huntsman textile effects product innovation - igcw 2019 conference/day 1... · presence in india...

Huntsman Textile EffectsProduct Innovation

Overview

CorporateGBOTCPS-2016 2

Content

Huntsman Businesses (Global)

Presence in India

Huntsman Textile Effects

− Close to our customers

− Revolution in Reactive Dyeing

− Transition from C8 to C6 & ultimately to Fluorine Free

chemistry

− Reduction in free Formaldehyde in FR

− Product Stewardship Programme


Polyurethanes

MDI

Polyols

PO/MTBE

TPU

Systems

Performance

Products

Performance

Specialties

Performance

Intermediates

Pigments

Titanium

Dioxide

Textile

Effects

Apparel &

Home

Textiles

Specialty

Textiles

Base Resins

Formulated

Systems

Specialty

Components

Differentiated Inorganic

Advanced

Materials

Huntsman Businesses (Global)

U.S. & Canada

31%(2)

Europe

28%(2)

Asia Pacific

23%(2)

Rest of World

18%(2)

USD38%

EUR31%

CHF5%

Other26%

Fixed Costsby Currency

Europe40%

Asia Pacific33%

U.S. & Canada

19%

Rest of World

8%

~15,000 Employees

Operating >80

Manufacturing

& R&D Facilities

in 30 Countries


Presence in India

Our journey began in 2000s

4 business verticals

30 strategic locations across India

3 manufacturing facilities

Revenues of around INR 3000 Cr

Our journey in India



Sustainable Innovation


Close to our customers

• Selling into more than 110 countries

• Serving over 10,000 customers worldwide

• Headquarters located in Singapore

• 14 primary manufacturing facilities in twelve countries including China,

Columbia, Germany, Guatemala, India, Indonesia, Mexico, Pakistan, Thailand,

Turkey, Switzerland, USA

• Employs approximately 4,200 employees and contractors

Products and processes for all fibers and a host of applications, including:

Apparel Home Automotive Interiors Nonwovens Digital

Textiles Carpets printing


Seeking sustainable solutions

New approaches required to address the issues relating to:

Growing world population

Scarcity of resources

Environmental pollution

Rising price

Increasing competition


• Save Resources

• Preserve the Environment

• Save Money

• Save Time

A Revolution in Reactive Dyeing

Sustainability requires INNOVATION!

Industry Needs

Shorter/more robust dyeing procedures

Reduced water consumption

Reduced energy consumption

Reduced effluent discharge

Improved ecological image

CorporateGBOTCPS-2016 10 10

Reactive Dyes – Next Generation?

The average water consumption for dyeing

1 kg of cotton

• Using conventional dyes

60 to 80 liters

• Using today’s Best Available Technology (BAT)

Textile Effects: NOVACRON® FN dyes

30 to 40 liters

• Can there be a step change with a new technology to only use half the water?


HUNTSMAN Innovation

A Revolution in Reactive Dyeing!

AVITERA® SE


AVITERA® SE: Save the Environment

HOT DYES WARM DYES

50 %

WATER

SAVING

AVITERA® SEBAT todayCOMMODITY

AVITERA® SE can save up to

50% of water and even more!

60-80 30-40 15-20 liter

Values per kg of Cotton



WARM DYES

BAT todayCOMMODITY


50% of energy and even more!

AVITERA® SE

HOT DYES

6.5 3.9 1.7 kg steam

2.2 1.5 0.7 kg CO2

Values per kg of Cotton



WARM DYES

BAT todayCOMMODITY


50% of time and even more!

AVITERA® SE

HOT DYES

7 5.5 4 hours

Values per Batch of Cotton


Ecological Value:

Economical Value:

AVITERA® SE

Reduced water use by up 50% and more

Reduced energy use by up to 50% and more

Reduced utility cost by 50%

Reduced processing time (>50%)

Increase productivity without CAPEX

Marketability to brands / retailers


AVITERA® SE

AVITERA® SE the right way into economical and environmental

sustainability

Production output increase without CAPEX

Significant increase in revenue and profit generation

from the dyehouse same assets

Water and utility savings of 50% and even more

State of the art fastness and color retention

Outstanding reproducibility and leveling properties


Managing the transition from

C8 to C6 and fluorine-free

alternatives

Control the inputs


Fluorochemical Industry Conversion from C8 to C6 Chemistry

• Many water and oil repellent products used

for long term protection of textiles are

based on C8 telomers.

• In manufacturing a trace amount of PFOA

can be generated as an unintended

byproduct in C8-based repellent materials.

• PFOA is an abbreviation for

Perfluorooctanoic Acid.

• C8-telomer is a chemical compound that

contains 8 carbon atoms and 17 fluorine

atoms.

PFT (perfluorinated surfactants)

perfluorinated perfluorinated

Alkylsulfonate Carboxylate

e. g. PFOS e. g. PFOA

Textile Effects


What is the difference?

OLEOPHOBOL® product based on C8:

CF CF CF3

perfluorinated side chains with varying

chain length (C4, C6, C8, C10 …) and CF3 3

CF2 C F2

CF2 CF2

CF2 CF2

CF2 CF

3

C F2 CF2

CF2 CF2

CF2 CF2

CF CF2

emphasis on C8

% F

60

CF2 C F2

CF2 CF

CF2 CF2

2

2

2

C F2 CF2

CF CF2 2

CF2 CF 2

50

40

30

CH2 CH2

CH2 C H2

O O

C O C O

CH CH

CH2 CH2 CH2

CH2 CH2

CH2 CH2

O O

C O C

CH CH

CH2

20

10

O 0

C4 F9

CH2

C6 F13 C8 F17 C10 F21 C12 F25 C14 F29

Textile Effects

CAPSTONE™


What is the difference?

OLEOPHOBOL® CP product based on C6:

CF2 CF2 CF2 CF2

CF2 CF2 CF2 CF2

CF2 CF CF CF2

perfluorinated side chains

based on C6

CAPSTONE™

% F

CF2 C F2

CF2 CF

CF2 CF2

2

2

2

C F2 CF2 100

CF CF2 80 2

CF2 CF

CH2 CH2

CH2 C H2

O O

C O C O

CH CH

CH2 CH2 CH2

2

CH2 CH2

CH2 CH2

O O

C O C

CH CH

CH2

60

40

20

O 0 C4 F9 C6 F13 C8 F17

CH2

C10 F21 C12 F25 C14 F29

Textile Effects

CAPSTONE™


PFOA Stewardship Program 2010/15

Launch of the EPA 2010/15 PFOA Stewardship Program in early 2006, to

reduce human and environmental exposure:

1st step: Achieve no later than 2010 a 95% reduction, measured from a year 2000 baseline, of PFOA, PFOA precursers and higher homologues in emissions and products.

2nd step: Elimination of PFOA, PFOA precursers and related higher homologue chemicals from emissions and products no later than 2015.

DuPont amongst seven other global major fluoropolymer and fluorotelomer producer voluntarily agreed to participate in this program.

Textile Effects

Ecological background


CAPSTONE™

Next generation of fluorchemicals based on short chain chemistry

Maximum performance -

Minimal environmental footprint


Textile Alliance

DuPont™ Capstone™ repellent and stain release products are sold by Huntsman

under the designation OLEOPHOBOL® CP.

The OLEOPHOBOL® CP portfolio

consists of various stain repellent and

soil release products based on new

short chain molecules, which can not break

down to PFOA in the environment.

Textile Effects

CAPSTONE™


Product overview

OLEOPHOBOL® CP-S Stain repellent for WO, SYN & blends in apparel end uses.

OLEOPHOBOL® CP-C Stain repellent for CO, SYN & blends in apparel and technical applications.

OLEOPHOBOL® CP-X Stain repellent product for CO, SYN & blends in technical end uses. Contains extender.

OLEOPHOBOL® CP-SLA Stain repellent for CO, SYN & blends mainly in apparel end uses. Contains extender.

OLEOPHOBOL® CP-R Stain release product for all fibers.

PHOBOTEX® CP-NH

Stain repellent for the unbranded (non-label) business on CO, SYN & blends. Contains extender.

Textile Effects

CAPSTONE™


PHOBOL® R

Innovative fluorine-free water repellents


PHOBOL® R

Conventional fluorine-free water repellents

Paraffine Polysiloxane Fat-mod. resin

n n

good water repellency good water repellency good water repellency

water proof limited durability used as extender in

no durability breathable combination with FC

tendency to chalk no oil and stain good durability

marking repellency tendency to chalk

impact on breathability marking

no oil and stain no oil and stain

repellency repellency

Textile Effects


One step ahead - New fluorine-free water repellents

Excellent water repellency

Suitable on all fibers

PHOBOL® RHP

Repellent High Performance

PHOBOL® RSH

Repellent Soft Hand

PHOBOL® RHW

Repellent High White

High durability

Simple application

No influence on fabric breathability

Products for soft hand and high degree of

white

Improvement of sewability and tear strength

Low influence on thermomigration

Meet Oeko-Tex® Standard 100

PFOA free* (* below limit of detection)

Compatible with fluorochemical finishes

High IQ™ branding option

Textile Effects

PHOBOL® R


Zelan™ R3Renewably sourced, non-

flurorinated, durable water

repellent


Sustainability—it’s the future of the apparel industry

why we developed Zelan™ R3 ?

Existing technologies - paraffin, silicones, melamines, dendrimers.

Breakthrough solution– Zelan™ R3

• Contains 63% renewably sourced content per ASTM method

6866

• Refers to material from plant origin that can be replenished

naturally over time

• Repels water and common water-based liquids

• Delivers high-performance repellency to at least 30 washes

• Performs well on cotton, synthetics, and blends

• Is applied in pad bath applications at loading levels

comparable to other repellent finishes


Zelan™ R3 finish works on a variety of fabrics

Polyester

Polyester/Spandex

Polyester/Cotton

Nylon

Nylon/Spandex

Cotton

Cotton/Spandex

Denim

Microfiber


Advantages and Differentiation of

PYROVATEX® CP–LF


Reduction in Formaldehyde release

Future Challenges

• Formaldehyde classified as carcinogen class 2

• Formaldehyde is expected to be added to the SVHC

list

• SVHC also triggers the ban of the substance by brand

and retailers

Advantages in Pyrovatex CP-LF

• Very effective, inventive FR product also based on P/N

chemistry

• ~ 80% reduction in formaldehyde smell during the

application

hardly no emission of formaldehyde into the working

• Possibility of combination with other finishing agents

• Target is to come out with total formaldehyde free flame

retardand


Huntsman Textile EffectsYour partner in solving the industry’s toughest challenges

Product

Stewardship

Programme


Huntsman Product Stewardship Programme

Product Stewardship is an

integrated business process for

identifying, managing and

minimizing the environmental,

health, safety and social impacts at

every stage of a products life cycle.


Product

Stewardship

Safer Products

Better Business

Everyone’s Responsibility

Sale and Use of Chemicals

Consumer Use of Products

Recycling, Re-Use & Disposal

Storage, Packaging & Distribution

Manufacture

Raw Materials Purchase

Product Design & Development


Work together Be Innovative

THANK YOU

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