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    ENVIRONMENTALSCIENCE 13e

    CHAPTER 2:Science, Matter, and Energy

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    Core Case Study:

    A Story about a Forest (1)

    Hubbard Brook Experimental Forest

    Question: What is the environmental

    impact of forest clear-cutting? Controlled experiment isolate

    variables

    Control group

    Experimental group

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    Core Case Study:

    A Story about a Forest (2)

    Measure loss of water and nutrients

    Compare results

    3040% increase in runoff68 times more nutrient loss

    Draw conclusions

    Cause-and-effect relationships

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    Fig. 2-1, p. 23

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    Fig. 2-3, p. 30

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    Undisturbed(control)watershed

    Disturbed(experimental)watershed

    Year

    Nitrate(NO3

    )concentratio

    n

    (milligram

    sperliter)

    Fig. 2-3, p. 30

    60

    40

    20

    1963 1964 1965 1966 1967 1968 1969 1970 1970 1972

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    2-1 What Do Scientists Do?

    Concept 2-1 Scientists collect dataand develop theories, models, and

    laws about how nature works.

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    Science

    Search for order in nature

    Observe behavior

    Attempt to identify cause and effectMake predictions

    Test predictions

    Draw conclusions

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    The Scientific Process (1)

    Identify problem/question

    Learn what is known about

    problem/question Ask question to be investigated

    Collect data

    Formulate a testable scientifichypothesis

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    The Scientific Process (2)

    Make testable projections

    Test projections with experiments

    Develop models

    Propose scientific theories

    Derive naturallaws

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    The Scientific Process (3)

    Four features of the scientific

    process:

    Curiosity

    Skepticism

    Peer review

    Reproducibility

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    Scientific lawWell-accepted

    pattern in data

    Identify a problem

    Find out what is known

    about the problem(literature search)

    Ask a question to be

    investigated

    Perform an experimentto answer the question

    and collect data

    Analyze data(check for patterns)

    P

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    Make testablepredictions

    Propose anhypothesis

    to explain data

    Use hypothesis to

    make testablepredictions

    Perform anexperiment

    to test predictions

    Accepthypothesis

    Scientific theoryWell-tested andwidely accepted

    hypothesis

    Revisehypothesis

    Testpredictions

    Fig. 2-2, p. 25

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    Scientific theory

    Well-tested andwidely acceptedhypothesis

    Stepped Art

    Testpredictions

    Make testablepredictions

    Accepthypothesis

    Revisehypothesis

    Perform an experiment

    to test predictions

    Use hypothesis to make testablepredictions

    Propose an hypothesisto explain data

    Analyze data(check for patterns)

    Scientific lawWell-acceptedpattern in data

    Perform an experimentto answer the question

    and collect data

    Ask a question to be

    investigated

    Find out what is knownabout the problem(literature search)

    Identify a problem

    Fig. 2-2, p. 25

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    Results of Science

    Goals

    Scientific theories

    Scientific laws

    Degree of certainty and general

    acceptance

    Frontier/tentative science

    Reliable science

    Unreliable science

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    Scientific Limitations

    Limitations 100% certain?

    Absolute proof versus probability

    Observational biasComplex interactions, many variables

    Estimates and extrapolating numbers

    Mathematical models

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    Science Focus: Climate Change

    (1) Natural greenhouse effect

    Keeps atmosphere temperatures moderate

    Three questions

    1. How much warming over the last 50years?

    2. How much of the warming is caused by

    humans adding carbon dioxide toatmosphere?

    3. How much will the atmosphere warm in

    the future, and what effects will it have?

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    Science Focus: Climate Change

    (2) International Panel on Climate Change

    2007 IPCC report:

    Very likely: 0.74 C increase 1906-2005

    Very likely: human activities main cause ofglobal warming

    Likely: earth mean surface temperature toincrease by ~3 C between 2005 and 2100.

    Climate change critics: most are notclimate experts

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    2-2 What Is Matter and How Do Physicaland Chemical Changes Affect It?

    Concept 2-2A Matter consists ofelements and compounds, which are inturn made up of atoms, ions, or molecules.

    Concept 2-2B Whenever matterundergoes a physical or chemical change,no atoms are created or destroyed (thelaw of conservation of matter).

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    What Is Matter?

    Matter has mass and occupiesspace

    Elements and CompoundsAtoms

    Ions

    Molecules

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    Table 2-1, p. 29

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    Building Blocks of Matter (1)

    Atomic Theory elements made fromatoms

    Atoms

    Protons positive charge

    Neutrons uncharged

    Electrons negative charge

    Nucleus

    One or more protons

    Usually one or more neutrons

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    Supplement 6, Fig. 1, p. S26

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    Supplement 6, Fig. 1, p. S26

    6 protons

    6 neutrons

    6 electrons

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    Building Blocks of Matter (2)

    Atomic number

    Number of protons

    Massnumber Neutrons + protons

    Isotopes

    Same atomic number, different mass

    Same number of protons, different number of

    neutrons

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    Building Blocks of Matter (3)

    Ion

    One or more net positive or negative electrical

    charges

    Molecule Combination of two or more atoms

    Chemical formula

    Number and type of each atom or ion

    Compounds

    Organic

    Inorganic

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    Supplement 6, Fig. 6, p. S28

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    Supplement 6, Fig. 6, p. S28

    Hydrochloricacid (HCl)

    Gastric fluid(1.03.0)

    Lemon juice,some acid rain

    Vinegar, wine,

    beer, oranges

    Tomatoes

    BananasBlack coffee

    BreadTypical rainwater

    Urine (5.07.0)

    Milk (6.6)

    Pure waterBlood (7.37.5)

    Egg white (8.0)

    Seawater (7.88.3)Baking soda

    100

    101

    102

    103

    104

    105

    106

    107

    108

    109

    1010

    1011

    1012

    1013

    1014Sodium hydroxide (NaOH)

    Phosphate detergentsBleach, Tums

    Soapy solutions,Milk of magnesia

    Household ammonia(10.511.9)

    Hair remover

    Oven cleaner

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    Supplement 6, Fig. 5, p. S27

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    Supplement 6, Fig. 5, p. S27

    CI2chlorine

    H2hydrogen

    O2oxygen

    N2nitrogen

    H2O

    water

    NO

    nitric oxide

    CO

    carbon monoxide

    HCI

    hydrogen chloride

    NO2

    nitrogen dioxide

    O3

    ozone

    SO2

    sulfur dioxide

    CO2

    carbon dioxide

    H2S

    hydrogen sulfide

    CH4

    methane

    NH3

    ammonia

    SO3

    sulfur trioxide

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    Table 2-2, p. 29

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    Table 2-3, p. 30

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    Organic Compounds

    Carbon-based compounds

    Hydrocarbons

    Chlorinated hydrocarbons

    Simple carbohydrates

    Complex carbohydrates

    Proteins

    Nucleic acids (DNA and RNA)

    Lipids

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    Matter Becomes Life

    Cells

    Genes

    DNATraits

    Chromosomes

    DNA

    Proteins

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    Fig. 2-4, p. 31

    A human body contains trillions

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    A human body contains trillionsof cells, each with an identical setof genes.

    Genes are segments of DNA onchromosomes that contain instructionsto make proteinsthe building blocks

    of life.

    Each chromosome contains a longDNA molecule in the form of a coileddouble helix.

    A specific pair of chromosomescontains one chromosome from eachparent.

    Each cell nucleus has an identical setof chromosomes, which are found in

    pairs.

    Each human cell (except for redblood cells) contains a nucleus.

    Fig. 2-4, p. 31

    A human body contains trillions

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    A human body contains trillionsof cells, each with an identical setof genes.

    Genes are segments of DNA onchromosomes that contain instructionsto make proteinsthe building blocks

    of life.

    Each chromosome contains a longDNA molecule in the form of a coileddouble helix.

    A specific pair of chromosomescontains one chromosome from eachparent.

    Each cell nucleus has an identical setof chromosomes, which are found in

    pairs.

    Each human cell (except for redblood cells) contains a nucleus.

    Stepped ArtFig. 2-4, p. 31

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    Matter Quality

    Usefulness as a resource

    Availability

    Concentration

    High quality

    Low quality

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    Fig. 2-5, p. 32

    Low QualityHigh Quality

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    Aluminum ore

    Solid

    Salt

    Coal

    Gasoline

    Aluminum can

    Gas

    Solution of salt in water

    Coal-fired powerplant emissions

    Automobile emissions

    Fig. 2-5, p. 32

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    Changes in Matter

    Physical

    Chemical

    Law of Conservation of MatterMatter only changes from one form to

    another

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    p. 32

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    p. 32

    Reactant(s) Product(s)

    Carbon + Oxygen

    C + O2

    Black solid Colorless gasColorless gas

    Energy

    Energy

    Energy

    Carbon dioxide +

    CO2 +

    +C CO O

    O

    O

    +

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    Nuclear Changes (1)

    Radioactive decay unstableisotopes

    Alpha particles

    Beta particles

    Gamma rays

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    Nuclear Changes (2)

    Nuclear fission

    Large mass isotopes split apart

    Chain reaction

    Nuclear fusion

    Two light isotopes forced together

    High temperature to start reaction

    Stars

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    Fig. 2-6, p. 33

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    Radioactive decay

    Radioactive isotope

    Gamma rays

    Beta particle(electron)

    Alpha particle(helium-4 nucleus)

    Radioactive decayoccurs when nuclei ofunstable isotopesspontaneously emit fast-moving chunks of matter(alpha particles or beta

    particles), high-energyradiation (gamma rays), orboth at a fixed rate. Aparticular radioactiveisotope may emit any oneor a combination of thethree items shown in thediagram.

    Fig. 2-6, p. 33

    ++

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    Nuclear fission Uranium-235

    Uranium-235

    Neutron

    Fissionfragment

    Fissionfragment

    Energy

    Energy

    Energy

    Energy

    Nuclear fission occurs when thenuclei of certain isotopes with largemass numbers (such as uranium-235)are split apart into lighter nuclei when

    struck by a neutron and releaseenergy plus two or three moreneutrons. Each neutron can trigger anadditional fission reaction and lead toa chain reaction, which releases anenormous amount of energy.

    Fig. 2-6, p. 33

    n

    n

    nn

    n

    n

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    Nuclear fusion

    Fuel

    Proton Neutron

    Hydrogen-2(deuterium nucleus)

    Hydrogen-3(tritium nucleus)

    100million C

    Reactionconditions Products

    Helium-4 nucleus

    Energy

    Neutron

    Nuclear fusion occurs when twoisotopes of light elements, such

    as hydrogen, are forced togetherat extremely high temperaturesuntil they fuse to form a heaviernucleus and release a tremendousamount of energy.

    Fig. 2-6, p. 33

    Uranium-235

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    Neutron

    Uranium-235

    Fission

    fragment

    Fission

    fragment

    Energyn

    n

    n

    Energy

    Energy

    n

    n

    n

    Energy

    Uranium-235

    Uranium-235

    Uranium-235

    Uranium-235

    Uranium-235

    Uranium-235

    Uranium-235

    Uranium-235

    Stepped Art

    Fig. 2-6, p. 33

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    2-3 What Is Energy and How Do Physicaland Chemical Changes Affect It?

    Concept 2-3A When energy is converted fromone form to another in a physical or chemicalchange, no energy is created or destroyed (first

    law of thermodynamics).

    Concept 2-3B Whenever energy is convertedfrom one form to another in a physical orchemical change, we end up with lower qualityor less usable energy than we started with(second law of thermodynamics).

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    What Is Energy?

    Energy the capacity to do work ortransfer heat

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    Types of Energy

    Potentialenergy stored energyGasoline

    Water behind a dam

    Kineticenergy energy in motionWind, flowing water, electricity

    Heat

    flow from warm to coldElectromagnetic radiation

    wavelength and relative energy

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    Fig. 2-7, p. 34

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    Fig. 2-7, p. 34

    Ultraviolet

    Ene

    rgyemittedfro

    ms

    un(kcal/cm

    2/min)

    0

    5

    10

    15

    1 2 2.50.25 3

    Wavelength (micrometers)

    Visible

    Infrared

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    Energy Quality (1)

    High-quality energy

    Concentrated, high capacity to do work

    High-temperature heat

    Nuclear fission

    Concentrated sunlight

    High-velocity windFossil fuels

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    Energy Quality (2)

    Low-quality energy

    Dispersed

    Heat in atmosphere

    Heat in ocean

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    Laws of Thermodynamics

    First law of thermodynamics

    Energy input = Energy output

    Energy is neither created or destroyed

    Energy only changes from one form to

    another

    Second law of thermodynamicsEnergy use results in lower-quality

    energy

    Dispersed heat loss

    Consequences of the Second

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    Consequences of the Second

    Law of Thermodynamics

    Automobiles

    ~13% moves car

    ~87% dissipates as low-quality heat into the

    environment

    Incandescent light bulb

    ~5% useful light

    ~95% heat

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    Fig. 2-8, p. 36

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    Solarenergy

    Chemical energy(photo-synthesis)

    Mechanicalenergy

    (moving,thinking, living)

    Chemicalenergy(food)

    Wasteheat

    Wasteheat

    Wasteheat

    Wasteheat

    Fig. 2-8, p. 36

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    Three Big Ideas of This Chapter

    There is no away

    Law of conservation of matter

    You cannot get something for nothingFirst law of thermodynamics

    You cannot break even

    Second law of thermodynamics

    A i ti S b t i ti l

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    Animation: Subatomic particles

    Animation: Atomic number, mass

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/atomic_particles.html
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    at o to c u be , assnumber

    A i ti I i b d

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/mass_number.html
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    Animation: Ionic bonds

    A i ti C b b d

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/ionic_bond.html
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    Animation: Carbon bonds

    Animation Half life

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/carbon_bonding.html
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    Animation: Half-life

    Animation: Visible light

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/half_life.html
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    Animation: Visible light

    Animation: Total energy remains

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/light_wavelength.html
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    gyconstant

    Animation: Energy flow

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/energy_constant.html
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    Animation: Energy flow

    Animation: Economic types

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/energy_flow.html
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    Animation: Economic types

    Animation: Martian doing

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/hi_low-throughput.html
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    gmechanical work

    Animation: Energy flow from Sun

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/martian_working.html
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    Animation: Energy flow from Sun

    to Earth

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/sun_to_earth.html
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    Animation: Energy Use

    Animation: Hubbard Brook

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/energy_pie.html
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    Animation: Hubbard Brook

    Experiment

    Animation: Categories of Food

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/hubbard_brook.html
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    Animation: Categories of Food

    Webs

    http://localhost/var/www/apps/conversion/tmp/scratch_3/Animations/food_webs_v2.html