HCl, F<-<-X, v´=1, R & S series:

Simulation of REMPI-current spectrum

Agust, heima, ...HClnov07-/HClF1simul-021107ak.pxpAgust, heima, ...HClnov07-/HClF1simul-021107aka.pxp Agust, heima, ...HClnov07-/excel files/HClF1simul-021107ak.xlsAgust, www, ...HClnov07-/HClF1simul-021107ak.ppt

H35Cl H37Cl

B''(v´ =0) 10,439826 10,42401826

D´´ 5,09E-04 0,000507232

B' 10,1307 10,11536033

D´ 0,0011646 0,001161076

35 0,979592507

37 0,981078032

0.2

0.1

0.0

-0.1

-0.2

16014012010080604020

(1xhv)

J´=43

2

56

7 8

H35Cl

H37Cl

R, S, series

R, S, series

J´=32

4

5

6

78

9

2 3

23

45 4 5 6

V,V´= 14Q

J´=234567

0.2

0.1

0.0

-0.1

-0.2

4035302520

J´=32

4

2

2 3

2

4

H35Cl

R, S, series

H37ClR, S, series

(1xhv)

-0.2

-0.1

0.0

0.1

75706560555045

J´=43

5

6

78

9

35

4

H35Cl

R, S, series

H37Cl

R, S, series

(1xhv)

-0.20

-0.15

-0.10

-0.05

0.00

0.05

160140120100

5

67

8H35Cl

H37Cl

R, S, series

R, S, series

5 6

(1xhv)

0.2

0.1

0.0

-0.1

-0.2

85.6585.6085.5585.5085.4585.40x10

3

J´=43

2

56

7 8

H35Cl

H37Cl

R, S, series

R, S, series

J´=32

4

5

6

78

9

2 3

23

45 4 5 6

2xhv ( based on Greens value for J´=2(R))

-0.20

-0.15

-0.10

-0.05

0.00

0.05

-35 -30 -25 -20 -15 -10 -5 0

H35Cl

J´= 2

J´= 2

34

5

6

7

89

10

shiftedP serie

Q serie

(1xhv)

-0.2

-0.1

0.0

0.1

-90 -80 -70 -60 -50 -40 -30

J´= 2345

67

H35ClP serie

?

(1xhv)

Comments:

•J´ Assignments made by Ashildur are correct.

•Is the peak on slide 9 marked ? Perhaps J´=8?? Shifted largely?

•J´=8 peak in the R seria overlaps heavily with the J´=4 peak in the S Serie.