fresh properties of limestone calcined clay cement (lc3
TRANSCRIPT
www.LC3.ch
Fresh properties of Limestone Calcined
Clay Cement (LC3) pastes
Sendhil Vigneshwar Dhanapal & Prakash Nanthagopalan
IIT Bombay
India
Outline of the presentation
» Introduction
» Material Properties
» Results and discussions
» Conclusions
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Introduction
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» Limestone Calcined Clay Cement (LC3)
» 50% clinker, 31 % clay and 15 % limestone and 4 % gypsum
» Objective
» To investigate the fresh properties of the LC3 pastes
» Methodology
Optimization of Superplasticiser dosage Slump retention Setting
time
Materials Used
» Cement used
» LC3
» Ordinary Portland Cement (OPC) -53 grade
» Portland Pozzolana Cement (PPC) - 70% OPC + 30 % Fly ash (by mass)
» SP used
» Ligno Sulfonate based (Ligno)
» Sulfonated Napathalene Formaldehyde (SNF)
» Poly Carboxylic Ether (PCE)
» Potable water
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Physical properties of cement
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Material
characteristics
LC3 OPC PPC
Specific
Gravity
2.90 3.15 3.10
D50 (µm) 4.30 14.25 18.76
Physical properties of cement
Consistency test
Initial and final setting time
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Cement Consistency %
LC3 31
OPC 30
PPC 29
Cement Initial setting time (min.) Final setting time (min.)
LC3 90 180
OPC 90 190
PPC 120 180
ESEM images
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Oxide Composition of cement
LC3 OPC PPC
CaO (%) 40.05 58.58 39.95
Sio2 (%) 25.44 23.59 28.68
Al2O3 (%) 26.33 8.21 22.09
Fe2o3 (%) 3.49 3.64 3.54
K2O (%) 0.16 0.21 0.30
Na2O (%) 1.94 2.46 1.77
MgO (%) 1.80 2.36 1.821
P2O5 (%) 0.10 0.30 0.21
Tio2 (%) 0.59 0.24 0.59
BaO (%) 0.00 0.35 0.16
Mn2o3 (%) 0.04 0.04 0.045
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Physical properties of Superplasticizers
LIGNO SNF PCE
Specific gravity 1.243 1.237 1.103
Physical
appearance
Dark brown
liquid
Brown liquid Colorless liquid
Solid content 43.49 42.34 50.55
pH 6.07 8.92 6.50
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Test Combinations
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Cement SP w/c ratio
LC3 Ligno 0.25
OPC SNF 0.35
PPC PCE 0.45
0.55
Optimization of Superplasticizer dosage
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Optimization of SP dosage – Mini Slump test
38.1 mm
19 mm
57
mm
38
.1 m
m
15.9 mm22.2 mm
3.2 mm 6.4 mm
Step Activity Duration (s) Speed*
1 Dry mixing of cement and fly ash 120 1
2 Add 80 % total water 60 1
3 Clean the side walls 15
4 Add 20 % water + SP 60 1
5 Clean side walls 15
6 Final mixing 120 2
*Speed 1 – Agitator = 140 ± 5 rpm and attachment = 62 ± 5 rpmSpeed 2 – Agitator = 285 ± 10 rpm and attachment = 125 ± 10 rpm
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Optimization of SP - Ligno
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Optimization of SP - SNF
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Optimization of SP - PCE
SP w/c LC3 OPC PPC
Ligno
0.25 * * *
0.35 1.52 1.39 0.86
0.45 1.04 0.65 0.70
0.55 0.87 0.43 0.10
SNF
0.25 * * *
0.35 0.93 0.76 1.06
0.45 0.76 0.42 0.68
0.55 0.59 0.30 0.34
PCE
0.25 2.02 2.02 1.00
0.35 1.01 0.35 0.60
0.45 0.35 0.20 0.10
0.55 0.30 0.10 0.10 16
Optimized dosage of SP
Slump retention studies
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Slump retention - Ligno
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Slump retention - SNF
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Slump retention- PCE
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Setting time studies
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Setting time with Ligno
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Setting time using SNF
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Setting time using PCE
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Conclusion
» LC3 requires high SP dosage than the OPC and PPC this can be attributed
to the high surface area and the Shape of the cement particles
» LC3 has higher slump retention capacity compared to OPC and PPC
» Setting time of LC3 – Delayed initial setting time.
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Thank you
LC3 project
Sendhil Vigneshwar Dhanapal
Civil Engineering Department
Structural Division
Indian Institute of Technology Bombay , India – 400076
Email: [email protected]