hazard communication ghs/ghs 2012

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OSHAcademy Course 705. Hazard Communication GHS/GHS 2012. Trainer Name Position Company Phone Email (Revise as needed) . Objective - PowerPoint PPT Presentation

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Page 1: Hazard Communication GHS/GHS 2012

OSHAcademy Course 705

Page 2: Hazard Communication GHS/GHS 2012

Trainer NamePosition

Company PhoneEmail

(Revise as needed)

Page 3: Hazard Communication GHS/GHS 2012

Objective

Describe the Hazard Communication Standard (HCS) requirements and the four practical elements of the rule for the purpose of informing employees of classified chemicals, their hazards, and protective measures to prevent injury or illness.

1. Written Hazard Communication Program2. Safety Data Sheets (SDSs)3. Labeling4. Employee Information and Training

Page 4: Hazard Communication GHS/GHS 2012

The new HCS 2012 is now aligned with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS) that provides many benefits, including the following:

•Provides a common and coherent approach to classifying chemicals and communicating hazard information on labels and safety data sheets; •Improves the quality and consistency of hazard information in the workplace;•Helps reduce trade barriers; •Results in productivity improvements for American businesses that regularly handle, store, and use classified hazardous chemicals;•Provides cost savings for American businesses that periodically update safety data sheets and labels for classified chemicals.•Remember, the old HCS 1994 gave workers the right to know, but the new HCS 2012 gives workers the right to understand: this is a very important change, so look for it on the final exam!

HCS 2012 and the GHS

Page 5: Hazard Communication GHS/GHS 2012

The purpose of the HCS 2012 is to make sure that:

1.The hazards of all chemicals produced or imported are classified, and 2.information about the classified hazards is transmitted to employers and employees.

Classifying the potential hazards of chemicals, and communicating information concerning hazards and appropriate protective measures to employees, may include:•Developing and maintaining a written hazard communication program;•Listing the hazardous chemicals present;•Labeling containers of chemicals in the workplace; •Labeling containers of chemicals being shipped to other workplaces;•Preparing and distributing SDSs to employees and downstream employers;•Developing and implementing employee training programs.

Remember, OSHA's new HCS 2012 is intended to be consistent with the provisions of the United Nations' GHS. (This will be on the exam!)

Page 6: Hazard Communication GHS/GHS 2012

Scope and Application

The HCS 2012 requires chemical manufacturers or importers to classify the hazards of chemicals which they produce or import.

It requires all employers to provide information to their employees about the hazardous chemicals to which they are exposed, by means of:

1.a hazard communication program, 2.labels and other forms of warning, 3.safety data sheets, and 4.information and training.

Page 7: Hazard Communication GHS/GHS 2012

Scope and Application

In addition, the HCS requires distributors to transmit the required information to employers.

Employers who do not produce or import chemicals need only focus on those parts of this rule that deal with establishing a workplace program and communicating information to their workers.

Page 8: Hazard Communication GHS/GHS 2012

HCS/GHS 2012 Timeline

Page 9: Hazard Communication GHS/GHS 2012

What are “Hazardous Chemicals”?

"Hazardous chemical" means any chemical which is classified as a physical hazard or a health hazard, a simple asphyxiant, combustible dust, pyrophoric gas, or hazard not otherwise classified.

Physical hazards - reactions that could occur if chemicals are handled or stored improperly. This could result in a fire, explosion, and/or toxic gas release.

Health hazards - health effects caused directly by the chemicals themselves, not an injury resulting from a reaction. All chemical materials can cause health problems under the wrong conditions.

Page 10: Hazard Communication GHS/GHS 2012

Forms of Hazardous Chemicals

Dusts - are finely divided particles. Example - wood dust.

Fumes - are even smaller particles usually formed when solid metal is heated and vaporized, and then condenses as tiny particles.

Fibers - are similar to dusts but are of an elongated shape. Examples - asbestos and fiberglass.

Mists - are liquid droplets that have been sprayed into the atmosphere.

Vapors - are gases formed when liquid evaporates.

Gases - are substances that are normally airborne at room temperature. A vapor is the gaseous phase of a substance which is a normally a liquid or solid at room temperature.

Solids - such as metal, treated wood, plastic.

Liquids - the most common form in the workplace.

Page 11: Hazard Communication GHS/GHS 2012

The Three States of Matter

Liquid - A quantity of liquid has a definite volume, but takes on the shape of its container.

Gas - A quantity of gas has the shape and volume of the container it occupies.

Solid - A solid has a definite shape and volume regardless of the container into which it is placed.

Page 12: Hazard Communication GHS/GHS 2012

List chemicals you use in the workplace.Check the boxes if you know the chemical’s

Health Effects PPE Emergency Procedures

Page 13: Hazard Communication GHS/GHS 2012

Chemical effects

The effects chemicals have on the various organs of the human body depend on several important factors:

1. The form of the chemical : Is the chemical a solid, liquid, or gas?

2. How the chemical Contacts the body: Is the chemical ingested, inhaled, absorbed, or injected?

3. The amount, or dose, the body receives. How much chemical makes its way into the body?

4. How toxic the chemical is. How poisonous is the chemical?

Page 14: Hazard Communication GHS/GHS 2012

Chemical effects

At excessive levels, substances contacting or entering the body may cause reversible or irreversible toxic effects.

Chemical Essential tohealth

OSHAregulated

Zinc Y YManganese Y YCopper Y YMolybdenum Y YSelenium Y YChromium Y YNickel Y YTin Y Y

Page 15: Hazard Communication GHS/GHS 2012

Chemical toxicity, amongother factors, depends onthe dose.

1 microgram of botulin can kill 20 million mice!

Page 16: Hazard Communication GHS/GHS 2012

Routes of EntryAbsorption - Contact with the skin may result in four possible actions:

1. Skin acts as effective barrier.

2. Skin reacts causing local irritation or skin destruction.

3. Skin sensitization.

4. Skin penetration to bloodstream.

Page 17: Hazard Communication GHS/GHS 2012

Routes of EntryInhalation - Contact with respiratory system may result in two possible actions:

1. If particle larger than 5 microns, normally expelled.

2. If particle smaller than 5 microns, likely entry into alveolar sacs.

Page 18: Hazard Communication GHS/GHS 2012

Routes of EntryIngestion - Contact with digestive system may result in two possible actions:

1. Detoxification through dilution, enzyme action, and elimination.

2. Absorption into the blood stream.

A fourth route:

Injection – harmful substance is injected below the skin

Page 19: Hazard Communication GHS/GHS 2012

Control Strategies

The Hierarchy of Controls

1. ENGINEERING

2. ADMINISTRATIVE

3. PERSONAL PROTECTIVE EQUIPMENT

Page 20: Hazard Communication GHS/GHS 2012

Control StrategiesThe Hierarchy of Controls

The first three strategies focus on doing something with the hazard.

1. Elimination2. Substitution3. Engineering Controls

The last two strategies focus on doing something with behaviors to reduce exposure to the hazard.

4. Administrative Controls. 5. Personal Protective Equipment (PPE).

Page 21: Hazard Communication GHS/GHS 2012

Three ways to inform workers of hazardous chemicals.

1. Container Labels

2. Safety Data Sheet - SDS

3. Training

Page 22: Hazard Communication GHS/GHS 2012

Chemical manufacturers must…

1. Assess hazards

2. Distribute SDS

3. Produce and revise label for container

Page 23: Hazard Communication GHS/GHS 2012

Distributors must…

1. Transmit SDS

2. Retails/Wholesale distributors must:

• Provide SDS to commercial accounts & post sign.

• Provide hazardous chemical manufacturer address and phone number to employers who do not have commercial account.

Page 24: Hazard Communication GHS/GHS 2012

Employers must…

1. Develop a written Hazard Communication (HAZCOM) Program

2. Maintain SDS’s

3. Implement and perform container labeling

4. Conduct employee information and training

Page 25: Hazard Communication GHS/GHS 2012

Rules Apply To:

Any chemical that employees may be exposed to under normal conditions in the workplace or in a foreseeable emergency.

Page 26: Hazard Communication GHS/GHS 2012

Rules do not apply to:

Hazardous wastes

Hazardous substances

Tobacco or tobacco products

Food or alcoholic beverages

Wood or wood products

Articles

Page 27: Hazard Communication GHS/GHS 2012

Drugs

Consumer products or hazardous substances

Nuisance particulates

Rules do not apply to:

Ionizing and nonionizing radiation

Biological hazards

Page 28: Hazard Communication GHS/GHS 2012

WrittenHazard

CommunicationProgram

Page 29: Hazard Communication GHS/GHS 2012

Must be available to:

Employees

Employee representatives

OSHA Representative

Page 30: Hazard Communication GHS/GHS 2012

Labeling container

SDS maintenance

Information and training

Three subject areas in the Written Program:

Page 31: Hazard Communication GHS/GHS 2012

Other subject areas within the written program :

List of hazardous chemicals

Methods for non-routine tasks

Pipe and piping systems

Mobile unit procedures

Page 32: Hazard Communication GHS/GHS 2012

Multi- employer procedures

Provide SDS to all employees

Inform other employees of precautionary measures

Inform other employees of labeling systems

Page 33: Hazard Communication GHS/GHS 2012

Using the labels the instructor has made available, list 3 chemical products, their hazard warning, and possible location of use in a given operation.

Page 34: Hazard Communication GHS/GHS 2012

Product name Hazard warning Location of use

Chemicals List

Gasoline Flammable Shop, vehicles

Page 35: Hazard Communication GHS/GHS 2012

Using the sample written hazard communication program, follow along with the instructor as major portions of your program are completed.

Page 36: Hazard Communication GHS/GHS 2012

Types of Containers

Container labeling can be a very effective method to communicate the physical and health hazards of chemicals used in the workplace. The information on a container label will vary depending on what type of container it is and how it is used.

We'll discuss labeling requirements under the old 1994 HCS and the new (GHS) labeling requirements adopted by the HCS 2012.

Page 37: Hazard Communication GHS/GHS 2012

Types of Containers

Types of containers referred to in the hazard communication standard:

• Shipped/Primary container labels - on shipped containers

• Workplace/Secondary container labels - on employer containers

• Stationary container labels - on large tanks, etc.• Portable containers - there are NO label requirements

Page 38: Hazard Communication GHS/GHS 2012

The "old" Primary Container Label Requirements

Most containers shipped directly from the manufacturer or purchased from a distributor are called shipped or primary containers. Labeling information on these containers is usually adequate in communicating the hazards of the chemical.

Under the old HCS 1994, the chemical manufacturer, importer, or distributor must ensure that each container of hazardous chemicals leaving the workplace is labeled, tagged or marked with the following three elements of information:

•Identity of the hazardous chemical(s)

•Appropriate hazard warnings, including target organ effects of the hazardous chemical, and

•Name and address of the chemical manufacturer, importer, or other responsible party.

Page 39: Hazard Communication GHS/GHS 2012

Label Requirements

L o r s b a n 5 0 W

In s e c t ic id eW a r n in g

S k in & E y e I r r i t a n t

D O W E L A N C OIn d ia n a p o l is , IN 4 6 3 8 6

Primary Container Label

Page 40: Hazard Communication GHS/GHS 2012

The "new" Shipped - Primary Container Label Requirements

Under the new HSC 2012, labels on primary containers shipped from manufacturers or distributors, the container must be labeled, tagged or marked with the following six items:

1.Product Identifier 2.Signal words

3.Hazard Statements

4.Pictograms

5.Precautionary statements

6.Supplier identification

Page 41: Hazard Communication GHS/GHS 2012

Sample HCS 2012 Primary Container Label

Page 42: Hazard Communication GHS/GHS 2012

Workplace or Secondary Container Labeling

The employer must ensure that each workplace or secondary container of hazardous chemicals in the workplace is labeled, tagged or marked with either:

1. The information required on shipped container labels; or,

2. Product identifier and words, pictures, symbols, or combination thereof, which provide at least general information regarding the hazards of the chemicals, and which, in conjunction with the other information immediately available to employees under the hazard communication program, will provide employees with the specific information regarding the physical and health hazards of the hazardous chemical.

Page 43: Hazard Communication GHS/GHS 2012

Lorsban 50W

InsecticideW arning

Skin & E ye Irritant

Secondary Container Label

Label Requirements

Page 44: Hazard Communication GHS/GHS 2012

Label RequirementsPortable Container Label – Not Req’d

Page 45: Hazard Communication GHS/GHS 2012

…means that the hazardous chemical will be under the control of and used only by the person who transfers it from a labeled container and only within the work shift in which it is transferred.

“Immediate use”

Page 46: Hazard Communication GHS/GHS 2012

Label RequirementsStationary

Container Label

Page 47: Hazard Communication GHS/GHS 2012

HCS Pictograms and Hazards

Health Hazard Flame Exclamation Mark

Gas Cylinder Corrosion Exploding Bomb

Flame Over Circle Environment Skull and Crossbones

HCS/GHS Pictograms and Hazards

Page 48: Hazard Communication GHS/GHS 2012

Piping systems.

Those pipes and piping systems containing or transporting hazardouschemicals must be labeled accordingto Division 2/H, Hazardous Materials.

Other labeling requirements…

Page 49: Hazard Communication GHS/GHS 2012

Never deface orremove labels

Unless the container is immediatelymarked with the required information.

No need to affix new label if old labels meet requirements.

Other labeling requirements…

Page 50: Hazard Communication GHS/GHS 2012

Displaying Labels

Legible, and in English.

May add other languages.

Prominently displayed on container, or readily available

in work area.

Other labeling requirements…

Page 51: Hazard Communication GHS/GHS 2012

Labels not required on:

• Pesticides

• Chemical substances or mixtures

• Food, food additives, drugs…

• Distilled spirits, wine, malt beverages

• Agricultural or vegetable seeds

Other labeling requirements…

Page 52: Hazard Communication GHS/GHS 2012

Solid Materials

Label required only with initial shipment. Need not be included with subsequent shipments unless information on the label changes.

Other labeling requirements…

Page 53: Hazard Communication GHS/GHS 2012

Label category:

What’s wrong?

What might be the result?

Exercise: What’s wrong with these labels?

Page 54: Hazard Communication GHS/GHS 2012

Label category:

What’s wrong?

What might be the result?

Exercise: What’s wrong with these labels?

Page 55: Hazard Communication GHS/GHS 2012

Safety Data Sheets(SDS)

For all hazardous chemicals

Readily available - normal work hours

Immediately accessible - emergencies

Page 56: Hazard Communication GHS/GHS 2012

SDS Management

Here are some more important requirements manufacturers, importers and distributors must meet:

The manufacturer or importer must:

•Prepare one SDS that applies to all similar mixtures where complex mixtures have similar hazards and contents (i.e. the chemical ingredients are essentially the same, but the specific composition varies from mixture to mixture).•Ensure that the SDS information recorded accurately reflects the scientific evidence used in making the hazard classification.•Add new information to the SDS within three months after becoming aware of any significant new information regarding the hazards of a chemical, or ways to protect against the hazards.•If the chemical is not currently being produced or imported, add any new information to the material SDS before the chemical is introduced into the workplace again.•Provide an appropriate SDS with the initial shipment, with the first shipment after a SDS is updated, and as requested by the employer or distributor.•Provide SDS's with the shipped containers or send the SDS's to the distributor or employer prior to or at the time of the shipment.

Page 57: Hazard Communication GHS/GHS 2012

SDS Management (Continued)

Distributors must:

•Ensure that SDS, and updated information, are provided to other distributors and employers with their initial shipment and with the first shipment after a SDS is updated;

•Provide SDS with the shipped containers, or send them to the other distributor or employer prior to or at the time of the shipment;

•Retail distributor selling hazardous chemicals to employers having a commercial account must:

1. provide a SDS to such employers upon request, and

2. post a sign or otherwise inform them that a SDS is available.

Page 58: Hazard Communication GHS/GHS 2012

What about employer responsibilities?Employers must obtain a SDS from the chemical manufacturer or importer as soon as possible if the SDS is not provided with a shipment that has been labeled as a hazardous chemical.

Employers must maintain copies of the required SDSs in their workplace for each hazardous chemical, and must ensure that SDS are readily accessible during each work shift to employees when they are in their work area(s).

Electronic access and other alternatives to maintaining paper copies of the SDS are permitted as long as no barriers to immediate employee access in each workplace are created by such options. Make sure employees know how to quickly access SDS information that is stored in on computers or online.

Where employees must travel between workplaces during a workshift, i.e., their work is carried out at more than one geographical location, the SDSs may be kept at the primary workplace facility. In this situation, the employer must ensure that employees can immediately obtain the required information in an emergency.

Page 59: Hazard Communication GHS/GHS 2012

What about employer responsibilities?SDSs may be kept at the primary workplace facility, as long as the employer has a representative available at all times to ensure ready access (within a few minutes) to this information. This is the only situation in which an employer is allowed to transmit hazard information via voice communication. The employer must address in the written hazard communication plan how SDS information will be conveyed to remote worksites.

SDSs may be kept in any form, including operating procedures, and may be designed to cover groups of hazardous chemicals in a work area where it may be more appropriate to address the hazards of a process rather than individual hazardous chemicals.

Readily available. However, the employer must make sure that in all cases the required information is provided for each hazardous chemical, and is readily available during each work shift to employees when they are in their work area(s).

Immediately accessible. Employees who work at more than one site during the work shift must be able to obtain SDS information immediately (within seconds) in an emergency.

Page 60: Hazard Communication GHS/GHS 2012

Providing the SDSWho must have them?

•Chemical manufacturers and importers must obtain or develop a SDS for each hazardous chemical they produce or import. •Employers must have a SDS in the workplace for each hazardous chemical which they use.

Page 61: Hazard Communication GHS/GHS 2012

SDS Changes

Significant new hazard informationor ways to protect against hazardmust be added to the SDS withinthree months.

Page 62: Hazard Communication GHS/GHS 2012

Failure to Provide an SDS

If a SDS is not provided with shipment of hazardous chemical,the employer must obtain one from the manufacturer as soon as possible.

Page 63: Hazard Communication GHS/GHS 2012

Remote work sites...

• SDS may be kept at a central location at the primary workplace.

• SDS must be readily available in a non- emergency situation.

• SDS must be immediately accessible in an emergency.

Page 64: Hazard Communication GHS/GHS 2012

Kept in any form

Examples:

• Paper

• Computer file

May cover groups of hazards

Page 65: Hazard Communication GHS/GHS 2012

The SDS form

The chemical manufacturer or importer preparing the safety data sheet must ensure that it is in English (although the employer may maintain copies in other languages as well).

Sample GHS Safety Data Sheet

1. IdentificationProduct Name: Chemical StuffSynonyms: Methytrexil SolutionateCAS Number: 000-00-0Product Use: Organic SynthesisManufacturer/Supplier: My CompanyAddress: Any Street, Mytown, TX 00000General Information: 555-123-4567Transportation Emergency Number: CHEMTREC: 800-424-9300

Page 66: Hazard Communication GHS/GHS 2012

2. Hazards Identification - GHS Classification:

Page 67: Hazard Communication GHS/GHS 2012

2. Hazards Identification - GHS Label

Page 68: Hazard Communication GHS/GHS 2012

3. Composition / Information on Ingredients

Component    CAS Number    Weight %Methyltoxy       000-00-0       80(See Section 8 for Exposure Limits)

Page 69: Hazard Communication GHS/GHS 2012

4. First Aid Measures

Eye: Eye irritation. Flush immediately with large amounts of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Get immediate medical attention.

Skin: Itching or burning of the skin. Immediately flush the skin with plenty of water while removing contaminated clothing and shoes. Get immediate medical attention. Wash contaminated clothing before reuse.

Inhalation: Nasal irritation, headache, dizziness, nausea, vomiting, heart palpitations, breathing difficulty, cyanosis, tremors, weakness, red flushing of face, irritability. Remove exposed person from source of exposure to fresh air. If not breathing, clear airway and start cardiopulmonary resuscitation (CPR). Avoid mouth-to-mouth resuscitation.

Ingestion: Get immediate medical attention. Do not induce vomiting unless directed by medical personnel.

Page 70: Hazard Communication GHS/GHS 2012

5. Fire Fighting MeasuresSuitable Extinguishing Media: Use dry chemical, foam, or carbon dioxide to extinguish fire. Water may be ineffective but should be used to cool fire-exposed containers, structures and to protect personnel. Use water to dilute spills and to flush them away from sources of ignition.

Fire Fighting Procedures: Do not flush down sewers or other drainage systems. Exposed firefighters must wear NIOSH-approved positive pressure self-contained breathing apparatus with full-face mask and full protective clothing.

Unusual Fire and Explosion Hazards: Dangerous when exposed to heat or flame. Will form flammable or explosive mixtures with air at room temperature. Vapor or gas may spread to distant ignition sources and flash back. Vapors or gas may accumulate in low areas. Runoff to sewer may cause fire or explosion hazard. Containers may explode in heat of fire. Vapors may concentrate in confined areas. Liquid will float and may reignite on the surface of water.

Combustion Products: Irritating or toxic substances may be emitted upon thermal decomposition. Thermal decomposition products may include oxides of carbon and nitrogen.

Page 71: Hazard Communication GHS/GHS 2012

6. Accidental Release MeasuresKeep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. (Also see Section 8).

Vapor protective clothing should be worn for spills and leaks. Shut off ignition sources; no flares, smoking or flames in hazard area. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal.

Do not flush to sewer or waterways. Prevent release to the environment if possible. Refer to Section 15 for spill/release reporting information.

Page 72: Hazard Communication GHS/GHS 2012

7. Handling and StorageHandling -Do not get in eyes, on skin or on clothing. Do not breathe vapors or mists. Keep container closed. Use only with adequate ventilation. Use good personal hygiene practices. Wash hands before eating, drinking, smoking. Remove contaminated clothing and clean before re-use. Destroy contaminated belts and shoes and other items that cannot be decontaminated.

Keep away from heat and flame. Keep operating temperatures below ignition temperatures at all times. Use non-sparking tools.

Storage - Store in tightly closed containers in cool, dry, well-ventilated area away from heat, sources of ignition and incompatibles. Ground lines and equipment used during transfer to reduce the possibility of static spark-initiated fire or explosion. Store at ambient or lower temperature. Store out of direct sunlight. Keep containers tightly closed and upright when not in use. Protect against physical damage.

Empty containers may contain toxic, flammable and explosive residue or vapors. Do not cut, grind, drill, or weld on or near containers unless precautions are taken against these hazards.

Page 73: Hazard Communication GHS/GHS 2012

8. Exposure Controls / Personal Protection

Exposure Limits

Component, Methyltoxy - TWA: 3 ppm (skin) - STEL: C 15 ppm (15 min.)

Engineering Controls: Local exhaust ventilation may be necessary to control air contaminants to their exposure limits.

Personal Protective Equipment (PPE)

Eye Protection: Wear chemical safety goggles and face shield.

Skin Protection: Avoid skin contact. Wear gloves impervious to conditions of use.

Respiratory Protection: If exposure limits are exceeded, NIOSH approved respiratory protection should be worn.

Page 74: Hazard Communication GHS/GHS 2012

9. Physical and Chemical PropertiesFlashpoint: 2oC (35oF)Autoignition Temperature: 480oC (896oF)Boiling Point: 77oC (170.6oF) @ 760 mm HgMelting Point: -82oCVapor Pressure: 100.0 mm Hg @ 23oCVapor Density: 1.7; (Air = 1)% Solubility in Water: 10 @ 20ºCPour Point: NAMolecular Formula: MixtureWeight: Mixture

Page 75: Hazard Communication GHS/GHS 2012

9. Physical and Chemical Properties (Continued)Odor/Appearance: Clear, colorless liquid with mild, pungent odor.Lower Flammability Limit: >3.00%Upper Flammability Limit: <15.00%Specific Gravity: 0.82g/ml @ 20oC% Volatile: 100Evaporation Rate (Water=1): 5(Butyl Acetate =1)Viscosity: 0.3 cP @ 25oCOctanol/Water Partition Coefficient: log Kow: 0.5

pH: 7, 8% aqueous solutionMolecular Weight: Mixture

Page 76: Hazard Communication GHS/GHS 2012

10. Stability and ReactivityStability/Incompatibility: Incompatible with ammonia, amines, bromine, strong bases and strong acids.

Hazardous Reactions/Decomposition Products: Thermal decomposition products may include oxides of carbon and nitrogen.

Page 77: Hazard Communication GHS/GHS 2012

11. Toxicological InformationSigns and Symptoms of Overexposure: Eye and nasal irritation, headache, dizziness, nausea, vomiting, heart palpitations, difficulty breathing, cyanosis, tremors, weakness, itching or burning of the skin.

Acute Effects:

Eye Contact: may cause severe conjunctival irritation and corneal damage.

Skin Contact: may cause reddening, blistering or burns with permanent damage. Harmful if absorbed through the skin. May cause allergic skin reaction.

Inhalation: may cause severe irritation with possible lung damage (pulmonary edema).

Ingestion: may cause severe gastrointestinal burns.

Target Organ Effects: May cause gastrointestinal (oral), respiratory tract, nervous system and blood effects based on experimental animal data. May cause cardiovascular system and liver effects.

Page 78: Hazard Communication GHS/GHS 2012

11. Toxicological Information (Continued)Chronic Effects: based on experimental animal data, may cause changes to genetic material; adverse effects on the developing fetus or on reproduction at doses that were toxic to the mother. Methyltoxy is classified by IARC as group 2B and by NTP as reasonably anticipated to be a human carcinogen. OSHA regulates Methyltoxy as a potential carcinogen.

Medical Conditions Aggravated by Exposure: preexisting diseases of the respiratory tract, nervous system, cardiovascular system, liver or gastrointestinal tract.

Acute Toxicity Values

Oral LD50 (Rat) = 100 mg/kg

Dermal LD50 (Rabbit) = 225-300 mg/kg

Inhalation LC50 (Rat) = 200 ppm/4 hr., 1100 ppm vapor/1 hr

Page 79: Hazard Communication GHS/GHS 2012

12. Ecological InformationLC50 (Fathead Minnows) = 9 mg/L/96 hr.

EC50 (Daphnia) = 8.6 mg/L/48 hr.

Bioaccumulation is not expected to be significant.

This product is readily biodegradable.

Page 80: Hazard Communication GHS/GHS 2012

13. Disposal ConsiderationsAs sold, this product, when discarded or disposed of, is a hazardous waste according to Federal regulations (40 CFR 261). It is listed as Hazardous Waste Number Z000, listed due to its toxicity.

The transportation, storage, treatment and disposal of this waste material must be conducted in compliance with 40 CFR 262, 263, 264, 268 and 270. Disposal can occur only in properly permitted facilities. Refer to state and local requirements for any additional requirements, as these may be different from Federal laws and regulations.

Chemical additions, processing or otherwise altering this material may make waste management information presented in the SDS incomplete, inaccurate or otherwise inappropriate.

Page 81: Hazard Communication GHS/GHS 2012

14. Transport InformationU.S. Department of Transportation (DOT)

Proper Shipping Name: Methyltoxy

Hazard Class: 3, 6.1

UN/NA Number: UN0000

Packing Group: PG 2

Labels Required: Flammable Liquid and Toxic

International Maritime Organization (IMDG)

Proper Shipping Name: Methyltoxy

Hazard Class: 3 Subsidiary 6.1

UN/NA Number: UN0000

Packing Group: PG 2

Labels Required: Flammable Liquid and Toxic

Page 82: Hazard Communication GHS/GHS 2012

15. Regulatory InformationU.S. Federal Regulations

Comprehensive Environmental Response and Liability Act of 1980 (CERCLA):Toxic Substances Control Act (TSCA):Clean Water Act (CWA): Clean Air Act (CAA): Superfund Amendments and Reauthorization Act (SARA) Title III Information:SARA Section 311/312 (40 CFR 370) Hazard Categories:

Immediate Hazard: XDelayed Hazard: XFire Hazard: X

Pressure Hazard:Reactivity Hazard:Component    CAS Number    Maximum %Methyltoxy       000-00-0       80

State Regulations

California: Component    CAS Number    Maximum %Methyltoxy       000-00-0       80

Page 83: Hazard Communication GHS/GHS 2012

15. Regulatory Information

International Regulations

Canadian Environmental Protection Act:Canadian Workplace Hazardous Materials Information System (WHMIS):European Inventory of Existing Chemicals (EINECS):

EU Classification: Phrases:R11: Highly flammable.R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.R37/38: Irritating to respiratory system and skin.R41: Risk of serious damage to eyes.

Page 84: Hazard Communication GHS/GHS 2012

16. Other InformationNational Fire Protection Association (NFPA) Ratings: This information is intended solely for the use of individuals trained in the NFPA system.

Health: 3Flammability: 3Reactivity: 0

Revision Indicator: New SDS

Disclaimer: The information contained herein is accurate to the best of our knowledge. ABC Inc. makes no warranty of any kind, express or implied, concerning the safe use of this material in your process or in combination with other substances.

Page 85: Hazard Communication GHS/GHS 2012

1. Identity

2. Physical and chemical characteristics

3. Physical hazards

4. Health hazards

5. Primary Routes of Entry

6. OSHA/ACGIH PELs

OLD HCS 1994 MSDS ELEMENTS

Page 86: Hazard Communication GHS/GHS 2012

7. National Toxicology Program on Carcinogens

8. Safe handling precautions

9. Control measures

10. Emergency procedures

11. Date of SDS preparation

12. Name, address, telephone number

Page 87: Hazard Communication GHS/GHS 2012

Employees must be informed of:

•The requirements of the HCS 2012;

•Any operations in their work area where hazardous chemicals are present; and,

•The location and availability of the written hazard communication program, including the required list(s) of hazardous chemicals, and SDSs required by the HCS.

Information and Training

Page 88: Hazard Communication GHS/GHS 2012

Employee training must include at least:

•Methods and observations that may be used to detect the presence or release of a hazardous chemical in the work area (such as monitoring conducted by the employer, continuous monitoring devices, visual appearance or odor of hazardous chemicals when being released, etc.);

•The physical, health hazards, simple asphyxiation, combustible dust, and pyrophoric gas hazards, as well as hazards not otherwise classified, of the chemicals in the work area;

•The measures employees can take to protect themselves from these hazards.

•The details of the hazard communication program developed by the employer.

Information and Training

Page 89: Hazard Communication GHS/GHS 2012

Required training elements:

• An overview of the requirements• Chemicals present in their workplace• Location and availability of program• Physical and health effects…• Methods and observation techniques…• How to reduce or prevent exposure…• Steps taken to reduce or prevent exposure…• Safety emergency procedures to follow…• How to read labels and review SDSs…

Page 90: Hazard Communication GHS/GHS 2012

Using the SDS and label the instructor has made available, each group will prepare to deliver a brief training program to the class.

Focus your training on these three areas:

• Health Effects

• Personal Protective Equipment

• Emergency Procedures

Page 91: Hazard Communication GHS/GHS 2012

OSHA Inspections

What the compliance officer will inspect:

The written program

Who’s responsible?

Proper labeling

Safety Data Sheets

Information and Training

“What are the procedures for...”

Page 92: Hazard Communication GHS/GHS 2012

Trade Secrets

The manufacturer, distributor cannot withhold chemical identity from health professional in an emergency.

Page 93: Hazard Communication GHS/GHS 2012

GET STARTED!

1. Become familiar with the standard.2. Identify responsible staff. 3. Identify hazardous chemicals in your workplace.4. Prepare and implement a written plan.5. Prepare and conduct a training program.6. Monitor the program. Revise as needed.

Page 94: Hazard Communication GHS/GHS 2012

Before you run…

Complete evaluations