foranext lithium ion battery salts lifsi litdi · 2020-01-25 · organic chemistry pilot shared...
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LITHIUM SALTS AND BATTERYELECTROLYTES DEVELOPMENT/
Ultra-pure chemicals for lithium ion batteries
YOUR KEY PARTNER.
Ultra-pure chemicals designed to fit all voltage cathode/anode systems
Pure lithium salts or formulated electrolyte solutions at your convenience
High voltage corrosion resistance along with battery lifetime and calendar life
Synergies with the other Arkema battery products
FORANEXT® KEY TECHNOLOGIES
LiFSI and LiTDI are known as the next blockbuster lithium salts but their performance is highly related to their purity. Due to a smart industrial process, Arkema’s ultra-pure LiFSI and LiTDI present outstanding performance.
LiTDI increases lifetime at high temperature: SEI stabilization, HF and water scavengers and cathode protective film.
LiFSI
Ioni
c co
nduc
tivity
(mS/
cm)
0
2.75
5.5
8.25
11
LiPF6 LiTFSI LiClO4 LiBF4
Salts in EC/EMC 3/7
CONDUCTIVITY +10%COMPARED TO BEST SOLUTIONS
Disc
harg
e C
apac
ity (%
)
Cycle number0
0
20
40
60
80
100
200 400 600
Pouch cell NMC (111)/Graphite Charge/Discharge 1C at 45°C
Reference
AT LEAST +25% SAVED CAPACITYDURING SEI FORMATION
LiFSI
LiTDI
BATTERY ELECTROLYTE SOLUTIONS.
Arkema developed two new lithium salts with very high purity industrial process to improve overall battery performance for multiple cathode and anode technologies.
Extended lifetime additive Improved SEI stability High chemical stability versus acids, water Better electrochemical stability (4.7V) Improved aluminum passivation Enabling synergies with LiFSI
High ionic conductivity High electrochemical stability (>5V) Better thermal stability Main salt or additive value Best salt for lithium metal technology
LiFSI LiTDI
A designer of materials and innovative solutions, Arkema shapes materials and creates new uses that accelerate customer performance. Our balanced business portfolio spans high-performance materials, industrial specialties
and coating solutions. Our globally recognized brands are ranked among the leaders in the markets we serve. Reporting annual sales of €7.5 billion, we employ approximately 20,000 people worldwide and operate in close
to 50 countries. We are committed to active engagement with all our stakeholders. Our research centers in North America, France and Asia concentrate on advances in bio-based products, new energies, water management,
electronic solutions, lightweight materials and design, home efficiency and insulation. www.arkema.com
The statements Disclaimers - Please consult Arkema’s disclaimer regarding the use of Arkema’s products on:http://www.arkema.com/en/products/product-safety/disclaimer/index.html
Headquarters: Arkema France420, rue d’Estienne d’Orves
92705 Colombes Cedex – FranceTel: +33 (0)1 49 00 80 80
Fax: +33 (0)1 49 00 83 96arkema.com
Pierre-Bénite, FRHF fluorination laboratory and pilot plantCatalyst testing facilityOrganic chemistry pilotShared analytics and application lab
Saint-Auban, FR
Changshu, PRCShared analytical laboratory
The leading fluorine specialist
World class laboratories for fluorine and halogen chemistry research. Comprehensive analytical resources to support synthesis/process R&D. Over 30 years’ experience with anhydrous HF-based, catalyzed chemistry.
R&D
Factory
King of Prussia, PAFluorination laboratoryChemical synthesis laboratoryShared analytics and application lab
Calvert City, KY
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Arkema Inc. (Americas)900 First Avenue
King of Prussia, PA 19406Tel.: +1 610 205 7000Fax: +1 610 205 7497
[email protected]://www.forane.com/en/specialties/