hbr mass resolved rempi and imaging rempi
DESCRIPTION
HBr Mass resolved REMPI and Imaging REMPI. E. H + X + + e. J + v +. HX + + e. H + X**. IE(HX). J´ v´. (2+1)REMPI: 2h n + HX ->-> HX**(v´,J´) 1h n + HX** -> HX + (v + ,J + ). HX**. Rydb. H + Br / Br *. J´´ v´´= 0. HX. r(HX). E. H + X + + e. J + v +. - PowerPoint PPT PresentationTRANSCRIPT
HBr Mass resolved REMPIandImaging REMPI
Rydb.
H + Br/Br*
r(HX)J´´ v´´= 0
HX
HX**
HX+ + e
J´ v´
IE(HX) H + X**
H + X+ + e
J+ v+
E
(2+1)REMPI:
2hn + HX ->-> HX**(v´,J´)1hn + HX** -> HX+(v+,J+)
Rydb.
H + Br/Br*
r(HX)J´´ v´´= 0
HX
HX**
HX+ + e
J´ v´
H + X**
H + X+ + e
J+ v+
E
H+X-/Ion-pair/V
v´,J´(2+2)REMPI:
2hn + HX ->-> H+X-(v´,J´)2hn + H+X- -> H + X+
350x103
300
250
200
150
100
50
Re
lati
ve
in
ten
sit
y
/a.u
.
81.45x10381.4081.3581.3081.2581.2081.15
Wavenumber 2h/cm-1
I1 Q
2468
P234567
R2 3 4 5 6 7 8
S2 3 4 5 6
79Br+
H79Br+
60x103
40
20
0
-20
Re
lativ
e I
nte
nsi
ty
80.7x10380.680.580.4
Wavenumber /cm-1
m3(v'=0)
V1
(m+9)
H79
Br+
79Br
+
H+
0123456Q
27QP R
S
23456 2 3 4
2
k3(v'=0)
85.3685.3585.3485.33x10
3
H35Cl+
35Cl+
Q
J´=J´´ = 9 8 7 6 5 4 3 2
HCl, F1D2
2h n / cm-1
Inte
nsi
ty
r(H-X)
Energy
HX
H X ** H+--X-
HX+ X+
e-
e-
+
HX REMPI:
IE limit
v´
J´
v´
J´
State
Interactions ?
E
State
Interactions ?
(1) / y0 (2) / y01 2
c1y01
ya
c2y02= +
yb =c1
´y0 c2´y0-
1 2
c1c2+2 2
= 1
E
WEci
2
4
2
12
12
2
2
E
Fraction Rydb. Fraction ion-pair
W 12:
Interaction
strength
(1) / y0 (2) / y01 2
c1y01
ya
c2y02= +
yb =c1
´y0 c2´y0-
1 2
c1c2+2 2
= 1
E
WEci
2
4
2
12
12
2
2
E
Fraction Rydb. Fraction ion-pair
(1) / y0 (2) / y01 2
c1y01
ya
c2y02= +
yb =c1
´y0 c2´y0-
1 2
c1c2+2 2
= 1
E
WEci
2
4
2
12
12
2
2
E( ) E(J´)DE
E
Fraction Rydb. Fraction ion-pair
87.6x103
87.4
87.2
87.0
86.8
E v
´,J´
/ cm
-1
-120 -100 -80 -60 -40 -20 0 EJ´+1,J´ / cm
-1
V state
v´=13
v´=14
v´=1
F state
J´=8 J´=8
x
HCl:
F1D2
V1 S
I.e. Mixing (c12 and c2
2) J´ dependent:
(1) / y0 (2) / y01 2
c1y01
ya
c2y02= +
yb =c1
´y0 c2´y0-
1 2
c1c2+2 2
= 1
E
WEci
2
4
2
12
12
2
2
E( ) E(J´)
E
Fraction Rydb. Fraction ion-pair
HX+ X+
0
0.05
0.1
0.15
0.2
0.25
0.3
4 5 6 7 8 9J´
I(C
l+)/
I(H
Cl+
)
H35Cl H37Cl
F, v´=1 X, v´=0
85.3685.3585.3485.33x10
3
H35Cl+
35Cl+
Q
J´=J´´ = 9 8 7 6 5 4 3 2
HCl, F1D2
2h n / cm-1
Com-press-ion
E x p a n s i o n
Inte
nsi
ty
87.6x103
87.4
87.2
87.0
86.8
E v
´,J´
/ cm
-1
150100500-50-100 dEJ´+1,J´ / cm
-1
V state
v´=14
v´=1
F state
J´=8
J´=7
J´=8
J´=7
F (v´=1)
fig.3c
87.6x103
87.4
87.2
87.0
86.8
E v
´,J´
/ cm
-1
150100500-50-100 dEJ´+1,J´ / cm
-1
V state
v´=14
v´=1
F state
J´=8
J´=7
J´=8
J´=7
F (v´=1)
fig.3c
DE
2/120
201
2
1202
01 )(4
2
1
2
1EEWEEEi
Above: Weak „near-resonance“ state interaction (W12 small)
Below: Strong „off-resonance interaction“
Rel
ativ
e In
ten
sity
77.98x103
77.9677.9477.9277.9077.8877.86
Wavenumber 2hv/cm-1
Q
02489 7 6
E1
79Br
H79
Br
10
H79Br
E
H + Br/Br*
r(HX)J´´ v´´= 0
HX
HX**
HX+ + e
J´ v´=0
H + X**
H + X+ + e
J+ v+
E
H+X- /Ion-pair/V
v´=m+5v´=m+4
E
H + Br/Br*
r(HX)J´´ v´´= 0
HX
HX**
HX+ + e
J´ v´=0
H + X**
H + X+ + e
J+ v+
E
H+X- /Ion-pair/V
v´=m+5v´=m+4
79.8
79.6
79.4
79.2
x103
J´=0
J´=6
J´=9J´=6 v´=m+5
H79Br
E 1S(0+), v´=0
J´=9 v´=m+4
J´=0
V 1S(0+)
Off resonance
W´=0 W´=0
J´=6
J´=0
E/c
m-1
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
I(7
9 Br+
)/I(H
79 B
r+)
0 1 2 3 4 5 6 7 8 9J'
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
Experimental data V(v'=m+4) V(v'=m+5)
Exp: Calc:E(0)
8
6
4
2
0
Line
wid
th
/cm
-1
86420 J'
V1
'=m+4)
4
3
2
1
0
Line
wid
th
/cm
-1543210 J'
V1
'=m+5)
2.0
1.5
1.0
0.5
0.0
Line
wid
th
/cm
-1
86420 J'
E1
'=0)
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
I(7
9B
r+)/
I(H
79B
r+)
0 1 2 3 4 5 6 7 8 9J'
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
Experimental data V(v'=m+4) V(v'=m+5)
79.8
79.6
79.4
79.2
x103
J´=0
J´=6
J´=9J´=6 v´=m+5
H79Br
E 1S(0+), v´=0
J´=9 v´=m+4
J´=0
V 1S(0+)
J´=6
J´=0
E/c
m-1
140
120
100
80
60
40
20
J', J
'-1
/cm
-1
987654321J'
E(v'=0) Exp. Cal.
70
60
50
40
30
20
10
J'
, J'-1
/c
m-1
987654321J'
V(v'=m+4) Exp. Cal.
60
50
40
30
20
10
J'
, J'-1
/c
m-1
654321 J'
V(v'=m+5) Exp. Cal.
Imaging experiments in Crete:
Suggestions for experiments:-relevant to our studies (see above):
1) Studies relevant to strong state interactions vs. J´(http://jcp.aip.org/resource/1/jcpsa6/v138/i4/p044308_s1?isAuthorized=no /JCP; 2013)(or https://notendur.hi.is/~agust/rannsoknir/papers/jcp138-044308-13.pdf)Record ion images (H+, Br+, HBr+ (?)) vs J´ for two-photon, one-color resonance excitations to J´ levels ofa) The Rydberg state E(v´=0); For Q lines, J´=0, 2, ..8, 9(?) b) The Ion-pair state V(v´=m+5); For Q lines, J´=0, 2, ..8, 9(?) c) The Ion-pair state V(v´= m+4); For Q lines, J´=0, 2, ..8, 9(?) (excitation range: 77520 – 78450 cm-1/9.61-9.73 eV; photons: 258.00-254.94 nm;see lines: https://notendur.hi.is/~agust/rannsoknir/papers/jcp93-4624-90.pdf and/orhttps://notendur.hi.is/~agust/rannsoknir/papers/HBr/jms90-152-81.pdf)
::
2) Studies relevant to i) weak resonance state interactions and ii) strong interactions vs. J´(http://jcp.aip.org/resource/1/jcpsa6/v136/i21/p214315_s1?isAuthorized=no /JCP, 2012)(or https://notendur.hi.is/agust/rannsoknir/papers/HBr/jcp136-214315-12.pdf ) Record ion images (H+, Br+, HBr+ (?)) vs J´ for two-photon one color resonance excitations to J´ levels ofa) The Rydberg state F(v´=1); Q lines, J´=3, 4,5,6,7 (i)b) The Rydberg state E(v´=1); Q lines, J´= 0,1,….7(?) (ii)c) The Rydberg state H(v´=0), Q lines, J´= 0,1,….9(?) (ii)d) The Ion-pair state V(v´=m+7), Q lines, J´= 0,1, ..(5),..9 (i and ii)e) The Ion-pair state V(v´=m+8), Q lines, J´= 0,1,…7 (ii)(excitation range 79040-80300 cm-1/9.80 – 9.96 eV; photons: 253.04-249.07 nm;see lines: http://jcp.aip.org/resource/1/jcpsa6/v136/i21/p214315_s1?isAuthorized=no and/orhttps://notendur.hi.is/~agust/rannsoknir/papers/jcp93-4624-90.pdf and/orhttps://notendur.hi.is/~agust/rannsoknir/papers/HBr/jms90-152-81.pdf)
a)H+
b)Br+ and Br+ from Br resonancesc)Br- (<= H+ + Br-)
500x103
400
300
200
100
0
Rel
ativ
e In
ten
sity
/a.
u.
78.4x10378.278.077.877.6
Wavenumber /cm-1
E1+(v'=0)
V1+(v'=m+4)
V1+(v'=m+5)
X40
Q010
O01234567
S2 3 4 5 6 7 8 9
Q
Q
012345678
0123456
8
H79Br+
79Br+
H+
i33(v'=0)
Q R
9
200x103
150
100
50
0
-50
Inte
nsity
/a
.u.
79.5x10379.479.379.279.1
Wavenumber /cm-1
F1 (v'=1)
Q
P
R
S
2
2 3 4 5 6
2 3 54
2
10
11 3
O
45678910
234
23 10456789
V1 (v'=m+7)
Q
81Br+
H81Br+
H+
Br atomic line
7 8
H1 (v'=0)
O8 7 6 5 4 3 2 1
6 7
5
How are the H+ ´s formed?
H* + Br (3/2)
Ry V/Ion-pair
[ 4P,5s ] 3P
H* + Br*(1/2)
[ B2S ]..
H + Br**(5s)
H+ + Br(3/2)
H+ + Br-
[22P]1S0,3P0
H* + Br (3/2)H+ + Br -
Ry V/Ion-pair
[ 4P,5s ] 3P
H* + Br*(1/2)
[22P]..
[ B2S ]..
H + Br**(5s)
H+ + Br (3/2)/Br*(1/2)
HBr+(v+)(3/2,1/2)
H* + Br (3/2)H+ + Br-
Ry V/Ion-pair
[ 4P,5s ] 3P
H* + Br*(1/2)
[22P]1S0,3P0[ B2S ]..
H + Br**(5s)
H+ + Br*(1/2)
H+ + Br-
Ry V/Ion-pair
HBr+(X2P)
HBr+(A2S+)
HBr***
[A2S+]..
In summary (?):
Ry V/Ion-pair
H+ + Br(3/2,1/2) H+ + Br*(1/2, 3/2)
….via HBr***/H+Br- (2+1) hn….via HBr+(v+) (2+2) hn….via H* + Br/Br* (2+2) hn
H+ + Br (3/2)/Br*(1/2)H+ + Br-
Imaging experiments / data
E(0):
HBr, E(v´=0), J´= 1
J´= 1,2,…….
4
3
2
1
0
2.52.01.51.00.50.0
At(wave1): 0.076328At(wave1): 0.076328At(wave1): 0.076328At(wave1): 0.07867A0(wave1): 0.092539At(wave1): 0.05684At(wave3): 0.064184At(wave1): 0.076328At(wave3): 0.075018At(wave5): 0.061072At(wave7): 0.049266At(wave9): 0.048207At(wave11): 0.046259At(wave13): 0.043698At(wave15): 0.051772At(wave17): 0.050678
J´= 10(?)
98
765
432
1
KER/eV
Signal predictions
H+ + Br(3/2,1/2) H+ + Br*(1/2, 3/2) ….via H* + Br/Br* (2+2) hn
H + Br
HBr
HBr**
HBr+ + e
H + Br**
H + Br+ + e
E
H+Br-
H* + Br*(1/2)H* + Br (3/2)
H+ + Br*(1/2)H+ + Br (3/2)
E(J´´)
3hn
D0(HBr)
E(H*)
KER(3/2) KER(1/2)
SO(Br*)
E(J´´)+3hn = D0(HBr) +E(H*)+KER(3/2) => KER(3/2)=3hn + E(J´´)–D0(HBr)-E(H*)E(J´´)+3hn = D0(HBr) +E(H*)+KER(3/2) + SO(Br*) => KER(1/2)=3hn + E(J´´)–D0(HBr)-E(H*)-SO(Br*)
KER(3/2)=3hn + E(J´´)–D0(HBr)-E(H*)KER(1/2)=3hn + E(J´´)–D0(HBr)-E(H*)-SO(Br*)
E(J´´) = B´´(J´´(J´´+ 1)) – D´´J´´2(J´´+ 1)2
H+ + Br(3/2,1/2) H+ + Br*(1/2, 3/2) ….via H* + Br/Br* (2+2) hn
….via HBr***/H+Br- (2+1) hnH+ + Br-
KER= 3hn + E(J´´) – D0(HBr) - IE(H) + EA(Br)
4
3
2
1
0
0.60.40.20.0
At(wave1): 0.076328At(wave1): 0.076328At(wave1): 0.076328At(wave1): 0.07867A0(wave1): 0.092539At(wave1): 0.05684At(wave3): 0.064184At(wave1): 0.076328At(wave3): 0.075018At(wave5): 0.061072At(wave7): 0.049266At(wave9): 0.048207At(wave11): 0.046259At(wave13): 0.043698At(wave15): 0.051772At(wave17): 0.050678 H+ + Br(3/2)H+ +
Br(1/2)
Predicted KER´sFor H+ + Br-
J´= 10
9
876
54
321
HBr, E(0):
KER/eV
KER(3/2)=3hn + E(J´´)–D0(HBr)-E(H*)KER(1/2)=3hn + E(J´´)–D0(HBr)-E(H*)-SO(Br*)
E(J´´) = B´´(J´´(J´´+ 1)) – D´´J´´2(J´´+ 1)2
H+ + Br(3/2,1/2) H+ + Br*(1/2, 3/2) ….via H* + Br/Br* (2+2) hn
H+ + Br (3/2)/Br*(1/2) ….via HBr+(3/2,v+)/HBr+(1/2,v+) (2+2) hn
….via HBr***/H+Br- (2+1) hnH+ + Br-
KER= 3hn + E(J´´) – D0(HBr) - IE(H) + EA(Br)
KER(3/2<- 3/2)= hn + IE(HBr+ (3/2)) + G0(HBr+ (3/2),v+) –D0(HBr) - IE(H)KER(1/2<- 3/2)= hn + IE(HBr+ (3/2)) + G0(HBr+ (3/2),v+) –D0(HBr) - IE(H)-SO(Br*)KER(3/2<- 1/2)= hn + IE(HBr+ (1/2)) + G0(HBr+ (1/2),v+) –D0(HBr) - IE(H)KER(1/2<- 1/2)= hn + IE(HBr+ (1/2)) + G0(HBr+ (1/2),v+) –D0(HBr) - IE(H)-SO(Br*) G0 (HBr+) = we(v++1/2) – wexe (v++1/2)2+weye (v++1/2)3
-(we(1/2) – wexe (1/2)2+weye (1/2)3)
4
3
2
1
0
2.52.01.51.00.50.0
At(wave1): 0.076328At(wave1): 0.076328At(wave1): 0.076328At(wave1): 0.07867A0(wave1): 0.092539At(wave1): 0.05684At(wave3): 0.064184At(wave1): 0.076328At(wave3): 0.075018At(wave5): 0.061072At(wave7): 0.049266At(wave9): 0.048207At(wave11): 0.046259At(wave13): 0.043698At(wave15): 0.051772At(wave17): 0.050678
Negligible shift of peaks
HBr, E(0):
H+ + Br(1/2)
H+ + Br(3/2)
H+ + Br (3/2)/Br*(1/2)
<- HBr+(3/2,v+)/HBr+*(1/2,v+)
KER/eV
1.0
0.8
0.6
0.4
0.2
0.0
2.52.01.51.00.50.0
v+= 8 9 10 11 12 13
v+= 9 10 11 12 13 14
v+= 6 7 8 9 10 11
v+= 9 10 11 12 13 14Br/Br* HBr+/HBr+*½ <- ½3/2 <- ½½ <- 3/23/2 <- 3/2
HBr, E(0), J´=1:
H+ + Br(1/2)
H+ + Br(3/2)
H+ + Br (3/2)/Br*(1/2)
<- HBr+(3/2,v+)/HBr+*(1/2,v+)
KER/eV
Agust,lab top,C:/…/E0-KER-131124a.pxp
Ry V/Ion-pair
H+ + Br(3/2,1/2) H+ + Br*(1/2, 3/2)
….via HBr***/H+Br- (2+1) hn….via HBr+(v+) (2+2) hn….via H* + Br/Br* (2+2) hn
H+ + Br (3/2)/Br*(1/2)H+ + Br-
Signal of Channel via Ion-pairSignal of Channel via Rydberg
vs. J´ measure of Rydberg-Ion-pair interactions vs. J´
1.0
0.8
0.6
0.4
0.2
0.0
2.52.01.51.00.50.0
v+= 8 9 10 11 12 13
v+= 9 10 11 12 13 14
v+= 6 7 8 9 10 11
v+= 9 10 11 12 13 14Br/Br* HBr+/HBr+*½ <- ½3/2 <- ½½ <- 3/23/2 <- 3/2
HBr, E(0):
H+ + Br(1/2)
H+ + Br(3/2)
H+ + Br (3/2)/Br*(1/2)
<- HBr+(3/2,v+)/HBr+*(1/2,v+)
Agust,lab top,C:/…/E0-KER-131124b.pxp (Gr1, Lay0)
KER/eV
0.25
0.20
0.15
0.10
0.05
0.00
8642
J´
Agust,lab top,C:/…/E0-KER-131124c.pxp (Gr1, Lay0)
H+ + Br*(1/2, 3/2)<- H* + Br/Br*
H+ + Br(3/2,1/2)<- H* + Br/Br*
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
I(79
Br+
)/I(H
79B
r+)
0 1 2 3 4 5 6 7 8 9J'
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
Experimental data V(v'=m+4) V(v'=m+5)
0.75
0.70
0.65
0.60
0.55
0.50
8642 J´
H+ + Br (3/2)/Br*(1/2)<- HBr+(v+)
H+ + Br(3/2,1/2)<- H* + Br/Br*
Agust,lab top,C:/…/E0-KER-131124c.pxp (Gr1, Lay0)
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
I(79
Br+
)/I(H
79B
r+)
0 1 2 3 4 5 6 7 8 9J'
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
Experimental data V(v'=m+4) V(v'=m+5)
Ion-pair states
V(m+4) and V(m+5) spectra:
1.2
1.0
0.8
0.6
0.4
0.2
0.0
2.52.01.51.00.50.0
HBrJ´= 1
KER/eV
V(m+5)
E(0)
V(m+4)
Agust,lab top,C:/…/E0-KER-131125.pxp (Gr2, Lay3)
H+ + Br(1/2)
H+ + Br(3/2)
H+ + Br (3/2)/Br*(1/2)
<- HBr+(3/2,v+)/HBr+*(1/2,v+)
Br/Br* HBr+/HBr+*
½ <- ½3/2 <- ½½ <- 3/23/2 <- 3/2
v+= 10 11 12 13
v+= 9 10
0.4
0.3
0.2
0.1
0.0
78.678.478.278.0x10
3
H+ + Br*(1/2, 3/2)<- H* + Br/Br*
H+ + Br(3/2,1/2)<- H* + Br/Br*
2hn/cm-1
Agust,lab top,C:/…/E0-KER-131124d.pxp (Gr3, Lay3)
E(0)
V(m+4)
V(m+5)
J´= 1 2 3 4 5 6 7 8 9
J´= 012 3 4 5 6 7 8
J´= 0 1 2 3
H+ + Br*(1/2, 3/2)<- H* + Br/Br*
H+ + Br(3/2,1/2)<- H* + Br/Br*Larger for the V states than E(0)
0.4
0.3
0.2
0.1
0.0
78.678.478.278.0x10
3
H+ + Br*(1/2, 3/2)<- H* + Br/Br*
H+ + Br(3/2,1/2)<- H* + Br/Br*
2hn/cm-1
Agust,lab top,C:/…/E0-KER-131124d.pxp (Gr3, Lay3)
E(0)
V(m+4)
V(m+5)
J´= 1 2 3 4 5 6 7 8 9
J´= 012 3 4 5 6 7 8
J´= 0 1 2 3
H+ angular distributions:
H++Br(1/2)
H++Br(3/2)
H++Br(1/2) || || || (^)H++Br(3/2) ^^^
H++Br(1/2) ^ ^^H++Br(3/2) ^,||^,||^,||
H++Br(1/2) ^ ^^H++Br(3/2) ^,||||||
H++Br(1/2)
H++Br(3/2)
J´ 1 2 3 4 5 6 7 8 9
H++Br(1/2) || || ||,^ ^ ^ ^ ^ ^ ^
H++Br(3/2) ^ ^ ^ ^,|| ^,|| ^,|| ^,|| || ||
H* + Br (3/2)
E1S+ V/1S+
[ 4P,5s ] 3P
H* + Br*(1/2)
[ B2S ]..
H + Br**(5s)
H+ + Br(3/2)
H+ + Br-
[22P]1S0,3P0
H* + Br (3/2)H+ + Br-
[ 4P,5s ] 3P
H* + Br*(1/2)
[22P]1S0,3P0[ B2S ]..
H + Br**(5s)
H+ + Br*(1/2)
E1S+ V/1S+
Br+ images
a)HBr Molecular resonancesb)Br atom resonances
H + Br/Br*
r(HX)J´´ v´´= 0
HX
HX**
HX+ + e
J´ v´
H + X**
H + X+ + e
J+ v+
E
H+X- /Ion-pair/V
v´,J´
a) HBr Molecular resonances
3hn: X+ <- H + X**
2hn: X+ <-<-<- H+ Br/Br*
1hn: X+ <-<-<- H+ Br/Br*
KER´s
Max:
KER(81Br)eV
0,0351970,03524
0,0353070,0353960,0355090,0356440,035801
0,035980,0361770,036403
81Br KER 81Br KERKER(Br(3/2)) KER(Br(1/2))eV eV
0,013269482 0,0076973880,013317537 0,0077454430,013390194 0,00781810,013487191 0,0079150970,013608705 0,0080366120,013754375 0,008182282
0,01392428 0,0083521860,014117805 0,0085457110,014334023 0,008761930,014576229 0,009004135
81Br KER 81Br KERKER(Br(3/2)) KER(Br(1/2))eV eV
0,072191331 0,0666192370,072236967 0,066664873
0,0723066 0,0667345060,072399741 0,0668276470,072516795 0,0669447010,072657098 0,0670850040,072820878 0,0672487850,073006995 0,0674349010,073213688 0,0676415940,073447652 0,067875558
J´
123456789
10
HBr, E(0); Br+ KER´s
1hn 2hn 3hn
„blob“!
H + X/X*
r(HX)J´´ v´´= 0
HX
HX**
HX+ + e
J´ v´
H + X**
H + X+ + e
J+ v+
E
H+X- /Ion-pair/V
v´,J´
a) Br atom resonances
X+ + e
X**
X/X*
Only „1hn channel“ observed
HBr „near-resonance“ interactions:Exp. 3 & 4 (?):
Alternative HBr experiments(3 & 4):
3) „near-resonance“ interaction: k3P1(v´= 0) (k(0)) and V(m+9) for J´= 7Ref: https://notendur.hi.is/~agust/rannsoknir/papers/HBr/jms282-20-12.pdf :
3) „near-resonance“ interaction: k3P1(v´= 0) (k(0)) and V(m+9) for J´= 7Ref: https://notendur.hi.is/~agust/rannsoknir/papers/HBr/jms282-20-12.pdf :
4) „near-resonance“ interaction: 6pp3S-(v´= 0) and V(m+17) for J´= 7,8,9Ref: https://notendur.hi.is/~agust/rannsoknir/papers/HBr/jms282-20-12.pdf :
O Q S
4) „near-resonance“ interaction: 6pp3S-(v´= 0) and V(m+17) for J´= 7,8,9Ref: https://notendur.hi.is/~agust/rannsoknir/papers/HBr/jms282-20-12.pdf :
4) „near-resonance“ interaction: 6pp3S-(v´= 0) and V(m+17) for J´= 7,8,9Ref: https://notendur.hi.is/~agust/rannsoknir/papers/HBr/jms282-20-12.pdf :
4) „near-resonance“ interaction: 6pp3S-(v´= 0) and V(m+17) for J´= 7,8,9Ref: https://notendur.hi.is/~agust/rannsoknir/papers/HBr/jms282-20-12.pdf :