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UNIVERSIDAD NACIONAL DEL CENTRO DEL PER

FACULTAD DE INGENIERÍA QUÍMICESCUELA ACADÉMICA PROFESIONAL DE INGENIERÍA QUÍMICA AM

PROYECTO DE INVESTIGACIÓNINGENIERÍA DE BIOPROCESOS

2015

DOCENTE:Ms. Gladys Maritza ÁVILA CARHUALLANUI

SEMESTRE: V

INTEGRANTES:INDIGOYEN RAMIRE!HUARINGA YUPANUIPOMA DAMIANDANIELRUI! HERMO!ASOSA RAYMUNDOVELASUE! ALIAGA



TÍTULO

" O#TENCIÓN DE #IOETANOL A PART

CASCARA DE NARAN$A "



O%t&'&r %i(&ta'(l a )artir d& la*as*ara d& )i+a &' ,' )r(*&s(d& -&r&'ta*i/' al*(0/li*a

&dia't& i*r((r1a'is(saccharomyces cerevisiae.

OBJETIVOS

OBJETIVO

GENERAL:



C()r&'d&r la i)(rta'*ia d&l )r(*&

d& -&r&'ta*i/' a'a&r/%i*a )ara la(%t&'*i/' d&l %i(&ta'(l.

R&alizar ,' (d&l( d& -&r&'ta*i/'s&'*illa )ara la (%t&'*i/' d&l %i(&ta'

Darl& ,' 2al(r a1r&1ad( a ',&straat&ria )ria 3)i+a4

D&t&ri'ar ',5ri*a&'t& la *a'tidd& al*(0(l ),r( 6,& s& (%ti&'& l,&1(

la d&stila*i/'.

OBJETIVOSESPECIFICOS:



INTRODUCCIÓN

Las t5*'i*as a*t,al&s d& )r(d,**i/' d& &ta'(l a )artir d& *&r&al&s y *a+a d& az7*ar)r&s&'ta' &l )r(%l&a d& la s&1,ridad ali&'taria. D& i1,al -(ra8 la )r(d,**i/' d&&ta'(l *ar%,ra't& )(r &di( d& &stas at&rias )rias '( 0a ll&'ad( las &9)&*tati2as*(' r&s)&*t( a la disi',*i/' d& 1as&s i'2&r'ad&r(s y d& a,&'t( &' la )r(d,**i/' d&&'&r1:a *(' r&s)&*t( a la 1astada. P(r (tr( lad(8 s&17' Uyaz;' < Gil 3=>>?48 &' &l,'d( s& )r(d,*&' a)r(9iada&'t& @>> ill('&s d& t('&ladas )(r a+( d& r&sid,(ss/lid(s8 l(s *,al&s 1&'&ra' 1ra2&s )r(%l&as8 '( s/l( )(r &l d&t&ri(r( )r(1r&si2( d&l&di( a%i&'t&8 si'( ta%i5' d&sd& &l ),'t( d& 2ista &*('/i*( ),&st( 6,& l(s*(st(s d& r&*(l&**i/'8 tra's)(rt& y dis)(si*i/' B'al s(' *ada 2&z ay(r&s. P(r &st(8 s& &st; i),lsa'd( &l &st,di( d& la )r(d,**i/' d& %i(&ta'(l d& t&r*&ra

1&'&ra*i/'8 &l *,al &s )r(d,*id( a )artir d& %i(asa li1'(*&l,l/si*a r&sid,al8*(),&sta d& a*,&rd( *(' Olss(' < Ha0'Hii1&rdl 3@4 )(r d(s )(l:&r(s d&

*ar%(0idrat(s8 la *&l,l(sa 3?FF>4 y la 0&i*&l,l(sa 3@F=F48 y ,' )(l:&r( -&'/li*(8la li1'i'a 3=>=F4. El %i(&ta'(l d& t&r*&ra 1&'&ra*i/' s& ),&d& (%t&'&r a )artir d& ara%&s 1l,*(sad(s )r(d,*id(s &' la 0idr/lisis d& r&sid,(s li1'(*&l,l/si*(s. U'a d& las)ri'*i)al&s -,&'t&s d& la *,al s& ),&d& (%t&'&r ara%& 1l,*(sad( s(' las *;s*aras d&-r,tas 6,& &' s, 1ra' ay(r:a s(' *('sid&radas %i(asas d&s2al(rizadas. E' lasi'd,strias d&l *&'tr( d&l P&r7 dir&*ta&'t& &' la *i,dad d& H,a'*ay(8 -r,tas *(( la)i+a8 ti&'&' 1ra' i',&'*ia &' &l &r*ad(8 )&r( s,s *;s*aras s(' d&s&*0adas8d&sa)r(2&*0a'd( &l 2al(r 6,& 5stas ti&'&' y ad&;s 6,& &l ,s( d& &st& s,%)r(d,*t(a1r:*(la s& liita a la ali&'ta*i/' d& 1a'ad( %(2i'(. El %i(&ta'(l (%t&'id( )(r-&r&'ta*i/' d& &sta at&ria )ria 6,& *('ti&'&' 0idrat(s d& *ar%('(8 s& ada)ta)arti*,lar&'t& %i&' )ara s,stit,ir a la 1as(li'a &' l(s (t(r&s d& &'*&'did( )(r*0is)a. La )r(d,**i/' d& &ta'(l *(%,sti%l& a )artir d& at&rial li1'(*&l,l/si*( s& 0a

*('2&rtid( &' ,'a alt&r'ati2a i't&r&sa't& &' la ,tiliza*i/' d& &st& ti)( d& r&sid,(s 6,&)(dr:a' a%rir ',&2(s &r*ad(s )ara s, r&2al(riza*i/'. E' la )r(d,**i/' d& %i(&ta'(lartir d& at&rial li '(*&l,l/si*( ti&'&' l, ar 2ari(s r(*&s(s -:si*(s8 ,:i*(s



MARCO TEÓRICO



O#TENCIÓN DE#IOETANOL A PARTIR

DEL PIA

S, )r(y&*t( s& %asa &' (%t&'*i/'

d& %i(&ta'(l a )artir d& la *as*arad& Pi+a8 &' s, )r(y&*t( &lla t(a,'a t&)&rat,ra &'tr& >F> C

)ara la -&r&'ta*i/'8 l,&1( a+ad&las &'zias )ara s, -&r&'ta*i/'y (%t,2( ,' %i(&ta'(l al .. El

tra%a( s& r&aliz( &' la

U'i2&rsidad I'd,strial d& Sa'Ta'da'd&r &l a+( =>@?.

ANTECEDENTES

VA!UE!SUEIRO 8LAURA

ANTECEDENTES:



BIOETANOL:

S& d&'

#i(&ta'(l (%t&'id( a )a-,&'t&s d& %i2&1&tal i&

,1(s ri*(ssa*ar(sa8 )r(ri*(s &' ala )artir at&rial&s



#i(*ar%,ra't& L:6,id( )r(d,*id( )(r -&r&'ta*i/' d& l(saz7*ar&s *('t&'id(s &' )la'tas.

Para s, )r(d,**i/' s& ),&d&',tilizar ,'a a)lia 2ari&dad d&at&rias )rias 3*a+a d& az7*ar8a:z8 r&(la*0a8 *&r&al&s8

r&sid,(s -(r&stal&s8 *as*aras d&-r,tas yQ( 2&1&tal&s8 &t*.4.

E' l(s (r:1&'&s d& la i'd,striaa,t((2ilista -,& ,'( d& l(s)ri&r(s *ar%,ra't&s 6,& s&*('sid&rar('.

BIOETANOL:



• NAOH•CASCARA DE

PIA TRIURADA

• REMOLACHA• CAAA!UCAR

• MELA!A• CASCARA DE

PIA

LIGNI!ACIÓN

HIDROLOSIS

HIDROLOSIS

A!UCARESKERMENTACION

DESTILACION

ETANOHIDRATA

DESHIDRATACION

#IOETANOL

Li1'iza*i/'8 Hidr/lisis8 K&r&'ta*i/'8D&stila*i/'

PRODUCCIÓN DELBIOETANOL:



• Ela%(ra*i/' d&%i(*(%,sti%l&s

• O%t&'*i/' d& %i(*(%,sti%l&s

3EF8EF8 EDIESEL8 E T#E4.

• Ali&'ta*i/' d& (t(r&s81&'&rad(r&s a6,i'arias.

• O9i1&'a*i/' y a,&'t( d&(*ta'a& &' 1as(li'as8s,stit,y&'d( &l MT#E 35t&r&til t&rt %,t:li*(8

Gas(0(l42i&ra

APLICACIÓN DELBIOETANOL:



El %i(&ta'(l &s ,' *(),&st( 6,:i*( 6,& ),&d&,tilizars& *(( *(%,sti%l&.

El *(%,sti%l& r&s,lta't& d& la &z*la d& Eta'(l yGas(li'a s& *('(*& *(( 1as(0(l ( al*('a-ta.

El &ta'(l ta%i5' s& ,tiliza *ada 2&z ;s *((a+adid( )ara (9i1&'ar la 1as(li'a &st;'dar8

r&&)laza'd( al 5t&r &til t&rt %,t:li*(3MT#E4.

Para la )r(d,**i/' d& &ta'(l &' &l (tr(s )a:s&s s&,tiliza ay(r&'t& *(( -,&'t& %i(asa.

S&17' &st,di(s la *;s*ara d& )i+a *('ti&'&',&r(sas *las&s d& az7*ar8 *(( )(r &&)l( la-r,*t(sa.

BIOETANOL Y LACÁSCARA DE PIÑA:



PROPIEDADES DE LAPIÑA:



• Alt&ra*i/' d& las *5l,las 2&1&tal&s )(rala*&'ai&'t( d& li1'i'a &' las&%ra'as *&l,lar&s. La li1'iB*a*i/'-(rtal&*& la r&sist&'*ia &*;'i*a a la )r&si/'*(' ,'a *i&rta )5rdida d& &lasti*idad. E' laad&ra ad&;s d& la li1'i'a8 s& &'*,&'tra'ta%i5' at&rias *,rti&'t&s *(' )i1&'t((s*,r(8 *(( )r(t&**i/' -r&'t& a las

%a*t&rias. M&dia't& *(**i/' *(' 0idr(s,lti-(d& *al*i( ),&d&' &9tra&rs& d& ',&2( lasli1'i'as8 6,&da'd( *(( r&st( la &str,*t,ra*&l,l/si*a.

LIGNIFICACIÓN:



Es ,'a r&a**i/' 6,:i*a&'tr& ,'a (l5*,la d& a1,ay (tra (l5*,la8 &' la *,alla (l5*,la d& a1,a s&di2id& y s,s ;t((s )asa' a-(rar )art& d& (tra&s)&*i& 6,:i*a. Estar&a**i/' &s i)(rta't& )(r&l 1ra' '7&r( d&*('t&9t(s &' l(s 6,& &la1,a a*t7a *((dis(l2&'t&.

HIDROLISIS ÁCIDA:



La -&r&'ta*i/' al*(0/li*a &s ,' )r(*&s(%i(l/1i*( d& -&r&'ta*i/' &' )l&'a

a,s&'*ia d& air& 3(9:1&'( O=48 (ri1i'ad()(r la a*ti2idad d& al1,'(si*r((r1a'is(s 6,& )r(*&sa' l(s0idrat(s d& *ar%('( 3)(r r&1la 1&'&ralaz7*ar&sJ *(( ),&d&' s&r )(r &&)l( la1l,*(sa8 la -r,*t(sa8 la sa*ar(sa8 &lalid/'8 &t*.4 )ara (%t&'&r *(()r(d,*t(s B'al&sJ ,' al*(0(l &' -(ra d&&ta'(l 3*,ya -/r,la 6,:i*a &sJ CH?CH=OH48 di/9id( d& *ar%('( 3CO=4 &' -(ra d&1as y ,'as (l5*,las d& ATP 6,&

*('s,&' l(s )r()i(s i*r((r1a'is(s &'

FERMENTACIÓN:



D&stila*i/' d('d& l(s2a)(r&s )r(d,*id(s s('i'&diata&'t&*a'alizad(s 0a*ia ,'

*('d&'sad(r8 &l *,al l(sr&-r&s*a y *('d&'sa d&(d( 6,& &l d&stilad('( r&s,lta ),r(.

DESTILACIÓN SIMPLE:



La l&2ad,ra d&

3Saccharomyces cerevisiah('1( ,'i*&l,lar8 ,' ti)( ,tilizad( i'd,strial&'t&-a%ri*a*i/' d& )a'8 *&r2&z*i*l( d& 2ida d& las l&2ad,d(s -(ras8 ,'a 0a)l(i

di)l(id&. A%as -(ras s&d& -(ra as&9,al )(r 1&*('di*i('&s ,y d&t&r-(ra di)l(id& &s ta%i5' r&)r(d,*irs& s&9,al&'t&.

Saccharomyces cerevisiae

Clasificación científica

Reino: Fungi

División: Ascomycota

Clase: Hemiascomycetes

Orden: Saccharomycetales

Familia: Saccharomycetaceae

Gnero: Saccharomyces

!s"ecie: S. cerevisiae

#om$re $inomial


SACCHAROMYCESCEREVISAE:



LUGAR DE EJECUCIÓN

L a !

" a

QU Í M

I C A



METODOLOGÍA



MATERIALES Y EQUIPOS:

E6,i)( d& d&stila*i/' *()l&t(.

@ T&r/&tr( )&a*0i&tr( = Pr(%&tas =F>L y F>>L @ E%,d( @ Ki(la d& @>>>L = Ki(las d& @>>L Pa)&l Bltr( Vas(s d& )r&*i)ita*i/' d& @>>>

L. @ Varilla



R&a'#$(!):

La *as*ara d& )i+aJ ?1.NaOH >8@ NJ = LNaOH FNJ @> lL&2ad,ra s&*a 3Sa*0ar(y*&s

C&r2isa&4J ?=1.H=SO al =.



PROCEDIMIENTO



T"$#*"a'$+,

E-$.$,a'$+

, %&L$/,$#!)

H$%"+-$)$)0'$%a

F$-#"a'$+,

F&".&,#a'$+,

D&)#$-a'$+,

C;s*ara d& Nara'a

B$!&#a,!-

C;s*ara d& Pi+a Trit,rada 3? 14

Gl,*(sa y S/lid(s

S/lid(s

H=SO =. 3@> l4

@F Mi',t(s

)H .FF.>

Sa**0ar(y*&s C&r&2isia& 3 ?= 14? d:as

T a)r(9. C

NaOH >.@ N 3=L4



REDUCCIONDE TAMAÑO

SOLUCIONNa1OH2 Y

H3SO4



H$%"!-$)$)

E-$.$,a'$+,

%& L$/,$#!)



F$-#"a'$!,

R&/*-a'$+,%&- 5H



R&'#!"&)




T$&.5! %&6&".&,#a'$+,

M*&)#"a)



La ,tiliza*i/' d& ,'a isa *alidad d& *as*ara d& )i)ara s, &(r a';lisis d& %i(&ta'(l.U'a d& las )ri'*i)al&s liita*i('&s d& &st& )r(*&s( d

l&2ad,ras a las *('*&'tra*i('&s d&l al*(0(l 6,& &st&ll&2a a )r(d,*ir d,ra't& la -&r&'ta*i/' a0:i*r((r1a'is(s *(( l( &s sa**0ar(y*&s *&r&2isi

&st(s s()(rta' &l => d& la *('*&'tra*i/' &' &l 2(l,El &6,i)( d& d&stila*i/' '( )r(d,*& la &B*a*ia &s)&ra)ara la (%t&'*i/' d&l %i(&ta'(l.

SUGERENCIAS

CONCLUSIONES



CONCLUSIONES

S& (%t,2( %i(&ta'(l a )artir d& la *as*ara d& La -&r&'ta*i/' ti&'& 6,& s&r a'a&r/%i*a ya

)r(*&s( )&rit& 6,& &l (9:1&'( '( s& (9id& yr&alizara tra'6,ila&'t& la r&a**i/' )ara la d&l %i(&ta'(l.

S& (%t,2( ,' (d&l( d& -&r&'ta*i/' s&'*

(%t&'*i/' d& %i(&ta'(l. S& di( ,' 2al(r a1r&1ad( a la *as*ara d& )i+

)r(*&s( d& tras-(ra*i/' a %i(&ta'(l. R&aliza(s ,' (d&l( d& d&stila*i/' s&'*illa

(%t&'*i/' d&l %i(&ta'(l

Í



• 0tt)JQQ.%i(6,ii*a.*(Q&'say(sQPr(d,**iC?#?'DlaPartirD&Q@@.0tl

• 0tt)JQQ-&r&'ta*i('y&9tra**i('.%l(1s)(t.)&Q• 0tt)JQQ&s.slid&s0ar&.'&tQ(0a''al(r&'a@Qli*(rd&)i+a• A)r(2&*0ai&'t( d&l %a1az( d& )i+a )ara (%t&'&r *&l,l(

%i(&ta'(l R(*:( A't('i( Cr,z@ 8 A'a M. M&'d(za Mart:'& Y(la'da C0;2&z Ci'*(@ 8 $. L,is Ri2&ra Ar&'ta@ 8 M. $a2i&G/&z=

• 0tt)JQQ&s.ii)&dia.(r1QiiQPast&,riza*iC?#?R(dr:1,&zKis*0&.3*((rd.4

• 0tt)JQQ&s.ii)&dia.(r1QiiQPi+a• 0tt)JQQ%(ta'i*al('li'&.*(Q)i'a.0t•

P,%li*a*i/' SAGPYAINVIRAM. $,'i( =>>F.

BIBLIOGRAFÍA

http://www.bioquimica.com/ensayos/Producci%C3%B3n-De-Bioetanol-a-Partir-De/81416797.html


http://fermentacionyextraccion.blogspot.pe/

http://es.slideshare.net/johannalorena16/licor-de-pi%C3%B1a

http://es.wikipedia.org/wiki/Pasteurizaci%C3%B3Rodr%C3%ADguezFischer,C.(coord.)








http://es.slideshare.net/johannalorena16/licor-de-pi%C3%B1a

http://fermentacionyextraccion.blogspot.pe/



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