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OWEA Conference June 26, 2019 Dave Rutowski Hach Process Optimization Evaluation of high precision in-situ analysis against benchtop lab analyzers for process insight

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Page 1: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

OWEA Conference June 26, 2019Dave Rutowski – Hach Process Optimization

Evaluation of high precision in-situ analysis against benchtop lab analyzers

for process insight

Page 2: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

Why do we need improved analysys?

• The Clean Water Action Plan provides a blueprint for Federal agencies to work with States and others stakeholders in restoring and protecting the Nation’s water resources.

• A key part of the Action Plan provides for expanded efforts to reduce nutrient over enrichment of waters.

• The Great Lakes States have taken the lead in addressing nutrient pollution with limits in some areas to go down to 0.04 mg/L.

Page 3: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

We have the technology to do more in less space

Page 4: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

We have the technology to have unparalleled Clarity

Page 5: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

THE LAB, GOLD STANDARD OF ANALYSIS

Calibrated Standards

CCV, CCB, True Zero Cal

Standard Curves

EPA Approved Methods

Stable Environment Temperature Humidity Clean

Page 6: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

IN THE FIELD, THINGS CAN GET MESSY…….

Page 7: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

TREATMENT IS A HIGHLY VARIABLE OPERATION

Operator Questions -• What to measure – and why?• Where to measure it?• Is a daily grab sample representative, good enough?

– Hint: It is not• Is my plant running as designed?• Is my instrument giving me correct readings?• What do I do with the data?• Do the chemical, power savings matter?

– Hint: Absolutely7

Page 8: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

TREATMENT IS A BUSINESS

• Retiring workforce - Institutional knowledgeis leaving the industry

• Changing Raw Materials – Factories come and go– Population changes– I&I / Pb mitigation

• Budget concerns

• Compliance regulations

• Data management– Common Platform / Language– Data Security– Remote Access

Everyone is being asked to do more with less but how?

Page 9: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

PhosphaxPortfolioComparison

Parameter Existing Phosphax Models Phosphax sc LR

Range (PO4-P) High Range: 1 - 50 mg/LMedium Range: 0.05 - 15 mg/L 0.015 - 2.0 mg/L

Method Standard Vandat Molybdat Vandat Molybdat (Yellow 2.0)

Response time Less than 5 mins 10 mins

Channels 2 channel 1 channel

Accuracy 2% + 0.05 mg/L 2% + 0.015 mg/L

Since 2004 Launched Sept 2018

Page 10: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

Hach Family of Phosphax Analyzers

Phosphax sc MR (Medium Range)

(0.05-15 mg/L PO4-P) Aeration basin applicationsSurface water monitoring

Industrial effluent

Phosphax sc HR (High Range)

(1-50 mg/L PO4-P) Aeration basin applications Muni/Industrial WW Inlet

Phosphax sc LR (Low Range)

(0.015-2 mg/L PO4-P)Aeration basin applicationsSurface water monitoring

Industrial effluent

NEW!

Page 11: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

New Photometric Unit

12

• Lower concentrations of Ortho-P in a sample require a longer measurement path length.

Phosphax sc MR : b= 18mmPhosphax sc LR : b= 36mm

Page 12: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

• Glass cuvette is expected to last the whole life time of the analyzer- More durable vs plastic cuvette in most analyzers.

• Glass cuvette is less prone to air bubbles compared to plastic cuvette in most analyzers.

• Double path length reduces effect of bubbles, if any.

New Photometric Unit

Io I Io I

b 2b

Page 13: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

• The Filtration Module prepares sample through two ultra-filtration membranes (0.15 µ)

• Modules are immersed in the process tank.

• Peristaltic pump pulls the sample through one filter at a time, allowing for optimal cleaning.

• Unit automatically cleans by forcing vigorous stream of air bubbles against sides of the filter modules.

SAMPLE CONDITIONING

FILTRATION MODULES

Filtrax sc

14

Page 14: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

Additional Features, integration and operation

e

Available in indoor and outdoor versions •The housing is weatherproof so that the unit can be installed right

at the basin, even in the toughest climates.

Claros Enabled•You can leverage Hach Water Intelligence to collect, manage and

analyze data.•Full Featured “Plug and Play” Digital sc controller.

Zero requirement to cool reagents•Longer shelf life of reagents.•Ships with at least a 4-month supply of reagents.

Automatic calibration and cleaning•Automatic cleaning at customized intervals and automatic zero-

calibration at each measuring cycle.•Low maintenance.

Page 15: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

Product Applications

Municipal Effluent Surface Water Monitoring

Industrial effluent

Page 16: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

Company ConfidentialCompany Confidential

Beta Test Insights

Page 17: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

Company Confidential

Beta Test Locations

2 locations in Wisconsin 4 locations in Germany

Page 18: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

Company Confidential

-0.05

0.05

0.15

0.25

0.35

0.45

0.55

0.65

0.75

0.85

0.95

1.05

1.15

1.25

1.35

1.45

1.55

1.65

1.75

Conc

entr

atio

n (m

g/L P

O4-

P)

Zeit

Beta Test Janesville Phosphax sc LR

Against Lab DataPsc LR

Lab

Comparable Lab and Process Results in Very Low Ranges

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Lab vs Process Comparison – an Overlap

0.000

0.100

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0.500

0.600

0.700

Phosphax sc LR [mg/l] Lab test [mg/l]

*Lab tests were done using TNT 843 chemistry/LZP269 cuvette and a Hach DR3900/6000 photometer

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Company Confidential

0

0.02

0.04

0.06

0.08

0.1

0.12

Beta-test Phosphax sc LR (0.015 – 2.0)Phosphax sc MR (0.05 – 15.0) Psc LR

Psc

High Stability/Less Noise of the Measured Values with the New Phosphax sc LR

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Company Confidential

0

0.1

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0.9

1

1.1

1.2

Conc

entr

atio

n (m

g/L P

O4-

P)

Psc LR

Applitek

Results Comparable to Blue Method of Applitek Instrument

Beta-test Phosphax sc LR and Applitek

Page 22: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

PROCESS MANAGEMENT

Standardized RTC control modules • Adapt plant operation to varying

load situations and plant performance – Improved compliance (minimize risk)– Reduced OPEX / Short ROI (economically viable)– Improved process transparency

All analytical input signals validated by Instrument Management / PROGNOSYS®– High reliability, high uptime

Page 23: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

PROCESS MANAGEMENT EXPERIENCE

Large number of installations• 1850 sites in EU, US, China operating an CPM

– 70 % of plants between 2-8 MGD

Experienced Global CPM Team • Growing team of CMP consultants

– 28 in EU, 5 in US

• Sales & Service NA: 250 associates• Centralized (US and EU) CMP Service/Commissioning experts

providing remote support & monitoring

• 3150 control modules in operation • Growing number of industrial CPM

Tailored Solution

Page 24: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

SF Nitrification (step feed) NH4-N - Energy (aeration intensity)

MOV DO Control NA - Energy (aeration intensity)

NA RTC TEAM - TARGETINGN

utrie

nt R

emov

al

Page 25: Evaluation of high precision in-situ analysis against ... · Hint: Absolutely 7. TREATMENT IS A BUSINESS • Retiring workforce - Institutional knowledge is leaving the industry •

COMMITTED TO SUPPORT YOU FROM DESIGN TO OPERATION