gtc tour of coffeyville resources nitrogen fertilizer … flow diagram nh 3 product asu ammonia...
TRANSCRIPT
GTC Tourofof
Coffeyville ResourcesNitrogen Fertilizer
FacilityFacilityJune 17, 2008
Coolwater Demonstration Project
Coffeyville Nitrogen Plant
Block Flow Diagram NH3 Product
ASU Ammonia Synthesis UAN Plant
Nitrogen
Hydrogen
UAN Product
CO2 PurificationPressure Swing
Absorption (PSA)
Hydrogen
CO2 Vent
S CO Shif / Acid
Oxygen
RecycleRaw H2
Syn-gasScrubbing
CO Shift/Gas Cooling
Acid Gas Removal
(Selexol)Quench Gasifier
Coke GrindingSlurry Preparation
SulfurRecovery
H2S
Block Flow Diagram NH3 ProductLinde
ASU Ammonia Synthesis UAN Plant
Nitrogen
Hydrogen
UAN Product
CO2 PurificationPressure Swing
Absorption (PSA)
Hydrogen
CO2 Vent
S CO Shif / Acid
Oxygen
RecycleRaw H2
Syn-gasScrubbing
CO Shift/Gas Cooling
Acid Gas Removal
(Selexol)Quench Gasifier
Coke GrindingSlurry Preparation
SulfurRecovery
H2S
Linde Air Separation Unit
Block Flow Diagram NH3 Product
ASU Ammonia Synthesis UAN Plant
Nitrogen
Hydrogen
UAN Product
CO2 PurificationPressure Swing
Absorption (PSA)
Hydrogen
CO2 Vent
S CO Shif / Acid
Oxygen
RecycleRaw H2
Syn-gasScrubbing
CO Shift/Gas Cooling
Acid Gas Removal
(Selexol)Quench Gasifier
Sl
Coke GrindingSlurry Preparation
SulfurRecovery
H2SSlag
RefineryRefineryCokers
Coke Handling
Coke Conveyor and Rod Mill Structure
Main and Spare Gasifier Structures
M iMainGasifierVessel
Slag
Block Flow Diagram NH3 Product
ASU Ammonia Synthesis UAN Plant
Nitrogen
Hydrogen
UAN Product
CO2 PurificationPressure Swing
Absorption (PSA)
Hydrogen
CO2 Vent
S CO Shif / Acid
Oxygen
RecycleRaw H2
Syn-gasScrubbing
CO Shift/Gas Cooling
Acid Gas Removal
(Selexol)Quench Gasifier
Coke GrindingSlurry Preparation
SulfurRecovery
H2S
Block Flow Diagram NH3 Product
ASU Ammonia Synthesis UAN Plant
Nitrogen
Hydrogen
UAN Product
CO2 PurificationPressure Swing
Absorption (PSA)
Hydrogen
CO2 Vent
S CO Shif / Acid
Oxygen
RecycleRaw H2 CO2
Syn-gasScrubbing
CO Shift/Gas Cooling
Acid Gas Removal
(Selexol)Quench Gasifier
Coke GrindingSlurry Preparation
SulfurRecovery
H2S
COCO2Absorber
H2S Concentratorand Stripper
Block Flow Diagram NH3 Product
ASU Ammonia Synthesis UAN Plant
Nitrogen
Hydrogen
UAN Product
CO2 PurificationPressure Swing
Absorption (PSA)
Hydrogen
CO2 Vent
S CO Shif / Acid
Oxygen
RecycleRaw H2
Syn-gasScrubbing
CO Shift/Gas Cooling
Acid Gas Removal
(Selexol)Quench Gasifier
Tessenderlo Kerley
Coke GrindingSlurry Preparation
SulfurRecovery
H2S
Tessenderlo Kerley
Block Flow Diagram NH3 Product
ASU Ammonia Synthesis UAN Plant
Nitrogen
Hydrogen
UAN Product
CO2
CO2 PurificationPressure Swing
Absorption (PSA)
Hydrogen
CO2 Vent
CO2
S CO Shif / Acid
Oxygen
RecycleRaw H2
CO2
Syn-gasScrubbing
CO Shift/Gas Cooling
Acid Gas Removal
(Selexol)Quench Gasifier
Coke GrindingSlurry Preparation
SulfurRecovery
H2S
Block Flow Diagram NH3 Product
ASU Ammonia Synthesis UAN Plant
Nitrogen
Hydrogen
UAN Product
CO2 PurificationPressure Swing
Absorption (PSA)
Hydrogen
CO2 Vent
S CO Shif / Acid
Oxygen
RecycleRaw H2
Syn-gasScrubbing
CO Shift/Gas Cooling
Acid Gas Removal
(Selexol)Quench Gasifier
Coke GrindingSlurry Preparation
SulfurRecovery
H2S
PSAPSAVessels
Block Flow Diagram NH3Product
ASU Ammonia Synthesis UAN Plant
Nitrogen
Hydrogen
UAN Product
CO2 PurificationPressure Swing
Absorption (PSA)
Hydrogen
CO2 Vent
S CO Shif / Acid
Oxygen
RecycleRaw H2
Syn-gasScrubbing
CO Shift/Gas Cooling
Acid Gas Removal
(Selexol)Quench Gasifier
Coke GrindingSlurry Preparation
SulfurRecovery
H2S
Ammonia Synthesis and Refrigeration
Syn-gas and Refrigeration Compressors
Ammonia Storage Tank
Block Flow Diagram NH3 Product
ASU Ammonia Synthesis UAN Plant
Nitrogen
Hydrogen
UAN Product
CO2
Ammonia
CO2 PurificationPressure Swing
Absorption (PSA)
Hydrogen
CO2 Vent
CO2
S CO Shif / Acid
Oxygen
RecycleRaw H2
Syn-gasScrubbing
CO Shift/Gas Cooling
Acid Gas Removal
(Selexol)Quench Gasifier
Coke GrindingSlurry Preparation
SulfurRecovery
H2S
UAN Plant
UAN Rail Loading Facility
Operators at work in the control room
Nitrogen Fertilizer 101
Nitrogen Fertilizer 101
• Nitrogen is a basic nutrient for all plants
Nitrogen Fertilizer 101
• Nitrogen is a basic nutrient for all plants• It does not build up in the soil, so it needs to p
be applied each growing season
Nitrogen Fertilizer 101
• Nitrogen is a basic nutrient for all plants.• It does not build up in the soil, so it needs to p
be applied each growing season.• Ammonia is the basic building block for nearly
all fertilizers that contain nitrogen.
Nitrogen Fertilizer 101
• Nitrogen is a basic nutrient for all plants.• It does not build up in the soil, so it needs to p
be applied each growing season.• Ammonia is the basic building block for nearly
all fertilizers that contain nitrogen.• In 2005, the US produced 8.7 million tons of
ammonia.
Nitrogen Fertilizer 101
• Nitrogen is a basic nutrient for all plants.• It does not build up in the soil, so it needs to p
be applied each growing season.• Ammonia is the basic building block for nearly
all fertilizers that contain nitrogen.• In 2005, the US produced 8.7 million tons of
ammonia.• In 2005, the US consumed 14.7 million tons
f iof ammonia.
Nitrogen Fertilizer 101
• Nitrogen is a basic nutrient for all plants.• It does not build up in the soil, so it needs to p
be applied each growing season.• Ammonia is the basic building block for nearly
all fertilizers that contain nitrogen.• In 2005, the US produced 8.7 million tons of
ammonia.• In 2005, the US consumed 14.7 million tons
f iof ammonia.• Nearly all was produced using natural gas!
Nitrogen Fertilizer 102
Nitrogen Fertilizer 102A i h b ild ( l )Ammonia cash cost build-up (example)
Gas Cost $10 per mmBtux Gas consumption 32 mmBtu per short ton
= Gas cost $320 per short ton+ other production costs $20 per ton
= Total Cash Cost $340 per ton
Nitrogen Fertilizer Market
• Global market
Nitrogen Fertilizer Market
• Global marketA i d i t d i t th US• Ammonia and urea are imported into the US
Nitrogen Fertilizer Market
• Global marketA i d i t d i t th US• Ammonia and urea are imported into the US
• US Production is in decline primarily due to l tlow cost gas overseas
Nitrogen Fertilizer Market
• Global marketA i d i t d i t th US• Ammonia and urea are imported into the US
• US Production is in decline primarily due to l tlow cost gas overseas
• Due to infrastructure limitations (pipelines, rail cars) domestic plants continue to operatecars), domestic plants continue to operate when the demand (and price) support it.
Nitrogen Fertilizer Market
• Global marketA i d i t d i t th US• Ammonia and urea are imported into the US
• US Production is in decline primarily due to l tlow cost gas overseas
• Due to infrastructure limitations (pipelines, rail cars) domestic plants continue to operatecars), domestic plants continue to operate when the demand (and price) support it.
• US Demand is set by acres of corn (primarily)• US Demand is set by acres of corn (primarily) and wheat (to a lesser extent).
The future looks bright for Gasification!