document

<I' Golder Associates January 27, 2017

Metropolitan Council Environmental Services Industrial Waste Division 390 Robert St. N. St. Paul, MN 55101

Attention: Ms. Ashley Corbeille

Project No.:023-6105.017

RE: 2016 FOURTH QUARTER REPORTING PERIOD INFORMATION AND DECEMBER SAMPLING RESULTS SM Rs INDUSTRIAL DISCHARGE PERMIT NUMBER 2289 SOUTHEAST PUMP AND TREAT SYSTEM CANADIAN PACIFIC SHOREHAM FACILITY

Dear Ms. Corbeille:

On behalf of Canadian Pacific, enclosed is the 2016 Fourth Quarter Reporting Period Information -SMR and December 2016 Sampling Resu/ts-SMR for the site located at 281h & Central Avenue NE, Minneapolis MN. In accordance with the Metropolitan Council Environmental Services (MCES) Industrial Discharge Permit Number 2289, effective October 1, 2016 (MCES permit), this submittal documents the volume and quality of water discharged from the groundwater pump and treat system owned by Canadian Pacific.

The total quantity of water discharged into the sanitary sewer system during this reporting quarter was 3, 787,600 gallons. The average daily discharge for the system was 41, 170 gallons.

Required information for the discharge is provided as follows: • Attachment A - Reporting Period Information - SMR. • Attachment B - Sampling Results - SMR • Attachment C - Analytical data from Pace Analytical Services, LLC for the December 2016

monthly sampling event. • Attachment D - Field Instrument pH calibration record.

Analytical results from the December 2016 sampling event1 showed that the treated discharge water was in compliance with the MCES permit discharge limitations during this reporting period.

1 Note that in addition to the required sampling for sample point SP-01 (identified as sample SE EFFLUENT in the attached lab report), Canadian Pacific voluntarily samples groundwater from the five recovery wells (RW07-39-SP, RW07-40-SP, RW06-28-I, RW07-38-I, RW06-27-BR) on a quarterly basis. All analytical data is included in Attachment C; only the required discharge data is included in the Sampling Results - SMR in (Attachment 8).

Golder Associates Inc. 1751 West County Rd. B, Ste. 105

Roseville, MN USA 55113 Tel: (651) 697-9737 Fax: (651) 697-9737 www.golder.com

Golder Associates: Operations in Africa, Asia, Australasia, Europe, North America and South America

Ms. Ashley Corbeille MCES 2

January 27, 2017 023-6105.017

If you have any questions or comments, please do not hesitate to contact Barbara Johnson at (651) 697-9737. Thank you for your assistance in this matter.

Very truly yours,

GOLDER ASSOCIATES INC.

Alan Phillips Staff Geologist

Cc: Ms. Aimee Zack, CP Ms. Claire Mackler, Golder

Barbara Johnson, PE Associate

<Ii Golder Associates

Attachment A

REPORTING PERIOD INFORMATION – SELF-MONITORING REPORT

Metropolitan Council Environmental Services Industrial Waste & Pollution Prevention Section 390 North Robert Street St. Paul, Minnesota 55101-1805

For MCES Use Only

Permit No: Staff: Received: 0 L 45 E

REPORTING PERIOD INFORMATION - SMR for Special Discharge Permits

1. Permittee Name: Canadian Pacific Railway Permit No: 2289 ----2. Facility Address: 28th Ave NE & Central Ave NE, Minneapolis, MN 55418

Billing Address Changed? 0 Yes EJ No Changes: ---------------------

Mailing Address Changed? 0 Yes EJ No Changes:

3. Reporting Period: Year: 2016 Check applicable period below:

Quarterly Reporters: D Jan-Mar D Apr-Jun D Jul-Sep [!] Oct-Dec

Annual Reporters: D Jan-Dec

4. Discharge Information:

Indicate whether the wastewater was discharged on-site and/or hauled during this reporting period, and complete the associated questions. If no wastewater was discharged to MCES during this reporting period, indicate no discharge.

D No Discharge to MCES during this reporting period

If no discharge is selected, proceed directly to Item #5.

[{] On-Site Discharge

A. Total volume discharged during this reporting period (gallons): 3,787,600 ----------------

B. Total days of discharge during this reporting period (days): 92 ----------------

C. Average volume discharged per day (gallons/day): 41 , 170 ----------------

D. Method of volume determination for this period: Effluent flow meter ---------------~

D Hauled Discharge

A. Total number of loads hauled during this reporting period:

B. Total volume hauled during this reporting period (gallons):

C. Total days of discharge during this reporting period (days):

D. Average volume per discharge day (gallons/day):

E. Method of volume determination for this period:

F. Liquid Waste Hauler name and permit number:

Report form help sheet

Spec-SMR-RPl-2016 Page 1of2

5. Changes/Problems: Have there been significant process problems/changes during this reporting period?

D Yes [!]No If Yes with no previous MCES notification, add explanation below:

6. Planned Changes: Are there any planned or expected future changes that will impact discharge volume or quality?

D Yes [!]No If Yes, add explanation below:

7. Data Sheets: I certify that all sampling data that occurred during this reporting period has been submitted to MCES.

Ej Yes D No If No, add explanation below:

8. Representative Discharge: Are the analytical results submitted during this reporting period representative of the

wastewater discharged during this reporting period?

E!Yes D No If No, add explanation below:

9. General comments regarding submission:

10. Certification Statement:

"I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to ensure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties under law for submitting false information, including the possibility of fine and imprisonment for known violations."

Name (print): Barbara Johnson, PE Title: Authorized Representative for Canadian Pacific

Signature: .&vvJ~ Date: I b1/1z

Email: [email protected] Phone: 651-697-9737

Spec-SMR-RPl-2016 Page 2 of 2

Attachment B

SAMPLING RESULTS – SELF MONITORING REPORT December 2016

Metropolitan Council Environmental Services Industrial Waste & Pollution Prevention Section 390 North Robert Street St. Paul, Minnesota 55101-1805

For MCES Use Only

Permit No: Staff:

Received: 0 L 45 E

SAMPLING RESULTS - SMR for Standard and Special Discharge Permits Please complete Page 2 of this form for each monitoring point with sampling requirements in Attachment A of the Permit.

1. Permittee Name: Canadian Pacific Railway Permit No: 2289 ------2. Facility Address: 28th Ave NE & Central Ave NE, Minneapolis, MN 55418

3. Reporting Period: Year: 20_1_6 ___ _ Choose applicable period below:

D

Quarterly Reporter: D Jan-Mar

Semi-Annual Reporter: D Jan-Jun

Annual Reporter: D Jan-Dec

D Apr-Jun

D Jul-Dec

D Jul-Sep EJ Oct-Dec

No discharge/No sampling this period. If checked, proceed to section 9 below and do not complete page 2.

4. Proper Sampling: Were all samples collected and composited according to permit requirements?

EJ Yes D No If No, add explanation below:

5. Proper Analysis: Were all analyses conducted per permit requirements? Ej Yes D No If No, add explanation below:

6. Representative Discha~: Are the an~ical results representative of the wastewater discharged during this monitoring event? ~ Yes LJ No If No, add explanation below:

7. Compliance Status: Compare the analytical results with the corresponding discharge limits in your Permit. Do any analytical results exceed the corresponding discharge limit(s) in your Permit? D Yes El No If Yes, add explanation below:

When did you become aware of the exceedance(s)?

8. General comments regard ing submission:

9. Certification Statement: "I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to ensure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties under law for submitting false information, including the possibility of fine and imprisonment for known violations."

Name (print) : Barbara Johnson, PE

Signature: d~-~ Email: [email protected]

Page 1of2

Title: Authorized Representative for Canadian Pacific

Date:

Phone: 651-697-9737

Reporl form help sheet

SMR-SR-2016

Sample Results: Submit one result sheet for each sampling day per monitoring point. Enter daily values for each sampling event from one monitoring point, in accordance with requirements in the Industrial Discharge Permit (Section 8). Daily and long-term values shall be compared to Discharge Limitations in Permit Section A.1 for compliance determinations. Attach all laboratory data sheets and supporting calculations.

Monitoring Point: SP-01 Description: Effluent discharge line

Sample Start Date & Time: 12/12/1614:30 Sample End Date & Time: _1_2_11_21_1_6_1_4_:3_0 ______ _

Discharge volume through monitoring point on sampling day: 27,683 (estimated)

Sample collected by: D Permittee EJ Other, name: Golder Associates Inc.

gallons

Method of collection: 0 Manual D Automatic

Sample composited by: D Permittee D Other, name: ------------- Composite method: N_A ____________ _

Substance Analytical Result Unit Detection Limits Analysis Method Sample Method

Sample Laboratory Result Container Type Name

pH 6.7 s.u. 0-14 4500-H+ Grab-Single Other Field Measurement

Total Suspended Solids <0.95 mg/I 0.95 25400 Grab - Single Plastic - 1 quart Pace Analytical Services, LLC

Chemical Oxygen Demand <14.2 mg/I 14.2 410.4 Grab - Single Other Pace Analytical Services, LLC

1, 1-Dichloroethane 0.0217 mg/I 0.00024 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, LLC

1, 1-Dichloroethene 0.0062 mg/I 0.00041 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, LLC

cis-1,2-Dichloroethene 0.0188 mg/I 0.00026 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, LLC

trans-1,2-Dichloroethene 0.00026 mg/I 0.00026 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, LLC

Tetrachloroethene 0.0470 mg/I 0.00050 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services. LLC

1, 1, 1-Trichloroethane 0.0211 mg/I 0.00050 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services. LLC

Trichloroethene 0.0057 mg/I 0.00033 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, LLC

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I

Page 2 of 2 SMR-SR-2016

Attachment C

ANALYTICAL DATA FROM PACE ANALYTICAL SERVICES, LLC

December 2016

#=CL#

December 21, 2016

LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40143366

40143366Project:Pace Project No.:

RE:

Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102

023-6105-017 CP-SHOREHAM YARD

Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on December 13, 2016.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Laurie [email protected] Manager

Enclosures

REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC1241 Bellevue Street - Suite 9

Green Bay, WI 54302(920)469-2436

Page 1 of 28

#=CP#

CERTIFICATIONS

Pace Project No.:Project:

40143366023-6105-017 CP-SHOREHAM YARD

Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky UST Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334New York Certification #: 12064North Dakota Certification #: R-150

Virginia VELAP ID: 460263South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1Wisconsin Certification #: 405132750Wisconsin DATCP Certification #: 105-444USDA Soil Permit #: P330-16-00157Federal Fish & Wildlife Permit #: LE51774A-0




Green Bay, WI 54302(920)469-2436

Page 2 of 28

#=SS#

SAMPLE SUMMARY


40143366023-6105-017 CP-SHOREHAM YARD

Lab ID Sample ID Matrix Date Collected Date Received

40143366001 121216-0800-200 Water 12/12/16 08:00 12/13/16 09:00

40143366002 RW07-39-SP-1216-100 Water 12/12/16 14:05 12/13/16 09:00

40143366003 RW07-40-SP-1216-100 Water 12/12/16 14:10 12/13/16 09:00

40143366004 RW06-28-I-1216-100 Water 12/12/16 14:15 12/13/16 09:00

40143366005 RW07-38-I-1216-100 Water 12/12/16 14:20 12/13/16 09:00

40143366006 RW06-27-BR-1216-100 Water 12/12/16 14:25 12/13/16 09:00

40143366007 SE EFFLUENT Water 12/12/16 14:30 12/13/16 09:00




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#=SA#

SAMPLE ANALYTE COUNT


40143366023-6105-017 CP-SHOREHAM YARD

Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts

40143366001 121216-0800-200 EPA 8260 71 PASI-GMDS

40143366002 RW07-39-SP-1216-100 EPA 8260 71 PASI-GMDS

40143366003 RW07-40-SP-1216-100 EPA 8260 71 PASI-GMDS

40143366004 RW06-28-I-1216-100 EPA 8260 71 PASI-GMDS

40143366005 RW07-38-I-1216-100 EPA 8260 71 PASI-GMDS

40143366006 RW06-27-BR-1216-100 EPA 8260 71 PASI-GMDS

40143366007 SE EFFLUENT EPA 8260 71 PASI-GMDS

SM 2540D 1 PASI-GDDY

EPA 410.4 1 PASI-GTJJ




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Page 4 of 28

#=AR#

ANALYTICAL RESULTS


40143366023-6105-017 CP-SHOREHAM YARD

Sample: 121216-0800-200 Lab ID: 40143366001 Collected: 12/12/16 08:00 Received: 12/13/16 09:00 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 82608260 MSV

Acetone <3.0 ug/L 12/14/16 14:20 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 12/14/16 14:20 107-05-15.0 2.2 1Benzene <0.50 ug/L 12/14/16 14:20 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 12/14/16 14:20 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 12/14/16 14:20 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 12/14/16 14:20 75-27-41.0 0.50 1Bromoform <0.50 ug/L 12/14/16 14:20 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 12/14/16 14:20 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 12/14/16 14:20 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 12/14/16 14:20 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 12/14/16 14:20 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 12/14/16 14:20 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 12/14/16 14:20 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 12/14/16 14:20 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 12/14/16 14:20 75-00-31.0 0.37 1Chloroform <2.5 ug/L 12/14/16 14:20 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 12/14/16 14:20 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 12/14/16 14:20 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 12/14/16 14:20 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 12/14/16 14:20 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 12/14/16 14:20 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 12/14/16 14:20 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 12/14/16 14:20 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 12/14/16 14:20 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 12/14/16 14:20 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 12/14/16 14:20 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 12/14/16 14:20 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 12/14/16 14:20 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 12/14/16 14:20 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 12/14/16 14:20 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 12/14/16 14:20 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 12/14/16 14:20 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 12/14/16 14:20 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 12/14/16 14:20 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 12/14/16 14:20 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 12/14/16 14:20 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 12/14/16 14:20 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 12/14/16 14:20 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 12/14/16 14:20 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 12/14/16 14:20 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 12/14/16 14:20 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 12/14/16 14:20 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 12/14/16 14:20 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 12/14/16 14:20 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 12/14/16 14:20 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 12/14/16 14:20 108-10-15.0 2.1 1


without the written consent of Pace Analytical Services, LLC.Date: 12/21/2016 02:59 PM


Green Bay, WI 54302(920)469-2436

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#=AR#

ANALYTICAL RESULTS


40143366023-6105-017 CP-SHOREHAM YARD

Sample: 121216-0800-200 Lab ID: 40143366001 Collected: 12/12/16 08:00 Received: 12/13/16 09:00 Matrix: Water



Methyl-tert-butyl ether <0.17 ug/L 12/14/16 14:20 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 12/14/16 14:20 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 12/14/16 14:20 103-65-11.0 0.50 1Styrene <0.50 ug/L 12/14/16 14:20 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 12/14/16 14:20 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 12/14/16 14:20 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 12/14/16 14:20 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 12/14/16 14:20 109-99-95.0 2.0 1Toluene <0.50 ug/L 12/14/16 14:20 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 12/14/16 14:20 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 12/14/16 14:20 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 12/14/16 14:20 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 12/14/16 14:20 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 12/14/16 14:20 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 12/14/16 14:20 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 12/14/16 14:20 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 12/14/16 14:20 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 12/14/16 14:20 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 12/14/16 14:20 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 12/14/16 14:20 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 12/14/16 14:20 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 12/14/16 14:20 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 92 % 12/14/16 14:20 460-00-470-130 1Dibromofluoromethane (S) 100 % 12/14/16 14:20 1868-53-770-130 1Toluene-d8 (S) 104 % 12/14/16 14:20 2037-26-570-130 1




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#=AR#

ANALYTICAL RESULTS


40143366023-6105-017 CP-SHOREHAM YARD

Sample: RW07-39-SP-1216-100 Lab ID: 40143366002 Collected: 12/12/16 14:05 Received: 12/13/16 09:00 Matrix: Water



Acetone <14.8 ug/L 12/14/16 19:56 67-64-1100 14.8 5Allyl chloride <10.8 ug/L 12/14/16 19:56 107-05-125.0 10.8 5Benzene <2.5 ug/L 12/14/16 19:56 71-43-25.0 2.5 5Bromobenzene <1.2 ug/L 12/14/16 19:56 108-86-15.0 1.2 5Bromochloromethane <1.7 ug/L 12/14/16 19:56 74-97-55.0 1.7 5Bromodichloromethane <2.5 ug/L 12/14/16 19:56 75-27-45.0 2.5 5Bromoform <2.5 ug/L 12/14/16 19:56 75-25-25.0 2.5 5Bromomethane <12.2 ug/L 12/14/16 19:56 74-83-925.0 12.2 52-Butanone (MEK) <14.9 ug/L 12/14/16 19:56 78-93-3100 14.9 5n-Butylbenzene <2.5 ug/L 12/14/16 19:56 104-51-85.0 2.5 5sec-Butylbenzene <10.9 ug/L 12/14/16 19:56 135-98-825.0 10.9 5tert-Butylbenzene <0.90 ug/L 12/14/16 19:56 98-06-65.0 0.90 5Carbon tetrachloride <2.5 ug/L 12/14/16 19:56 56-23-55.0 2.5 5Chlorobenzene <2.5 ug/L 12/14/16 19:56 108-90-75.0 2.5 5Chloroethane <1.9 ug/L 12/14/16 19:56 75-00-35.0 1.9 5Chloroform <12.5 ug/L 12/14/16 19:56 67-66-325.0 12.5 5Chloromethane <2.5 ug/L 12/14/16 19:56 74-87-35.0 2.5 52-Chlorotoluene <2.5 ug/L 12/14/16 19:56 95-49-85.0 2.5 54-Chlorotoluene <1.1 ug/L 12/14/16 19:56 106-43-45.0 1.1 51,2-Dibromo-3-chloropropane <10.8 ug/L 12/14/16 19:56 96-12-825.0 10.8 5Dibromochloromethane <2.5 ug/L 12/14/16 19:56 124-48-15.0 2.5 51,2-Dibromoethane (EDB) <0.89 ug/L 12/14/16 19:56 106-93-45.0 0.89 5Dibromomethane <2.1 ug/L 12/14/16 19:56 74-95-35.0 2.1 51,2-Dichlorobenzene <2.5 ug/L 12/14/16 19:56 95-50-15.0 2.5 51,3-Dichlorobenzene <2.5 ug/L 12/14/16 19:56 541-73-15.0 2.5 51,4-Dichlorobenzene <2.5 ug/L 12/14/16 19:56 106-46-75.0 2.5 5Dichlorodifluoromethane <1.1 ug/L 12/14/16 19:56 75-71-85.0 1.1 51,1-Dichloroethane 64.9 ug/L 12/14/16 19:56 75-34-35.0 1.2 51,2-Dichloroethane <0.84 ug/L 12/14/16 19:56 107-06-25.0 0.84 51,1-Dichloroethene 23.9 ug/L 12/14/16 19:56 75-35-45.0 2.1 5cis-1,2-Dichloroethene 41.9 ug/L 12/14/16 19:56 156-59-25.0 1.3 5trans-1,2-Dichloroethene <1.3 ug/L 12/14/16 19:56 156-60-55.0 1.3 5Dichlorofluoromethane <1.1 ug/L 12/14/16 19:56 75-43-45.0 1.1 51,2-Dichloropropane <1.2 ug/L 12/14/16 19:56 78-87-55.0 1.2 51,3-Dichloropropane <2.5 ug/L 12/14/16 19:56 142-28-95.0 2.5 52,2-Dichloropropane <2.4 ug/L 12/14/16 19:56 594-20-75.0 2.4 51,1-Dichloropropene <2.2 ug/L 12/14/16 19:56 563-58-65.0 2.2 5cis-1,3-Dichloropropene <2.5 ug/L 12/14/16 19:56 10061-01-55.0 2.5 5trans-1,3-Dichloropropene <1.1 ug/L 12/14/16 19:56 10061-02-65.0 1.1 5Diethyl ether (Ethyl ether) <11.1 ug/L 12/14/16 19:56 60-29-725.0 11.1 5Ethylbenzene <2.5 ug/L 12/14/16 19:56 100-41-45.0 2.5 5Hexachloro-1,3-butadiene <10.5 ug/L 12/14/16 19:56 87-68-325.0 10.5 5Isopropylbenzene (Cumene) <0.72 ug/L 12/14/16 19:56 98-82-85.0 0.72 5p-Isopropyltoluene <2.5 ug/L 12/14/16 19:56 99-87-65.0 2.5 5Methylene Chloride <1.2 ug/L 12/14/16 19:56 75-09-25.0 1.2 54-Methyl-2-pentanone (MIBK) <10.7 ug/L 12/14/16 19:56 108-10-125.0 10.7 5




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Methyl-tert-butyl ether <0.87 ug/L 12/14/16 19:56 1634-04-45.0 0.87 5Naphthalene <12.5 ug/L 12/14/16 19:56 91-20-325.0 12.5 5n-Propylbenzene <2.5 ug/L 12/14/16 19:56 103-65-15.0 2.5 5Styrene <2.5 ug/L 12/14/16 19:56 100-42-55.0 2.5 51,1,1,2-Tetrachloroethane <0.90 ug/L 12/14/16 19:56 630-20-65.0 0.90 51,1,2,2-Tetrachloroethane <1.2 ug/L 12/14/16 19:56 79-34-55.0 1.2 5Tetrachloroethene 259 ug/L 12/14/16 19:56 127-18-45.0 2.5 5Tetrahydrofuran <10.2 ug/L 12/14/16 19:56 109-99-925.0 10.2 5Toluene <2.5 ug/L 12/14/16 19:56 108-88-35.0 2.5 51,2,3-Trichlorobenzene <10.7 ug/L 12/14/16 19:56 87-61-625.0 10.7 51,2,4-Trichlorobenzene <11.0 ug/L 12/14/16 19:56 120-82-125.0 11.0 51,1,1-Trichloroethane 142 ug/L 12/14/16 19:56 71-55-65.0 2.5 51,1,2-Trichloroethane <0.99 ug/L 12/14/16 19:56 79-00-55.0 0.99 5Trichloroethene 16.4 ug/L 12/14/16 19:56 79-01-65.0 1.7 5Trichlorofluoromethane <0.92 ug/L 12/14/16 19:56 75-69-45.0 0.92 51,2,3-Trichloropropane <2.5 ug/L 12/14/16 19:56 96-18-45.0 2.5 51,1,2-Trichlorotrifluoroethane <4.1 ug/L 12/14/16 19:56 76-13-125.0 4.1 51,2,4-Trimethylbenzene <2.5 ug/L 12/14/16 19:56 95-63-65.0 2.5 51,3,5-Trimethylbenzene <2.5 ug/L 12/14/16 19:56 108-67-85.0 2.5 5Vinyl chloride <0.88 ug/L 12/14/16 19:56 75-01-45.0 0.88 5m&p-Xylene <5.0 ug/L 12/14/16 19:56 179601-23-110.0 5.0 5o-Xylene <2.5 ug/L 12/14/16 19:56 95-47-65.0 2.5 5Surrogates4-Bromofluorobenzene (S) 92 % 12/14/16 19:56 460-00-470-130 5Dibromofluoromethane (S) 105 % 12/14/16 19:56 1868-53-770-130 5Toluene-d8 (S) 99 % 12/14/16 19:56 2037-26-570-130 5




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ANALYTICAL RESULTS


40143366023-6105-017 CP-SHOREHAM YARD




Acetone <3.0 ug/L 12/14/16 18:33 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 12/14/16 18:33 107-05-15.0 2.2 1Benzene <0.50 ug/L 12/14/16 18:33 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 12/14/16 18:33 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 12/14/16 18:33 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 12/14/16 18:33 75-27-41.0 0.50 1Bromoform <0.50 ug/L 12/14/16 18:33 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 12/14/16 18:33 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 12/14/16 18:33 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 12/14/16 18:33 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 12/14/16 18:33 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 12/14/16 18:33 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 12/14/16 18:33 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 12/14/16 18:33 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 12/14/16 18:33 75-00-31.0 0.37 1Chloroform <2.5 ug/L 12/14/16 18:33 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 12/14/16 18:33 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 12/14/16 18:33 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 12/14/16 18:33 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 12/14/16 18:33 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 12/14/16 18:33 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 12/14/16 18:33 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 12/14/16 18:33 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 12/14/16 18:33 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 12/14/16 18:33 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 12/14/16 18:33 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 12/14/16 18:33 75-71-81.0 0.22 11,1-Dichloroethane 20.2 ug/L 12/14/16 18:33 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 12/14/16 18:33 107-06-21.0 0.17 11,1-Dichloroethene 6.1 ug/L 12/14/16 18:33 75-35-41.0 0.41 1cis-1,2-Dichloroethene 14.8 ug/L 12/14/16 18:33 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 12/14/16 18:33 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 12/14/16 18:33 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 12/14/16 18:33 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 12/14/16 18:33 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 12/14/16 18:33 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 12/14/16 18:33 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 12/14/16 18:33 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 12/14/16 18:33 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 12/14/16 18:33 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 12/14/16 18:33 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 12/14/16 18:33 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 12/14/16 18:33 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 12/14/16 18:33 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 12/14/16 18:33 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 12/14/16 18:33 108-10-15.0 2.1 1




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Methyl-tert-butyl ether <0.17 ug/L 12/14/16 18:33 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 12/14/16 18:33 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 12/14/16 18:33 103-65-11.0 0.50 1Styrene <0.50 ug/L 12/14/16 18:33 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 12/14/16 18:33 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 12/14/16 18:33 79-34-51.0 0.25 1Tetrachloroethene 47.2 ug/L 12/14/16 18:33 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 12/14/16 18:33 109-99-95.0 2.0 1Toluene <0.50 ug/L 12/14/16 18:33 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 12/14/16 18:33 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 12/14/16 18:33 120-82-15.0 2.2 11,1,1-Trichloroethane 25.7 ug/L 12/14/16 18:33 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 12/14/16 18:33 79-00-51.0 0.20 1Trichloroethene 3.6 ug/L 12/14/16 18:33 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 12/14/16 18:33 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 12/14/16 18:33 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 12/14/16 18:33 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 12/14/16 18:33 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 12/14/16 18:33 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 12/14/16 18:33 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 12/14/16 18:33 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 12/14/16 18:33 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 91 % 12/14/16 18:33 460-00-470-130 1Dibromofluoromethane (S) 101 % 12/14/16 18:33 1868-53-770-130 1Toluene-d8 (S) 100 % 12/14/16 18:33 2037-26-570-130 1




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ANALYTICAL RESULTS


40143366023-6105-017 CP-SHOREHAM YARD

Sample: RW06-28-I-1216-100 Lab ID: 40143366004 Collected: 12/12/16 14:15 Received: 12/13/16 09:00 Matrix: Water







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ANALYTICAL RESULTS


40143366023-6105-017 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 12/14/16 18:12 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 12/14/16 18:12 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 12/14/16 18:12 103-65-11.0 0.50 1Styrene <0.50 ug/L 12/14/16 18:12 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 12/14/16 18:12 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 12/14/16 18:12 79-34-51.0 0.25 1Tetrachloroethene 7.9 ug/L 12/14/16 18:12 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 12/14/16 18:12 109-99-95.0 2.0 1Toluene 1.1 ug/L 12/14/16 18:12 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 12/14/16 18:12 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 12/14/16 18:12 120-82-15.0 2.2 11,1,1-Trichloroethane 5.0 ug/L 12/14/16 18:12 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 12/14/16 18:12 79-00-51.0 0.20 1Trichloroethene 0.89J ug/L 12/14/16 18:12 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 12/14/16 18:12 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 12/14/16 18:12 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 12/14/16 18:12 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 12/14/16 18:12 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 12/14/16 18:12 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 12/14/16 18:12 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 12/14/16 18:12 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 12/14/16 18:12 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 88 % 12/14/16 18:12 460-00-470-130 1Dibromofluoromethane (S) 102 % 12/14/16 18:12 1868-53-770-130 1Toluene-d8 (S) 102 % 12/14/16 18:12 2037-26-570-130 1




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ANALYTICAL RESULTS


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ANALYTICAL RESULTS


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ANALYTICAL RESULTS


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Sample: RW06-27-BR-1216-100 Lab ID: 40143366006 Collected: 12/12/16 14:25 Received: 12/13/16 09:00 Matrix: Water



Acetone <3.0 ug/L 12/14/16 17:30 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 12/14/16 17:30 107-05-15.0 2.2 1Benzene <0.50 ug/L 12/14/16 17:30 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 12/14/16 17:30 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 12/14/16 17:30 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 12/14/16 17:30 75-27-41.0 0.50 1Bromoform <0.50 ug/L 12/14/16 17:30 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 12/14/16 17:30 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 12/14/16 17:30 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 12/14/16 17:30 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 12/14/16 17:30 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 12/14/16 17:30 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 12/14/16 17:30 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 12/14/16 17:30 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 12/14/16 17:30 75-00-31.0 0.37 1Chloroform <2.5 ug/L 12/14/16 17:30 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 12/14/16 17:30 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 12/14/16 17:30 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 12/14/16 17:30 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 12/14/16 17:30 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 12/14/16 17:30 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 12/14/16 17:30 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 12/14/16 17:30 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 12/14/16 17:30 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 12/14/16 17:30 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 12/14/16 17:30 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 12/14/16 17:30 75-71-81.0 0.22 11,1-Dichloroethane 17.2 ug/L 12/14/16 17:30 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 12/14/16 17:30 107-06-21.0 0.17 11,1-Dichloroethene 4.5 ug/L 12/14/16 17:30 75-35-41.0 0.41 1cis-1,2-Dichloroethene 26.5 ug/L 12/14/16 17:30 156-59-21.0 0.26 1trans-1,2-Dichloroethene 0.31J ug/L 12/14/16 17:30 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 12/14/16 17:30 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 12/14/16 17:30 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 12/14/16 17:30 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 12/14/16 17:30 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 12/14/16 17:30 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 12/14/16 17:30 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 12/14/16 17:30 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 12/14/16 17:30 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 12/14/16 17:30 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 12/14/16 17:30 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 12/14/16 17:30 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 12/14/16 17:30 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 12/14/16 17:30 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 12/14/16 17:30 108-10-15.0 2.1 1




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ANALYTICAL RESULTS


40143366023-6105-017 CP-SHOREHAM YARD

Sample: RW06-27-BR-1216-100 Lab ID: 40143366006 Collected: 12/12/16 14:25 Received: 12/13/16 09:00 Matrix: Water



Methyl-tert-butyl ether <0.17 ug/L 12/14/16 17:30 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 12/14/16 17:30 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 12/14/16 17:30 103-65-11.0 0.50 1Styrene <0.50 ug/L 12/14/16 17:30 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 12/14/16 17:30 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 12/14/16 17:30 79-34-51.0 0.25 1Tetrachloroethene 27.6 ug/L 12/14/16 17:30 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 12/14/16 17:30 109-99-95.0 2.0 1Toluene <0.50 ug/L 12/14/16 17:30 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 12/14/16 17:30 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 12/14/16 17:30 120-82-15.0 2.2 11,1,1-Trichloroethane 9.2 ug/L 12/14/16 17:30 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 12/14/16 17:30 79-00-51.0 0.20 1Trichloroethene 6.5 ug/L 12/14/16 17:30 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 12/14/16 17:30 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 12/14/16 17:30 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 12/14/16 17:30 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 12/14/16 17:30 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 12/14/16 17:30 108-67-81.0 0.50 1Vinyl chloride 0.32J ug/L 12/14/16 17:30 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 12/14/16 17:30 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 12/14/16 17:30 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 88 % 12/14/16 17:30 460-00-470-130 1Dibromofluoromethane (S) 100 % 12/14/16 17:30 1868-53-770-130 1Toluene-d8 (S) 101 % 12/14/16 17:30 2037-26-570-130 1




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ANALYTICAL RESULTS


40143366023-6105-017 CP-SHOREHAM YARD

Sample: SE EFFLUENT Lab ID: 40143366007 Collected: 12/12/16 14:30 Received: 12/13/16 09:00 Matrix: Water



Acetone <3.0 ug/L 12/14/16 17:09 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 12/14/16 17:09 107-05-15.0 2.2 1Benzene <0.50 ug/L 12/14/16 17:09 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 12/14/16 17:09 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 12/14/16 17:09 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 12/14/16 17:09 75-27-41.0 0.50 1Bromoform <0.50 ug/L 12/14/16 17:09 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 12/14/16 17:09 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 12/14/16 17:09 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 12/14/16 17:09 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 12/14/16 17:09 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 12/14/16 17:09 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 12/14/16 17:09 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 12/14/16 17:09 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 12/14/16 17:09 75-00-31.0 0.37 1Chloroform <2.5 ug/L 12/14/16 17:09 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 12/14/16 17:09 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 12/14/16 17:09 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 12/14/16 17:09 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 12/14/16 17:09 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 12/14/16 17:09 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 12/14/16 17:09 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 12/14/16 17:09 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 12/14/16 17:09 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 12/14/16 17:09 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 12/14/16 17:09 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 12/14/16 17:09 75-71-81.0 0.22 11,1-Dichloroethane 21.7 ug/L 12/14/16 17:09 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 12/14/16 17:09 107-06-21.0 0.17 11,1-Dichloroethene 6.2 ug/L 12/14/16 17:09 75-35-41.0 0.41 1cis-1,2-Dichloroethene 18.8 ug/L 12/14/16 17:09 156-59-21.0 0.26 1trans-1,2-Dichloroethene 0.26J ug/L 12/14/16 17:09 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 12/14/16 17:09 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 12/14/16 17:09 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 12/14/16 17:09 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 12/14/16 17:09 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 12/14/16 17:09 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 12/14/16 17:09 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 12/14/16 17:09 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 12/14/16 17:09 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 12/14/16 17:09 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 12/14/16 17:09 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 12/14/16 17:09 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 12/14/16 17:09 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 12/14/16 17:09 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 12/14/16 17:09 108-10-15.0 2.1 1




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ANALYTICAL RESULTS


40143366023-6105-017 CP-SHOREHAM YARD

Sample: SE EFFLUENT Lab ID: 40143366007 Collected: 12/12/16 14:30 Received: 12/13/16 09:00 Matrix: Water




Analytical Method: SM 2540D2540D Total Suspended Solids

Total Suspended Solids <0.95 mg/L 12/14/16 10:152.0 0.95 1

Analytical Method: EPA 410.4 Preparation Method: EPA 410.4410.4 COD

Chemical Oxygen Demand <14.2 mg/L 12/20/16 13:2112/20/16 10:4047.2 14.2 1




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#=QC#

QUALITY CONTROL DATA


40143366023-6105-017 CP-SHOREHAM YARD

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:QC Batch Method:

Analysis Method:Analysis Description:

244167EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40143366001, 40143366002, 40143366003, 40143366004, 40143366005, 40143366006, 40143366007

Parameter UnitsBlankResult

ReportingLimit Qualifiers

METHOD BLANK: 1445925Associated Lab Samples: 40143366001, 40143366002, 40143366003, 40143366004, 40143366005, 40143366006, 40143366007

Matrix: Water

AnalyzedMDL

1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 12/14/16 11:520.181,1,1-Trichloroethane ug/L <0.50 1.0 12/14/16 11:520.501,1,2,2-Tetrachloroethane ug/L <0.25 1.0 12/14/16 11:520.251,1,2-Trichloroethane ug/L <0.20 1.0 12/14/16 11:520.201,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 12/14/16 11:520.811,1-Dichloroethane ug/L <0.24 1.0 12/14/16 11:520.241,1-Dichloroethene ug/L <0.41 1.0 12/14/16 11:520.411,1-Dichloropropene ug/L <0.44 1.0 12/14/16 11:520.441,2,3-Trichlorobenzene ug/L <2.1 5.0 12/14/16 11:522.11,2,3-Trichloropropane ug/L <0.50 1.0 12/14/16 11:520.501,2,4-Trichlorobenzene ug/L <2.2 5.0 12/14/16 11:522.21,2,4-Trimethylbenzene ug/L <0.50 1.0 12/14/16 11:520.501,2-Dibromo-3-chloropropane ug/L <2.2 5.0 12/14/16 11:522.21,2-Dibromoethane (EDB) ug/L <0.18 1.0 12/14/16 11:520.181,2-Dichlorobenzene ug/L <0.50 1.0 12/14/16 11:520.501,2-Dichloroethane ug/L <0.17 1.0 12/14/16 11:520.171,2-Dichloropropane ug/L <0.23 1.0 12/14/16 11:520.231,3,5-Trimethylbenzene ug/L <0.50 1.0 12/14/16 11:520.501,3-Dichlorobenzene ug/L <0.50 1.0 12/14/16 11:520.501,3-Dichloropropane ug/L <0.50 1.0 12/14/16 11:520.501,4-Dichlorobenzene ug/L <0.50 1.0 12/14/16 11:520.502,2-Dichloropropane ug/L <0.48 1.0 12/14/16 11:520.482-Butanone (MEK) ug/L <3.0 20.0 12/14/16 11:523.02-Chlorotoluene ug/L <0.50 1.0 12/14/16 11:520.504-Chlorotoluene ug/L <0.21 1.0 12/14/16 11:520.214-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 12/14/16 11:522.1Acetone ug/L <3.0 20.0 12/14/16 11:523.0Allyl chloride ug/L <2.2 5.0 12/14/16 11:522.2Benzene ug/L <0.50 1.0 12/14/16 11:520.50Bromobenzene ug/L <0.23 1.0 12/14/16 11:520.23Bromochloromethane ug/L <0.34 1.0 12/14/16 11:520.34Bromodichloromethane ug/L <0.50 1.0 12/14/16 11:520.50Bromoform ug/L <0.50 1.0 12/14/16 11:520.50Bromomethane ug/L <2.4 5.0 12/14/16 11:522.4Carbon tetrachloride ug/L <0.50 1.0 12/14/16 11:520.50Chlorobenzene ug/L <0.50 1.0 12/14/16 11:520.50Chloroethane ug/L <0.37 1.0 12/14/16 11:520.37Chloroform ug/L <2.5 5.0 12/14/16 11:522.5Chloromethane ug/L <0.50 1.0 12/14/16 11:520.50cis-1,2-Dichloroethene ug/L <0.26 1.0 12/14/16 11:520.26cis-1,3-Dichloropropene ug/L <0.50 1.0 12/14/16 11:520.50




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#=QC#



40143366023-6105-017 CP-SHOREHAM YARD




METHOD BLANK: 1445925Associated Lab Samples: 40143366001, 40143366002, 40143366003, 40143366004, 40143366005, 40143366006, 40143366007

Matrix: Water

AnalyzedMDL

Dibromochloromethane ug/L <0.50 1.0 12/14/16 11:520.50Dibromomethane ug/L <0.43 1.0 12/14/16 11:520.43Dichlorodifluoromethane ug/L <0.22 1.0 12/14/16 11:520.22Dichlorofluoromethane ug/L <0.21 1.0 12/14/16 11:520.21Diethyl ether (Ethyl ether) ug/L <2.2 5.0 12/14/16 11:522.2Ethylbenzene ug/L <0.50 1.0 12/14/16 11:520.50Hexachloro-1,3-butadiene ug/L <2.1 5.0 12/14/16 11:522.1Isopropylbenzene (Cumene) ug/L <0.14 1.0 12/14/16 11:520.14m&p-Xylene ug/L <1.0 2.0 12/14/16 11:521.0Methyl-tert-butyl ether ug/L <0.17 1.0 12/14/16 11:520.17Methylene Chloride ug/L <0.23 1.0 12/14/16 11:520.23n-Butylbenzene ug/L <0.50 1.0 12/14/16 11:520.50n-Propylbenzene ug/L <0.50 1.0 12/14/16 11:520.50Naphthalene ug/L <2.5 5.0 12/14/16 11:522.5o-Xylene ug/L <0.50 1.0 12/14/16 11:520.50p-Isopropyltoluene ug/L <0.50 1.0 12/14/16 11:520.50sec-Butylbenzene ug/L <2.2 5.0 12/14/16 11:522.2Styrene ug/L <0.50 1.0 12/14/16 11:520.50tert-Butylbenzene ug/L <0.18 1.0 12/14/16 11:520.18Tetrachloroethene ug/L <0.50 1.0 12/14/16 11:520.50Tetrahydrofuran ug/L <2.0 5.0 12/14/16 11:522.0Toluene ug/L <0.50 1.0 12/14/16 11:520.50trans-1,2-Dichloroethene ug/L <0.26 1.0 12/14/16 11:520.26trans-1,3-Dichloropropene ug/L <0.23 1.0 12/14/16 11:520.23Trichloroethene ug/L <0.33 1.0 12/14/16 11:520.33Trichlorofluoromethane ug/L <0.18 1.0 12/14/16 11:520.18Vinyl chloride ug/L <0.18 1.0 12/14/16 11:520.184-Bromofluorobenzene (S) % 91 70-130 12/14/16 11:52Dibromofluoromethane (S) % 101 70-130 12/14/16 11:52Toluene-d8 (S) % 96 70-130 12/14/16 11:52

Parameter UnitsLCS

Result% RecLimits Qualifiers% RecConc.

1445926LABORATORY CONTROL SAMPLE:LCSSpike

1,1,1-Trichloroethane ug/L 57.250 114 70-1311,1,2,2-Tetrachloroethane ug/L 51.950 104 67-1301,1,2-Trichloroethane ug/L 53.550 107 70-1301,1,2-Trichlorotrifluoroethane ug/L 57.150 114 50-1501,1-Dichloroethane ug/L 56.750 113 70-1331,1-Dichloroethene ug/L 46.950 94 70-1301,2,4-Trichlorobenzene ug/L 52.850 106 70-1301,2-Dibromo-3-chloropropane ug/L 49.250 98 50-1501,2-Dibromoethane (EDB) ug/L 52.450 105 70-1301,2-Dichlorobenzene ug/L 53.550 107 70-130




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40143366023-6105-017 CP-SHOREHAM YARD


Parameter UnitsLCS



1,2-Dichloroethane ug/L 55.150 110 70-1301,2-Dichloropropane ug/L 55.050 110 70-1301,3-Dichlorobenzene ug/L 51.850 104 70-1301,4-Dichlorobenzene ug/L 51.650 103 70-130Benzene ug/L 55.250 110 60-135Bromodichloromethane ug/L 54.050 108 70-130Bromoform ug/L 60.750 121 70-130Bromomethane ug/L 28.950 58 33-130Carbon tetrachloride ug/L 58.450 117 70-138Chlorobenzene ug/L 53.950 108 70-130Chloroethane ug/L 46.950 94 51-130Chloroform ug/L 53.650 107 70-130Chloromethane ug/L 30.950 62 25-132cis-1,2-Dichloroethene ug/L 56.450 113 69-130cis-1,3-Dichloropropene ug/L 57.750 115 70-130Dibromochloromethane ug/L 52.950 106 70-130Dichlorodifluoromethane ug/L 15.650 31 23-130Ethylbenzene ug/L 57.150 114 70-136Isopropylbenzene (Cumene) ug/L 59.650 119 70-140m&p-Xylene ug/L 114100 114 70-138Methyl-tert-butyl ether ug/L 55.850 112 66-138Methylene Chloride ug/L 53.150 106 70-130o-Xylene ug/L 57.950 116 70-134Styrene ug/L 55.450 111 70-133Tetrachloroethene ug/L 53.650 107 70-138Toluene ug/L 53.550 107 70-130trans-1,2-Dichloroethene ug/L 52.850 106 70-131trans-1,3-Dichloropropene ug/L 51.250 102 69-130Trichloroethene ug/L 53.550 107 70-130Trichlorofluoromethane ug/L 51.850 104 50-150Vinyl chloride ug/L 37.650 75 49-1304-Bromofluorobenzene (S) % 104 70-130Dibromofluoromethane (S) % 110 70-130Toluene-d8 (S) % 98 70-130

Parameter UnitsMS

Result% RecLimits Qual% RecConc.

1445927MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpikeResult

40143366007

1445928

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L 50 115 70-134112 2 205021.1 78.6 76.91,1,2,2-Tetrachloroethane ug/L 50 98 67-13097 1 2050<0.25 49.1 48.41,1,2-Trichloroethane ug/L 50 102 70-130101 1 2050<0.20 51.0 50.61,1,2-Trichlorotrifluoroethane ug/L 50 113 50-150112 1 2050<0.81 56.6 56.21,1-Dichloroethane ug/L 50 115 70-134116 1 205021.7 78.9 79.71,1-Dichloroethene ug/L 50 93 68-13692 1 20506.2 52.8 52.1




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40143366023-6105-017 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40143366007

1445928

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,2,4-Trichlorobenzene ug/L 50 102 62-139104 2 2050<2.2 50.8 51.91,2-Dibromo-3-chloropropane

ug/L 50 93 50-15092 1 2050<2.2 46.7 46.1

1,2-Dibromoethane (EDB) ug/L 50 103 70-130101 2 2050<0.18 51.7 50.71,2-Dichlorobenzene ug/L 50 102 70-130102 1 2050<0.50 50.9 51.21,2-Dichloroethane ug/L 50 108 70-130112 4 2050<0.17 53.9 56.11,2-Dichloropropane ug/L 50 104 70-130108 3 2050<0.23 52.2 53.91,3-Dichlorobenzene ug/L 50 100 70-131100 0 2050<0.50 50.1 49.91,4-Dichlorobenzene ug/L 50 101 70-130101 0 2050<0.50 50.5 50.4Benzene ug/L 50 108 57-138114 5 2050<0.50 54.1 56.8Bromodichloromethane ug/L 50 103 70-130104 1 2050<0.50 51.7 52.2Bromoform ug/L 50 115 70-130115 0 2050<0.50 57.7 57.5Bromomethane ug/L 50 63 33-13066 4 2750<2.4 31.5 32.8Carbon tetrachloride ug/L 50 111 70-138108 3 2050<0.50 55.6 54.1Chlorobenzene ug/L 50 104 70-130103 1 2050<0.50 52.0 51.7Chloroethane ug/L 50 94 51-13095 0 2050<0.37 47.1 47.3Chloroform ug/L 50 107 70-130107 0 2050<2.5 53.7 53.6Chloromethane ug/L 50 60 25-13263 6 2050<0.50 30.0 31.7cis-1,2-Dichloroethene ug/L 50 112 61-140114 1 205018.8 74.9 75.7cis-1,3-Dichloropropene ug/L 50 112 70-130112 0 2050<0.50 56.0 55.9Dibromochloromethane ug/L 50 102 70-130102 0 2050<0.50 51.0 50.9Dichlorodifluoromethane ug/L 50 29 23-13028 3 2050<0.22 14.6 14.1Ethylbenzene ug/L 50 110 70-138109 0 2050<0.50 54.9 54.7Isopropylbenzene (Cumene) ug/L 50 116 70-152116 1 2050<0.14 58.2 57.9m&p-Xylene ug/L 100 110 70-140111 1 20100<1.0 110 111Methyl-tert-butyl ether ug/L 50 112 66-139110 2 2050<0.17 55.9 55.1Methylene Chloride ug/L 50 102 70-130103 1 2050<0.23 51.2 51.6o-Xylene ug/L 50 112 70-134111 1 2050<0.50 56.1 55.6Styrene ug/L 50 108 70-138107 1 2050<0.50 54.0 53.3Tetrachloroethene ug/L 50 102 70-148108 3 205047.0 97.9 101Toluene ug/L 50 104 70-130104 1 2050<0.50 52.2 51.9trans-1,2-Dichloroethene ug/L 50 106 70-133107 1 20500.26J 53.2 53.5trans-1,3-Dichloropropene ug/L 50 99 69-13099 0 2050<0.23 49.4 49.3Trichloroethene ug/L 50 104 70-131104 0 20505.7 57.8 57.9Trichlorofluoromethane ug/L 50 104 50-150104 0 2050<0.18 52.0 51.9Vinyl chloride ug/L 50 74 49-13375 2 2050<0.18 36.9 37.64-Bromofluorobenzene (S) % 104 70-130104Dibromofluoromethane (S) % 110 70-130107Toluene-d8 (S) % 98 70-13099




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40143366023-6105-017 CP-SHOREHAM YARD




244158SM 2540D

SM 2540D2540D Total Suspended Solids

Associated Lab Samples: 40143366007



METHOD BLANK: 1445888Associated Lab Samples: 40143366007

Matrix: Water

AnalyzedMDL

Total Suspended Solids mg/L <0.48 1.0 12/14/16 10:140.48

Parameter UnitsLCS



Total Suspended Solids mg/L 96.0100 96 80-120

Parameter UnitsDup

ResultMaxRPD QualifiersRPDResult

401433660071445890SAMPLE DUPLICATE:

Total Suspended Solids mg/L <0.95 5<0.95

Parameter UnitsDup

ResultMaxRPD QualifiersRPDResult

401434180011445891SAMPLE DUPLICATE:

Total Suspended Solids mg/L 32.0 1 532.4




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40143366023-6105-017 CP-SHOREHAM YARD




244596EPA 410.4

EPA 410.4410.4 COD

Associated Lab Samples: 40143366007



METHOD BLANK: 1448078Associated Lab Samples: 40143366007

Matrix: Water

AnalyzedMDL

Chemical Oxygen Demand mg/L <13.4 44.8 12/20/16 13:2013.4

Parameter UnitsLCS



Chemical Oxygen Demand mg/L 506500 101 90-110

Parameter UnitsMS



MSSpikeResult

40143366007

1448081

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chemical Oxygen Demand mg/L 526 103 90-110103 0 10526<14.2 551 549

Parameter UnitsMS



MSSpikeResult

40143362001

1448083

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chemical Oxygen Demand mg/L 526 102 90-110103 1 10526<14.2 535 542




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#=QL#

QUALIFIERS


40143366023-6105-017 CP-SHOREHAM YARD

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES

Pace Analytical Services - Green BayPASI-G




Green Bay, WI 54302(920)469-2436

Page 25 of 28

#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE


40143366023-6105-017 CP-SHOREHAM YARD

Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch

40143366001 244167121216-0800-200 EPA 826040143366002 244167RW07-39-SP-1216-100 EPA 826040143366003 244167RW07-40-SP-1216-100 EPA 826040143366004 244167RW06-28-I-1216-100 EPA 826040143366005 244167RW07-38-I-1216-100 EPA 826040143366006 244167RW06-27-BR-1216-100 EPA 826040143366007 244167SE EFFLUENT EPA 8260

40143366007 244158SE EFFLUENT SM 2540D

40143366007 244596 244677SE EFFLUENT EPA 410.4 EPA 410.4




Green Bay, WI 54302(920)469-2436

Page 26 of 28

Pag

e 27

of 2

8(Please Print Clearly) of

ompanyName: I Gololer ftSSCq

Branch/Location: I /'1 f-. ~ V'{ c.J

. ·• J UPPER MIDWEST REGION E_ _/'" cP1 MN: 612-607-1700 WI: 920-469-2 36 V (<:::_ eVI 4olLl33w{tl

Project Contact: I A\ 1< S () VI ~ { / www.pacelltbs.oom

Phone: 14 7 3 -6 "f S-- ( C( 2.... 2. CHAIN OF CUSTODY :preservation Codes

Project Number: I() '-.'3 - 6 LO 5" - 0 l 7 A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

Project Name: ICP ~S~Of('~~....., Yet..- H=Sodium Bisulfate Solution

Project State: I jv\_ tJ Sampled By (Print):! A\ C'( -'I

Sampled By (Sign):

PO#:

Data Package Options (billable)

D EPA Level Ill

D EPA Level IV

PACE LAB#

MS/llllSD D On your sample

(billable) D NOT needed on

your sample

Regulatory Program:

FILTERED? (YES/NO)

PRESERVATION (CODE)*

Matrix Codes A=Air W=Water B = Biota OW = Drinking Water C = Charcoal GW = Ground Water 0 =Oil SW= Surface Water S=Soil SI =Sludae

DATE I TIME

12../lt/tt I c<g~o l i.f O)

\~lO 1'1/S-1120 ltfl-5'

!=Sodium Thiosulfate J=Other

N

c

Q

JJ A

~ J-

Quote#:

Mail To Contact:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CLIENT COMMENTS

LAB COMMENTS Profile#

"?-.

I -,. I .. Ix I I I I I I I ··Er':IOm/ b 1-i5brM.pL /..-f Y,P11

ush Turnaround Time Requested - Prelims (Rush TAT subject to approval/surcharge)

Date Needed:

PACE Project No.

Transmit Prelim Rush Results by (complete what you want): I y l.< 1 r ~ - , - w , ~ ~ I IRecelpt Temp I I " t .. Emall#1:

Emall#2: Telephone:

Fax:

Samples on HOLD are subject to

speclal pricing and release of llablllty

C019a(27 Jun2006)

:elinquished By: Datemme: Received By: DatefTime:

\ieiil!OilT006/14t06

of 28

;'!2ceAnalyticat iClient Name: Uo{cLe4

Sample Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9

Green Bay, WI 54302

Project#

Courier: r Fed Ex r UPS ~ Client r Ptfe :>ther: WoJ--tiD Tracking#: \1.3S'Sl.RU -Custody Seal on Cooler/Box Present: f"' yes - no Seals intact: r yes V no

Custody Seal on Samples Present: r yes p-· no Seals intact: r yes - no

W0#"40143366 111111 11111 111 11111111 40143366

Packing Material: '7' Bubble Wrap p-' Bubble Bags r None . r Other

Thermometer Used "0¥.- 58 . , Type of le~ Blue Dry None Y Samples on ice, cooling process has begun

Cooler Temperature Uncorr: 3 /Corr: L{ ~gical Tissue is Frozen: r yes

Temp Blank Present: pYes rno r no Person examini1 contents:

Temp should be above freezing to 6°C for all sample except Biota. Date: t ..Z.--13 "7 Frozen Biota Samples should be received :s 0°c. Comments: Initials: M.~

Chain of Custody Present: Jives ONo ON/A 1.

Chain of Custody Filled Out: Jdves ONo ON/A 2.

Chain of Custody Relinquished: ¢'~es ONo ON/A 3.

Sampler Name & Signature on COC: ¢ves ONo ON/A 4.

Samples Arrived within Hold Time: ¢"res ONo ON/A 5.

- VOA Samples frozen upon receipt 0Yes ONo Date/Time:

Short Hold Time Analvsis (<72hr): 0Yes JZ(No ON/A 6.

Rush Turn Around Time Requested: 0Yes Jlf'No ON/A 7.

Sufficient Volume: ¢'ves ONo ON/A 8.

Correct Containers Used: rf':es ONo ON/A 9.

-Pace Containers Used: ';z{ves ONo ON/A

-Pace IR Containers Used: Oves ONo ~/A

Containers Intact: rives ONo ON/A 10.

Filtered volume received for Dissolved tests Oves ONo oWA 11.

Sample Labels match COC: ~es ONo ON/A 12.

-Includes date/time/ID/Analysis Matrix: \J\\ All containers needing preservation have been checked. r:{: r HN03 r H2S04 r NaOH r NaOH +ZnAct (Non-Compliance noted in 13.) )'.es ONo ON/A 13. Aii ront'iiiners needing preserv""ation are tound to be-,;- - - - - - - - - - - -compliance with EPA recommendation. rjves ONo ON/A (HN03, H2S.04 :s2; NaOH+ZnAct ~9. NaOH <:12) e~pt~~t;;;,~ T"oC. :rox-:Toii.- --- --- --¢ --- --- -- Initial when tJ\. \ALab Std mo of l·uatet O&G, WI , Phenolics, OTHER: Yes 0No completed preservative Time:

Headspace in VOA Vials ( >6mm): Oves ¢No ON/A 14.

Trip Blank Present: ¢ves ONo ON/A 15.

Trip Blank Custody Seals Present

Pace Trip Blank Lot# (if purchased): ~ 1 J_ jives ONo ON/A

Client Notification/ Resolution: If checked, see attached form for additional comments D Person Contacted: Date/Time:

~------------------------- ------------------Comments/ Resolution: ------------------------------------------------------~----------------------~

Project Manager Review:

F-GB-C-031-Rev.03 (9April2015) SCUR Fonn

Attachment D

FIELD INSTRUMENT pH CALIBRATION RECORDS

Page _ l_of_ l_

Field Instrument pH Calibration Records

INSTRUMENT (MAKE/MODEL NO.) Sper Scientific/850051 INSTRUMENT NO. ____ _

STANDARD INFORMATION

Project Number: 0236105017 Project Name_: _C_P-_S_h_or_eh_a_m_Y_a __ rd _________ _

Standard Vendor: Field Environmental Instruments

Prepared Date: NA Where Prepared: _____ _.._N...._..A

Purchase Date: 11/17/2016 Expiration Date: Varies Grade: NIA Units: Standard Units

Standard 4.0 @25 °c Lot# F158-18 Exp Date 6/14/18



DATE TIME TEMP STD INSTRUMENT %DEV

(mm/dd/yy} (hr:min} DEGC VALUE RESPONSE

lt/U/ l 6 f)'i;- IG.o 7.o l,O 0

i I '5"'> { l 'j- , . .--. ) L( '() '--< .o ()

~ I )-'i-S I?-, S- l o.o l 0 ,() 0 P-!6/t6 t35S [ 5· Lf . 7.c 7.o a

l l '( 0() , ,I 'f ~cc l-LO G'

'-Jr l ~DS l '1. ) LO,Q l e .. o d

\1-/i// 6 l (DO Jtf l~n L-(. 0 L( ,Q 0 l

7.o 7~() r llOf l'f:O 0

'11 l 1 ( 0 () ~ ~ ) to .o l D .a C)

12-/fL//' tl(1g ,~ ,o 7,() 1.0 0 l li..f '10 /7.5' ~,o i-r.o (j

';V l't.'1t ,.-, ) ' I

}{) ,() I 0 I f) cJ -

\l /l1/ll t7cg \~ ' C) 7. (J ·7, (J Q i •

\7 /l ~.o LL 8 cJ i ').0 '11 l7 I G \~ . 5- t c .~o i o. rl 0

-

PASS/ CALIBRATED SAMPLER FAIL (YES, NO) INITIALS

p v j-1/) (

f .

v Jj-f (

p y A- p ~ '( JI p y ff p f '( .J f ~ y H \\ y ff -~ '( f f p y ~f J y tlf ~ "( 4f p y ii ·.P f ·y 4 /J p ''-/ /~p

Acceptable calibration check is if the meter reads within +/- 0.2 pH units of the value of appropriate calibration standard.

\\MIN 1-V-FS l\Projects\Golder Projects\023 PROJECTS\023-6105 Shoreham Yard File Review\East Side Southeast P&T System\MCES Special Discharge Reports\pH_ Calibration Form.doc

Golder Associates REV-2-03/07

document

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