draft trip report - integrated assessment · dear ms. wagner. tetra tech em inc. (tetra tech) is...

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SDMS DocID 2095107

April 14,2006

Ms. Christine Wagner (3HS32) On-Scene Coordinator (OSC) U.S. Environmental Protection Agency Region 3 1630 Arch Street Philadelphia, Pennsylvania 19103

Subject: Draft Trip Report for the Oceana Salvage Site - Integrated Assessment EPA Contract No. EP-S3-05-02 Technical Direction Docoment No. £03-001-06-01-001 Document Tracking No. 0132

Dear Ms. Wagner.

Tetra Tech EM Inc. (Tetra Tech) is submitting the draft trip report for the Oceana Salvage site that summarizes the integrated assessment sanpling events conducted in January 2006. If you have any questions regarding this report, please call me at (610) 364-2132.

Sincerely,

a a Enclosure

cc: TDD File

AR100122

Draft TRIP REPORT FOR THE

OCEANA SALVAGE SITE INTEGRATED ASSESSMENT

VIRGINIA BEACH, VIRGINIA BEACH CITY, VIRGINIA

Prepared for

U.S. Environmental Protection Agency Region 3 1650 Arch Street

Philadelphia, Pennsylvania 19103

Submitted by

Tetra Tech EM Inc. 7 Creek Parkway, Suite 700

Boothwyn, Pennsylvzinia 19061

EPA Contract No. EP-S3-05-02

EPA Site Spill ID A3EH

Technical Direction Document No. E03-001 -06-01 -001 , Document Tracking No. 0132

April 14, 2006

Prepared by Approved by

Marian Murphy Site Lead '" START Point of Contact

AR100123

CONTENTS Section Page

1.0 INTRODUCTION 1

2.0 BACKGROUND 1 2.1 SITE LOCATION : 1 2.2 SITE DESCRIPTION AND HISTORY 2 2.3 PREVIOUS SITE ACTIVITIES. 5

3.0 SITE ACTIVITIES 6 3.1 SAMPLE COLLECTION .: 6

3.1.1 Surface Soil Sampling , , 9 3JL,2__S_ubsurface_Soil_Sampling.„. ™™„ ^ ™ 10 3.1.3 Sediment Sampling 11 3.1.4 Surface Water Sampling 11 3.1.5 Non-potable Groundwater Sampling 12 3.1.6 Potable Groundwater Sampling 12

3.2 SAMPLE HANDLING PROCEDURES 13 3.3 ADDITIONAL SITE ACTIVITIES 13

4.0 ANALYTICAL RESULTS 13

5.0 SUMMARY 13

REFERENCES 15

Appendix

A Oceana Salvage Site Sketch

B Oceana Salvage Site Photographic Documentation

Attachment

Validated Analytical Data Packages

AR100124

FIGURES Figure Page

1 SITE LOCATION MAP.. 3

2 SITE LAYOUT MAP 4

3' SAMPLING LOCATION MAP; 7

TABLES Table Page

1 SAMPLING SUMMARY 8

AR100125

1.0 INTRODUCTION

Under Eastern Area Superfund Technical Assessment and Response Team (START) Contract

No. EP-S3-05-02, Technical Direction Document (TDD) No. E03-001-06-01-001, U.S.

Environmental Protection Agency (EPA) Region 3 tasked Tetra Tiech EM Inc. (Tetra Tech) to

conduct an integrated assessment at the Oceana Salvage site in Virginia Beach City, Virginia.

The objectives of this integrated assessment were to: (1) characterize the extent of contamination

on site, (2) characterize off-site migration, (3) evaluate whether substances present on site pose

an immediate threat to human health or the environment, and (4) collect analytical data to assess

-need-for-additional-action-under-the-Gomprehensiye^nvirGnmental-ResponserCompensation,

and Liability Act (CERCLA) as amended by the Superfund Amendments and Reauthorization

Act (SARA). Multimedia samples were collected to measure total concentrations of lead, the

contaminant of concem, in accordance with the sampling and analysis plan for the Oceana

Salvage site (Tetra Tech 2006b). For the integrated assessment, Tetra Tech collected field

samples from January 30,2006, through January 31,2006.

This trip report provides site background in Section 2.0, describes site activities in Section 3.0,

summarizes analytical results in Section 4.0, and summarizes the seimpling event in Section 5.0.

All references cited in this report are listed after the text.

2.0 BACKGROUND

This section describes the site location and summarizes previous activities and investigations at

the site.

2.1 SITE LOCATION

The Oceana Salvage site is located at 1040 South Oceana Boulevard (Virginia State Route 615)

in Virginia Beach City, Virginia, as shown in Figure 1, Site Location Map (USGS 1989a, 1989b).

The geographic coordinates for the approximate center of the site are 36.812250° north latitude

and 75-978908° west longitude. The site is bordered to the north and west by Oceana Naval Air

Oceana Salvage Site Tetra Tech EM Inc. Draft Trip Report TDD No. £03 -001 -06-01 -001 ApriI14,2006 Page 1 ofl6

AR100126

Station (NAS) property, to the east by the Holiday Trav-L-Park camp sites, and to the south by

undeveloped land.

2.2 SITE DESCRIPTION AND HISTORY

The Oceana Salvage site is located primarily at the Oceana Salvage Yard (salvage yard), which is

owned by Oceana Salvage, Inc (OSI). According to Nick Anoia, the owner of the Anoia

Recycling, LLC, the OSI property is leased by Anoia Recycling, LLC from Ms. Malban, the wife

of the former owner/operator of OSI. The Oceana Salvage Yard is operated by Anoia Recycling,

XLC as an auto salvage and recycle yard~(Tetra 'lech~2006a). Physical access to the salvage yard

is via an unpaved gravel roadway connecting Oceana Salvage Yard to Oceana Boulevard,

approximately 1,200 feet north of the main entrance to NAS. A three-strand, barbed-wire and

post fence is installed along the property boundary between NAS and the Oceana Salvage Yard.

This type of fencing also delineates the boundary of the access road from Oceana Boulevard to

the salvage yard (Engineering and Environment Inc. [E«&E 2002]). A chain link fence is installed

along the property boundary between the Oceana Salvage Yard and the Holiday Trav-L-Park.

Figure 2, Site Layout Map (USGS 1994), illustrates the layout of the site.

The NAS property functions as an imoccupied buffer zone (with woodlands, wetlands, and open

fields) for the airbase. Materials of concern that have been observed on NAS property include ,

buried lead acid batteries, battery casing parts, battery tailings, and leeid-contaminated soil.

These materials were accumulated while conducting salvaging and battery recycling operations

during the early 1990s. The salvage yard has operated at its ctirrent location for approximately

45 years. During part of this time, OSI encroached on NAS property. Currently, OSI does not

conduct any salvaging operations on NAS property, and has reportedly discontinued all battery

recycling activities on the OSI site. Some waste materials from historic OSI operations remain

on NAS property (E&E 2002). Apparently, a large volume of crushed battery casings was

brought to the salvage yard in the 1960s and either biiried or used as fill material on the OSI and

NAS properties. Evidence suggests that OSI was also involved in "battery cracking," the

combined process of breaking open whole batteries and removing recyclable lead plates (E&E

2002).

Oceana Salvage Site Tetra Tech EM Inc. Draft Trip Report TDD No. E03-001 -06-01-001 April! 4, 2006 Page2ofl6

AR100127

Source: Modified from USGS T.S-Minute Series Topographic Quadrangles, Princess Anne, Virginia, 1965, Pbotorevised 1986, Photoinspected 1989 Virginia Beach. Virginia. 1%5. Pboloreviscd 1986. Photoinspected 1989

0.25 0.5 I Miles

Quadrangle Location = D

Virginia

Oceana Salvage Site Virginia Beach, Virgima

Figure 1 Site Location Map

TDD No. E03-001-06-01-001 EPA Contract No. EP-S3-05-02

Draft Trip Report

Ma^rgted on Januaiy 26,2006 Tetra Tech START

-v3„jr) Tv;.a, '-^^Hcf

Page 3 of 16 AR100128

7«vorv»

Quadrangle Location = D

Virginia

Oceana Salvage Site Virginia Beach, Virginia

Figure 2 Site L^out Map

TDD No. E03-001-06-01-001 EPA Contract No. EP-S3-05-02

Draft Trip Report

Mqa.CTeated

-3m on Jaouaiy 27,2006 Tetra Tech START

Page 4 of 16

AR100129

2.3 PREVIOUS SITE ACTIVITIES

On January 1992, the Virginia Department of Waste Management (VADWM) received a

citizen's complaint, VADWM #002576, alleging that petroleum product was intentionally

dumped and that battery cracking was conducted at the site. In April 1992, a representative of

the Virginia State Water Control Board (VA SWCB) investigated a small spill of petroleum

product as Pollution Complaint #92-1830. In June 1993, the Virginia Department of

Environmental Quality (VADEQ) conducted a joint inspection with VA SWCB and found on-

site storage of lead-acid batteries and battery wastes. In July 1993, VADEQ issued a notification

"of Violation, RI002376, and demanded that operations cease at the unauthorized battery

reclamation facility. Some of the batteries and casing materials were removed between 1993 and

1995 as part of the cleanup effort by OSI. The cleanup effort included one of the areas, referred

to as Burial Unit #1, where debris including scrap, auto parts, and battery wastes had been

accumulated and buried. Burial Unit #1 lies primarily on NAS property, but may extend onto

OSI property. The battery waste and contaminated soil removed from Burial Unit #1 was

temporarily stored in two piles, hazardous waste management unit (HWMU) #1 located on NAS

property, and HWMU #2 located on OSI property. The waste material was then moved to the

solidified waste area on OSI property and mixed with Portland cement. During cleanup actions,

OSI removed portions but not all of the waste materials from Burial Unit #1 (E&E 2002).

Soil sampling conducted by NAS in 1996 and by OSI in September 1997 indicated elevated

levels of lead throughout the site, including the Burial Unit #1 area. In November 1997, OSI and

VADEQ investigated Burial Unit #1 and found that crushed battery casing and other solid wastes

remamed buried there (E&E 2002). In July 2002, VADEQ issued a Consent Order to Oceana

Salvage, Inc., to complete cleanup of Burial Unit #1, to submit and implement a closure plan for

Waste Piles #1 and #2 (HWMU #1 and #2, respectively), and to submit and implement a

groimdwater monitoring plan (VADEQ 2002). To date, OSI has not met the requirements of this

Consent Order.

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AR100130

3.0 SITE ACTIVITIES

This section summarizes sample collection, sample handling procedures, and other site activities.

3.1 SAMPLE COLLECTION

Tetra Tech collected surface soil, sediment, surface water, groundwater, potable water, and field

quality assurance/quality control (QA/QC) samples at the site for the integrated assessment on

Jantjary 30 and 31, 2006. Actual sample locations were chosen based on site conditions and

access. An x-ray fluorescence (XRF) unit (Niton 722s), visual evidence, and historical data Were

used to choose biased sampling locations.

A total of 29 multimedia samples were collected during the sampling event-eight surface soil,

nine sediment, eight surface water, one groundwater, and three potable water samples. Figure 3

presents the surface soil, sediment, surface water, and groundwater sampling locations at the

Oceana Salvage site.

During the sampling event, surface soil, subsurface soil, sediment, surface water, and

groundwater sampling locations were identified using a Trimble Global Positioning System

(GPS) unit. The Trimble GPS unit is capable of identifying locations with an accuracy of less ,

than 3 feet from the actual locations under normal field conditions.

The sample identifier, sample date, sample time, sample matrix, and comments for each sample

are documented in Table 1, Sampling Summary. The sample traffic reports are included as part

of the validated analytical data packages attached.

Oceana Salvage Site Tetra Tech EM Inc. Draft Trip Report TDD No. E03-001 -06-01 -001 AprilM, 2006 Page 6 of 16

AR100131

Legend O Sampling location

I ^ ^ { Approximate property boundary

Approximate burial unit #1 bonndaiy

' ~ Waste pile #1

Source: Modified from USGS Digital Ortliophoto (DOQQ) mosaic for Princess Anne Quadrangle, Virginia. Virginia Economic Development Partnership, 1994

Quadrangle Location = O

Virginia

Oceana Salvage Site Virginia Beach, Virginia

Figure 3 Sampling Location Map

TDD No. E03-001-06^ 1-001 EPA Contract Na EP-S3-05-02

Map cretted on April 11,2006 Fetra Tech START

Draft Trip Rq)ort So

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AR100132

TABLE 1

Sample Identifier

, SW-01

SW-02

SW-03

-SW--04-

SW-05

SW-08

SW-09 SW-FB-01

SD-01

SD-02

SD-03

SD-04

SD-05

SD-06

SD-07

SD-08

SD-09

GW-01

PW-01

PW-02

SAMPLING SUMMARY

Sample Date

1/30/2006

1/30/2006

PW-FB-01

1/30/2006

"1/30/2006-

1/30/2006

1/30/2006

1/31/2006 1/30/2006

1/30/2006

1/30/2006

1/30/2006

1/30/2006

1/30/2006

1/30/2006

1/30/2006

1/30/2006

1/31/2006

1/30/2006

1/30/2006

1/30/2006

1/30/2006

Sample Time

Sample Matrix

13:15

13.50

14:10

-14r20-

14.35

17:00

8:40 13:00

13:15

13:50

14:10

14:20

14.35

15:30

15:45

17:00

8:40

14:50

16:30

16:40

13:05

Surface Water

Surface Water

Surface Water

Surface -Wa te r -Surface Water

Surface Water

Surface Water

Field QC

Sediment

Sediment

Sediment

Sediment

Sediment

Sediment

Sediment

Sediment

Sediment

Ground Water

Potable Well

Potable Well

Field QC

Latitude and Longitude

36.8080845720 -76.0009188970 36.8072632710 -76.0007283760

36.8055459350 -76.0012600380 36.8055459350 =76:001-2600380 36.8058319230 -76.0022435470 36.8023449220 -75.9943703200

36.8009239850 -75.9927875060

36.8080845720 -76.0009188970 36.8072632710 -76.0007283760

36.8055459350 -76.0012600380 36.8055459350 -76.0012600380 36.8058319230 -76.0022435470 36.8081020670 -75.9999068350 36.8074361130 -76.0004881610 36.8023449220 -75.9943703200

36.8009239850 -75.9927875060

36.8059820640 -76.0015179990

36.8051723870 -75.9963974970 36.8051723870 -75^9963974970

Comments

On site, drainage ditch on western boundary of site, wetland area, PPE On site, drainage ditch on eastern

boundary of site, PPE On site, confluence of drainage

ditches in southeast corner of site, downstream of site

-Bupl icateof^W^a-On site, south side of site wetland

area, PPE Off site, east side of HTP near

cabin C51. downstream of SW-03 Off site, east side of General Booth Boulevard in tributary to Redwing

Lake, downstream of SW-08 Field Blank

On site, drainage ditch on western boundary of site, PPE

On site, drainage ditch on eastern boundary of site. PPE

On site, confluence of drainage ditches in southeast comer of site,

downstream

Duplicate of SD-03 On site, south side of site wetland

area, PPE Off site, drainage ditch west side of HTP between campsites 549 & 552 Off site, drainage ditch west side of HTP behveen campsites 556 & 557

Off site, east side of HTP near cabin C51, downstream of SD-03

Off site, east side of General Booth Boulevard in tributary to Redwing

Lake, downstream of SD-08

On site, non-potable well

Off site. HTP potable well

Duplicate of PW-01 Field Blank

Oceana Salvage Site Draft Trip Report April 14, 2006

Tetra Tech EM Inc. TDD No. E03-001-06-01-001

P a g e 8 o n 6 AR100133

Site surface soils were screened in situ by XRF at approximately 100-foot intervals. Two areas

of lead-contaminated soil were identified at the site using in situ XRF screening: waste pile #1

containing approximately 100 cubic yards of soil, and waste pile #2 containing approximately 5

cubic yards of soil. No other areas of lead contamination in surface soil were detected above the

limit of detection for the XRF approximately 100 to 200 milligrams per kilogram. Sample SS-04

was collected at the toe of a large soil pile at the southeast comer of the site to coiifirm the XRF

result of non-detect. Soil samples SS-05 to SS-08 were collected at campsites on the Holiday

Trav-L-Park property to document off-site migration of lead. No additional areas of elevated

^eadcontamination'WeredetectedDfiF'siteby'iirsitcrXRF screening; therefoFe, sampling^locations

were chosen along the site perimeter between the Holiday Trav-L-Park and the Oceana Salvage

yard.

Tetra Tech also recorded sample identifiers, sample dates, sample times, and sample locations on

data sheets. The soil was homogenized in a clean disposable alxmiinum pan and placed in a

certified-clean, labeled, clear, wide-mouth glass jar for shipment to the approved laboratory.

Dedicated plastic scoops and nitrile gloves were used for sampling and to transfer the

homogenized soil to jars. Soil samples were collected in accordance with Tetra Tech SOP No.

005, "Soil Sampling" (Tetra Tech 1999b).

3.1.2 Subsurface Soil Sampling

Subsurface soil samples were not collected because surface sampling of the waste pile #1 was

sufficient for the purpose of identifying a source on the OSI property. In addition, EPA did not

have access to sample the NAS property where previous data show that the lead battery waste

had been buried.

Oceana Salvage Site Tetra Tech EM Inc. Draft Trip Report TDD No. E03-001-06-01-001 April 14,2006 Page 10 of 16

AR100134

3.1.3 Sediment Sampling

Sediment samples were collected from the drainage ditches around the site and downstream of

the site; Nine sediment samples were collected. Five sediment samples (SD-01 to -05) were

collected on site, including one duplicate sample. Two sediment samples (SD-06 and -07) were

collected in drainage ditches on the Holiday Trav-L-Park property close to the site. Two

downstream sediment samples (SD-08 and -09) were collected in the tributary between the site

and the Redwing Lake. Tetra Tech did not collect upstream samples because EPA did not have

access to the NAS property upgradient of the site.

Sediment samples were collected using disposable poly scoops and nitrile gloves. Sediment was

placed into a disposable aluminum pan, and the sample was homogenized with a dedicated

plastic scoop. Large rocks, debris, and excess water were removed from the sediment sample

before the sediment was placed into certified-clean, labeled, clear, wide-mouth glass jars for

shipment to the approved laboratory. Sediment sampling was conducted following Tetra Tech

SOP No. 006, "Sediment and Sludge Sampling" (tetra Tech 2000b). All sediment sampling

equipment was dedicated.

3.L4 Surface Water Sampling

Eight siirface water samples were collected, including one duplicate and a field blank. Four

surface water samples (SW-01, -02, -03 and -05) and one duplicate sample (SW-04) were

collected in the drainage ditches around the site. Two surface water samples (SW-08 and -09)

were collected downstream, east of the site between the site and Redwing Lake. The surface

water had little or no visible flow. At the location of surface water sample SW-08, the stream

flowed slowly—less than 1 cubic foot per second—from the culvert that passed under General

Booth Boulevard. The sampling locations where surface water samples SW-01, SW-05, and

SW-09 were collected have characteristics of wetlands. The nature and extent of the wetlands

were not formally characterized during this event. Tetra Tech did not collect upstream samples

because EPA did not have access to the NAS property slightly upgradient of the Oceana Salvage

yard.

Oceana Salvage Site Tetra Tech EM Inc. Draft Trip Report TDD No. E03-001-06-01-001 April 14, 2006 Page 11 of 16

AR100135

Samples were collected directly into a certified-clean, wide-mouth, 1-liter plastic jar preserved

with nitric acid (HNO3) to a pH less than 2. Water samples were collected in accordance with

Tetra Tech SOP No. 009, "Surface Water Sampling" (Tetra Tech 1999c).

3.1.5 Non-potable Groundwater Sampling

Tefra Tech collected one non-potable groundwater sample (GW-01) during this sampling event.

The depth of this well, located on the site, was not available. Tetra Tech samplers noted that the

""well'waterhad'aswampyodOT:

At the sampling location, Tetra Tech purged the well for 15 minutes from the outside spigot

Only dedicated sampling equipment was used to collect groundwater samples. Groundwater

samples were collected in accordance with EPA Region 4 SOP, "Sampling of Potable Water

Supplies" (EPA 2001). The sample was collected directly into a certified-clean, wide-mouth, 1-

liter plastic jar preserved with HNO3 to a pH less than 2.

3.1.6 Potable Groundwater Sampling

Tetra Tech collected a total of three potable groundwater samples (PW-01), including a blank

(PW-FB-01) and a duplicate sample (PW-02). The potable well sampled was located on the

Holiday Trav-L-Park property. The depth of this well is not known.

At the sampling location, Tetra Tech purged the well for 15 minutes from the outside spigot at

campsite 130. Only dedicated sampling equipment was used to collect potable well samples.

Potable well samples were collected in accordance with EPA Region 4 SOP, "Sampling of

Potable Water Supplies" (EPA 2001). The sample was collected directly into a certified-clean,

wide-mouth, 1 -liter plastic jar preserved with HNO3 to a pH less than 2.

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AR100136

3.2 SAMPLE HANDLING PROCEDURES

Samples were handled and packaged in accordance with the Tetra Tech SOP No. 019, "Packaging

and Shipping Samples" and with the Tetra Tech "Quality Assurance Project Plan (QAPP) for

START' (Tetra Tech 2000a, 2005). All samples collected were sent through the EPA Region 3

Analytical Services and Quality Assurance Branch (ASQAB) under the Delivery of Analytical

Services No. R32432, The ASQAB laboratory was used for the analysis. Appropriate samples

were preserved, and all samples were kept on ice during delivery to the CLP-approved laboratory.

"33 ADDITIONAL SITE ACTIVITIES

The trash generated during the sampling event was disposed of as industrial waste at a solid

waste landfill. The well water was purged directly onto the ground from outside taps.

4.0 ANALYTICAL RESULTS

The following section presents the analytical results for surface soil, sediment, surface water,

non-potable groundwater, and potable groundwater samples collected during the January 2006

sampling event for the Oceana.Salvage site. The validated analytical packages are included as an

Attachment. All analytical data were validated through the Region 3 ASQAB using EPA Region

2 validation protocols "Region III Modifications to the Laboratory Data Validation Functional

Guidelines for Evaluating Inorganic Analyses" (EPA 1993) and "Innovative Approaches to Data

Validation" (EPA 1995).

5.0 SUMMARY

Tetra Tech conducted an integrated assessment sampling event at the Oceana Salvage site in

January 2006, collecting surface soil, sediment, surface water, non-potable well groundwater, and

potable well groundwater samples. The integrated assessment sampling event was conducted to

assist EPA in identifying: (1) the nature and extent of on site lead contamination, (2) off-site

Oceana Salvage Site Tetra Tech EM Inc. Draft Trip Report TDD No. E03-001-06-01-001 AprilM, 2006 Page 13 of 16

AR100137

migration of lead, and (3) whether any emergency removal work is required to mitigate the threat

to human health and the environment posed by the lead contamination.

The analytical results and field screening data indicate at least two sources of lead at the site—

waste piles #1 and #2. Lead was detected in the surface water and sediment samples collected

aroimd the site boimdaries. Lead was also detected in the groundwater on site.

The lead contamination has not yet impacted the Holiday Trav-L-Park potable well, about 0.25

mile from the site. Lead was detected at 98.7 micrograms per kilogram off site in surface soil

"saiTiple (SS-06)~collected ifom"tlieT?oliday^Trav-L^Pafk campsite 566~The other source of lead

contamination adjacent to the site is the NAS property, where lead battery casings and debris

were buried.

A fence is erected along little more than half of the perimeter between the site and the Holiday

Trav-L-Park; therefore, the on-site waste piles are accessible from some of the campsites at the

Holiday Trav-L-Park that border the site. However, these campsites are not used by long-term

campers (defined as up to 6-month stay), and no permanent residents reportedly live at any of

these campsites.

Oceana Salvage Site Tetra Tech EM Inc. Draft Trip Report TDDNo. EO3-0O1-06-O1-001 April 14, 2006 Page 14 of 16

AR100138

REFERENCES

Engineering and Envirpnment Inc. (E&E). 2002. "Remedial Action Plan Burial Unit No. 1." Virginia Beach, Virginia. August.

Tetra Tech EM Inc. (Tetra Tech). 1999a. "Recording of Notes in Field Logbook." Standard Operating Procedure (SOP) No. 024. November.

Tetra Tech. 1999b. "Soil Sampling." SOP No. 005. December.

Tetra Tech. 1999c. "Surface Water Sampling." SOP No. 009. December.

"Tetra Tech. 2006&. "Packaging and Shipping Samples." SOP No. 019. January.

Tetra Tech. 2000b. "Sediment and Sludge Sampling." SOP No. 006. December.

Tetra Tech. 2000c. "Groundwater Sampling." SOP No. 010. March.

Tetra Tech. 2005. "Quality Assurance Project Plan (QAPP) for START." August.

Tetra Tech. 2006a. "Oceana Salvage Site Log Book." January 27.

Tetra Tech. 2006b. "Sampling and Analysis Plan for the Oceana Salvage Site" March 31.

U.S. Environmental Protection Agency (EPA). 1993. "Region III Modifications to the

Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses." Region 3 Office of Analytical Services and Quality Assurance (OASQA). Fort Meade, Maryland. April.

EPA. 1995. "Innovative Approaches to Data Validation." Region 3 OASQA. Fort Meade, Maryland. June.

EPA. 2001. "Sampling Potable Water Supplies." EnvironmentallrrvestigationsStandard Operating Procedures and Quality Assurance Manual, Section 8. Region 4, Athens, Georgia. November.

CommonvvealthofVirginiaDepartmentof Environmental Quality (VADEQ). 2002. "Virginia Waste Management Board Enforcement Action Order by Consent Issued to Oceana Salvage, Inc." Virginia Beach, Virginia. July 30.

Oceana Salvage Site Tetra Tech EM Inc. Draft Trip Report TDD No. E03-001 -06-01 -001 April 14, 2006 Page 15 of 16

AR100139

REFERENCES (continued)

U.S. Geological Survey (USGS). 1989a. USGS 7.5-Minute Series Topographic Quadrangles, Princess Arme, Virginia. 1965, Pbotorevised 1986, photoinspected 1989.

USGS. 1989b. USGS 7.5-Minute Series Topographic Quadrangles, Virginia Beach, Virginia. 1965, Pbotorevised 1986, photoinspected 1989.

USGS. 1994. USGS Digital Orthophoto (DOQQ) mosaic for Princess Anne Quadrangle, Virginia. Virginia Economic Development Partnership. Modification.

Oceana Salvage Site Tetra Tech EM Inc. Draft Trip Report TDD No. E03-001 -06-01 -001 April 14,2006 / Page 16 of 16 AR100140

APPENDIX A

OCEANA SALVAGE SITE SKETCH

2 pages

AR100141

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I hi K:^^ .^J TETRA •fECTI "EM Mi: Client: EPA Region 3 Site Name: Oceana Salvage Site Location: Virginia Beach, Virginia Date: April 14,2006

^/îogr^fhie OoeumwiimikHt Prepared by: Tetra Tech EM Inc. Photographer: flJHHl^ TDD Number: EOôBSÔl-OOl

Photograph No. 1

-Photograph Date:—January-30r 2006

Orientation: Northeast

Description: Oceana Salvage yard front office.

Photograph No. 2

Photograph Date: January 30, 2006

Orientation: Northwest

Description: Waste Pile #2 in foreground with battery casings and debris. Waste Pile #1 in background.

: ^ ^ * . ^ - ' i . .«-•>*.•• • ' • ' . • • . • - : ' • ' • " • • • ..'-..'-"i.r, - *- .Cr? IB'.' I^WiK*^K53^JS»?

Paw 1 of 9 AR100144

APPENDIX B

OCEANA SALVAGE SITE PHOTOGRAPfflC DOCUMENTATION

9 pages

AR100145

TETKA TECH EM IMC Client: EPA Region 3 Site Name: Oceana Salvage Site Location: Virginia Beach, Virginia Date: April 14, 2006

Prepared by: Tetra Tech EM Inc. PhotographeR 4 f l H P H k TDD Number E03-001-06-01-001

Photograph No. 3

Photograph Date: January 30, 2006 -=—

Orientation: Northeast

Description: Oceana Salvage yard. Waste Pile #2 middle right. "Clean fill" soil pile in background at &r end of yard.

Photograph No. 4


Orientation: West

Description: Waste Pile #1.

Paw 2 of 9 AR100146

. - .•^-^ TETl^A TECH EM E-^C Client: EPA Region 3 Site Name: Oceana Salvage Site Location: Virginia Beach, Virginia Date: April 14,2006

Prepared by: T r t r a T w ^ M Inc. Photographer: ^ ^ H ^ B B TDD Number: E03-001-06-01-001

Photograph No. 5


Orientation: North

Description: Fragmities and bamboo at location of samples SD-01 and SW-01. Center northwest boundary of Oceana Salvage yard.

Photograph No. 6


Description: Fragmities and bamboo at location of samples SD-01 and SW-01. Center northwest boundary of Oceana Salvage yard.

Paw 3 of 9 AR100147

A TECH EM mC CUent: EPA Region 3 Site Name: Oceana Salvage Site Location: Virginia Beach, Virginia Date: April 14, 2006

Prepared by: Tetra Tech EM Inc. Photographen B H H p H I TDD Number: E03-001-06-01-001

Photograph No. 7


Description: Fn^gmitiesand bamboo at location of samples SD-01 and SW-01. Center northwest boundary of Oceana • Salvage yard. Barbed wire fence marks the boundary between Oceana NAS and Oceana Salvage yard.

'fife

Photograph No. 8


Orientation: Southeast

Description: Waste Pile #1 viewed from drainage ditch.

Paw 4 of 9 AR100148

• i '.'•

TETl^A TECH "EM INC. Client: EPA Region 3 Site Name: Oceana Salvage Site Location: Virginia Beach, Virginia Date: April 14, 2006

Prepared by: Tetra Tech EM Inc. Pho tographe r :mHVi i f t TDD Numben E03-001-06-01-001

Photograph No. 9


Orientation: Southwest

Description: Bamboo at location of samples SD-03 and SW-Q3. Southeast comer of Oceana Salvage yard.

Photograph No. 10



Description: Fragmities at location of san^les SD-OS and SW-05. Southwest end of Oceana Salvage yard.

Paw 5 of 9 AR100149

j -a tsi? \ il_> .1 .TVJ7A .1 . i j V,- .^ .1 i,-jl^'i. •.J. 4 V- -

Client: EPA Region 3 Site Name: Oceana Salvage Site Location: Virginia Beach, Virginia Date: April 14, 2006

Photograph No. 11

Photograph Date: Januaiy 30, 2006


Description: Location of sample SS-OS. Oceana Salvage yard viewed from Holiday Trav-L-Paik canping site 545. No fence at this location.

Prepared by: Tetra Tech EM Inc. Photographer: i f l m ^ P i TDD Number: E03-001-06-01-001

Photograph No. 12



Description: Location of sample SD-06. Drainage ditch on Holiday Trav-L-Park property.

Paw 6 of 9 AR100150

?.fa.| r%. ' ^ t ^ . ^ . . . ^ TETRA TECH CM INC CUent: EPA Region 3 Site Name: Oceana Salvage Site Location: Virginia Beach, Virginia Date: April 14, 2006

Phoio^;ifphie Ooetuumnimdion Prepared by: Tetra Tech EM Inc. Photographer: J ^ j p H P H P TDD Number: E03-001-06-01-001

Photograph No. 13

Photograph Date: January 30, 2006 •


Description: Location of sanple SD-07. Drainage ditch on ^ Holiday Trav-L-Park property.

Photograph No. 14



Description: Location of sample SS-06. HoUday Trav-L-Park propoty near campsite 566. Fence blocks access to the Oceana Salvage yard from the campsites at this location.

Paw 7 of 9 AR100151

TETRA TECH EM ENC Client: EPA Region 3 Site Name: Oceana Salvage Site Location: Virginia Beach, Virginia Date: April 14,2006

Prepared by: Tetra Tech EM Inc. Photographer: i ^ ^ H P I B TDD Number: E03-001-06-01-001

Photograph No. 15



Description: Location of sample SS-06. Holiday Trav-L-Paric propoty near campsite 566.

^ 1 \ S - ^ • • ' • : ^ ' ^'- '^i-- ^ i ' .

Photograph No. 16



Description: Location of samples PW-01 and SS-07. Holiday Trav-L-Park propaty campsite 130. Well was purged for 15 minutes.

Paw 8 of 9 AR100152

1

I • . . ^ ^ J TETl^A TECTi E:M INC. Client: EPA Region 3 Site Name: Oceana Salvage Site Location: Virginia Beach, Virginia Date: April 14, 2006

Phoiogfn^phic Ooeummaimaan Prepared by: Tetra Tech EM Inc. Photographer: i f l ^ H l f t TDD Number: E03-001-06-01-001

Photograph No. 17

Photograph Date: January 30, 2006 •

Orientation: Southeast

Description: Location of samples SW-08, SD-08, and SS-08 in foreground. Holiday Trav-L-Park property cabin C51.

Photograph No. 18


Description: Collection point of sample GW-01. Punq) for on-site, non-potable well. PVC piping between well and punp. Construction of well not known.

Page 9 of9 AR100153

ATTACHMENT

VALIDATED ANALYTICAL DATA PACKAGES

AR100154

^ ^ ^w^

^ P R O T * ^

U.S. EPA REGION III Analytical Services & Quality Assurance Branch

Environmental Science Center 701 Mapes Road

Fort Meade, Maryland 20755-^350

O

• . • ;: m ••••--•--•• X

^ •40M«K r.

LABORATORY FINAL RESULTS

OCEANA SALVAGE

Lab Request # : REQ06114 Request Form : DAS R32432 Report prepared on: 03/14/2006

Site contact(s) : Christine Wagner (3HS32)

Approved for release:

7 - •• • / '

A ? 6 A B Repr0jientative

J

ASC2AB Contact: Jill Bllyeu, Quality Assurance Officer Phone: 410-306-2638 E-mail: [email protected]

1 of 19 AR100155

mailto:[email protected]

U.S. EPA REGION III ANALYTICAL SERVICES £ QUALITY ASSURANCE BRANCH

SITE NAME:

LAB REQUEST #

OCUUU SALVAGE

MQ0C1L4 SAMPLE DESCRIPTIONS

SMHPI* i

06020119

06020720

06020721

06020722

06020723

06020724

0602072S

06020726

06020727

06020728

06020729

06020730

06020731

06020732

06020733

, 06020734

S, 06020735

" 06020736

06020737

06020738

06020739

06020740

06020741

06020742

06020743

06020744

0602074S

06020746

06020747

Statifin

GM-01

PH-01

PW-02

PW-FB-01

SD-01

SD-02

SD-03

SD-04

SD-05

SD-06

3D-07

SD-08

SD-09

SS-01

SS-02

SS-03

SS-04

SS-05

SS-06

SS-07

SS-08

S«-0l

SW-02

SW-03

SW-04

SW-05

SW-08

SW-09

SW-FB-01

Daacciction

GW-01

PW-01

PW-02

PM-FB-01

SD-01

SD-02

SD-03

SD-04

SD-OS

SO-06

SD-07

SD-08

SO-09

SS-01

ss-oi SS-03

SS-04

SS-05

SS-06

SS-07

SS-08

SW-01

SW-02

SW-03

SW-04

SW-05

SW-08

SW-09

SW-FB-01

l U t r l g

Ground WsCer

Drinking Water

Orlnliing Hater

Drinking Water

Bottom Sediment

Bottom Sediment

Bottom Sediment

Bottom Sediment

Bottom Sediment

Bottom Sediment

Bottom Sediment

Bottom Sediment

Bottom sediment

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Soil

Surface Hater

Surface Hater

Surface Hater

Surface Hater

Surface Hater

Surface Hater

Surface Water

Surface Hater

or Deposition

or Deposition

or Deposition

or Deposition

or Deposition

or Deposition

or Deposition

or Deposition

or Deposition

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

GRAB

End Collaotion Date T l —

01/30/2006 14:50

01/30/2006 16:30

01/30/2006 16:40

01/30/2006 13:05

01/30/2006 13:15

01/30/2006 13:50

01/30/2006 14:10

01/30/2006 14:20

01/30/2006 14:35

01/30/2006 15:30

01/30/2006 15:45

01/30/2006 17:00

01/31/2006 08:40

01/30/2006 13:30

01/30/2006 13:40

01/30/2006 13:50

01/30/2006 14:00

01/30/2006 15:25

01/30/2006 16:00

01/30/2006 16:25

01/30/2006 17:00

01/30/2006 13:15

01/30/2006 13:50

01/30/2006 14:10

01/30/2006 14:20

01/30/2006 14:35

01/30/2006 17:00

01/31/2006 08:40

01/30/2006 13:00

AR100156

U.S. EPA REGION III ANALYTICAL SERVICES & QUALITY ASSURANCE BRANCH ; .TL" (lAMn : OCEANA SALVAGE

l A i ! k-£.;i.;t.s; s : R E Q O e i i * " TESTS RSQUESTEO

INORGANICS

H e t a l s A n a l y s i s

P e x c a n t Dry H e i g h t

060207

i9 :20J2 i

X : >: X

1

22 23

>: ' I C

: ^

24 2 S | 2 6

1 1 X 1 X X

> : | X X

2 7 ; 2 8

X X

X ; X

2 9 ] 3 0 i 3 1

X X X

A j X . X 1

32:33

X I X X : X

34

X

X

35

X

3 6

x'

X i X

i

17138 139:40j41142 143 44145 46147.

X X 1 X : y i X 1 • 1

x i - x | x ! 1

X , X X : V . >; I X

(Z - laat Raqueated)

Q

AR100157

o - 4 .

to

S I T E NAME:

LAB REOUEST I :

OCIAMA SALVAOB

M Q 0 6 1 I 4

USEPA Region III Analytical Services t Quality Assurance Branch

QUALIFIER CODE AND GLOSSARY DEFINITIONS

Qualieiar Codaa Appllad to a«Bpl« Raault*

N NJ

NA NR R

U UJ UL <

However, the difference la

Not detected substantially above (10 times) the level reported In the laboratory or field blanks (includes field, trip, rinsate, and equipment blanks). See report narrative for analyst's comments and observations concerning thlA result. Value exceeds a theoretically greater value (e.g., dissolved>total, orthophosphate>total phosphorus). within the expected precision of the analytical techniques and is not statistically aignlfleant: An Interference exists which masks tha true response. See report narrative for explanation. The identification of the analyte is acceptable! the reported value is an estimate. The identification of the analyte is acceptable; the reported value nay be biased high. The actual v^lua is expected to be less than tha reported value. The identification of the analyte is acceptable; the reported value may be biased low. The actual value la expected to be greater than the reported value. There is presumptive evidence that the analyte Is present; the analyte Is reported as a tentative ideijtlfication. There is presumptive evidence that the analyte is present; the analyte is reported as a tentative identification. The reported value is an estimate. Not analyzed - analysis not perfomed. Not requested - analysis not requested. The presence or absence of the analyte can not be determined from the data due to severe quality control problems. The data are rejected and considered unusable. { Tentatively Identified Compound. Identified as a result of a library search using the EPA/NIST Mass Spectral Library. Standards were not used to verify the identity and qusntity of the compound. The reported value is an lestimste. The analyte was not detected at or above the quantitation limit. The analyte was not detected at or above the quantitation limit. The quantitation limit is an estimade. Tha analyte was not detected. The quantitation limit is probably higher due to indications of a low bias. Sample value below quantitation limit. Quantitation limit reported.

Qu*llfl«c Cedaa Applied to Quality Contcel Raaulta

A Quality control value is outside acceptance limits. O Sample and/or laboratory duplicate values are below the quantitation limit. No precision data reported TO Spike recovery too dilute for accurate quantitation.

Quallflar Codaa Appliad to Hicrobiology Raaulta

< Less than. <• Less than or equal to. >' Greater than or equal to. > Greater than.

Cloaaary:

( ) Numbers In parentheses are analytical spike recoveries (e.g., post-digestion spikes). ( I Numbers in brackets are matrix spike recoveries (e.g., pre-dlgestion spikes). CFU Colony Forming Unit. ISF A prepared sample aliquot fortified with a known concentration of target analyte (s) or a representative subset of target

analytes and analyzed. Its purpose is to determine whether the sample matrix contributes bias to tlie analytical results. LSF A sample aliquot fortified with a known concentration of analyte(s) or a representative subset of target analytes and carried

throughout the entire lab method. It is analyzed to determine whether the sample matrix contributes bias to the analytical results. MS/MSD Hatrlx spike/matrix spike duplicate; a known increment of target analyte added to a sample before preparation or analyses. MSA Value obtained by Method of Standard Additions in which calibration atandards are prepared in the skmple matrix

(see EPA method 200.9). RPD Relative Percent Difference (RPO)~ is used to measure precision, when duplicates are analyzed. tRec Percent Itecovery (%Rec) is an expression of accuracy.

AR100158

U.S EPA REGION III ANALYTICAL SERVICES & QUALITY ASSURANCE BRANCH SITE NAME : OCBAMX SALV3U3

LAB REQUEST #: MQ06114 INORGANIC ANALYTICAL SAMPLE RESULTS

SAMPLX WMBW:

SZATIOH ID:

06020719

or-oi

0(020720

W-01

06020721

nr-02

06020722

n-iB-oi

06020723

SO-01

Matala Aiwlysia

Lead

Pareant Dry Weight

Percent Dry Height (60C)

38 ug/L <1 ug/L <1 ug/L <1 ug/L 72.4 ug/g

56.5 4

o

AR100159

U.S EPA REGION III ANALYTICAL SERVICES i QUALITY ASSURANCE BRANCH SITE NAME : O d A l U SALVAGK

LAB REQUEST # : MQ06114 INORGANIC ANALYTICAL SAMPLE RESULTS

SAMPLE NUMBER:

STATION ID:

Matala Analyala

Lead

Paxcant Dry Weight

Percent Dry Weight (60C)

o

06020724

XO-02

309 ug/g

67.3 I

06020725

SO-03

112 ug/g

56.6 t

06020726

ao -o i

n n o oQfucixi

06020727

SD-OS

115 ug/g 13100 ug/g

55.4 t 48.7 t

06020728

SS-06

14.4 ug/g

63.0 4

AR100160

U . S EPA REGION I I I ANALYTICAL SERVICES & QUALITY ASSURANCE BRANCH

SITE NAME : OCaUUiA SALVAGE

LAB REQUEST » : SEO0C114 " INORGANIC ANALYTICAL SAMPLE RESULTS

SAMPLE HOieXR:

SCATZOH ID:

Matala Analyala

Lead

Paroant Dry Weight


<D

06020729

SD-07

06020730

so-oa 06020731

SD-09

06020732

S8-01

maiM

06020733

8S-02

21.6 ug/g

53.6 \

39.8 ug/g 32.4 ug/g 4240 ug/g 19500 J ug/g

50.4 % 39.8 t 86.9 t 85.9 «

AR100161

U.S EPA REGION I I I ANALYTIOlL SERVICES t QUALITY ASSURANCE BRANCH SITE NAME : OCSAMA 8ALVASB

LAB REQUEST # : R£O06114 Ntuuoxie INORGANIC ANALYTICAL SAMPLE RESULTS

SAMPLE UUMBER:

STATION 10:

Metala Analyala.

Lead

Percent Dry Weight

Percent Dry Weight (60C)

06020734

8S-03

n u a DoiLxcui

06020733

8S-04

11700 ug/g 10.3 ug/g

85.5 % 61..6

06020736

88-03

7.5 ug/g

82.3 %

06020737

SS-06

06020738

88-07

98.7 ug/g

4 8 . 1 t

10.5 ug/g

8 6 . 4 4

00 o

AR100162

U.S EPA REGION I I I ANALYTICAL S I T E NAME : OCXAMA SALVAGE

LAB REQUEST • : R E Q 0 6 1 1 4

SAMPLC KOMBIR:

SXATIOH ID:

SERVICES fi QUALITY ASSURANCE BRANCH

INORGANIC ANALYTICAL SAMPLE R E S U L T S '

06020739 06020740 06020741

88-08 8W-01 8W-02 SM0LB I I W U S t M n i

06020742

8W-03 taota

06020743

8W-04 rxau auMtcaa

Itotala Analyala

Lead

Percent Dry Weight

Percent Dry Height (600

30.2 ug/g 16 ug/L 33 ug/L

76.0 %

432 ug/L 68 ug/L

to o

AR100163

U . S EPA REGION I I I ANALYTICAL SERVICES & QUALITY ASSURANCE BRANCH

SITE NAME : OCKANA SALVAGE

LAB REQUEST *: RBQ06114 " INORGANIC ANALYTICAL SAMPLE RESULTS

SAMPLE NOMBER:

STATION ID:

Matala Analyala

06020744 sw-os

0602074S , sw-O*

06020746

SW-09

06020747

sw-n-oi

Lead

Percent Dry Weight


o Q

121 ug/L <i ug/L 4 ug/L <1 ug/L

AR100164

U.S EPA REGION III ANALYTICAL SERVICES & QUALITY ASSURANCE BRANCH SITE NAME: OCEAMA SALVAGE

LAB REQUEST I : lutQ06114 INORGANIC QUALITY CONTROL RESULTS

SAMPLE HOMUW:

STAXICH ID:

06020720

PW-01

06020721

SW-02

06020723

80-01

06020724

8D-02

Matala Analyala

Lead

Percent Dry Weight

Percent Dry Height (60c)

Units: % SEC RPD

109]

% DEC

110]

USD

o

(O

AR100165

U.S EPA REGION I I I ANALYTICAL SITE NAME: OCEANA SALVAGE

LAB REQUEST « : RSQ06114

SAMPLE RtEBSR:

STATIOH ID:

Un i t s :

Matala Analyala Lead

Percent Dry Weight Percent Dry Height (60c)

SERVICES i QUALITY ASSURANCE BRANCH

INORGANIC QUALITY CONTROL RESULTS

06020732 06020733

88-01 88-02

t REC RPD BSD

1 TL.) 41 A

• )

06020735

88-04

EPD

^ .

-

06020740

BW-Ol

1 EEC

1 107)

•

to o

AR100166

U . S EPA REGION I I I ANALYTICAL SERVICES & QUALITY ASSURANCE ^ANCH

SITE NAME: «VEAM1V SALVAGE

LAB REQUEST * : REQ06114 INORGANIC QUALITY CONTROL R E S U L T S

SAMPLE WOMBER: 06020741

STAXIOM ID: 8W-02

Units: RPD

Metala Analyala

Lead

Percant Dry Weight

Percent Dry Height (60c)

(] « Mf (I - Mr

o

AR100167

U.S. EPA REGION III ANALYTICAL SERVICES « QUALITY ASSURANCE BRANCH

Site Haae

Lab Ra<iueat • :

OCEANA SALVAGE

REQ06114 Wat Dry ConvarEion Tabic

Tha wat/dzy weight conversion table ia presaated for tha ooavaalaaoa e( tha d a U oaax. Tha attached analyst narratives sUta wither a teat was datexaised on a wet ec dry weight bsala. Any dlfCaranea ta aigniCioant Ctguxea between tha two B O I V M S la an artlfaet of tha reporting Cnaekion and doaa aot iaviy that tha ealoolatad value baa graatac praolalon than tha •eaaared value.

Sampla Wuffcer

06020723

0t020724

0602072S

06020726

06020727

06020728

06020729

06020730

06020731

06020732

06020733

^06020734

- 2,06020735

• "O06020736

06020737

06020736

06020739

Stetlen

to

SO-01

SD-02

SO-03

SO-04

SD-OS

SD-06

SD-07

sD-oe SD-09

SS-Oi

SS-02

SS-03

SS-04

SS-05

SS»06 "

SS-07

SS-OS

SAM

SAM

SAM

FD2

SAM

SAH

SAM

SAH

SAM

SAM

SAM

FD2

SAM

SAM

SAH

SAH

SAM

Percent (60C) Percer.c (60C) Pareant (60C) Peccant (600 Peccent I60C) Peccant (60C) Peccant (60CI Percant (60CI Percent (SOCI Percent. I60CI Percent (60CI Percent (60CI Percent (60C) Percent (60C) Percent (60C) Percent (60CI Percent (60C)

Dry Height

Dcy Nelghe

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dcy Height

Metal*

Metal!

Matala

Hstals

Metals

Hatals

Metals

Analysis

Analyala

Analyala

Analysis

Analysis

Analyala

Analysis

Hetals Analyala

Metals

Metala

Metals

Analyals

Analyals

Analysis

Metals Analysis

Matala Analysis

Hetals Analysis

Metala

Metala

Analysis

Analysis

Hetals Analyals

bead

Laed

Lead

Lead

Lead

Lead

Lead

Lead

Lead

Lead

Lead

Lead

bead

Lead

Lead

Lead

Lead

Pnita Bl£- sa

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

40*}

208

63

64

6380

S.l

11.6

20.1

12.9

3685

16751 J

10004

. < • «

6.2

47.5

» • !

23

72.4

309

112

115

13100

14.4

21.6

39.6

32.4

4240

19500 J

11700

10.3

7,5

98,7

10.S

30.2

AR100168

Lead fPb) Dt^wm^nqtlniiH

Analysts:

LMTf Chemist LMTT Chemist

Methods:

SeveDteen (17) soil and twelve (12) aqueous samples from OCEANA SALVAGE (REQ06114) were prepared for analyses by acid digestion. Lead (Pb) analyses were conducted on the soil samples by inductively coupled plasma-atomic emission spectrometry (ICP-AES) February 23, 2006 and March 9,2006. The determinations of lead (Pb) in the aqueous samples were perfbrmed~via graphiteliimaoe atomic absorption spectroscopy (GFAAS)Tebruary 28^20067 The samplJB and the Quality Control (QC) results are presented in the attau±ed tables. The following are the digestion, analytical tedmiques, and methods employed:

EHgestion Methods EPA Method 200.2 ^ and Internal SOP R3-QA1553, metals digestion procedure.

Analytical Methods EPA Method 200.7 <> and Internal SOP R3-QA159.2, metals by ICP-AES. EPA Method 200.9 « and Internal SOP R3-QA149.1, metals by GFAAS.

^ EPA Methods for the Determination of Metals in &ivironmental Samples, May 1994.

Notes:

Results for solid samples are reported in )ig/g (ppm) DRY weight at 60 degrees centigrade. This, Percent Dry Weight test, pertains only to metals results. The drying temperature of 60 degrees centigrade is selected to retain volatile elements. The % Dry Weight (60 C) is reported to allow for conversion to wet weight

15 of 19 AR100169

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AR100170

^ C D A USEPA Contract Laboratory Program ^ ^ ' - " ' ^ Generic Chain of Custody

Data Shipped:

CamarNama:

AirtriU:

Shipped to:

2A6a006

FedEx

6407 9942 2890

US EPA Region 3 QAS/QA Lab Env immnt I Science Ctr 701 Mapes Road FL Meade MO 20755-5350 (410) 305-2667

co/z/^ iz:(C

S A M P L E N o . HATRK/

S A H P i a CONC/ TYPE

Refersnce Case Cliant No: R32432

800 No: L For Lab Use Only

L i b C o i i b w l Noi

Unl lPi tea:

Tranafar To:

Lab Con tac t No:

UnRPitoa:

AMLYSS mviMtOUND

TAG No/ n f iSERVATneBaUi i

OOUJECT FORLABUSEOH.Y Sany l iCoadi f laOnRMi lp t

Ground Water/ L/G

PoUb le We l l / UG

Potable WelU UG

L/G

M/G

WQ

M/G

M/G

M/G

M/G

Das-Pb (14)

Das-Pb(14}

Oas-Pb(t4)

Oas-Pb(M)

Pb ICPAES (14)

Pb tCPAES (14)

Pb ICPAES (14)

Pb ICPAES (14)

EM1651(HN03)(1)

EM1662 (HN03) (1)

EM1656 (HN03) (1)

EM1657(HN03)(1)

EMI 627 (Ice Only) (1)

EMie28(loeOnly)(1)

EM1629 (Ice Only) (1)


Pb ICPAES (14) EM1631 (loe Only) (1)

Pb ICPAES (14) EM1632 (Ice Only) (1)

GW-01

PW-01

PW-02

PW-FB^l

SO^I

S042

S D ^

5004

SD05

SD46

S:

S:

S:

S:

S:

S:

S:

S:

S:

S:

1/30/2006

1/30 2006

1/300006

1/300006

i/3oaooe

1/300006

1/30/2006

1/300006

1/30O006

1/300006

^ ^ OiOZC7'^'^'^

"50 O c 0 7 . C 7 - ^ i

1410 o u y 2 ^ 7 - ^ S ^

* 0^07,07-^7 15:30 6 U y Z 0 7 - ^ f

Sh'vmsntforCat ComptofcVY

Sanipl«<() to ba uaod ItorlalMiMMy QC:

P W - 0 1 , S S - 0 1 , SW-01

AddMoMl S a n v l t r a tgna l im( t ) : Cootar T«np«n<ul« UpoaRacapl:

Chaia o f Cualody Seal Numbar.

ConeantoaUon: L > Low, M > LiMMadkjm, H - High Anaiyut Key:

Das-Pb - Das-Pb by ICP/MS. Pb ICPAES > O A & P b by ICP/AES

Typa/Daalgnata: CompoaH* • C. Grab • O CufUMly Saal Intact? Shipmant Iced?

TR Number. 3-435110168-020606-0001 PR pravidaa pfallminary raaulis. Raquaais Ipr praUmlnary raauKa wHI inciaaae analytical coat*. Send Copy to: Sample Managenwnt Office. Attn: Heather Bauer, CSC. 1500(1 Conliemnce Center Dr., Chantilly, VA 20151-3819; Phone 703«184200; 703/818-4602

liABORATORY COPY i;Fax FWi1.047 p , Q « i o f 3 AR100171

dEF^ USEPA Contract Laboratory Program Generic Cliain of Custody

DataShlppad: 2/6/2006

CamarNama: FedEx

AlibiU: 6407 9942 2890

SMppodto: US EPA Region 3 OAS/QA Lab EnvimmntI Science CIr 701 Mapes Road FL Meade MD 20755-5350 (410)305-2667 | 4

2jg|<^ n:e>d mUt/'^:^

SAMPLE No. MATRIX/

SAMfUR CONC/ TYPE

AHtaaai JkHHoJ ncBBiwkTncraaiiH • UXATKM

EH

Rsforance Case Client No: R32432

SOONo: L For Lab U M Only

Lab Contract No: ^

J UNIPitca: _

TfsnaftrTo:

LabContractNo: _

UnRPrtca:

SAHiUCOUlECr O A C m M l

F0RUBUSEON.y Saavia Coadion On Raoilpt

a

SD-07

SO-08

S D ^

SS-01

SS-02

SS-03

SS-04

SS-05

S S ^

SS«7

Sediment/

^Sediment/

_ Sediment/

Surface Soil/

Surface Soil/

Surface Soil/

Surface Soil/

Surface SoiU

Surface SolV

Surface Soil/

M/G

M/G

M/G

M/G

M/G

M/G

M/G

M/G

M/G

M/G

Pb ICPAES (14)

Pb ICPAES (14)

Pb ICPAES (14)

Pb ICPAES (14)

Pb ICPAES (14)

Pb ICPAES (14)

Pb ICPAES (14)

Pb ICPAES (14)

Pb ICPAES (14)

Pb ICPAES (14)








EM1640 (loe Only) (1)



SCM)7

SD48

St>09

SS-01

SS-02

SS43

S&04

S S ^

SS-06

SS-07

S:

S:

S:

S:

S:

S:

S:

S:

S:

S:

1/30O006

1/30O006

1/31/2006

1/3QO006

1/30O006

1/30O006

1/30O006

1/3QO006

1/300006

1/3QO006

17:00 0(x> 0 7 ^ ^ 7 - 3 ^

«•« (O^^^^V'^Z

13 30 (0(^;<r72^V'-^<2-

13-50 0 ^ ) C ) 2 6 V - 3 ^

U:00 6 ^ ) 6 1 0 7 - 3 ^

^s^ O/oOZclS^

''•• 060207-^3^

ShipiAOTtlarCaf Cainptele?Y

Analyils Key:

Das-Pb >Oas-Pb by ICF

SampKsl to ba uaad fcr labontoiy OC:

PW-01. SS-01, SW-01

•/MS. Pb ICPAES > QASPb by ICP/AES

TypaCaalanatr. Compoaba - C. Grab - G

CoolvTanpanbi* UpanRKiipl:

Cliabi of CHStody 8oal Nufflbar

Cuatody Saal Inlaci? Shipmani lead?

TR Number: 3-435110168-020606-0001 LABORATORY COPY PR provldaa prallnilnary raautts Raquaata for praOmlnaiyrasidlswilinciMaeanaMlcal coats. •M«-~mBv«^ • ' « « - « • ' « ^ •-«. » •«« •.^ « Send Copy to: Sample Management Office, Attn: Huther Bauer, CSC, 1500() Confefence Center Dr., ChantiUy. VA 20151-3819, Phone 703«18J4200; ?tx ^"^^^ P»a» 2 of 3 703/818-4602

AR100172

^ C D A USEPA Contract Laboratory Program ^ ^ ^ ^ ' ^ Generic Cliain of Custody

OataSMppad: 2/6O006

CantarNamt: FedEx

Airttill: 6407 9942 2890

Shippadio: US EPA Region 3 OAS/QA Lab

.Enwinunntl Science Ctr 701 Mapes Road Ft. Meade MD 20755-5350 (410) 305-2667

Chain of Cuetody Raoord

Rallnqulshad By (Daia/TtaM|

•/b o(g illo

l joi / i ; ^ ' i ^ h h f / Z ' a ^ iwtPrtca:

SAMPLE No.

UATRK/ SAIinBt

CONC/

r»pe ANALVSB/

TVffNAROUND TAONoJ

FReSBWATNBBoliis tOCATKM

•nnH

Reference Case Client No: R32432

BOO No: L For UbUaa Only

Lab Contiact No:

TtmsfarTo:

LabContiaetNo:

UnKPrtca:

aiuauoouca FGRLABUSEON.Y Simpk CondNon On Rsoeipi

SS-08

SW-01

SW-02

SW-03

09

S. SW-04

ID

SW-OS

SW-08

SW-09

SW-ffrOI

Surface Soil/ M/G

Surface Water/ M/G

Surface Water/ M/G

Surface Water/ M/G

Surface Water/ M/G

Surface Water/ M/G

Surface Water/ M/C

Pb ICPAES (14)

Pb tCPAES (14)

Pb ICPAES (14)

Pb ICPAES (14)

Pb ICPAES (14)

Pb ICPAES (14)

Pb ICPAES (14)

EM1643 (loe Only) (1)

EM1644 (HN03) (1)

EMI 645 (HN03) (1)

EM1646(HN03)(1)

EMie47(HN03)(1)

EM1648(HN03)(1)

EM1649.(HN03)(1)

Surface Water/ M/G Pb ICPAES (14) EM1650 (HN03) (1)

M/G Pb ICPAES (14) EM1655 (HN03) (1)

SS08

SW-01

SW-Q2

SW-03

SW-04

SW-05

SW-08

SW-09

SW-FB-01

S: 1/3QO006

S: 1/3QO006

S: 1/300006

S: 1/30O006

S: 1/30O006

S: 1/3QO006

S: 1/30/2006

S: 1/31/2006

S: 1/3QO006

«=«> D6o707-'^l

^ ' Oi07^c^7-¥^

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i*:35 0 ( , 0 7 ^ 7 - ^ Y

17:00 6 k 0 2 ^ 7 - ^ S ^

8:40 ^ i p O l ^ l - ^ C ^

13:00 6 0 2 0 1 - ^ 7

1 ShipmrntforCaf Comptte7Y

1 AiulyslsKey:

0 a s - P b « Das-Pb by ICF

Sampta(«) to ba w a d for laboratoiy QC:

PW-01. SS-01, SW-01

Ceneentistloii: L • Low. M - LoMMadhm, H - High

>/MS. Pb ICPAES - 0AS4>b by ICP/AES

Cootff Tatnpantin UpenRMipt: |

TypaCaalpiafo; Cempoaaa - C. Gob - G

Ctidki of Custody Saai Number

Cuatody S M I IMactT Stilpnant lead? 1

1 TR Number. 3^35110168-020606-0001

leasts. PR pnwidas prsllminary rasuits. RsqusstsforpraUmlnafyraauttswHIncraaseanaMlcal Send Copy to: Sampl^ Management Office, Attn: Heather Bauer, CSC, 1S0(X} Conference Center Dr.. Chantilly. VA 20151-3819; Phone 703/8184200; Fax 703/618-4602 I

LABORATORY COPY F»M.047 Pag. 3 of 3

AR100173

OniCIN lOr CYEA (6ie) 48S-64ie SHtPPINQ TETRR TECH EH INC 7 CREEK PflPKIMV

_SU ITC^aO — BooTHuvN. PA iseei UNITED STATES US

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Ship Data: MFEBBe Aotua l Hat : 0 7 . t L B HAN S y s t a M : 7EMee/CAFE22eS Account: 5 244614406 Xl lMMd: 30x20x10 IN

TO REGION 3 CLIENTS USEPfl REGION 3 ENVIRONnENTM. SCIENCE CENTER 701 nPPES ROM)

FT. GEORGE HEADE, HD 207555350

(410) 306-2001

FedEx E x p r a i i

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TRKt 6407 9942 2890 aaet

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19 of 19 AR100174

Lead (Pb> Dptgnn^nfttinna

Analysts:

LMTT Chemist LMl i demis t

Methods:

Seventeen (17) soil and twelve (12) aqueous samples from OCEANA SALVAGE (REQ06114) were prepared for analyses by add digestion. Lead (Pb) analyses were conducted on the soil samples by inductively coupled plasma-atomic emission spec^metry (ICP-AES) February 23, 2006 and March 9,2006. The determinations of lead (Pb) in the aqueous samples were

-performed via grapMte-fimiaceatoinicabsorption^pectroscopy^GFAAS)Tebruary~28720O6. The sample and the Quality Control (QC) results are presented in the attadied tables. The following are the digestion, analytical tedmiques, and methods employed:

Digestion Mediods EPA Method 200.2 ^ and Internal SOP R3-QA1SS3, metals digestion procedure:

Analytical Methods EPA Method 200.7 <*> and Internal SOP R3-QA159.2, metals by ICP-AES. EPA Method 200.9 <> and Internal SOP R3-QA149.1, metals by GFAAS.

^' EPA Methods for the Determination of Metals in Envirormiental Samples, May 1994.

Notes:

Results for solid samples are reported m ^g/g (ppm) DRY weight at 60 degrees centigrade. This, Percent Dry Weight test, pertains only to metals results. Hie drying temperature of 60 degrees centigrade is selected to retain volatile elements. The % Dry Weight (60 Q is reported to allow for conversion to wet weight

15 of 19 AR100175

U . S . EPA REGION I I I ANALYTICiO. SERVICES « QUALITY ASSURANCE BRANCH

Wet Dry Convaralon Table S i t a MaM

Lab K a ^ M t •

OCEJ^X SALVAGE

REO06114

The Mt/dry mlgtit eemrerelon table 1* pxaewitad foe tba o u n n i e a M of tha daU uaar. Itta attadiad aaalyat nazeaUvM a U U alMtlMr a Mat aaa dataxalaad oa a vat or dry Mlgtit baeie. Any diffaraaea la alflnifleant tlguxaa batiiaaa Uia tM ooliaaia la an ar tUaot of tha caporttag Canotlaa and doaa aot imfly that tha aaJenlatad value haa gxaater pxaclelon than tha aeaetued «alua.

S«a«>lB

miftMt

0S020723

0(020724

06P2072S

0(020726

06020727

06020728

06020729

06020730

0<a2a7a)

06020732

06020333

^06020734 A a,0«02073S

. *06020736

06020737

06020738

06020739

Station

2...

SO-01

SD-02

SD-03

SD-04

SD-05

SD-06

SD-07

SD-OB

SD-09

SS-01

SS-02

ss-a3

SS-04

SS-05

SS-06

SS-07

SS-OB

SAH

SAM

SAM

FD2

SAH

SAN

SAM

SAH

SAM

SAH

SAN

ro2

SAM

SAM

SAH

SAH

SAM

Percent 160C) Percent <60C) Percent (60CI Percent (60CI Percent 160CI Percent (60CI Percent

rcoci Percent (60CI Percent (COC) Percent (60C) Percent <60C) Percent 1600 Percent (60O Percent I60CI Percent (60O Percent («0C) Percent (600

Dry Height

Dry Neight

Dry Height

Dry Height

Dry Height

Ozy Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

Dry Height

56.5

67.3

56.6

55.4

48.7

63

53.6

50.4

39.8

86.9

85.9

85.5

81.8

82.3

48.1

S«.4

76

Metali Analysis

Hetals Analysis

Metals Analyals

Hatais Analysis

Hetsls Analysis

Metals Analysis

Hatals Analysis

Metals Analysis

Hetals Analysis

Hetals Analysis

Metals Analysis

Metals Analysis

Morals Analysis

Metals Analysis

Hetals Analysis

Hatals Analysis

Hetals Analysis

Lead

Uad

Lead

Uad

Lead

Uad.

Uad

Uad

Uad

Uad

Uad

Uad

Uad

Lead

Uad

Uad

Lead

asm Bl£- EflC

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

ug/g

40:9

208

63

«4

6380

9.1

11.6

20.1

12.9

3685

16751 J

10004

8.4

6.2

47.5

9.1

23

72.4

309

112

115

13100

14.4

21.6

39.6

32.4

4240

19500 J

11700

10.3

7.5

98.7

10.5

30.2

AR100176

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