document

<I' Golder Associates April 14, 2016

Metropolitan Council Environmental Services Industrial Waste Division 390 Robert St. N. St. Paul, MN 55101

Attention: Ms. Ashley Corbeille

RE: 2016 FIRST QUARTER SPECIAL DISCHARGE REPORT INDUSTRIAL DISCHARGE PERMIT NUMBER 2289 SOUTHEAST PUMP AND TREAT SYSTEM CANADIAN PACIFIC SHOREHAM FACILITY

Dear Ms. Corbeille:

Project No.:023-6105.016

On behalf of Canadian Pacific, enclosed is the 2016 First Quarter Special Discharge Report for the site located at 281h & Central Avenue NE, Minneapolis MN. In accordance with the Metropolitan Council Environmental Services (MCES) Industrial Discharge Permit Number 2289, effective October 1, 2013 (MCES permit), this submittal documents the volume and quality of water discharged from the groundwater pump and treat system owned by Canadian Pacific.

The total quantity of water discharged into the sanitary sewer system during this reporting quarter was 3,287,300 gallons. The average daily discharge for the system was 36, 124 gallons.

Required information for the discharge is provided as follows: • Attachment A - Special Discharge Report. • Attachment B - analytical data from Pace Analytical Inc. for the January 2016 monthly sampling

event. • Attachment C - analytical data from Pace Analytical Inc. for the February 2016 monthly sampling

event. • Attachment D - analytical data from Pace Analytical Inc. for the March 2016 monthly sampling

event.

Analytical results from these sampling events1 showed that the treated discharge water was in compliance with the MCES permit discharge limitations during this reporting period.

1 Note that in addition to the required sampling for sample point SP-01 (identified as sample SE EFFLUENT in the attached lab reports), Canadian Pacific voluntarily samples groundwater from the five recovery wells (RW0?-39-SP, RW0?-40-SP, RW06-28-I, RW0?-38-1, RW06-27-BR) on a quarterly basis. All analytical data is included in Attachments B, C and D; only the required discharge data is included in the Special Discharge Report in Attachment A and the corresponding analytical reports.

Golder Associates Inc. 1751 West County Rd. B, Ste. 105

Roseville, MN USA 55113 Tel: (651) 697-9737 Fax: (651) 697-9737 www.golder.com

Golder Associates: Operations in Africa, Asia, Australasia, Europe, North America and South America

Ms. Ashley Corbeille MCES 2

April 14, 2016 023-6105.016

If you have any questions or comments, please do not hesitate to contact Barbara Johnson at (651) 697-9737. Thank you for your assistance in this matter.

Very truly yours,

GOLDER ASSOCIATES INC.

Alan Phillips Staff Geologist

Cc: Ms. Aimee Zack, CP Ms. Claire Mackler, Golder

~~ Barbara Johnson, PE Associate

<!I Golder Associates

Attachment A

SPECIAL DISCHARGE REPORT

Metropolitan Council Environmental Services Industrial Waste & Pollution Prevention Section 390 North Robert Street St. Paul, Minnesota 55101-1805

For MCES Use Only

Permit No: Staff: Received : 0 L 45 E

SPECIAL DISCHARGE REPORT- REPORTING PERIOD INFORMATION

1. Permittee Name: Canadian Pacific Railway Permit No: 2289 ----2. Facility Address: 28th Ave NE & Central Ave NE, Minneapolis, MN 55418

Billing Address Changed? 0 Yes @ No Changes:---------------------

Mailing Address Changed? Q Yes (!) No Changes:

3. Reporting Period: Year: 2016 Check applicable period below:

Quarterly Reporters: (!) Jan-Mar 0 Apr-Jun 0 Jul-Sep 0 Oct-Dec

Annual Reporters: 0 Jan-Dec

4. Discharge Information:

Indicate whether the wastewater was discharged on-site and/or hauled during this reporting period, and complete the associated questions. If no wastewater was discharged to MCES during this reporting period, indicate no discharge.

D No Discharge to MCES during this reporting period

If no discharge is selected, proceed directly to Item #5.

I./ I On-Site Discharge

A. Total volume discharged during this reporting period (gallons): 3,287,300 ----------------

8. Total days of discharge during this reporting period (days): 91 ----------------

C. Average volume discharged per day (gallons/day): 36, 124 ----------------

D. Method of volume determination for this period: Effluent flow meter ----------------

0 Hauled Discharge

A. Total number of loads hauled during this reporting period:

B. Total volume hauled during this reporting period (gallons):

C. Total days of discharge during this reporting period (days):

D. Average volume per discharge day (gallons/day):

E. Method of volume determination for this period:

F. Liquid Waste Hauler name and permit number:

Report form help sheet

SDR-RPl-2015 Page 1of2

5. Changes/Problems: Have there been significant process problems/changes during this reporting period?

0 Yes (!) No If Yes with no previous MCES notification, add explanation below:

6. Planned Changes: Are there any planned or expected future changes that will impact discharge volume or quality?

0 Yes ® No If Yes, add explanation below:

7. Data Sheets: I certify that all sampling data that occurred during this reporting period has been submitted to MCES.

(!) Yes 0 No If No, add explanation below:

8. Representative Discharge: Are the analytical results submitted during this reporting period representative of the

wastewater discharged during this reporting period?

@ Yes 0 No If No, add explanation below:

9. General comments regarding submission:

10. Certification Statement:

"/ certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to ensure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties under law for submitting false information, including the possibility of fine and imprisonment for known violations."

Name (print): Barbara Johnson, PE Title: Authorized Representative for Canadian Pacific

Signature: -~<f~ Date: r:f.w /p Email: [email protected] Phone: 651-697-9737

SDR-RPl-2015 Page 2 of 2

Metropolitan Council Environmental Services Industrial Waste & Pollution Prevention Section 390 North Robert Street St. Paul, Minnesota 55101-1805

For MCES Use Only

Permit No: Staff:

Received: 0 L 45 E

SPECIAL DISCHARGE REPORT - SAMPLING RESULTS Please complete Page 2 of this form for each monitoring point with sampling requirements in Attachment A of the Permit.

1. Permittee Name: Canadian Pacific Railway

2. Facility Address: 28th Ave NE & Central Ave NE, Minneapolis, MN 55418

3. Reporting Period: Year: 20_1_6 ___ _ Choose applicable period below:

Quarterly Reporter: ® Jan-Mar

Semi-Annual Reporter: 0 Jan-Jun

Annual Reporter: O Jan-Dec

0 Apr-Jun

O Jul-Dec

0 Jul-Sep 0 Oct-Dec

Permit No: 2289 ------

4. Proper Sampling: Were all samples collected and composited according to permit requirements?

EJ Yes D No If No, add explanation below:

5. Proper Analysis: Were all analyses conducted per permit requirements? Ej Yes D No If No, add explanation below:

6. Representative Discha~: Are the an~ical results representative of the wastewater discharged during this monitoring event? L!.J Yes LJ No If No, add explanation below:

7. Compliance Status: Compare the analytical results with the corresponding discharge limits in your Permit. Do any analytical results exceed the corresponding discharge limit(s) in your Permit? D Yes Ej No If Yes, add explanation below:

When did you become aware of the exceedance(s)?

8. General comments regarding submission: Total suspended solids, chemical oxygen demand, and pH are sampled quarterly while volatile organic compounds are sampled monthly. An entry of "NS" in the following sample result tables indicates that the given parameter was not analyzed during the specified monthly sampling event.

9. Certification Statement: "I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to ensure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties under law for submitting false information, including the possibility of fine and imprisonment for known violations. "

Name (print): Barbara Johnson, PE Title: Authorized Representative for Canadian Pacific

Signature: Date:

Email: [email protected] Phone: 651-697-9737

Report form help sheet

Page 1 of 2 SDR-SR-2015

Sample Results: Submit one result sheet for each sampling day per monitoring point. Enter daily values for each sampling event from one monitoring point, in accordance with requirements in the Industrial Discharge Permit (Section B). Daily and long-term values shall be compared to Discharge Limitations in Permit Section A.1 for compliance determinations. Attach all laboratory data sheets and supporting calculations.

Monitoring Point: SP-01 Description: Effluent discharge line

Sample Start Date & Time: 1/18/1615:50 Sample End Date & Time: _1_11_8_11_6_1_5_:5_0 ______ _

Discharge volume through monitoring point on sampling day: 22,149 (estimated)

Sample collected by: D Permittee 0 Other, name: Golder Associates Inc.

gallons

Method of collection: 0 Manual D Automatic

Sample composited by: D Permittee D Other, name: ------------- Composite method: N_A ____________ _

Substance Analytical Result Unit Detection Limits Analysis Method Sample Method Sample Laboratory Result Container Type Name

pH NS s.u.

Total Suspended Solids NS mg/I

Chemical Oxygen Demand NS mg/I

1, 1-Dichloroethane 0.0154 mg/I 0.00024 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

1, 1-Dichloroethene 0.0050 mg/I 0.00041 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

cis-1,2-Dichloroethene 0.0145 mg/I 0.00026 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

Tetrachloroethene 0.0409 mg/I 0.00050 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

1, 1, 1-Trichloroethane 0.0129 mg/I 0.00050 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

Trichloroethene 0.0058 mg/I 0.00033 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

Vinyl chloride 0.00018 mg/I 0.00018 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I






Sample collected by: D Permittee El Other, name: Golder Associates Inc.

gallons

Method of collection: 0 Manual D Automatic

Sample composited by: D Permittee D Other, name: ------------- Composite method: N_A _____________ _

Substance Analytical Result Unit Detection Limits Analysis Method Sample Method

Sample Laboratory Result Container Type Name

pH NS S.U.

Total Suspended Solids NS mg/I

Chemical Oxygen Demand NS mg/I




Tetrachloroethene 0.0396 mg/I 0.00050 EPA 8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.



mg/I

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I






Sample collected by: D Permittee EJ Other, name: Golder Associates Inc.

gallons

Method of collection: EJ Manual D Automatic

Sample composited by: D Permittee D Other, name: ------------- Composite method: N_A ____________ _

Substance Analytical Result Unit Detection Limits Analysis Method Sample Method Sample Laboratory

Result Container Type Name

pH 7.2 S.U. O.Q10 4500H+ Grab-Single Plastic - 1 Liter Pace Analytical Services, Inc.

Total Suspended Solids <0.95 mg/I 0.95 SM 25400 Grab - Single Plastic - 1 Liter Pace Analytical Services, Inc.

Chemical Oxygen Demand 15.0 mg/I 14.2 EPA410.4 Grab - Single Plastic - 250 ml Pace Analytical Services, Inc.




T etrachloroethene 0.0405 mg/I 0.00050 EPA8260 Grab - Single Vial - 40ml clear Pace Analytical Services, Inc.



mg/I

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I

mg/I


Attachment B

ANALYTICAL RESULTS FOR TREATED GROUNDWATER

January 2016

#=CL#

January 26, 2016

LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40127268

40127268Project:Pace Project No.:

RE:

Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102

023-6105-016 CP-SHOREHAM YARD

Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on January 20, 2016.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Laurie [email protected] Manager

Enclosures

REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9

Green Bay, WI 54302(920)469-2436

Page 1 of 15

#=CP#

CERTIFICATIONS

Pace Project No.:Project:

40127268023-6105-016 CP-SHOREHAM YARD

Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334Virginia VELAP ID: 460263

North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Virginia VELAP ID: 460263Virginia VELAP Certification ID: 460263Wisconsin Certification #: 405132750




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SAMPLE SUMMARY


40127268023-6105-016 CP-SHOREHAM YARD

Lab ID Sample ID Matrix Date Collected Date Received

40127268001 011816-0800-200 Water 01/18/16 08:00 01/20/16 08:50

40127268002 SE EFFLUENT Water 01/18/16 15:50 01/20/16 08:50




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SAMPLE ANALYTE COUNT


40127268023-6105-016 CP-SHOREHAM YARD

Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts

40127268001 011816-0800-200 EPA 8260 71 PASI-GHNW

40127268002 SE EFFLUENT EPA 8260 71 PASI-GHNW




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ANALYTICAL RESULTS


40127268023-6105-016 CP-SHOREHAM YARD

Sample: 011816-0800-200 Lab ID: 40127268001 Collected: 01/18/16 08:00 Received: 01/20/16 08:50 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 82608260 MSV

Acetone <3.0 ug/L 01/22/16 14:16 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 01/22/16 14:16 107-05-15.0 2.2 1Benzene <0.50 ug/L 01/22/16 14:16 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 01/22/16 14:16 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 01/22/16 14:16 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 01/22/16 14:16 75-27-41.0 0.50 1Bromoform <0.50 ug/L 01/22/16 14:16 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 01/22/16 14:16 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 01/22/16 14:16 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 01/22/16 14:16 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 01/22/16 14:16 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 01/22/16 14:16 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 01/22/16 14:16 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 01/22/16 14:16 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 01/22/16 14:16 75-00-31.0 0.37 1Chloroform <2.5 ug/L 01/22/16 14:16 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 01/22/16 14:16 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 01/22/16 14:16 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 01/22/16 14:16 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 01/22/16 14:16 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 01/22/16 14:16 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 01/22/16 14:16 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 01/22/16 14:16 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 01/22/16 14:16 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 01/22/16 14:16 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 01/22/16 14:16 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 01/22/16 14:16 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 01/22/16 14:16 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 01/22/16 14:16 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 01/22/16 14:16 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 01/22/16 14:16 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 01/22/16 14:16 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 01/22/16 14:16 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 01/22/16 14:16 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 01/22/16 14:16 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 01/22/16 14:16 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 01/22/16 14:16 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 01/22/16 14:16 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 01/22/16 14:16 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 01/22/16 14:16 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 01/22/16 14:16 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 01/22/16 14:16 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 01/22/16 14:16 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 01/22/16 14:16 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 01/22/16 14:16 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 01/22/16 14:16 108-10-15.0 2.1 1


without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 10:15 AM


Green Bay, WI 54302(920)469-2436

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ANALYTICAL RESULTS


40127268023-6105-016 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 01/22/16 14:16 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 01/22/16 14:16 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 01/22/16 14:16 103-65-11.0 0.50 1Styrene <0.50 ug/L 01/22/16 14:16 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 01/22/16 14:16 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 01/22/16 14:16 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 01/22/16 14:16 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 01/22/16 14:16 109-99-95.0 2.0 1Toluene <0.50 ug/L 01/22/16 14:16 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 01/22/16 14:16 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 01/22/16 14:16 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 01/22/16 14:16 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 01/22/16 14:16 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 01/22/16 14:16 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 01/22/16 14:16 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 01/22/16 14:16 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 01/22/16 14:16 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 01/22/16 14:16 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 01/22/16 14:16 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 01/22/16 14:16 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 01/22/16 14:16 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 01/22/16 14:16 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 96 % 01/22/16 14:16 460-00-470-130 1Dibromofluoromethane (S) 115 % 01/22/16 14:16 1868-53-770-130 1Toluene-d8 (S) 98 % 01/22/16 14:16 2037-26-570-130 1




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ANALYTICAL RESULTS


40127268023-6105-016 CP-SHOREHAM YARD

Sample: SE EFFLUENT Lab ID: 40127268002 Collected: 01/18/16 15:50 Received: 01/20/16 08:50 Matrix: Water



Acetone <3.0 ug/L 01/22/16 14:38 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 01/22/16 14:38 107-05-15.0 2.2 1Benzene <0.50 ug/L 01/22/16 14:38 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 01/22/16 14:38 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 01/22/16 14:38 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 01/22/16 14:38 75-27-41.0 0.50 1Bromoform <0.50 ug/L 01/22/16 14:38 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 01/22/16 14:38 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 01/22/16 14:38 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 01/22/16 14:38 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 01/22/16 14:38 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 01/22/16 14:38 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 01/22/16 14:38 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 01/22/16 14:38 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 01/22/16 14:38 75-00-31.0 0.37 1Chloroform <2.5 ug/L 01/22/16 14:38 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 01/22/16 14:38 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 01/22/16 14:38 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 01/22/16 14:38 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 01/22/16 14:38 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 01/22/16 14:38 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 01/22/16 14:38 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 01/22/16 14:38 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 01/22/16 14:38 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 01/22/16 14:38 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 01/22/16 14:38 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 01/22/16 14:38 75-71-81.0 0.22 11,1-Dichloroethane 15.4 ug/L 01/22/16 14:38 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 01/22/16 14:38 107-06-21.0 0.17 11,1-Dichloroethene 5.0 ug/L 01/22/16 14:38 75-35-41.0 0.41 1cis-1,2-Dichloroethene 14.5 ug/L 01/22/16 14:38 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 01/22/16 14:38 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 01/22/16 14:38 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 01/22/16 14:38 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 01/22/16 14:38 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 01/22/16 14:38 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 01/22/16 14:38 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 01/22/16 14:38 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 01/22/16 14:38 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 01/22/16 14:38 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 01/22/16 14:38 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 01/22/16 14:38 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 01/22/16 14:38 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 01/22/16 14:38 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 01/22/16 14:38 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 01/22/16 14:38 108-10-15.0 2.1 1




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ANALYTICAL RESULTS


40127268023-6105-016 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 01/22/16 14:38 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 01/22/16 14:38 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 01/22/16 14:38 103-65-11.0 0.50 1Styrene <0.50 ug/L 01/22/16 14:38 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 01/22/16 14:38 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 01/22/16 14:38 79-34-51.0 0.25 1Tetrachloroethene 40.9 ug/L 01/22/16 14:38 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 01/22/16 14:38 109-99-95.0 2.0 1Toluene <0.50 ug/L 01/22/16 14:38 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 01/22/16 14:38 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 01/22/16 14:38 120-82-15.0 2.2 11,1,1-Trichloroethane 12.9 ug/L 01/22/16 14:38 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 01/22/16 14:38 79-00-51.0 0.20 1Trichloroethene 5.8 ug/L 01/22/16 14:38 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 01/22/16 14:38 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 01/22/16 14:38 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 01/22/16 14:38 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 01/22/16 14:38 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 01/22/16 14:38 108-67-81.0 0.50 1Vinyl chloride 0.18J ug/L 01/22/16 14:38 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 01/22/16 14:38 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 01/22/16 14:38 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 95 % 01/22/16 14:38 460-00-470-130 1Dibromofluoromethane (S) 112 % 01/22/16 14:38 1868-53-770-130 1Toluene-d8 (S) 97 % 01/22/16 14:38 2037-26-570-130 1




Green Bay, WI 54302(920)469-2436

Page 8 of 15

#=QC#

QUALITY CONTROL DATA


40127268023-6105-016 CP-SHOREHAM YARD

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:QC Batch Method:

Analysis Method:Analysis Description:

MSV/31978EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40127268001, 40127268002

Parameter UnitsBlankResult

ReportingLimit Qualifiers

METHOD BLANK: 1286689Associated Lab Samples: 40127268001, 40127268002

Matrix: Water

AnalyzedMDL

1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 01/22/16 06:490.181,1,1-Trichloroethane ug/L <0.50 1.0 01/22/16 06:490.501,1,2,2-Tetrachloroethane ug/L <0.25 1.0 01/22/16 06:490.251,1,2-Trichloroethane ug/L <0.20 1.0 01/22/16 06:490.201,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 01/22/16 06:490.811,1-Dichloroethane ug/L <0.24 1.0 01/22/16 06:490.241,1-Dichloroethene ug/L <0.41 1.0 01/22/16 06:490.411,1-Dichloropropene ug/L <0.44 1.0 01/22/16 06:490.441,2,3-Trichlorobenzene ug/L <2.1 5.0 01/22/16 06:492.11,2,3-Trichloropropane ug/L <0.50 1.0 01/22/16 06:490.501,2,4-Trichlorobenzene ug/L <2.2 5.0 01/22/16 06:492.21,2,4-Trimethylbenzene ug/L <0.50 1.0 01/22/16 06:490.501,2-Dibromo-3-chloropropane ug/L <2.2 5.0 01/22/16 06:492.21,2-Dibromoethane (EDB) ug/L <0.18 1.0 01/22/16 06:490.181,2-Dichlorobenzene ug/L <0.50 1.0 01/22/16 06:490.501,2-Dichloroethane ug/L <0.17 1.0 01/22/16 06:490.171,2-Dichloropropane ug/L <0.23 1.0 01/22/16 06:490.231,3,5-Trimethylbenzene ug/L <0.50 1.0 01/22/16 06:490.501,3-Dichlorobenzene ug/L <0.50 1.0 01/22/16 06:490.501,3-Dichloropropane ug/L <0.50 1.0 01/22/16 06:490.501,4-Dichlorobenzene ug/L <0.50 1.0 01/22/16 06:490.502,2-Dichloropropane ug/L <0.48 1.0 01/22/16 06:490.482-Butanone (MEK) ug/L <3.0 20.0 01/22/16 06:493.02-Chlorotoluene ug/L <0.50 1.0 01/22/16 06:490.504-Chlorotoluene ug/L <0.21 1.0 01/22/16 06:490.214-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 01/22/16 06:492.1Acetone ug/L <3.0 20.0 01/22/16 06:493.0Allyl chloride ug/L <2.2 5.0 01/22/16 06:492.2Benzene ug/L <0.50 1.0 01/22/16 06:490.50Bromobenzene ug/L <0.23 1.0 01/22/16 06:490.23Bromochloromethane ug/L <0.34 1.0 01/22/16 06:490.34Bromodichloromethane ug/L <0.50 1.0 01/22/16 06:490.50Bromoform ug/L <0.50 1.0 01/22/16 06:490.50Bromomethane ug/L <2.4 5.0 01/22/16 06:492.4Carbon tetrachloride ug/L <0.50 1.0 01/22/16 06:490.50Chlorobenzene ug/L <0.50 1.0 01/22/16 06:490.50Chloroethane ug/L <0.37 1.0 01/22/16 06:490.37Chloroform ug/L <2.5 5.0 01/22/16 06:492.5Chloromethane ug/L <0.50 1.0 01/22/16 06:490.50cis-1,2-Dichloroethene ug/L <0.26 1.0 01/22/16 06:490.26cis-1,3-Dichloropropene ug/L <0.50 1.0 01/22/16 06:490.50




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#=QC#



40127268023-6105-016 CP-SHOREHAM YARD





Matrix: Water

AnalyzedMDL

Dibromochloromethane ug/L <0.50 1.0 01/22/16 06:490.50Dibromomethane ug/L <0.43 1.0 01/22/16 06:490.43Dichlorodifluoromethane ug/L <0.22 1.0 01/22/16 06:490.22Dichlorofluoromethane ug/L <0.21 1.0 01/22/16 06:490.21Diethyl ether (Ethyl ether) ug/L <2.2 5.0 01/22/16 06:492.2Ethylbenzene ug/L <0.50 1.0 01/22/16 06:490.50Hexachloro-1,3-butadiene ug/L <2.1 5.0 01/22/16 06:492.1Isopropylbenzene (Cumene) ug/L <0.14 1.0 01/22/16 06:490.14m&p-Xylene ug/L <1.0 2.0 01/22/16 06:491.0Methyl-tert-butyl ether ug/L <0.17 1.0 01/22/16 06:490.17Methylene Chloride ug/L <0.23 1.0 01/22/16 06:490.23n-Butylbenzene ug/L <0.50 1.0 01/22/16 06:490.50n-Propylbenzene ug/L <0.50 1.0 01/22/16 06:490.50Naphthalene ug/L <2.5 5.0 01/22/16 06:492.5o-Xylene ug/L <0.50 1.0 01/22/16 06:490.50p-Isopropyltoluene ug/L <0.50 1.0 01/22/16 06:490.50sec-Butylbenzene ug/L <2.2 5.0 01/22/16 06:492.2Styrene ug/L <0.50 1.0 01/22/16 06:490.50tert-Butylbenzene ug/L <0.18 1.0 01/22/16 06:490.18Tetrachloroethene ug/L <0.50 1.0 01/22/16 06:490.50Tetrahydrofuran ug/L <2.0 5.0 01/22/16 06:492.0Toluene ug/L <0.50 1.0 01/22/16 06:490.50trans-1,2-Dichloroethene ug/L <0.26 1.0 01/22/16 06:490.26trans-1,3-Dichloropropene ug/L <0.23 1.0 01/22/16 06:490.23Trichloroethene ug/L <0.33 1.0 01/22/16 06:490.33Trichlorofluoromethane ug/L <0.18 1.0 01/22/16 06:490.18Vinyl chloride ug/L <0.18 1.0 01/22/16 06:490.184-Bromofluorobenzene (S) % 97 70-130 01/22/16 06:49Dibromofluoromethane (S) % 115 70-130 01/22/16 06:49Toluene-d8 (S) % 98 70-130 01/22/16 06:49

Parameter UnitsLCS

Result% RecLimits Qualifiers% RecConc.

1286690LABORATORY CONTROL SAMPLE:LCSSpike

1,1,1-Trichloroethane ug/L 54.350 109 70-1301,1,2,2-Tetrachloroethane ug/L 50.150 100 70-1301,1,2-Trichloroethane ug/L 53.150 106 70-1301,1,2-Trichlorotrifluoroethane ug/L 55.450 111 50-1501,1-Dichloroethane ug/L 50.850 102 70-1301,1-Dichloroethene ug/L 49.350 99 70-1301,2,4-Trichlorobenzene ug/L 55.050 110 70-1301,2-Dibromo-3-chloropropane ug/L 50.150 100 50-1501,2-Dibromoethane (EDB) ug/L 55.250 110 70-1301,2-Dichlorobenzene ug/L 54.850 110 70-130




Green Bay, WI 54302(920)469-2436

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#=QC#



40127268023-6105-016 CP-SHOREHAM YARD


Parameter UnitsLCS



1,2-Dichloroethane ug/L 52.350 105 70-1311,2-Dichloropropane ug/L 53.050 106 70-1301,3-Dichlorobenzene ug/L 54.950 110 70-1301,4-Dichlorobenzene ug/L 54.550 109 70-130Benzene ug/L 53.250 106 70-130Bromodichloromethane ug/L 54.250 108 70-130Bromoform ug/L 52.950 106 68-130Bromomethane ug/L 31.950 64 38-137Carbon tetrachloride ug/L 56.050 112 70-130Chlorobenzene ug/L 55.850 112 70-130Chloroethane ug/L 40.450 81 70-136Chloroform ug/L 53.550 107 70-130Chloromethane ug/L 33.450 67 48-144cis-1,2-Dichloroethene ug/L 51.850 104 70-130cis-1,3-Dichloropropene ug/L 53.050 106 70-130Dibromochloromethane ug/L 55.850 112 70-130Dichlorodifluoromethane ug/L 24.350 49 33-157Ethylbenzene ug/L 57.750 115 70-132Isopropylbenzene (Cumene) ug/L 60.650 121 70-130m&p-Xylene ug/L 118100 118 70-131Methyl-tert-butyl ether ug/L 51.250 102 48-141Methylene Chloride ug/L 50.450 101 70-130o-Xylene ug/L 58.650 117 70-131Styrene ug/L 55.350 111 70-130Tetrachloroethene ug/L 57.450 115 70-130Toluene ug/L 55.950 112 70-130trans-1,2-Dichloroethene ug/L 52.450 105 70-130trans-1,3-Dichloropropene ug/L 48.650 97 70-130Trichloroethene ug/L 56.450 113 70-130Trichlorofluoromethane ug/L 52.350 105 50-150Vinyl chloride ug/L 42.250 84 65-1424-Bromofluorobenzene (S) % 102 70-130Dibromofluoromethane (S) % 93 70-130Toluene-d8 (S) % 100 70-130




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#=QL#

QUALIFIERS


40127268023-6105-016 CP-SHOREHAM YARD

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES

Pace Analytical Services - Green BayPASI-G




Green Bay, WI 54302(920)469-2436

Page 12 of 15

#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE


40127268023-6105-016 CP-SHOREHAM YARD

Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch

40127268001 MSV/31978011816-0800-200 EPA 826040127268002 MSV/31978SE EFFLUENT EPA 8260




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Pag

e 14

of 1

5

UPPER MIDWEST REGION Page

ompany Name:

Branch/Location:

Project Contact:

Phone:

Project Number:

Project Name:

Project State:

Sampled By (Print):

Sampled By (Sign):

PO#: Regulatory Program:

·eAnalytica/ 411

WWW.pacelab.S.oom

MN,612~

CHAIN OF CUSTODY •preservation Codes

A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

H=Sodium Bisulfate Solution !=Sodium Thiosulfate J=O!her

FILTERED? (YES/NO)

PRESERVATION (CODE)*

Data Package Options (blllable)

MS/MSD 0 On your sample

(billable) 0 NOT needed on

your sample

Matrix Codes

0 EPA Level Ill

0 EPA Level IV

PACE LAB# I CLIENT FIELD ID

Ct lilG -ocz,oo .,.z..co 5t;; e{.fl'1e"

A=Air B =Biota C =Charcoal O=Oil s =Soil

Rush Turnaround Time Requested - Prelims (Rush TAT subject to approval/surcharge)

Date Needed:

'(j >

• ~ I <'.'.'300;n~u~ \ i :::> <

Mail To Contact:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CLIENT COMMENTS

LAB COMMENTS (lab Use Only)

- Lill""\. ,e 5 .un..,,,.\.,B

Profile#

PACE Project No. ~ Oate!Time:

I'& y;:~;:,te. / I': 7 0 400--1'2-V ·"'

I TransmitPrTlimRushResultsby(completewhatyouwant): I v VV\11\1.,:) I IQ\ /1 ll¥ ~',,!,,?\ 1 I ~ .,......,.,,..., J, 11,.)l.ll'-'C l ldl II'"'\ N="4RecelptTemp=

Emall#1: •c

Emall#2:

Telephone:

Fax:

Samples on HOLD are subject to

special pricing and release of llablllty

C019a(27 Jun2006)

Datemme: Received By:

Datemme: Received By:

Date/Time:

Date/Time:

Sample Receipt pH

OK I Adjusted

of 15

Sample Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9

Green Bay, WI 54302

ace Analytical"

~lientName: (?x)\der ASSoc1<Ak.5 Courier: r Fed Ex r UPS - Client r Pace ;)ther: V\/a)tD Tracking #: q (,a3'...@Q4 ~ ~

Project#:' WOl.40127268 1111111111111111111111

Custody Seal on Cooler/Box Present: l'(r yes - no Seals intact: ff yes r no

Custody Seal on Samples Present: r yes rr-no Seals intact: r yes ano

40127268

Packing Material: r('subble Wr~p ly"Bubble Bags r None r Other

Thermometer Used SQ -?,? Type of Ice:~ ~lue ~ry N~ne Samples on ice, cooling process has begun

Cooler Temperature Uncorr· (' 1 /Corr· G ~g1cal Tissue IS Frozen: r yes

Temp Blank Present: ryes ~o r no Person examinin~ iontents: Date: 11~ 0 Temp should be above freezing to 6°C for all sample except Biota. Initials:· - ~\\

Frozen Biota Samples should be received s; 0°C. Comments: ·-Chain of Custody Present: ~s ONo ON/A 1.

Chain of Custody Filled Out: ~es ONo ON/A 2.

Chain of Custody Relinquished: ~s 0No ON/A 3.

Sampler Name & Signature on COC: ~es ONo ON/A 4. -Samples Arrived within Hold Time: ~s ONo ON/A 5.

- VOA Samples frozen upon receipt OYes ONo DatefTime:

Short Hold Time Analysis (<72hr): 0Yes ~o ON/A 6.

Rush Turn Around Time Requested: OYes ~o ON/A 7.

Sufficient Volume: ~s ONo ON/A 8.

Correct Containers Used: ~s ONo ON/A 9.

-Pace Containers Used: ~ ONo ON/A

-Pace IR Containers Used: OYes ONo MA

Mves .,,

Containers Intact: ONo ON/A 10. -

Filtered volume received for Dissolved tests OYes ONo ikN'1A 11.

Sample Labels match COC: ~ONo ON/A 12.

-Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked.

0Yes ONo t;]'N/A r HN03 r H2S04 r NaOH r NaOH +ZnAct (Non-Compliance noted in 13.) 13. - --- -- - --- .. -- -- - --- ---- -- --- --- -- - ---All containers needing preservation are found to be in compliance with EPA recommendation. OYes ONo ~A (HN9~J:!~~ ~<?lj+Zn!-9t ~9.:. ~aOlj ~12) ______________ exceptions: OA, liforrn, TOC, TOX, TOH, '(v. Initial when 'Lab Std #ID of luaret O&G, WIDR , henolics, OTHER: Yes 0No completed preservative Time:

Headspace in VOA Vials ( >6mm): efves ONo ON/A 14.

Trip Blank Present: (1'.lves ONo ON/A 15.

Trip Blank Custody Seals Present 9f'es DNo ON/A

Pace Trip Blank Lot# (if purchased): ~lnc'ci>J llv cos-\nro~( \o.h\:' B" \fA.011 (I> Client Notification/ Resolution: If checked, see attached form for additional comments 0

Person Contacted: Date/Time: ~~~~~~~~~~~~~-

Comments/ Resolution: ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

Project Manager Review: Date:

F-GB-C-031-Rev.03 (9April2015) SCUR Form

Attachment C


February 2016

#=CL#

February 25, 2016



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on February 23, 2016.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 16

#=CP#

CERTIFICATIONS


40128529023-6105-015 CP-SHOREHAM YARD

Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334Virginia VELAP ID: 460263North Dakota Certification #: R-150

South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Virginia VELAP Certification ID: 460263Virginia VELAP ID: 460263Wisconsin Certification #: 405132750Wisconsin DATCP Certification #: 105-444




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#=SS#

SAMPLE SUMMARY


40128529023-6105-015 CP-SHOREHAM YARD


40128529001 022216-0800-200 Water 02/22/16 08:00 02/23/16 08:45





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#=SA#



40128529023-6105-015 CP-SHOREHAM YARD


40128529001 022216-0800-200 EPA 8260 71 PASI-GHNW

40128529002 SE EFFLUENT EPA 8260 71 PASI-GHNW




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#=AR#

ANALYTICAL RESULTS


40128529023-6105-015 CP-SHOREHAM YARD






without the written consent of Pace Analytical Services, Inc..Date: 02/25/2016 03:17 PM


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#=AR#

ANALYTICAL RESULTS


40128529023-6105-015 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40128529023-6105-015 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40128529023-6105-015 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 02/24/16 15:45 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 02/24/16 15:45 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 02/24/16 15:45 103-65-11.0 0.50 1Styrene <0.50 ug/L 02/24/16 15:45 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 02/24/16 15:45 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 02/24/16 15:45 79-34-51.0 0.25 1Tetrachloroethene 39.6 ug/L 02/24/16 15:45 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 02/24/16 15:45 109-99-95.0 2.0 1Toluene <0.50 ug/L 02/24/16 15:45 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 02/24/16 15:45 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 02/24/16 15:45 120-82-15.0 2.2 11,1,1-Trichloroethane 12.8 ug/L 02/24/16 15:45 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 02/24/16 15:45 79-00-51.0 0.20 1Trichloroethene 5.1 ug/L 02/24/16 15:45 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 02/24/16 15:45 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 02/24/16 15:45 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 02/24/16 15:45 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 02/24/16 15:45 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 02/24/16 15:45 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 02/24/16 15:45 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 02/24/16 15:45 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 02/24/16 15:45 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 97 % 02/24/16 15:45 460-00-470-130 1Dibromofluoromethane (S) 99 % 02/24/16 15:45 1868-53-770-130 1Toluene-d8 (S) 92 % 02/24/16 15:45 2037-26-570-130 1




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#=QC#



40128529023-6105-015 CP-SHOREHAM YARD




MSV/32318EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40128529001, 40128529002




Matrix: Water

AnalyzedMDL





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#=QC#



40128529023-6105-015 CP-SHOREHAM YARD





Matrix: Water

AnalyzedMDL


Parameter UnitsLCS







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#=QC#



40128529023-6105-015 CP-SHOREHAM YARD


Parameter UnitsLCS



1,2-Dichloroethane ug/L 19.020 95 70-1311,2-Dichloropropane ug/L 19.020 95 70-1301,3-Dichlorobenzene ug/L 18.520 92 70-1301,4-Dichlorobenzene ug/L 19.720 99 70-130Benzene ug/L 17.820 89 70-130Bromodichloromethane ug/L 20.020 100 70-130Bromoform ug/L 19.720 98 68-130Bromomethane ug/L 15.120 75 38-137Carbon tetrachloride ug/L 21.520 107 70-130Chlorobenzene ug/L 21.620 108 70-130Chloroethane ug/L 16.220 81 70-136Chloroform ug/L 18.620 93 70-130Chloromethane ug/L 13.420 67 48-144cis-1,2-Dichloroethene ug/L 18.720 94 70-130cis-1,3-Dichloropropene ug/L 19.220 96 70-130Dibromochloromethane ug/L 20.320 101 70-130Dichlorodifluoromethane ug/L 10.320 52 33-157Ethylbenzene ug/L 20.720 103 70-132Isopropylbenzene (Cumene) ug/L 21.320 106 70-130m&p-Xylene ug/L 43.040 107 70-131Methyl-tert-butyl ether ug/L 18.520 92 48-141Methylene Chloride ug/L 17.820 89 70-130o-Xylene ug/L 20.520 103 70-131Styrene ug/L 21.620 108 70-130Tetrachloroethene ug/L 21.520 108 70-130Toluene ug/L 20.020 100 70-130trans-1,2-Dichloroethene ug/L 19.220 96 70-130trans-1,3-Dichloropropene ug/L 17.620 88 70-130Trichloroethene ug/L 21.220 106 70-130Trichlorofluoromethane ug/L 20.420 102 50-150Vinyl chloride ug/L 17.620 88 65-1424-Bromofluorobenzene (S) % 108 70-130Dibromofluoromethane (S) % 98 70-130Toluene-d8 (S) % 94 70-130

Parameter UnitsMS

Result% RecLimits Qual% RecConc.

1298587MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpikeResult

40128493005

1298588

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L 50 98 70-13097 1 2050<0.50 49.1 48.71,1,2,2-Tetrachloroethane ug/L 50 94 70-13094 1 2050<0.25 46.8 47.21,1,2-Trichloroethane ug/L 50 96 70-13098 2 2050<0.20 48.1 49.01,1,2-Trichlorotrifluoroethane ug/L 50 102 50-151102 0 2050<0.81 50.8 50.91,1-Dichloroethane ug/L 50 83 70-13484 2 2050<0.24 41.3 42.21,1-Dichloroethene ug/L 50 85 70-13986 1 2050<0.41 42.6 43.1




Green Bay, WI 54302(920)469-2436

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#=QC#



40128529023-6105-015 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40128493005

1298588

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,2,4-Trichlorobenzene ug/L 50 96 70-13096 1 2050<2.2 47.9 48.21,2-Dibromo-3-chloropropane

ug/L 50 95 50-15096 1 2050<2.2 47.4 47.8

1,2-Dibromoethane (EDB) ug/L 50 101 70-130105 4 2050<0.18 50.5 52.51,2-Dichlorobenzene ug/L 50 93 70-13094 0 2050<0.50 46.7 46.81,2-Dichloroethane ug/L 50 90 70-13291 1 2050<0.17 44.9 45.41,2-Dichloropropane ug/L 50 88 70-13093 5 2050<0.23 44.1 46.41,3-Dichlorobenzene ug/L 50 92 70-13094 2 2050<0.50 46.2 46.91,4-Dichlorobenzene ug/L 50 94 70-13095 0 2050<0.50 47.1 47.3Benzene ug/L 50 82 70-13083 0 2050<0.50 41.2 41.3Bromodichloromethane ug/L 50 99 70-132100 1 2050<0.50 49.6 49.9Bromoform ug/L 50 101 68-130103 1 2050<0.50 50.7 51.3Bromomethane ug/L 50 69 38-14172 5 2050<2.4 34.3 36.2Carbon tetrachloride ug/L 50 104 70-130103 1 2050<0.50 52.2 51.6Chlorobenzene ug/L 50 104 70-130106 2 2050<0.50 51.9 52.9Chloroethane ug/L 50 73 66-15273 0 2050<0.37 36.7 36.7Chloroform ug/L 50 88 70-13087 0 2050<2.5 43.8 43.7Chloromethane ug/L 50 67 44-15168 1 2050<0.50 33.6 33.9cis-1,2-Dichloroethene ug/L 50 88 70-13088 1 2050<0.26 43.8 44.1cis-1,3-Dichloropropene ug/L 50 99 70-130102 3 2050<0.50 49.3 50.8Dibromochloromethane ug/L 50 104 70-130105 1 2050<0.50 52.0 52.4Dichlorodifluoromethane ug/L 50 49 29-16050 1 2050<0.22 24.7 25.0Ethylbenzene ug/L 50 103 70-132104 1 2050<0.50 51.5 52.1Isopropylbenzene (Cumene) ug/L 50 107 70-130108 1 2050<0.14 53.3 54.0m&p-Xylene ug/L 100 107 70-131107 0 20100<1.0 107 107Methyl-tert-butyl ether ug/L 50 88 48-14390 2 2050<0.17 44.1 45.1Methylene Chloride ug/L 50 85 70-13085 1 2050<0.23 42.3 42.5o-Xylene ug/L 50 103 70-131104 1 2050<0.50 51.5 52.0Styrene ug/L 50 108 70-130110 2 2050<0.50 53.9 55.0Tetrachloroethene ug/L 50 102 70-130103 1 2050<0.50 51.1 51.5Toluene ug/L 50 96 70-13098 2 2050<0.50 47.9 48.8trans-1,2-Dichloroethene ug/L 50 90 70-13290 0 2050<0.26 44.8 44.9trans-1,3-Dichloropropene ug/L 50 91 70-13091 0 2050<0.23 45.4 45.5Trichloroethene ug/L 50 101 70-130102 1 2050<0.33 50.4 50.9Trichlorofluoromethane ug/L 50 94 50-15395 2 2050<0.18 46.9 47.7Vinyl chloride ug/L 50 86 60-15586 0 2050<0.18 43.0 43.24-Bromofluorobenzene (S) % 109 70-130110Dibromofluoromethane (S) % 97 70-13096Toluene-d8 (S) % 96 70-13096




Green Bay, WI 54302(920)469-2436

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#=QL#

QUALIFIERS


40128529023-6105-015 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES





Green Bay, WI 54302(920)469-2436

Page 13 of 16

#=CR#



40128529023-6105-015 CP-SHOREHAM YARD


40128529001 MSV/32318022216-0800-200 EPA 826040128529002 MSV/32318SE EFFLUENT EPA 8260




Green Bay, WI 54302(920)469-2436

Page 14 of 16

Pag

e 15

of 1

6(Please Print Clearly)

Company Name:

Branch/Location:

Project Contact:

Phone:

Project Number:

Project Name:

Project State:

Sampled By (Print):

Sampled By (Sign):

PO#:

~es

Regulatory Program:

UPPER MIDWEST REGION t'f 1-/Q/l'/,GL 't MN'' '](o-607-170-0 w1, 920469-2 /' <;;? '0 of \IJl l> f u" .J.'" 1

Quote#:

·eAna.lytical • www.pecelabs.oom

CHAIN OF CUSTODY Mall To Contact:

*Preservation Codes A=None B=HCL C=H2S04 D=HND3 E=DI Water F=Methanol G=NaOH

H=Sodium Bisulfate Solution !=Sodium Thiosulfate J=Other

FILTERED? (YES/NO)


Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Data Package Options (billable)

llllS/MSD 0 On your sample

(billable) 0 NOT needed on

your sample

Matrix Codes

0 EPA level Ill

0 EPA level IV

PACE LAB# CLIENT FIELD ID

(/0 &1...'lZ..\~-~~~ ~uio

~ SE E.f.fl"'e~

A=Nr B =Biota C =Charcoal O=Oil


Date Needed: Transmit Prelim Rush Results by (complete what you want}:

Emall#1:

Emall#2:

,Telephone:

Fax:

W=Water OW= Drinking Water GW = Ground Water SW = Surface Water


special pricing and release of llablllty

Relinquished By:

C019a(27 Jun2006)

Datemme:

Datemme: :eceived By:

Invoice To Phone:

CLIENT COMMENTS

Date/Time:

Dateffime:

LAB COMMENTS (lab Use Only)

Profile#

~ 5·-

PACE Project No.

Sample Receipt pH

OK I Adjusted

ustodv Seal

oc

of 16


Green Bay, WI 54302

race Analytical' Project#: W0#:4012as29

~lWUI I Ill 11111111

/ Client Name: [JJ) Jc/er Courier: r Fed Ex riJPs - Client r Pace Jther: wa lt[,O Tracking #: a_ Custody Sea-1'""'0;:;.n"""'c'-0-'o~le::::or'""te,_o'"'x-P..:r;;..e.1..s-e-nt-:~..,_,,r-s---. -n-o--3-ea_l_s-in-t-ac_t_: I\' ,.c;is r no

Custody Seal on Samples Present: r es r no Seals intact: ~s - no

Packing Material: r Bubble Wrap r Bubble Bags r J.Clf.\e r Other

Thermometer Used SR LRf Type of Ice:~ ~lue ~ry N~ne Psamples on ice, cooling process has begun

Cooler Temperature mrr: -~ /Corr: ~ B1olog1cal Tissue IS Frozen: r yes

Temp Blank Present: es rno r no ~~~~oA{a~·contents: Temp should be above freezing to 6°C for all sample except Biota.

Initials: ~ Frozen Biota Samples should be received:;; 0°C. ~

Comments:

Chain of Custody Present: ·~~ ONo ON/A 1.

Chain of Custody Filled Out: IS ,,, YE!S 0No ON/A 2.

Chain of Custody Relinquished: fSa<,js 0No ON/A 3.

Sampler Name & Signature on COC: l)G, 0No ON/A 4.

Samples Arrived within Hold Time: ~s ONo ON/A 5.

- VOA Samples frozen upon receipt 0Yes 0No Date/Time:

Short Hold Time Analysis (<72hr): OYes r!l:iJ ON/A 6.

Rush Turn Around Time Requested: 0Yes ~ ON/A 7.

Sufficient Volume: ri)es ONo ON/A 8.

Correct Containers Used: ~es 0No ON/A 9.

-Pace Containers Used: es 0No ON/A

-Pace IR Containers Used: OYes 0No iJ Containers Intact: ~s 0No ON/A 10.

\

't5ifJA Filtered volume received for Dissolved tests OYes 0No 11.

Sample Labels match COC: ~es 0No ON/A 12.

-Includes date/time/ID/Analysis Matrix: w All containers needing preservation have been checked. rfo-.

r HN03 r H2S04 r NaOH r NaOH +ZnAct (Non-Compliance noted in 13.) OYes ONo /A 13. -- -- -- - ---- -- -- - --- -- - - -- --- --- ---- --All containers needing preservation are found to be in ~

compliance with EPA recommendation. OYes ONo ·IA (~92:.!::!2@ :;;_2.:_ Na<;?':!+Zn~~t~9.:. ~aO!j ~12) ______________ exceptions: 0 coliform, TOC, TOX, TOH, )C@e Initial when llab Std #ID of 1ua1e1 O&G, WIDROW, Phenolics, OTHER: s 0No completed preservative Time:

Headspace in VOA Vials ( >6mm): ~s ONo ON/A 14./JD I /(}f,d ,.:::) l:l 7. /J; /J l Trip Blank Present: 0Yes f ON/A 15. l I

Trip Blank Custody Seals Present 0Yes No ~ Pace Trip Blank Lot# (if purchased): Client Notification/ Resolution: If checked, see attached form for additional comments LJ

Person Contacted: DatefTime: ---------------------Comments/ Resolution: ________________ -------------------------------------

Project Manager Review:

F-GB-C-031-Rev.03 (9April2015) SCUR Form

Attachment D


March 2016

#=CL#

March 30, 2016



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on March 17, 2016. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

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#=CP#

CERTIFICATIONS


40129502023-6105-016 CP-SHOREHAM YARD

Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334Virginia VELAP ID: 460263North Dakota Certification #: R-150

South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Virginia VELAP Certification ID: 460263Virginia VELAP ID: 460263Wisconsin Certification #: 405132750Wisconsin DATCP Certification #: 105-444




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#=SS#

SAMPLE SUMMARY


40129502023-6105-016 CP-SHOREHAM YARD


40129502001 031616-0800-200 Water 03/16/16 08:00 03/17/16 08:40

40129502002 RW07-39-SP-0316-100 Water 03/16/16 16:15 03/17/16 08:40

40129502003 RW07-40-SP-0316-100 Water 03/16/16 16:20 03/17/16 08:40

40129502004 RW06-28-I-0316-100 Water 03/16/16 16:25 03/17/16 08:40

40129502005 RW07-38-I-0316-100 Water 03/16/16 16:27 03/17/16 08:40

40129502006 RW06-27-BR-0316-100 Water 03/16/16 16:30 03/17/16 08:40





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#=SA#



40129502023-6105-016 CP-SHOREHAM YARD


40129502001 031616-0800-200 EPA 8260 71 PASI-GLAP

40129502002 RW07-39-SP-0316-100 EPA 8260 71 PASI-GLAP

40129502003 RW07-40-SP-0316-100 EPA 8260 71 PASI-GLAP

40129502004 RW06-28-I-0316-100 EPA 8260 71 PASI-GLAP

40129502005 RW07-38-I-0316-100 EPA 8260 71 PASI-GLAP

40129502006 RW06-27-BR-0316-100 EPA 8260 71 PASI-GLAP

40129502007 SE EFFLUENT EPA 8260 71 PASI-GLAP

SM 2540D 1 PASI-GDDY

SM 4500-H+B 1 PASI-GALY

EPA 410.4 1 PASI-GTJJ




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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD

Sample: RW07-39-SP-0316-100 Lab ID: 40129502002 Collected: 03/16/16 16:15 Received: 03/17/16 08:40 Matrix: Water







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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 03/21/16 10:27 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 03/21/16 10:27 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 03/21/16 10:27 103-65-11.0 0.50 1Styrene <0.50 ug/L 03/21/16 10:27 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 03/21/16 10:27 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 03/21/16 10:27 79-34-51.0 0.25 1Tetrachloroethene 280 ug/L 03/21/16 10:27 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 03/21/16 10:27 109-99-95.0 2.0 1Toluene <0.50 ug/L 03/21/16 10:27 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 03/21/16 10:27 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 03/21/16 10:27 120-82-15.0 2.2 11,1,1-Trichloroethane 129 ug/L 03/21/16 10:27 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 03/21/16 10:27 79-00-51.0 0.20 1Trichloroethene 14.8 ug/L 03/21/16 10:27 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 03/21/16 10:27 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 03/21/16 10:27 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 03/21/16 10:27 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 03/21/16 10:27 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 03/21/16 10:27 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 03/21/16 10:27 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 03/21/16 10:27 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 03/21/16 10:27 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 98 % 03/21/16 10:27 460-00-470-130 1Dibromofluoromethane (S) 103 % 03/21/16 10:27 1868-53-770-130 1Toluene-d8 (S) 101 % 03/21/16 10:27 2037-26-570-130 1




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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD

Sample: RW06-28-I-0316-100 Lab ID: 40129502004 Collected: 03/16/16 16:25 Received: 03/17/16 08:40 Matrix: Water







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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 03/21/16 11:11 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 03/21/16 11:11 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 03/21/16 11:11 103-65-11.0 0.50 1Styrene <0.50 ug/L 03/21/16 11:11 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 03/21/16 11:11 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 03/21/16 11:11 79-34-51.0 0.25 1Tetrachloroethene 8.8 ug/L 03/21/16 11:11 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 03/21/16 11:11 109-99-95.0 2.0 1Toluene <0.50 ug/L 03/21/16 11:11 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 03/21/16 11:11 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 03/21/16 11:11 120-82-15.0 2.2 11,1,1-Trichloroethane 4.5 ug/L 03/21/16 11:11 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 03/21/16 11:11 79-00-51.0 0.20 1Trichloroethene 0.84J ug/L 03/21/16 11:11 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 03/21/16 11:11 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 03/21/16 11:11 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 03/21/16 11:11 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 03/21/16 11:11 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 03/21/16 11:11 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 03/21/16 11:11 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 03/21/16 11:11 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 03/21/16 11:11 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 95 % 03/21/16 11:11 460-00-470-130 1Dibromofluoromethane (S) 100 % 03/21/16 11:11 1868-53-770-130 1Toluene-d8 (S) 100 % 03/21/16 11:11 2037-26-570-130 1




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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD

Sample: RW06-27-BR-0316-100 Lab ID: 40129502006 Collected: 03/16/16 16:30 Received: 03/17/16 08:40 Matrix: Water







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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD

Sample: RW06-27-BR-0316-100 Lab ID: 40129502006 Collected: 03/16/16 16:30 Received: 03/17/16 08:40 Matrix: Water



Methyl-tert-butyl ether <0.17 ug/L 03/21/16 11:55 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 03/21/16 11:55 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 03/21/16 11:55 103-65-11.0 0.50 1Styrene <0.50 ug/L 03/21/16 11:55 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 03/21/16 11:55 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 03/21/16 11:55 79-34-51.0 0.25 1Tetrachloroethene 25.1 ug/L 03/21/16 11:55 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 03/21/16 11:55 109-99-95.0 2.0 1Toluene <0.50 ug/L 03/21/16 11:55 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 03/21/16 11:55 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 03/21/16 11:55 120-82-15.0 2.2 11,1,1-Trichloroethane 5.8 ug/L 03/21/16 11:55 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 03/21/16 11:55 79-00-51.0 0.20 1Trichloroethene 4.6 ug/L 03/21/16 11:55 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 03/21/16 11:55 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 03/21/16 11:55 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 03/21/16 11:55 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 03/21/16 11:55 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 03/21/16 11:55 108-67-81.0 0.50 1Vinyl chloride 0.29J ug/L 03/21/16 11:55 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 03/21/16 11:55 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 03/21/16 11:55 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 101 % 03/21/16 11:55 460-00-470-130 1Dibromofluoromethane (S) 100 % 03/21/16 11:55 1868-53-770-130 1Toluene-d8 (S) 104 % 03/21/16 11:55 2037-26-570-130 1




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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40129502023-6105-016 CP-SHOREHAM YARD





Analytical Method: SM 2540D2540D Total Suspended Solids

Total Suspended Solids <0.95 mg/L 03/18/16 07:562.0 0.95 1

Analytical Method: SM 4500-H+B4500H+ pH, Electrometric

pH 7.2 Std. Units 03/17/16 13:55 H60.10 0.010 1

Analytical Method: EPA 410.4 Preparation Method: EPA 410.4410.4 COD

Chemical Oxygen Demand 15.0J mg/L 03/28/16 12:3303/28/16 09:0247.2 14.2 1




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#=QC#



40129502023-6105-016 CP-SHOREHAM YARD




MSV/32626EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40129502001, 40129502002, 40129502003, 40129502004, 40129502005, 40129502006, 40129502007



METHOD BLANK: 1308291Associated Lab Samples: 40129502001, 40129502002, 40129502003, 40129502004, 40129502005, 40129502006, 40129502007

Matrix: Water

AnalyzedMDL





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#=QC#



40129502023-6105-016 CP-SHOREHAM YARD




METHOD BLANK: 1308291Associated Lab Samples: 40129502001, 40129502002, 40129502003, 40129502004, 40129502005, 40129502006, 40129502007

Matrix: Water

AnalyzedMDL


Parameter UnitsLCS







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#=QC#



40129502023-6105-016 CP-SHOREHAM YARD


Parameter UnitsLCS



1,2-Dichloroethane ug/L 52.550 105 70-1311,2-Dichloropropane ug/L 53.050 106 70-1301,3-Dichlorobenzene ug/L 53.450 107 70-1301,4-Dichlorobenzene ug/L 54.350 109 70-130Benzene ug/L 55.250 110 70-130Bromodichloromethane ug/L 56.450 113 70-130Bromoform ug/L 46.450 93 68-130Bromomethane ug/L 34.650 69 38-137Carbon tetrachloride ug/L 58.750 117 70-130Chlorobenzene ug/L 54.050 108 70-130Chloroethane ug/L 46.050 92 70-136Chloroform ug/L 53.150 106 70-130Chloromethane ug/L 45.450 91 48-144cis-1,2-Dichloroethene ug/L 53.150 106 70-130cis-1,3-Dichloropropene ug/L 50.550 101 70-130Dibromochloromethane ug/L 52.050 104 70-130Dichlorodifluoromethane ug/L 47.050 94 33-157Ethylbenzene ug/L 59.350 119 70-132Isopropylbenzene (Cumene) ug/L 61.750 123 70-130m&p-Xylene ug/L 119100 119 70-131Methyl-tert-butyl ether ug/L 43.250 86 48-141Methylene Chloride ug/L 52.050 104 70-130o-Xylene ug/L 58.150 116 70-131Styrene ug/L 59.650 119 70-130Tetrachloroethene ug/L 61.650 123 70-130Toluene ug/L 57.650 115 70-130trans-1,2-Dichloroethene ug/L 55.950 112 70-130trans-1,3-Dichloropropene ug/L 46.950 94 70-130Trichloroethene ug/L 59.850 120 70-130Trichlorofluoromethane ug/L 68.750 137 50-150Vinyl chloride ug/L 49.250 98 65-1424-Bromofluorobenzene (S) % 107 70-130Dibromofluoromethane (S) % 99 70-130Toluene-d8 (S) % 100 70-130

Parameter UnitsMS



MSSpikeResult

40129308001

1308520

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L R150 121 70-13086 34 2050<0.50 60.7 42.91,1,2,2-Tetrachloroethane ug/L 50 99 70-13082 18 2050<0.25 49.3 41.01,1,2-Trichloroethane ug/L R150 115 70-13091 23 2050<0.20 57.6 45.51,1,2-Trichlorotrifluoroethane ug/L M1,R150 152 50-151111 32 2050<0.81 76.2 55.41,1-Dichloroethane ug/L R150 99 70-13472 31 2050<0.24 49.4 36.11,1-Dichloroethene ug/L R150 115 70-13985 30 2050<0.41 57.5 42.3




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#=QC#



40129502023-6105-016 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40129308001

1308520

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,2,4-Trichlorobenzene ug/L M1,R150 102 70-13062 48 2050<2.2 51.5 31.51,2-Dibromo-3-chloropropane

ug/L 50 78 50-15074 5 2050<2.2 38.9 36.9

1,2-Dibromoethane (EDB) ug/L R150 109 70-13088 21 2050<0.18 54.7 44.21,2-Dichlorobenzene ug/L R150 109 70-13076 36 2050<0.50 54.4 37.91,2-Dichloroethane ug/L R150 105 70-13275 33 2050<0.17 52.6 37.61,2-Dichloropropane ug/L R150 109 70-13081 29 2050<0.23 54.3 40.71,3-Dichlorobenzene ug/L R150 108 70-13074 38 2050<0.50 54.2 37.01,4-Dichlorobenzene ug/L R150 111 70-13076 38 2050<0.50 55.7 37.8Benzene ug/L R150 111 70-13080 33 2050<0.50 55.7 40.0Bromodichloromethane ug/L R150 115 70-13284 32 2050<0.50 57.6 41.9Bromoform ug/L R150 96 68-13074 26 2050<0.50 47.9 37.0Bromomethane ug/L R150 73 38-14155 29 2050<2.4 36.6 27.3Carbon tetrachloride ug/L R150 127 70-13086 38 2050<0.50 63.6 43.1Chlorobenzene ug/L R150 113 70-13082 32 2050<0.50 56.7 41.2Chloroethane ug/L R150 93 66-15270 28 2050<0.37 46.5 35.0Chloroform ug/L R150 108 70-13080 30 2050<2.5 53.8 39.9Chloromethane ug/L R150 95 44-15167 35 2050<0.50 47.5 33.4cis-1,2-Dichloroethene ug/L R150 106 70-13077 31 2050<0.26 53.0 38.6cis-1,3-Dichloropropene ug/L R150 105 70-13076 33 2050<0.50 52.7 37.9Dibromochloromethane ug/L R150 106 70-13080 28 2050<0.50 53.0 40.0Dichlorodifluoromethane ug/L R150 102 29-16075 30 2050<0.22 51.2 37.7Ethylbenzene ug/L R150 124 70-13287 34 2050<0.50 61.8 43.7Isopropylbenzene (Cumene) ug/L M1,R150 132 70-13091 36 2050<0.14 66.0 45.6m&p-Xylene ug/L R1100 124 70-13189 33 20100<1.0 124 89.1Methyl-tert-butyl ether ug/L R150 89 48-14365 31 2050<0.17 44.7 32.7Methylene Chloride ug/L R150 107 70-13075 36 2050<0.23 53.4 37.3o-Xylene ug/L R150 121 70-13186 33 2050<0.50 60.6 43.2Styrene ug/L R150 124 70-13085 37 2050<0.50 61.8 42.5Tetrachloroethene ug/L R150 130 70-13095 31 2050<0.50 64.9 47.5Toluene ug/L R150 119 70-13086 32 2050<0.50 59.5 43.1trans-1,2-Dichloroethene ug/L R150 116 70-13280 36 2050<0.26 57.8 40.0trans-1,3-Dichloropropene ug/L R150 94 70-13070 29 2050<0.23 46.9 35.1Trichloroethene ug/L R150 125 70-13091 31 2050<0.33 62.4 45.4Trichlorofluoromethane ug/L R150 146 50-153106 32 2050<0.18 73.0 53.1Vinyl chloride ug/L R150 110 60-15576 37 2050<0.18 55.0 38.04-Bromofluorobenzene (S) % 107 70-130107Dibromofluoromethane (S) % 99 70-13095Toluene-d8 (S) % 102 70-130103




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#=QC#



40129502023-6105-016 CP-SHOREHAM YARD




WET/24635SM 2540D

SM 2540D2540D Total Suspended Solids

Associated Lab Samples: 40129502007



METHOD BLANK: 1308311Associated Lab Samples: 40129502007

Matrix: Water

AnalyzedMDL

Total Suspended Solids mg/L <0.48 1.0 03/18/16 07:550.48

Parameter UnitsLCS



Total Suspended Solids mg/L 102100 102 80-120

Parameter UnitsDup

ResultMaxRPD QualifiersRPDResult

401294840021308313SAMPLE DUPLICATE:

Total Suspended Solids mg/L 23.6 2 524.0

Parameter UnitsDup



Total Suspended Solids mg/L 6.6 R16 56.2




Green Bay, WI 54302(920)469-2436

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#=QC#



40129502023-6105-016 CP-SHOREHAM YARD




WET/24631SM 4500-H+B

SM 4500-H+B4500H+B pH


Parameter UnitsDup



pH Std. Units 7.5 H60 57.6




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#=QC#



40129502023-6105-016 CP-SHOREHAM YARD




WETA/32844EPA 410.4

EPA 410.4410.4 COD




METHOD BLANK: 1310962Associated Lab Samples: 40129502007

Matrix: Water

AnalyzedMDL

Chemical Oxygen Demand mg/L <13.4 44.8 03/28/16 12:3213.4

Parameter UnitsLCS



Chemical Oxygen Demand mg/L 499500 100 90-110

Parameter UnitsMS



MSSpikeResult

40129493001

1310965

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chemical Oxygen Demand mg/L 5000 97 90-11096 1 1050001640 6470 6420

Parameter UnitsMS



MSSpikeResult

40129502007

1310967

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chemical Oxygen Demand mg/L 526 98 90-11098 0 1052615.0J 530 530




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#=QL#

QUALIFIERS


40129502023-6105-016 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES


ANALYTE QUALIFIERS

Analysis initiated outside of the 15 minute EPA required holding time.H6Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1RPD value was outside control limits.R1




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#=CR#



40129502023-6105-016 CP-SHOREHAM YARD


40129502001 MSV/32626031616-0800-200 EPA 826040129502002 MSV/32626RW07-39-SP-0316-100 EPA 826040129502003 MSV/32626RW07-40-SP-0316-100 EPA 826040129502004 MSV/32626RW06-28-I-0316-100 EPA 826040129502005 MSV/32626RW07-38-I-0316-100 EPA 826040129502006 MSV/32626RW06-27-BR-0316-100 EPA 826040129502007 MSV/32626SE EFFLUENT EPA 8260

40129502007 WET/24635SE EFFLUENT SM 2540D

40129502007 WET/24631SE EFFLUENT SM 4500-H+B

40129502007 WETA/32844 WETA/32867SE EFFLUENT EPA 410.4 EPA 410.4




Green Bay, WI 54302(920)469-2436

Page 27 of 29

Pag

e 28

of 2

9

Company Name:

Branch/Location:

Project Contact:

Phone:

Project Number:

Project Name:

Project State:

Sampled By (Print):

Sampled By (Sign):

PO#: l-t LO'L Regulatory Program:

UPPER MIDWEST REGION

MN: 612-607-1700 WI: 920-469-2416

·eAnalytical• www.pecelabs.oom 'f\1\\1\-

CHAIN OF CUSTODY *Preservation Codes

A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

H=Sodium Bisulfate Solution !=Sodium Thiosulfate J=Other

FILTERED? (YES/NO)


/\/I tv' c

:::;J:-

Quote#:

Mail To Contact:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Data Package Options (billable)

MS/MSD Matrix Codes A=Air

D EPALevellll D On your sample

(billable) D NOT needed on

your sample

B =Biota C=Charcoal O=OH D EPA Level IV

PACE LAB# CLIENT FIELD ID

ex::> <9'3 l' \6 00~ (tW97-'31- ·~6~ l' -tfO

003 l\.W'$7-'t&-~ P-0"3\6-l6t9

RW~6-1..l-I -t9'll' -f~~

CX6 IRW«>7-1~ -I-e 31,-lse OO(p l~W'~' -1. 7-BP.,-t9:\l6-166

3P~I e>e>Zll SE effl


Date Needed: Transmit Prelim Rush Results by (complete what you want):

Emall#1:

Emall#2:

,Telephone:

Fax:

W=Water OW= Drinking Water GW = Ground Water SW = Surface Water


special pricing and release of Uablllty

Relinquished By:

C019a(27 Jun2006)

0 0 v

"-.. V'l Vl )-

Date/Time: :eceived By:

oice To Phone:

CLIENT COMMENTS

5

Oate!Time:

LAB COMMENTS (Lab Use Only)

\l-C\501-

Profile#

PACE Project No.

4011._qSO'L I oc

CoOler Custody Seal

Presentl~Jii:) Intact I Not Intact

VersiOO 6.(f-06114700

of 29


Green Bay, WI 54302

raceAnalyticat Project#:

·Client Name: Gzoldd Courier: r Fed Ex.r UPS - Client r Pace Jther: \/\/a.J tt,n Tracking#: / OOB R 03- / Custody Seal on Cooler/Box Present: r yes ~no Seals intact: r yes r no

Custody Seal on Samples Present: r yes J(;lno Seals intact: r yes - no

W0#.40129502 1111111111111111111111 40129502

Packing Material: r Bubble Wrap ~ubble Bags r ~CU\ . r Other

Thermometer Used S\< ( RA Type of lce:~lue Dry None 'i:ZJ>amples on ice, cooling process has begun

Cooler Temperature Uncorr· ~ /Corr- \ Biological Tissue is Frozen: r yes

Temp Blank Present: ryes 0 rno Person exlm~ ~ontents:

Temp should be above freezing to 6°C for all sample except Biota. Date: _g II ~ Frozen Biota Samples should be received s 0°C. Comments: Initials: = Chain of Custody Present: 6(;} ONo ON/A 1.

Chain of Custody Filled Out: ~ ONo ON/A 2.

Chain of Custody Relinquished: ~Js ONo ON/A 3.

Sampler Name & Signature on COG: ~s ONo ON/A 4.

Samples Arrived within Hold Time: 6'L ONo ON/A 5.

- VOA Samples frozen upon receipt 0Yes ONo Date/Time:

Short Hold Time Analysis (<72hr): 0Yes CW ON/A 6.

Rush Turn Around Time Requested: OYes ~ ON/A 7.

Sufficient Volume: ~es ONo ON/A 8.

Correct Containers Used: ~ ONo ON/A 9.

-Pace Containers Used: ONo ON/A

-Pace IR Containers Used: OYes ONo ~ Containers Intact: ~es ONo ON/A 10.

Filtered volume received for Dissolved tests OYes ONo ~ 11.

Sample Labels match COG: ~es ONo ON/A 12.

-Includes date/time/ID/Analysis Matrix: \/\/ All containers needing preservation have been checked. ~

r HN03 f12S04 rNaOH r NaOH +ZnAct (Non-Compliance noted in 13.) s ONo ON/A 13. --------------------------- ---------All containers needing preservation are found to be in compliance with EPA recommendation. ~s ONo ON/A (~9~· H~sJ~ ~S?~~nf"9~9.:. ~ao11 ~12) ______________ exceptions· 0 coliform, TOC, TOX, TOH, ~ Initial when rn~b Std #ID of luatet O&G, WIDR , Phenolics, OTHER: s 0No completed reservative Time:

Headspace in VOA Vials ( >6mm): 0Yes ~o ON/A 14.

Trip Blank Present: OYes ~ ON/A 15.

Trip Blank Custody Seals Present 0Yes o ~ Pace Trip Blank Lot# (if purchased):

Client Notification/ Resolution: If checked, see attached form for additional comments~)

Project Manager Review: Date: __ 3_("""47b~----F-GB-C-031-Rev.03 (9April2015) SCUR Form

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