OCalib. BlankReagent BlankLCS
Jfi£-(oOlLl - '- l£-3.
Calib. Verification
XI'dI'd1-0i-O/•o1.0t'Ohti
| Calib. Blank /.oI &3- (&&d- 1 - (3 j A£^
wrJ> VV9 ^3-6oV5 - /-/ifi.
I I -/A.
1 —— — J•
I '-
|
. _ . . .. . _.
RecaiibrationCalib. VerificationCalib. Blank
Calib. Verification! Calib. Blank"" ' "" - ——— - ——— ——— - -
Final CalibrationCalib. VerificationCalib. Blank
/•L>/-OJ i-o
X/-</L-0
X' . .•£ '^ . ' ' - ' " ' ' • T """ "
X/-o)-d
X• ,~ian nn-=-
Xd-OVOO'<yo/mo^^.4.0-OOJO-OOZO-ooSo-ofl0-ooctO-OZ-30-OQO
X0-t )37^OcJ<i>^£>C>3
O-O3&0-GO20003Q003__
0-tt>_Q
o.oooO-OOO O&od0.03. 3 1 O-O3L3
XO-O^OO*x>o
X
- xooy/O-COO
X
' ' X0.0*39 9/*6<ro-oo5*<O-ocS&<£>3$ 88%<0-Occ^<O-OQ$0.00 gO-O39 9/?tJ^-o.ooyo.o^ /o&<o-onsf<o-oo&~0-0*3 /lS%
X&.Q*-j 1 ^Styc,*?0' 00*5
X
I LCS and Calibration Verification: JiPfl &£^-JE__£( / True Value: O-O^_3 f^w\-)CRDL: 5 ({L0b )Spike « Q.\ mL of o?f) mg/L
n Comments ;std. in final volume of /OO mL * 0-6J£) mg/L spike
Analyst Checked: ^5^ Date: fa&SfflffQ*C. Approved: fh rf Da te i £ /fj£/3 (*
5
^__5,-, 1,' in ^^^^TpT-^TJjtP-FS^•Jfnj;;1
llIlll
Accu-Labs Keseareh, Inc.
JLHGA Atomic Absorption
Element:
Water
Procedure No. Date:'?
F 7006 Rev. F
Time 9?£ength: /96 ' d ) "^ BG 3 x Modifier: |\J. A)0-, 4- Mo JJO^
lfx Soil Othel:
Date Prepared: |/ i
!r PE 5000 No. 82067PE 603 No. S2034PE 5000Z No. 82143_^_
STANDARDS (op,^IfiLy Prepared by: &>
Analyst:I .D.L. : ft,
... . Page |
.4
&#of /
CalibrationStandardStandard
Standard 3:
Blank12( 6-0^0 )
Initialo.coo0-OSO abs a O.i*j IO./oO.o-a.lm .-*, ,va/...
RecalibrationJLQ&il_0 0$t>O./OOtf.Olol % = 90,
Final
% =
EPA No. Samole NumberDilution .Reading Reading Cone.
Aliouot Factor 1 2 (
tttfd 57£-hi f c £!*-/
to F i> •*/"/<?
Initial Calib.Calib. Verificationcalib. BlankReagent BlankLCS
fy£ '(,,02-1 * 1-i*L-£.
Calib. VerificationCalib. Blank(03-bO 3.1 • <2,S63 - 60 V3 * /
-/£•is-RecalibrationCalib. VerificationCalib. Blank
Calib. VerificationCalib. Blank
Final calibrationCalib. VerificationCalib. Blank
XliO
1=
X/-o1-0
X
X/-o/.o/.o„„ ,/Q. , ,. _ . /--(>/.oJ-d
/.oAt>
_.. _/.t?_ -
/•oX7-0
X
Xd.6>V5,9-CXOO.O-OOd)D-ovoO-OD/D-ooD _0.oV5o.oo/O-O&)o-oooO-OOOo-oos
XO-OfVQ.OO 1
X
XO-O*JSO-QOOo-oooo-oV/O- oo fO-oo /0-..OCLO
o-ooo0.0/0O-OO 1o-ool0-O03
X<!>• ^y5Q.OO 1
X
— t-=i ——————' X}.0Y^ 9d^)^0-OO6"<O-tJO5O'O^O $oc%.<0- 00$<O.oo$<O-006"0.tfV$ 9o^^O-oc^Q.Q/O /0L)%t)<V>OO5"^Q'&O£3~&OO $ $0%
X •0.£>y5 ^><8<0.ooo'
X
><Vt
l
LCS and Calibration Verification;CRDLs ______ 6 (Spike » Q.l _
Ttue Value: O-05O )of _//)_._. mg/L std. in final volume o£
Comments: Analyst Checked:Q.C. Approved: ^
Q.OIQ mq/L spikeDate i
Accu-t-abs Research, Inc.
III1
I
HGA Atomic Absorption
Element:Wavelength:____
I Matrix Modifier:T _ . I _ _ . Procedure Ko. j^___________^11111 BG BD _ PE 5000 No* 8205?
PE 603 No. 82034 ,„
F 7006 Rev. E
Pate;6/JQ./?6 Time 3 .-QO^^ Analy5t:__^^|-
I .D.L. : o.Watsr Soil Other Page _j_ of
Date Prepared:_STANDARDS
Prepared by:
Calibration BlankStandard 1Standard 2
InitialO'OOOO-O-SX5 abs - O.I3.Qo./oo
RecalibrationO-OOOO.O5t3o-foo
Final
Standard 3: ( 0,0.1EPA Ko. Samole Munber
Initial Calib. ICalib. Verification! /Calib. Blank \Reacrer.t Blank ILCS t
•ID PC &7 3- b3 -kOZI - ' 1- 1C. Ip7V i -^ iCalib. Verification!Calib. Blank !
f\ \
rnp 1) VV9 &3 -60V3 • / 1-/^i i 1
Dilution Reading Reading Cone-Aliauot Factor 1 2 (ftp/tO
X X I X X ^ ^ x.O / •O
/ • O0-O3S O'oai, O-Q21* IO^%O'OOO O.OOO 4O.OOS1
/•O i o-ooo b.o&o \ <o>ootf_ . /-oAc)
0-02?G-000/•o o.ooo
AO o.oooI.Q o-oa.$
_ „ t'O . . . . . CL-QPO
_.. ... . _ _ . . ../,_o_. __/.o•AS v /-tJ
iRecalibrationCalib. VerificationCalib. Blank
] t
i1 •
XL><;
X/•o
O.0*3fc/I B 5^/\
O-ooo0,000O.O2-L)O .OOOO-^VO
0-Oot) D.^OOO-OOO O-OOo
O-O&7 103%<O.oo$<o-oo^<O-O06"0-02(3 /L)V%<o.ooo"6./PV/ f^^6<o.oo6"^o-oo^
O-O^ 1 O-ObZ \O-O(*/ /^>7n
XO 03^
/,(^ O ftrtO
Calib. Verification! Calib. Blank
Final CalibrationCalib. VerificationCalib. Blank
' X X&-O3-7fi'OO{}
1
X
LCS and Calibration Verification: /0P/} ||CRDL: /O ^ -f-pk )Spike «O./ O i.5 'tf »L of .^O mg/LComments :
X
I1
X X
O.oj.7 /c^%ko-^o^
X
£3-17 it 1 True Value; Q-033 (oO/v^)std. in final volume of /OG> mL ** 0>Q<SO tng/L spike
Analyst Checked: ,^ $, , . . „ 1(,.~k,«&-P* Approved:
Date: b/AO l#<tfy feV Dflte: Tla|£k
<r&"
•(!&
Accu-Labs Hesearch, IncEGA Atoanic Absorption
F 7006 Eev. f
Element:____Wavelength.:_ _Matrix Modifier :_Water *s^ Soil
not._ Procedvire Ho. __
BG && PE 5000 Ho. 82067m__________ PE 603 No. 82034_Other P£ SOOOZ No. 8 2 1 4 3
Date:_7 Aa/?6 Time^Anal ys t ;_J5»_//..,I .D.L. t_Q,OC>3Page f of
Bate Prepared:STANDARDS
Prepared bys
Calibration BlankStandard 1Standard 2
Standard 3: ( O ./5O >
InitialD.ODOO-AOO abs « 0^n/0-(300O./YO % - 93
Recalibrationti-oooA.IOO
f t j <35 % » /0:i
Final
% =II EPA No. Samole NumberDilution .Reading Reading
Alicruot Factor 1 2
Avg.Cone
trt^C ^^A.•^rjpc ^7*y
HT)F 3? -y-/9
. I —— ._™™=
Initial Calib.Calib. VerificationCalib. BlankReagent BlankLCS
^^ -/£ '- 3.
Calib. VerificationCalib. Blank
& 3 - (o O <2 / ' 55£3- 6OV3 - /
- //2.- /5
RecalibrationCalib. VerificationCalib. Blank
X' •O
wXAOl.d
\
Calib. VerificationCalib. Blank
--- ,KJ. 1 - *
Final CalibrationCalib. VerificationCalib* Blank
X
XJ-0
IA>_ . AOy.o/.o
AO/OAO/•O
-/•OAO^10/ •O
r x/-O/.t^
X
Xo.ovp0 -OOOO.OOIo^oY9
. .0-000 .^ •Ofl/0-£>V9o.ooo
XO-OV9/>..O00
' X<).£>/<? ^^<O.f7O5o-ooo 1 <o.oo5O.OV9
O-ooOO.6O6_ .O-oo 30-0-^5QiO^a
0^30 1 0-/3V0-0070,000O-035*
XO-O^)O-OQO
X
0-OO.5_ _O-OOO
0-OV9 9j><i•^ODOS<.o,oo$<^O'Oo50-o^7 W
<OOO6"^ ./3J 66*0-0^6
_<0.G_O5O'<?3y 0-056 ^
X6.059
Q.QOO
XD-OtO /^O<0-005
1
X X
III<3
LCS and Calibration Verification:CM3L: **/Q ____Spike = d(A__ wti of
JbJLVLv$J(/. True Value-^
Comments:mg/L atd. in final volume of _/_Od_
Analyst Checked; JQ.C . Approved; ==j_
^?^5O (<mg/L spike
Date:
IIIIIII
II
Accu-Labs Research/ Inc.
\iHGA Atomic Absorption
Element:__,Wavelength:^____Matrix Kodieieir:_Water i/"* Soil
Procedure Mo.«nm BQ^D,._ PE SOOO No. 82067^" _ PE 603 No. S2Q34"
F 7006 Rev, E
TimeAnal ys t :,_Jjj.//_I .O . L . j /
Other f of /gTftupApgs
Date greoarsdt b iAfo l$b Prepared by;
Calibration BlankStandard 1Standard 2
Standard 3: f 0.07 A )
Initial f ReealibrationO.OOO ! &00OO.O&& sbs « <lit>9^o,/ooO-CL25 % «• 7^7
£>, otfQf <?' /<?<> _
Final
0-O7JL % * /6>3 I % =»
E?A No. Samole NumbeAvg.
Dilution Reading Reading Cone,Aliouot Factor 1 2 (fif)^^!
CMi Initial Calib. X X1 Calib. Verification! id! Calib. Blank1 Reaaent Blanjc* LCS
TH F<L d27,2 ''kd*t*O3l- /! */£
J")V ; *<ii Calib. Verificationf Calib. Blankf 6 > < 3 - & O 2 / -.2.5.tn t_2>. _jtfv*? ! 43- ^o.vd v * .. _f * /£t - 1$
-- - , ^T-l.,-^r-^-.-,F,-»^r.l-^--T -
, ™ /
3y/. ^
1 //
X i Xd-Obl f O,0b(*d-OOZ- f O.OOIO-OOO ' O'OOO0-05*1 &(&±t
Q.OQ3 I O'OOO_0-OOO O.OOO/ . . . . _ .0-0/3 _ o.o/z-3 O - O 6 V 6.tobl~
/ O-OOO C-&Q0
- • •/ ——V
t Recalibration Xs Calib. Verificationj Calib. Blank1
i.ot.O
\ 1i- ,- - r~ ,. , , .,™ ,,, ,„ ,TT
!» Calib. VerificationI Caiib. Blank!r!i1f Final Calibration
Calib. Verification1 Calib* Blank
i O-tilO O-O1 1... / . 6-000 o-ooo_ 1 O-OOO 6.t?UO_ _ _ _ / 0-OiSt 0.0$<J
X X ' X_ Z_ L O-^fo? o^fea^_ _/ _ . _ _ 0-croo j o.ooo1f
1
X
t
fil
Ii
X' - J
X X
i r
-~""pr" '•• —— —XA/33 A>3&<0'Q&6< o-t> 03"&./JL$ 95 #j<10ip06""<& >OO£>*&>O/*>£ > ./ <26> 9<?%<O,0O6~
0-O70 H1%<0-0o5'<t> ootfO-OQ& io<tfu
XOJ50 101%<O4)O3
X
s
LCS and Calibration Verification: t •QtPflCRDL:
True Value;Spike - taComments:
std. in final voluma of _/tfgj__ tnL =Analyst Checked: _. Jk..H_.Q»C . Approved:___
spikeDateDate
1Accu-Labs Research, Inc. • F 7009 Rev. F
a Mercury - Cold Vapor Methodi— «*. Wavelength ! at-£>3f ' na Procedure Mo. zcO/GxrU Dates wff'&fc' Time: &'$Z)&*~<'L. PE 503 Ho* 82066
1 Water ^^soil ' OtherSamples Digested and transferred to AA rocm:Date/Time (fttf-fib? 0}'0Qpr*t Analyst \^P
1 ' . . ' - . . - . . .- .. •„'?•&"."''•. -.. ... ,. „. „ .^ „; .i •••,•£' ' . . - * _• *^f...V-""* ' i<£»— • /O **&&y- - -Date Prepared: ^ ' ' ^^
IM.'* ——— T^-.™ . ^.,, -rni , --^———— .=» ——————— -B^,, .—— _________________ - —— ______________________ _______________________________________________________ ___________
i.«', STANDARDS
Analyst: *^t.D.t*. s^-^2^35^ ( ^^v? }Page of ' '
. "-. * ' : ! i:' _.* ! .' ^,r'.^ff^ . . ,
Prepared by: ^fConcentration ( )l Initial (rtm) Recalibration (rrsn) t Avg, (mm)
Calibration Blank O-C&D & d? 1 VStandard 1 Q-*&**3 /£~fy /*/& I /S'af.S"
( Standard 2 t^>-d^>5U //^ /£>/ I /&&,$"standard 3 O*r&/ &O .5<S I 5^Standard 4 ^-OOO^J 3^ <^^ • ' 3ff-S>'
•
Standard 5 I &• COO3-> /9 /^ I /'7. i JStandard 6 I I
Bottle " • Dilution ReadingI K P A Mo . Samole Number Number Aliauot Factor (rrsn)
I Initial Calib. X i XFcalib. Verification! 53 ; /CO
I i Reaoent BlankI LCS'• 59*<3o/^ $
|
, - _ . ..^-, l l l l... .... — , .„.- , . ! ———————————— L_.- .;. ————— L.. . _ . v. _ _ . . . . _ . . . T_\te&~dot4 /
1 - - ' ^ ._._ . ... /^ .. ' , ^
1Calib. Verification
1 Calib. Blank1 ^5F<^/"c?/7/f/ ^
|._ .. . ._ ._ . . . . /A
1 ^>1 *3S
I ^TiFC 373L \&3-fco£l 1. ._ !//?_*fn P c »3 *i *-/ ^?
I., . <x S
RecalibrationCalib. Verification
6V ' i^>55(^^"T) ^..as? . . . . ..... . . . . .&ot?f i«?(3-/(Ojp•^Vfob&7&$(&9 iTO i7/ !
Jo273 ..-7-V >/
X X7-S _7«)
XS >
(<^D
Xsv^5gy/^L
( ^9
'"vK" "£L@O
IL1/^3/57.
JT3 (^.^VV/
Concentration' X
£ 33 Hjt^Q *45-CC&L ^A.33 /0?<?££D'CQt£LO-OOI3f).&Q3 f$y?&^O&Oci*/>ooo§d-coio ^"?u
3/ 1 &&>$$//PP/Offf7. ~e .. . _
35/I /VX
<50O
9' ™7 " "//53
X/^3
*Q-6C£bL& 33 ///%*&*OCOSLO <cQ) tay^.£&-GO03- *^£S$OQ &% «O€C&*/-Q.OOCfc l(f^£d,tO3?L>43-OX& £>% <t-G-OOOcZ- <ft£Ot /&?&
X-0.3/ //>3*?o
§| tCS and Calibration Verification: £83~<^ ' True Value: &>3Q (s)/)/yj )CRDL:_ _ 0,^ (Pr?b 5
H Spike' » /,c) mL of O./ mq/L
Comments:i
. . . . . t ,
std* in final volume 06 /oO a^ =* OQbi& sigA* spikeAnalystQ.C . Apj
Checked; O^7 " Data s/fr-/*? * * £&. .iroved: 2?^ Date: 'Jl&f^^
CVJ
I Accu-La-bs Research, Inc.Ho.
CYANIDEF 7007 Rev. E
B & L Spec Nom Wavelength: 57S nm Dats j ^O^' f^Time j *'»rf^/~
Water v Soil ^ Other _ Analyst: '/} L^£J^J
1Date Prepared:
1• :
I Calibra-ion BlankStandard 1Standard 2Standard 3
I Standard 4• Standard §
I .D.L . : y { jPa9e -.—..-/- O1^ _ /
STANDARDS ^^ ',&~3-0'~%& Prepared by: >^f J^f/^y-^^^4—
/ ' " '" ,Concentration Initial Recalibration Average
(*£ f/ ) 5&A*& Absorbance Absorbance Absorbanre& & 0V &.QO ri Cfi^ff &&O 0,439 0 S)3Vgfd> /) ft »0$tj fl.£%& d i d^Z.£-&'& d t&iy /y.iJS' o 1 2 li/z
-sTO't) V> 3*1 d,ij3? 0 , fy37/0&t () £l &l<? &; #/3' /} , rf/> ^
( Dilution Concentration CJSPA Ko. Samole Number Aliouot Factor fcbsorbance (P^b ) J4$l
Initial Calib. X \ X
1Calib. Verification i j&vO /, C
\ Calib.1 Reaoent
Blank ojbo /rfiBlank £*&& /t f)
LCS £SQ //#
I /7/^r. ^ 72. f £ »2- &42/ -2- -/ &&$&£ /t&f*i £c 3~~? 65- *&£ aj~ ^ -j£ zsftfrQ /, &ft>1 FC £*?£/ fr^-fat
I M1 Ffr <??*/ £ >2-^£ <_ . ,„ . ,„ . „„.„..1• Calib.
Calib.
1 . . . _ . . - -
I .M • . , . , . - ———— -
-
1
I RecalibCalib.Calib*
'^•L — *^ ~*i*- ^~<?^M/ ' /i/2?ZI - 5- -^& ^oTO «/ 1 A(5
1
Verification 2JY? /, 6Blank d'Att f /±0*
1
x x o__ _r f2/^ fOi _ IQU% W- _ S '• n ,. ,,-._=,_* —— K —— , >-2
,tf O ^-,5*1 6 ^-^^(7 d -^.^-fl -^'0f /<?? ' 41J *?V
/ 0 / ' ^ <"/ G <? 1 0i^/ ? <^> /) <r/o«"»<? ; ^^, fi <iOj / $ ® ' 9^ i /
iii
-,. A *? . . _ . _ _ . _ .. .. 7&/t.f_ __ /03
If i i
f if - i 1\ i i
1ration X X j X XVerificationBlank 1
• Calibration* Verification: $£M*/ $.gtf<v<f True Value: /0&,d ( f/£ )• LCS : 5. <
CRDL: 10
3 Spike * _T7_f)_ »L of« Comments:•
^t Xi. "h? n^7 True Value : /<5V. d ( /W) J( )
_S70 mg/L std. in final volume ofAnalyst Checked:Q.C. Approved:
ji<rO BL = 4?tl$6 wg/L spike/^/ Da te ; ^ "2 ? ..-*%
i^> (^- Date: ....'fl-f ?/!?(*»
IIIIr 7001 Rev . A
£?A Total Metals Oioest ioo SheetProcedure Number 3307200 Qata
Ana ly se
Sample MumberInitialVolume{m l }
Final AcidVolume Added(m l ) (m l ) Metals to be Run• •—• — •
Reagent BlankBcs-o^oa/ /• /€i1
57-^9/V /• ———— —1 //c^«
Itt
X
3
I ,V
to
V^
o
y
,
'
:>3
/I1
H .M . , Group I ,4 li, WAg"" "Al/Ba , V, As/Se, Be, Sb, Tl , SnO., Group U II, Pb/Ag,Al/Ba , V, As/Se, Be, Sb, Tl , SnH .M . , Group I 4 n, Pb/Ag,Al/Ba , V, As/Se , Be, Sb, Tl , SnH . M . , Group I A II, Pb/Ag,Al/Ba , V, As/Se, Be, Sb, Tl , SnO., "Group 1 4 11, Pb/Ag,Al/Ba, V, As/Se, Be, Sb, Tl , SnH .M . , Group i & II, Pb/Ag ,Al/Ba, V, As/Se, Be, Sb, Tl , SnH .M . , Group i & 11, Pb/Ag,A l/Ba , V, As/Se, Be, Sb, Tl , SnO:, Group I A II, Pb/Ag,Al/Ba , V, As/Se v Be, Sb, Tl , SnI.M., Group 1 5 II, Pb/Ag,Al/Ba , V, As/Se, Be, Sb, Tl , Sn
1Spike Data: SampleVolume— ALR Number (ml)K3~<&)<3/ c?S|3-^HS IS
1
1
"• -
• i i i
. «.,
Standard Soike Used1 2 3 4 b b .-n
LXi/
JsLx^
y 10 11 12 13 14 Comments
i.Alkali Metals and Al/Ba Spl i t Yes { 1 Mo {lv Digest ion Comments on Reverse Side.
.*.-• J — • • . ' . ' • v '
IT.^rCMr-*oo
9 \f 2 L 0 0
Research, Inc. 7014 Rev. D1111111I111
Element; AJO- £u^*j &&J&J PS 5000 No. 82067 i*^~^ PS 50002 No. 82143Analyst: & H" PS 603 No, 82034Date: 7/^/^6* Times 1? rcjp <X/r<—/
1 s$±tf ^*3 ^* 1 V * fl
3 C-fcjLfei _ " _. :. . _ " ' _ : ' :Sbd-bO&l- 16 -/£ 17 -4L8 ^3. 6-o-VJ - /9 C-6jUb
10 C^\)ejuJ11 fcS-fcoV. - //ft12 fj'J C_-^13 i> 3 -& > £ >V3- «?14 -cSig15 -3i6jLLec_i .IJ 317 C'UfxJ . Ivs^v19 k3 - 6>oV3- V2 0 - 5 121 -422 "723 -$24jt«u:/;J--^fe/-5?- C 6 C > )25 C'OfiJLL/
B272929303132333435
Date: Time:1234567 r--.?„.„ ... ™ .. ,. , ., ... . OJ10 f—11 00
1314151617181920212223242526272829303132333435
Comments
SCJVCjj
OC; j
OO T
"IS2J
61 1|
Hjj
u j
L ||9 j
K028 -OK C09 3d"OK 0005 3d
e
r-y ^/ifc?7 -
5CTcTcTTTc'oc
82
92
QZ
81isiEl
01
- 7 2
i
iiiiiiii
IIIIIIII
Acca~,a:)s Research, [ n c .
AnalyUiJp-^Date; y A3Q/$6» Time :I J^ 32 C-lUa^J. b4 ^fC-S/* . i
6 - /£7 — ^tsC8 4j_^0</3 - /rt /* /3 4 i^"^
Jo C-O^J11 f e?3* &>oV3 ' /£,12 ^C513 6>3 - f eQV3^ 31* * <?£15 -3Hjt^cJ 43^3^^.Jjj^j ____
^JL&^S____19 ^3 . 60^3 - Y1° -5j j _ -422 -712 __ -SILf^Mjbl iC-l)CAxJ26272829303132333d35
' 70 H Sev. c£?A MCA In jec t ion lc<j . ,
^kl Pe 5000 .'!o, 3?067 */P£ 603 flo. 32034
//(jo ft/v~-~ 0<i te : T ime :'i i:t 2il 3i! 43 5iU1 7" 81! 9I 'O111II 12II 13finHi;;ll61(17iiisid?ilzoHa1122!!23!iz«liasllzeI! 27\\2SII 20! '30I i3lJ32!l33!lj<P35
CMr-oo
0 S E I 0 0
1111118i
11I
III•Bi
EE"
oAna lys: : J& A-Qate: 6/;25r/£k1 ..jcd, .J_..._ .3 f ,fejj^4 ^55 65 - 60*2 /678 6,3-^^/3^C^iUU^
10 C-i.KA.-t
11 &3-k £ >Y3i o .if /"*
13 fc3-&0V,31415^XJLjTjcJL v517 C-0«AJI (3 / b< A lvI O I ^ 11 tf t'
i? ^5 - koY202!222324 C-6Lfe .25 f.U.eW26 &3-foji/3272629303lA2X^-Jl ^l^Al^4_.33 C- CUUL3-i35
c;i- Inc. f 70 N 3ev. c£?A MCA [. i jection La^
-) P£ SQOO Mo. (3^067PC 603 No, 3203-1
Time: f.-at) a*— s Date: T ime :!! I:l 2il 3 , 'i! 4
- /- II s^ t » 6-5 I I 7
- / !| 8II 9II 10- ie !lnI l2
- 3 f| l3"<2|€ If 14- ^ II I?
jtrJi '1 1"ill?ilis
3- V ih.o- 5 IUo
/ IUi* • w [ 12 1- 7 II 2?/ n *—
-? 1 123IJ24»2S
- 5 x !Us- d j? \ |J27' - .6 j /0^ 128- XZ ZL 'zn-i / i=3o
xX<^3 Ii3lJ32i l33! l34. 3 5
LACMh-oo
tore-its:
1111111111I1
Accu-Laiss Research, Inc. F 70 14 Rev. DEPA HGA Injection Log
Element: Ai- PE 5000 No. 82067 PE 5000Z No. 8 2 1 4 3 t^--pX
Analyst: jB'/J' PE 603 No. 82034Dates 7/3/tfk Time: 9-COOxr^- Date; 7 l$Jg(s Time: //}.' ^O1 ht_rl 32 CNOeiJ3 C.&&]b
e f o p - f c o a/ - /7 -/£8 "<H
9 r-Jf»jJioC^6JLk^1 1 ^ - f c O A / - ^ 512 ^3 -6OV3- /13 -/£14 -/5I5j(^^ ^iP <316 C^U^^J17 c-ejut181920212223242526272829303 132333435
1 &L$ 32 C-Oe>vJ3 £. 6JLk>
v
4 * • £ • 6Lfe>. _5 tf^L 5 _ . ... __ _._ . . _ . . __ _ ___
7 -j£8 "39 C- U^ru^
10 C-feJLfe-11 ^3 - ^0^/3 - ^/12 -5
CMLACM
OO
13 -414 -715 - ?1& JCj JlO^- d£eJ? 3j * j i l l * . ^
is C <3JLfe^>19 U3 - ^OV5 - S5^, '-20 C-Ue/iJ21 C-6jm_2223242526272829303132333435
Comments
11111II1111
1
,„ „— ..-j-.^s-ii.HWssiisalM;m»^*^^^>*»^'^^^^
Acc-u-I^bs Research, Inc. F 7 0 1 4 Rev. DEPA HGA Injection Log
Element: J& - &'WCCl ^ £ Jk^> PE 5000 No. 82067 PS 50002 Wo. 82 143 LS^Analyst; & & P£ 603 Ho. 82034 .Date: 1 /.2.I&C? time: /.'O5o*W_ . .U . ( r f . . t .V, , ——— .„ ... ———- • .- f"
1 fcJtdX 3 . . ... ._ . __ _2 Q^wJ ' I3 C-&Uk}4 //) -^
5 b 2 . f , o J / - ' l6 -i£7 -c28 & 3 - & O Y 3 - /9 C - 6 A^J
10 C* l^-eju^/11 ( ^ 3 -60 - ^3 - /£ I12 S13 fo 3 &>o YS j (314 ~t?i?15 -3isXUxJ. vSJjJ1 317 C-0?<vJ>1 " " ." ; y18 C-fCX-D
- 19 6> 3 - &o~t/$ - rf20 -521 "^22 - 723 -?24 C- &Xt>25 C' UU^26 ,.)3-66V3' / ^ /Oy27 -/(^28 XAjoal iAP29C-UfiuJ , _ _ _ . . . _ . . _ . _ . . „ . . _ _ . _ _30 C-6JL|E3132333435
Date: Time:1
•~_ ..— - - . - - . ._ .-5 —————————————————————— _-7
^9 "^
10 ^11 O12 °13141516171819 *2021222324252627282930 : ' ' "" ' " • ' " " ' " ' '"" ' !"~-'~t~*3132333435 " : -
Comments
s 3esearch, inc. ' 70U11111111111
Mr''TiDate : ^/,30/S1 6ir<J3Z-JML&IA/3 C-fcJuS4 -£-&JLJo5 ^CS6 kP- it>0«7g?. C-.UoiV. r»r) C -At k>~ ^- WJ__-t JK^f
12 63- ko <1314I$X_FJCJ&Iisr-O^Jl' C- 6JLk^181920212223242526272829303132333435
£P^ MCA [njectio.1 Loc;f jL P£ 5000 ?!o. 32067
PC 603 f!o. 32034 4^6.- T ime : #:oo<Wv. 0<Ue: ^/io/5^ ^i^e: j--&op^j
'• I 4^J v5•I 2 C iO^Ju^if 3 c% go^B 4 ^-6XJt>!l 5 ^fc S
/ - y 3 6 ^ >3-4o^(3- 5L- /e II ? - - ^ j e- 1 '! « 3'^ t| 8 -3i i| •
11 10 c- fcJubil - 3s hi (o^ -'toV3- V/3- / . Hl2 " -^
-; £ I I 13 -4-As H i * - ^
^fjj 3 His -P•'is X-$jCjou& ^SJtc^ 3«i7 C~O^AA/ilis ^,aJLtoill? G> 3 - yo-^B- $5Hzo C- f <W1 121 C-6JLfex11221)23II 241125BZP1 1271128hi1^0bi:lj2:!33!l34P35
<Mr-oo
-1
0 0 7 2 5 5
0 0 7 2 5 6
11111111
1I1
Accu-Lalas Research, Inc. • F 7 0 1 4 Rev. DEPA HGA injection Log
/ A )Element; ,&MJ * .H/TJX U^J PS 5000 No. 82067 PE 50002 No. 8 2 1 4 3Analyst: £}\- PE 603 No. 82034 is^Date: ")r*>r%(a Time: 5?,'/^Qx»-O Date: Ti-ne :1 j&d 32 C-U^uJ3 C-fcAjS?4 /5?Cf>5 by- - bQ£l- I6 -/£7 -- tsi-8 k3' £ > o-Y3^ /9 C- &Lte)11 k 3 " b^ V3 - / fL12 (7) £*$13 f e .3- f eO </3- ^14 -^£15 . -3 _
iv e>D«A>/18 C - (5JJ^19 It^-^O*/^- 420 "521 "t?22 "723 -£24 f-6JLfc;>->C I ** i I A ' /)
26 k3- t ,A57* / ~ /0V27 - J -/ t > y2829303132333435
1234 '56789
101 112
———— in- ,,. ™ , . CM
oo1 314(51617181920212223242526272829303132333435
Comments
111111111111Ia'
i
Accu-i.i3S Research, Jnc ,eP-i HCA r
Ana l y s : : J5> ^Date: b/_3i. Ifib • Time: ty-.OOQsY^-sI fj^ 32 r-UtiuJi -^ (
4 ^.ftjLfe.*> £r <,° f7\ L .-> . • _ . . .._
6 fc> 3 -(s>O3 1 ~ 17 1 ^"* I K-^
8 - Xg C-UeW
10 C . ( Lk;11 (^,koa /- 12 k .V6oV3- /13 -/fi14 * Isj-j )C-&-?_ -J!- "iXo' O16 (^ _ ^ ) *(J\ju4
n r^eiJLHis1920212223242S"26272829303132333435
•• 70 U 3ev. CTje c t i on Log
P£ 5000 Mo. 3?067P£ 603 Mo. 32034 </-Odte: fctefe/tffe Time: /.5.-V5 ^^
if 1 ^tJ 3:l 2 0-0 -il 3 c-ajLiS. . _ . _ . . .it , ..1! 4 *x-fe.lJe.>» f *^) -* /•5 (ACsS ^!| 6 J^M^ - 3II 7 • ,5fiII 8 -3 'il ^"^cT^r 'jj!lio C-6jJu"11 L> 5 • /-?o */ s * *y1 1 1 ? - *=!II it -_.!
II 13 "61 . 14 - 1His ^HlgjC^^ 3&J .? "111? C^O^WIlia C~&U?>Hi? f c >3 - f c ^ * /3 * RiJUo r-Ue^("lai T-dlS1122«23IJ241125II 26!l271128||2q • ' " , . ;;————•" - . ' . . , . „ . . .
1:30Ii3lLzi l33!l34i'35
cctTi<Mr-oo
Comments
111111111111•11I*
1
^ ". - -t » y X/i O-* / ^j
Analyst: ,);, (4-Date : &/6&/2P6 • Time :t^fcj) 32 /1 i \ . i( -V &IA-JYT)
4 tfc$5 fcj- £ > £ £/- }o " 1 K7 -A -
9 <%6JLfcioC^UeiJli ^3-fooV3 - /£12 ,#£613 -- 40^J - £W -a JtJ5 . -316 ^rtjLLcJ- Al^ 317 CtfvuJis CMJUL^19 4 ,3 -6 ,033- ^/20 -52! -£,22 -723 -^24 C-fcjUb———— W.gAW ———————26 1)272829303132333435
? 7 0 1 4 3ev. cEPA h'GA [e ject ion Log
pj^j* P£ 5000 Ho. a?0o7P£ 603 Ho. 32034 i/
^.•/f a-vv^w 04 te : T ime :•'! I:l 2|| 3 , . . .^r-^fl^^M—— » - - .
i! 4!l 5ii 6
A* II 7!I 8!l 9II 10!lnII 12
-» II 13-^y 'll4-jy II 15
ills!ll7ilia
-£i II 19~,2y II 20-^ »21-2* 1 122
- 5-X 1 123II 24Has«26»271128
- • 11 20boIi3l:l32il33334P35
oLHCMh-OO
Comments
8GJ
on
'o
'a* o3 -h
O
OO
0 0 7 2 6 0
IIIiii1I
Accu-Ubs Research , Inc.7003 Rev. A
Internal Cha i n of CustodyOr i c i n a l
Case Number.„ ALR Number
Log-in date _Log-in timeSample CustodianComments:
Locat ionSample TypePreservat ion and Volume
CMr-oo
IE?A Total Metals Oige s t i o i SheetProcedure Number 3307200I Analyst
F 700 L 3ev. A
Timef .'<£
- Initial . Final AcidVolume Volume Added
• Sample Mum&er (ml) (m l ) (m l ) Metals to be Run -fttLReagent Blank
Icsba-ti&i-i1 //e
n o-L
* 43-<ky/3 /I ^
Sl-£}/¥ 11 //?
/ec3
iM/
ceO
\/V
HM>>ncr
_A^_/
/Y~
H .M . , Group 1 .5 II, Pb/Ag .At/Ba, V, As/Se, 8e% Sb, Tl , Sn
l i .M., (irbu'p'l "i 11, Pb/Ag, ""Al/Ba , V, As/Se, Be , Sb, Tl , SnH.M., Group 1 A U, Pb/Ag, """"Al/Ba , V, As/Se, Be, Sb, Tl , SnH .M . , Group i A II, Pb/Ag, " "Al/Ba, V, As/Se, Be, Sb, Tl . SnTU,M. t Group I i 11, PbMg,Al/Ba, V, As/Se, Be. Sb, Tl . Sn
- H . M . , Group I & u, Pb/Ag/~Al/Ba, V, As/Se, Be, Sb, Tl , SnH .M . , Group I 3 H s Pb/Ag,Al/Ba, V, As/Se , Be, Sb, Tl , SnH .M . , Ooup I A ii, Pb/Ag,Al/Ba, V, As/Se, Be, Sb, Tl , SnO., Group 1 A 11, Pb/Ag,Al/Ba, V, As/Se, Be, Sb, Tl , SnISpike Data:
iiSampleYol ume
ALR Number (ml) ,-&o£it aS*^W3'/S
•
toOWO
Standard Spike Used ^
V(X
\PI//
JA>Si/
JUi"/£'i/
§''(/txx
y ti ,**;(Xtx
aoyi u^amii> wt--c/
I/iX
6-t^
\ •
is'is
\/' L
.,,
<•Comments
/-
I .Alka l i Metals and Al/Ba Split Yes (*»-^
i;j Digestion Comments on Reverse Side.Ho ( )
CMvOCM.f-Oo
11111111_•
I19IIIi
I
I
MO. 3807200 REV. 8
Std. 1
Std. 2
Std. 3Std, 4Std. 5
Std. 6
Std. 9Std. 10Std. 11Std. 12Std. 13
' Std. 14
Std. 7
Std. 8
* HC1/MNOWRITTENAPPROVEDPAGE 5
ElementCr
, ,,CuPbCoFeZnMnMiBeSn*Sb*CdAgNaCaKMgAlBa
ElementAsPbTl(*• jCdSeV
3 digest ion£*tts>OF 7
Water - Flame Dige s t i o nSpk . So l . Spike
Cone, (pom) Vol . (ml)20 1.0255050
100100 0.2100100 0-4
50 0.1100 0.2
25 ,50 0 . 1050
1000 101000 101000 51000 . 51000 0.21000 0.2
Water - Furnace Diges t ionSpk. So l . SpikeCone, (ppm) Vol. (ml)
20 0.12050 0.1
"""51050
analyzed by furnace atomicDATE S#k, QA
, ——— Q- —— -E-J --——-—————— - .—— - -T- _ .—— '- -. x- ——— .
Sp i k e sFina l
Vo l . (ml)100
100
100100100
100
100100100100100100
SpikesFinalVol. (ml)
100
10,0
absorptionT]ft-___&- A *~ ' -in- •--,-_-
SpikeCone, (ppm)
0.2000 ,250.0.5000.5001 *00.2000.2000.400 vC0.050 <^r~0.200 o0.050 0
0 .0500.0501001005050
2.02.0
Spike •Cone, (ppm)
0.0200.0200.0500.0050.0100.050 , ,
*
DATE '2-~b-%^
" in" 3^
AV" cob 'D-eoo *Q- .200 *0 -eoo~*o-eoo*o~COO '0 -
AV
"7 200V0-C 0 0 * 0 -
AV ~20Q*0-5" 2.00*0-
; - eoo *o-2 0 0 * 0
A V 2 0 0 * 0 -»l#0 2 0 0 * 0 -
2£010^A V 2 0 1 * 0
J O T * 02 0 0 * 0 -2 0 0 * 0 -
AV 200 *0 «2 0 0 * 0 -
__I£0^0-AV 2 0 0 * 0 -
AVIOQ*^T O I ' O
^ ^7 Z O T * 00 0 1 * 0I 0 0 6 0 -1 0 0 * 0 -too *p~Too^o^roo-J
noAV 6 6 0 * 0
O O T * 06 6 0 * 09 9 0 * 0
esAV
03
TS
zvAV
i 9 0 * 0o o t * o1 6 0 - 0i 6 0 * 0Z 6 0 * 0O S O ° 0
s e i ' o0 0 0 * 0o i e * o6 0 C * 0O l E ' O
AV
AV
T 0 0 * 0 -2 0 0 * 0 -1 0 0 * 0 -8 6 0 - 02 . 6 0 * 00 0 1 * 0"TW "V 9 0 * 0£ 9 0 * 0O C T * 09 6 0 * 05 6 0 * 0S 6 0 * 00 9 0 * 0
AV
AV00
TSAV
^ 9 0 * 0?v 0 0 0 * 0AV 9 0 0 * 0 -
9 0 0 * 0
Uo-ot . eo *oO g Q ' O9 0 0 * 0 -iOO *0«
AV
AAV 9 0 0 * 0i 9 0 0 * 0
soo *o-S O O ' C -Av—^orr^"
00 WO0 90J *0AY ToF*!r 900 *0 -
900/0^AV TbO*UH;"^\ t/bo 'o-0 ^00 *0-AV
f r O O - 0AV-.*>AV^
AVt\#
AV0^AV^25AV
00
TSAV
^ v o t * oS O T ' 0E O T ' O
-TW-0-£00 *0 -e o o * o -2 0 0 * 0 -
^ 20'0'0*2 0 0 * 0 -8 6 0 - 06 6 0 * 0seo'iS 9 0 * 0S 9 0 * 05 9 0 * 0O O T ' O9 6 0 * 0i 6 0 * 09 6 0 * 00 9 0 * 09 2 T * 08 2 T * 0
2V 0 0 0 * 0AV
LZfQ
I
IIII1II
c>O CO Cr. o Ox *— CD
«ooooooooooo - » oO O O O O O O O O O O O O Q
o o o o oo o o
o o co o oo o oo o oo o o o o o1 1 1
t>o03 03 00O'O Oo o o
<J»-« r-4 'UK*o o oo o o*' • •o o oI I 1
I f
11 1 j '' I I *M l !i - -.
••*I. 3\y\i
\?>\j
III
-0 ,002-0 .002-0 .002
0 . 0 0 00 . 0 5 60 , 0 5 50 . 0 5 60 .0500 . 0 9 80 . 0 9 90 . 0 9 80 . 1 0 00 * 0 7 30 . 0 7 0 '0 . 0 7 1
AV !
AZ 1
AVsi ;cCAVS2lA->"*-'AV
0 . 0 2 70 . 0 2 7
&*-AV
• 0 . 0 0 0• 0 * 0 0 1
"0. _QOQ0 . 0 5 4
• 0 . 0 5 5 b^0 . 0 5 5 , .AV0 . 0 2 60 . 0 2 6 CO
. 0 * 0 2 6 , A V-o .ooo V- 0 * 0 0 1 AV
0 . 5 3 50 . 5 3 30 . 5 3 4
M/ 0 . 0 0 0cJ 0 . 2 7 1
-T 0 . 2 5 5f 0 .263
0 . 0 5 0xc^ 0 * 0 9 7^ 0 . 0 9 87 0 . 0 9 8
0 . 1 0 0< 0 . 0 6 9
0 . 0 7 00 . 0 7 00 . 0 2 60 . 0 2 60 . 0 2 6
-0 .000- 0 , 0 0 0"0 .000
0 . 0 4 10 , 0 4 1fL .04t0 , 0 2 50 , 0 2 5— ii®2^_0 * 0 2 70 . 0 2 60 . 0 2 60 . 0 2 10 , 0 2 1
0 , 0 1 7-JUOilL" 0 . 0 0 0- 0 . 0 0 0 {-^Qjjuija-
0 . 0 2 50 . 0 2 6 i6 * 0 2 60 . 0 1 8
J » »0 1S^*VAaAJjtUl*tttqiillf| - f lAA
\f W \f *9 *F
^;'.; 0 *040 V• Jilil l0 , 0 3 20 .033
0 .039 *r . 0 . 0 3 9
0 *035 •0 .034 ^0 .03d
AVAZ
AVSICCAVS2
£$AV
cOAV* i Vd>^
. AVid3
TTAV'AV/^AV
^V\AV
,A/^^iAV
CV), . AVi^AV
S.-5*AV
AV1^i* -AV_1yAV
0 . 0 0 00 . 0 0 00 . 0 0 0o .oqo0 . 0 4 90 . 0 4 9
0 . 0 9 90 . 0 9 70 . 0 9 80 . 1 0 00 . 0 7 10 . 0 6 90. .070,
^ .0250 . 0 2 6
AVA2
AV51CCAV52
AV
- 0 . 0 0 1-0 .00 1_-_Q.O_01
0 .0300 . 0 2 9
' AV. \o^ CM, AV ^4 °^ o
AV0 . 0 3 10 . 0 2 90 . 0 3 10 * 0 3 00.0_3_ 1 .
5AV
- AV0 . 0 4 60 . 0 4 5O.Q4.5-0 . 0 4 10 . 0 3 6
1AV
AV• 0 . 0 0 1' 0 . 0 0 10.02$0 . 0 2 60 . 0 2 5
AV
AV
I /
AV220 *02 2 0 * 0
AV 9 2 0 * 0L 0 2 0 * 0820JLQ-6 0 0 * 0
^ 6 0 0 * 06 0 0 * 0
AV 0 1 0 * 0£~ U Q * 0
* • Q I O * Q
AV^ 4 0 0 * 01 0 0 - 01 0 0 * 0
9 1 0 * 09 1 0 * 01 1 0 * 0
AV
A V
o^'|Qro-g AVIX) (0n\ AV
(TT2SAV
D0
IS
0 0 0 * 0 -J 0 0 0 * 0 -
0 0 0 * 0 -0 0 0 * 00 0 0 * 0 -1 2 0 * 0120 *08 2 0 * 02 1 0 * 02 1 0 * 00 0 1 * 06 6 0 * 0I O I - Q8 6 0 * 0o s o * o6 1 2 * 0
z v 0 0 0 * 0AV e * g * o
A V 0 0 0 * 00 0 0 * 0 -J}QJLAV ScOn-D 520
AV
AAA,_g.JO^_0,
r*23AV
0Q
ISAV
ZVAV
7 S 1 0 * 00 0 1 * 0V O I ' OV 0 l * 0fO l 'O0 9 0 * 0on * o6 9 1 * 02 1 1 * 00 0 0 * 0S 8 2 ' 0S 8 2 * 0S B 2 * 0
AV
AV
AV
AV
AV
1 1 0 * 0inrs^o"0 0 0 * 00 0 0 * 0O O Q Q0 0 0 * 0
A V
9 1 0 * 0S I O ' Ono *oworn0 0 0 * 0 -0 0 0 * 0 -9 2 0 * 0S 2 0 * 09 2 0 * 0
AVt
AV
AV
2 0 0 * 0_ IPO*Q1 0 0 * 01 0 0 * 01 0 0 * 09 0 0 * 01 0 0 * 09 0 0 * 09 2 0 * 0220^0-
AV k 000"T-,\9d 0 0 0 * 0
0 0 0 * 0AV r^00^0"
0 0 0 * 0
1 2 0 * 0AVVt^2SAV
00
ISAV
ZVAy
2 Z . O * 02 1 0 * 0U0 *00 0 1 * 06 6 0 * 06 6 0 * 06 6 0 * 0O S O ' OS I Z ' O1 ^ 1 2 * 09 1 2 * 00 0 0 * 0S 6 2 ' 0S 6 2 * 09 6 2 * 0
IIIIIII
:V>f\
IIIII
o o oo o oro l\i re[CJ IV C*J
f I ro o c* » •o o o0 0 0
t I Io o o• • •O O O]O O
— fvj
o o o* • •0 0 0re re re*£> \O CD
t [ to o o• ft *0 0 0o o o
o o o» • *o o occ •—
o o o* • *ooo oa: o> CD
o o cr• • •o o co o oJro re
O O O» * »o o c.o o oO O O» * *O O O;W CA> CJO:i 02 -4
o o oO O C'c o o
o oo o o10 O O
o o o• • •0 0 0OJ CO £>o -j. o
<t>
o o o o o o o o o o o o o o, 0 0 0o o
—_ > c. C.1 >CS,. <.
cr. «— oO (A
en on
> >
I t Io o c?* ft •o o oo c. oC' O O
o o o• • •o o c;H- •«• O
>c
o o o o a-lo o oI t 1o o o o o o o
c cr, o-j -4 -J Cro rsj •— C
O c oU. &c> en
O o o oo c c:o o o o
[si <:
|o o o• * •o o oC*> U CO
oc/
o o oo o oco cu c*>en -j en
o o oo o oro ro
o o o* * •o o o01 a»Ca
o o o1
!O O Ocn enO Oo o oo o o.000
o o o, 000
n o o• • •0 0 0en CT> —i
o o o* • »r o o
CD a> :!_
O O Oo o o
o o o• * •o o o(CO GJ to
I I 1o o o.» « *poopoop o o
o o oo o o'o o o(o o o
o o oO
O O Q O O O O O O O O O O O oo o o •— o to re
> O O
o co ro.
rs: <
0 0 7 2 6 8
o o o o o
0 0 7 2 6 9
ooo* » *o o o *-O Cf> O
o o o o oo o o
o o* »o oO O O00 O
PO- O O O O O C O O
> O O
! f io o o1
• • • i0 0 0o o oto ro ro
O'O O1
» * •o o o^- *- o
o o o o o o o o o o o o o o o» * •• * J> » * * * * * * * ^ *O O O ' — O O O O O O O O O O Oen O —J o *o xO u s t/r cn t n t n
o o o• » *So o o
_ >0r=. -c O X o o
ooo» *o oooo• • •oooo>
o o o• * • ;oooen tn CT> Uj
ooo* * •ooo
V
L_L0 0 7 2 7 0
i.3 O 0 O (
Ci? C&
O O O O
V® CD G> CD CD CD GI O G1 G" CD G* G1 CD CD
CD CDG1 CD; co o:« K" -• ^- CDCD CD G* CDi— t-'- CDO G>
01 or r_<r<^. c
C3 O Q CD
c: c. c:r^ F
CC' CO M O *— CO lsO CDI O O «.r* I> 3>
---I
CD1
O
I 1 IO E' G' Gt CD* G» *— G' CD C3 CD CD G' CD
Cfl f-1CO CD
K« 3> O O
X'i5
C O O O O
"25 O
C& CD COCOCDCD
CD CO'CJO CS> E« dCJ CD 3 CD G" Ev CD
CD G« G'• » •C" G' CDCD' CD CD
C& Gf CD CD G-• * I * * "CD G' Gl CD GI CDCD G-liEi O C-I'>— to >—Iro w to* CD G'
> J
\z\ CDCD CDCD CD CD
CD GI G'O G* CDCD G' CD
IB iCT>
£ c.
O O j
"S> t-tl *• C/lco co eo coO toto Z- T--
I
0 0 7 2 7 1
I
0 0 0 ' 0600 '0008 :0
oo-JIV)-Jro
0 I 0 " 0O T 0 ' 00 I 0 ' 0
0^0 '0
ss soreny t-0i *0
000 '1?000 ' 0-000 '0-
IIIIIIIIII
AH 6DQ ' ©- •"• *• • • • •-— --'
... • ' -' ~ •' - '-.•**-—• '«. - . .... , ^
. : - ———— . ,.„.. _ , „ . . . . . ._ __ _^ — " • - - - - •• - _ ———— _ _ _ . . . . . . . . ,^,.. I | E . , , _ , , . . , , " • " - - • • - - • - - - .
~ - - _ . ' - --- - .
AH 000-0j < n T60 '0"^ 000-0-
A H 1 1 0 * 0< S n0 '0I T 9 ' 0
AH 1 0 0 - 0 r 'H 0 I y ' 0icn 0^ *0 L e^*s~f'y IRf i -P i 0 I 0 ' 0AH'": 'ty'y ' AH 0 t o ' 0
?t ^0- t3 0 T 0 ' 0rt^S 0 2 0 - 0 $ 0 T 0 - 0
T ^ 0 ' 9 G I0 "0° S3 0 9 T - 0 ' - r ' y 0 T 0 ' 6O AH £ 0 1 - 0 ^ 0 1 0 * 0p- j 0 t 0 T ' 9 " AH 100-0 'V IS 0 S 0 - 0 ^;CO T 6 0 - 0"^ AH ren- f l 1 0 0 - 0V^ 2-tl 'fl ^^ ?^r' '0A "^T S O ' 0 ' J 5 ^ 0 • 0
AH 1 0 0 * 0 f [^ 0^0"'0f f i P ' -Q fl^f*5 f '^f ' *01 0 0 - 0 6 3 0 ' 0
AH 600"' 0 " * £ 0 0 T " 0-^/ € 0 0 ' 0 nH -^'0
| 6 0 0 * 0 T s 0S0 '666R' f i r t H 0 S Q - 0AH 9 t -0 '0 I f i0 '0_
S f70 '0 2H 0 0 0 - 0AH 000 ' 0-
800 '0-0 0 0 - 0
0 0 T 0 - 9- - 680 '0
AH 0 T 0 ' 0# 0 10 -0 C 'ntTTTF^ :-- - . . . . ^ 6 0 0 - 0 - i :- - _ ,.._ _ j7 Jigis_ * '
-•• - ^y"^n^T*~ "r-- •—0 S 0 " 0
AH £ 6 0 - 0 C"^ | S 0 0 ' 0
if? -J@0 *0 ,,AH FPTT0 " C
A3 9^0 'A?i?r *0 cAH1 "000^™
_,/g3 009-3-^ 0 0 0 ' 0AH tyy '0
^ . J £60-0//^ £ 00 *0
AH 800 ' S < _ .^€ 600 '0
860 '0AH 300 B f l^ » S00 '0
3 0 0 - 0AH 6 6 0 - 0| 300'0
6 0 0 * 0AH 0c ;0-g^0Cfl-qAH 0 0 0 - 0 ^
-^|P 009 *0 -000 "0AH 5 ^0 *0 ^St-0'y \ (
AH U O - 0 0'(pi-5 3^.0 '0 7
0 ^ 0 * 0 B^SS 0 0 1 * 0 ^AH £ 0 T ' 0 A"
•t —— - * ^.\i ^(yi T * tt \ * '
IS 0 S 0 * 0 (AH S S T ' 0 A
J S T ' Ocsre vfAZH 009 "0 Ai ^r (y T 1 0 - 0 - AT T 0 - 0 -
i•!•BB"B•iiiiiiiiiiii
I1I1111111
.
1 1
- r r ? ? - O . O G 3I* • W 1 V t -m -s. i r*~f, -J-? - G . J 0 3™ t • 0 c o ,. c r /- - * .1 . G ' 0 • >> 0 « u 0 Ui r *i tV c ' c c 3 yl/ o .ob i! t ' ! . 1 , O . U C 3 : A^ 0 . 0 4 9
• V f ! n s n T ' t i U O ° ! ^ ° -0 5 lJ<N\^ \ 06? c ° 'U 9 ' \^\ C * ° 6 5
' oV o'odl c yV ° ' I 2 b ^ l \* ° ' 0 8 5
; *$</ V ' ° d ? C
f A^u* O . O b G 1 ^ 0 . 1 0 0' *3 r HP " vxO^ f c . U b S C 0 . 0 7 1
.^ ^ j??S^ ^ 0 C . : c l t ^^£72^r\ ' 1 . J / o J y rtj-r . . _ T^ ,"^ 'H> v r i ^^ A0^ t * l u j L O . u ^ OA^ f * n?f i C ° V- C ' u 7 4 ^ ^ - G 2 7. V$ _ k » U 2 G \ r f,0 3™1 —7 — ^T-r-V T T i -. > L * 0 0 ' J _ - U * u G ^
, 5nnC6iK- <stf C . C 2 5 . 1 - 0 . 0 0 2l ' O U O XT r lot ; CU ' 7 n A g"r i 1 1 " i/ " u . J 2 b C . O a ^-C . 0 0 1 y>A(K- y —— -T-?^ — /- ^- f t * ^ o . U C O ^A, |6. 0 . 0 4 7" u . O u O . ;ii C^ 1 ' "7™ r > fi^7^77 — ' ^ *.^,V.Q., 0 * u ? 6u!«e i0 • ° - < J ° t ' e.^!16 -j6^2^-•~; — r^ — ' L . O O C - o . o o o .:" 'rn 1 ' L > 0 2 9 LCi c ' 0 0 0 l" • U * u U l r - « c j- O . u U l . , 9 , i i n. ,- r . IC- t * 0 0 0 ^- 0 . 0 0 1 - rw r ^ '— ' ——— ~ T "* -• t. • UUjj^
^ " " ' coo ^ ~rrJloiA-> -.T,y,t pOU . i t . ( . r n=i-'.0 , . . . t . U O O-W U * u ^ J r v } f i , r0- t IOK C^ b * G O O Ti.ff . _ 0 . 0 ^ o S 1W . , , ,, L . 0 0 1 |- u . u LU ^((C, t . 'G2b , v !-c_,oa.a . f n,. o> 1.. .T, , vr L . U^a [——JSL?4 . T l>"6
f n n7 C . U U 1 , , /-0. 00 1 i - r •- i .isifii- r ' i r V43 -^w^ 4i i-i O f A r- i ' i 0 * J U 1 ,>" - ^ , . .00 1 . ' r nrt 57> f -ifi i , -^&£_L^\P J u-^i /A u . c o i /~?^- c.ooi >
7'n?" ^*^l T"r'n^ C . O O L - '0 * 0 0 u — j — ?r T^ tO . C 5 3 ^ ^? ^0 * 0 5 3 - U 'U ° 'C . C 5 0 I0 . ^ 8 4 C iG . C G O C . __________ , ;o . i o o E :.-. -•:,^^ .H 7" " l""r' ——— ^r:" •" • ' ~ rrrr*- — i0 . 0 7 3 ^^ . ____£^." Vli_.J ____ £^ :" :-^,,,T"; :/'^' ' ' | !
G . G 2 6 . .^J1 IL21 ' ' ~~" """" — ~"~~
ICC to
3WCOJ
C6J 16 ^J-1* ^§5 CMco r-•*• t — JBI*- 0
0 . 0 0 1
I
IIIIII
C - 0 0 20 * 0 0 2U . 0 5 G
mcvoo
I
I
I
0 . 0 0 30 . 0 0 2C * OCOt . 2 7 30 . 2 B 9C. I 00 IG . 2 3 9 C0 . 2 0 0 t
lJJJL2_sU5
0 . 0 4 ^ . ,
- O . O u l
.0 . u49_• 0 . 0 0 1' L . 0 (, 0( . . 0 0 0
0 . 0 0 1p_^.0_U3
• 0 * J 1 4 &• O . U U 2• C . . C 0 30. 1 JUG_. 1 3_4O . O d ?
. 00 j
_CJ. 034• 0 * G U 4• 0 . 0 0 3C . 0 0 0C . 0 9 6O . O S 40 , 1 0 00 . 2 6 20 . 2 0 00 . 1 5 4
C ; * 0 6 0
3 \9&>XYv
- 0 * 0 0 4- 0 . 0 0 5
G . O G CG . 2 1 30 . 1 0 0 I <JG * 2 B a C JL* • 2o 1 C Ot . 2CC L0 . 1 3 J in v* (^f- i c -> yrts yC . 0 b 6 j, .-• t .-. *-\, • V •> V __
- O . U 0 3 ^|t.- 0 . 0 0 5t • J^D P^il^-0 . 01 g _ '.0 * 0 5 - 10 . 0 5 5 ^ C b
O . C 0 10 . 0 0 3 ^
0 * 0 1 0 ^C . 0 5 6 ^ J« c ; . o 54 „- c . o uo ri*j|iL" o . og_L.C . O l 1 jC . U O & . '
0 . 0 0 3 50 * 0 0 4 ,O . U U b ^6% b o / _0 . 0 0 6 '" t . oo i " SO . G O I ^
- 0 . 0 0 1- U . 0 0 3
U . Q O Ot , 126 CC . U 7 CC. lUu 10 . 2 2 8 C "^ • ^ <J J u0 . 1 3 5 i ^0 * 0 4 5 ,-.1
0 . 0 0 1 ,- | \(~J''*r;QjJr \Oo , u f c 3 C's r-il LU* CM
—— ;"~ —— - ———— •* r~)0 . 0 0 2-u cfnCjfo^ o
C . 0 0 3
IIIII
III
0 . 0 7 00 . 0 6 4
t . o e iC * C 5 5
O . U 6 5 \" Got
r-CMoo
IIIIIIIIIII
V
t . u b7 - . jj •* f C ^*0. u b f c ^G . G
- G * C C 1 _- G * 0 u 3^ti^GOST7ob9 Lc0 * 0 p 4 - -
b . 0 0 3 jj^USiil—*- G% 0 G 3 £^G..,O.OA_J
0 . 0 1 3_£*^1Z-
U . U & 4 f t )(. V__b.*j36Z-- G . O u l- G . O J b .
L * 07u is.• G . 0 0 1 |•G_._Jj)3^.•u * 0 u8 \0• u . 0 09 _0 .051 | 5A. q5A_JO . U 0 2C . 0 0 1C o O u O0 . 0 4 3U . Q 4 9G . C 5 0C. 1UO CC. 101 CG . 1 0 CG . O G 9C . O b B0 . 0 6 2 V
• 0 . 0 0 1• G . U G Q
CO
^.^\yV)M>
X&
V*
• G . O G 6• C . 0 0 7C * 0 0 00 . 1 1 0G.I Uu . 0 5 0
C 9 20 9 61 OC0 6 9
tC
LP0.0 TjJ*t . O b f c \
0 . 0 6 & V :
l .U i *0 . 0 4 2
C . J 0 20 . 0 0 1C ,0000 . 0 4 6G . G 4 7o « 0 5 0o * o * e0* luu0 . 0 7 6G . 0 7 1
cJ• 00
C * u 7 lu . u65
10 . 0 D J
COr-CMh-oo
6 13 100
O O 3o ON O
'"> 0/0 o]
O
o
0 8 2 1 0 0
r\ . ,--;-
J J J J j J J J/J
IIIIII
oo-Jro
IIIIIIIIII
NO. 3807108 REV. 8
QUALITY CONTROL SAMPLES
1) KBS 164352) Trace Metal 3 - WP5813) Trace Metal 3 - WP4754) Minerals 2 - WP8S25) £P Extract Metals - WP2836) Trace Metal 2 - WP4S17) Munic ipal Digested Sludge - 9768) Trace Metal III - WP5819} Tin Standard; 1000 ppm - American Scientif ic Products
10) £P Extract Metals 3 - WP 233 at 10 dilution11) Trace Metals 1 - WP 284 * I "12) Trace Metals 2 - WP 284 - I13) Trace Metals 2 - WP 1183-2
*143 Trace Metals - WP 378-13
COCMr-oo
WRITTENAPPROVED /> APAGE 1 OF
OA
I-
I PERK N-ELMgR CHART NO. 056-7300 i : r r
PERKJN.TEI CHART NO. 056-7300
IIII
I
r-cx^CMr-o
IIIIIIIIIII
*x%ew2
*-2
33CD
CM
OO
IIIII
rNO. 056-7300
IIIIIIII sow
BEBK
OsJ
oo
Li
tuC
Or *>
0 o Z 1 0 0
ITr
a i i i
J_L 5) 7D
COoo
I C O n
;t0 0 7 2 9 1
L
i i t
1
ao 0 7
oo
•-o
——
I"*"
_
-4—
— t— >*
— vr/
Vljb /\ Vk ,y- *c\f\;?
X*
^•,, ^rt\
•4^Vr'
(^\rSJl^y\V
_
y-V"- "-rr-,(,:\ L.I~T
zEh=tt
r/i- - •-— /SwvJ's
90 ON .lyvHo 6J31A
[""
ri3~~i
- — •— —
-"" * r—
— j
^J >!fcJ^
TT]
Jci
-
1
-
-
_
-
.BH
MHH
E 1! I1 Ii IE 1= 1
BIi I- •1i 1r I
1i
- - •
. . . . . .
oo•^ 11
ro —\o — -4-2>
(\353
•
•^~iH?. "N\\f
** T
\1
./"J"
T-*v
*"
-t?'V->,r-p/\\tjr./
y/
A.
ff
-v—iV-\
(I
T^*-K
j~
^pvlA-*J
- ,
ff
-,\ \\W
'
—
V\"
'
•
1
i
1
-
1
—
i j.«-
^j'- — J ——
i '
i'
t' *
-S—
"C
<i
<u
"J"C
c•*
L
-c
-€
!-•
=)3
313'
\
H
>Lt
iJ
i.a
si
JJ
it*J
-—UJ
4^(_J
CTts-J
0?O
-*-^CJ
GCC
7j*a
a
— i
1 1
(
^^—
1
1
B1B—— •
= I1
^_•HHI
i••
' 1•
I- •
, i•1iB
ii
IIIII
I(AONCMr-OO
L . L: v_- L t ;. u L L L L L
/^ i™\ ~*i n "1
Z3O
o Ho
,.* u
CHART 159-1003
3d
^r
I
II
u -j _i
IIIIIII
1I
sitv£ £ >j
m tr
i
<Jv3 ffi
eooi-esi
~n
I
Oo-Jro\oCD
iii
ii
IIIIII
CHART NO. 056-7300
iIIIII
o
O3
OD
--O,
.to
.o.
-.©.
jO_
s-
CD
~ v^
* C\Jr-oo
Z3
"CT
IICD
1
•crCc
!I
2m
l
01
n 4) 5) ( 0ice 9) 5) 23
0 0 7 3 0 1
III
II
I
9X -—tJfJ.
_J
CVo
oo
£ 0 f L 0 0
0 £ 100
0 £ 100
• HHa
90k LOO
CDU3
0 0 7 3 0 7
6 0 2 1 0 0
0 IP £ L 0 0
IIIIIII1
r r r r
I
3£ ??
r-oo
rCHART NO. 056-7300
iiiiiiiiiii
CM
oo
IH Accu-Labs Research, Inc. p 7 0 1 9 Rev. FHGA Analytical Spikes
• Element: xi-p Procedure No. $$Q1 <3G *j Date: 7/3 l$b Time %: Q fya^^Wavelength: <?,'7 6 1™ BG BIP PE 5000 Ho. 82067 «— •- Analyst; £ l<f-Matrix Mc-difier: PE 603 No. S2034 I. D.L. : £>.OO$ (-ooy^A
• Water <^- Soil i^- Other PE S Q Q O Z No, 8 2 1 4 3 Paqe ) of /•
• Date Prsoared: 7/6STANDARDS (pn^O
/?£ Ptepared by: _J^/^ ___ , _ _ _
" initial_ Calibration Blank O.OOOB Standard 1 O -Q$0 abs " O'//V• Standard 2 O./OV
Standard 2: ( O-O*|O ) O-Ob? * ~ 97
!
F-ecalibration Final&-OOOD.OSOO-/OVO-Q&S * "" 9^ % -
1 - Sample Avg. ^Sample Cone. Dilution Reading Reading Cone*
I S am o l e Number Dilution <<2£*O Factor 1 2 ^JSL£x^ % Rec. ^~Initial Cilib.Calib. VerificationCalib. Blank
I LCS&;? -60 £/ - /
- /£
1 ™ .. .„ .„.„-£ .. ,~fo 3 * 6» O 7 3 - /caiib. BlankCalib. Verification
x ' *xV
V/ •O;.o/-6>/.o
_ .-7.fi.,™.-. . . . J( '- .- -X
• ^3-6^V,3 •/ £ . 1 /.(/t7\C $>. . .. .-. _ .. . . . . . .
|-*?£——— rf —— |
Recalibrar^on
1Calib. VerificationCalib. Bla-k(03 -6OVJ * V
- 1 . . , . .., -r __ "7
*-^
1 Calib. BlankCalib. Verification
H•
1 Final CalibrationCalib* VerificationCalib. Blank
._. y-.Q . .t-ohO
...„/..<>_ .X)(
X_ _ / £ > . _ .
/•t>/•o/ .01 -i>
XV
X
YX
O./oV<0-^,T{Q.QQ£<. OiOO^"^O-Oo^"
YV
<€>.OO^
X„. /.p.#« '3^ 1A
_ .3. . . . .a,3b./bl %^o>oot>•^O'O/ys'^o -oo5"
X\*<0-OO^^c>'OoS
^O'O55"^O-^O^i"t o .000"•cv:
X
55.=3
X//a. A , __.3rt(A
, / -
X
XO-/O//). OOOO1 '07£ . £ >6>-vO O6»^5O-070(9-6>VfoO-^oo0,/Od)0<9V4?0-/^5
X 1 ' 'XQ.JOO O.toiO>O&O -<O-O03~0.//.0. \O_2n&.O&>3 1 O-IZtfQ.Olpp \ 0-/3&f^.O^I 1 O'O9dO'OvoO-O9^o,o*/yO-/O2..^.05? 1 0.0,5^£ ) £ >g^
0-051X^ , ^97
o.ooo
0-OS1 .X
0.'0<M..b-o$i O-O5VO'O^^ o.o*jtL0-OS5 O-OStLo-o5& O-O5&b-oss o-c&'i0 .000 O-oooO'O^S 0-O9^
X X
I
<Q,QO£t?-<^9?^ ,05"^0«2i£*Q.ttk
x f '/(jo r-o?*y.- /->V.i-'
/O7//,5759?'yzL9397. _ „_
6-tH5 !96O*/^>3 ! 5*6.
X 1 XO-O9 7<VX6£6~i>v^^•£>97^ ./^5"OJO*f
j2-dM?L-<Q'Qo£0-07?
9^S^^/5' 79 /97
1
T
X X
H LCS and Calibration Verification: J§>P/3 //^3*3T ^ 5- True Value: Q,/til {&&>r^}CHDL: (00
m comments :( &pA ) Spike - 2 x CRD^
AnalystQ .C . Apj
«,„. , . ,„„.. , ,„. , ,„. . .
Checked : j& /r Date^7
/ »
nroved: /•' (^ bate: "il^{^(,
--ll
IIAccu-labs Research , Inc. HGA Ana ly t i ca l Spikes.E lement : Procedure No. Date:
7019 Rev . E
Time•Wavelength: /93 .~? nm BG fa"Matrix Modi Her: W, K)O-JWater ts $oi 1 ^ Otheri Date Prepared :__^_/,
1 . _ _ . . . . _ . . _ . _ . . . . . . . in iCal ibrat ion blank OQOO
D PE STP£ 6fc
iDO No. 9203 No. 320o7 tx- Analys t : ^^4- r
34 I .O . L . : o-ooj- t«<^^J^age ( of '\STANDARDS (^r— 5 . .30/^6 Prepared by: & rt-
t ' iaT" "'^ ' " '""•" •"•" ™"™ -. Standard 1 O,0$t> abs a 0-263• standard 2 O>/OO
• standard 3: (0-0^6 ^ D -070
B - SampleSample Number Di lut ion
— . Initial talib.• Cal ib . Ver if i cat ion™ Ca l i b . 8 lan<
LCS
I (*$.I*02L~ 1-i£. . . . . . . . . _ : £
1 <r3-bo43.* ICal i b . B lan<
x' T '""XAO ™/•o _
. . . _ . A . O . . . _/ •O
.* a_/00
ueca n bran on | Mna lO.Qodo.o^oO-/000.01O % = /Ot) % =
Sample Avg.Cone. Di lut ion Reading Reading Cone,(oo/yxl Factor 1 2 fc^ % Rec.TX " " 'n "" '" " '
Vv:
.^ •6>^VO-OO/o0,001<ro.0o6"/.b ! <o,oo3
Y >
XAC)AO
_ . . AO... , AO, . ™. T , ,../.'-t> ,„ .
. _ . . / • .0,...,_,,,,^CL ,/ • O
XO-O^6>. o.c » i. t>, < >v/ ._.0,A>«. . .
0-0.47. a,o? / „.d.O'fO-ooo
X i ' "™O.O3.G 6.CA(f.O.OOO SO>Oo£.O.O4 1 0.041_O-03.5 0-OJL5O.OZfo 0-OZb
_0-03-[ Q.02I\. o-o n o,o/gO-OOO <0<OO&
X_j2k^~$5~95
V5LZ^5-_90
i
US and Cal ibrat ion Verification:^ p A) Spike - 2 x CROU
& I True Value:CRDL:Comments: Analyst Checked^Q.C . Approved:^ " Date
"oo
I• Wavelength: £ £3.3"Matrix MOdiher: /vM-jM,
nn BG R j> PE 5UQQ No. 820oru^ Analyst:POc/ * AU/UO-* PE 603 No. 33034" ———— I .O .L . :Water ^ son ^ other °
-JLtf " ' •^•C*t>tT \(Lfr^\Page / of /
I STANDARDS (frz^J , :, r : : JDate Prepared: ^ t3LSl$(* Prepared by: ,&/<
I n i t i a fCalibration Blank 0.000. standard 1 M$v abs = tf.A5/I standard 2 ft.tcn)
•standard 3: ( o-o70 ) o-o70 « */c*f
Keca i ibrat ton h i na iO-OOO f)'0^*^0-050 0-050o./^n) o-/ooo-o^ % - 99 o-ob0! * - 99
( Sample Avg.Sample Cone. Dilution Reading Reading Cone.
Sample Number Dilution feoO Factor 1 2 (tarJ % Rec._ Initial tah'b.I Calib. Verif icat ion™ Cal ib . BlinkLCS " In ' '
w<? * B^O <3 / • /
- 2• Cal ib . 'Blankj Ca l i b . Ver i f i ca t ion
B b3 - bOid - (ft.1 ^/^ <^B / *1 L- ^H A Jt / >\ ^y 3 *}
~CT p.
I ^^^J?Recai ibrationCal ib . Verif cation
ICalifa. BlarK63 - 6Oy3 - V
»J
'" C^
1 - 7-"£talib. Blank
I taTib. Ver i f i ca t i on65-6oy3 - ^-PJ^.
ffl ** "**• ""^-7Final Calibration
1 Calib. Verificationtaltb. Blank
XyV/.oJ<O/•£)/-o/.oXVI-O/•o
y. it)/6>A6>
Xyx/-6>/•O/ •O/-O
.7 -0 . . .VV
/O/o. . - / » „ . . ./tf"" 1C" '
Vx0-o38<0'Oo-5^<"0-OCXS"0 . Ool?-;o.oo5"
VX"
< 0'O£6~0-^3^O-O7^-005^(p-Oto^
Xvx
^,O«59O-OSfoO Ol3-O-O3(0O-O^^y)C
o-oo?0,006O-OO?O.OOGp-oo-yx ^.
X/•O/•o/V)/./)/-O_ /-o . _.1-01$i 0
/'O/.o/•d/•O""" '4' • • • " •//o . ./•oAOAC
.- .,/•{?. ,.,.,/•oy-oy-p,,,, / ( ) . .^HiM'/D
/O
— r
XO-QVOO'OOOf) .Q4/Q0-O/&.&.O/3o-on0-00*10-ood
0.0-VOO-OoS0-QSOd.on-yO- Oh3O-O 73
Xo oyoOooOO-O&30-03*?
O.O3Jo-oyo0-O500-ObO.o-oioo.onO-O/bO-O IbO -Ol 1Q-O/$1 X
X id-o^oo-oodO-oV?O-O/5LO.-Q/J!O-.o \ $O-OO9
_Q -Q00_>^yo. „.. -os^>
<3-O?VO-ObjL0-0? /"' X ' 'O'C?39O'GQOO-o&lL003-1o oal0-0 3^O-OcJO
O-OOt)O-oY^o-o/i0 O75"^ . o/&(?-o/7"T" im
I VAt?-oyy<o.oos*o.oV9O-D/^tO'cya0-O/5*O,oo?•tO'605o/oyoO-Oc?^(^•OC>OQ-O7</O.Ofo.3Q-07J
XO.oVo/o.ooS'0-Ofc<3-0-0*^5D-O.2/c>-o390-05O<t)-0^5"o-^y^0-0/7' 0-016Q4.tt> .oonQAIS'X " '
X93no
/<3.QAJOloo9093^ o . _ .
//O^o ^evo M,^o — x —?J^o/^9f)9 o
cJO <2^//o93IOU9090//O
'/OX
«)LCS and Calibration Verification; faffi d-S^-X Hi True Value: O, £>*/*> la^^JCROL: 5 (o/ib )
fl Comments:Spike - 2 x CRDL
•Analyst Checked: h{j Date: 6/ttVH
in
oo
.•/ft.Q.C. Approved:
IIIIII
Accu™r>ass Kesearch, ^
Element: :^__Wavelength:___Matrix Modifier:Water
HGA Analytical Spikes
procedure No.nm SOOO No . 82067
603 No. 82024
F 70 19 Rev. F
:^./°?/y(;_ Tine _ . _/ • ' ' • > S'g.
Otber___ Analyst \_
_______ I, O.L. : ..PS 50002 No, 82143^ _ _ Page / of /
Date Prepared; Prepared by:
calibration BlankStandard 1Standard 2
Standard 3: ( 0-O10 >
Initial0.O00O'OtfD abs =» 0,A512jO'toO,.0-02,1 , ,V? /£/
Recalibrationp -0000-O5DO'/OOO-O70 % = /OO
Final0'O0£f0.0<5~O0./0Ot>-O"M % = /0j
Samole Number
Sample Avg,Sample Cone. Dilution Reading Reading Cone.
Dilution (Q&v^b Factor 1 2 (QAv^> % Rec,Initial Calib.Calib. VerificationCalib. BlankLCS(2^ • k>03- f •* /-/ £^3 bO^/3 • ICalib. Blank iCalib. Verification63-6i9</J - /^^563-6O-Y$ • ,5-^^, i
-3RecalibrationCalib . VerificationCalib. Blank6 3 -6oV3 - V
-5^-i>-'J-J
Calib, BlankCalib. Verificationb3'{0 0*V 3 - /
~/£
Final CalibrationCalib* VerificationCalib. Blank
XyV/.O1-01-0/•oA0yt
/ •O/Oy.oAt)/•O
XVy/. £ >/-o
__ A.O. .
/•OKY
_../_0.._.t "
X- -V . . . . . .
V
' xc •
XO-oVD<"0-oa5"<O'OO$<O'OO6'<6-oc)3'X
V
o.o-v/^Q-OG^T•^O-OO-S•(O.OD-5
XVV
<0-O06<O-Oo£<0-OO&<0'OO5'<0'Oo6
Vy
<0'OO5"•(Q-OV'5
XX
X
X/•£>/•O. ./a . ./•£ >/•(L>/• 0_/ .o ./•OAD
_ _. /,0 . .. . ./ • (?A 6>/ .0X/-oho
-J-0 .- -
I-O/-o n
/ •o ./ • o/.o1010
X/.o/ i)
Xtf.O-S'50-^00(p. 0500-00? .0-00$a f*Vt P• Cxv/o
f) 'OO 30-O£ >O0 -Orfb0.003/)-Q$O0 -O/Oo.-o/o. _0-0 /d)
XO-O*/(yO-oot .O '0/0 _O-O/O ...0.010 -o-o/oO.o/lO.OQOi^oV5
O-oo 7.0 -o_0 ?
XO'O-yt?Q...O.OJ-
XO-PV^O-OOoO-oQIO<oo$0-ooS
._ D-.OO1^0,000O -O-*/(y0 -O03O -O£>/0- <?O?
0,0/00-0/0
XD'OV6O -OO 'o.o/oO--0/Qo-o/oo-o/oo-ono-ooj0-o*JbQ^QO^0,06^
X0-OV6
1 O.QOO
i i —0-oy6><0<6t)5^£.,0500-#o7o-ooi?0-co$0.003<O.0030-OV6tP-Oo3O'OSO.0:0/0-0-0/0-6-0./0 __
XO •£>•</£>• O-O^)^o^o/oO-OY£>O-O/C?0.O/Oo-o//<TO'OO^O.O-'J faO-OO^Tto-ooy
X0'(>V(«><Q,VC&
X<2-
/ot)9c)#c.^o/<Lfi
9.3.^£,?o/oo/oo
!O6X
9^/oo/oo
100/oo//o?^9.<)^^
X9 A-
IIIII
LCS and Calibration Verification: &P./Jcr^—
CRPL: __ ___^_________lfU)h J Spike * 2 x CBDI,
True Value:, Q_>O<5O
Comments: Analyst Checked :Q .C . AP pr oved :
Date
IlAcc'j-labs
Element:
, Inc. HGA Analytical SpikesProcedure No. Date:
i'Matrix Mod i f i e r :Water ^-" Sci '
PE 5000 M6T 82067PE 603 Ho. 32034'
jtnerSTANDARDS
Date Prepared: Prepared by:
CaTi"&ration SUnk. Standard I
.itandard iStandard 3: ( &.QIQ J
In i t ia6-000O-O$v> abs -/>./£}?_0,/oO
Reca l i b rauon » Mn < i l6 -0 ^0 io * o :To fn.ioo f
O.Qktf ^ ~ 97 f 0 - O 7 0 % = /t/O 1 % =iSample Numbe*Sample Avg,
Sample Cone . Dilut ion Reading Reading Cone.Di lut ion b/wJ Factor i 2 (OC^L Rec
IIII
in it ial Ca l i b .Cal ib . Verif icat ionCa l i b . BlankLCS " r""" -1""1 ' "/9r? - ($02} ' 1
* "/£* 5-
£3- f e0V3 - /Cal ib . lllanicCa ib. Ver i f i ca t ion^>3 -6^y.3 - JJ^,/Cv5^3-6^JV3- J
"~£-,Skecal ibration
Calib. Verification£ a t i b . O l a n k~5-6
. . . . . . . . .-.7Ca l i b . Blanktahb, verification
Hna i talibrallontall"b'. Ver if icat ionta1i"&7 Blank
X><
AC?I-O/'O/•o1-0
Vyl.O/•o
/'O/•Of'Ox
VV/-c'/•o
1-0I-OI-O\\
It
1 "xVY
.0^031 .<o-oo^<O>OOd^Ot£)O$•^.O'^O^y
Vy<o.ooS0.03$<o>oo&^.O-OO-^<0'OOf>x
XY
<0'#0k5<0'OO^j<O'OO£^O'OO^"<t)'OO_5'
XX
" 'TV'"
X i/.o_ _ _ A L > _ . . . .„,, ,/; .a ,AO»-i)
1.01.0/•oI - O. . . / . oA6
/.D/ . oX
/.OAO
/ •O/.oAOAO
. _ . l-D/ • O/-o
X
X6-OQijQ.QO2O-OV7O - O / Vc J . 0 / 3O'QllO-OaiO>oozo.oai0.0AO0 .0*1$o-o^oo. 0=3.01 1 1 "X "<^-O5^0.006O-O/^O.OIb0-6/Po-on0,0/7<?.O5 3
X
"X 'o-o^^O,(00 /O-t>V7O-OHQ.OI^OOl-fO<O3 10.O&Z0.03.10-O3.0
O-O-/9o o^ao-oa.2< > -OAO
XO>03-^O.OOOo-oc/^ • r t/ '?0.QI9O-OIJ0 61*1o.oooO-O35
X '
-nr—Q^Ab
<OtOQ$\o.oy?o.ot*j0.013Q-o/*L 'd'OAi i<o-oo5iOiOlT0-O5X?(?-o-v?0*OJ.\G-O23.O.oaox0-Oa<f•^0-005"<>..<> ite.o-onO.O/9o-ond,Qt$<o.oo50.0-25
~5t
xwi
IOI).1*. ,.70/05/o^/tro/^5*IO5no/uOT "9^#0^595?590/00
i
LCS and Cal ibrat ion VerificatiQn:^^^CROL:
Tme Value-) SpiJte * Z x CROL
Comments: Analyst Checked:Q .C . Date: li
oo
Accu-Labs ?.esearch, Inc. ' F 7019 Rev. j-HGA Analytical Spikes
In
Element: J^J Procedure No. 3J?#7-2/9 Date: -7/3/^6 Time $.'/5dt^Wavelength: c^V-^ ""* BG6 £ > PE S O O O No. 82067 Analyst: f0 14Matrix Modifier:
1 Water t^ soil *—--"« Date Pi
PE 603 No. 82034 t^-' I .D.L . : <p./DOv5 (^2J2^-/}Other PE 50002 No. 8 2 1 4 3 Page / of /
•spared: 7/5^S (OA»0)
/<?6 Prepared by : ^ fl
* InitialCalibration Blank 0-OOf)
( Standard 1 0./0C) abs =/>.JAc)| i i m i _. ——— . _ ————— ————— _ — — .. — ———— _. . u tf-.\.j. 9
Standard 2 O>3OOStandard 3: ( O - > 50 > O-'Y^- * = 95
Recslibration Final(O-OOO 'O -OOO0-/OO 0-/OO0-200 Ot ^OOft.J*/Q % = 9^ O-^i* % - 9 7
| {Sample Avg.Sample Cone. Dilution Reading Reading Cone. 00
Sanole Number Dilution (pp.vM Factor "1 2 (f?/V^ % Rec. ^• Initial Caiib.• Calib. Verification
Calib. Blank
I LCS6-5- (yOdi~ J
- l£
1 . . . ,„„" «? ! . , . , . . _t> 5 * 6> 0 V3 " /Calib. BlankCalib. Verification
|6>3-f cO <V3- /£ .
tn C, O6 3 -60-^3 - 3
|
-<?£"3
RecalibrationM Calib. Verification• Calib. Blank* t> 3 •£> £ > V3 - V
-51 ^6-7
-S
1Calib. BlankCalib. VerificationL>3 -(zQOl ' I
-/ £
1 Final Calibration -Calib. VerificationCalib. slark
XV
X1-0l.Ot-b
1-0. . . in......yx
„. f-0, - , -„ . . .An/•O. ,_ /-a, . . . . ,
X\V/o/ •O/-o
/•6>/ o>y/o, . , / ( , ? „ „
XVy
1 XV
Xo-oy9•^o-od'T<"O/Ci65^^0-^x5^i)-C»3 6
X)t^o-oo?'O-QS^<QCQ$'<o<oo$o-o/o
X. V*
O-^D^^j.oo^'-^0-006"#-C>o6< O'O$S
V-M
<O-Ot>^^O-CD6'
XVV
X 1Ac)
....^.-•(? ,„-///
, .1 , ,„,/
X 1 X
O-0&O0-1310,0/7 _
. . 0-0/6/. . . .O-oY/9o^joO
O-OV-50'/7< ^O-/3 7
, Q.Ql? ,0.01*3
l lx^)OV7<o.oo5
_O-/3O0-01?0-0/6
O-O79 tO-075QO*{to 00^1o-woo(5-O63 1 o-oYS*
/ "1 O-oY7/ 1 0-/3-5j 1
. . . / , . ,„„x/
/j/
-,, / - , , -///to
. . . . IQ.
X. . . . AO
O-o 5V^>-o650-070xO-O55O-003D-06 /h-oiol0.08*70-Ob60-076O-OO3
_j)-Ofc /o-o^50-O7L
X0-052.
o-o-y.*)O-/330-057ft-ObrtP-O6V
X6>-(95^(0-<yo-3o-ofo30-0 7 /o. noO-Ohl0-07V0-oa-V
<O.oo^.D- .05/
0- A3 9^2_,o54_O-Ofoi?^)-Ofo7x0-(?5*y<"£)-OO5O-Ofo.2.
Lc).o69
X | v<?y l
t^-_/<?/ °<35 £& O(3O eu?.*?/61/O2.fi$9 570*7 /
X^oi&>8
JSL> . . . _tf .099 I«V£>o^70-075^^0-oo5
Q-0£i> 1 0-O3tf&O(0O
Q-Q7<2
X0-053
. _ _/-0_ I. . .O.tfOi. 1 D-OOL
0-O6J/5-O7JL
7fe>9VQ7k"7^9^
1
X0 -O5£>^O-OO^
1 LCS and Calibration Verification: (5tYV lKA/A*O AAJUsA&JiA, True Value: /).O5OCRDL: VO ( e^i )| Comments :
Spike =* 2 x CRDLi ' . 1 ;..u.~i,.. r "• ' "'" "'
Analyst Checked: ^/r Date: !S
X/i^u
( pp,^)
Q.C. Approved: Jfa Date: 7/,J/^_
Irecu-Labs Research , Inc.
.Element:__\1HGA Analyt i ca l Sp ike s
nmProcedure No.BG
latrix Modifier:Water ^ Soil
Date: A,4o. 8ZOo7
P£ 603 No. 32034' Ana y s tI .O . L . :
7019 RevT J m e . _ 3//
Date Prepared:STANDARDS
Prepared by: tJ£>
Cal ibrat ion B lank. Standard 1
Standard 2Standard 3: { 0-O70 J
In i t ia l6*DOOCLQSzQ abs s 0-AL7o, /ooO'Ol ^ ^ x /yV
Reca li orationO'OOOo-o^o . . . . . _O'lOO0-071 % a /of
rMna
% a
Samole NumberSample
Sample Cone. DilutionDi lut ion (oo*A Factor Reading Reading1 2
Avg.Cone.
ReciII
Init ial Ca l l b .Ca l i b . Ver i r i ca * . onCa l i b . BlankLCS ' •""" ""&><? - (?0& Lz_J
- }&• a
t?3 - £ >oY3 - /Cal ib . BlankCal i b . Ver i f i ca t i onfo 3 -60V3 - /£<^CS
£?3~( <?O10- J=<2£-3Recanbrat ion
Cal i b . Ver i f i cat ionCa l i b . B lank^ a - i?o*is - -V
- 6r-?-*Cal i b . B l an k
Calil). Ver i f i ca t i on
F i na l Ca l i b r a t i o nCalib . VerificationI'ahb™. Blank
xVl-Oi-0t.o/.o1.0yX
/•O1-0/•oI-OTC"">
V/ .Oi-6I O1 -O10VV
X
'XVx
< ? •/ £ 3<O.O£>6"<O-OO$0-013<0>OO5'
VX
<O>OOSO-iA^O-o£ &O-OSi^o.das
XOf•<
O-03-i0*01.10-03.3O-O'ySO'O^/O
Vv:
x *•
Xa./a.//£113~{£3A<2
X^J ^^-?JcP3.I3
X
X£ •066.£ .O0£0 . //3
.&.U2.LO-O/ ^VO-09.?£>.<^o3O .(5^5"O.o^J-O'in .
.. 0.06. 3..^ .f^5?.O-ot>3O-OO /0-05?o-oSIO-OV7
0-O(o 3O.Ofeja .O - o o /
~J2j2&£L
X
XQ-0^70,0_o_/
D-./J3LO-tOL,O-JQ 10-O6^O-O^S
O.OOd.0-0 (3°l<^ .O99O. /7kO D6? SO-Ob60-057X
0-066O'OOO0-^57Q-O6OO-oy?o-Ofo3O-O5*?o-oooO-ObO
x
""1"^v —— ~"
0-/33<O-OO^"<?.5^5O./03O-/OOC-/2-3O-O9 (?^O-oo^0 - / 3 7<D-^9<?/?'^3^$$$r\\O-/3A,o.nsx r i
Q't**}<O-006o-usD.IOI/\ 1 1 O pC/' v/ 7 O/A 1 *l O
O-/3. /< 0-005-O, /JO
' "X "
X/^3/i>5_/o3loo//O?•?
JOk9f/o-y*/oo. 93'"" X"""-/oo^-y7V73#*>5 /93 ,
X "'
LCS and Cal ibrat ion Verif icat ion:CRDL: _____ ^0.. _ tfLp^) )Comments: ' . •
Spike * 2 x CROUTrue Value: 0,/j.Q
Analyst Checked;Q-C . Approved: Pate
oo
IIr'\
iiiiiii
QUALITY CONTROL REPORT NUMBER F 7024 Rev. A
Nurrderf6/
515?5^60
4,3
Date In
4 fab
Case Ho. Numberof Samples/a
6
5797573d5AS57^0
5/!S AQ/ffF
P
SA-5
513
7 -i,/ - /
7
SampieCustod ian
cJ, o(X1
oo
ooex}
SL>
o 0ft)
tDa.
-o
ro
O
n>
o-^ >•
O
f= CO
r>a>
cr
O
O
PI
O
cucr
ro
DOT 32 1
REPORTING SCHEDULEF 7026
DateRece ived
>bttec>
,{(,[$(*7/6 tot
/ t r /r) f
- 1/kfSlf
Hummer ofSamp l e siff
2
\
¥
QC ReportHo .
& /
^A
63
CaseHo .
5A5
(&@a£ i
fa& / „>
Weekly Report( SMO)
2^ ^/&/?(^
-^ ^A/^
^ 6/^/^6
s
Sample Traff icReport( S M O )
/"/VA t/'/C(-xX
^M
&/&/*<>
U. 5- <^
6/^//0//, 5. /^^^
— c >a ta PaicvrSionJ
T
Cha in of Distort/( H E I C )
• 0 0 7 3 2 2
ID 0 7 3 2 3