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Environmental Control Systems BG Verkehr Industriedialog 04. Juni 2013 Presented by Andreas BEZOLD / Environmental Control Systems Air Quality

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Page 1: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Environmental Control SystemsBG Verkehr Industriedialog 04. Juni 2013g

Presented byAndreas BEZOLD / Environmental Control Systems – Air Qualityy y

Page 2: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Environmental Control Systems

Requirements and System Solutions

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

Page 3: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

The Environment

June 2013

hot day on groundcold day on ground

lower stratospherehigh humidity pg y

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1

• -43 °C to -65 °C• less than one percent humidity• ~ 200 hPa• Ozone

Page 4: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

The Requirements...

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

Certification requirements:qoutside air flowair quality (CO2, CO, O3, ...)cabin pressure-levelpcabin temperatures

…Functional requirements: removal of high thermal loads removal of high thermal loads

(passenger, avionic, IFE, galleys,...) independence of environment

(TcabTamb) Customer requirements:(TcabTamb) structural integrity (∆ P)

… high degree of flexibility comfort payload temperature control low maintenance costs low fuel consumption

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 5: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

The Source of Pressure – The Bleed System

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 6: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Turbofan Engine – Working Principle

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

Bypass air stream

Fan

Fuel

Fan Nozzle

TurbineFuel injector

Turbine

Exhaust

Core Air Stream

CompressorCombustion

Chamber Turbine Nozzle

Compression and Bleed Air extraction

Combustion Exhaust

Air is taken from compressor stage UPSTREAM of the combustion chamber

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 7: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Shaft Bearing Lubrication System simplified

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

Exxon, 2009

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 8: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Conditioning of Air – The Pack

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

Cooling - Expansion Cooling

Hot bleed air:Hi h

Cold ambient air:Low pressureLow temperature

High pressureHigh temperature

C ld bl d i

Hea

Engines / APU / High pressure

Cold bleed air:Cabin pressureLow temperature

at Absorp

ground cart

tion

Hot ambient air:Low pressureHigh temperature

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 9: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Air Distribution – The Ventilation System

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

• Even distribution of conditioned air throughout the fuselage• Sizing and integration of needed blowing / extraction fans and ducting• Sizing and positioning of air outlets• Using mixing principle to balance airflow with temperature gradients at increased

humidityhumidity

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 10: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

The Entire Picture

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 11: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

What drives ECS energy demand

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

demand of cooling airflow based on cabin heat balance and air exchange determines performance of air

diti i ( b i i tifi dconditioning (above minimum certified airflows) and pressurization.

Example A320 net energy demand p gyduring flight:

Cooling: ~ 20 kWPressure adaption: 150 kWPressure adaption: ~ 150 kWVentilation: ~ 3 kW

Actual consumption considerably higher

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

p y g

Page 12: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

ECS Development Parameters (Assortment)

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

APU

Equipment Cooling

Power Generation

Engine

Power Transmission

Power Conversion

During development of an ECS concept many parameters need to be taken into account in order to assure an optimum in Aerodynamics

Weight

order to assure an optimum in operational safety, reliability and energy consumption

Aerodynamics (Drag)

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 13: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Composition and Toxicity of Engine Oils

What do we know from Literature?

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

Page 14: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Engine oil…

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

…consist mainly of synthetic fatty acid esters of Pentaerythritol or Trimethylolpropane

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 15: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

TCP – Production and Isomeric Structure

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

OHOHOHTri-cresyl-phosphate exists in 10 isomeric forms, depending of the position of the

para-cresolmeta-cresolortho-cresol

CHCH3

CH3

p g pmethyl groups. The ortho-isomers (rather their metabolic products in human bodies) are neurotoxic at sufficiently high concentration but only of vanishingly lowCH3

P ClCl Cl

Oconcentration but only of vanishingly low concentration in the engine oil.

+phosphorus oxychloride

neurotoxic

ortho-meta-

neurotoxic configuration

)para-

Tri-cresyl-phosphate

a)

a) Henschler and other scientists could not find any symptoms t hi h d f TCP d f d t l

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Tri-cresyl-phosphate even at high doses for TCP made from para- and meta-cresyls.

Page 16: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

TCP – Toxicity in Relation to TOCP

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

• neurotoxicity of TCP depends on the content of ortho-isomers, which is given by the ortho-cresol concentration in the crude reaction mixture

• mono-ortho-isomers are more toxic than di- and tri-ortho-isomers • jet engine oil contains about 2-3% TCP, which contains < 0,2 % ortho-isomers

and according to Henschler is of significantly lower toxicity than pure TOCPg g y y p

Henschler, 1958

Tri-ortho-cresyl-h h (TOCP)

o-cresol TCP mixture [%]

phosphate (TOCP)TLV (0,1 mg/m³ TWA)ACGIH 2001

here we are

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 17: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

TCP – Content in JEO in practice

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

• Department of Defense (Australia) determined TCP isomers in different jet engine oils from one single manufacturer

• Total TCP content 2-3%• Total ortho-isomer concentration (< 50 ppm) below 0,2% of total TCP

0.2 %

Denola, Mazurek, 2008

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 18: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Measurements on Aircraft

Published data on TCP

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

Page 19: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Measurements on Aircraft - TCP

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

Some measurements of TCP concentrations are available, some of them taken during fume and even smoke events, all of them are at concentration well below l l bli h d h d f h lthlevels published as hazardous for health

Hanhela (2005): 0,4-49 µg/m³ total-TCP on military aircraft including incident with oil ingestion by APU (49 µg/m³) (Hanhela 2005)ingestion by APU (49 µg/m ) (Hanhela 2005)

Cranfield University (2011): 95% of 981 samples from 100 flights w/o detectable level. Max. 37 µg/m³ total-TCP for a single sample. Max 8 µg/m³ average concentration during 1 flight. Findings of TOCP far below ACGIH TLV (?). g g g ( )

Van Netten (2009): 0,03-0,08 µg/m³ Total-TCP in BAe146 w/o incidentSolbu (2011): max. 0,29 µg/m³ total-TCP w/o incident. 5 µg/m³ on aircraft on ground with

strong oil smell. Higher exposure seen at aircraft mechanics.Denola (2011): max. 51 µg/m³ total-TCP on military aircraft with smoke eventASHRAE (2012): ~1,5 ng/m³ m-TCP detected during one out of 63 flights

• All above studies able to clearly distinguish between 10 TCP isomers could not detect any TCP ortho-isomer in the cabin. This is quite consistent with the information we have on the composition of JEO

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

information we have on the composition of JEO

Page 20: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Measurements on aircraft - Conclusion

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

• Even during oil contamination events, reported TCP levels do not exceed ACGIH TLV for TOCP

• ortho-Isomers of TCP were not reported (except by Cranfield at concentrations far below ACGIH TLV )

• This is consistent with published information on composition of Jet Engine Oilsp p g• Inconsistencies between studies (i.e. TOCP findings) should be clarified

• Few data available on other contaminants during such event• Few data available on other contaminants during such event• No significantly increased VOC concentration during smell on ground (Solbu, 2011)• No significantly increased CO concentration during oil smell incident (visible haze) on

ground (van Netten 1998)ground (van Netten, 1998)

• ASHRAE 1262 TRP results on air quality on 83 commercial flights did not contain f k t Ai lit t t d b i bl b tt th ifume or smoke events. Air quality stated being comparable or better than in offices, schools or residences with few exceptions. Several compounds related to passengers.

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 21: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Airbus Air Quality Measurements

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

Page 22: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1

Measurement Technologies

June 2013

• Online measurement with PTR-MSI d t t t i t i hi h t l l ti• In order to trace contaminants in a high temporal resolution

• Correlate trace contaminants with aircraft system data

• Component Class Specific Adsorbent Cartridges/Filters• Analyze and identify chemical components• Match identified components with molecular mass data from PTR-MS

• Particulate Measurement (Aerosol spectrometer)• In case of non gaseous contaminationIn case of non gaseous contamination• If possible determine organic load of particulate matter

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 23: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Monitoring – PTR-MS-TOF on aeroplane

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 24: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Integrative Sampling Methods (Fraunhofer IBP)

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

• Integrated concept with sensors and adsorbent tubes installed in trolley sized housinghousing

• Removable box with quick connections containing sampling tubes (up to 32)

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 25: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Conclusion

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

• Cabin Air Quality remains a high priority topic for the industry

• Cabin odour can occur and may be caused by many sources including engine related sources, but this does not necessarily indicate a high concentration of contaminants either toxic or non-toxicconcentration of contaminants, either toxic or non toxic

• Reported in-service events are difficult to investigate. The links between the reported cabin air quality event, the potential source and a confirmed medical condition remains difficult to establish

• However recognizing the industry concerns, Airbus and other t k h ld itt d t i hstakeholders are committed to ongoing research programmes

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 26: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

PTR-MS-TOF - Next Generation

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.

Page 27: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

Thank you !Thank you!

Thank you !

Page 28: Environmental Control Systems · BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013 Some measurements of TCP concentrations are available, some of

BG Verkehr Industriedialog CAQ - Andreas BEZOLD - Ref. PR1310342 - Issue 1 June 2013

© AIRBUS Operations GmbH All rights reserved Confidential and proprietary document This document and all information contained herein is the sole property of AIRBUS Operations GmbH No intellectual property© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document. This document and all information contained herein is the sole property of AIRBUS Operations GmbH. No intellectual propertyrights are granted by the delivery of this document or the disclosure of its content. This document shall not be reproduced or disclosed to a third party without the express written consent of AIRBUS Operations GmbH. Thisdocument and its content shall not be used for any purpose other than that for which it is supplied. The statements made herein do not constitute an offer. They are based on the mentioned assumptions and are expressedin good faith. Where the supporting grounds for these statements are not shown, AIRBUS Operations GmbH will be pleased to explain the basis thereof.AIRBUS, its logo, A300, A310, A318, A319, A320, A321, A330, A340, A350, A380, A400M are registered trademarks.

© AIRBUS Operations GmbH. All rights reserved. Confidential and proprietary document.