[i/67531/metadc...whc-sd-wm-tp-389. rev. i tank 241 4-1 06 tank characterization plan c. s. homi...

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2. ECN category (mark one) 3. Originator's Name, Organization, MSIN, 30. USP Required? and Telephone No. Clarence Homi, Evaluation and [I Yes [XI NO Planning, R2-12. 373-1097 5. Project TitlelNo.1Work Order No. 6. Bldg./Sys./Fac. No. Tank 241-S-106 241 -S- 106 8. O o c m n t Numbers Changed by this ECN 9. Related ECN NOCS). (includes sheet no. and rev.) WHC-SD-WM-TP-389, Rev. 0 N/A supplemental 11 Direct Revision 1x1 Change ECN I1 Temporary [I standby [I Supersedure I1 CancelNoid I1 4. Date 05/09/96 7. Approval Designator N/A 10. Related PO No. N/A lla. Modification Work [] Yes (fill out Blk. llb) uork Complete (;:m631555 ........................................ 1 ENGINEERING CHANGE NOTICE PW.l.IJ- PmL lld. Restored to Original Condi- N/A tion (Temp. or Standby ECN only) I Cog. Engineer Signature .% Date I Cog. Engineer Signature t. Date [XI No (NA Blks. llb, 12. Description of Change llc, lld) 1 I I Complete revision. ~~ 13a. Justification (mark one) Criteria Change [XI Design Improvement [] Enviromntel [] Facility Deactivation [I AS-FOUnd [] Facilitate Const [] Const. Error/Omission [] Design Errorlhnission [I 13b. Justification Details Changed to comply with new template and DOE-RL recommended modifications. 1L. Distribution (include name, HSIN, erd no. of copies) See attached distribution A-7900-013-2 (ll/94) GEFD95 A-78MOlJ-I

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Page 1: [I/67531/metadc...WHC-SD-WM-TP-389. Rev. I Tank 241 4-1 06 Tank Characterization Plan C. S. Homi Westinghouse Hanford Company. Richland, WA 99352 U. S. Department of Energy Contract

2. ECN category (mark one)

3. Originator's Name, Organization, MSIN, 30. USP Required? and Telephone No.

Clarence Homi, E v a l u a t i o n and [I Yes [XI NO

Plann ing , R2-12. 373-1097 5. Project TitlelNo.1Work Order No. 6. Bldg./Sys./Fac. No.

Tank 241-S-106 241 - S - 106 8. O o c m n t Numbers Changed by this ECN 9. Related ECN NOCS).

(includes sheet no. and rev.)

WHC-SD-WM-TP-389, Rev. 0 N/A

supplemental 11 Direct Revision 1x1 Change ECN I1 Temporary [I standby [I Supersedure I1 CancelNoid I1

4 . Date

05/09/96

7. Approval Designator

N/A 10. Related PO No.

N/A lla. Modification Work

[ ] Yes (fill out Blk. llb)

uork Complete

(;:m631555 ........................................ 1 ENGINEERING CHANGE NOTICE

PW.l.IJ- PmL

lld. Restored to Original Condi-

N/A tion (Temp. or Standby ECN only)

I Cog. Engineer Signature .% Date I Cog. Engineer Signature t. Date [XI No (NA Blks. llb,

12. Description of Change llc, lld) 1 I I

Complete r e v i s i o n .

~~

13a. Justification (mark one) Criteria Change [XI Design Improvement [ ] Enviromntel [ ] Facility Deactivation [I AS-FOUnd [] Facilitate Const [] Const. Error/Omission [] Design Errorlhnission [I 13b. Justification Details Changed t o comply w i t h new template and DOE-RL recommended m o d i f i c a t i o n s .

1L. Distribution (include name, HSIN, erd no. of copies) See a t tached d i s t r i b u t i o n

A-7900-013-2 (ll/94) GEFD95

A - 7 8 M O l J - I

Page 2: [I/67531/metadc...WHC-SD-WM-TP-389. Rev. I Tank 241 4-1 06 Tank Characterization Plan C. S. Homi Westinghouse Hanford Company. Richland, WA 99352 U. S. Department of Energy Contract

Page 2 of 2 ENGINEERING CHANGE NOTICE

Functional Design Criteria

operat,ng Spaclflcatlo"

Criticality Specification Conceptual Design Repon

Equipment Spec.

conrt. spec.

Procurement Spec.

Vendor Information

OM Manual

FSARISAR

Safety Equipman1 List

Radiation Work Permit

1. ECN (use no. frm pg. 1)

ECN-631555

StrassIOorign Report

Interface C ~ n l r o l Drawing

Calibration Procedure lnstallatoon Pracsdurs

Maintenance Procedure

Engineering Procadurs

15. Design 16. Cost Impact COWSTRUCTION ENGINEERING V e r i f i c a t i o n

Required A d d i t i o n a l [I $ A d d i t i o n a l [ ] $

[XI No Savings [I $ Savings [I $ [I Yes

[I [I [I [I [I

operatong I"StrYCtl0"

Operating Procedure

Operational Safety Requireinent

IEFD Drawing

Cell Airanpement Drawing

Essential Material SPeCifiClltcm r 1

17. Schedule I n p a c t (days)

I n p r o v e r e n t [I Delay [I

[I [I [I [I [I [ I [I [I [I [I

Procalf Flow Chart [I r i

Health Phyricr Procedure

Spares Multiple Unit Listing

Test PiocedurealSpecificatlDn

Component Index

ASME Coded Item

Human Factor Consideration

Computer Software

Electric Circuit Schedule

ICRS Procedure

Proce~s Control ManuallPlm

Purchase Requisition _ _ _ _ [I [I

[I [I [I [I

Tickler File Fsc. Proc. S m p . Schedule

l"Jpec1lOn Plan [I [I [I

Environmentsi Impact Statement

Inventory Adptment R B ~ U B S ~

Environmentel R w o n

Environmentel Permit

19. Other A f fec ted D o c w n t s : (NOTE: D o c m n t s l i s t e d below U i I L n o t be r e v i s e d by t h i s ECN.) S igna tu res below i n d i c a t e t h a t t h e s i g n i n g o r g a n i z a t i o n has been n o t i f i e d o f o t h e r a f f e c t e d d o c m n t r l i s t e d below.

D o c m n t Number lRevis ion D o c w n t NumberlRevision D o c w n t Nunber Rev is ion

N / A

20. Approvals

S igna tu re OPERATIONS AN0 ENGINEERING

Cog. Hgr. J.W. Hun

PA

S a f e t y

Envi ron.

Other 1.1. B h l e Y ?&,

Date S igna tu re ARCHITECT-ENGINEER

PE

PA

Sa fe ty

Design

Envi ron.

Other

Date

DEPARTMENT OF ENERGY

S igna tu re or B C o n t r o l Number t h a t t r a c k s t h e Approval S igna tu re

DEPARTMENT OF ENERGY

S igna tu re or B C o n t r o l Number t h a t t r a c k s t h e Approval S igna tu re

ADDITIONAL

A-7900-013-3 (11194) CEF096

Page 3: [I/67531/metadc...WHC-SD-WM-TP-389. Rev. I Tank 241 4-1 06 Tank Characterization Plan C. S. Homi Westinghouse Hanford Company. Richland, WA 99352 U. S. Department of Energy Contract

WHC-SD-WM-TP-389. Rev. I

Tank 241 4 - 1 06 Tank Characterization Plan

C. S . Homi Westinghouse Hanford Company. Rich land, WA 99352 U . S. Department o f Energy Con t rac t DE-AC06-87RL10930

EDT/ECN: ECN-631555 UC: 2070 Org Code: 79200 Charge Code: N4G6A B&R Code: EW 3120074 T o t a l Pages: 8

Key Words: C h a r a c t e r i z a t i o n , General Sa fe ty I ssues , S p e c i f i c S a f e t y I ssues , I n f o r m a t i o n Requirements, Schedule

A b s t r a c t : T h i s document i s a p l a n t h a t i d e n t i f i e s t h e i n f o r m a t i o n needed t o address r e l e v a n t i ssues concern ing s h o r t - t e r m and long - te rm s to rage and long - te rm management o f s i n g l e - s h e l l tank 241-S-106.

TRADEMARK oISCLAIMER. Reference h e r e i n t o any s p c i f i c conmercial product process o r s e r v i c e by t r a d e name, trademerk, manufacturer, o r o the ru i se , does no t necessa r i l y c o k t i t u t e LP imp ly i t s endorsrment, reconmendation, o r f avo r ing by t h e U n i t e d States Goverrment o r any agency thereof or i t s c o n t r a c t o r s o r subcontractors.

P r i n t e d i n t h e U n i t e d S ta tes of America. To o b t a i n copies of t h i s d o c m n t con tac t : UHCIBCS D o c m n t Con t ro l Services, P.O. Box 1970, M a i l s t o p H6-08, R ich land UA 99352: Phone (509) 372-2620: Fax (509) 376-4989.

h

Approved for Public Release A-6400-073 (10195) GEF321

Page 4: [I/67531/metadc...WHC-SD-WM-TP-389. Rev. I Tank 241 4-1 06 Tank Characterization Plan C. S. Homi Westinghouse Hanford Company. Richland, WA 99352 U. S. Department of Energy Contract

(11 Oocunent N h r RECORD OF REVISION

WHC-SD-WM-TP-389 Page 1

(3) Revision I L ) Description of Chawe - Replace, Add. and Detete Pages

0 ( 7 ) I n i t i a l l y re leased 08/28/95 on EDT- 613372.

A-7320.005 (08/91) UEF168

Authorized for Release 1 5 ) Cog. Engr. ( 6 ) Cog. Wgr. Date

-

C . S . Homi S . J . E b e r l e i n

RS 1 I n c o r p o r a t e per ECN-631555.

Page 5: [I/67531/metadc...WHC-SD-WM-TP-389. Rev. I Tank 241 4-1 06 Tank Characterization Plan C. S. Homi Westinghouse Hanford Company. Richland, WA 99352 U. S. Department of Energy Contract

WHC-SD-Wh4-TF'-389 Revision 1

UC-2070

Tank 241 4 - 1 06 Tank Characterization Plan L. L. Buckley Westinghouse Hanford Company

Date Published May 1996

Pre wed for the U.S. D artmen! of Energy Of&e of Environmental?estomtion and Waste Management

Westinghouse P 0 Box 1970

Hanford COmpatly kchland,Washmgton

Management and Operations Contractor for lhe U.S. Department of Energy under Contract DE-AC06-87RLl0930

Approved for Public Release

Page 6: [I/67531/metadc...WHC-SD-WM-TP-389. Rev. I Tank 241 4-1 06 Tank Characterization Plan C. S. Homi Westinghouse Hanford Company. Richland, WA 99352 U. S. Department of Energy Contract

WHC-SO-WM-TP-389 REV I

TABLE OF CONTENTS

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.0 INTRODUCTION 1

2.0 PROGRAM ELEMENTS REQUIRING INFORMATION FOR 241-5-106 . . . . . . . . . . . 1

2.1 GENERAL SAFETY ISSUES . . . . . . . . . . . . . . . . . . . . . . . . . . 1

2.2 SPECIFIC SAFETY ISSUES . . . . . . . . . . . . . . . . . . . . . . . . . 2

2.2.1 Fe r rocyan ide . . . . . . . . . . . . . . . . . . . . . . . . . . 2 2.2.2 Organ ic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 2.2.3 H igh Heat . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.2.4 Flammable Gas . . . . . . . . . . . . . . . . . . . . . . . . . . 2 2.2.5 Vapor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 2.2.6 C r i t i c a l i t y . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

2.3 CONTINUING OPERATIONS . . . . . . . . . . . . . . . . . . . . . . . . 2

2 .3 .1 Compatibility/Stabilization . . . . . . . . . . . . . . . . . . . 2 2.3.2 Evaporator . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

2.4 DOUBLE-SHELL TANK WASTE ANALYSIS PLAN . . . . . . . . . . . . . . . . . . 3

2.5 DISPOSAL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

2

3

2.5.1 R e t r i e v a l . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 2.5.2 Pretreatment/Vitrification . . . . . . . . . . . . . . . . . . . 3

2.6 HISTORICAL MODEL EVALUATION . . . . . . . . . . . . . . . . . . . . . . . 3

3.0 HOW INFORMATION WILL BE OBTAINED . . . . . . . . . . . . . . . . . . . . . 3

4.0 PRIORITY OF INFORMATION REQUIREMENTS . . . . . . . . . . . . . . . . . . . 3

5.0 WHEN INFORMATION WILL BE AVAILABLE . . . . . . . . . . . . . . . . . . . . 4

6.0 REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

LIST OF TABLES

Tab le 4-1: I n t e g r a t e d DQO Requirements and P r i o r i t i e s . . . . . . . . . . . . . . 4

ii

Page 7: [I/67531/metadc...WHC-SD-WM-TP-389. Rev. I Tank 241 4-1 06 Tank Characterization Plan C. S. Homi Westinghouse Hanford Company. Richland, WA 99352 U. S. Department of Energy Contract

WHC-SD-WM-TP-389 REV I

1 .O INTRODUCTION

Th is Tank C h a r a c t e r i z a t i o n P lan (TCP) i d e n t i f i e s t h e i n f o r m a t i o n needed t o address r e l e v a n t i ssues concern ing sho r t - te rm and 1 ong-term sa fe s to rage and long- te rm management o f s i n g l e - s h e l l t a n k 241-S-106 (S-106). I t shou ld be understood t h a t t h e v a r i o u s needs and issues sur round ing t a n k S-106 are e v o l v i n g as new i n f o r m a t i o n about t h e t a n k i s uncovered. As a r e s u l t o f t h i s p rogress ion , t h i s TCP addresses o n l y t h e i ssues t h a t , t o t h i s da te , have been i d e n t i f i e d . I t i s expected t h a t d e v i a t i o n s f rom t h i s p l a n may occur as a d d i t i o n a l i ssues o r needs a r i s e which impact t h e management o f t a n k S-106. Th is TCP w i l l be r e v i s e d as necessary t o r e f l e c t those changes o r d e v i a t i o n s .

Tank S-106 was cons t ruc ted between 1943 and 1944 and was p u t i n t o s e r v i c e i n 1953. I n i t i a l l y t a n k S-106 rece ived REDOX f a c i l i t y waste f rom t h e second q u a r t e r o f 1953 u n t i l t h e t h i r d q u a r t e r o f 1973. From t h e t h i r d q u a r t e r o f 1955 u n t i l t h e t h i r d q u a r t e r o f 1973, t h e t a n k rece ived waste water . From t h e f o u r t h q u a r t e r o f 1973 u n t i l t h e second q u a r t e r o f 1976, t h e t a n k rece ived bottoms and r e c y c l e wastes f rom t h e 242-S EvaporatorlCrystallizer. I n the second q u a r t e r o f 1976, t h e t a n k was f i l l e d w i t h sa l t cake . The t a n k i s sound and was removed from s e r v i c e i n 1976. Tank S-106 i s p a s s i v e l y v e n t i l a t e d and a w a i t i n g i n t e r i m s t a b i l i z a t i o n and i n t r u s i o n p r e v e n t i o n ( B r e v i c k 1994) .

T h i s p l a n r e f l e c t s t h e bes t i n f o r m a t i o n a v a i l a b l e as o f May 1996.

Presen t l y , t h e tank waste i s c l a s s i f i e d as non-complexed (B rev i ck 1995) .

Tank S-106 c u r r e n t l y con ta ins a t o t a l waste volume o f 2,055 kL (543 kga l ) , which i s e q u i v a l e n t t o 520 cm (204 i n ) o f waste as measured f rom t h e base l i ne o f t h e t a n k (Hanlon 1996) .

Th is t a n k i s n o t on any Watch L i s t .

Near- term sampl ing and a n a l y s i s a c t i v i t i e s a re focused on e i t h e r v e r i f y i n g o r changing t h e Watch L i s t t ank s ta tus , and i d e n t i f y i n g any new s a f e t y issues. Should any s a f e t y i ssues be i d e n t i f i e d , a d d i t i o n a l a n a l y s i s w i l l occur c o n s i s t e n t w i t h t h e i d e n t i f i e d i ssue .

I n a d d i t i o n t o t h e r e s o l u t i o n o f t h e s a f e t y issues, i t i s in tended t h a t a l l t ank waste w i l l be s u b j e c t t o p re t rea tmen t and r e t r i e v a l t o p repare f o r f i n a l s to rage o r d i sposa l . P resen t l y , these long-range p lans have y e t t o be f u l l y i d e n t i f i e d and are, t h e r e f o r e , n o t i nc luded i n t h i s document.

2 . 0 PROGRAM ELEMENTS REQUIRING INFORMATION FOR TANK 241-5-106

T h i s s e c t i o n i d e n t i f i e s t h e va r ious program elements, and i d e n t i f i e s which o f these programs r e q u i r e c h a r a c t e r i z a t i o n d a t a f rom tank S-106.

2 .1 GENERAL SAFETY ISSUES

The Tank S a f e t y Screen ing Data Q u a l i t y Ob jec t i ve (Dukelow e t a l . 1995) desc r ibes t h e sampl ing and a n a l y t i c a l requ i rements t h a t a re used t o screen waste tanks f o r u n i d e n t i f i e d s a f e t y i ssues . A n a l y t i c a l requ i rements f o r t h e s a f e t y sc reen ing o f a t a n k a re energe t i cs , t o t a l a lpha a c t i v i t y , mo is tu re conten t , d e n s i t y , and flammable gas concen t ra t i on .

1

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WHC-SD-WM-TP-389 REV 1

2 . 2 SPECIFIC SAFETY ISSUES

2 . 2 . 1 Fer rocyan ide

c u r r e n t l y i d e n t i f i e d f o r t h i s program element .

2 . 2 . 2 Organic

c u r r e n t l y i d e n t i f i e d f o r t h i s program element .

2 . 2 . 3 H i g h Heat

c u r r e n t l y i d e n t i f i e d f o r t h i s program element.

2 . 2 . 4 Flammable Gas

a re c u r r e n t l y i d e n t i f i e d f o r t h i s program element.

2 . 2 . 5 Vapor

A l l 177 underground tanks must be vapor-sampled f o r o rgan ic s o l v e n t sc reen ing as p e r Recommendation 93-5 Imp lemen ta t i on P l a n (DOE-RL 1996). Some tanks may r e q u i r e a d d i t i o n a l vapor sampl ing due t o o t h e r program needs. These tanks may be c l a s s i f i e d i n t o f o u r c a t e g o r i e s : (1 ) t hose tanks which a re t o be r o t a r y mode co re sampled (as a consequence o f t h e r o t a r y sampling system exhaustor p e r m i t requ i remen ts ) ; (2 ) t anks on t h e Organic o r Ferrocyanide Watch L i s t s ; (3 ) t anks i n C farm; and (4 ) t a n k 241-EX-104, due t o vapor exposure. I n f o r m a t i o n needs must s a t i s f y Data Q u a l i t y O b j e c t i v e s f o r Tank Hazardous Vapor S a f e t y Sc reen ing (Osborne and Buckley 1995), and f o r r o t a r y mode on ly , R o t a r y Core Vapor Sampl ing Data Q u a l i t y O b j e c t i v e ( P r i c e 1994), and Data Q u a l i t y O b j e c t i v e f o r Regu la to ry Requirements f o r Hazardous and R a d i o a c t i v e A i r Emiss ions Sampl ing and A n a l y s i s (Mulkey and M a r k i l l i e 1995) as amended by S t a t u s o f t h e Cur ren t Unders tand ing o f t h e T o x i c A i r P o l l u t a n t s (TAPS) and Han fo rd Tank Farm Vapor Space C h a r a c t e r i z a t i o n ; Recommended P a t h Fotward and J u s t i f i c a t i o n f o r Cont inued RMCS Exhaus te r Opera t i ons (Laws 1996).

2 . 2 . 6 C r i t i c a l i t y

No i n f o r m a t i o n separate f rom t h a t f o r t h e genera l s a f e t y i s s u e o f t a n k S-106 a r e c u r r e n t l y i d e n t i f i e d f o r t h i s program element. However, i f t h e genera l s a f e t y sc reen ing o f t a n k S-106 i d e n t i f i e s a p o t e n t i a l c r i t i c a l i t y concern, analyses f o r f i s s i l e m a t e r i a l s and neu t ron so rbe rs and poisons w i l l be per formed as i d e n t i f i e d i n t h e s a f e t y sc reen ing d a t a q u a l i t y o b j e c t i v e .

T h i s t a n k i s n o t on t h e Ferrocyanide Watch L i s t ; t h e r e f o r e , no i n f o r m a t i o n needs a r e

Tank 5-106 i s n o t on t h e Organics Watch L i s t ; t h e r e f o r e , no i n f o r m a t i o n needs a r e

T h i s t a n k i s n o t on t h e High Heat Watch L i s t ; t h e r e f o r e , no i n f o r m a t i o n needs a re

T h i s t a n k i s n o t on t h e Flammable Gas Watch L i s t ; t h e r e f o r e , no i n f o r m a t i o n needs

2 . 3 CONTINUING OPERATIONS

2 . 3 . 1 Compati b i 1 i t y / S t a b i 1 i z a t i o n

T h i s s e c t i o n does n o t app ly t o t a n k S-106.

2

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WHC-SD-WM-TP-389 REV 1

2 .3 .2 Evaporator

T h i s s e c t i o n does n o t app ly t o t a n k S-106.

2 . 4 DOUBLE-SHELL TANK WASTE ANALYSIS PLAN

T h i s s e c t i o n does n o t app ly because tank S-106 i s a s i n g l e s h e l l tank .

2 . 5 DISPOSAL

2 .5 .1 R e t r i e v a l

t aken f rom t a n k S-106.

2.5.2 Pretreatment/Vitrification

Tank S-106 has n o t been i d e n t i f i e d as a bounding tank f o r p re t rea tmen t / d i sposa l process development s t r a t e g y (Kupfer e t a l . 1995). A l l tanks were p r i o r i t i z e d us ing t h e p re t rea tmen t s t r a t e g y i n t h e Tank Waste C h a r a c t e r i z a t i o n Bas is (Brown e t a l . 1995) document and a p o r t i o n o f a rch i ve sample m a t e r i a l c o u l d be used f o r p re t rea tmen t t e s t i n g i f a v a i l a b l e . The s t r a t e g y does n o t r e q u i r e any s p e c i f i c ana lyses t o be done on t h e samples .

Cur ren t r e t r i e v a l needs (Bloom and Nguyen 1995) do n o t c a l l f o r t e s t samples t o be

2 .6 HISTORICAL MODEL EVALUATION

Bounding tanks and da ta requ i rements f o r h i s t o r i c a l model eva lua t i ons a re found i n Tank S-106 H i s t o r i c a l Model E v a l u a t i o n Data Requirements (Simpson and McCain 1995).

i s n o t i d e n t i f i e d as a p r imary bounding tank f o r h i s t o r i c a l model eva lua t i ons .

3 . 0 HOW INFORMATION WILL BE OBTAINED

The number o f samples r e q u i r e d t o c h a r a c t e r i z e a tank i s a f u n c t i o n o f waste he te rogene i t y and t h e d e s i r e d conf idence t o make a c o r r e c t d e c i s i o n . As d i r e c t e d by t h e s a f e t y sc reen ing OQO, i f inadequate i n fo rma t ion e x i s t s t o de termine an a p p r o p r i a t e number o f samples, two v e r t i c a l p r o f i l e s w i l l be ob ta ined. These v e r t i c a l p r o f i l e s may be ob ta ined u s i n g core, auger ( f o r sha l low tanks) , o r g rab samples. I f a n a l y s i s o f these p r o f i l e s r e v e a l s t h a t a d d i t i o n a l p r o f i l e s a re necessary t o meet da ta needs, more sample p r o f i l e s w i l l be requested. P r i o r t o r o t a r y sampl ing i t i s necessary t o vapor sample t h e t a n k p e r t h e requ i rements o f Ro ta ry Core Vapor Sampl ing Data Q u a l i t y O b j e c t i v e ( P r i c e 1994).

4.0 PRIORITY OF INFORMATION REQUIREMENTS

Vapor sampl ing i s scheduled t o beg in i n May 1996. Rotary mode co re sampl ing i s scheduled t o beg in i n J u l y 1997 (S tan ton 1996). Refer t o Tab le 4-1 f o r t h e c u r r e n t DQO requ i rements and planned sampl ing and a n a l y t i c a l requ i rements .

3

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Sampl ing

Sampl i n g

Mode Core Sampling

* Consul

WHC-SD-WM-TP-389 REV 1

Tab le 4-1: I n t e g r a t e d DQO Requirements and P r i o r i t i e s

A p p l i c a b l e Issues

-Organic So lven t l a y e r 93-5 Vapor Issue -Rotary Mode Sampling 040 -Hazardous Vapor DQO

-Sa fe ty Screen ing DQO

each a p p l i c a b l e DO0

Sampling Requirements*

S tee l c a n i s t e r s , T r i p l e Sorbent Traps, Sorbent Trap Systems

Core samples f rom 2 r i s e r s separated r a d i a l l y t o t h e maximum e x t e n t poss ib le .

Combust ib le gas measurement. I f o r c e a t t h e t ime f o r '

A n a l y t i c a l Requirements*

F1 ammable Gas Organic Vapors Permanent Gases

F lammab i l i t y , Energet ics , Mo is tu re , T o t a l a lpha a c t i v i t y , Dens i t y

.mpl ing and a n a l y t i c a l requ i rements .

5.0 WHEN INFORMATION WILL BE AVAILABLE

Accord ing t o S tan ton (1996), da ta a re expected t o be a v a i l a b l e f rom t h e r o t a r y mode co re sampl ing event f o r t ank S-106 i n November 1997. Vapor sampl ing da ta a re expected i n J u l y 1996. These t imes may be a l t e r e d i f t h e sampl ing schedule changes.

6.0 REFERENCES

Bloom, G. R . , Q. H. Nguyen, 1995, C h a r a c t e r i z a t i o n Data Needs f o r Development, Design, and Opera t i on o f R e t r i e v a l Equipment Developed Through the Data Q u a l i t y O b j e c t i v e Process, WHC-SO-WM-DQO-008, Rev. 0, Westinghouse Hanford Company, R ich land, Washington.

B rev i ck , C . H., 1995, H i s t o r i c a l Tank Content Es t ima te f o r t h e Southwest Quadrant o f t h e Han fo rd 200 East Areas, WHC-SD-WM-ER-352, Rev. OA, I C F Ka ise r Hanford Company, R ich land, Washington.

B rev i ck , C . H., 1994, Suppor t i ng Document f o r t he H i s t o r i c a l Tank Content Es t ima te f o r 5 Tank Farm, WHC-SD-WM-ER-323, Rev. 0, ICF Ka ise r Hanford Company, R ich land, Washington.

Brown, T. M., S. J . Eber le in , and T. J . Kunthara, 1995, Tank Waste C h a r a c t e r i z a t i o n Bas is , 1995, WHC-SD-WM-TA-164, Rev 1, Westinghouse Hanford Company, R ich land, Washington.

DOE-RL, 1996, Recommendation 93-5 Imp lementa t ion Plan, DOE/RL-94-0001, Rev. 1, U.S. Department o f Energy, R ich land, Washington.

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WHC-SD-WM-TP-389 REV 1

Dukelow, G . T., J. W. Hunt, H . Babad, and J. E. Meacham, 1995, Tank S a f e t y Screen ing Data Q u a l i t y Ob jec t i ve , WHC-SD-WM-SP-004, Rev 2 , Westinghouse Hanford Company, R i c h l and, Washington .

Hanlon, B.M., 1996, Waste Tank Summary f o r Month End ing January 31, 1996, WHC-EP-0182-94, Westinghouse Hanford Company, R ich l and, Washington.

Kupfer, M. J., W . W . Schu l t z , J. T. Slankas, 1995, S t r a t e g y f o r Sampl ing Han fo rd S i t e Tank Wastes f o r Development o f D isposa l Technology, WHC-SD-WM-TA-154, Rev. 1, Westi nghouse Hanford Company, R i c h l and, Washington.

Laws, G . L., 1996, S t a t u s o f t h e Cur ren t Unders tand ing o f t h e Tox ic A i r P o l l u t a n t s (TAPS) and Han fo rd Tank Farm Vapor Space Charac te r i za t i on ; Recommended P a t h Forward and J u s t i f i c a t i o n f o r Cont inued RMCS Exhauster Operat ions, ( te lephone conference memorandum, 01830-96-022, t o D i s t r i b u t i o n , March 8) Westinghouse Hanford Company, R ich land, Washington.

Mulkey, C . H. K. 0. M a r k i l l i e , 1995, Data Q u a l i t y O b j e c t i v e f o r Regu la to ry Requirements f o r Hazardous And Rad ioac t i ve A i r Emissions Sampl ing and Ana lys i s , WHC- SD-WM-DQO-021, Rev. 0, Westinghouse Hanford Company, R ich land, Washington

Osborne, J. W . , L. L . Buckley, 1995, Data Q u a i i t y Ob jec t i ves f o r Tank Hazardous Vapor S a f e t y Screening, WHC-SD-WM-DQO-002, Rev. 2, Westinghouse Hanford, R ich land, Washington.

Osborne, J. W . , J. L. Huckaby, E. R. Hew i t t , C . M. Anderson, D. D. Mahlum, B. A . Pu ls iphe r , and J. Y . Young, 1994, Data Q u a l i t y Ob jec t i ves f o r Gener ic In-Tank H e a l t h and S a f e t y Vapor I s s u e Reso lu t ion , WHC-SD-WM-DQO-002, Rev. 0, Westinghouse Hanford, R i c h l and, Washington.

P r i ce , D. N . 1994, Ro ta ry Core Vapor Sampl ing Data Q u a l i t y Ob jec t i ve , WHC-SD-WM-SP-003, Rev. 0, Westinghouse Hanford Company, R ich land, Washington.

Simpson, B. C . , D. J. McCain, 1995, H i s t o r i c a l Model E v a l u a t i o n Data Requirements, WHC-SD-WM-DQO-018, Rev. 0, Westinghouse Hanford Company, R ich land, Washington.

Stanton, G . A . , 1996, Base l i ne Sampl ing Schedule, Change 96-02, ( i n t e r n a l memo 75610-96-06, t o D i s t r i b u t i o n , A p r i l 17) , Westinghouse Hanford Company, R ich land, Washington.

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DISTRIBUTION SHEET To From

D i s t r i b u t i o n Project Tit leMlork Order WHC-SD-WM-TP-389, Rev. 1. "Tank Plan"

U. S . DeDartment o f Enersv - R ich land F i e l d O f f i c e

W . L i o u N . W. W i l l i s

Westinqhouse Hanford ComDanv

L . L . Buckley G. D. Forehand C. S . Homi Cen t ra l F i l e s T.C.R.C.

DFFSITE

U . S. DeDartment o f Enerqv - Headauarters O f f i c e o f Environmental R e s t o r a t i o n and Waste Management EM-563 12800 M i dd l ebrook Road Germantown, MD 20874

J . A. P o p p i t i

S l - 5 4 X s7-54 X

R2-12 X S7-21 X R2-12 X A3-88 X R2-12 X

X

A-6000.135 (01/93) UEF067