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    Outline:

    Climate and PollutionKinds of Pollution

    Sources

    Transport Effects of Air Pollution

    Air Pollution Control

    2

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    Climate and Air Pollution

    Over the past 20years, developedcountries have

    made progress inimproving airquality.

    Unfortunately, airquality in thedeveloping worldhas been getting

    worse. 3

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    Primary and Secondary

    Pollutants,

    Natural and Human

    Air pollutants occur either as

    gases or particulate matter Primary air pollutants: emitted directly into

    the air

    Secondary pollutants: reactions betweenprimary pollutants and atmospheric

    compounds

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    Sulfur dioxide- acid rain, health damage,

    visibility reduction Nitrogen oxides- acid rain, eutrophication,

    growth of weedy species

    Carbon monoxide- inhibited respiration

    Leadandmercury- neurological damage

    Chlorofluorocarbons- ozone depletion

    Particulate matter- lung damage, cancer

    Volatile organic compounds(isoprenes,

    terpenes, methane, & benzene,

    chloroform, etc) oxidized to CO,

    CO2 in the atmosphere; carcinogens?

    Major Air Pollutants:Problems

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    Los Angeles

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    8TheInternational Geosphere-Biosphere Programme (IGBP) is a research program thatstudies the phenomenon of Global Change

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    Indoor Air Pollution

    Smoking - diseasesrelated to smoking

    responsible for 20% of

    deaths in the U.S.

    In less-developed

    countries, poorly

    ventilated heating and

    cooking fires representthe greatest source of

    indoor air pollution.

    The Silent Killer

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    Indoor PollutantSources

    Indoor air pollutants comefrom:

    underground diffusion,

    combustion, and

    chemical emissions.

    Most indoor air pollution canbe reduced by increasingbuilding ventilations.

    Radon gas (a radioactive decayproduct of uranium) is the mostharmful indoor pollutant whenfound in high concentrations.

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    Long range transport

    Stratospheric ozone depletion

    Montreal Protocol - 1987

    Interactions Between Climate

    Processes and Air Pollution

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    Jet Streams & Jet Streaks

    http://ww2010.atmos.uiuc.edu/(Gh)/guides/mtr/cyc/upa/jet.rxml

    http://sd.znet.com/~aringler/jet.htm

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    Long range transport of pollutants

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    Circumpolar

    winds

    transport air

    pollution from

    heavily

    industrialized

    regions to the

    Arctic, where

    high levels of

    smog

    accumulate. 15

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    Ozone Depletion

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    Stratospheric Ozone Destruction byChlorine Atoms and UV Radiation

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    Production of chloroflurocarbons

    (CFCs)

    Montreal Protocol passed in 1987

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    http://en.wikipedia.org/wiki/File:Future_ozone_layer_concentrations.jpg

    NASA projections of stratospheric ozoneconcentrations if chlorofluorocarbons had not

    been banned.From the historical

    record we know thattotal column ozone

    values of less than 220

    Dobson Units were notobserved prior to 1979.

    http://upload.wikimedia.org/wikipedia/commons/b/b4/Future_ozone_layer_concentrations.jpg
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    Effects of Air Pollution

    Human health Plant pathology

    Visibility reduction

    Acid deposition

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    Ecosystem damage caused by sulfur dioxideemissions and acid rain. (near Sudbury Ontario)

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    Acid Precipitation, 2000

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    Frazier fir stand on Mount Mitchell in the Appalachian Mountains

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    Acid Rainfall affects:

    Plants - directly(weakens or killsplants)

    Soils - directly(leaching of basecationseg, Ca & Mg)

    Plants - indirectly(lower soil nutrients,insects attack weak trees)

    Frazier fir stand on Mount Mitchell in the Appalachian Mountainsof North Carolina

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    Air Pollution Control

    Early approach:

    Dilution is the solution to pollution

    Particulate removal - air filters

    Sulfur removal - scrubbers

    Nitrogen oxide reduction - catalytic converters

    Hydrocarbon controls - afterburners

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    Automobile Emission Control System

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    CLEAN AIR LEGISLATION

    Clean Air Act (1963)- First national air

    pollution control. (usingincentives, egfederal grants to states)

    Clean Air Act (1970)rewrote original Act. Identified critical pollutants

    Established ambient air quality standards.

    Primary Standards - Human health

    Secondary Standards - Materials, environment,

    aesthetic and comfort.27

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    Conventional Pollutants US Clean Air Act designated seven major

    (conventional or criteria) pollutants forwhich maximum ambient air levels aremandated.

    Sulfur DioxideCarbon Monoxide

    Particulates

    HydrocarbonsNitrogen Oxides

    Photochemical Oxidants

    Lead 28

    Clean Air Act

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    Clean Air Act

    Revision (1990)- Included provision for:

    Acid Rain

    Urban Smog

    Toxic Air Pollutants

    Ozone Protection

    Marketing Pollution Rights

    Fugitive emissions of volatile organics

    Ambient ozone, soot, and dust.

    NOx emissions

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    Cl Ai A t

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    Clean Air Act Clear Skies ( 2002)didnt passmarket-based

    approach, tried to eliminate new source review of 1977

    which was pollution controls on old equip as well as new

    equip

    Clean Air Interstate Rule (CAIR2005)

    Eliminated new source review,

    Set emission standards for SO2, NOx, PM

    Depends upon cap-and-trade (can buy credits from

    nonpolluting) OK nationally but can create hot spots of pollution locally

    Interstate rule because pollution can drift across state

    borders affecting ambient pollution levels30

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    Current Conditions and

    Future ProspectsDeveloped vs.Developing

    Countries

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    Tend to be much higher in large cities in

    developing countries than in developedcountries

    Total Suspended Particulates (TSP)

    CURRENT AND FUTURE

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    CURRENT AND FUTURE

    CONDITIONS

    In the United States, air quality has

    improved dramatically in the last decade in

    terms of major large-volume pollutants.

    Cities where pollution is largely from trafficstill have serious air quality problems.

    Major metropolitan areas of many

    developing countries are growing atexplosive rates, and environmental quality

    is very poor.

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    S G d N U S T d

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    Some Good News: U.S. Trends

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    U.S. emissions

    of six major air

    pollutants in1970 compared

    with 2002.

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    Summary:

    Atmosphere and Climate

    Climate Change

    El Nino

    Human Causes

    Climate and PollutionKinds of Pollution

    Sources

    Transport Effects of Air Pollution

    Air Pollution Control

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