HCl, j(=1)

agust,www,...Sept10/PPT-211210ak.pptagust,heima,....Sept10/XLS-211210ak.xlsagust,heima,....Sept10/PXP-211210ak.pxpagust,heima,...Sept10/Look for J7-211210.pxpagust,heima,....Sept10/PXP-311210ak.pxpagust,heima,....juni09/grof fyrir J astond-150609hrh.xls

130

120

110

100

90

80

6.05.55.04.54.03.53.0

agust,heima,....Sept10/PXP-211210ak.pxp; Lay:0, Gr:2

j(=1; S) Green

E(J´,J´-1)

J´

250

200

150

100

50

0

x103

89.2589.2089.1589.10x10

3

J'=7 (?)

S

2 3 4

5

agust,heima,...Sept10/Look for J7-211210.pxp

2? 3 4 5AK assignment

H35Cl+

35Cl+

H+

S

j(=1; S)Green / j(=1; S)AK

NB: 35Cl+/H35Cl+ is very high according to Q line according to KM; see slide 6 below

NB: actuallyThis could be J´=2 (35Cl+)

140

120

100

80

60

765432

agust,heima,....Sept10/PXP-211210ak.pxp; Lay:1, Gr:1

S

j(=1; P,Q,R,S) Green

140

120

100

80

60

765432

Probably not correct since this point should be larger due toInteraction with V, v´=20; see slide 3 above

Fits nicely with the R serie datai.e. points

agust,heima,....Sept10/PXP-211210ak.pxp; Lay:1, Gr:1 & ...XLS-211210ak.xls

S, AK

KM´s paper manuscript (TS(II) paper, version 12.12.10, fig. 2a

0

0.2

0.4

0.6

0.8

1

1.2

1 2 3 4 5 6J´

CalcExp

I(35

Cl+

)/I(

H35

Cl+

) ra

tio

140

120

100

80

60

765432

E(J´,J´-1)

J´

agust,heima,....Sept10/PXP-311210ak.pxp; Lay:2, Gr:3 & ..

j(=1; Q) Green

a = 21.667 ± 3.02b = 18.358 ± 0.498

GreenE(J´)Q

89030.2889087.0289166.7

89261.1989374.9489506.1889656.63

J´01234567

agust,heima,....Sept10/XLS-211210ak.xls

agust,heima,....Sept10/XLS-211210ak.xls

35

30

25

20

15

65432

E(J´,J´-1)

J´

agust,heima,....Sept10/PXP-311210ak.pxp; Lay:3, Gr:4 & ..

V(=1; Q), v´=20; Green

a = 1.128 ± 1.84 b = 6.446 ± 0.434

agust,heima,....juni09/grof fyrir J astond-150609hrh.xls

Energy level89085.6

89092.4789107.6189126.4789152.9489187.5489227.03

J'0123456

Orkumunur á þrepum

6.8715.1318.8726.4634.6139.49

agust,heima,....juni09/grof fyrir J astond-150609hrh.xls

)1()1(´)(´)(

)1()1(´)(´)(´0

´0

´´´20

02

02

´0

´0

´´´10

01

01

JJJJBJEJE

JJJJBJEJE

For 1 = Rydberg state and 2 0 ion-pair state

Here Calculated both for j and V,v´=20 states

89.78

89.76

89.74

89.72

89.70

89.68

x103

2.01.51.00.50.0

E1 (J´)

E10(J´)

(E10(J´) +E20(J´))/2

E20(J´)

(E2 (J´)

2/1

202

01

2

102

0112 ´)(´)(´)(´)(´)(

2

12

4

1´)(

JEJEJEJEJEJW

agust,heima,....Sept10/aHCl(3+1)j3S(0)Calc-141210ak.pxp, Lay: 8, Gr:12

J´(V, v´=21)

J´(j, v´=0)

)

W12 derived

E10(J´) E1 (J´) and E2

0(J´) needed:

Different ways to evaluted W12 (W12´) from E0(J´), E(J´) and EV(J´)via (J´) (= E(J´)-E0(J´)), see:http://www3.hi.is/~agust/rannsoknir/rempi/hcl/Jan11/PDF-020111ak.pdf

agust,heima,...Jan11/XLS-020111ak.xls

The above calculation for E0 evaluations is based on E(J´=7) = E0(J´=7)

j(1) V, v´=20H35Cl H35Cl

j(1) j(1) j(1) V,v´=20 W12 W12´J´ E(J´)=nju(Q)+E(J´´) EV(J´)=nju(Q)+E(J´´) comment DE0 DE E0 D(E-E0) EV0

0 89085.61 89030.27762 89092.47 40.025 89030.97 0.689132522 89091.78087 lower 6.510291 4.6034712 89087.02064 89107.61 58.383 56.743023 89089.35 2.329109201 89105.28089 lower 6.521512 2.6623963 89166.70465 89126.47 76.741 79.684009 89166.09 0.613899507 89127.0839higher 4.931851 1.4237034 89261.19301 89152.94 95.099 94.488363 89261.19 0.003262073 89152.94326higher 0.594238 0.1328765 89374.93689 89187.54 113.46 113.74387 89374.65 0.29013646 89187.83014higher 7.367937 1.3451956 89506.17522 89227.03 131.82 131.23833 89506.46 0.286529879 89227.31653higher #NUM! #NUM!7 89656.63475 150.17 150.45953 89656.63 0