document

<I' Golder Associates July 26, 2016

Metropolitan Council Environmental Services Industrial Waste Division 390 Robert St. N. St. Paul, MN 55101

Attention: Ms. Ashley Corbeille

RE: 2016 SECOND QUARTER SPECIAL DISCHARGE REPORT INDUSTRIAL DISCHARGE PERMIT NUMBER 2289 SOUTHEAST PUMP AND TREAT SYSTEM CANADIAN PACIFIC SHOREHAM FACILITY

Dear Ms. Corbeille:

Project No.:023-6105.016

On behalf of Canadian Pacific, enclosed is the 2016 Second Quarter Special Discharge Report for the site located at 281h & Central Avenue NE, Minneapolis MN. In accordance with the Metropolitan Council Environmental Services (MCES) Industrial Discharge Permit Number 2289, effective October 1, 2013 (MCES permit), this submittal documents the volume and quality of water discharged from the groundwater pump and treat system owned by Canadian Pacific.

The total quantity of water discharged into the sanitary sewer system during this reporting quarter was 3,575,720 gallons. The average daily discharge for the system was 39,294 gallons.

Required information for the discharge is provided as follows: • Attachment A - Special Discharge Report. • Attachment B - analytical data from Pace Analytical Inc. for the April 2016 monthly sampling

event. • Attachment C - analytical data from Pace Analytical Inc. for the May 2016 monthly sampling

event. • Attachment D - analytical data from Pace Analytical Inc. for the June 2016 monthly sampling

event.

Analytical results from these sampling events1 showed that the treated discharge water was in compliance with the MCES permit discharge limitations during this reporting period.

1 Note that in addition to the required sampling for sample point SP-01 (identified as sample SE EFFLUENT in the attached lab reports), Canadian Pacific voluntarily samples groundwater from the five recovery wells (RW0?-39-SP, RW0?-40-SP, RW06-28-I, RW0?-38-1, RW06-27-BR) on a quarterly basis. All analytical data is included in Attachments B, C and D; only the required discharge data is included in the Special Discharge Report in Attachment A and the corresponding analytical reports.

Golder Associates Inc. 1751 West County Rd. B, Ste. 105

Roseville, MN USA 55113 Tel: (651) 697-9737 Fax: (651) 697-9737 www.golder.com

Golder Associates: Operations in Africa, Asia, Australasia, Europe, North America and South America

Ms. Ashley Corbeille MCES 2

July 26, 2016 023-6105.016

If you have any questions or comments, please do not hesitate to contact Barbara Johnson at (651) 697-9737. Thank you for your assistance in this matter.

Very truly yours,

GOLDER ASSOCIATES INC.

Af..__~/ Alan Phillips Staff Geologist

Cc: Ms. Aimee Zack, CP Ms. Claire Mackler, Golder

~'1~~ Barbara Johnson, PE Associate

<II Golder Associates

Attachment A

SPECIAL DISCHARGE REPORT

Metropolitan Council Environmental Services Industrial Waste & Pollution Prevention Section 390 North Robert Street St. Paul, Minnesota 55101-1805

For MCES Use Only

Permit No: Staff: Received: 0 L 45 E

SPECIAL DISCHARGE REPORT - REPORTING PERIOD INFORMATION

1. Permittee Name: Canadian Pacific Railway Permit No: 2289 ----2. Facility Address: 28th Ave NE & Central Ave NE, Minneapolis, MN 55418

Billing Address Changed? O ves @ No Changes: ____________________ _

Mailing Address Changed? Q Yes (!) No Changes:

3. Reporting Period: Year: 2016 Check applicable period below:

Quarterly Reporters: 0 Jan-Mar (!) Apr-Jun 0 Jul-Sep 0 Oct-Dec

Annual Reporters: 0 Jan-Dec

4. Discharge Information:

Indicate whether the wastewater was discharged on-site and/or hauled during this reporting period, and complete the associated questions. If no wastewater was discharged to MCES during this reporting period, indicate no discharge.

D No Discharge to MCES during this reporting period

If no discharge is selected, proceed directly to Item #5.

I./ I On-Site Discharge

A. Total volume discharged during this reporting period (gallons): 3,575,720 ----------------

8. Total days of discharge during this reporting period (days): 91 ----------------

C. Average volume discharged per day (gallons/day): 39,294 ----------------

0 . Method of volume determination for this period: Effluent flow meter ---------------~

D Hauled Discharge

A. Total number of loads hauled during this reporting period:

B. Total volume hauled during this reporting period (gallons):

C. Total days of discharge during this reporting period (days):

D. Average volume per discharge day (gallons/day):

E. Method of volume determination for this period:

F. Liquid Waste Hauler name and permit number:

Report form help sheet

SDR-RPl-2015 Page 1of2

5. Changes/Problems: Have there been significant process problems/changes during this reporting period?

0 Yes (!)No If Yes with no previous MCES notification, add explanation below:

6. Planned Changes: Are there any planned or expected future changes that will impact discharge volume or quality?

0 Yes ®No If Yes, add explanation below:

7. Data Sheets: I certify that all sampling data that occurred during this reporting period has been submitted to MCES.

® Yes 0 No If No, add explanation below:

8. Representative Discharge: Are the analytical results submitted during this reporting period representative of the

wastewater discharged during this reporting period?

@ Yes 0 No If No, add explanation below:

9. General comments regarding submission:

10. Certification Statement:

"I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to ensure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties under law for submitting false information, including the possibility of fine and imprisonment for known violations."

Name (print): Barbara Johnson, PE Title: Authorized Representative for Canadian Pacific

Signature: -~~ Date: 7/z~!tb

Email: [email protected] Phone: 651-697-9737

SDR-RPl-2015 Page 2 of 2

Metropolitan Council Environmental Services Industrial Waste & Pollution Prevention Section 390 North Robert Street St. Paul, Minnesota 55101-1805

For MCES Use Only

Permit No: Staff: Received: 0 L 45 E

SPECIAL DISCHARGE REPORT - SAMPLING RESULTS Please complete Page 2 of this form for each monitoring point with sampling requirements in Attachment A of the Permit.

1. Permittee Name: Canadian Pacific Railway

2. Facility Address: 28th Ave NE & Central Ave NE, Minneapolis, MN 55418

3. Reporting Period: Year: 2016 Choose applicable period below:

Quarterly Reporter: 0 Jan-Mar

Semi-Annual Reporter: 0 Jan-Jun

Annual Reporter: O Jan-Dec

(!)Apr-Jun

Q Jul-Dec

0 Jul-Sep 0 Oct-Dec

Permit No: 2289 -------

4. Proper Sampling: Were all samples collected and composited according to permit requirements?

l!J Yes D No If No, add explanation below:

5. Proper Analysis: Were all analyses conducted per permit requirements? EJ Yes D No If No, add explanation below:

6. Representative Discha~: Are the an~ical results representative of the wastewater discharged during this monitoring event? l..!_J Yes LJ No If No, add explanation below:

7. Compliance Status: Compare the analytical results with the corresponding discharge limits in your Permit. Do any analytical results exceed the corresponding discharge limit(s) in your Permit? D Yes EJ No If Yes, add explanation below:

When did you become aware of the exceedance(s)?

8. General comments regarding submission: Total suspended solids, chemical oxygen demand, and pH are sampled quarterly while volatile organic compounds are sampled monthly. An entry of "NS" in the following sample result tables indicates that the given parameter was not analyzed during the specified monthly sampling event.

9. Certification Statement: "I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to ensure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties under law for submitting false information, including the possibility of fine and imprisonment for known violations."

Name (print): Barbara Johnson, PE Title: Authorized Representative for Canadian Pacific

Signature: Date:

Email: [email protected] Phone: 651-697-9737

Report form help sheet

Page 1 of 2 SDR-SR-2015

Sample Results: Submit one result sheet for each sampling day per monitoring point. Enter daily values for each sampling event from one monitoring point, in accordance with requirements in the Industrial Discharge Permit (Section B). Daily and long-term values shall be compared to Discharge Limitations in Permit Section A.1 for compliance determinations. Attach all laboratory data sheets and supporting calculations.

Monitoring Point: SP-01 Description: Effluent discharge line

Sample Start Date & Time: 4/13/1613:55 Sample End Date & Time: _4_11_3_11_6_1_3_:5_5 ______ _

Discharge volume through monitoring point on sampling day: 27,328 (estimated)

Sample collected by: D Permittee 0 Other, name: Golder Associates Inc.

gallons

Method of collection: 0 Manual D Automatic

Sample composited by: D Permittee D Other, name: ------------- Composite method: N_A ____________ _

Substance Analytical Result Unit Detection Limits Analysis Method Sample Method

Sample Laboratory Result Container Tvpe Name

pH NS S.U .

Total Suspended Solids NS mg/I

Chemical Oxygen Demand NS mg/I

1, 1-Dichloroethane 0.0136 mg/I 0.00024 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

1, 1-Dichloroethene 0.0050 mg/I 0.00041 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

cis-1,2-Dichloroethene 0.0114 mg/I 0.00026 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

Tetrachloroethene 0.0352 mg/I 0.00050 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

1, 1, 1-Trichloroethane 0.0112 mg/I 0.00050 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

Trichloroethene 0.0046 mg/I 0.00033 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

mg/I Other

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I


Sample Results: Submit one result sheet for each sampling day per monitoring point. Enter daily values for each sampling event from one monitoring point, in accordance with requirements in the Industrial Discharge Permit (Section B). Daily and long-term values shall be compared to Discharge Limitations in Permit Section A.1 for compliance determinations. Attach all laboratory data sheets and supporting calculations.


Sample Start Date & Time: 5/16/1615:30 Sample End Date & Time: _5_11_6_11_6_1_5_:3_o ______ _


Sample collected by: D Permittee 0 Other, name: Golder Associates Inc.

gallons

Method of collection: EJ Manual D Automatic

Sample composited by: D Permittee D Other, name: ------------- Composite method: N_A ____________ _

Substance Analytical Result Unit Detection Limits Analysis Method Sample Method Sample Laboratory

Result Container Tvoe Name

pH NS S.U.

Total Suspended Solids NS mg/I

Chemical Oxygen Demand NS mg/I



cis-1,2-Dichloroethene 0.0117 mg/I 0.00026 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services. Inc.

Tetrachloroethene 0.0377 mg/I 0.00050 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

1, 1, 1-Trichloroethane 0.0104 mg/I 0.00050 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services. Inc.


mg/I Other

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I


Sample Results: Submit one result sheet for each sampling day per monitoring point. Enter daily values for each sampling event from one monitoring point, in accordance with requirements in the Industrial Discharge Permit (Section 8). Daily and long-term values shall be compared to Discharge Limitations in Permit Section A.1 for compliance determinations. Attach all laboratory data sheets and supporting calculations.


Sample Start Date & Time: 6/13/1614:00 Sample End Date & Time: _6_11_3_11_6_1_4_:o_o ______ _


Sample collected by: D Permittee EJ Other, name: Golder Associates Inc.

gallons

Method of collection: EJ Manual D Automatic

Sample composited by: D Permittee D Other, name: ------------- Composite method: N_A _____________ _

Substance Analytical Result Unit Detection Limits Analysis Method Sample Method Sample Laboratory

Result Container Tvoe Name

pH 7.7 S.U. 0.010 SM 4500-H+B Grab-Single Plastic -1L Pace Analytical Services, Inc.

Total Suspended Solids <0.95 mg/I 0.95 SM 25400 Grab - Single Plastic - 1 L Pace Analytical Services, Inc.

Chemical Oxygen Demand <13.4 mg/I 13.4 EPA410.4 Grab - Single Plastic - 250 ml Pace Analytical Services. Inc.



cis-1,2-Dichloroethene 0.0126 mg/I 0.00026 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services. Inc.

Tetrachloroethene 0.0369 mg/I 0.00050 EPA 8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

1, 1, 1-Trichloroethane 0.0135 mg/I 0.00050 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services. Inc.


mg/I Other

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I


Attachment B

ANALYTICAL RESULTS FOR TREATED GROUNDWATER

April 2016

#=CL#

April 20, 2016

LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40130761

40130761Project:Pace Project No.:

RE:

Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102

023-6105-016 CP-SHOREHAM YARD

Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on April 14, 2016. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Laurie [email protected] Manager

Enclosures

REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9

Green Bay, WI 54302(920)469-2436

Page 1 of 18

#=CP#

CERTIFICATIONS

Pace Project No.:Project:

40130761023-6105-016 CP-SHOREHAM YARD

Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334Virginia VELAP ID: 460263North Dakota Certification #: R-150

South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Virginia VELAP Certification ID: 460263Virginia VELAP ID: 460263Wisconsin Certification #: 405132750Wisconsin DATCP Certification #: 105-444




Green Bay, WI 54302(920)469-2436

Page 2 of 18

#=SS#

SAMPLE SUMMARY


40130761023-6105-016 CP-SHOREHAM YARD

Lab ID Sample ID Matrix Date Collected Date Received

40130761001 041316-0900-200 Water 04/13/16 09:00 04/14/16 08:50

40130761002 SE EFFLUENT Water 04/13/16 13:55 04/14/16 08:50




Green Bay, WI 54302(920)469-2436

Page 3 of 18

#=SA#

SAMPLE ANALYTE COUNT


40130761023-6105-016 CP-SHOREHAM YARD

Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts

40130761001 041316-0900-200 EPA 8260 71 PASI-GLAP

40130761002 SE EFFLUENT EPA 8260 71 PASI-GLAP




Green Bay, WI 54302(920)469-2436

Page 4 of 18

#=AR#

ANALYTICAL RESULTS


40130761023-6105-016 CP-SHOREHAM YARD

Sample: 041316-0900-200 Lab ID: 40130761001 Collected: 04/13/16 09:00 Received: 04/14/16 08:50 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 82608260 MSV

Acetone 21.2 ug/L 04/18/16 09:10 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 04/18/16 09:10 107-05-15.0 2.2 1Benzene <0.50 ug/L 04/18/16 09:10 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 04/18/16 09:10 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 04/18/16 09:10 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 04/18/16 09:10 75-27-41.0 0.50 1Bromoform <0.50 ug/L 04/18/16 09:10 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 04/18/16 09:10 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 04/18/16 09:10 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 04/18/16 09:10 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 04/18/16 09:10 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 04/18/16 09:10 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 04/18/16 09:10 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 04/18/16 09:10 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 04/18/16 09:10 75-00-31.0 0.37 1Chloroform <2.5 ug/L 04/18/16 09:10 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 04/18/16 09:10 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 04/18/16 09:10 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 04/18/16 09:10 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 04/18/16 09:10 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 04/18/16 09:10 124-48-15.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 04/18/16 09:10 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 04/18/16 09:10 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 04/18/16 09:10 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 04/18/16 09:10 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 04/18/16 09:10 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 04/18/16 09:10 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 04/18/16 09:10 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 04/18/16 09:10 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 04/18/16 09:10 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 04/18/16 09:10 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 04/18/16 09:10 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 04/18/16 09:10 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 04/18/16 09:10 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 04/18/16 09:10 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 04/18/16 09:10 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 04/18/16 09:10 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 04/18/16 09:10 10061-01-55.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 04/18/16 09:10 10061-02-620.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 04/18/16 09:10 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 04/18/16 09:10 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 04/18/16 09:10 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 04/18/16 09:10 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 04/18/16 09:10 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 04/18/16 09:10 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 04/18/16 09:10 108-10-120.0 2.1 1


without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 10:21 AM


Green Bay, WI 54302(920)469-2436

Page 5 of 18

#=AR#

ANALYTICAL RESULTS


40130761023-6105-016 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 04/18/16 09:10 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 04/18/16 09:10 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 04/18/16 09:10 103-65-11.0 0.50 1Styrene <0.50 ug/L 04/18/16 09:10 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 04/18/16 09:10 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 04/18/16 09:10 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 04/18/16 09:10 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 04/18/16 09:10 109-99-95.0 2.0 1Toluene <0.50 ug/L 04/18/16 09:10 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 04/18/16 09:10 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 04/18/16 09:10 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 04/18/16 09:10 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 04/18/16 09:10 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 04/18/16 09:10 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 04/18/16 09:10 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 04/18/16 09:10 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 04/18/16 09:10 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 04/18/16 09:10 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 04/18/16 09:10 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 04/18/16 09:10 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 04/18/16 09:10 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 04/18/16 09:10 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 86 % 04/18/16 09:10 460-00-470-130 1Dibromofluoromethane (S) 109 % 04/18/16 09:10 1868-53-770-130 1Toluene-d8 (S) 96 % 04/18/16 09:10 2037-26-570-130 1




Green Bay, WI 54302(920)469-2436

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#=AR#

ANALYTICAL RESULTS


40130761023-6105-016 CP-SHOREHAM YARD

Sample: SE EFFLUENT Lab ID: 40130761002 Collected: 04/13/16 13:55 Received: 04/14/16 08:50 Matrix: Water



Acetone <3.0 ug/L 04/18/16 08:47 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 04/18/16 08:47 107-05-15.0 2.2 1Benzene <0.50 ug/L 04/18/16 08:47 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 04/18/16 08:47 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 04/18/16 08:47 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 04/18/16 08:47 75-27-41.0 0.50 1Bromoform <0.50 ug/L 04/18/16 08:47 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 04/18/16 08:47 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 04/18/16 08:47 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 04/18/16 08:47 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 04/18/16 08:47 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 04/18/16 08:47 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 04/18/16 08:47 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 04/18/16 08:47 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 04/18/16 08:47 75-00-31.0 0.37 1Chloroform <2.5 ug/L 04/18/16 08:47 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 04/18/16 08:47 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 04/18/16 08:47 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 04/18/16 08:47 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 04/18/16 08:47 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 04/18/16 08:47 124-48-15.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 04/18/16 08:47 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 04/18/16 08:47 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 04/18/16 08:47 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 04/18/16 08:47 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 04/18/16 08:47 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 04/18/16 08:47 75-71-81.0 0.22 11,1-Dichloroethane 13.6 ug/L 04/18/16 08:47 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 04/18/16 08:47 107-06-21.0 0.17 11,1-Dichloroethene 5.0 ug/L 04/18/16 08:47 75-35-41.0 0.41 1cis-1,2-Dichloroethene 11.4 ug/L 04/18/16 08:47 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 04/18/16 08:47 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 04/18/16 08:47 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 04/18/16 08:47 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 04/18/16 08:47 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 04/18/16 08:47 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 04/18/16 08:47 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 04/18/16 08:47 10061-01-55.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 04/18/16 08:47 10061-02-620.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 04/18/16 08:47 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 04/18/16 08:47 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 04/18/16 08:47 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 04/18/16 08:47 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 04/18/16 08:47 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 04/18/16 08:47 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 04/18/16 08:47 108-10-120.0 2.1 1




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ANALYTICAL RESULTS


40130761023-6105-016 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 04/18/16 08:47 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 04/18/16 08:47 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 04/18/16 08:47 103-65-11.0 0.50 1Styrene <0.50 ug/L 04/18/16 08:47 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 04/18/16 08:47 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 04/18/16 08:47 79-34-51.0 0.25 1Tetrachloroethene 35.2 ug/L 04/18/16 08:47 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 04/18/16 08:47 109-99-95.0 2.0 1Toluene <0.50 ug/L 04/18/16 08:47 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 04/18/16 08:47 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 04/18/16 08:47 120-82-15.0 2.2 11,1,1-Trichloroethane 11.2 ug/L 04/18/16 08:47 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 04/18/16 08:47 79-00-51.0 0.20 1Trichloroethene 4.6 ug/L 04/18/16 08:47 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 04/18/16 08:47 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 04/18/16 08:47 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 04/18/16 08:47 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 04/18/16 08:47 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 04/18/16 08:47 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 04/18/16 08:47 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 04/18/16 08:47 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 04/18/16 08:47 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 86 % 04/18/16 08:47 460-00-470-130 1Dibromofluoromethane (S) 107 % 04/18/16 08:47 1868-53-770-130 1Toluene-d8 (S) 97 % 04/18/16 08:47 2037-26-570-130 1




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QUALITY CONTROL DATA


40130761023-6105-016 CP-SHOREHAM YARD

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:QC Batch Method:

Analysis Method:Analysis Description:

MSV/33024EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40130761001, 40130761002

Parameter UnitsBlankResult

ReportingLimit Qualifiers

METHOD BLANK: 1320408Associated Lab Samples: 40130761001, 40130761002

Matrix: Water

AnalyzedMDL

1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 04/18/16 06:330.181,1,1-Trichloroethane ug/L <0.50 1.0 04/18/16 06:330.501,1,2,2-Tetrachloroethane ug/L <0.25 1.0 04/18/16 06:330.251,1,2-Trichloroethane ug/L <0.20 1.0 04/18/16 06:330.201,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 04/18/16 06:330.811,1-Dichloroethane ug/L <0.24 1.0 04/18/16 06:330.241,1-Dichloroethene ug/L <0.41 1.0 04/18/16 06:330.411,1-Dichloropropene ug/L <0.44 1.0 04/18/16 06:330.441,2,3-Trichlorobenzene ug/L <2.1 5.0 04/18/16 06:332.11,2,3-Trichloropropane ug/L <0.50 1.0 04/18/16 06:330.501,2,4-Trichlorobenzene ug/L <2.2 5.0 04/18/16 06:332.21,2,4-Trimethylbenzene ug/L <0.50 1.0 04/18/16 06:330.501,2-Dibromo-3-chloropropane ug/L <2.2 5.0 04/18/16 06:332.21,2-Dibromoethane (EDB) ug/L <0.18 1.0 04/18/16 06:330.181,2-Dichlorobenzene ug/L <0.50 1.0 04/18/16 06:330.501,2-Dichloroethane ug/L <0.17 1.0 04/18/16 06:330.171,2-Dichloropropane ug/L <0.23 1.0 04/18/16 06:330.231,3,5-Trimethylbenzene ug/L <0.50 1.0 04/18/16 06:330.501,3-Dichlorobenzene ug/L <0.50 1.0 04/18/16 06:330.501,3-Dichloropropane ug/L <0.50 1.0 04/18/16 06:330.501,4-Dichlorobenzene ug/L <0.50 1.0 04/18/16 06:330.502,2-Dichloropropane ug/L <0.48 1.0 04/18/16 06:330.482-Butanone (MEK) ug/L <3.0 20.0 04/18/16 06:333.02-Chlorotoluene ug/L <0.50 1.0 04/18/16 06:330.504-Chlorotoluene ug/L <0.21 1.0 04/18/16 06:330.214-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 04/18/16 06:332.1Acetone ug/L <3.0 20.0 04/18/16 06:333.0Allyl chloride ug/L <2.2 5.0 04/18/16 06:332.2Benzene ug/L <0.50 1.0 04/18/16 06:330.50Bromobenzene ug/L <0.23 1.0 04/18/16 06:330.23Bromochloromethane ug/L <0.34 1.0 04/18/16 06:330.34Bromodichloromethane ug/L <0.50 1.0 04/18/16 06:330.50Bromoform ug/L <0.50 1.0 04/18/16 06:330.50Bromomethane ug/L <2.4 5.0 04/18/16 06:332.4Carbon tetrachloride ug/L <0.50 1.0 04/18/16 06:330.50Chlorobenzene ug/L <0.50 1.0 04/18/16 06:330.50Chloroethane ug/L <0.37 1.0 04/18/16 06:330.37Chloroform ug/L <2.5 5.0 04/18/16 06:332.5Chloromethane ug/L <0.50 1.0 04/18/16 06:330.50cis-1,2-Dichloroethene ug/L <0.26 1.0 04/18/16 06:330.26cis-1,3-Dichloropropene ug/L <0.50 1.0 04/18/16 06:330.50




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40130761023-6105-016 CP-SHOREHAM YARD





Matrix: Water

AnalyzedMDL

Dibromochloromethane ug/L <0.50 1.0 04/18/16 06:330.50Dibromomethane ug/L <0.43 1.0 04/18/16 06:330.43Dichlorodifluoromethane ug/L <0.22 1.0 04/18/16 06:330.22Dichlorofluoromethane ug/L <0.21 1.0 04/18/16 06:330.21Diethyl ether (Ethyl ether) ug/L <2.2 5.0 04/18/16 06:332.2Ethylbenzene ug/L <0.50 1.0 04/18/16 06:330.50Hexachloro-1,3-butadiene ug/L <2.1 5.0 04/18/16 06:332.1Isopropylbenzene (Cumene) ug/L <0.14 1.0 04/18/16 06:330.14m&p-Xylene ug/L <1.0 2.0 04/18/16 06:331.0Methyl-tert-butyl ether ug/L <0.17 1.0 04/18/16 06:330.17Methylene Chloride ug/L <0.23 1.0 04/18/16 06:330.23n-Butylbenzene ug/L <0.50 1.0 04/18/16 06:330.50n-Propylbenzene ug/L <0.50 1.0 04/18/16 06:330.50Naphthalene ug/L <2.5 5.0 04/18/16 06:332.5o-Xylene ug/L <0.50 1.0 04/18/16 06:330.50p-Isopropyltoluene ug/L <0.50 1.0 04/18/16 06:330.50sec-Butylbenzene ug/L <2.2 5.0 04/18/16 06:332.2Styrene ug/L <0.50 1.0 04/18/16 06:330.50tert-Butylbenzene ug/L <0.18 1.0 04/18/16 06:330.18Tetrachloroethene ug/L <0.50 1.0 04/18/16 06:330.50Tetrahydrofuran ug/L <2.0 5.0 04/18/16 06:332.0Toluene ug/L <0.50 1.0 04/18/16 06:330.50trans-1,2-Dichloroethene ug/L <0.26 1.0 04/18/16 06:330.26trans-1,3-Dichloropropene ug/L <0.23 1.0 04/18/16 06:330.23Trichloroethene ug/L <0.33 1.0 04/18/16 06:330.33Trichlorofluoromethane ug/L <0.18 1.0 04/18/16 06:330.18Vinyl chloride ug/L <0.18 1.0 04/18/16 06:330.184-Bromofluorobenzene (S) % 90 70-130 04/18/16 06:33Dibromofluoromethane (S) % 110 70-130 04/18/16 06:33Toluene-d8 (S) % 94 70-130 04/18/16 06:33

Parameter UnitsLCS

Result% RecLimits Qualifiers% RecConc.

1320409LABORATORY CONTROL SAMPLE:LCSSpike

1,1,1,2-Tetrachloroethane ug/L 45.71,1,1-Trichloroethane ug/L 45.050 90 70-1311,1,2,2-Tetrachloroethane ug/L 46.750 93 67-1301,1,2-Trichloroethane ug/L 46.050 92 70-1301,1,2-Trichlorotrifluoroethane ug/L 53.550 107 50-1501,1-Dichloroethane ug/L 46.050 92 70-1331,1-Dichloroethene ug/L 46.750 93 70-1301,1-Dichloropropene ug/L 40.31,2,3-Trichlorobenzene ug/L 36.41,2,3-Trichloropropane ug/L 47.9




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40130761023-6105-016 CP-SHOREHAM YARD


Parameter UnitsLCS



1,2,4-Trichlorobenzene ug/L 35.150 70 70-1301,2,4-Trimethylbenzene ug/L 39.51,2-Dibromo-3-chloropropane ug/L 38.250 76 50-1501,2-Dibromoethane (EDB) ug/L 44.050 88 70-1301,2-Dichlorobenzene ug/L 41.150 82 70-1301,2-Dichloroethane ug/L 47.650 95 70-1301,2-Dichloropropane ug/L 43.050 86 70-1301,3,5-Trimethylbenzene ug/L 40.91,3-Dichlorobenzene ug/L 42.050 84 70-1301,3-Dichloropropane ug/L 45.61,4-Dichlorobenzene ug/L 39.950 80 70-1302,2-Dichloropropane ug/L 43.62-Butanone (MEK) ug/L 65.52-Chlorotoluene ug/L 42.24-Chlorotoluene ug/L 44.44-Methyl-2-pentanone (MIBK) ug/L 43.9Acetone ug/L 82.2Allyl chloride ug/L 50.2Benzene ug/L 42.350 85 60-135Bromobenzene ug/L 44.4Bromochloromethane ug/L 48.4Bromodichloromethane ug/L 43.150 86 70-130Bromoform ug/L 43.650 87 70-130Bromomethane ug/L 57.250 114 33-130Carbon tetrachloride ug/L 46.450 93 70-138Chlorobenzene ug/L 43.650 87 70-130Chloroethane ug/L 40.450 81 51-130Chloroform ug/L 45.250 90 70-130Chloromethane ug/L 43.250 86 25-132cis-1,2-Dichloroethene ug/L 43.750 87 69-130cis-1,3-Dichloropropene ug/L 41.950 84 70-130Dibromochloromethane ug/L 43.950 88 70-130Dibromomethane ug/L 46.9Dichlorodifluoromethane ug/L 37.850 76 23-130Dichlorofluoromethane ug/L 44.3Diethyl ether (Ethyl ether) ug/L 52.2Ethylbenzene ug/L 44.150 88 70-136Hexachloro-1,3-butadiene ug/L 38.0Isopropylbenzene (Cumene) ug/L 42.650 85 70-140m&p-Xylene ug/L 87.3100 87 70-138Methyl-tert-butyl ether ug/L 47.650 95 66-138Methylene Chloride ug/L 42.650 85 70-130n-Butylbenzene ug/L 40.2n-Propylbenzene ug/L 44.9Naphthalene ug/L 35.4o-Xylene ug/L 40.750 81 70-134p-Isopropyltoluene ug/L 40.8




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40130761023-6105-016 CP-SHOREHAM YARD


Parameter UnitsLCS



sec-Butylbenzene ug/L 42.1Styrene ug/L 41.550 83 70-133tert-Butylbenzene ug/L 43.6Tetrachloroethene ug/L 49.650 99 70-138Tetrahydrofuran ug/L 44.0Toluene ug/L 43.950 88 70-130trans-1,2-Dichloroethene ug/L 47.950 96 70-131trans-1,3-Dichloropropene ug/L 43.050 86 69-130Trichloroethene ug/L 43.950 88 70-130Trichlorofluoromethane ug/L 47.750 95 50-150Vinyl chloride ug/L 46.750 93 49-1304-Bromofluorobenzene (S) % 98 70-130Dibromofluoromethane (S) % 104 70-130Toluene-d8 (S) % 101 70-130

Parameter UnitsMS

Result% RecLimits Qual% RecConc.

1321752MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpikeResult

40130761002

1321753

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1,2-Tetrachloroethane ug/L 5 20<0.18 43.8 46.11,1,1-Trichloroethane ug/L 50 88 70-13493 4 205011.2 55.2 57.61,1,2,2-Tetrachloroethane ug/L 50 89 67-13090 1 2050<0.25 44.3 44.81,1,2-Trichloroethane ug/L 50 90 70-13093 3 2050<0.20 45.2 46.41,1,2-Trichlorotrifluoroethane ug/L 50 105 50-150111 5 2050<0.81 52.5 55.41,1-Dichloroethane ug/L 50 87 70-13493 5 205013.6 57.2 59.91,1-Dichloroethene ug/L 50 92 68-13697 4 20505.0 51.2 53.51,1-Dichloropropene ug/L 16 20<0.44 37.4 43.91,2,3-Trichlorobenzene ug/L 1 20<2.1 36.0 35.81,2,3-Trichloropropane ug/L 4 20<0.50 44.3 46.01,2,4-Trichlorobenzene ug/L 50 70 62-13970 0 2050<2.2 35.2 35.31,2,4-Trimethylbenzene ug/L 6 20<0.50 36.4 38.61,2-Dibromo-3-chloropropane

ug/L 50 76 50-15074 3 2050<2.2 38.2 37.2

1,2-Dibromoethane (EDB) ug/L 50 88 70-13086 2 2050<0.18 43.9 43.11,2-Dichlorobenzene ug/L 50 80 70-13082 2 2050<0.50 40.2 41.11,2-Dichloroethane ug/L 50 92 70-13098 7 2050<0.17 45.8 49.11,2-Dichloropropane ug/L 50 89 70-13093 5 2050<0.23 44.5 46.61,3,5-Trimethylbenzene ug/L 5 20<0.50 37.7 39.71,3-Dichlorobenzene ug/L 50 80 70-13185 5 2050<0.50 40.2 42.41,3-Dichloropropane ug/L 2 20<0.50 43.9 44.91,4-Dichlorobenzene ug/L 50 76 70-13078 3 2050<0.50 38.1 39.12,2-Dichloropropane ug/L 6 20<0.48 42.5 45.22-Butanone (MEK) ug/L 20<3.0 <3.0 51.92-Chlorotoluene ug/L 3 20<0.50 40.9 42.24-Chlorotoluene ug/L 1 20<0.21 43.6 43.2




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40130761023-6105-016 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40130761002

1321753

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

4-Methyl-2-pentanone(MIBK)

ug/L 5 20<2.1 45.0 47.2

Acetone ug/L 3 23<3.0 50.8 49.3Allyl chloride ug/L 7 20<2.2 46.6 43.6Benzene ug/L 50 81 57-13887 7 2050<0.50 40.6 43.6Bromobenzene ug/L 6 20<0.23 42.1 44.8Bromochloromethane ug/L 6 20<0.34 45.8 48.5Bromodichloromethane ug/L 50 83 70-13086 3 2050<0.50 41.5 42.9Bromoform ug/L 50 85 70-13081 4 2050<0.50 42.4 40.7Bromomethane ug/L 50 121 33-130129 6 2750<2.4 60.6 64.5Carbon tetrachloride ug/L 50 89 70-13893 4 2050<0.50 44.6 46.7Chlorobenzene ug/L 50 85 70-13088 4 2050<0.50 42.4 43.9Chloroethane ug/L 50 81 51-13088 9 2050<0.37 40.4 44.2Chloroform ug/L 50 86 70-13092 7 2050<2.5 43.1 46.3Chloromethane ug/L 50 81 25-13289 9 2050<0.50 40.7 44.4cis-1,2-Dichloroethene ug/L 50 86 61-14097 9 205011.4 54.5 59.8cis-1,3-Dichloropropene ug/L 50 82 70-13082 1 2050<0.50 41.2 40.8Dibromochloromethane ug/L 50 87 70-13086 0 2050<0.50 43.3 43.2Dibromomethane ug/L 4 20<0.43 45.8 47.8Dichlorodifluoromethane ug/L 50 70 23-13074 6 2050<0.22 35.1 37.2Dichlorofluoromethane ug/L 7 20<0.21 43.1 46.2Diethyl ether (Ethyl ether) ug/L 5 20<2.2 52.1 54.5Ethylbenzene ug/L 50 86 70-13890 5 2050<0.50 43.0 45.2Hexachloro-1,3-butadiene ug/L 2 20<2.1 37.0 37.6Isopropylbenzene (Cumene) ug/L 50 84 70-15288 4 2050<0.14 42.0 43.8m&p-Xylene ug/L 100 85 70-14089 4 20100<1.0 85.1 88.6Methyl-tert-butyl ether ug/L 50 93 66-139100 8 2050<0.17 46.3 50.0Methylene Chloride ug/L 50 81 70-13087 8 2050<0.23 40.3 43.6n-Butylbenzene ug/L 2 20<0.50 38.7 39.4n-Propylbenzene ug/L 5 20<0.50 43.0 45.0Naphthalene ug/L 2 20<2.5 36.6 35.9o-Xylene ug/L 50 82 70-13486 5 2050<0.50 40.8 42.9p-Isopropyltoluene ug/L 2 20<0.50 38.8 39.8sec-Butylbenzene ug/L 5 20<2.2 39.9 42.1Styrene ug/L 50 78 70-13884 8 2050<0.50 38.8 41.8tert-Butylbenzene ug/L 5 20<0.18 41.6 43.6Tetrachloroethene ug/L 50 94 70-14896 1 205035.2 82.3 83.5Tetrahydrofuran ug/L 3 20<2.0 46.5 45.1Toluene ug/L 50 83 70-13083 0 2050<0.50 41.6 41.7trans-1,2-Dichloroethene ug/L 50 89 70-13399 10 2050<0.26 44.7 49.7trans-1,3-Dichloropropene ug/L 50 84 69-13083 1 2050<0.23 41.8 41.4Trichloroethene ug/L 50 86 70-13188 2 20504.6 47.7 48.7Trichlorofluoromethane ug/L 50 94 50-150100 6 2050<0.18 46.8 49.9Vinyl chloride ug/L 50 93 49-133107 14 2050<0.18 46.7 53.54-Bromofluorobenzene (S) % 97 70-13097Dibromofluoromethane (S) % 105 70-130106




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40130761023-6105-016 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40130761002

1321753

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Toluene-d8 (S) % 99 70-13097




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#=QL#

QUALIFIERS


40130761023-6105-016 CP-SHOREHAM YARD

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES

Pace Analytical Services - Green BayPASI-G




Green Bay, WI 54302(920)469-2436

Page 15 of 18

#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE


40130761023-6105-016 CP-SHOREHAM YARD

Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch

40130761001 MSV/33024041316-0900-200 EPA 826040130761002 MSV/33024SE EFFLUENT EPA 8260




Green Bay, WI 54302(920)469-2436

Page 16 of 18

Pag

e 17

of 1

8

UPPER MIDWEST REGION

ompany Name: t.5

ranch/Location:

roject Contact: I A I i 5D ~ 2 C l I

MN: 612-607-1700 WI: 920-469-

·eAnalytical• www.paceleb.s.oom ~ Quote#:

~ 7)-~'tS- - ('\l."2.. CHAIN OF CUSTODY Mail To Contact:

•ereservatlon Codes Project Number: 1~1.. ~ -6l 05' -{) l 6 A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

Project Name: I C ~ - S ~OR~~ M '('l, J. Project State: I M tJ Sampled By (Print):! A let') ?\\ }\ \r Sampled By (Sign): I A-L.. 'ti:/vn1 PO#:

Regulatory Program:

H=Sodium Bisulfate Solution

FILTERED? (YES/NO)

PRESERVATION (CODE)*

Data Package Options (blllable)

MS/MSD D On your sample

(billable) D NOT needed on

your sample

Matrix Codes

D EPALevellll

D EPA Level IV

PACE LAB# I CLIENT FIELD ID

A=Nr B =Biota C= Charcoal O=OH s =Soil

DATE

W=Water OW = Drinking Water GW = Ground Water SW = Surface Water

TIME

~if\~\ 4 ·-'9'\G()-1.Se '1/13/ltl O<lOO

E E{f\"'e"'t

Rush Turnaround Time Requested - Prelims (Rush TAT subject to approval/surcharge)

Date Needed:

M/1>//( l \ ~551 'vV

!=Sodium Thiosulfate J=Other

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CLIENT COMMENTS

LAB COMMENTS Profile#

PACE Project No.

I Transmit Pr?lim Rush Results by (complete what you want): I v \{ V\ I I \,C J - I/ I j I JI '1 V,PA. J I ;::Q"( z;r:•f-•'<l .2 )M'4L. II , , I f O '-'{)..JI I !Receipt Temp= Emall#1:

Emall#2:

Telephone:

Fax:

Samples on HOLD are subject to

special pricing and release of llablllty

C019a(27 Jun2006)

Oate!Time: Received By:

Dale/Time: Received By:

Date/Time:

Date/Time: Not Present

Not Intact

of 18

Sample Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9

Green Bay, WI 54302

Temp should be above freezing to 6°C for all sample except Biota. Frozen Biota Samples should be received $ o•c.

Chain of Custody !=>resent:

Chain of Custody Filled Out:

Chain of Custod Relinquished:

Sampler Name & Signature on COG:

Samples Arrived within Hold Time:

- VOA Samples frozen upon receipt

Short Hold Time Anal sis (<72hr):

Rush Turn Around Time Re uested:

Sufficient Volume:

Correct Containers Used:

-Pace Containers Used:

-Pace IR Containers Used:

Containers Intact:

Filtered volume received for Dissolved tests

Sample Labels match COG:

-Includes date/time/ID/Analysis Matrix:

Comments:

ON/A 1.

ON/A 2.

No ON/A 3.

ON/A 4.

ONo ON/A 5.

0Yes ONo Date/Time:

8.

ON/A 9.

ON/A

W0#.40130761 111111 1111111111111111 40130761

C::~~~o1Jxf Ni~contents:

Initials: *

All containers needing preservation have been checked. (Non-Compliance noted in 13.) r HN03 r H2S04 r NaOH r NaOH +ZnAct

Ail c'Ontainer"S Meeting P"res-;rv""ation ii're tounci tc> b"e -;;- - - - - - - - - - -

compliance with EPA recommendation. OYes ONo (HN03, ~2 $2; NaOH+ZnAct~9. NaOH <!:12) e-;;epticiri VOA, -ottf~~ T'oC: TOX, TOH, - - - - - - - - - - - - - -O&G, WID , Phenolics, OTHER: Yes 0No

Headspace in VOA Vials >6mm :

Trip Blank Present:

Trip Blank Custody Seals Present

Pace Trip Blank Lot# if purchased : Client Notification/ Resolution:

Initial when completed

ON/A 14.

ON/A 15.

ON/A

Person Contacted: Date/Time: ~~~~~~~~~~~~~--

Comments/ Resolution:

Lab Std #ID of preservative

If checked, see attached form for additional comments D

~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

Project Manager Review: Date: __ C\_J ... ~ ... ) ... A .... r-----F-GB-C-031-Rev.03 (9Apri12015) SCURFonn

Attachment C


May 2016

#=CL#

May 26, 2016



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on May 17, 2016. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 17

#=CP#

CERTIFICATIONS


40132350023-6105-016 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

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#=SS#

SAMPLE SUMMARY


40132350023-6105-016 CP-SHOREHAM YARD


40132350001 051616-0800-200 Water 05/16/16 08:00 05/17/16 08:50





Green Bay, WI 54302(920)469-2436

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#=SA#



40132350023-6105-016 CP-SHOREHAM YARD


40132350001 051616-0800-200 EPA 8260 71 PASI-GLAP





Green Bay, WI 54302(920)469-2436

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#=AR#

ANALYTICAL RESULTS


40132350023-6105-016 CP-SHOREHAM YARD




Acetone 19.3J ug/L 05/23/16 08:52 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 05/23/16 08:52 107-05-15.0 2.2 1Benzene <0.50 ug/L 05/23/16 08:52 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 05/23/16 08:52 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 05/23/16 08:52 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 05/23/16 08:52 75-27-41.0 0.50 1Bromoform <0.50 ug/L 05/23/16 08:52 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 05/23/16 08:52 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 05/23/16 08:52 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 05/23/16 08:52 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 05/23/16 08:52 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 05/23/16 08:52 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 05/23/16 08:52 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 05/23/16 08:52 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 05/23/16 08:52 75-00-31.0 0.37 1Chloroform <2.5 ug/L 05/23/16 08:52 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 05/23/16 08:52 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 05/23/16 08:52 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 05/23/16 08:52 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 05/23/16 08:52 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 05/23/16 08:52 124-48-15.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 05/23/16 08:52 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 05/23/16 08:52 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 05/23/16 08:52 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 05/23/16 08:52 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 05/23/16 08:52 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 05/23/16 08:52 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 05/23/16 08:52 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 05/23/16 08:52 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 05/23/16 08:52 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 05/23/16 08:52 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 05/23/16 08:52 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 05/23/16 08:52 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 05/23/16 08:52 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 05/23/16 08:52 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 05/23/16 08:52 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 05/23/16 08:52 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 05/23/16 08:52 10061-01-55.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 05/23/16 08:52 10061-02-620.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 05/23/16 08:52 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 05/23/16 08:52 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 05/23/16 08:52 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 05/23/16 08:52 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 05/23/16 08:52 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 05/23/16 08:52 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 05/23/16 08:52 108-10-120.0 2.1 1


without the written consent of Pace Analytical Services, Inc..Date: 05/26/2016 04:07 PM


Green Bay, WI 54302(920)469-2436

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#=AR#

ANALYTICAL RESULTS


40132350023-6105-016 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 05/23/16 08:52 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 05/23/16 08:52 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 05/23/16 08:52 103-65-11.0 0.50 1Styrene <0.50 ug/L 05/23/16 08:52 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 05/23/16 08:52 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 05/23/16 08:52 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 05/23/16 08:52 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 05/23/16 08:52 109-99-95.0 2.0 1Toluene <0.50 ug/L 05/23/16 08:52 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 05/23/16 08:52 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 05/23/16 08:52 120-82-1 L25.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 05/23/16 08:52 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 05/23/16 08:52 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 05/23/16 08:52 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 05/23/16 08:52 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 05/23/16 08:52 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 05/23/16 08:52 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 05/23/16 08:52 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 05/23/16 08:52 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 05/23/16 08:52 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 05/23/16 08:52 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 05/23/16 08:52 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 82 % 05/23/16 08:52 460-00-470-130 1Dibromofluoromethane (S) 127 % 05/23/16 08:52 1868-53-770-130 1Toluene-d8 (S) 98 % 05/23/16 08:52 2037-26-570-130 1




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#=AR#

ANALYTICAL RESULTS


40132350023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40132350023-6105-016 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 05/24/16 16:26 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 05/24/16 16:26 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 05/24/16 16:26 103-65-11.0 0.50 1Styrene <0.50 ug/L 05/24/16 16:26 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 05/24/16 16:26 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 05/24/16 16:26 79-34-51.0 0.25 1Tetrachloroethene 37.7 ug/L 05/24/16 16:26 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 05/24/16 16:26 109-99-95.0 2.0 1Toluene <0.50 ug/L 05/24/16 16:26 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 05/24/16 16:26 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 05/24/16 16:26 120-82-1 L25.0 2.2 11,1,1-Trichloroethane 10.4 ug/L 05/24/16 16:26 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 05/24/16 16:26 79-00-51.0 0.20 1Trichloroethene 4.6 ug/L 05/24/16 16:26 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 05/24/16 16:26 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 05/24/16 16:26 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 05/24/16 16:26 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 05/24/16 16:26 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 05/24/16 16:26 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 05/24/16 16:26 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 05/24/16 16:26 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 05/24/16 16:26 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 76 % 05/24/16 16:26 460-00-470-130 1Dibromofluoromethane (S) 103 % 05/24/16 16:26 1868-53-770-130 1Toluene-d8 (S) 97 % 05/24/16 16:26 2037-26-570-130 1




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#=QC#



40132350023-6105-016 CP-SHOREHAM YARD




MSV/33598EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40132350001, 40132350002




Matrix: Water

AnalyzedMDL





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#=QC#



40132350023-6105-016 CP-SHOREHAM YARD





Matrix: Water

AnalyzedMDL


Parameter UnitsLCS



1,1,1-Trichloroethane ug/L 45.550 91 70-1311,1,2,2-Tetrachloroethane ug/L 55.550 111 67-1301,1,2-Trichloroethane ug/L 49.550 99 70-1301,1,2-Trichlorotrifluoroethane ug/L 48.450 97 50-1501,1-Dichloroethane ug/L 46.950 94 70-1331,1-Dichloroethene ug/L 45.350 91 70-1301,2,4-Trichlorobenzene ug/L 33.3 L050 67 70-1301,2-Dibromo-3-chloropropane ug/L 40.250 80 50-1501,2-Dibromoethane (EDB) ug/L 42.650 85 70-1301,2-Dichlorobenzene ug/L 43.350 87 70-130




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#=QC#



40132350023-6105-016 CP-SHOREHAM YARD


Parameter UnitsLCS



1,2-Dichloroethane ug/L 51.850 104 70-1301,2-Dichloropropane ug/L 49.450 99 70-1301,3-Dichlorobenzene ug/L 42.450 85 70-1301,4-Dichlorobenzene ug/L 42.750 85 70-130Benzene ug/L 45.450 91 60-135Bromodichloromethane ug/L 47.250 94 70-130Bromoform ug/L 41.950 84 70-130Bromomethane ug/L 38.550 77 33-130Carbon tetrachloride ug/L 46.050 92 70-138Chlorobenzene ug/L 45.950 92 70-130Chloroethane ug/L 43.350 87 51-130Chloroform ug/L 47.950 96 70-130Chloromethane ug/L 33.050 66 25-132cis-1,2-Dichloroethene ug/L 44.350 89 69-130cis-1,3-Dichloropropene ug/L 43.850 88 70-130Dibromochloromethane ug/L 43.150 86 70-130Dichlorodifluoromethane ug/L 19.150 38 23-130Ethylbenzene ug/L 45.050 90 70-136Isopropylbenzene (Cumene) ug/L 46.350 93 70-140m&p-Xylene ug/L 87.7100 88 70-138Methyl-tert-butyl ether ug/L 50.650 101 66-138Methylene Chloride ug/L 45.450 91 70-130o-Xylene ug/L 41.050 82 70-134Styrene ug/L 42.550 85 70-133Tetrachloroethene ug/L 54.250 108 70-138Toluene ug/L 45.450 91 70-130trans-1,2-Dichloroethene ug/L 48.450 97 70-131trans-1,3-Dichloropropene ug/L 43.150 86 69-130Trichloroethene ug/L 46.750 93 70-130Trichlorofluoromethane ug/L 43.850 88 50-150Vinyl chloride ug/L 37.950 76 49-1304-Bromofluorobenzene (S) % 97 70-130Dibromofluoromethane (S) % 107 70-130Toluene-d8 (S) % 101 70-130

Parameter UnitsMS



MSSpikeResult

40132350002

1338373

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L 50 95 70-13495 0 205010.4 57.9 57.91,1,2,2-Tetrachloroethane ug/L 50 121 67-130116 5 2050<0.25 60.5 57.81,1,2-Trichloroethane ug/L 50 102 70-13098 4 2050<0.20 51.0 48.91,1,2-Trichlorotrifluoroethane ug/L 50 102 50-150103 1 2050<0.81 51.2 51.71,1-Dichloroethane ug/L 50 98 70-134107 7 205012.7 61.9 66.41,1-Dichloroethene ug/L 50 93 68-13694 2 20505.0 51.3 52.2




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#=QC#



40132350023-6105-016 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40132350002

1338373

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,2,4-Trichlorobenzene ug/L 50 74 62-13972 3 2050<2.2 36.9 35.91,2-Dibromo-3-chloropropane

ug/L 50 85 50-15075 12 2050<2.2 42.3 37.6

1,2-Dibromoethane (EDB) ug/L 50 88 70-13085 3 2050<0.18 43.9 42.51,2-Dichlorobenzene ug/L 50 91 70-13092 1 2050<0.50 45.6 45.91,2-Dichloroethane ug/L 50 106 70-130102 4 2050<0.17 53.1 51.21,2-Dichloropropane ug/L 50 98 70-13097 1 2050<0.23 49.1 48.61,3-Dichlorobenzene ug/L 50 88 70-13192 5 2050<0.50 43.9 46.01,4-Dichlorobenzene ug/L 50 89 70-13091 2 2050<0.50 44.7 45.4Benzene ug/L 50 90 57-13891 1 2050<0.50 45.0 45.5Bromodichloromethane ug/L 50 94 70-13093 1 2050<0.50 46.9 46.3Bromoform ug/L 50 83 70-13081 3 2050<0.50 41.5 40.5Bromomethane ug/L 50 90 33-13097 7 2750<2.4 45.2 48.3Carbon tetrachloride ug/L 50 91 70-13891 0 2050<0.50 45.4 45.5Chlorobenzene ug/L 50 90 70-13093 3 2050<0.50 45.0 46.4Chloroethane ug/L 50 83 51-13089 7 2050<0.37 41.5 44.5Chloroform ug/L 50 96 70-13097 0 2050<2.5 48.2 48.3Chloromethane ug/L 50 67 25-13262 6 2050<0.50 33.3 31.2cis-1,2-Dichloroethene ug/L 50 91 61-14092 0 205011.7 57.4 57.5cis-1,3-Dichloropropene ug/L 50 88 70-13083 6 2050<0.50 44.1 41.7Dibromochloromethane ug/L 50 90 70-13084 7 2050<0.50 45.0 42.1Dichlorodifluoromethane ug/L 50 40 23-13038 4 2050<0.22 19.8 19.0Ethylbenzene ug/L 50 89 70-13891 2 2050<0.50 44.7 45.7Isopropylbenzene (Cumene) ug/L 50 91 70-15291 0 2050<0.14 45.5 45.3m&p-Xylene ug/L 100 87 70-14087 1 20100<1.0 86.9 87.4Methyl-tert-butyl ether ug/L 50 96 66-13997 2 2050<0.17 47.8 48.6Methylene Chloride ug/L 50 88 70-13091 4 2050<0.23 43.8 45.7o-Xylene ug/L 50 80 70-13481 1 2050<0.50 40.2 40.7Styrene ug/L 50 85 70-13882 3 2050<0.50 42.4 41.1Tetrachloroethene ug/L 50 101 70-14898 2 205037.7 88.1 86.6Toluene ug/L 50 91 70-13091 0 2050<0.50 45.7 45.6trans-1,2-Dichloroethene ug/L 50 97 70-13397 1 2050<0.26 48.4 48.7trans-1,3-Dichloropropene ug/L 50 88 69-13084 5 2050<0.23 43.8 41.8Trichloroethene ug/L 50 95 70-13193 2 20504.6 52.0 50.9Trichlorofluoromethane ug/L 50 88 50-15088 0 2050<0.18 44.1 44.1Vinyl chloride ug/L 50 78 49-13380 2 2050<0.18 39.1 40.14-Bromofluorobenzene (S) % 96 70-13093Dibromofluoromethane (S) % 109 70-130111Toluene-d8 (S) % 101 70-130102




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#=QL#

QUALIFIERS


40132350023-6105-016 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES


ANALYTE QUALIFIERS

Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results may be biased low.L2




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#=CR#



40132350023-6105-016 CP-SHOREHAM YARD


40132350001 MSV/33598051616-0800-200 EPA 826040132350002 MSV/33598SE EFFLUENT EPA 8260




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e 15

of 1

7(Please Print Clearly) ~ UPPER MIDWEST REGION ~ Company Name: (;, ~ ! ,...J p ,,- J~Sf'JC {ci i-ei" Branch/Location: /J\ +.. l.,qvu l A]T

e.Analyticar MN,;;7-1700 WI' 920-469-2~ 1..+e1ot-~ v

www.pacetab.s.oom Project Contact: Al1sci11 Zoll Quote#:

Phone: 'l7 3 -~lf s- - I 'I 2...2.. CHAIN OF CUSTODY Mail To Contact:

~1( I fLPt/1 13q~~ ~

Project Number: 02..3 -6lOS- -OIK I *Preservation Codes Mail To Company: A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

Project Name: c (J - s· ~ore~qwi Yei,,-J H=Sodium Bisulfate Solution !=Sodium Thiosulfate J=Other Mail To Address:

Project State: /vitJ FILTERED? (YES/NO) Y/111 tJ

Sampled By (Print): A-fa.,, PIA1I/; P5 (AP) PRESERVATION ·PICfi 15 Invoice To Contact: (CODE)* l.llittet

Ah--E!~ ..

Sampled By (Sign): Invoice To Company: 111i••

PO#: Regulatory

I Invoice To Address: Program:

Data Package 012tions MS/MSD Matrix Codes (billable) A-Air W=Water

Pµ' "

0 D EPA Level Ill 0 On your sample B =Biota OW= Drinking Water

l (billable) c =Charcoal GW = Ground Water a Invoice To Phone: D EPA Level IV 0 NOT needed on O=Oil SW = Surface Water

s =Soil WW::: Waste Water ::> your sample SI= Sludae WP=Wi"" CLIENT LAB COMMENTS Profile# COLLECTION

PACE LAB# CUIENT FIELD ID MATRIX I· COMMENTS (Lab Use Only) DATE TIME

OV/ &Sl&:.\t-©~00-' 1()6) '5/1'1fl' O'b('() wt J 2..,c 8 -'-f DMOvl> tn7 v s~ E'f .f I '"' -e " +- 1i/lt/1' ff)O W' 1/·.·;. Jx t5 ,,J./(]MJ Jg

~t·~' ~ ' i '.1·!:·, [.; ... '\'~ .... ,:; .• l

~J·~'.~ ;·~;~~: ... '•fr' }

/:.~ '··· ·. 5

, .. ;;. '.

Rush Turnaround Time Requested - Prelims Relin~•"f /)(flril I ) Jltl/'l //...'{ 1 Rece7Y:J 1!! P~~ DatefTime• PACE Project No.

(Rush TAT subject to approval/surcharge) s tf,,·t<o1 It, •/tf 40/3Z3CTJ Date Needed: Retin .:...4,,....

·4~" trJ/::4~ Recei~By• Date/Time•

!5l7i Transmit Prelim Rush Results by (complete what you want): v~~. oc Emall#1:

Re777//0s/uJ :jwed By• ;:ku/ j DatefTime: c::f!;J; ~ecelpt Temp=

Date/Time:

o~ . j

Emall#2: 5-1'7-1 ~ l<1. ·11/1..--. ,,o G~rllP Sample Receipt pH

Telephone: Relinquished By: DatefTime: Recewed By: (} fl{/,,{!JL_. Date!Time: OK I Adjusted

Fax: r ........ r.ustodv Seal

Samples on HOLD are subject to Relinquished By: Date!Time: Recewed By: Date/Time: tres~l~ Not Pres;fit special pricing and release of llablllty lnta t I Not Intact

.. ___ - L',.. ,. .. , .. ,,_, .......

C019a(27 Jun2006)

st' fnA

~: I

of 17

Document Name: Minneapolis Cooler Transfer Check List

Document Number: F-MN-C-214-Rev.OO

Revised Date: 24Feb2016 Page 1of1

Issuing Authority: Pace Minnesota Quality Office

Minneapolis Service Center Cooler Transfer Check List

Client:

Desetination Lab:

Received with Custody Seal: Yes

Custody Seal Intact: Yes /(~\ ~ NA

Temp Read Corrected Temp Correction Factor

Temperature C: IR Gun:

Samples on ice, cooling process has begun

Rush/Short Hold:

Containers Intact: No

Re-packed and Re-Iced:

Temp Blank Included: No

Shipped By/Date:

Notes:

of 17

a Analytical'


Green Bay, WI 54302

.~lient Name: G 0 /der Courier: r Fed Ex r UPS r- Cl.ient r Pace Jther:

Tracking #: /!) 5 ;;Jfr'O "?

Project; W0#:40132350 111111 1111111111111111 40132350

Custody Seal on Cooler/Box Present: !i(yes - no Seals intact: .f" yes r no

Custody Seal on Samples Present: r yes rf'-i no Seals intact: r yes - no

Packing Material: .,e: B'§.e Wrap t"-- Bubble Bags r None . r Other

Thermometer UsedB._J ~ Type of lce:@Blue Dry None pc Samples on ice, cooling process has begun

Cooler Temperature Uncorr: 5 /Corr: 5 Biological Tissue is Frozen: r yes

Temp Blank Present: !llyes r no r no Per~on ~nin:t;d Temp should be above freezing to 6°C for all sample except Biota. Date. 7 .

Initials: · Frozen Biota Samples should be received s 0°C. Comments:

Chain of Custody Present: ~es 0No ON/A 1.

Chain of Custody Filled Out: !#Yes 0No ON/A 2.

Chain of Custody Relinquished: mes 0No ON/A 3.

Sampler Name & Signature on COC: tiYes 0No ON/A 4.

Samples Arrived within Hold Time: "'Yes 0No ON/A 5.

- VOA Samples frozen upon receipt 0Yes 0No Date/Time:

Short Hold Time Analysis (<72hr): 0Yes ~o ON/A 6.

Rush Turn Around Time Requested: DYes ~o ON/A 7.

Sufficient Volume: ~es dNo ON/A 8.

Correct Containers Used: mes 0No ON/A 9 .

-Pace Containers Used: .q;tYes 0No ON/A

-Pace IR Containers Used: 0Yes 0No ~N/A

Containers Intact: 'ttYes 0No ON/A 10.

Filtered volume received for Dissolved tests 0Yes 0No riN/A 11.

Sample Labels match COC: ~wNo ON/A 12 aJ_/- dY'l£.-.L('i ,/,,, f c.¥1 ~/)I~ ;(a_h .'l ~~ - -ft; <!uy! '

-1-l -Includes date/time/ID/Analysis Matrix: .::;-, rlV?

All containers needing preservation have been checked. (Non-Compliance noted in 13.) 0Yes 0No ~N/A 13.

r HN03 r H2S04 r NaOH r NaOH +'ZnAcP'-'

- --- --------- -- - --- --- --- ... - - --- -- ----All containers needing preservation are found to be in compliance Y!ith EPA recommendation. Dves ONo ~A (HN'}~~ s_2~ Na<,?~+Zn,t.~t <?:9.:. ~~~ !12) ______________ except10 : V , coliform, TOC, TOX, TOH, Cv Initial when llab Std #ID of luare1 O&G, WI , Phenolics, OTHER: Yes 0No completed preservative Time:

Headspace in VOA Vials ( >6mm): 0Yes riNo ON/A 14.

Trip Blank Present: 0Yes ~ ON/A 15.

Trip Blank Custody Seals Present DYes 0No ~ Pace Trip Blank Lot# (if purchased): Client Notification/ Resolution: If checked, see attached form for additional comments LJ

Project Manager Review: Date: _ __....s_-_,·l_? ... i .. <a ___ _

F-GB-C-031-Rev.03 (9April2015) SCUR Form

J

Attachment D


June 2016

#=CL#

June 20, 2016



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on June 14, 2016. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 30

#=CP#

CERTIFICATIONS


40133738023-6105-016 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 2 of 30

#=SS#

SAMPLE SUMMARY


40133738023-6105-016 CP-SHOREHAM YARD


40133738001 061316-0800-200 Water 06/13/16 08:00 06/14/16 08:40

40133738002 RW07-39-SP-0616-100 Water 06/13/16 13:40 06/14/16 08:40

40133738003 RW07-40-SP-0616-100 Water 06/13/16 13:45 06/14/16 08:40

40133738004 RW06-28-I-0616-100 Water 06/13/16 13:48 06/14/16 08:40

40133738005 RW07-38-I-0616-100 Water 06/13/16 13:52 06/14/16 08:40

40133738006 RW06-27-DR-0616-100 Water 06/13/16 13:55 06/14/16 08:40





Green Bay, WI 54302(920)469-2436

Page 3 of 30

#=SA#



40133738023-6105-016 CP-SHOREHAM YARD


40133738001 061316-0800-200 EPA 8260 71 PASI-GLAP

40133738002 RW07-39-SP-0616-100 EPA 8260 71 PASI-GLAP

40133738003 RW07-40-SP-0616-100 EPA 8260 71 PASI-GLAP

40133738004 RW06-28-I-0616-100 EPA 8260 71 PASI-GLAP

40133738005 RW07-38-I-0616-100 EPA 8260 71 PASI-GLAP

40133738006 RW06-27-DR-0616-100 EPA 8260 71 PASI-GLAP


SM 2540D 1 PASI-GJMN

SM 4500-H+B 1 PASI-GALY

EPA 410.4 1 PASI-GTJJ




Green Bay, WI 54302(920)469-2436

Page 4 of 30

#=AR#

ANALYTICAL RESULTS


40133738023-6105-016 CP-SHOREHAM YARD




Acetone <3.0 ug/L 06/17/16 02:04 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 06/17/16 02:04 107-05-15.0 2.2 1Benzene <0.50 ug/L 06/17/16 02:04 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 06/17/16 02:04 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 06/17/16 02:04 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 06/17/16 02:04 75-27-41.0 0.50 1Bromoform <0.50 ug/L 06/17/16 02:04 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 06/17/16 02:04 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 06/17/16 02:04 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 06/17/16 02:04 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 06/17/16 02:04 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 06/17/16 02:04 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 06/17/16 02:04 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 06/17/16 02:04 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 06/17/16 02:04 75-00-31.0 0.37 1Chloroform <2.5 ug/L 06/17/16 02:04 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 06/17/16 02:04 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 06/17/16 02:04 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 06/17/16 02:04 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 06/17/16 02:04 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 06/17/16 02:04 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 06/17/16 02:04 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 06/17/16 02:04 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 06/17/16 02:04 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 06/17/16 02:04 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 06/17/16 02:04 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 06/17/16 02:04 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 06/17/16 02:04 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 06/17/16 02:04 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 06/17/16 02:04 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 06/17/16 02:04 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 06/17/16 02:04 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 06/17/16 02:04 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 06/17/16 02:04 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 06/17/16 02:04 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 06/17/16 02:04 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 06/17/16 02:04 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 06/17/16 02:04 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 06/17/16 02:04 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 06/17/16 02:04 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 06/17/16 02:04 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 06/17/16 02:04 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 06/17/16 02:04 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 06/17/16 02:04 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 06/17/16 02:04 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 06/17/16 02:04 108-10-15.0 2.1 1




Green Bay, WI 54302(920)469-2436

Page 5 of 30

#=AR#

ANALYTICAL RESULTS


40133738023-6105-016 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 06/17/16 02:04 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 06/17/16 02:04 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 06/17/16 02:04 103-65-11.0 0.50 1Styrene <0.50 ug/L 06/17/16 02:04 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 06/17/16 02:04 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 06/17/16 02:04 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 06/17/16 02:04 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 06/17/16 02:04 109-99-95.0 2.0 1Toluene <0.50 ug/L 06/17/16 02:04 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 06/17/16 02:04 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 06/17/16 02:04 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 06/17/16 02:04 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 06/17/16 02:04 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 06/17/16 02:04 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 06/17/16 02:04 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 06/17/16 02:04 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 06/17/16 02:04 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 06/17/16 02:04 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 06/17/16 02:04 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 06/17/16 02:04 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 06/17/16 02:04 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 06/17/16 02:04 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 86 % 06/17/16 02:04 460-00-470-130 1Dibromofluoromethane (S) 95 % 06/17/16 02:04 1868-53-770-130 1Toluene-d8 (S) 104 % 06/17/16 02:04 2037-26-570-130 1




Green Bay, WI 54302(920)469-2436

Page 6 of 30

#=AR#

ANALYTICAL RESULTS


40133738023-6105-016 CP-SHOREHAM YARD

Sample: RW07-39-SP-0616-100 Lab ID: 40133738002 Collected: 06/13/16 13:40 Received: 06/14/16 08:40 Matrix: Water



Acetone <7.4 ug/L 06/17/16 09:14 67-64-150.0 7.4 2.5Allyl chloride <5.4 ug/L 06/17/16 09:14 107-05-112.5 5.4 2.5Benzene <1.2 ug/L 06/17/16 09:14 71-43-22.5 1.2 2.5Bromobenzene <0.58 ug/L 06/17/16 09:14 108-86-12.5 0.58 2.5Bromochloromethane <0.85 ug/L 06/17/16 09:14 74-97-52.5 0.85 2.5Bromodichloromethane <1.2 ug/L 06/17/16 09:14 75-27-42.5 1.2 2.5Bromoform <1.2 ug/L 06/17/16 09:14 75-25-22.5 1.2 2.5Bromomethane <6.1 ug/L 06/17/16 09:14 74-83-912.5 6.1 2.52-Butanone (MEK) <7.4 ug/L 06/17/16 09:14 78-93-350.0 7.4 2.5n-Butylbenzene <1.2 ug/L 06/17/16 09:14 104-51-82.5 1.2 2.5sec-Butylbenzene <5.5 ug/L 06/17/16 09:14 135-98-812.5 5.5 2.5tert-Butylbenzene <0.45 ug/L 06/17/16 09:14 98-06-62.5 0.45 2.5Carbon tetrachloride <1.2 ug/L 06/17/16 09:14 56-23-52.5 1.2 2.5Chlorobenzene <1.2 ug/L 06/17/16 09:14 108-90-72.5 1.2 2.5Chloroethane <0.94 ug/L 06/17/16 09:14 75-00-32.5 0.94 2.5Chloroform <6.2 ug/L 06/17/16 09:14 67-66-312.5 6.2 2.5Chloromethane <1.2 ug/L 06/17/16 09:14 74-87-32.5 1.2 2.52-Chlorotoluene <1.2 ug/L 06/17/16 09:14 95-49-82.5 1.2 2.54-Chlorotoluene <0.53 ug/L 06/17/16 09:14 106-43-42.5 0.53 2.51,2-Dibromo-3-chloropropane <5.4 ug/L 06/17/16 09:14 96-12-812.5 5.4 2.5Dibromochloromethane <1.2 ug/L 06/17/16 09:14 124-48-12.5 1.2 2.51,2-Dibromoethane (EDB) <0.44 ug/L 06/17/16 09:14 106-93-42.5 0.44 2.5Dibromomethane <1.1 ug/L 06/17/16 09:14 74-95-32.5 1.1 2.51,2-Dichlorobenzene <1.2 ug/L 06/17/16 09:14 95-50-12.5 1.2 2.51,3-Dichlorobenzene <1.2 ug/L 06/17/16 09:14 541-73-12.5 1.2 2.51,4-Dichlorobenzene <1.2 ug/L 06/17/16 09:14 106-46-72.5 1.2 2.5Dichlorodifluoromethane <0.56 ug/L 06/17/16 09:14 75-71-82.5 0.56 2.51,1-Dichloroethane 42.0 ug/L 06/17/16 09:14 75-34-32.5 0.60 2.51,2-Dichloroethane <0.42 ug/L 06/17/16 09:14 107-06-22.5 0.42 2.51,1-Dichloroethene 16.1 ug/L 06/17/16 09:14 75-35-42.5 1.0 2.5cis-1,2-Dichloroethene 27.5 ug/L 06/17/16 09:14 156-59-22.5 0.64 2.5trans-1,2-Dichloroethene 0.90J ug/L 06/17/16 09:14 156-60-52.5 0.64 2.5Dichlorofluoromethane <0.53 ug/L 06/17/16 09:14 75-43-42.5 0.53 2.51,2-Dichloropropane <0.58 ug/L 06/17/16 09:14 78-87-52.5 0.58 2.51,3-Dichloropropane <1.2 ug/L 06/17/16 09:14 142-28-92.5 1.2 2.52,2-Dichloropropane <1.2 ug/L 06/17/16 09:14 594-20-72.5 1.2 2.51,1-Dichloropropene <1.1 ug/L 06/17/16 09:14 563-58-62.5 1.1 2.5cis-1,3-Dichloropropene <1.2 ug/L 06/17/16 09:14 10061-01-52.5 1.2 2.5trans-1,3-Dichloropropene <0.57 ug/L 06/17/16 09:14 10061-02-62.5 0.57 2.5Diethyl ether (Ethyl ether) <5.6 ug/L 06/17/16 09:14 60-29-712.5 5.6 2.5Ethylbenzene <1.2 ug/L 06/17/16 09:14 100-41-42.5 1.2 2.5Hexachloro-1,3-butadiene <5.3 ug/L 06/17/16 09:14 87-68-312.5 5.3 2.5Isopropylbenzene (Cumene) <0.36 ug/L 06/17/16 09:14 98-82-82.5 0.36 2.5p-Isopropyltoluene <1.2 ug/L 06/17/16 09:14 99-87-62.5 1.2 2.5Methylene Chloride <0.58 ug/L 06/17/16 09:14 75-09-22.5 0.58 2.54-Methyl-2-pentanone (MIBK) <5.4 ug/L 06/17/16 09:14 108-10-112.5 5.4 2.5




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Page 7 of 30

#=AR#

ANALYTICAL RESULTS


40133738023-6105-016 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.44 ug/L 06/17/16 09:14 1634-04-42.5 0.44 2.5Naphthalene <6.2 ug/L 06/17/16 09:14 91-20-312.5 6.2 2.5n-Propylbenzene <1.2 ug/L 06/17/16 09:14 103-65-12.5 1.2 2.5Styrene <1.2 ug/L 06/17/16 09:14 100-42-52.5 1.2 2.51,1,1,2-Tetrachloroethane <0.45 ug/L 06/17/16 09:14 630-20-62.5 0.45 2.51,1,2,2-Tetrachloroethane <0.62 ug/L 06/17/16 09:14 79-34-52.5 0.62 2.5Tetrachloroethene 294 ug/L 06/17/16 09:14 127-18-42.5 1.2 2.5Tetrahydrofuran <5.1 ug/L 06/17/16 09:14 109-99-912.5 5.1 2.5Toluene <1.2 ug/L 06/17/16 09:14 108-88-32.5 1.2 2.51,2,3-Trichlorobenzene <5.3 ug/L 06/17/16 09:14 87-61-612.5 5.3 2.51,2,4-Trichlorobenzene <5.5 ug/L 06/17/16 09:14 120-82-112.5 5.5 2.51,1,1-Trichloroethane 98.0 ug/L 06/17/16 09:14 71-55-62.5 1.2 2.51,1,2-Trichloroethane <0.49 ug/L 06/17/16 09:14 79-00-52.5 0.49 2.5Trichloroethene 15.0 ug/L 06/17/16 09:14 79-01-62.5 0.83 2.5Trichlorofluoromethane <0.46 ug/L 06/17/16 09:14 75-69-42.5 0.46 2.51,2,3-Trichloropropane <1.2 ug/L 06/17/16 09:14 96-18-42.5 1.2 2.51,1,2-Trichlorotrifluoroethane <2.0 ug/L 06/17/16 09:14 76-13-112.5 2.0 2.51,2,4-Trimethylbenzene <1.2 ug/L 06/17/16 09:14 95-63-62.5 1.2 2.51,3,5-Trimethylbenzene <1.2 ug/L 06/17/16 09:14 108-67-82.5 1.2 2.5Vinyl chloride <0.44 ug/L 06/17/16 09:14 75-01-42.5 0.44 2.5m&p-Xylene <2.5 ug/L 06/17/16 09:14 179601-23-15.0 2.5 2.5o-Xylene <1.2 ug/L 06/17/16 09:14 95-47-62.5 1.2 2.5Surrogates4-Bromofluorobenzene (S) 85 % 06/17/16 09:14 460-00-470-130 2.5Dibromofluoromethane (S) 95 % 06/17/16 09:14 1868-53-770-130 2.5Toluene-d8 (S) 104 % 06/17/16 09:14 2037-26-570-130 2.5




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#=AR#

ANALYTICAL RESULTS


40133738023-6105-016 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

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#=AR#

ANALYTICAL RESULTS


40133738023-6105-016 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

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#=AR#

ANALYTICAL RESULTS


40133738023-6105-016 CP-SHOREHAM YARD

Sample: RW06-28-I-0616-100 Lab ID: 40133738004 Collected: 06/13/16 13:48 Received: 06/14/16 08:40 Matrix: Water







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Methyl-tert-butyl ether <0.17 ug/L 06/17/16 02:26 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 06/17/16 02:26 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 06/17/16 02:26 103-65-11.0 0.50 1Styrene <0.50 ug/L 06/17/16 02:26 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 06/17/16 02:26 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 06/17/16 02:26 79-34-51.0 0.25 1Tetrachloroethene 7.2 ug/L 06/17/16 02:26 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 06/17/16 02:26 109-99-95.0 2.0 1Toluene <0.50 ug/L 06/17/16 02:26 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 06/17/16 02:26 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 06/17/16 02:26 120-82-15.0 2.2 11,1,1-Trichloroethane 3.6 ug/L 06/17/16 02:26 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 06/17/16 02:26 79-00-51.0 0.20 1Trichloroethene 0.78J ug/L 06/17/16 02:26 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 06/17/16 02:26 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 06/17/16 02:26 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 06/17/16 02:26 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 06/17/16 02:26 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 06/17/16 02:26 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 06/17/16 02:26 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 06/17/16 02:26 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 06/17/16 02:26 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 86 % 06/17/16 02:26 460-00-470-130 1Dibromofluoromethane (S) 96 % 06/17/16 02:26 1868-53-770-130 1Toluene-d8 (S) 105 % 06/17/16 02:26 2037-26-570-130 1




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40133738023-6105-016 CP-SHOREHAM YARD

Sample: RW06-27-DR-0616-100 Lab ID: 40133738006 Collected: 06/13/16 13:55 Received: 06/14/16 08:40 Matrix: Water



Acetone <3.0 ug/L 06/17/16 08:52 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 06/17/16 08:52 107-05-15.0 2.2 1Benzene <0.50 ug/L 06/17/16 08:52 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 06/17/16 08:52 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 06/17/16 08:52 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 06/17/16 08:52 75-27-41.0 0.50 1Bromoform <0.50 ug/L 06/17/16 08:52 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 06/17/16 08:52 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 06/17/16 08:52 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 06/17/16 08:52 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 06/17/16 08:52 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 06/17/16 08:52 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 06/17/16 08:52 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 06/17/16 08:52 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 06/17/16 08:52 75-00-31.0 0.37 1Chloroform <2.5 ug/L 06/17/16 08:52 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 06/17/16 08:52 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 06/17/16 08:52 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 06/17/16 08:52 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 06/17/16 08:52 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 06/17/16 08:52 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 06/17/16 08:52 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 06/17/16 08:52 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 06/17/16 08:52 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 06/17/16 08:52 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 06/17/16 08:52 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 06/17/16 08:52 75-71-81.0 0.22 11,1-Dichloroethane 16.2 ug/L 06/17/16 08:52 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 06/17/16 08:52 107-06-21.0 0.17 11,1-Dichloroethene 5.2 ug/L 06/17/16 08:52 75-35-41.0 0.41 1cis-1,2-Dichloroethene 18.7 ug/L 06/17/16 08:52 156-59-21.0 0.26 1trans-1,2-Dichloroethene 0.40J ug/L 06/17/16 08:52 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 06/17/16 08:52 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 06/17/16 08:52 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 06/17/16 08:52 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 06/17/16 08:52 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 06/17/16 08:52 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 06/17/16 08:52 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 06/17/16 08:52 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 06/17/16 08:52 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 06/17/16 08:52 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 06/17/16 08:52 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 06/17/16 08:52 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 06/17/16 08:52 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 06/17/16 08:52 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 06/17/16 08:52 108-10-15.0 2.1 1




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ANALYTICAL RESULTS


40133738023-6105-016 CP-SHOREHAM YARD

Sample: RW06-27-DR-0616-100 Lab ID: 40133738006 Collected: 06/13/16 13:55 Received: 06/14/16 08:40 Matrix: Water



Methyl-tert-butyl ether <0.17 ug/L 06/17/16 08:52 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 06/17/16 08:52 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 06/17/16 08:52 103-65-11.0 0.50 1Styrene <0.50 ug/L 06/17/16 08:52 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 06/17/16 08:52 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 06/17/16 08:52 79-34-51.0 0.25 1Tetrachloroethene 31.2 ug/L 06/17/16 08:52 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 06/17/16 08:52 109-99-95.0 2.0 1Toluene <0.50 ug/L 06/17/16 08:52 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 06/17/16 08:52 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 06/17/16 08:52 120-82-15.0 2.2 11,1,1-Trichloroethane 8.5 ug/L 06/17/16 08:52 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 06/17/16 08:52 79-00-51.0 0.20 1Trichloroethene 5.8 ug/L 06/17/16 08:52 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 06/17/16 08:52 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 06/17/16 08:52 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 06/17/16 08:52 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 06/17/16 08:52 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 06/17/16 08:52 108-67-81.0 0.50 1Vinyl chloride 0.43J ug/L 06/17/16 08:52 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 06/17/16 08:52 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 06/17/16 08:52 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 87 % 06/17/16 08:52 460-00-470-130 1Dibromofluoromethane (S) 95 % 06/17/16 08:52 1868-53-770-130 1Toluene-d8 (S) 108 % 06/17/16 08:52 2037-26-570-130 1




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ANALYTICAL RESULTS


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ANALYTICAL RESULTS


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Analytical Method: SM 2540D2540D Total Suspended Solids

Total Suspended Solids <0.95 mg/L 06/16/16 10:342.0 0.95 1

Analytical Method: SM 4500-H+B4500H+ pH, Electrometric

pH 7.7 Std. Units 06/17/16 10:10 H60.10 0.010 1

Analytical Method: EPA 410.4 Preparation Method: EPA 410.4410.4 COD

Chemical Oxygen Demand <13.4 mg/L 06/15/16 12:1106/15/16 07:5244.8 13.4 1




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40133738023-6105-016 CP-SHOREHAM YARD




MSV/33951EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40133738001, 40133738002, 40133738003, 40133738004, 40133738005, 40133738006, 40133738007



METHOD BLANK: 1350022Associated Lab Samples: 40133738001, 40133738002, 40133738003, 40133738004, 40133738005, 40133738006, 40133738007

Matrix: Water

AnalyzedMDL





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40133738023-6105-016 CP-SHOREHAM YARD




METHOD BLANK: 1350022Associated Lab Samples: 40133738001, 40133738002, 40133738003, 40133738004, 40133738005, 40133738006, 40133738007

Matrix: Water

AnalyzedMDL


Parameter UnitsLCS



1,1,1-Trichloroethane ug/L 49.150 98 70-1311,1,2,2-Tetrachloroethane ug/L 43.950 88 67-1301,1,2-Trichloroethane ug/L 49.050 98 70-1301,1,2-Trichlorotrifluoroethane ug/L 57.650 115 50-1501,1-Dichloroethane ug/L 49.150 98 70-1331,1-Dichloroethene ug/L 49.550 99 70-1301,2,4-Trichlorobenzene ug/L 47.450 95 70-1301,2-Dibromo-3-chloropropane ug/L 43.850 88 50-1501,2-Dibromoethane (EDB) ug/L 51.450 103 70-1301,2-Dichlorobenzene ug/L 53.250 106 70-130




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40133738023-6105-016 CP-SHOREHAM YARD


Parameter UnitsLCS



1,2-Dichloroethane ug/L 42.850 86 70-1301,2-Dichloropropane ug/L 49.050 98 70-1301,3-Dichlorobenzene ug/L 52.650 105 70-1301,4-Dichlorobenzene ug/L 52.250 104 70-130Benzene ug/L 44.950 90 60-135Bromodichloromethane ug/L 50.150 100 70-130Bromoform ug/L 50.250 100 70-130Bromomethane ug/L 47.350 95 33-130Carbon tetrachloride ug/L 50.450 101 70-138Chlorobenzene ug/L 55.450 111 70-130Chloroethane ug/L 56.450 113 51-130Chloroform ug/L 45.250 90 70-130Chloromethane ug/L 54.250 108 25-132cis-1,2-Dichloroethene ug/L 44.150 88 69-130cis-1,3-Dichloropropene ug/L 47.050 94 70-130Dibromochloromethane ug/L 54.750 109 70-130Dichlorodifluoromethane ug/L 46.850 94 23-130Ethylbenzene ug/L 55.550 111 70-136Isopropylbenzene (Cumene) ug/L 57.850 116 70-140m&p-Xylene ug/L 118100 118 70-138Methyl-tert-butyl ether ug/L 43.650 87 66-138Methylene Chloride ug/L 46.050 92 70-130o-Xylene ug/L 56.850 114 70-134Styrene ug/L 58.250 116 70-133Tetrachloroethene ug/L 56.950 114 70-138Toluene ug/L 56.850 114 70-130trans-1,2-Dichloroethene ug/L 48.450 97 70-131trans-1,3-Dichloropropene ug/L 51.050 102 69-130Trichloroethene ug/L 51.150 102 70-130Trichlorofluoromethane ug/L 52.650 105 50-150Vinyl chloride ug/L 51.950 104 49-1304-Bromofluorobenzene (S) % 95 70-130Dibromofluoromethane (S) % 91 70-130Toluene-d8 (S) % 108 70-130

Parameter UnitsMS



MSSpikeResult

40133795001

1350246

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L 50 91 70-13493 3 2050<0.50 45.5 46.71,1,2,2-Tetrachloroethane ug/L 50 84 67-13087 4 2050<0.25 42.1 43.71,1,2-Trichloroethane ug/L 50 94 70-13096 3 2050<0.20 46.8 48.21,1,2-Trichlorotrifluoroethane ug/L 50 109 50-150110 1 2050<0.81 54.5 54.91,1-Dichloroethane ug/L 50 91 70-13496 5 2050<0.24 45.4 47.81,1-Dichloroethene ug/L 50 92 68-13696 4 2050<0.41 45.8 47.9




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40133738023-6105-016 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40133795001

1350246

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,2,4-Trichlorobenzene ug/L 50 93 62-13997 4 2050<2.2 46.5 48.41,2-Dibromo-3-chloropropane

ug/L 50 81 50-15091 12 2050<2.2 40.5 45.5

1,2-Dibromoethane (EDB) ug/L 50 100 70-130100 0 2050<0.18 50.0 49.91,2-Dichlorobenzene ug/L 50 102 70-130105 3 2050<0.50 51.2 52.71,2-Dichloroethane ug/L 50 80 70-13084 5 2050<0.17 39.8 42.01,2-Dichloropropane ug/L 50 97 70-13092 5 2050<0.23 48.3 45.91,3-Dichlorobenzene ug/L 50 102 70-131105 3 2050<0.50 50.9 52.31,4-Dichlorobenzene ug/L 50 103 70-130104 2 2050<0.50 51.3 52.2Benzene ug/L 50 85 57-13886 2 2050<0.50 42.3 43.0Bromodichloromethane ug/L 50 97 70-13095 1 2050<0.50 48.3 47.7Bromoform ug/L 50 96 70-130102 6 2050<0.50 48.2 51.1Bromomethane ug/L 50 103 33-130114 10 2750<2.4 51.5 57.0Carbon tetrachloride ug/L 50 96 70-13899 2 2050<0.50 48.2 49.4Chlorobenzene ug/L 50 106 70-130108 2 2050<0.50 53.1 54.1Chloroethane ug/L 50 103 51-130109 6 2050<0.37 51.5 54.4Chloroform ug/L 50 84 70-13087 3 2050<2.5 42.0 43.3Chloromethane ug/L 50 101 25-132104 2 2050<0.50 50.7 51.9cis-1,2-Dichloroethene ug/L 50 85 61-14086 1 2050<0.26 42.6 42.9cis-1,3-Dichloropropene ug/L 50 92 70-13091 1 2050<0.50 45.9 45.5Dibromochloromethane ug/L 50 106 70-130105 0 2050<0.50 52.8 52.6Dichlorodifluoromethane ug/L 50 86 23-13091 5 2050<0.22 43.0 45.4Ethylbenzene ug/L 50 106 70-138106 0 2050<0.50 53.1 53.2Isopropylbenzene (Cumene) ug/L 50 111 70-152111 0 2050<0.14 55.4 55.5m&p-Xylene ug/L 100 113 70-140115 2 20100<1.0 113 115Methyl-tert-butyl ether ug/L 50 81 66-13986 6 2050<0.17 40.4 43.0Methylene Chloride ug/L 50 84 70-13089 6 2050<0.23 41.9 44.5o-Xylene ug/L 50 109 70-134110 0 2050<0.50 54.7 54.8Styrene ug/L 50 112 70-138111 1 2050<0.50 55.9 55.4Tetrachloroethene ug/L 50 112 70-148110 2 2050<0.50 55.9 54.9Toluene ug/L 50 109 70-130109 0 2050<0.50 54.7 54.7trans-1,2-Dichloroethene ug/L 50 89 70-13393 5 2050<0.26 44.3 46.4trans-1,3-Dichloropropene ug/L 50 99 69-130101 3 2050<0.23 49.3 50.6Trichloroethene ug/L 50 99 70-13198 1 2050<0.33 49.6 49.1Trichlorofluoromethane ug/L 50 99 50-150101 2 2050<0.18 49.5 50.7Vinyl chloride ug/L 50 96 49-133102 7 2050<0.18 47.8 51.04-Bromofluorobenzene (S) % 96 70-13096Dibromofluoromethane (S) % 89 70-13089Toluene-d8 (S) % 106 70-130106




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40133738023-6105-016 CP-SHOREHAM YARD




WET/25450SM 2540D

SM 2540D2540D Total Suspended Solids

Associated Lab Samples: 40133738007



METHOD BLANK: 1350766Associated Lab Samples: 40133738007

Matrix: Water

AnalyzedMDL

Total Suspended Solids mg/L <0.48 1.0 06/16/16 10:340.48

Parameter UnitsLCS



Total Suspended Solids mg/L 104100 104 80-120

Parameter UnitsDup

ResultMaxRPD QualifiersRPDResult

401337810011350788SAMPLE DUPLICATE:

Total Suspended Solids mg/L 304 R110 5276

Parameter UnitsDup



Total Suspended Solids mg/L 5.0 R18 54.6




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40133738023-6105-016 CP-SHOREHAM YARD




WET/25467SM 4500-H+B

SM 4500-H+B4500H+B pH


Parameter UnitsDup



pH Std. Units 6.8 H60 56.8




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40133738023-6105-016 CP-SHOREHAM YARD




WETA/34157EPA 410.4

EPA 410.4410.4 COD




METHOD BLANK: 1349980Associated Lab Samples: 40133738007

Matrix: Water

AnalyzedMDL

Chemical Oxygen Demand mg/L <13.4 44.8 06/15/16 12:0913.4

Parameter UnitsLCS



Chemical Oxygen Demand mg/L 492500 98 90-110

Parameter UnitsMS



MSSpikeResult

40133349001

1349983

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chemical Oxygen Demand mg/L 4000 104 90-110102 1 1040001110 5280 5210

Parameter UnitsMS



MSSpikeResult

40133502001

1349985

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chemical Oxygen Demand mg/L 4000 99 90-110100 1 1040001990 5960 6000




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#=QL#

QUALIFIERS


40133738023-6105-016 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES


ANALYTE QUALIFIERS

Analysis initiated outside of the 15 minute EPA required holding time.H6RPD value was outside control limits.R1




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#=CR#



40133738023-6105-016 CP-SHOREHAM YARD


40133738001 MSV/33951061316-0800-200 EPA 826040133738002 MSV/33951RW07-39-SP-0616-100 EPA 826040133738003 MSV/33951RW07-40-SP-0616-100 EPA 826040133738004 MSV/33951RW06-28-I-0616-100 EPA 826040133738005 MSV/33951RW07-38-I-0616-100 EPA 826040133738006 MSV/33951RW06-27-DR-0616-100 EPA 826040133738007 MSV/33951SE EFFLUENT EPA 8260

40133738007 WET/25450SE EFFLUENT SM 2540D

40133738007 WET/25467SE EFFLUENT SM 4500-H+B

40133738007 WETA/34157 WETA/34164SE EFFLUENT EPA 410.4 EPA 410.4




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Pag

e 28

of 3

0(Please Print Clearly)

Company Name:

UPPER MIDWEST REGION

1\11111: 612-607-1700 WI:

Branch/Location: Analytical. www.pacelabs.oom

~ ~ • I !..JC2l??'Pi

Project Contact:

Phone:

Project Number:

Project Name:

Project State:

Sampled By (Print):

Sampled By (Sign):

PO#: Regulatory Program:

CHAIN OF CUSTODY *Preservation Codes

A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

H=Sodium Bisulfate Solution

FILTERED? (YES/NO)

PRESERVATION (CODE)*

YIN

!=Sodium Thiosulfate J=Other

Data Package Options (bHlable)

MS/MSD 0 On your sample

(billable) 0 NOT needed on

your sample

Matrix Codes

0 EPA Level Ill

0 EPA Level IV

A=Air B =Biota C =Charcoal O=Oil S=Soll SI= Slud

Rush Turnaround Time Requested - Prelims (Rush TAT subject to approval/surcharge)

Date Needed: Transmit Prelim Rush Results by (complete what you want):

alf #1:

W=Water OW= Drinking Water GW =Ground Water SW = Surface Water WW= Waste Water WP=Wi

Samples on HOLD are subject to

special pricing and release of llablllty

Relinquished By:

C019a(27 Jun2006)

Date/Time: Received By:

Quote#:

Mail To Contact:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CLIENT COMMENTS

Date/Time:

LAB COMMENTS Profile#

c/oi3373i

of 30

,.w*'j Document Name Revised Date 24Feb2016 • l / /' ,, Minneapolis Cooler Transfer Check List Page 1 of 1 / __ -,Pace Analytical -Document Number: Issuing Authority: F-MN-C-214-Rev.OO Pace Minnesota Quality Office

Minneapolis Service Center Cooler Transfer Check list '-10/6-37-&?

Client:

Desetination Lab:

Received with Custody Seal: Yes

Custody Seal Intact: Yes No

Temp Read Corrected Temp Correction Factor

Temperature C: l IRGun:~

{\j Samples on ice, cooling process has begun

Rush/Short Hold:

Containers Intact: No

Re-packed and Re-Iced:

Temp Blank Included: No

Shipped By/Date:

Notes:

of 30


Green Bay, WI 54302

aAnalytica( ; - Project #: ,.

.Client Name: \"l:[J\{>.e>C' Q.~. W0#:40133738 1111111111111111111111 Courier: r Fed Ex r UPS :-- Client r Pace :)th;\);:)()._\~ t;()

Tracking#: \ \)"] :.\9.:J~ - @ Custody Seal on Cooler/Box Present: rf yes - no Seals intact: rf yes r no ..._ __

40133738

Custody Seal on Samples Present: r yes f/ no Seals intact: r yes 7 no

Packing Material: rl Bubble Wr~ r/ Bubble Bags r None r Other

Thermometer Used 5R -O'?S Type of Ice: 9 Blue Dry None samples on ice, cooling process has begun

Cooler Temperature Uncorr: ~ /Corr:.S Biological Tissue is Frozen: r yes

Temp Blank Present: ryes rt no

Temp should be above freezing to 6°C for all sample except Biota. Frozen Biota Samples should be received s o•c. Comments:

Chain of Custody Present:

Chain of Custody Filled Out:

Chain of Custody Relinquished:

Sampler Name & Signature on COC:

Samples Arrived within Hold Time:

- VOA Samples frozen upon receipt

Short Hold Time Analysis (<72hr):

Rush Turn Around Time Requested:

Sufficient Volume:

Correct Containers Used:

-Pace Containers Used:

-Pace IR Containers Used:

Containers Intact:

Filtered volume received for Dissolved tests

Sample Labels match COC:

-Includes date/time/ID/Analysis Matrix:

0No ON/A 1.

0No ON/A 2.

~Yes ONo ON/A 3.

0No ON/A 4.

/Yes 0No ON/A 5.

0Yes ONo Date/Time:

0Yes ¢No ON/A 6.

0Yes •[}(No ON/A 7.

¢Yes 0No ON/A 8. , lYes 0No ON/A 9.

1Yes 0No ON/A

0Yes 0No /JN/A

DYes ONo ON/A 10.

0Yes ONo 4N/A 11.

r no

All containers needing preservation have been checked. ,.t (Non-Compliance noted in 13.) ~Yes ONo ON/A 13. r HN03 f H2S04 r NaOH r NaOH +ZnAct

Att containera needing preserV"ation are found to be -in - - - - - - - - - - - -complia ... ~~A recommendation. J1(, o ON (HN03(H2804 <2; aOH+ZnAct ~9. NaOH ~12) r Yes No /A e~eptlonSL_VQ&}coliform~ roe, -Tox-:Toi'.i.- - - - - - - - - L - - - - - - - - ..... ln"""it,...ia"'"I -w .... he_11 ___ -. _-_ j..,.L'""ab'""S""t..,.d""'#"'lo-o-=f------,,~uatr::1etr--------t O&G, WID~Phenolics, OTHER: f-lYes ONo completed\\ \'('('tpreservative Time:

Headspace in VOA Vials ( >6mm): 0Yes i;i'No ON/A 14.

Trip Blank Present:

Trip Blank Custody Seals Present

Pace Trip Blank Lot# (if purchased): ~lo_::::S Client Notification/ Resolution: If checked, see attached form for additional comments LJ

Person Contacted: Date/Time: --------------------Comments/ Resolution: ------------------------------------------------------------------

Project Manager Review: oate: __ ce_,.._\1 .... li.e....._ ___ _

F-GB-C-031-Rev.03 (9April2015) SCUR Form

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