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I-3EE_l P- D -680B O ctober 29. 1992 SUPERSED I NG P- D -680A Septe mber 9, 1988 FEDERAL SPECIFICATI ON DRY CLEAN I NG AND DECREASI NG SOLVENT + This specification w as approved by the Assistant Adm inistrator, O ffice of Federal SURD IY and Services, G eneral Services Adm inistration, for the use of all Federal ”Agencies. 1. SCOPE AND CLASSIFICATI ON 1.1 =. Dry cleaning and decreasing solvent consists of petroleum distillates. The different types are referred to as “140 ‘F solvent”. and “200 ‘F solvent”. They are used for dry stain re moving, And for decreasing of m achin; parts 1.2 Classification. D ry cleaning and decreasing types: three types of “Stoddard solvent”, cleaning, spot and in equipm ent m aintenance. solvent sha l l be the follow ing Type I - R egular (Stoddard solvent) ( M ilitary Sy mbol SO -1) Type II - H igh flash point ( M ilitary Sy mbol SD -2) Type 111 - Low odor w ith very high flash point (200 “F) ( M ilitary Sy mbol SO -3) 1.2.1 NATO classification. Type I - S-752 Type II - S-753 Type III - None 2. APPLICABLE DOCUMENTS 2.1 Governm ent docum ents. 2.1.1 Specifications. standards. and handbooks. The follow ing specifications, standards, and handbooks for m a part of this docum ent to the extent specified herein. Unless other w ise specified, the issues of these docum ents are those listed in the issue of the D epart m ent of D efense Index of Specifications and Standards ( OOD ISS) and supple m ent thereto, cited in the solicitation (see 6.2). Beneficial comm ents (recomm endations, additions, deletions) and any pertinent data which m ay be of use in i mproving this docum ent should be addressed to: USA Belvoir R esearch, D evelopm ent, and Engineering Center, ATTN : SATBE-TSE, Fort Belvoir, VA 22060-5606 by using the Standardization Docum ent I mprove m ent Proposal ( DD For m 1426) appearing at the end of this docum ent or by letter. AMSC N /A FSC 6850 D ISTR IBUTI ON STATEMENT A. Approved for pub l i c release, distribution is unli m ited. Downloaded from http://www.everyspec.com

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Page 1: Downloaded from I-3EE leveryspec.com/FED_SPECS/P/download.php?spec=P-D-680B...Desk , Bu i i d i ng 40 , 700 Robb i ns Avenue , Ph i l ade l ph i a , PA 19111 -5094.) 2.1.2 Other G

I-3EE_lP - D - 6 8 0BOc t o b e r 2 9 . 1 9 9 2SUPERSED I NGP - D - 6 8 0AS e p t emb e r 9 , 1 9 8 8

F EDERAL SPEC I F I CAT I ON

DRY CL EAN I NG AND DECREAS I NG SOLVENT+

T h i s s p e c i f i c a t i o n wa s a p p r o v e d b y t h e A s s i s t a n t Adm i n i s t r a t o r , O f f i c e o fF e d e r a l SURD I Y a n d S e r v i c e s , Ge n e r a l S e r v i c e s Adm i n i s t r a t i o n , f o r t h e u s e o fa l l F e d e r a l ”Ag e n c i e s .

1 . SCOPE AND CLASS I F I CAT I ON

1.1 =. Dry c l e a n i n g a n d d e c r e a s i n g s o l v e n t c o n s i s t s o fp e t r o l e um d i s t i l l a t e s . T h e d i f f e r e n t t y p e s a r e r e f e r r e d t o a s“ 1 4 0 ‘ F s o l v e n t ” . a n d “ 2 0 0 ‘ F s o l v e n t ” . T h e y a r e u s e d f o r d r ys t a i n r emo v i n g , An d f o r d e c r e a s i n g o f ma c h i n ; p a r t s

1 . 2 C l a s s i f i c a t i o n . D r y c l e a n i n g a n d d e c r e a s i n gt y p e s :

t h r e e t y p e s o f“ S t o d d a r d s o l v e n t ” ,c l e a n i n g , s p o t a n d

i n e q u i pme n t ma i n t e n a n c e .

s o l v e n t s h a l l b e t h e f o l l ow i n g

T y p e I - Re g u l a r ( S t o d d a r d s o l v e n t ) ( M i l i t a r y S ymb o l SO - 1 )T y p e I I - H i g h f l a s h p o i n t ( M i l i t a r y S ymb o l SD - 2 )T y p e 1 1 1 - L ow o d o r w i t h v e r y h i g h f l a s h p o i n t ( 2 0 0 “ F ) ( M i l i t a r y S ymb o l SO - 3 )

1 . 2 . 1 NATO c l a s s i f i c a t i o n .

T y p e I - S - 7 5 2T y p e II - S-753T y p e III - No n e

2. APPL I CABL E DOCUMENTS

2 . 1 Go v e r nme n t d o c ume n t s .

2 . 1 . 1 Sp e c i f i c a t i o n s . s t a n d a r d s . a n d h a n d b o o k s . T h e f o l l ow i n g s p e c i f i c a t i o n s ,s t a n d a r d s , a n d h a n d b o o k s f o r m a p a r t o f t h i s d o c ume n t t o t h e e x t e n t s p e c i f i e dh e r e i n . Un l e s s o t h e r w i s e s p e c i f i e d , t h e i s s u e s o f t h e s e d o c ume n t s a r e t h o s el i s t e d i n t h e i s s u e o f t h e De p a r t me n t o f De f e n s e I n d e x o f Sp e c i f i c a t i o n s a n d

S t a n d a r d s ( OOD I SS ) a n d s u p p l eme n t t h e r e t o , c i t e d i n t h e s o l i c i t a t i o n ( s e e 6 . 2 ) .

B e n e f i c i a l c omme n t s ( r e c omme n d a t i o n s , a d d i t i o n s , d e l e t i o n s ) a n d a n y p e r t i n e n td a t a wh i c h ma y b e o f u s e i n i mp r o v i n g t h i s d o c ume n t s h o u l d b e a d d r e s s e d t o :USA B e l v o i r Re s e a r c h , De v e l o pme n t , a n d E n g i n e e r i n g C e n t e r , AT TN : SATBE - TSE ,F o r t B e l v o i r , VA 2 2 0 6 0 - 5 6 0 6 b y u s i n g t h e S t a n d a r d i z a t i o n Do c ume n t I mp r o v eme n tP r o p o s a l ( DD F o r m 1 4 2 6 ) a p p e a r i n g a t t h e e n d o f t h i s d o c ume n t o r b y l e t t e r .

AMSC N / A F SC 6 8 5 0D I STR I BUT I ON STAT EMENT A . Ap p r o v e d f o r p u b l i c r e l e a s e , d i s t r i b u t i o n i s u n l i m i t e d .

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P - D - 6 8 0B

F e d e r a l S t a n d a r d :

F ED - STD - 1 4 1

F ED - STD - 3 1 3

F ED - STD - 7 9 1

P a i n t , V a r n i s h , L a c q u e r , a n d Re l a t e d Ma t e r i a l s ; Me t h o d so f I n s p e c t i o n , S amp l i n g a n d T e s t i n g .Ma t e r i a l S a f e t y Da t a , T r a n s p o r t a t i o n Da t a a n d D i s p o s a lDa t a f o r Ha z a r d o u s Ma t e r i a l s F u r n i s h e d t o Go v e r nme n tA c t i v i t i e s .L u b r i c a n t s , L i q u i d F u e l s , a n d Re l a t e d P r o d u c t s ; ’Me t h o d o fT e s t i n g .

( A c t i v i t i e s o u t s i d e t h e F e d e r a l Go v e r nme n t ma y o b t a i n c o p i e s o f F e d e r a l- s p e c i f i c a t i o n s , s t a n d a r d s , a n d c omme r c i a l i t em d e s c r i p t i o n s , a s o u t J = i n e d u n d e r

Ge n e r a l I n f o r ma t i o n i n t h e I n d e x o f F e d e r a l Sp e c i f i c a t i o n s a n d S t a n d a r d s , a n dComme r c i a l I t em De s c r i p t i o n s . T h e I n d e x , wh i c h i n c l u d e s c umu l a t i v e b i mo n t h l ys u p p l eme n t s a s i s s u e d , i s f o r s a l e o n a s u b s c r i p t i o n b a s i s b y t h e Su p e r i n t e n d e n to f Do c ume n t s , U . S . Go v e r nme n t P r i n t i n g O f f i c e , Wa s h i n g t o n , DC 2 0 4 0 2 .

( S i n g l e c o p i e s o f t h i s s p e c i f i c a t i o n , o t h e r F e d e r a l s p e c i f i c a t i o n s , a n dc omme r c i a l i t em d e s c r i p t i o n s r e q u i r e d b y a c t i v i t i e s o u t s i d e t h e F e d e r a l Go v e r nme n tf o r b i d d i n g p u r p o s e s a r e a v a i l a b l e w i t h o u t c h a r g e f r om Ge n e r a l S e r v i c e s

Adm i n i s t r a t i o n Bu s i n e s s S e r v i c e C e n t e r s i n Bo s t o n , MA ; New Yo r k , NY ; Ph i l a d e l p h i a ,PA ; Wa s h i n g t o n , DC ; A t l a n t a , GA ; Ch i c a g o , I L ; K a n s a s C i t y , MO ; F o r t Wo r t h , TX ;Ho u s t o n , TX ; Oe n v e r , CO ; S a n F r a n c i s c o , CA ; L o s An g e l e s , CA ; a n d Au b u r n , WA .

( F e d e r a l Go v e r nme n t a c t i v i t i e s ma y o b t a i n c o p i e s o f F e d e r a l s t a n d a r d i z a t i o nd o c ume n t s a n d t h e I n d e x o f F e d e r a l Sp e c i f i c a t i o n s , S t a n d a r d s , a n d Comme r c i a l I t emDe s c r i p t i o n s f r om e s t a b l i s h e d d i s t r i b u t i o n p o i n t s i n t h e i r a g e n c i e s . )

M i l i t a r v s t a n d a r d s :

M I L - STD - 1 0 5

IM I L - STD - 1 2 9 -M I L - STD - 1 4 7M I L - STD - 2 9 0 ~

S amp l i n g P r o c e d u r e s a n d T a b l e s f o r I n s p e c t i o n b yA t t r i b u t e s .Ma r k i n g f o r Sh i pme n t a n d S t o r a g e .P a l l e t i z e d Un i t L o a d s .P a c k a g i n g o f P e t r o l e um a n d Re l a t e d P r o d u c t s .

( Un l e s s o t h e r w i s e i n d i c a t e d , c o p i e s o f f e d e r a l a n d m i l i t a r y s p e c i f i c a t i o n s ,s t a n d a r d s . a n d h a n d b o o k s a r e a v a i l a b l e f r om t h e S t a n d a r d i z a t i o n Do c ume n t s O r d e rDe s k , Bu i i d i n g 4 0 , 7 0 0 Ro b b i n s A v e n u e , Ph i l a d e l p h i a , PA 19111 -5094.)

2.1.2 Other Go v e r nme n t d o c ume n t s . T h e f o l l ow i n g o t h e r Go v e r nme n t d o c ume n t sf o r m a p a r t o f t h i s d o c ume n t t o t h e e x t e n t s p e c i f i e d h e r e i n . Un l e s s o t h e r w i s es p e c i f i e d , t h e i s s u e s a r e t h o s e c i t e d i n t h e s o l i c i t a t i o n .

Co d e o f F e d e r a l Re g u l a t i o n s :

4 9 C FR - T r a n s p o r t a t i o n .

( a p p l i c a t i o n f o r c o p i e s s h o u l d b e a d d r e s s e d t o t h e Su p e r i n t e n d e n t o f Do c ume n t s ,Go v e r nme n t P r i n t i n g O f f i c e , Wa s h i n g t o n , OC 2 0 4 0 2 . )

I 2

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P - D - 6 8 0 8

F e d e r a l E n v i r o nme n t a l P r o t e c t i o n Ag e n c y ( EPA ) S t a n d a r d s :

EPA Me t h o d s f o r Ch em i c a l An a l y s i s o f Wa t e r a n d Wa s t e s , Me t h o d 4 2 0 . 1 Ph e n o l i c s ,T o t a l Re c o v e r a b l e .

( Ap p l i c a t i o n f o r c o p i e s s h o u l d b e a d d r e s s e d t o t h e USEPA , E n v i r o nme n t a lMo n i t o r i n g a n d Su p p o r t L a b o r a t o r y , 2 6 We s t Ma r t i n L u t h e r K i n g D r i v e , C i n c i n n a t i ,OH 4 5 2 6 8 . )

2 . 2 No n - Go v e r nme n t Du p l i c a t i o n s . T h e f o l l ow i n g d o c ume n t ( s ) f o r m a p a r t o f t h i ss p e c i f i c a t i o n t o t h e e x t e n t s p e c i f i e d h e r e i n . Un l e s s o t h e r w i s e s p e c i f i e d , t h ei s s u e s o f t h e d o c ume n t s wh i c h a r e DoD a d o p t e d a r e t h o s e l i s t e d in t h e i s s u e o f t h e

0 0D I SS c i t e d i n t h e s o l i c i t a t i o n . Un l e s s o t h e r w i s e s p e c i f i e d , t h e i s s u e s o fd o c ume n t s n o t l i s t e d i n t h e 0 0D I SS are t h e i s s u e s c i t e d i n t h e s o l i c i t a t i o n ( s e e6 . 2 ) .

Ame r i c a n So c i e t v f o r T e s t i n a a n d Ma t e r i a l s ( ASTM ) S t a n d a r d s :

D 5 6D 8 6D 1 3 0

0 1 5 6

0 2 3 5

0 4 4 5

0 6 1 1

D 8 4 7

D 1 1 3 3D 1 2 9 60 1 2 9 8

D 2 8 7 9

0 4 0 5 70 4 1 7 7

F l a s h Po i n t b y T a g C l o s e d T e s t e r , T e s t Me t h o d f o r .D i s t i l l a t i o n o f P e t r o l e um P r o d u c t s , T e s t Me t h o d f o r .De t e c t i o n o f Co p p e r Co r r o s i o n f r om P e t r o l e um P r o d u c t s b y t h e Co p p e rS t r i p T a r n i s h T e s t , Me t h o d f o r .S a y b o l t Co l o r o f P e t r o l e um P r o d u c t s ( S a y b o l t Ch r o n ome t e r Me t h o d ) ,T e s t Me t h o d f o r .M i n e r a l Sp i r i t s ( P e t r o l e um Sp i r i t s ) ( Hy d r o c a r b o n D r y c l e a n i n gSo l v e n t ) , S t a n d a r d Sp e c i f i c a t i o n f o r .K i n ema t i c V i s c o s i t y o f T r a n s p a r e n t a n d Op a q u e L i q u i d s ( a n d t h eC a l c u l a t i o n o f Dy n am i c V i s c o s i t i e s ) .An i l i n e Po i n t a n d M i x e d An i l i n e Po i n t o f P e t r o l e um P r o d u c t s a n dHy d r o c a r b o n So l v e n t s , T e s t Me t h o d f o r .A c i d i t y o f B e n z e n e , T o l u e n e , X y l e n e s , So l v e n t Na p h t h a s , a n d ’ S i m i l a rI n d u s t r i a l A r oma t i c Hy d r o c a r b o n s , T e s t Me t h o d f o r .

K a u r i - Bu t a n o l V a l u e o f Hy d r o c a r b o n So l v e n t s , T e s t Me t h o d f o r .Od o r o f Vo l a t i l e So l v e n t s a n d D i l u e n t s , T e s t Me t h o d f o r .De n s i t y , Re l a t i v e De n s i t y ( Sp e c i f i c G r a v i t y ) , o r AP I G r a v i t y o fC r u d e P e t r o l e um a n d L i q u i d P e t r o l e um P r o d u c t s b y Hy d r ome t e r Me t h o d .V a p o r P r e s s u r e - T emp e r a t u r e Re l a t i o n s h i p s a n d I n i t i a l De c omp o s i t i o nT emp e r a t u r e o f L i q u i d s b y I s o t e n i s c o p e , T e s t Me t h o d f o r .Ma n u a l S amp l i n g o f P e t r o l e um P r o d u c t s , P r a c t i c e f o r .Au t oma t i c S amp l i n g o f P e t r o l e um a n d P e t r o l e um P r o d u c t s , Me t h o d f o r .

( T h e ASTM t e s t me t h o d s l i s t e d a b o v e a r e a v a i l a b l e f r om ASTM , 1 9 1 6 Ra c e S t r e e t ,Ph i l a d e l p h i a , PA 1 9 1 0 3 . )

So u t h Co a s t A i r Ou a l i t y Ma n a g eme n t D i s t r i c t :

Ru l e 1 0 2 - Ph o t o c h em i c a l l y Re a c t i v e So l v e n t s .

( Ap p l i c a t i o n f o r c o p i e s s h o u l d b e a d d r e s s e d t o t h e So u t h Co a s t A i r Qu a l i t yMa n a g eme n t D i s t r i c t , 9 1 5 0 E . F l a i r O r i v e , E l Mo n t e , CA 91731)

( No n - Go v e r nme n t s t a n d a r d s a n d o t h e r p u b l i c a t i o n s a r e n o r ma l l y a v a i l a b l e f r om t h eo r g a n i z a t i o n s t h a t p r e p a r e o r d i s t r i b u t e t h e d o c ume n t s . T h e s e d o c ume n t s a l s o ma yb e a v a i l a b l e i n o r t h r o u g h l i b r a r i e s o r o t h e r i n f o r ma t i o n a l s e r v i c e s . )

3

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P - D - 6 8 0B

2 . 3 O r d e r o f p r e c e d e n c e . In t h e e v e n t o f a c o n f l i c t b e t we e n t h e t e x t o f t h i ss p e c i f i c a t i o n a n d t h e r e f e r e n c e s c i t e d h e r e i n , t h e t e x t o f t h i s s p e c i f i c a t i o ns h a l l t a k e p r e c e d e n c e . No t h i n g i n t h i s s p e c i f i c a t i o n , h owe v e r , s h a l l s u p e r s e d ea p p l i c a b l e l aws a n d r e g u l a t i o n s u n l e s s a s p e c i f i c e x emp t i o n h a s b e e n o b t a i n e d .

3 . REQU I REMENTS

3 . 1 Qu a n t i t a t i v e a n d q u a l i t a t i v e r e q u i r eme n t s . T h e s o l v e n t s s h a l l c o n f o r m t ot h e p h y s i c a l a n d c h em i c a l r e q u i r eme n t s i n t a b l e I wh e n t e s t e d a s s p e c i f i e d i n 4 . 5a n d t o t h e q u a l i t a t i v e a n d q u a n t i t a t i v e r e q u i r eme n t s a s s p e c i f i e d h e r e i n .

TA8 L E I . D r y c l e a n

CHARACT ER I ST I CS

F l a s h p o i n t , “ C , m i nD i s t i l l a t i o n , ‘ C :

I n i t i a l b o i l i n g p t . , m i n5 0 % r e c o v e r e dD r y p o i n t , ‘ C , ma x

An i l i n e p o i n t , ‘ CK a u r i - b u t a n o l v a l u eA l l owa b l e c o n s t i t u e n t s , ( % b y

v o l ume ) : 1 /( a ) So l v e n t w i t h o l e f i n i c o r

c y c l o - o l e f i n i cu n s a t u r a t i o n , ma x

( b ) A r oma t i c c omp o u n d s w i t he i g h t o r mo r e c a r b o na t oms , e x c e p t e t h y l -

‘ b e n z e n e , ma x( c ) T o t a l o f e t h y l b e n z e n e ,

t o l u e n e , a n d b r a n c h e dc h a i n k e t o n e s , ma x

( d ) T o t a l o f ( a ) + ( b ) + ( c ) ,ma x

T o t a l c h l o r i n e c o n t e n t ( p pm )ma x

Ap p a r e n t s p e c i f i c g r a v i t yNo n - v o l a t i l e r e s i d u e ( mg / 1 0 0

mL ) , ma xCo l o r , m i nOd o r Z J

Co r r o s i o n , c o p p e r , ma x 3 /A c i d i t yDo c t o r t e s tV a p o r p r e s s u r e , T o r r @ 2 0 ‘ C ,

ma xT o t a l p h e n o l c o n t e n t ( p pm ) ,

ma xV i s c o s i t y , c S t a t 2 5 “ C , ma x/ T h e s e ma x i mum l i m i t s a r e a s

~ a n d d e c i r e a s i n t

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~ / S amp l e s o f P - D - 6 8 o h a v i n g s a t i s f a c t o r y o d o r c h a r a c t e r i s t i c s s h a l l b e u s e d a sr e f e r e n c e s t a n d a r d s .

~ / T e s t f o r t h r e e h o u r s a t 1 0 0 “ C .

3.1.1 Appearance. T h e s o l v e n t s h a l l b e c l e a r a n d f r e e f r om s u s p e n d e d ma t t e ra n d u n d i s s o l v e d wa t e r wh e n o b s e r v e d a t 1 5 . 6 - 2 5 . 6 “ C .

3 . 2 Ma t e r i a l s . T h e h y d r o c a r b o n s o l v e n t s h a l l b e a v i r g i n g r a d e o r r e c y c l e ds o l v e n t d e r i v e d f r om p e t r o l e um d i s t i l l a t e s , f r a c t i o n s f r om r e c l a i m i n g a n dr e - r e f i n i n g p r o c e s s e s , o r a m i x t u r e o f t h e s e f r a c t i o n s . T h e r e s u l t a n t s o l v e n t

mu s t b e p r o d u c e d i n s u c h a ma n n e r a s i s n e c e s s a r y t o me e t t h e s p e c i f i e dr e q u i r eme n t s . - - - -

3 . 3 T o x i c i t v a n d c a r c i n o q e n i c i t y . T h e s o l v e n t s h a l l h a v e n o a d v e r s e e f f e c t s o nh uma n h e a l t h wh e n i t i s u s e d a s i n t e n d e d ( s e e 6 . 1 ) . T h e s o l v e n t s h a l l c o n t a i n n oc h em i c a l s l i s t e d a s c a r c i n o g e n s ( s e e 6 . 9 a n d 6 . 1 0 ) . An y c a r c i n o g e n i c c omp o n e n t si n t h e s o l v e n t i n a c o n c e n t r a t i o n o f 0 . 1 p e r c e n t o r g r e a t e r b y we i g h t o r b y v o l ume

w i l l b e r e g a r d e d a s t h e p r e s e n c e o f a c a r c i n o g e n i n t h e s o l v e n t .

4 . QUAL I TY ASSURANCE PROV I S I ONS

4.1 ~. Un l e s s o t h e r w i s e s p e c i f i e d i n t h e c o n t r a c to r p u r c h a s e o r d e r , t h e c o n t r a c t o r i s r e s p o n s i b l e f o r t h e p e r f o r ma n c e o f a l li n s p e c t i o n r e q u i r eme n t s a s s p e c i f i e d h e r e i n . E x c e p t a s o t h e r w i s e s p e c i f i e d i n t h e

c o n t r a c t o r p u r c h a s e o r d e r , t h e c o n t r a c t o r ma y u s e h i s own o r a n y o t h e r f a c i l i t i e ss u i t a b l e f o r t h e p e r f o r ma n c e o f t h e i n s p e c t i o n r e q u i r eme n t s s p e c i f i e d h e r e i n ,u n l e s s d i s a p p r o v e d b y t h e Go v e r nme n t . T h e Go v e r nme n t r e s e r v e s t h e r i g h t t op e r f o r m a n y o f t h e i n s p e c t i o n s s e t f o r t h i n t h e s p e c i f i c a t i o n wh e r e s u c hi n s p e c t i o n s a r e d e eme d n e c e s s a r y t o a s s u r e s u p p l i e s a n d s e r v i c e s c o n f o r m t op r e s c r i b e d r e q u i r eme n t s .

4 . 1 . 1 Re s p o n s i b i l i t y f o r c omp l i a n c e . A l l i t ems mu s t me e t a l l r e q u i r eme n t s o fs e c t i o n s 3 a n d 5 . T h e i n s p e c t i o n s e t f o r t h i n t h i s s p e c i f i c a t i o n s h a l l b e c ome ap a r t o f t h e c o n t r a c t o r ’ s o v e r a l l i n s p e c t i o n s y s t em o r q u a l i t y p r o g r am . T h ea b s e n c e o f a n y i n s p e c t i o n r e q u i r eme n t s i n t h e s p e c i f i c a t i o n s h a l l n o t r e l i e v e t h ec o n t r a c t o r o f t h e r e s p o n s i b i l i t y o f a s s u r i n g t h a t a l l p r o d u c t s o r s u p p l i e ss u bm i t t e d t o t h e Go v e r nme n t f o r a c c e p t a n c e c omp l y w i t h a l l r e q u i r eme n t s o f t h ec o n t r a c t . S amp l i n g i n q u a l i t y c o n f o r ma n c e d o e s n o t a u t h o r i z e s u bm i s s i o n o f k n ownd e f e c t i v e ma t e r i a l , e i t h e r i n d i c a t e d o r a c t u a l , n o r d o e s i t c omm i t t h e Go v e r nme n tt o a c c e p t a n c e o f d e f e c t i v e ma t e r i a l .

4 . 2 I n s t s e c t i o n . P e r f o r m i n s p e c t i o n i n a c c o r d a n c e w i t h F EO - STD - 7 9 1 , me t h o d9 6 0 1 . Un l e s s o t h e r w i s e s p e c i f i e d , a l l e x am i n a t i o n s a n d t e s t s s h a l l b e p e r f o r me da t a t emp e r a t u r e o f 2 5 * 3 “ C ( 7 7 t 5 “ F ) a n d a t a r e l a t i v e h um i d i t y b e t we e n 4 5 a n d5 5 p e r c e n t . Ph y s i c a l v a l u e s s p e c i f i e d i n t a b l e I a p p l y t o t h e a v e r a g e o f t h ed e t e r m i n a t i o n s ma d e o n t h e s amp l e s .

4 . 3 C l a s s i f i c a t i o n o f i n s p e c t i o n . T h e i n s p e c t i o n s s p e c i f i e d h e r e i n a r ec l a s s i f i e d a s f o l l ows :

a . Qu a l i t y c o n f o r ma n c e i n s p e c t i o n ( s e e 4 . 4 ) .b . I n s p e c t i o n o f p r e p a r a t i o n f o r d e l i v e r y ( s e e 4 . 6 ) .

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1

4 . 4 Qu a l i t y c o n f o r ma n c e i n s ~ e c t i o n . T h e q u a l i t y c o n f o r ma n c e t e s t s s h a l lc o n s i s t o f a l l t h e t e s t s s p e c i f i e d h e r e i n .

4.4.1 LQL. A l o t s h a l l c o n s i s t o f s o l v e n t s f r om o n e b a t c h o r t a n k o f f e r e d f o rd e l i v e r y a t o n e t i me . If ma t e r i a l c a n n o t b e i d e n t i f i e d b y b a t c h o r l o t , a l o ts h a l l c o n s i s t o f n o t mo r e t h a n 1 0 , 0 0 0 g a l l o n s o f f e r e d f o r d e l i v e r y a t o n e t i me .

I 4 . 4 . 2 S amP l i n q f o r e x am i n a t i o n . A r a n d om s amp l e o f c o n t a i n e r s f u l l y p r e p a r e df o r d e l i v e r y s h a l l b e t a k e n f r om e a c h l o t i n a c c o r d a n c e w i t h M I L - STD - 1 0 5 . S amp l es i z e s h a l l b e d e t e r m i n e d b y u s i n g M I L - STD - 1 0 5 , t a b l e I a n d t a b l e I I a , a t s p e c i a l

I i n s p e c t i o n l e v e l I I . A l o t s h a l l b e a c c e p t e d wh e n z e r o d e f e c t s a r e f o u n d a n d~ e j e c t e d wh e n o n e o r mo r e d e f e c t s a r e f o u n d . ~ . A

4 . 4 . 3 S amD l i n q f o r t e s t s . S amp l i n g o f a l o t f o r t e s t p u r p o s e s s h a l l b e i na c c o r d a n c e w i t h ASTM D 4 0 5 7 o r D 4 1 7 7 .

4 . 5 Ou a l i t v c o n f o r ma n c e t e s t s . Qu a l i t y c o n f o r ma n c e t e s t s s h a l l b e c o n d u c t e d a ss p e c i f i e d i n t a b l e II and 4.5.1 and 4.5.2, a s a p p l i c a b l e .

TABL E 1 1 . Ou a l i t v c o n f o r ma n c e t e s t i n q .

CHARACT ER I ST I C ASTM ME THODS OTHER ME THODS

F l a s h p o i n t D 5 6D i s t i l l a t i o n D 8 6K a u r i - Bu t a n o l v a l u e D 1 1 3 3A l l owa b l e c o n s t i t u e n t s , % v o l ume F ED - STD - 1 4 1 , me t h o d 7 3 5 6Ap p a r e n t s p e c i f i c g r a v i t y D 1 2 9 8An i l i n e p o i n t D 6 1 1Co l o r D 1 5 6Od o r D 1 2 9 6

. .

Co p p e r c o r r o s i o n D 1 3 0A c i d i t y D 8 4 7Do c t o r t e s t D 2 3 5V a p o r p r e s s u r e D 2 8 7 9T o t a l p h e n o l c o n t e n t EPA 4 2 0 . 1V i s c o s i t y D 4 4 5

4 . 5 . 1 No n - v o l a t i l e r e s i d u e . Wh e n p e r f o r m i n g t h i s t e s t , s u f f i c i e n t v e n t i l a t i o ns h a l l b e a v a i l a b l e t o ma i n t a i n t h e c o n c e n t r a t i o n o f t h e s o l v e n t b e l ow t h e r e q u i r e de x p o s u r e s t a n d a r d s . P l a c e 1 0 0 mL o f s o l v e n t i n t o a we i g h e d p o r c e l a i n d i s h .E v a p o r a t e t h e c o n t e n t s o v e r a s t e am b a t h u n t i l t h e r e i s n o f u r t h e r e v a p o r a t i o n .T h e n h e a t t h e d i s h a n d r e s i d u e t o c o n s t a n t we i g h t i n a n o v e n s e t a t 1 0 5 * 2 “ C .De t e r m i n e t h e we i g h t o f t h e n o n - v o l a t i l e r e s i d u e i n t h e d i s h . Co n d u c t t h e t e s t i nd u p l i c a t e a n d r e p o r t a s mg p e r 1 0 0 mL s o l v e n t .

4 . 5 . 2 T o t a l c h l o r i n e c o n t e n t . T h e t o t a l c h l o r i n e c o n t e n t o f t h e s o l v e n t s h a l lb e d e t e r m i n e d b y a g a s c h r oma t o g r a p h i c me t h o d , m i c r o c o u l ome t r i c me t h o d , o r b y t h eu s e o f a p o r t a b l e t e s t k i t f o r t h e q u a n t i t a t i v e a n a l y s i s o f c h l o r i n e ( s e e 6 . 6 ) .No n c o n f o r ma n c e t o t a b l e I s h a l l c o n s t i t u t e f a i l u r e o f t h i s t e s t .

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4 . 6 I n s p e c t i o n o f p r e p a r a t i o n f o r d e l i v e r y .

4 . 6 . 1 Ou a l i t y c o n f o r ma n c e i n s p e c t i o n o f r me r s a r a t i o n f o r d e l i v e r t .

4 . 6 . 1 . 1 Un i t o f D r o d u c t . F o r t h e p u r p o s e o f i n s p e c t i o n , a c omp l e t e p a c kp r e p a r e d f o r s h i pme n t s h a l l b e c o n s i d e r e d a u n i t o f p r o d u c t .

4 . 6 . 1 . 2 I n s p e c t i o n l o t . T h e i n s p e c t i o n l o t s h a l l b e a s d e f i n e d i n 4 . 4 . 1 ,p a c k e d f o r s h i pme n t .

4 . 6 . 1 . 3 S amp l i n q . S amp l e s f o r e x am i n a t i o n o f p r e p a r a t i o n f o r d e l i v e r y s h a l l b es e l e c t e d a t r a n d om f r om e a c h i n s p e c t i o n l o t i n a c c o r d a n c e . w , i t h p r o c e d u r ep r e s c r i b e d i n M I L - STD - 1 0 5 . S amp l e s i z e s h a l l b e d e t e r m i n e d b y u s i n g M I L - STD - 1 0 5 ,t a b l e I a n d t a b l e I I a . A l o t s h a l l b e a c c e p t e d wh e n z e r o d e f e c t s a r e f o u n d a n dr e j e c t e d wh e n o n e o r mo r e d e f e c t s a r e f o u n d .

~4 . 6 . 1 . 4 E x am i n a t i o n . S amp l e s s e l e c t e d i n a c c o r d a n c e w i t h 4 . 6 . 1 . 3 s h a l l b e

e x am i n e d f o r t h e d e f e c t s l i s t e d b e l ow .

101.102.103.104.

105.

106.107.108.

5.

Un i t c o n t a i n e r s n o t o f t h e s i z e ( s ) s p e c i f i e d .Un i t c o n t a i n e r s n o t a s s p e c i f i e d i n M I L - STD - 2 9 0 .I n t e r me d i a t e c o n t a i n e r s , wh e n r e q u i r e d , n o t a s s p e c i f i e d i n M I L - STD - 2 9 0 .

Qu a l i t y a n d a r r a n g eme n t o f u n i t c o n t a i n e r s p o s i t i o n e d w i t h i n i n t e r me d i a t ec o n t a i n e r s , wh e n r e q u i r e d , n o t a s s p e c i f i e d i n M I L - STD - 2 9 0 .Qu a n t i t y a n d a r r a n g eme n t o f f i l l e d i n t e r me d i a t e c o n t a i n e r s p a c k e d w i t h i ne x t e r i o r c o n t a i n e r s , wh e n r e q u i r e d , n o t a s s p e c i f i e d i n M I L - STD - 2 9 0 .E x t e r i o r c o n t a i n e r s , wh e n r e q u i r e d , n o t a s s p e c i f i e d i n M I L - STD - 2 9 0 .Ma r k i n g n o t a s s p e c i f i e d h e r e i n a n d i n M I L - STD - 1 2 9 o r M I L - STD - 2 9 0 .P a l l e t i z a t i o n , wh e n r e q u i r e d , n o t a s s p e c i f i e d i n M I L - STD - 1 4 7 .

PREPARAT I ON FOR OE L I VERY

5 . 1 P a c k i n q . Un i t c o n t a i n e r s s h a l l b e t h e s i z e o r s i z e s s p e c i f i e d i n 6 . 2 ( s e e6 . 3 ) a n d s h a l l c omp l y w i t h t h e a p p l i c a b l e r e q u i r eme n t s o f M I L - STO - 2 9 0 f o r l e v e l B ,C , o r c omme r c i a l , a s s p e c i f i e d ( s e e 6 . 2 ) . I n t e r me d i a t e c o n t a i n e r s wh e n r e q u i r e do f t h e s p e c i f i e d u n i t c o n t a i n e r s , s h a l l b e a s s p e c i f i e d t h e r e i n . Wh e n e x t e r i o rc o n t a i n e r s a r e r e q u i r e d , t h e y s h a l l b e i n a c c o r d a n c e w i t h t h e l e v e l B , C , o rc omme r c i a l r e q u i r eme n t s o f M I L - STD - 2 9 0 , a s s p e c i f i e d ( s e e 6 . 2 ) .

5 . 2 Ma r k i n q . I n a d d i t i o n t o a n y s p e c i a l o r i d e n t i f i c a t i o n ma r k i n g s r e q u i r e d b yt h e c o n t r a c t o r p u r c h a s e / d e l i v e r y o r d e r , a l l c o n t a i n e r s s h a l l b e ma r k e d i na c c o r d a n c e w i t h M I L - STD - 1 2 9 a n d , a s a p p l i c a b l e , M I L - STD - 2 9 0 .

5 . 3 P a l l e t i z a t i o n . Wh e n s p e c i f i e d ( s e e 6 . 2 ) , t h e p a c k e d d r y c l e a n i n g a n dd e c r e a s i n g s o l v e n t s h a l l b e p a l l e t i z e d i n a c c o r d a n c e w i t h M I L - STD - 1 4 7 . NOT E :P a l l e t i z e d l o a d s s h a l l b e ma r k e d i n a c c o r d a n c e w i t h M I L - STO - 1 2 9 .

6 . NOT ES

( T h i s s e c t i o nb e h e l p f u l , b u t

c o n t a i n s i n f o r ma t i o n o f a g e n e r a l o r e x p l a n a t o r y n a t u r e t h a t ma yi s n o t ma n d a t o r y . )

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I

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6 . 1 I n t e n d e d u s e . T h i s s o l v e n t i s a l s o k n own a s “ M i n e r a l Sp i r i t s ” o r“ P e t r o l e um Sp i r i t s ” . I t i s u s e d i n t h e d r y c l e a n i n g a n d t h e c o a t i n g s i n d u s t r i e s .I t i s u s e d i n t h e m i l i t a r y a s a d e g r e a s e r a n d c l e a n e r f o r ma c h i n e p a r t s .

6 . 1 . 1 T v p e I . T y p e I ( S t o d d a r d s o l v e n t ) i s i n t e n d e d a s a c omp a r a t i v e l y s a f ed r y c l e a n i n g s o l v e n t . Wh e n t y p e I s o l v e n t i s u s e d i n d o o r s , v e n t i l a t i o n s h a l l b es u f f i c i e n t t o p r e v e n t t h e a c c umu l a t i o n o f v a p o r s a b o v e r e q u i r e d e x p o s u r e l i m i t s .

6 . 1 . 2 T vDe I I . T y p e I I ( h i g h f l a s h p o i n t s o l v e n t ) i s i n t e n d e d wh e r e a s o l v e n tw i t h a h i g h e r f l a s h p o i n t i s d e s i r e d . I t i s r e c omme n d e d o v e r t y p e I f o r s a f e t ya n d r e g u l a t o r y r e a s o n s . Wh e n t y p e 1 1 s o l v e n t i s u s e d i n d o o r s , v e n t i l a t i o n s h a l lb e s u f f i c i e n t t o p r e v e n t t h e a c c umu l a t i o n o f i + v a p o r s a b o v e r e q u i r e d e x p o s u r el i m i t s .

6 . 1 . 3 T v p e III. T y p e III (low odor with v e r y h i g h f l a s h p o i n t s o l v e n t ) i si n t e n d e d t o b e u s e d wh e r e c o n f i n e d a t mo s p h e r i c c o n d i t i o n s r e q u i r e a c l e a n e r t h a t

c o n f o r ms t o t h e f e d e r a l Go v e r nme n t ’ s d i r e c t i v e s f o r r e d u c e d h a z a r d o u s ma t e r i a l s .

6 . 2 A c q u i s i t i o n r e q u i r eme n t s . A c q u i s i t i o n d o c ume n t s s h a l l s p e c i f y t h ef o l l ow i n g :

a . T i t l e , n umb e r a n d d a t e o f t h i s s p e c i f i c a t i o n .b . T y p e a n d q u a n t i t y .c . I s s u e o f DOD I SS t o b e c i t e d i n t h e s o l i c i t a t i o n , a n d i f r e q u i r e d , t h e

s p e c i f i c i s s u e o f i n d i v i d u a l d o c ume n t s r e f e r e n c e d ( s e e 2 . 1 . 1 a n d 2 . 2 ) .d . L e v e l o f p a c k a g i n g a n d p a c k i n g r e q u i r e d ( s e e 5 . 1 ) .e . An y s p e c i a l ma r k i n g s ( s e e 5 . 2 ) .f . Wh e n p a l l e t i z a t i o n i s r e q u i r e d ( s e e 5 . 3 ) .

6 . 3 Na t i o n a l s t o c k n umb e r s . s i z e s . d a s h n umb e r s . T h e n a t i o n a l s t o c k n umb e r s( NSNS ) , s i z e s a n d d a s h n umb e r s a r e l i s t e d i n t a b l e 1 1 1 .

TABL E III. Na t i o n a l s t o c k n umb e r s . s i z e s . d a s h n umb e r s .

r y J&

IIIIII111111IIIII111

S i z e / Un i t o f I s s u e

Bu l k4 Ou n c e1 Qu a r t1 Ga l l o n ( G l )5 Ga l l o n c a n ( Cn )5 5 Ga l l o n d r um ( D r )Bu l k1 P i n t c a n5 Ga l l o n c a n ( Cn )5 5 Ga l l o n d r um ( D r )5 Ga l l o n c a n ( Cn )5 5 Ga l l o n d r um ( O r )

miiiFTSD - 1 / S - 7 5 2SD - 1 / S - 7 5 2SD - 1 / S - 7 5 2SD - 1 / S - 7 5 2SD - 1 / S - 7 5 2SD - 1 / S - 7 5 2SD - 1 / S - 7 5 3SD - 1 / S - 7 5 3SD - 1 / S - 7 5 3SD - 1 / S - 7 5 3SD - 3 / n o n eSD - 3 / n o n e

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6 . 4 I n t e r n a t i o n a l s t a n d a r d i z a t i o n . C e r t a i n p r o v i s i o n s o f t h i s s p e c i f i c a t i o na r e t h e s u b j e c t o f i n t e r n a t i o n a l s t a n d a r d i z a t i o n a g r e eme n t ( NATO STANAG 1 1 3 5 ,a n n e x C ) . Wh e n ame n dme n t , r e v i s i o n , o r c a n c e l l a t i o n o f t h i s s p e c i f i c a t i o n i s

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p r o p o s e d wh i c h wo u l d a f f e c t o r v i o l a t e t h e i n t e r n a t i o n a l a g r e eme n t c o n c e r n e d , t h ep r e p a r i n g a c t i v i t y w i l J t a k e a p p r o p r i a t e r e c o n c i l i a t i o n a c t i o n t h r o u g hi n t e r n a t i o n a l c h a n n e l s , i n c l u d i n g d e p a r t me n t a l s t a n d a r d i z a t i o n o f f i c e s , i fr e q u i r e d .

6 . 5 O i sDo s a l a c t i o n s . D i s p o s a l o f t h i s p r o d u c t s h a l l b e i n a c c o r d a n c e w i t hl o c a l , s t a t e a n d F e d e r a l r e g u l a t i o n s . C a r e s h o u l d b e t a k e n t o a v o i d m i x i n g u s e dP - D - 6 8 0 w i t h o t h e r wa s t e ma t e r i a l s , e s p e c i a l l y t h o s e c o n t a i n i n g h a l o g e n a t e ds o l v e n t s .

6 . 6 Ma t e r i a l S a f e t v Da t a Sh e e t s . T h e c o n t r a c t i n g o f f i c e r s w i l l i d e n t i f y t h o s ea c t i v i t i e s r e q u i r i n g c o p i e s o f c omp l e t e d Ma t e r i a l S a f e t y Da t a Sh e e t s p r e p a r e d i n

I a c c o r d a n c e w i t h F ED - STD - 3 1 3 . T h e p e r t i n e n t Go v e r nme n t ma i l i n g a d d r e s s e s f o rs u bm i s s i o n o f d a t a a r e l i s t e d i n F ED - STD - 3 1 3 .

6 . 7 Ch l o r i n e d e t e c t i o n k i t . A s i mp l e , d i s p o s a b l e k i t f o r t h e d e t e c t i o n o ft o t a l c h l o r i n e s u p p l i e d b y t h e De x s i l Co r p o r a t i o n , Hamd e n , Co n n e c t i c u t , o r i t se q u i v a l e n t , ma y b e u s e d f o r t h e d e t e c t i o n o f t o t a l c h l o r i n e c o n t e n t . D i r e c t i o n sa c c omp a n y i n g t h e t e s t k i t s h a l l b e f o l l owe d .

6 . 8 P a r t o r i d e n t i f v i n c ! n umb e r ( P I N } . D r y c l e a n i n g a n d d e c r e a s i n g s o l v e n t f o rd e c r e a s i n g o f ma c h i n e p a r t s a n d f o r d r y c l e a n i n g , s p o t a n d s t a i n r emo v i n g u n d e rt h i s s p e c i f i c a t i o n s h a l l b e i d e n t i f i e d b y a P I N c o n s i s t i n g o f a “ 8 ” p r e f i x a n d ab a s i c s p e c i f i c a t i o n n umb e r , f o l l owe d b y t h e t wo d i g i t d a s h n umb e r f o u n d i n t a b l e1 1 1 , a s s h own i n t h e f o l l ow i n g e x amp l e :

I E x amp l e 8 - 6 8 0 - 0 1I

8 u l k ma t e r i a l i d e n t i f i e r I HSp e c i f i c a t i o n n umb e r ~ IDa s h number~

6 . 9 De f i n i t i o n s . T h e Oc c u p a t i o n a l S a f e t y a n d He a l t h Adm i n i s t r a t i o n ( OSHA )d e f i n i t i o n o f c a r c i n o g e n s a r e t h o s e c h em i c a l s / p r o c e s s e s a p p e a r i n ? i n l i s t s 1 , 2A ,a n d 2 8 o f t h e I n t e r n a t i o n a l Ag e n c y f o r Re s e a r c h o n C a n c e r ( I ARC ) J ; s u b s t a n c e sk n own t o b e c a r c i n o g e n i c , s u b s t a n c e s r e a s o n a b l y a n t i c i p a t e d t o b e c a r c i n o g e n i c a n do c c u p a t i o n a l e x p o s u r e s a s s o c i a t e d w i t h a t e c h n o l o g i c a l p r o c e s s k n own t o b ec a r c i n o g e n i c b y t h e Na t i o n a l T o x i c o l o g y P r o g r am ( NTP ) Re p o r t o n C a r c i n o g e n s( l a t e s t a n n u a l r e p o r t ) ” ; a n d OSHA r e g u l a t e d c a r c i n o g e n s .

6 . 1 0 T o x i c o l o g i c a l D r o d u c t f o r mu l a t i o n s i n f o r ma t i o n . T h e c o n t r a c t i n g o f f i c e rw i l l r e q u i r e t h e c o n t r a c t o r t o h a v e t h e t o x i c o l o g i c a l p r o d u c t f o r mu l a t i o n s a n d

~ / Co p i e s o f t h e s e v o l ume s ma y b e f o u n d i n me d i c a l l i b r a r i e s o r t h r o u g h t h e Wo r l dHe a l t h O r g a n i z a t i o n , 1 2 1 1 Ge n e v a 2 7 , Sw i t z e r l a n d .

9

z / Co p i e s ma y b e o b t a i n e d f r om t h e Pu b l i c He a l t h S e r v i c e , Na t i o n a l T o x i c o l o g yP r o g r am , Pu b l i c I n f o r ma t i o n O f f i c e , P . O . 8 0X 1 2 2 3 3 , MD 8 2 - 0 4 , Re s e a r c hT r i a n g l e P a r k , NC 2 7 7 0 9 .

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a s s o c i a t e d i n f o r ma t i o n a v a i l a b l e f o r r e v i ew b y t h e c o n t r a c t i n g a c t i v i t y t oe v a l u a t e t h e s a f e t y o f t h e ma t e r i a l f o r t h e p r o p o s e d u s e t h r o u g h t h e s u bm i s s i o n o ft h e Ma t e r i a l S a f e t y Da t a Sh e e t d e t a i l e d i n F ED - STD - 3 1 3 ( s e e 6 . 6 ) .

6 . 1 1 Su b . i e c t t e r m ( k e y wo r d ) l i s t i n q .

1 4 0 “ F s o l v e n t ( t y p e II)200 “F solvent (type 111)M i n e r a l s p i r i t sS t o d d a r d s o l v e n t ( t y p e I )P e t r o l e um s p i r i t s ( USA )Na p h t h a . . * ,

6 . 1 0 Ch a n q e s f r om p r e v i o u s i s s u e . Ma r g i n a l n o t a t i o n s a r e n o t u s e d i n t h i sr e v i s i o n t o i d e n t i f y c h a n g e s w i t h r e s p e c t t o t h e p r e v i o u s i s s u e d u e t o t h ee x t e n s i v e n e s s o f t h e c h a n g e s .

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