fretting wear of low current electrical contacts ... · 1 0.1 fretting wear of low current...
TRANSCRIPT
1
0.1
Fretting wear of low current electrical contacts:
quantification of electrical endurance
S. Fouvry1, J. Laporte
1, O. Perrinet
1, P. Jedrzejczyk
1,
O. Graton1
1 Ecole Centrale de Lyon, LTDS
Lyon, France
O. Alquier2, J. Sautel
3
2 PSA, Vélizy - France
3 Radiall,Voreppe, France
Abstract— In many industrial applications like automotive,
aeronautics, train but also nuclear energy connectors need to
maintain low stable electrical contact resistance. However, they
are subject to vibrations that cause severe fretting wear damage
which increases the electrical contact resistance and degrades
information transmission. Fretting wear damages can induce
dramatic increase of the direct current Electrical Contact
Resistance (ECR) inducing the connector failure. The purpose of
this paper is to expose a synthesis describing how fretting
loadings but also material properties of coatings can influence
the fretting DC-ECR behavior. The analysis first focuses on
“laboratory” fretting test specifications that must be as
representative as possible of the pin-clip interface and sufficiently
instrumented to measure fretting loading parameters such as
sliding amplitude, normal loading friction energy, and ambient
condition. To compare noble (Au, Ag) and non noble (Sn)
coatings, an ECR endurance variable is introduced so that
N(fretting cycle) = Nc when ∆R> ∆Rc = 4mΩ. This study first
investigates the effect of the sliding condition and the transition
from an infinite ECR endurance under partial slip condition to a
finite endurance above the gross slip transition.
Then focusing on the gross slip finite endurances, different
formulations are introduced to quantify the effect of fretting
sliding amplitude, normal force, material properties but also
coating thickness. Focusing on Ag/Ag interface, this research
demonstrates that the ECR endurance is controlled by the
fretting wear rate of the contact. This investigation also
underlines how the application of sequential large reciprocatings
can increase the fretting ECR endurance through a refilling
process of fretting scar with silver transferred from the outer
part of the lateral reciprocating track.
I. INTRODUCTION
In automotive applications and many other industrial
domains (energy,aviation, etc.), the number of electrical
devices has increased significantly in recent decades. The
safety of systems and people relies on the quality of electrical
connectors. These are, however, subject to vibrations (car
engine, thermal environment) which induce micro-
displacements in the contact. Those movements cause
interface wear and induce debris formation, which increase
electrical contact resistance and degrade information
transmission [1]. Extensive studies have been done to
determine the mechanisms of electrical contact damage. Many
researchers have worked on this issue [2-8]. Silver coatings
were the focus of thorough investigations by Kassman-
Rudolphi et al. [3] and Song et al. [9]. Park et al. performed
[10] extensive researches on the influence of environmental
loads on the electrical resistance. Ren et al. investigated the
influence of temperature [11] and fretting corrosion on contact
resistance. Silver-plated electrical contacts were extensively
studied in [3, 12-16]. The influence of corrosive atmosphere
was addressed by Chudowsky et al. [13] whereas Imrell [14]
addressed the influence of coating thickness. Most of these
researches focused on material or tribo-chemical aspects of the
problem. The purpose of this paper is to synthesize the
tribological approach developed at LTDS describing the ECR
evolution using a friction energy approach to quantify the
fretting wear of electrical contacts.
Fig. 1. Illustration of the fretting damages and related increase of electrical
contact resistance in a pin-clip contact of connector subjected to vibrations.
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II. EXPERIMENTAL STATEGY
Low current connectors are usually qualified using
normative vibration tests. Due to inertial effects, oscillating
displacements (i.e. fretting) are occurring between pin and clip
contacts promoting fretting wear and potentially electrical
contact resistance (ECR) failures. The larger the acceleration,
the larger the relative displacement, the faster the surface wear
and finally the shorter the ECR endurance. This technical
approach is however limited in many aspects. For instance,
due to accessibility aspects, the real sliding conditions
operating between the pin and clip remain unknown whereas
the normal force is only estimated from elastic computations
of the clip bending shape.
To better investigate the effects of fretting damages,
alternative laboratory “fretting” test systems were designed to
be representative of low current pin-clip interfaces and
sufficiently instrumented to measure fretting loadings such as
sliding amplitude, normal force, friction energy, and ambient
conditions (relative humidity & temperature).
A. Contact configuration
The most common laboratory contact configuration is the
sphere/plane geometry, firstly because it approximates well
the pin-clip contact and secondly because it avoids
experimental dispersions induced by contact misalignments.
The sphere/plane geometry is presently established using a
crossed cylinder configuration with a cylinder radius r = 2.3
mm (i.e. equivalent to a r =2.3 mm radius sphere/plane
contact) (Fig. 2) [15]. The cylindrical shape of specimens was
obtained by a stamping process of CuSn4 or CuZn37 thin
rectangular plates. Then a electrodepositing process was
applied to coat the Cu alloy substrate with a 2µm nickel
interlayer to limit copper diffusion. Then various Ag, Au or Sn
top layers were deposited using an equivalent
electrodepositing process.
It is interesting to note that by translating the two
cylindrical specimens, more than 20 fretting tests could be
performed on a single specimen pair. Hence less than 8
specimens are required to investigate a given contact
configuration. This reduces the experimental cost and above
all the coating discrepancy. Except specific cases, the given
investigation focuses on homogeneous interfaces which
implies the application of similar specimens.
B. Fretting Test
As illustrated in Fig. 2, the low current LTDS electrical
fretting test involves a crossed cylinder contact configuration.
Fig. 2 : Illustration of LTDS fretting test and crossed cylinders contact
configuration
One specimen holder is fixed on the bottom frame and the
other adapted on the top moving harm connected to the
fretting actuator. For high frequencies and small
displacements electromagnetic shaker are usually preferred.
For larger reciprocating slidings, linear electromagnetic
actuators can be considered. Recent systems associate these
two actuator technologies [16]. The test system needs to be
instrumented to measure the relative displacement (δ) between
the specimens (laser sensor), and to measure the tangential
force (Q) induced by the contact sliding. The normal load is
applied using a dead mass. Note that flexure stripes are
usually adopted to guarantee that the normal load is well
transmitted via the contact and not supported by the fretting
frame. Most of this research work was undertaken keeping
constant the normal load P=3 N. This normal load was
optimized in relationship with the cylinder radius (r = 2.3 mm)
to reproduce the contact configuration of a standard pin-clip
automotive contact configuration. Assuming Hertzian
hypothesis, it leads to a maximum pressure pmax,H = 780 MPa
and a contact radius aH=43 µm. Tests were performed in a
close chamber to control relative humidity and temperature.
The present synthesis focuses on mechanical aspects and
therefore all the experiments were done in dry conditions
(RH= 10%) and at ambient temperature (T=25°C).
3
Fig. 3 : Illustration of the fretting loop, definition of quantitative variables,
plotting of fretting loops versus N (log scale) leads to the Fretting Log
representation.
A key aspect to investigate fretting wear damages is the
plotting of the so-called “fretting loop” related to the evolution
of the tangential force versus the applied displacement (Fig.
3). From the fretting loop, the tangential force amplitude (Q*),
the displacement amplitude (δ*), the friction energy (Ed) (i.e.
area of the fretting loop) but also the residual displacement
(δ0) measured on the δ axis when the tangential force is zero
are extracted [17]. The coefficient of friction is then given by:
*µ Q P=
(1)
If the forces parameters (P & Q) are effectively applied in the
contact, the real displacement operating inside the contact is
more difficult to establish. In fact, a significant part of the
measured displacement is accommodated by the tangential
deformation of the frame. The measured displacement (δ) can
be defined as the sum of the real contact displacement (δC) and
the apparatus accommodation components (δA). Assuming an
elastic response of the test system, δA can be expressed as the
product of the operating tangential force by the test apparatus
compliance (CA) [17]:
( ) ( ) ( ) ( ) ( )C A C At t t t C Q tδ δ δ δ= + = + ×
(2)
Hence for a given displacement amplitude δ*, different contact
slidings are occurring depending on the fretting setup used.
This explains why it is so difficult to compare experimental
fretting data in literature. To palliate such discrepancy, one
solution consists in considering the residual displacement
measured when Q=0.
0 ,0 ( 0)C Qδ δ δ= = =
(3)
Indeed when the tangential force is zero, there is no more
signature of the test. Any test performed imposing a given δ0 is
comparable regardless the test apparatus. Besides δ0 provides
a rather fine estimation of the real sliding amplitude operating
inside the interface [17]. Indeed δ0 can be expressed as the
sum of the effective interfacial sliding amplitude (δS) and a
plastic shear amplitude occurring inside the interface (δp) [18].
Plastic accommodation can be approximated by multiplying
the cyclic shear strain amplitude (γp) by the plastic coating
thickness (e).
0p
S p S eδ δ δ δ γ= + = + ×
(4)
Most of the studied coatings are very thin (less few microns).
Hence, plastic shear accommodation can be neglected and the
effective contact sliding amplitude ( Sδ ) approximated by the
residual displacement [17, 19]:
0Sδ δ≈
(5)
Depending on the scientific objectives, the present
experimental investigation was performed monitoring either δ*
for the sliding condition analysis and δ0 for the gross slip
fretting wear rate investigation.
C. DC electrical contact resistance measurements
To measure the electrical contact resistance during the test, a
four wire method was applied [17] (Fig. 2). A current source
applies I= 0.005A with a 10V voltage compliance, whereas a
µvoltmeter system measures the contact voltage with a 0.01µV
resolution. This system enables electrical resistance from 10-6
to 103
to be measured. The lifetime of the contact was
assumed equal to the number of sliding cycles to reach the
threshold value of the electrical resistance, ∆Rc=0.004 (Fig.
1&4).
III. PLAIN FRETTING SLIDING
A. Influence of partial and gross slip sliding conditions
As illustrated in figure 4a, the ECR resistance highly depends
on the applied displacement amplitude. Former investigations
demonstrated that as long as the fretting contact is running
under small partial slip condition, inducing closed fretting
loop, low and stable ECR are maintained, inducing an infinite
ECR endurance. Partial slip condition maintains an inner
undamaged stick zone providing direct metal/metal
interactions and a good electrical conduction [8].
4
(a)
(b)
Fig. 4. (a) Displacement amplitude and sliding condition on ECR
evolutions; (b) evolution of the ECR as a function of the displacement
amplitude at 10 000 fretting cycles (Sn/Sn (e= 1.3 µm); P= 3N, f= 30 Hz,
RH=10%, T=25°C).
However, when the displacement amplitude overpasses the
gross slip transition (δt), a full sliding is operating over the
whole fretted interface inducing a quadratic fretting loop
shape. This promotes a generalized surface wear, the
formation of nonconductive oxide debris and finally a decay
of ECR (Fig. 4b). As developed by Hannel et al, the fretting
sliding transition can be considered as a mechanical criterion
discriminating finite and infinite electrical contact endurance
[8]:
*
*
Nc infinite
Nc finite
t
t
δ δδ δ
< ⇒ →≥ ⇒ →
(6)
B. ECR endurance chart
The larger the sliding amplitude the faster the surface wear,
the faster the ECR rising and therefore the shorter the ECR
endurance (Fig. 5). To quantify the ECR endurance,
endurance charts have been introduced plotting the evolution
of Nc versus the applied displacement amplitude. Asymptotic
evolutions were observed and formalized using a simple
power law function [15]:
*( )=
− nt
NcNc δ
δ δ
(7)
With Ncδ the ECR endurance when δ*-δt = 1µm and n the
absolute value of the ln(Nc)-ln(δ*-δt) decreasing slope.
Fig. 5. Endurance curves of Sn/Sn, Ag/Ag and Au/Au fretting interfaces
(e=1.3 µm, P= 3N, f= 30 Hz, RH=10%, T=25°C). Comparison between
experiments and power law function.
The ECR endurance relationship is simplified using the
residual displacement variable according [15, 20]:
* 0 * then t tif δ δ δ δ δ> = −
(8)
and therefore :
0( )=
n
NcNc δ
δ
(9)
Fig. 5 suggests that this power law function is able to describe
the ECR endurance whatever the nature of the coating. Non-
noble Sn coating promotes a very fast formation of
nonconductive oxide debris and consequently very short ECR
endurances. In contrast, noble coatings like Au or Ag require
first to eliminate the noble material from the fretted interface
before generating oxide debris from fretting wear of non noble
Ni sub-layer and Cu alloy substrate. This surface wear delay
provides longer ECR endurances.
C. ECR endurance ratio chart
To quantify the comparison between surface treatments (i.e.
coating X versus Y), an endurance ratio KX/Y= Nc(X)/Nc(Y) is
considered and plotted versus the applied displacement
amplitude [15].
5
Fig. 6. Comparison of electrical coating endurance performances (Ag versus
Sn) as a function of the applied displacement amplitude.
Fig. 6 shows that for small partial slip conditions the ratio is
equal to 1 according that the two contacts are running under
partial slip condition en therefore the ECR endurance is
infinite whatever the nature of the coating. When the two
interfaces reach the gross slip condition (δ*> δt(Sn)= δt(Ag)),
the higher endurance of silver coating induces a very high
value of KAg/Sn . However the endurance ratio decreases
asymptotically with the increase of the sliding amplitude.
Indeed the larger the sliding amplitude, the faster the surface
wear and finally the smaller the endurance difference between
the two tribo-systems.
D. ECR response of heterogeneous interfaces
Heterogeneous interfaces can be observed in industrial
applications. Experimental investigations suggest that if the
nature of materials is similar (i.e. noble/noble or non-
noble/noble) the ECR endurance of heterogeneous contact
corresponds to the averaged value of the corresponding
homogeneous interfaces (i.e. NcAu/Ag ≈ (NcAu/Au + NcAg/Ag.)/2).
In contrast noble/non noble interfaces display a very different
response (Fig. 7) [21]. For instance the ECR endurance of a
Ag/Sn interface is 10 times larger than the corresponding
Sn/Sn contact but more than 30 times smaller than the Ag/Ag
interface. Deeper investigations demonstrate that the
heterogeneous contact still obeys a noble/noble fretting wear
response: the ECR failure is reached when most of the
available noble material is worn out from the fretting
interface. However, it demonstrates that the presence of a Sn
layer by forming very abrasive Sn oxides sharply increases the
fretting wear rate of the silver layer and in return drastically
reduces the ECR endurance.
Fig. 7. Evolution of ECR endurance (e = 2µm, Nc :∆R>∆Rth= 4mΩ, I =5
mA, δg = +/- 9 µm, RH=10%, P=3N, T=25 °C, f=30Hz) as a function of
residual displacement amplitude (i.e sliding amplitude): comparison between
Sn/Sn, Ag/Ag homogeneous interfaces and heterogeneous Ag/Sn interface
[21].
E. ECR response & interface chemical composition
SEM and EDS analysis of Ag/Ag fretting scars at Nc display
a typical “U-shape” distribution of silver concentration (Fig;
8) [12, 15].
Fig. 8. Ag, O, Ni and Cu concentration (At.%) profiles in the fretting scar of a
lower sample (Ag/Ag, e=2µm, P=3N, f=30Hz, T=25°C, RH=10%, δg=±9µm,
Nc=97,500 cycles).
6
If on lateral sides the Ag concentration is still high, the silver
concentration remaining in the inner part is very poor. A
reverse distribution is observed for the oxygen concentration
which is maximal in the inner part of the fretting scar. This
observation implies that the ECR-failure may be related to the
chemical composition of the central part of the fretted area
where the maximum contact pressures inducing electrical
junctions are operating. Hence a chemical concentration
criteria consisting in computing the averaged atomic
composition in an inner square area with a diagonal equal to
20% of the final fretting scar diameter (ϕf) is introduced (Fig.
9). Interrupted tests clearly underline that the rising of ECR
corresponds to a progressive elimination of silver material and
an increase of oxide debris. The analysis of various coating
thicknesses and fretting sliding conditions showed that the
ECR failure could be related to a chemical composition
threshold [12, 15]:
N= Nc if [Ag]at%< 5% and [O]at% > 45% (10)
Fig. 9. O and Ag concentrations (At.%) in the fretting scar at ECR failure
(Ag/Ag, e=2µm, P=3N, f=30Hz, T=25°C, RH=10%, δ0=±4µm to ±16.75µm).
F. Friction energy wear approach
ECR Fretting response of noble coatings is controlled by a
progressive wear process. Many investigations demonstrated
that the fretting wear rate can be formalized using a friction
energy description [22]. The main assumption of this theory is
that the increment of wear depth (h) per fretting fretting cycle
may be related to the local friction energy density imputed in
the fretted interface per fretting cycle (φ). Assuming that worn
interfaces promote flat pressure and therefore flat friction
energy profiles, it justifies a mean friction energy density
approximation:
f
f
Ed
Aϕ = (11)
With Ed the friction energy dissipated during a fretting cycle
and Af the final contact area measured at the contact opening.
Fig. 10a compares the ECR evolution obtained for different
sliding amplitudes and various normal loads. The single
sliding amplitude description displays a rather large
discrepancy. For each normal load a given set of Ncδ and n
parameters needs to be applied to predict the ECR endurance.
In contrast, the friction energy formulation leads to a single
endurance master curve [12]. This confirms a posteriori the
potential interest of predicting the fretting ECR-endurance
using the more general friction energy density approach.
Again the ECR endurance can be formalized using a power
law function:
( )=
f
NcNc
ϕβϕ
(12)
With Ncφ the ECR endurance when φf=1 J/m² and β the
absolute value of the decreasing slope of ln(Nc)-ln(φf) curve.
(a)
(b)
Fig. 10. (a) evolution of ECR endurance versus sliding amplitude (i.e.
residual displacement δ0 for 6 different normal forces (1N to 6N) (Ag/Ag,
e=2µm, f=30Hz, T=25°C, RH=10%) with Ncδ(6N)=24.105 cycles, n(6N) =2.22,
Ncδ(1N)=14.107 cycles and n(1N) =2.58; (b) related evolution of ECR
endurance versus mean friction energy density (identification of a single
master curve).
The integration of fretting loop to compute the friction energy
is long and fastidious. Friction energy can be extrapolated
from fretting sliding parameters according to [17] :
04Ed Pµ δ= × × × (13)
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Alternatively the contact area extension is well described
using a power law function of normal force [12]:
0m
fA A P= ×
(14)
Combining equations (12), (13) and (14), a basic explicit
expression of fretting ECR endurance is derived [12]:
0
(1 )0
1
4 −
= × × × ×
m
ANc Nc
P
β
ϕ βδ µ
(15)
Although a very large spectrum of normal loads and sliding
amplitudes was investigated, Fig. 11 confirms the stability of
the proposal to formalize the studied Ag/Ag ECR fretting
endurance [12].
Fig. 11. Comparison between experimental and predicted ECR endurances as
a function of sliding amplitude (δ0), normal force (P) and coating thickness (e)
(Ag/Ag, f=30Hz, T=25°C, RH=10%) (eref= 2 µm, Ncφ=8.1012 cycles, β=
2.583, A0=72,575 µm² and m=0.256).
The few parameters required by the model (A0, β and m) can
be easily extracted from a limited number of fretting tests. Of
course these variables will depend on the contact geometry
and material properties and need to be related to the studied
interface.
G. Influence of coating thickness
The noble coating ECR response is controlled by surface wear
processes. This suggests that the thicker the coating layer, the
longer the ECR endurance [12,20,23,24]. Different
investigations performed on gold and silver coatings confirm
this tendency and showed that the increase of Nc versus
coating thickness (e) is not linear but fits a power law function
with exponent values between 2.5 and 3 [12]. Hence for the
studied Ag/Ag interface (P= 3N, f= 30 Hz, δ0 = ±9 µm) it was
found:
w
ref ref
Nc e
Nc e
=
(16)
with w= 2.85 and Ncref= 97,5000 cycles the ECR endurance
when eref =2 µm.
Fig. 12. Evolution of ECR endurance versus silver coating thickness (Ag/Ag,
f=30Hz, T=25°C, RH=10%, P =3N, δ0 = 9µm), eref =2 µm,
Ncref(e=eref)=97,500 cycles.
Several hypotheses can be considered to explain the rather
high value of w exponent. First it may be stated that the ECR
failure (Nc) is occurring for a fretting wear volume threshold
(Vc) which itself is proportional to the available silver volume
in the fretted interface(V[Ag]). This implies the following
relationships:
2[ ]∝ ∝ ×Ag fVc V e a
(17)
Where af is the contact radius at the ECR failure.
The thicker the coating layer, the larger the wear volume
required to reach the ECR failure and therefore the larger
contact radius af . Fig. 13 confirms a significant increase of af
with the coating thickness.
Fig. 13. Evolution of final contact radius at ECR failure as a function of
coating thickness (Ag/Ag, f=30Hz, T=25°C, RH=10%, P =3N, δ0 = 9µm).
A power law function can be considered so that :
,1= × hf f µma a e
(18)
8
with af,1µm= 125µm (i.e. the extrapolated contact radius when
e= 1µm) and h = 0.43.
This implies
(1 2 ) 1.86[ ] =
+∝ hAgVc e e
(19)
The predicted value of w exponent (1.86) is smaller than the
experimental one (w=2.85). A residual contribution needs to
be considered so that:
(1 2 ) = − + ×w hκ
(20)
Which is found around 1≈κ .
This residual contribution can be related to the plastic shear
accommodation of the interface. Indeed, thicker silver
coatings increase the plastic accommodation of pδ and
consequently decrease the effective sliding amplitude δS
providing that δ0 is kept constant (equation (4)) [19]. A
reduction of the effective sliding amplitude by reducing the
friction dissipation decreases the wear rate and therefore
increases the ECR endurance. Deeper FEM investigations
involving elastoplastic analyses are expected to quantify this
plastic strain description of the interface. Such investigation
will require accurate estimation of cyclic silver plastic
hardening which unfortunately is still not available.
This coating thickness description can be re-injected in the
friction energy description to predict the ECR failure coupling
equation (15) and (16) [12].
0
(1 )0
1
4 −
= × × × × ×
w
mref
A eNc Nc
eP
β
ϕ βδ µ
(21)
Again, Fig.11 confirms the stability of this approach. Many
improvements could be considered to take into account the
effect of ambient condition, material properties, contact
geometry, etc. However this investigation suggests that in
using a simple friction energy density description, the ECR
fretting endurance can be predicted or at least formalized.
IV. COMPLEX FRETTING-RECIPROCATING SLIDING
Real connectors undergo fretting but also macro sliding
induced by intermittent plug-in and un-plug-in procedures.
Hence, there is a key interest to evaluate how the combined
application of fretting and macro sliding can influence the
ECR endurance [16, 25]. To investigate this aspect a constant
fretting sliding condition (P= 3N, f= 30 Hz, δ0 = ±9µm, T=
25°C, RH=10%) was considered and the effect of intermittent
macro sliding applied every Nf fretting cycle, with a total
stroke D from 250 µm to 1500 µm at a constant vR=8.3µm/s
reciprocating sliding speed was investigated. The analysis
demonstrated that the periodic application of macro sliding
sharply increases the ECR endurance (Fig. 14). Surface
analysis suggests that this increase of ECR lifetime is induced
by a transfer process of silver material from the outer
reciprocating track toward the fretting scar. ECR failure is
observed when fretting but also outer reciprocating tracks are
becoming very poor in silver material:
Nc when in fretting scar: [Ag]at%<5% and [O]at%>45%
& in reciprocating track [Ag]at%<5% (22)
Fig. 14. Evolution of ECR as a function of fretting cycles (P=3N, RH=10%,
δ0,ref = ±9µm, T=25°C): comparison between plain fretting and fretting +
reciprocating sliding (D=1mm, Nf =10,000 fretting cycles), related SEM
observations of upper fretting scar at ECR failure.
On the other hand, fretting ECR failure occurs when no more
additional silver can be transferred from the reciprocating
track. Fretting endurance under combined fretting-
reciprocating slidings depends on the reciprocating stroke (D)
but also on the number of fretting cycle (Nf) applied between
macro sliding. Indeed, if Nf period is too long, the ECR failure
can be reached before the successive macro sliding refills the
fretting scar with transferred silver material. This tendency
was illustrated by a stair case decreasing evolution of Nc
versus Nf [16].
For D=1mm the transition was established at Nf,tr = 4.3 104
cycles. This stair case evolution can be expressed using a
sigmoid function [16]:
9
( )max (0)
(0)
,1 /f f tr
Nc NcNc Nc
N Nα
− = + +
(23)
Fig. 15. Evolution of Nc fretting ECR endurance related to the complex
fretting-reciprocating sliding sequence (Ag/Ag, e=2µm, P=3N, RH=10%,
T=25°C, f=30Hz, δ0= ±9µm and D =1mm at v=8.3µm/s) as a function of
fretting cycles per block (Nf).
With Nc(0) the minimum endurance related to the plain fretting
condition (NR=0), Ncmax the maximum endurance related to a
full silver transfer condition. For the studied Ag/Ag interface
it was found Nc(0)=105 cycles and Ncmax= 2.10
5 cycles,
whereas the best fitting of Nc evolution was found for α =
3.53. The full silver transfer condition inducing the highest
Ncmax endurance plateau was observed for the shortest fretting
period so that Nf < Nf_ft ≈ 2.104 cycles. It corresponds to a
limited number of reciprocating sliding NR_ft =10 above which
all the silver material present in the reciprocating track is
effectively transferred in the fretting scar before the ECR
failure. Focusing on a full transfer condition (Nf = 104 cycles <
Nf,ft , so NR> NR,ft) we investigate the evolution of the fretting
endurance Nc (total number of fretting cycle before ECR
failure) as a function the the reciprocating stroke D. An
unexpected non monotonic evolution is observed (Fig. 16).
The ECR endurance decreases from the plain fretting
condition (D=0) Nc(0) down to the minimum value Nc(ϕf)
observed when the reciprocating stroke is equivalent to the
diameter of the fretting scar (i.e. D= fφ ). Then a quasi linear
increase is observed. Such typical evolution can be formalized
expressing the ECR endurance as the ratio between the silver
worn volume (Vc) at ECR failure divided by the fretting wear
volume rate per fretting cycle ( fV& ):
VcNc
V=
&
(24)
To formulate the ECR endurance prediction both Vc and fV&
must be explicited.
Fig. 16. Evolution of fretting ECR endurance (Nc = total fretting cycles before
ECR failure ∆R> ∆Rth=4mΩ) (P=3N, RH=10%, T=25°C, f=30Hz, δ*g,ref = ±
9µm and Nf =10,000 cycles) as a function of reciprocating sliding stroke
(250µm ⩽ D ⩽ 1500µm at v=8.3µm/s), comparison between experiment and
silver wear rate modeling.
The silver worn volume at ECR failure can be expressed as a k
proportion of the available silver volume in fretting and
reciprocating fretted interfaces (V [Ag] ) (Fig. 17) [16]:
[ ]2
f
Ag fVc k V k e Dπ φ
φ×
= × = × × × +
(25)
Where fφ
is the diameter of the fretting scar measured at the
ECR failure.
Fig. 17. Illustration of the estimation of available silver volume involved in
the fretting-reciprocating domains.
The experimental analysis gives k≈ 0.94 which infers that
most of the available sliver volume is worn out at the ECR
failure.
Alternatively, the silver wear rate can be approximated with:
VcV
Nc=&
(25)
10
The non-monotonous evolution of Nc in Fig. 16 suggests that
the fretting wear rate is not constant but depends on the
reciprocating stroke (Fig. 18).
To illustrate such an evolution the fretting wear rates obtained
for 3 key reciprocating strokes are computed :
Plain fretting (D=0) : (0)
(0)(0)
=&Vc
VNc
Maximum wear rate (D= fφ ) : ( )
( )
( )
=& f
f
f
VcV
Nc
φφ
φ
Large stroke (D=Dref=1000µm) : ( )
( )( )
=& ref
refref
VcV
Nc (26)
Using experimental results we found (0)V& = 4 µm3/cycle ,
( )fV φ& = 26 µm
3/cycle and ( )refV& = 7 µm
3/cycle.
Hence two fretting wear regimes can be observed depending
on the reciprocating stroke (Fig. 18):
D< fφ : (0) ( ) (0)( ) ( / ) SD
f
nfV V V V Dφ φ= + − ×& & & &
D> fφ : ( ) ( ) ( )( ) ( / ) LD
f
nref ref fV V V V Dφ φ= + − ×& & & &
(27)
With nSD and nLD respectively the small and large stroke
exponents driving the effect of D regarding fretting wear rate.
Fig. 18. Evolution of the mean fretting wear rate at ECR failure versus the
applied reciprocating stroke D ((P=3N, RH=10%, T=25°C, f=30Hz, δ0,ref = ±
9µm and Nf =10,000 cycles).
Combining Eq. 24 and 26, the ECR endurance can then be
expressed by :
D< fφ :
(0) ( ) (0)2( ) ( / )
× × × = × +
+ − × & & & SD
f
f f
nf
k eNc D
V V V Dφ
φ π φφ
D> fφ :
( ) ( ) ( )2( ) ( / )
× × × = × +
+ − × & & & LD
f
f f
nref ref f
k eNc D
V V V Dφ
φ π φφ
(28)
The best fitting regarding ECR endurance was found with nSD
=2 and nLD=-3. Fig. 16 confirms a very good correlation with
the experiments. This confirms the interest of the proposed
wear rate description. ECR endurance predictions however
depend on the silver wear rate which is characterized by a
non-monotonous evolution (Fig. 18). The wear rate rising
during the first domain D< fφ may be explained by the third
body theory: the sequential introduction of macro sliding by
ejecting wear debris outside the fretting scar increases the
silver fretting wear rate. However, above fφ , a constant wear
rate should be expected providing that all the reciprocating
slidings were performed at a constant reciprocating sliding
speed (vR=8.3µm/s). The asymptotic decrease above fφ is
still unclear. Again, considering third body theory, it may be
considered that because the worn fretting area is becoming
larger when D is increased due to longer Nc endurance, wear
debris remain longer in the fretting interface inducing thicker
third body layer. The fretting wear rate is therefore decreasing
according that a larger proportion of the friction energy is
consumed by the third body layer rather than to be involved in
the degradation of silver coating. Deeper investigations need
to be undertaken to quantify this aspect thus to provide a
physical demonstration of discontinuous fretting wear rate
evolution versus the reciprocating stroke.
V. CONLUSION
This synthesis displayed a thorough analysis of fretting wear
effects on ECR and ECR endurance response. The following
points have been underlined.
- The ECR endurance (Nc) depends on the displacement
amplitude (δ*).
If the contact is running under partial slip (δ*< δt), Nc is
infinite.
If the contact is running under part gross slip (δ*> δt), Nc is
finite whatever the nature of the material.
Focusing on gross slip condition it was concluded:
Plain fretting condition:
- The ECR endurance is better formalised using the so-called
“residual displacement” (δ0) parameter to consider the
effective sliding amplitude imposed in the interface.
- Non noble coatings display very short ECR endurance due to
the immediate formation of oxide debris. The ECR endurance
of noble coatings is longer due to the delay required to fully
eliminate the presence of noble material like Au or Ag from
the fretting interface.
- Heterogeneous noble/non noble ECR interfaces display
rather short ECR endurances according that non noble
materials like Sn generate abrasive oxides which accelerate
the wear rate of noble coating.
- ECR failure is occurring when most of the noble material is
worn out from the contact and replaced by an oxide debris
induced by the fretting wear of non noble sublayers. A
11
chemical composition criterion of inner fretting scars was
established: Nc when [Ag]at%<5% and [O]at%>45%.
- Noble coating ECR endurance which is fretting wear rate
dependent can be rationalised as an inverse power law
function of friction energy density (i.e. 1∝ fNc βϕ ). For the
particular case of constant normal force condition, this general
formulation can be simplified to a simple inverse evolution of
sliding amplitude (i.e. 01∝ nNc δ ).
- Noble coating ECR endurance displays an exponential
increase versus coating thickness (i.e. ∝ wNc e with w>2.5).
The large w exponent may be explained by the lateral
extension of fretting scar (i.e. available silver volume 1.9
[ ] ∝AgVc e ) and an increase of the plastic accommodation
within the interface which tends to decrease the effective
sliding.
- Simple explicit formulations are introduced to quantify the
ECR endurance using a limited number of parameters which
can be identified using a restricted number of experimental
fretting test.
Complex Fretting & Reciprocating sliding condition:
- The application of intermittent macro reciprocating slidings
increases the global ECR fretting endurance. This increase of
the ECR endurance was explained by a transfer process of
silver from the outer reciprocating track toward the fretting
scar. Taking into account the fact that the fretting wear rate
depends on the reciprocating stroke, a simple model was
introduced to predict the fretting ECR endurance under
complex fretting-reciprocating slidings.
The synthesis demonstrates that the ECR of low current noble
fretting contacts can be quantified using very basic
formulation taking into account the friction energy dissipated
in the interface. Future developments are now required to
better integrate the material properties and contact geometry.
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