ELECTROCERAMICS IV

Volume II

Electronic and Ionic ConductorsSuperconductorsIntegrated Functions and SubstratesMagneticsProcessing and Mechanical Properties

Edited by

R. Waser

and

S. HoffmannD. BonnenbergCh. Hoffmann

Institut fur Werkstoffe der Elektrotechnik (IWE)

RWTH Aachen, University of Technology

GERMANY

Augustinus Buchhandlung

IX

CONTENTS OF VOLUME 2

ELECTRONIC AND IONIC CONDUCTORS

Ceramic Materials for SOFC and Electrochemical Reactor TechnologyB.C.H. Steele 663

Trends in the Development and Application of Negative Temperature Coefficient OxideCeramics

A. Feltz 677

Electrical Transport in Highly Conducting TitanatesR. Moos, W. Menesklou, A. Gnudi, K.-H. Hardtl 685

Electrical Conductivity and Defect Structure in the System Sr Tii-xFex03_y (x = 0.1 - 0.8)S. Steinsvik, T. Norby, P. Kofstad 691

Theory of Oxygen Transport Through Mixed Conducting PerovskitesM.H.R. Lankhorst, H.J.M. Bouwmeester, H. Verweij 697

Protonic and Native Ionic Conductivity in OxidesT. Norby, Y. Larring 703

Ionic and Electronic Conductors for Solid Oxide Fuel CellsW. Schafer, D. StoRen 711

Ceramic Components for Solid Oxide Fuel Cell (SOFC) with Metallic InterconnectorE. Ivers-Tiffee, W. Wersing, H. Greiner 719

Impedance Spectroscopy Analysis of the Electric Behavior of Ceramic CompositesM. Kleitz. E. Djurado, P.O. Robert, M.C. Steil, F. Thevenot 725

Electrical Conductivity of LaMnO3-Based PerovskitesG. Stochniol, E. Syskakis, E. Wermelskirchen, A. Naoumidis, H. Nickel 733

Impedance Response of Yb-doped SrCeO3 in a Water Vapour Free EnvironmentM. Cappadonia, L.G.J. de Haart, Th. Matzke, U. Stimming 737

Vacuum-Tight Joints of Proton-Conducting SrCeO3 and (X-AI2O3 for Use in an ElectrochemicalHydrogen Gas Sensor

K. Vercammen 741

Na-Beta-Alumina - a Mixed Ionic-Electronic ConductorH. Nafe 745

Dynamic Characteristics of SrTiO3 Thick Film as an Oxygen SensorS.-S. Cho, H.-G. Kim 749

Electrical Conductivity Change with Crystallization of Some Alkali Alumino Silicate GlassesS. N. Salama and Z. S. El Mandouh 753

Gas and Humidity Sensitive Electrical Properties of La2CuO4-ZnO Hetero-ContactsE. Traversa, A. Bearzotti, M. Mryayama, H. Yanagida 755

Ionic Conductivity Measurements of Natural Fluorite at Low TemperatureM.C. Amamra, H. Klimczyk, M. Rial, G. Petot-Ervas, C. Petot 759

Effects of Structural Disorder on the Optical Properties of Cubic Stabilized ZirconiaM. Bassi, P. Camagni, G. Samoggia, S. Torre 763

Electrical Properties of Sb-Doped SnO2 Powders, Ceramics, and Single CrystalsG. Bebr, J; Werner, P. Dordor, G. Couturier, D. Elefant 767

Lowering of the Cathode Overpotential of SOFC by Electrolyte DopingP. Bohac, A. Orliukas, L.J. Gauckler 771

Electrical Conductivity of P-Alumina Based ElectrolytesM.M. Bucko, G. Rog 775

Electrical Properties of Thick Film Silicon-Doped a-Fe2O3 Humidity SensorC. Cantalini, H.T. Sun, M. Faccio, G. Ferri, M. Pelino 777

Composite (YSZ+LSM) Ceramic Filters with High Oxygen Electrochemical PermeabilityA.D.S. Costa, J.A. Labrincha, F.M.B. Marques 781

Preparation and Properties of the High Temperature NTC Thermistor CeramicsM. Diaconescu, M. Anghel, V. GhHa, M. Nicolae 785

Influence of the Microstructure on the Ionic Conductivity of Yttrium Doped ZirconiaM. Rial, C. Lacour, M.C. Amamra, G. Petot-Ervas, C. Petot 789

Electrical Conductivity of the Brownmillerite-Structured Oxides, Ba2ln2-XMXO5C.A.J. Rsher, R.J. Brook 793

Humidity Sensitive and Varistor Tin Dioxide Based CeramicsA.B. Glot. A.M. Nadzhafzade, A.I. h/on 797

Solid Solutions of Ternary Oxide Ceramics as Active Materials for Humidity SensorsD.L. Hates, T. Hashemi, A.W. Brinkman 801

XI

Activation Volume of Proton Transport in NH4NDWO6R. Hinrichs, G. Tomandl, J.A.H. da Jornada 803

Oxide Ionic Conductivity of Lanthanum-Strontium Manganites CeramicsV. V. Kharton, A. V. Nicolaev, E. N. Naumovich, J. S. Gayduk, A. A. Vecher 807

Electrochemical and Structural Properties of SnO2 and Sb:SnO2 Transparent Electrodes withMixed Electronically Conductive and Ion-Storage Characteristics

U. Lavrencic Stangar, B. Orel, F. Svegl 809

Electrochemical Method of Determination of the Oxygen Diffusion Coefficient in ZirconiaM. Mokchah, M. Rial, C. Petot, G. Petot-Ervas 813

Thermopower of Highly Donor Doped Sri_xLaxTIO3-CeramicsR. Moos, A. Gnudi, K.-H. Hardtl 815

Oxide Ionic Conductors in the System Bi2O3 - PbO - Y2O3E. N. Naumovich, S. A. Skilkov, V. V. Kharton, A. A. Vecher 819

Oxide Ionic and Electronic Conductivity of SrCoi_xMxO3-

Xll

Mechanical Relaxation Measurements in the Protonic Conductors SrCeO3 and SrZrO3L. Zimmermann, H.G. Bohn, W. Schilling, E. Syskakis 857

EPR Study of the Cerium Valence State in Nd2_xCexCuO4C.B. Azzoni, A. Pateari, F. Scardina, L. Bolis, G. Spinolo 861

Cathodic Polarization of Lao.9Mn03-$ Screen-Printed Electrodes on Thin YSZ ElectrolyteLayers

F.M. Figueiredo, JA. Labrincha, J.R. Frade, F.M. Marques 865

Thermoelectric Properties of CdIn2O4 with Spinel StructureY. Ochi 869

Low Temperature Sol-Gel Syntheses of the Cubic Zirconium Oxide for Ceramic SolidElectrolyte Production

M.V. Tsodikov, O.G. Ellert, O.V. Bukhtenko, D. I. Kochubey 873

Electrical Properties of Bioactive Ceramics in a Broad Frequency and Temperature RangeH. Rail, P. Lunkenheimer, J. Alkemper, H. Fuess, R. Bohmer, A. LokJI 875

Kinetics of Charge Carriers in Nd2CuO4 and Nd2Cui_xLix04_5 (0

Xll l

EBSP and SIMS Studies of Oxygen Tracer Diffusion in the High Temperature SuperconductorLa2-xSrxCu04-6

J.CIaus, G.Borchardt, S.Weber, S.Scherrer 917

The Oxygen Content of the High-Temperature Superconducting CompoundBi2+xSr3_yCay Cu2Og.ni with Respect to Varying Ca and Bi Contents

P. Majewski, H.L. Su, F. Aldinger 923

Possible Application of HTSC Ceramics in Power EngineeringP. Komarek 929

Enhancement in Critical Current Density of Ultra-Fine MgO Added Bi-2212/Ag CompositeTape under Magnetic Field

H.-D. Kim, J.-W. Ko, S.-Y. Lee, K.-H. Ha, J.-H. Ahn, H.-S. Chung, K. Togano 939

Processing of YBaCuO by a Sol-Gel Precursor: Sintering and Weak Links BehaviourF.J. Gotor, P. Odier, N. Pellerin, A.R. Fert 945

Melt Processing of YBa2Cu3O7G.J. Schmitz 951

Phase Diagrams as the Guide for Microstructure Control of Y-Ba-Cu-0 CeramicsG. Krabbes, P. Schatzle, U. Wiesner, W. Bieger, G. Stover 957

Phase Equilibria in the System Bi203/Pb0-Sr0-Ca0-Cu0 with Special Regard to the(Bi,Pb)2Sr2Ca2Cu30io+d Phase

S. Kaesche, P. Majewski, F. Aldinger 961

Thin Films of YBa2Cu307_x for Microwave ApplicationsJ. Musorf, E. Waffenschmidt, X. He, F. Arndt, K. Heime 965

Preparation and Characterization of YBa2(Cui_xZnx)3O7-$ Thin FilmsM. Ye, M. Mehbod, R. Deltour, Y.F. Guo, C. De Boeck, P.H. Duvigneaud, G. Moorgat,F. Cambier 969

Phase Diagrams of the Systems La(Nd)2Cui_xLix04_5 and La(Nd)2CuLix04+ 8 >n a SubsolidusRegion

O.N. Razumovskaya, L.M. Rudkovskaya, L.A. Shilkina, V.I. Makarov 973

Electrochemical Deposition of Superconducting Bi-Sr-Ca-Cu-O and Tl-Bi-Sr-Ca-Cu-OFilms on Silver Substrate

S. Chatterjee, S. Banerjee, B.K. Chaudhuri 975

Controlled Precipitation of Pinning Centres During Melt Growth of Freeze Dried PrecursorsD. Dterickx, O. van der Biest, W. Boon, K. Rosseel, Y. Bruynseraede 979

XIV

Influence of the Oxygen Partial Pressure During Cooling Procedure, and Mechnical Stresses onthe Superconducting Properties of Ag-Bi2Sr2CaCu2Ox Screen-Printed "Bipes

BA. Glowacki 983

Sol-Gel Chemistry of Y - B a - C u - 0 SystemM. Bele, S. Pejovnik 987

Synthesis of Single-Phase Bi2Sr3CaCu2Og+5 Superconductor by Spray-Drying Nitrate-EDTASolution and Characterization

Y.-F. Guo, P.-H. Duvigneaud 989

Low Temperature and Low P02 Preparation of Melt Quenched High-TemperatureSuperconducting Bi2212 Bulk Ceramics

P. Majewski, S. Kaesche 993

Preparation, Characterization and Optimization of YiBa2Cu3O7_3c and Bi2Sr2CaiCu2Og+8 ThinFilms

J. Auge, U. Rudiger, B. Beschoten, H.G. Roskos, G. Guntherodt, H. Kurz 997

Bi-Sr-Ca-Cu Superconducting Ceramics Prepared from Amorphous MaterialN. Nanba, M. Kokubun, K. Nagata 1001

Preparation and Densification of HTc (2223) Phase SuperconductorA. Tampteri, G. Celotti, G.N. Babini 1005

Ferroelectric and Superconducting Properties of YBa2Cu3O7_8—BaT103 CompositesSA. Gridnev, S.A. Fadeev, S.P. Rogova 1009

Determination of Temperature Dependence of Oxygen in YBa2Cu3Ox by Structure RefinementsBased on Powder X-Ray Diffraction Analysis

K. Ikeda, T. Horiuchi, H. Shima 1011

Low-J'ield Dependence of the Intergranular Jc Measured Using AC SusceptibilityA. Buekenhoudt, J. Cornells 1015

Polarized Dght Microstructure Analysis of DYBa2Cu3O7_x Melt Textured in Magnetic FieldP. Diko, M. Ausloos, R. Cloots 1019

7_x Superconductive Tapes and Wires: Suspension Spinning and Tape Casting Using aPhase Inversion Technique

H. Weyten, W. Adriansens, V. Bukenbergs, A. Buekenhoudt, R. Leysen, J. Comelis 1021

Densification of Y2BaCuOs Substrates for Solid-Liquid Processing of YBa2Cu3O7_xSuperconductive Layers

L. Ryelandt, J. Lapin, F. Delannay 1025

Grain Growth in YBa2Cu3O7_x (123)-Y2BaCu05 (211) Sintered Powder CompositesI. Sargankova, P. Diko 1029

Relaxation of Mechanically Milled YBa2Cu3O7_x Studied by Differential Scanning CalorimetryI. Sargankova, P. Diko, S. Matas, J. Mihalik, M. Reissner, W. Steiner 1031

I N T E G R A T E D F U N C T I O N S A N D SUBSTRATES

Miniaturization and Integration of Passive Components by Multilayer Ceramic TechnologyA. Okamoto 1035

Ceramic Multilayer Modules: A New Concept for Integration of Passive ComponentsP.H.M. Keizer, W.R. De Wild 1045

Integrated Passive Functions: Toward a new Generation of ChipsH. Salze 1055

Composite "Moonie" Actuator and its ReliabiltiyA. Dogan, K. Uchino, R.E. Newnham 1061

Multilayer Electronic CeramicsD. Schmid, B. Hoffmann 1069

Improvement of Multilayer Chip LC Filters Utilizing a New Ceramic Material for HighFrequency, Low-Loss Functional Devices

U. Ender, B.E. Helms et al 1075

SAW Properties of La, Sm Modified Lead TStanate CeramicsC.E. Millar, L. Pedersen, L. Pardo, J. Ricote, C. Atemany, B. Jimenez.G. Feuillard,Y. Janin 1083

Modern Substrate Concepts for the Microelectronic IndustryA. Roosen 1089

Integrated SubstrateR.R. Tummala 1097

AI2O3-AI2O3 Laminnar CeramicsJ. Ravez, V. Andriamampianina, J.L. Miane, P. Letullier, J.M. Heintz 1105

Sintering and Properties of Aluminium Nitride SubstratesD. Ltoert 1107

XVI

Sintering of Ruthenium Oxide-Based Resistive CoatingsA. Ntemann, G. Roche, P. Marchet, J.P. Mercurio 1111

Diffusion of Titanium into Alumina Ceramics using Active SoldersW.K. Wtosinski, W. Otesinska, A. Bien 1115

Problems of Surface Conductivity in Electrical Resistance Measurements and Their Implicationfor the R E D Effect

F. Scneuermann, W. Kestemich 1119

Fabrication and Characterization of Erbium-Doped LiNbO3 for Integrated OpticsM. Fleuster, L. Beckers, St. Bauer, W. Zander, Ch. Buchal, H. Holzbrecher, U. Breuer 1123

MAGNETICS

Recent Developments in Power FerritesJ. Pankert 1129

Effect of Additions on Electromagnetic Properties of High Frequency MnZn FerritesR. Lebourgeois, J.P. Ganne, S. Pignard, P. Garrin, B. Lloret 1137

Dry Pressing of Tliin -Walled Ferrite PotcoresM.J.M. de Graaf, R.J.A. van der Drift, H.J. Glass 1143

Low Temperature Sintering in Ni-Zn-Cu FerriteT. Nakamura, T. Tsutaoka 1149

Microcrystalline and Nanocrystalline Hexaferrites Prepared by the Glass Crystallization MethodP. GSrnert 1155

Magnetostrictive and Demagnetizing Phenomena in FerritesP. Perriat, M. Guyot 1157

3 D ^ E M Modelling of Ferrite Cores Power Losses and Corresponding Temperature DistributionM. Esguerra, R. Lucke 1159

Ferrimagnetic Thin Films Prepared by Pulsed Laser DepositionM. Guyot, R. Krishnan, A. Lifsi, M. Porte, M. Raibaut, P. Renaudin, P. Rougier, M. Tessier,V. Cagan 1165

The Preparation of Fe-Ferrite and its Magnetic PropertiesM. Alavi, J. Amighian, E. Musavi 1167

XV11

Preparation of Isotropic Ba-Hexaferrite Using Hematite By-Product of Local Steel FactoryJ. Amighian, M. Mozaffari 1171

The Preparation and Thermal Properties of Cobalt Ferroxplana Single CrystalS.J. Kim, T.O. Kim 1175

Sol-Gel Derived Fine Hexaferrite ParticlesC. Surig, K.A. Hempel, D. Bonnenberg, J. Roumen, H.^J. Klaar 1179

Glass Crystallization of Nanocrystalline BaFei2-2XCoxTixOi9 ParticlesR. Muller, W. Schuppel, P. G6rnert 1183

About New Magnetic CoIn2Se4T. Koneshova, O.G. Ellert 1187

Microstructure and Electromagnetic Properties of Polycrystalline YIG Containing DopantsJ.-D. Lee, T.-O. Kim 1189

Magnetic Susceptibility and Dielectric Studies on Iron-Titanium Oxygen System at LowTemperatures

R.P. Viswanath, A.T. Seshadri 1193

Sol-Gel Processing of YIG Fibers and FilmsF. Essl, A. Thierauf, R. Jahn, D. Sporn, M. Baier, A. Forchel 1197

PROCESSING AND MECHANICAL PROPERTIES

Fracture of Dielectric Ceramics: A Brief ReviewG. de With 1 2 0 3

Crack Growth in Ferrroelectric Ceramics under Mechanical and Electrical LoadingG.A. Schneider, A. Rostek, B. Zickgraf, F. Aldinger 1211

Mechanical Reliability of Ferrite Cores: Thermo-Mechanical Stress in Operating Conditionsand in Strength Tests

LJ.M.G. Dortmans, M.J.M. de Graaf, G. de With 1217

Electric and Magnetic Field Contribution to the Microwave Sintering of CeramicsA. Cherradi, G. Desgardin, J. Provost, B. Raveau 1219

Spin-On Processing of Perovskite Thin Films for Innovative Microelectronic DevicesM.KIee 1 2 2 5

XV111

Single Crystal Thin Films via Solution Precursor ProcessingF.F. Lange 1233

Chemical Homogeneity and Morphology of Alkoxy-Derived PZT PowdersM. Kosec, B. Malic 1245

Processing and Properties of Wet-Chemically Derived Modified PZT Thin FilmsS. Seifert, S. Meridein, W. Grond, A. Schonecker 1251

Surface Segregation, Microstructure and Sinterability of a -Alumina Powders Doped withMagnesium

M. Tebtoub, D. Monceau, M.C. Amamra, C. Petot, G. Petot-Ervas 1255

Low Sintering PZT by Liquid Phase FormationH.-O. Gesemann, A. Schdnecker 1259

Electrical Conductivity of LaCrO3 Sintered at Low Temperature (

XIX

Novel Preparation Method and Properties of PTS and PZTS Glass-CeramicK. Yao, L. Zhang, X. Yao 1303

Preparation and Properties of ZnS Doped GlassH. Liu, S. Wang, S. Lu, L. Zhang, X. Yao 1307

PUT Powders from Water Soluble PrecursorsW. Liu, L Zhang, X. Yao 1311

Sol-Gel Synthesis and Characterization of a Conducting Ceramic/Metal CompositeS. Dandoy, I. Baukens, M. Ghodsi 1315

Processing and Physical Properties of Sol-Gel Derived Nanostructured Ni-ZrO2 CermetsJ. GroBmann, K. Rose, D. Sporn 1319

Zirconia-Tungsten ElectrocompositeS. Vives, C. Guizard, L. Cot, C. Oberlin 1323

Properties of Ceramics-Copper Joint "Directly Bonded" by Means of Copper-Carbon FibreComposite

W.K. Wlosinski, Z. Librant, W. Olesinska 1327

Electrotechnical Ceramics, Based on Porcelain Stones of KirgistanS.J. Jekisheva, T.I. Koneshova 1331

Electrotechnical Porcelain Based on Calcinated Caoline with Addition of MineralisatorG.N. Maslennikova 1333

Gel Cordierite for Electronic PackagingA. Goldstein, V. Belov, I. Belov 1335

Powder Preparation of Inorganic Materials by Spray DryingH.A.M. van Hal, W.A. Groen 1339

Electrophysical Properties of CasGasOu Single CrystalsS.L Londar 1343

Preparation of Materials with Controllable Grain Boundary Size from Water-Soluble Com-pounds

L.A. Reznitchenko, O.N. Razumovskaya, LA. Shilkina, V.A. Aleshin, V.I. Makarov,Yu.F. Korovin, V.G. Chiprinko, A.G. Okhapkin 1345

Conformational Mechanism of Pyroelectric Response in Macromolecules SystemsN.N. Matveev, A.F. Klinskikh 1349

A Possible Application of Volcanic Stones for Electric and Electronic CeramicsE. Albert 1351

XX

Preparation of La Doped Sr(Ti(i_y)Zry)O3 (y = 0... 1) Dielectric Ceramic Thin FilmsS. Hoffmann, M. Klee, R. Waser 1353

Hot-Forging of Ba6-3XSmg+2XTiigO54 Ceramics for Microwave ApplicationsCh. Hoffmann, R. Waser 1357

Pulsed Laser Deposition and Patterning of Electroceramic Thin FilmsM. Mertin, D. Offenberg, C.W. An, DA. Wesner, E.W. Kreutz 1361