hazmat ch11
TRANSCRIPT
Mission-Specific Competencies: Product Control
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Objectives (1 of 4)
• Describe and identify the control options available to operations level responders
• Describe and identify the control options available for flammable liquid and flammable gas incidents
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Objectives (2 of 4)
• Describe purpose, equipment, precautions associated with control options
• Describe the applicability and characteristics of aqueous film-forming foam, alcohol-resistant concentrates, fluoroprotein foams, protein foams, and high-expansion foams
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Objectives (3 of 4)
• Identify the location and describe the use of emergency remote shut-off devices on MC/DOT-306/406, MC/DOT-307/407, and MC-331 cargo tanks containing flammable liquids or gases
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Objectives (4 of 4)
• Describe the recovery phase, and the transition from emergency to clean-up
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Confinement
• Keeps hazardous material within area of release
• Done by– Damming– Diking– Confining vapors
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Containment
• Stops material from leaking from container
• Examples– Patching container– Righting overturned container
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Control Options
• Solution must be quick and safe
• Should minimize negative effects on– People– Property– Environment
• Use risk-based thought process
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Sometimes No Action Is Safest Course (1 of 2)
• Create safe perimeter– Be aware of natural control points
• Let problem stabilize on its own
• Protect exposures
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Sometimes No Action Is Safest Course (2 of 2)
Sometimes it is necessary to let the problem stabilize on its own.
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Absorption (1 of 5)
• Absorbent material soaks up liquid release– Vermiculite– Clay– Peat moss– Spill pads
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Absorption (2 of 5)
Spill pads are often used to soak up a liquid hazardous material.
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Absorption (3 of 5)
• Effective only on flat surfaces
• Disposal of used material is necessary
• Requires close proximity to spill
• Adds volume to spill
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Absorption (4 of 5)
• Some materials repel water while absorbing spilled liquid
• Useful to contain oil spill on body of water
• Spill booms used on water or land
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Absorption (5 of 5)
A spill boom can be used to confine a liquid.
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Adsorption
• Contaminant adheres to surface of material– Silica– Activated carbon
• Can generate heat
• Functions like Velcro—sticks to product
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Damming
• Used when liquid flows in channel
• Progress is stopped by blocking channel
• Three kinds of dam– Complete dam– Overflow dam– Underflow dam
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Complete Dam
• Placed across small stream or ditch
• Completely stops flow of material
• Used for – Basically dry stream or ditch– Small amount of hazardous material
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Overflow Dam (1 of 2)
• Contains materials heavier than water
• Pipe through dam allows water flow
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Overflow Dam (2 of 2)
An overflow dam is used to contain materials that are heavier than water.
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Underflow Dam (1 of 2)
• Contains materials lighter than water
• Pipe through dam allows water flow
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Underflow Dam (2 of 2)
An underflow dam is used to contain materials that are lighter than water.
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Diking
• Barrier, keeps hazardous material in place
• Materials used– Sand– Dirt– Loose absorbent– Concrete
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Dilution
• Addition of water or another substance
• Weakens strength of hazardous material
• Typically used for corrosives
• Increases volume– May overwhelm containment measures
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Diversion (1 of 2)
• Redirects flow from endangered area– Existing curbs– Curvature of roadway– Dirt berms– Spill booms– Plastic tarps filled with sand, dirt, or clay
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Diversion (2 of 2)
Diversion methods are not as “permanent” as a dike, and they can be constructed fairly quickly.
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Retention• Creates defined area to hold material
• Example: Digging a hole– Allows material to collect or pool
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Remote Valve Shut-off
• Pre-existing shutdown device in system
• Found in– Chemical processes– Piped systems that carry chemicals– Cargo tanks
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MC-306/DOT-406 Cargo Tank (1 of 2)
• Carries flammable liquids, explosives, poisons
• Has various safety features
• Has remote shut-off valve
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MC-306/DOT-406 Cargo Tank (2 of 2)
The remote shut-off valve is typically found near the front of the cab, adjacent to the driver’s door, or at the rear of an
MC-306/DOT-406 cargo tank.
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MC-307/DOT-407 Cargo Tank (1 of 2)
• Carries low-pressure chemicals– Flammables– Combustible liquids– Mild corrosives – Poisons
• Has remote shut-off valve
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MC-307/DOT-407 Cargo Tank (2 of 2)
The remote shut-off valve is typically found near the front of the cab, adjacent to the driver’s door, or at the rear of an
MC-307/DOT-407 cargo tank.
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MC-331 Cargo Tank (1 of 2)
• Carries compressed liquefied gases– Anhydrous ammonia– Propane– Butane– Liquefied petroleum gas (LPG)
• Has remote shut-off valves
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MC-331 Cargo Tank (2 of 2)
The MC-331 cargo tank has remote shut-off valves at both ends of the tank, internal shut-off valves, a rotary gauge depicting
product pressure, and two top-mounted vents.
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Vapor Dispersion
• Spreads vapors out
• Thereby lowers their concentration
• Hose streams
• Fans
• Other ventilation systems
• Consequences should be considered
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Vapor Suppression
• Controls fumes given off by materials
• Particularly for flammable liquids
• Example: Gasoline
• Uses blanket of foam
• Reducing temperature may also suppress vapor
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Foams Used in Vapor Suppression
• Aqueous film-forming foam (AFFF)
• Alcohol-resistant concentrates
• Fluoroprotein foam
• Protein foam
• High-expansion foam
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Applying Foam (1 of 4)
• Several ways to apply foam– Bounce-off method– Rain-down method– Roll-in method
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Applying Foam (2 of 4)
The bounce-off method.
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Applying Foam (3 of 4)
The rain-down method.
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Applying Foam (4 of 4)
The roll-in method.
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Recovery Phase (1 of 3)
• Danger has passed or is controlled– Danger to people– Danger to property– Danger to the environment
• Clean-up begins
• Can be lengthy in large-scale incidents
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Recovery Phase (2 of 3)
The recovery phase involves clean-up, determination of the responsible party, and implementation of cost recovery.
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Recovery Phase (3 of 3)
• Initial responders may also perform clean-up
• Commercial companies may perform clean-up
• Returns exposure area to original condition
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Summary (1 of 2)
• Various factors must be evaluated to choose a control option
• Sometimes safe perimeter can be created and the problem left to stabilize on its own
• Control techniques contain, redirect, or lower concentration of hazardous material
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Summary (2 of 2)
• Options include absorption, diversion, damming, diking, shut-off valves, special foams
• Recovery phase returns exposure area to original condition
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