fast, accurate environmental testing...gc columns fast, accurate environmental testing using zebron...
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GC Columns
Fast, Accurate Environmental Testing
Using Zebron GC ColumnsFeaturing
• Pesticides• Diesel Range Organics• Semivolatiles• Dioxane• And more…..
www.phenomenex.com/environmental
2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 min
Column: Zebron™ ZB-SemiVolatiles
Dimensions: 30 meter x 0.25 mm x 0.25 µm
Part No.: 7HG-G027-11
Injection: Split 10:1 @ 280 °C, 1 µL
Recommended Liner: Zebron PLUS Single Taper with Wool, 4 mm ID
Liner Part No.: AG2-0A11-05 (for Agilent® Systems)
Septum: AG0-4697 (PhenoRed™-400)
Inlet Seal: AG0-8620 (Easy Seals™)
Carrier Gas: Helium @ 1.4 mL/min (constant flow)
Oven Program: 40 °C for 0.5 min to 260 °C @ 40 °C/min to 295 °C @ 6 °C/min to 325 °C @ 25 °C/min for 2 min
Detector: MSD @ 340 °C; 45 – 450 amu
Sample: Analytes are 25 ppm in dichloromethane
Ap
p ID
205
82
Column: Zebron ZB-SemiVolatiles
Dimensions: 30 meter x 0.25 mm x 0.25 µm
Part No.: 7HG-G027-11
Injection: Splitless @ 250 °C, 1 µL
Recommended Liner: Zebron PLUS Single Taper with Wool, 4 mm ID
Liner Part No.: AG2-0A11-05 (for Agilent Systems)
Septum: AG0-4697 (PhenoRed-400)
Inlet Seal: AG0-8620 (Easy Seals)
Carrier Gas: Helium @ 1.6 mL/min (constant flow)
Oven Program: 40 °C for 0.66 min to 260°C @ 30 °C/min to 295 °C @ 6 °C/min to 325 °C @ 25 °C/min for 2 min
Detector: MSD @ 300 °C; 40-500 amu
Waste Water Matrix Extraction
3 4 5 6 7 8 9 10 11 12 13 14 15 16 min
Standard Curve at 25 µg/mL
3 4 5 6 7 8 9 10 11 12 13 14 15 16 min
Rapid and accurate chromatography
137 Analytes in 16 mins
TN-2039
Ap
p ID
230
75A
pp
ID 2
3071
See entire analyte list and technical note at www.phenomenex.com/search
Phenomenex l WEB: www.phenomenex.com
Semi-Volatile Organic Compounds
Bases, Acids, and Neutrals by GC-MS
A) Zebron™ ZB-CLPesticides-1
B) Zebron ZB-CLPesticides-2
12
3
4
5
6 7
8 9 1011 12 13 14 1516
17 18
19
2021 22
0 2 4 6 8 10 min
0 2 4 6 8 10 min
1 2
3
4
56
7 89
1011
1213
141516
1718 19
20
21
22
Column: As listed
Dimensions: A) 30 meter x 0.32 mm x 0.32 µmB) 30 meter x 0.32 mm x 0.25 µm
Part No.: A) 7HM-G028-51B) 7HM-G029-11
Injection: Splitless @ 250 °C, 1 µL
Recommended Liner: Zebron PLUS Single Taper with Wool, 4 mm ID
Liner Part No.: AG2-0A11-05 (for Agilent® Systems)
Septum: AG0-4697 (PhenoRed™-400)
Sample: Analytes are 100 ng/mL in hexane
1. 2,4,5,6-TCMX (Surr) 2. a-BHC 3. g-BHC 4. b-BHC 5. d-BHC 6. Heptachlor 7. Aldrin 8. Heptachlor epoxide 9. trans-Chlordane 10. cis-Chlordane 11. Endosulfan I
12. 4,4’-DDE13. Dieldrin14. Endrin15. 4,4’-DDD16. Endosulfan II17. 4,4’-DDT18. Endrin aldehyde19. Methoxychlor20. Endosulfan sulfate21. Endrin ketone22. Decachlorobiphenyl (Surr)
Ap
p ID
241
25
Tap Water Extracted Ion Chromatogram at 25 ng/mL
Column: Zebron ZB-624
Dimensions: 30 meter x 0.25 mm x 1.4 µm
Part No.: 7HG-G005-27
Guard Column: 5 m Z-Guard™ (7AG-G000-00-GZ0)
Injection: Splitless @ 200 °C (hold 0.5 min), 2.0 µL
Ap
p ID
233
73A
pp
ID 2
3374
Ap
p ID
241
25
Recommended Liner: Zebron PLUS Single Taper Z-Liner™, 4 mm ID
Liner Part No.: AG2-0A13-05 (for Agilent Systems)
Septum: AG0-4697 (PhenoRed-400)
Inlet Seal: AG0-8620 (Easy Seals)
Carrier Gas: Helium @ 1.5 mL/min (constant flow)
Oven Program: 30 °C for 1 min to 90 °C @ 20 °C/min to 250 °C @ 50 °C/min
Detector: MSD @ 250 °C
Sample: 1. THF-d82. 1,4-dioxane-d83. 1,4-dioxane
Inlet Seal: AG0-8620 (Easy Seals™)
Carrier Gas: Hydrogen @ 3.5 mL/min (constant flow)
Oven Program: 85 °C for 0.5 min to 195 °C @ 45 °C/min for 3 min to 330 °C @ 30 °C/min
Detector: ECD @ 330 °C
1
2
3
4.2 4.4 4.6 4.8 5.0 5.2 5.4 5.6 5.8 6.0 6.2 6.4 6.6 6.8 7.0
4.2 4.4 4.6 4.8 5.0 5.2 5.4 5.6 5.8 6.0 6.2 6.4 6.6 6.8 7.0
4.2 4.4 4.6 4.8 5.0 5.2 5.4 5.6 5.8 6.0 6.2 6.4 6.6 6.8 7.0
Phenomenex l WEB: www.phenomenex.com
Chlorinated Pesticides using Hydrogen
1,4-Dioxane by GC-MS
Diesel Fuel Hydrocarbons
Diesel Range Organics (DROs) by GC
0 2
12
4 6 8 10 12 min 0 2 4 6 8 10 12 14 min
1
2
Column: Zebron ZB-5HT Inferno™ ZB-1HT InfernoDimensions: 15 meter x 0.32 mm x 0.10 μm 15 meter x 0.32 mm x 0.25 μm
Part No.: 7EM-G015-02 7EM-G014-11
Injection: On-Column @ 63 °C, 0.1 μL Splitless @ 300 °C, 20 μL
Carrier Gas: Helium @ 2.7 mL/min (constant flow) Helium @ 2 mL/min (constant flow)
Oven Program : 60 °C to 375 °C at 25 °C/min 50 °C for 2 min to 320 °C @ 30 °C/min for 5 min
Detector: FID @ 400 °C FID @ 330 °C
Sample: Diesel Fuel was 200 ppm in Dichloromethane with Internal Standards at 50 ppm
1. Decane2. Tetracontane
Ap
p ID
161
47
Ap
p ID
181
53
Multi-Residue Pesticides by GC-MS
Ap
p ID
161
84
Column: Zebron™ ZB-MultiResidue™-1
Dimensions: 30 meter x 0.25 mm x 0.25 µm
Part No.: 7HG-G016-11
Injection: Splitless @ 260 °C, 1 µL
Recommended Liner: Zebron PLUS Single Taper with Wool, 4 mm ID
Liner Part No.: AG2-0A11-05 (for Agilent® Systems)
Septum: AG0-4697 (PhenoRed™-400)
Inlet Seal: AG0-8620 (Easy Seals™)
Carrier Gas: Helium @ 0.9 mL/min (constant flow)
Oven Program: 80 °C for 0.5 min to 150 °C @ 10 °C/min to 240 °C @ 4 °C/min to 320 °C @ 15 °C/min for 3 min
Detector: MSD @ 320 °C; 45-400 amu
Sample: Analytes are 1 ppm in dichloromethane
Recommended Liner: Zebron PLUS Single Taper, 4 mm ID
Liner Part No.: AG2-0A10-05
Septum: AG0-4696 (PhenoRed-400)
Inlet Seal: AG0-8620 (Easy Seals)
8 10 12 14 16 18 20 22 24 26 28 30 32 34
4
13-15
12
6-78
10
9 11
53
21
17
min
16
57
55
88
89
96
9798
99100101
102103
104105
108
107
106 109 112110,11190
91
92,93
94,95
5654
53
14 16 18 min 22 24 min
44-45
84
46-47
36,37 41-43 61 80-81
64-66
63
6059 62 67
68 7058
69 75 7985
71-74
77,7876 82
86 87
83
39
5052
49
51
48
20
21 24 25
26
273031
32
33
34
35
40
38
29
28
22
19
18
23
Zebron ZB-5HT Inferno Zebron ZB-1HT Inferno
TN-2021See entire analyte list and technical note at www.phenomenex.com/search
Phenomenex l WEB: www.phenomenex.com
More GC columns, kits, and accessories available at
www.phenomenex.com/GC
Essentials Inferno™ Plus Unlimited
Please contact your Phenomenex representative for additional products and assistance.
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4977
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Phenomenex l WEB: www.phenomenex.com
Drinking WaterTrihalomethanes by GC/MS with Selected Ion Monitoring (SIM) •Volatile Halogenated Organics by Purge & Trap GC/PID/ELCD •Volatile Aromatics and Unsaturated Organics by Purge & Trap GC •1,2-Dibromoethane (EDB), 1,2-Dibromo-3-chloropropane (DBCP), and 1,2,3-Trichloropropane (123TCP) by GC •Organohalide Pesticides & Aroclors by GC/ECD • •Nitrogen & Phosphorus Containing Pesticides by GC/NPD •Chlorinated Pesticides by GC/ECD •Ethylene Thiourea (ETU) by GC/NPD •2, 3, 7, 8-Tetrachlorodibenzo-p-dioxin by GC/HRMS •Chlorinated Acids by Liquid-Liquid Extraction, Derivatization and GC/ECD •Nitrosamines by Solid Phase Extraction (SPE) and GC/MS/MS with Large Volume injection •1,4-Dioxane by Solid Phase Extraction (SPE) and GC/MS with Selected Ion Monitoring (SIM) •Triazine Pesticides and their Degradates by GC/MS •Purgeable Organic Compounds by GC/MS •Semi-volatile Organic Chemicals by Solid Phase Extraction (SPE) and GC/MS •Phenols by Solid Phase Extraction (SPE) and GC/MS •Explosives and Related Compounds by Solid Phase Extraction (SPE) and GC/MS •Endothall by Aqueous Derivatization, Liquid-Solid Extraction, and GC/ECD •Chlorinated Solvents & Disinfection Byproducts by Liquid-Liquid Extraction and GC/ECD • •Haloacetic Acids and Dalapon by Liquid-Liquid Extraction, Derivatization, and GC/ECD •Carbonyl Compounds by Pentafluorobenzylhydroxylamine Derivatization and GC/ECD •
Solid WasteHalogenated Volatile Organics by GC/ELCD •Nonhalogenated Organics by GC •Aromatic Volatile Organics by GC/PID •Aromatic and Halogenated Volatiles by GC/PID or GC/ELCD •Acrolein and Acrylonitrile by GC/FID •Acrylamide by GC/ECD •Phenols by GC/ECD or GC/FID •Phthalate Esters by GC/ECD •Organochlorine Pesticides by GC/ECD • •Polychlorinated Biphenyls (PCBs) by GC/ECD • •Nitroaromatics and Cyclic Ketones by GC/ECD or GC/NPD •Explosives by GC/ECD •Polynuclear Aromatic Hydrocarbons by GC/FID •Chlorinated Hydrocarbons by GC/ECD •Aniline and Selected Derivatives by GC/NPD •Organophosphorus Pesticides by GC/FPD or GC/NPD •Chlorinated Herbicides by GC/ECD •Volatile Organic Compounds by GC/MS •Semi-volatile Organic Compounds by GC/MS •Polynuclear Aromatic Hydrocarbons (PAHs ) by SPME and GC/MS with Selected Ion Monitoring (SIM) •Polychlorinated Dibenzo-P-Dioxins (PCDDs) and Polychlorinated Dibenzofurans (PCDFs) By HRGC/LRMS •Polychlorinated Dibenzo-P-Dioxins (PCDDs) and Polychlorinated Dibenzofurans (PCDFs) By HRGC/LRMS •Semi-Volatile Organic Compounds by GC/FT-IR •Bis(2-chloroethyl) Ether and Hydrolysis Products by Direct Aqueous Injection GC/FT-IR •
Waste WaterPurgeable Halocarbons by Purge & Trap GC •Purgeable Aromatics by Purge & Trap GC •Acrolein & Acrylonitrile Purge & Trap GC •Phenols by GC/ECD •Phthalate Esters by GC/ECD •Nitrosamines by GC/NPD •Organochlorine Pesticides and PCBs by GC/ECD •Nitroaromatics & Isophorone by GC/FID and GC/ECD •Polynuclear Aromatic Hydrocarbons by GC/FID •Haloethers by GC/ECD •2,3,7,8-Tetrachlorodibenzo-p-dioxin by GC/MS •Chlorinated Herbicides by GC/ECD •Triazine Herbicides by GC/MS •Organophosphorus Pesticides by GC/MS •Purgeable Volatiles by Purge & Trap GC/MS •Base/Neutral and Acids by GC/MS •Tetra- through Octa-Chlorinated Dioxins and Furans by Isotope Dilution HRGC/HRMS •Polybrominated Diphenyl Esters (PBDEs) by HRGC/HRMS •Organohalide Pesticides, Organophosphorus Pesticides, and Phenoxy-Acid Herbicides by GC •Volatile Organic Compounds by Isotope Dilution GC/MS •Semi-volatile Organic Compounds by Isotope Dilution GC/MS •Organophosphorous Pesticides by GC/FPD •Phenoxy-Acid Herbicides by GC/ECD •Dazomet by GC/NPD •Pharmaceutical Volatile Organic Compounds by Purge & Trap GC or Isotope Dilution GC/MS • •Polychlorinated Biphenyl (PCB) Congeners by HRGC/HRMS •Pharmaceutical Manufacturing Volatile Organic Compounds by GC/FID •
ZB-6
24
ZB-5
0
ZB-W
AX
ZB-C
LPes
ticid
es -1
& 2
ZB-M
ultiR
esid
ue™- 1
& 2
ZB-S
emiV
olat
iles
ZB-1
plus
™
ZB-5
plus
™
ZB-W
AXpl
us™
ZB-5
HT
Select the GC Column for your Environmental Methods
Ordering InformationZebron™ ZB-SemiVolatiles GC ColumnsZB-SemiVolatiles GC ColumnsLength (m) ID (mm) df (µm) Temp. Limits (°C) Part No.
15 0.25 0.25 -60 to 325/350 7EG-G027-1115 0.25 0.50 -60 to 325/350 7EG-G027-1720 0.18 0.18 -60 to 325/350 7FD-G027-0820 0.18 0.36 -60 to 325/350 7FD-G027-5330 0.25 0.25 -60 to 325/350 7HG-G027-1130 0.25 0.50 -60 to 325/350 7HG-G027-1760 0.25 0.25 -60 to 325/350 7KG-G027-11
Zebron ZB-1HT Inferno™ GC Columns
Length (m) ID (mm) df (µm) Temp. Limits (°C) Part No.5 0.53 0.10 -60 to 400/430 7AK-G014-0210 0.32 0.25 -60 to 400/430 7CM-G014-1115 0.25 0.10 -60 to 400/430 7EG-G014-0215 0.25 0.25 -60 to 400/430 7EG-G014-1115 0.32 0.10 -60 to 400/430 7EM-G014-0215 0.32 0.25 -60 to 400/430 7EM-G014-1115 0.53 0.15 -60 to 400 7EK-G014-0520 0.18 0.18 -60 to 400/430 7FD-G014-0830 0.25 0.10 -60 to 400/430 7HG-G014-0230 0.25 0.25 -60 to 400/430 7HG-G014-1130 0.32 0.10 -60 to 400/430 7HM-G014-0230 0.32 0.25 -60 to 400/430 7HM-G014-1130 0.53 0.15 -60 to 400 7HK-G014-05
Zebron ZB-5HT Inferno GC Columns
Length (m) ID (mm) df (µm) Temp. Limits (°C) Part No.15 0.25 0.10 -60 to 400/430 7EG-G015-0215 0.25 0.25 -60 to 400/430 7EG-G015-1115 0.32 0.10 -60 to 400/430 7EM-G015-0215 0.32 0.25 -60 to 400/430 7EM-G015-1115 0.53 0.15 -60 to 400 7EK-G015-0520 0.18 0.18 -60 to 400/430 7FD-G015-0830 0.25 0.10 -60 to 400/430 7HG-G015-0230 0.25 0.25 -60 to 400/430 7HG-G015-1130 0.32 0.10 -60 to 400/430 7HM-G015-0230 0.32 0.25 -60 to 400/430 7HM-G015-1130 0.53 0.15 -60 to 400 7HK-G015-0560 0.25 0.25 -60 to 400/430 7KG-G015-11
Note: If you need a 5 in. cage, simply add a (-B) after the part number, e.g., 7HG-G015-11-B. Some exceptions may apply. Agilent 6850 and some SRI and process GC systems use only 5 in. cages.
Ordering Information
More GC columns, kits, and accessories available at
www.phenomenex.com/GC
If Zebron columns do not provide you with equivalent or better separations as compared to any other GC col-umn of the same phase and comparable dimensions, return the column with comparative data within 45 days for a FULL REFUND!
Zebron™ ZB-CLPesticides GC Columns ZB-CLPesticides-1 GC ColumnsLength (m) ID (mm) df (µm) Temp. Limits (°C) Part No.
30 0.25 0.25 40 to 320/340 7HG-G028-1130 0.32 0.32 40 to 320/340 7HM-G028-5130 0.32 0.50 40 to 320/340 7HM-G028-1730 0.53 0.50 40 to 320/340 7HK-G028-17
ZB-CLPesticides-2 GC ColumnsLength (m) ID (mm) df (µm) Temp. Limits (°C) Part No.
30 0.25 0.20 40 to 320/340 7HG-G029-1030 0.32 0.25 40 to 320/340 7HM-G029-1130 0.32 0.50 40 to 320/340 7HM-G029-1730 0.53 0.42 40 to 320/340 7HK-G029-16
Zebron ZB-MultiResidue™ GC ColumnsZB-MultiResidue-1 GC ColumnsLength (m) ID (mm) df (µm) Temp. Limits (°C) Part No.
20 0.18 0.18 -60 to 320/340 7FD-G016-08
30 0.25 0.25 -60 to 320/340 7HG-G016-11
30 0.32 0.25 -60 to 320/340 7HM-G016-11
30 0.32 0.50 -60 to 320/340 7HM-G016-17
30 0.53 0.50 -60 to 320/340 7HK-G016-17
ZB-MultiResidue-2 GC ColumnsLength (m) ID (mm) df (µm) Temp. Limits (°C) Part No.
30 0.25 0.20 -60 to 320/340 7HG-G017-1030 0.32 0.25 -60 to 320/340 7HM-G017-1130 0.53 0.50 -60 to 320/340 7HK-G017-17
Zebron ZB-624 GC Columns
Length (m) ID (mm) df (µm) Temp. Limits (°C) Part No.20 0.18 1.00 -20 to 260 7FD-G005-22
30 0.25 1.40 -20 to 260 7HG-G005-27
30 0.32 1.80 -20 to 260 7HM-G005-31
30 0.53 3.00 -20 to 260 7HK-G005-36
60 0.25 1.40 -20 to 260 7KG-G005-27
60 0.32 1.80 -20 to 260 7KM-G005-31
60 0.53 3.00 -20 to 260 7KK-G005-36
75 0.53 3.00 -20 to 260 7LK-G005-36
105 0.53 3.00 -20 to 260 7NK-G005-36Note: If you need a 5 in. cage, simply add a (-B) after the part number, e.g., 7HG-G005-27-B. Some exceptions may apply. Agilent 6850 and some SRI and process GC systems use only 5 in. cages.
Fast, Accurate Environmental TestingUsing Zebron GC Columns
www.phenomenex.com/environmental
GC Columns
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4977
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Terms and Conditions Subject to Phenomenex standard terms & conditions, which may be viewed at www.phenomenex.com/TermsandConditions. Trademarks Inferno, MultiResidue, Z-Liner, EasySeals, PhenoRed, 1plus, 5plus, WAXplus, Z-Guard, and Zebron are trademarks of Phenomenex. Agilent is a registered trademark of Agilent Technologies, Inc.© 2017 Phenomenex, Inc. All rights reserved.
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