Download - Heat Exchanger
Appendix F -63
Production of 100,000 MTA Hydrogen
F.10 SIZING AND COSTING FOR HEAT EXCHANGER
Heat Exchanger, X-5Heat exchanger type 2 shell and 4 tubesDesign type Split-ring floating headHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side NgShell side SteamHeat duty (kW) 11666.670a) Equipment sizing
shell tubeStream Steam NG
617.60 330.86
579.55 607.25
344.10306.4057.71
334.10
R = ( eqn. 12.6 )= 0.138
S= ( eqn. 12.7 )= 0.964
Ft can be obtained from fig 12.19 ( vol. 6 ),
0.8900
Tin (K)
Tout (K)
T1(oC) = T2(oC) = t1(oC) = t2(oC) =
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =
T1 = inlet temperature to shellT2 = outlet temperature from shellt1 = inlet temperature to tubet2 = outlet temperature from tube
T2T1
t2
t1
Appendix F -64
Production of 100,000 MTA Hydrogen
( eqn. 12.4 )
74.9681
Therefore, the actual temperature difference is
66.7216
Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 454.264
Provisional area of heat exchanger, A can be obtained trough the formulae,
Provisional area, A 384.92164143.2620
b) Tube rating ( App.5.-2, Tranport Processes )Material Carbon steelBWG number 18
2.4419.0516.56
Material Thermal Conductivity ( W/m.K ) 16.3
0.1460
1.5718
Number of tube, Nt
2636
Tube pitch is the distance between tube centres and formulated as
DTlm can be calculated from the equation,
DTlm =
FtDTlm =
W/(C.m2)
m2
ft2
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)
Heat transfer area of a tube, At
Area of one tube, At (m2)
(ft2)
Number of tube, Nt
ΔT lm=(T 1−t 2 )−(T2−t1 )
ln(T1−t 2 )(T2−t 1 )
Q=UA ΔTalignl ¿ lm ¿¿¿
A t=Lt πDalignl ¿ to ¿ ¿¿
A=Q
UΔT lm
N t=AA t
Appendix F -65
Production of 100,000 MTA Hydrogen
23.8125
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition )
0.249( 2 passes ) n 2.207
( eqn. 12.3b )
1269.1683
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 72
For Split-ring floating head, Ds = Db + shell bundle clearance
1.3412
c) Tube side coefficient
Mean temperature (K)
Mean temperature (K) 469.0550
215.4105
659
0.1420
Tube pitch, Pt (mm)
Triangular pitch K1
The bundle diameter, Db
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(Tc.in +Tc,out)/2
Tube cross-sectional area, At
Tube cross-sectional area, At
Tube cross-sectional area, At mm2
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Pt=1 . 25×D to
Db=D to( N t / K1 )1 /n
A t=πDti2
¿4 ¿¿
¿
AT=N t A t
Appendix F -66
Production of 100,000 MTA Hydrogen
Mass flow rate (inside tube), m 10.1183 kg/s
71.2794
Physical properties of the tube side fluidPhysical properties of Water
1015.2654
7.94E-044.17172369041347 kJ/kg.K
0.09488828968 W/m.K
Linear velocity, u
Reynold number, Re
Prandtl number, Pr
linear velocity, u (m/s) 0.0702Reynold number, Re 1486.072Prandtl number, Pr 34.9211
147.3430
From figure 12.23, Chemical Engineering, Vol. 6
0.0035
( eqn. 12.15 )
96.26738( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
d) Tube side pressure drop
From figure 12.24 'Chemical Engineering'. Vol. 6
Fluid velocity, nf
mass velocity, nf kg/m2.s
water density, rt kg/m3
Viscosity of water, mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi W/m2.C
v f=m / AT
u=v f / ρ
Re=ρuDti
μ
Pr=Cp μ
k f
hi=k f jh RePr0 . 33
Dti ( μμw )
0 .14
Appendix F -67
Production of 100,000 MTA Hydrogen
0.0030
( eqn. 12.20 )where m = 0.25 for laminar flow, Re<2100 m = 0.14 for turbulent flow, Re>2100
0.0302 kPa (acceptable)
e) Shell side coefficient1.3412 m Baffle
diameter
1.2071 mBaffle Diameter 1.3396 m
23.8125 mm
( eqn. 12.21 )
0.3238
204583 kg/hr
175.5206
( eqn. 12.23 )
friction factor, jf
Tube side pressure drop, DPt
Np = number of tube side passes
Tube side pressure drop,
DPt
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As m2
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs kg/s.m2
Shell side equivalent diameter, De
ΔPs=N p [ 8 jf ( L/ Dti )(μ
μw)−m+2. 5 ]
ρus2
2
Baffle Diameter=D s−0 . 0016
Baffle Spacing , lB=0 .9∗Ds
A s=( p t−Dto )D s lB
pt
sss AwG /
De=1 .1Dto
( pz2−0.971 Dto
2 )
Appendix F -68
Production of 100,000 MTA Hydrogen
13.5265 mm
Mean temperature (C)
Mean temperature (C) 598.5750
Physical properties of shell fluid (light hydrocarbon)
Physical properties
3.9318
3.3589E-052.60682510137189 kJ/kg.K
0.1718 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 2989.010Prandtl number, Pr 0.5096
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0100
( eqn. 12.25 )
303.966
f) Shell side pressure drop
44.6413 m/s
From figure 12.30 'Chemical Engineering'. Vol. 6
0.0800
Shell side equivalent diameter, De
Tmean = (Tshell.in +Tshell.out)/2
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs W/m2.C
Linear velocity, us
Linear velocity, us
friction factor, jf
Re=Gs De /μ
hs=k f jh RePr1/3
De ( μμw )
0 .14
us=Gs / ρ
Appendix F -69
Production of 100,000 MTA Hydrogen
( eqn. 12.26 )
Shell side presure drop, 26979084.0816 Pa (acceptable)
26979.0841 kPa
g) Overall Coefficient
303.966
96.26738
5000
5500
16.30.01656
0.01905
Overall heat transfer coefficient can be calculated by using the formula
( eqn. 12.1 )Therefore,
0.0157305122079733
63.5707208245343
1
Shell side presure drop, DPs
DPs
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (from Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
1/Uo =
Uo = W/m2.C
h) Number of baffle, Nb
Number of baffle, Nb
Nbaffle
hs=k f jh RePr1/3
De ( μμw )
0 .14
1Uo
= 1hs
+ 1hod
+d to ln (d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Nb=( L/ lB)−1
Appendix F -70
Production of 100,000 MTA Hydrogen
Costing
Type Shell and tube
384.9216Material Carbon SteelFeed Pressure 5.07bar
With reference to costing method proposed by L.T. Biegler,Base Cost, C
Bare Module Cost, BMC For 100<S<10000 ft2,Co 5000So 400
Materials and Pressure Correction Factor, MPF a 0.65UF 3.219048
Total area (ft2) 4143.26Base cost, C ($) 22850.9134Modular factor, MF 3.29Design factor, Fd 1.0 (Floating head)Pressure factor, Fp 0Material factor, Fm 1 (CS/CS)MPF 1Bare module cost ($) 242,006.407Bare module cost (RM) 919,624.348
Area (m2)
C=C0( S/ S0 )α
BMC=BC (C )×MF
MPF=Fm( F p+Fd)
Appendix F -71
Production of 100,000 MTA Hydrogen
Heat Exchanger, X-11
Heat exchanger type 1 shell and 2 tubesDesign type Split-ring floating headHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side organic solventsShell side methanolHeat duty (kW) 3321.390
a) Equipment sizingshell tube
Stream methanol organic solvent300.15 284.15
294.15 289.79
R = ( eqn. 12.6 )R= 1.064
S= ( eqn. 12.7 )S= 0.353
Ft can be obtained from fig 12.19 ( vol. 6 ),
0.9800
Tin (K)
Tout (K)
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =
DTlm can be calculated from the equation,
ΔT lm=(T 1−t2 )−(T2−t1 )
ln(T1−t 2 )(T2−t 1 )
T1 = inlet temperature to shellT2 = outlet temperature from shellt1 = inlet temperature to tubet2 = outlet temperature from tube
T2
T1
t2
t1
Appendix F -72
Production of 100,000 MTA Hydrogen
( eqn. 12.4 )
10.1789Therefore, the actual temperature difference is
9.9754
Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 900
Provisional area of heat exchanger, A can be obtained trough the formulae,
Provisional area, A 369.95493972.9842
b) Tube rating ( App.5.-2, Tranport Processes )Material Carbon steelBWG number 18
2.4419.0516.56
Material Thermal Conductivity ( W/m.K ) 16.3
0.1460
1.5718Number of tube, Nt
2533
Tube pitch is the distance between tube centres and formulated as
23.8125
DTlm =
FtDTlm =
W/(C.m2)
m2
ft2
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)
Heat transfer area of a tube, At
Area of one tube, At (m2)
(ft2)
Number of tube, Nt
Tube pitch, Pt (mm)
ΔT lm=(T 1−t2 )−(T2−t1 )
ln(T1−t 2 )(T2−t 1 )
Q=UA ΔTalignl¿ lm ¿¿¿
A t=Lt πDalignl ¿ to ¿ ¿¿
A=Q
UΔT lm
N t=AA t
Pt=1 . 25×D to
Appendix F -73
Production of 100,000 MTA Hydrogen
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition )
0.249( 2 passes ) n 2.207
( eqn. 12.3b )
1246.5656
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 78
For Split-ring floating head, Ds = Db + shell bundle clearance
1.3246
c) Tube side coefficient
Mean temperature (K)
Mean temperature (K) 286.9700
215.4105
633
0.1364
Mass flow rate (inside tube), m 166.1064 kg/hr
Triangular pitch K1
The bundle diameter, Db
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(Tc.in +Tc,out)/2
Tube cross-sectional area, At
Tube cross-sectional area, At
Tube cross-sectional area, At mm2
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Fluid velocity, nf
Db=D to( N t / K1 )1 /n
A t=πDti2
¿4 ¿¿
¿
AT=N t A t
Appendix F -74
Production of 100,000 MTA Hydrogen
1217.4888
Physical properties of the tube side fluidPhysical properties
838.4112
5.15E-043.5453121354088 kJ/kg.K
0.57972579598 W/m.K
Linear velocity, u
Reynold number, Re
Prandtl number, Pr
linear velocity, u (m/s) 1.4521Reynold number, Re 39166.029Prandtl number, Pr 3.1481
147.3430
From figure 12.23, Chemical Engineering, Vol. 6
0.0037
( eqn. 12.15 )
7406.777( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
d) Tube side pressure drop
From figure 12.24 'Chemical Engineering'. Vol. 6
0.0034
mass velocity, nf kg/m2.s
density, rt kg/m3
Viscosity, mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi W/m2.C
friction factor, jf
Tube side pressure drop, DPt
v f=m / AT
u=v f / ρ
Re=ρuDti
μ
Pr=Cp μk f
hi=k f jh RePr0 . 33
Dti ( μμw )
0 .14
Appendix F -75
Production of 100,000 MTA Hydrogen
( eqn. 12.20 )where m = 0.25 for laminar flow, Re<2100 m = 0.14 for turbulent flow, Re>2100
11.5054 kPa (acceptable)
e) Shell side coefficient1.3246 m Baffle
diameter
1.1921 mBaffle Diameter 1.3230 m
23.8125 mm
( eqn. 12.21 )
0.3158
720925.4752 kg/hr
634.1155
( eqn. 12.23 )
13.5265 mm
Mean temperature (C)
Np = number of tube side passes
Tube side pressure drop,
DPt
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As m2
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs kg/s.m2
Shell side equivalent diameter, De
Shell side equivalent diameter, De
ΔPs=N p [ 8 jf ( L/ Dti )(μμw
)−m+2. 5 ]ρus
2
2
Baffle Diameter=D s−0 . 0016
Baffle Spacing , lB=0 . 9∗Ds
A s=( p t−Dto )D s lB
pt
sss AwG /
De=1 . 1Dto
( pz2−0. 971 Dto
2 )
Appendix F -76
Production of 100,000 MTA Hydrogen
Mean temperature (C) 297.1500
Physical properties of shell fluid
Physical properties
799.8603
5.1581E-043.69813443294356 kJ/kg.K
0.6155 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 16662.361Prandtl number, Pr 3.0990
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0055
( eqn. 12.25 )
6057.223
f) Shell side pressure drop
0.7928 m/s
From figure 12.30 'Chemical Engineering'. Vol. 6
0.0630
Tmean = (Tshell.in +Tshell.out)/2
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs W/m2.C
Linear velocity, us
Linear velocity, us
friction factor, jf
Shell side presure drop, DPs
Re=Gs De /μ
hs=k f jh RePr1/3
De ( μμw )
0 .14
us=Gs / ρ
hs=k f jh RePr1/3
De ( μμw )
0 .14
Appendix F -77
Production of 100,000 MTA Hydrogen
( eqn. 12.26 )
Shell side presure drop, 1495229.0275 Pa (acceptable)
1495.2290 kPa
g) Overall Coefficient
6057.223
7406.777
5000
5500
16.30.01656
0.01905
Overall heat transfer coefficient can be calculated by using the formula
( eqn. 12.1 )Therefore,
0.00081141584494073
1232.41369543757
1
DPs
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (from Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
1/Uo =
Uo = W/m2.C
h) Number of baffle, Nb
Number of baffle, Nb
Nbaffle
hs=k f jh RePr1/3
De ( μμw )
0 .14
1Uo
= 1hs
+ 1hod
+d to ln (d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Nb=( L/ lB)−1
C=C 0(S/S0)α
BMC= BC(C)×MF
MPF= Fm(Fp+Fd)
Appendix F -78
Production of 100,000 MTA Hydrogen
Costing
Type Shell and tube
369.9549Material Carbon SteelFeed Pressure 24 bar
With reference to costing method proposed by L.T. Biegler,Base Cost, C
For 100<S<10000 ft2,Co 5000
Bare Module Cost, BMC So 400a 0.65UF 3.219048
Materials and Pressure Correction Factor, MPF
Total area (ft2) 3972.98Base cost, C ($) 22236.0146Modular factor, MF 3.29Design factor, Fd 1.0 (Floating head)Pressure factor, Fp 0Material factor, Fm 1 (CS/CS)MPF 1Bare module cost ($) $235,494Bare module cost (RM) 894,878
Area (m2)
C=C0( S/ S0 )α
BMC=BC (C )×MF
MPF=Fm( F p+Fd)
Appendix F -79
Production of 100,000 MTA Hydrogen
Heat Exchanger, X-13
Heat exchanger type 1 shell and 2 tubesDesign type Split-ring floaring headHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side Methanol recoveredShell side Light HydrocarbonHeat duty (kW) 3057.170
a) Equipment sizingshell tube
Stream Light Hydrocarbon Methanol573.15 290.15
548.97 295.97
R = ( eqn. 12.6 )R= 4.155
S= ( eqn. 12.7 )S= 0.021
Ft can be obtained from fig 12.19 ( vol. 6 ),
1.0000
( eqn. 12.4 )
267.8952
Therefore, the actual temperature difference is
Tin (K)
Tout (K)
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =DTlm can be calculated from the equation,
DTlm =
ΔT lm=(T 1−t2 )−(T2−t1 )
ln(T1−t2 )(T2−t1 )
T1 = inlet temperature to shellT2 = outlet temperature from shellt1 = inlet temperature to tubet2 = outlet temperature from tube
T2
T1
t2
t1
Appendix F -80
Production of 100,000 MTA Hydrogen
267.8952
Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 400
Provisional area of heat exchanger, A can be obtained trough the formulae,
Provisional area, A 28.5295307.0894
b) Tube rating ( App.5.-2, Tranport Processes )Material Carbon steelBWG number 14
2.4419.0514.83
Material Thermal Conductivity ( W/m.K ) 16.3
0.1460
Number of tube, Nt
195
Tube pitch is the distance between tube centres and formulated as
23.8125
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition )
0.249( 2 passes ) n 2.207
FtDTlm =
W/(C.m2)
m2
ft2
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)
Heat transfer area of a tube, At
Area of one tube, At (m2)
(ft2)
Number of tube, Nt
Tube pitch, Pt (mm)
Triangular pitch K1
Q=UA ΔTalignl¿ lm ¿¿¿
A t=Lt πDalignl ¿ to ¿ ¿¿
A=Q
UΔT lm
N t=AA t
Pt=1 . 25×D to
Appendix F -81
Production of 100,000 MTA Hydrogen
( eqn. 12.3b )
390.3703
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 57
For Split-ring floating head, Ds = Db + shell bundle clearance
0.4474
c) Tube side coefficient
Mean temperature (C)
Mean temperature (K) 293.0600
172.7542
49
0.0084
Mass flow rate (inside tube), m 142.3730 kg/s
16873.2532
The bundle diameter, Db
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(Tc.in +Tc,out)/2
Tube cross-sectional area, At
Tube cross-sectional area, At
Tube cross-sectional area, At mm2
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Fluid velocity, nf
Methanol mass velocity, nf kg/m2.s
Db=D to( N t / K1 )1 /n
A t=πDti2
¿4 ¿¿
¿
AT=N t A t
v f=m / AT
Appendix F -82
Production of 100,000 MTA Hydrogen
Physical properties of the tube side fluidPhysical properties of Water
803.3824
5.11E-043.68951132359407 kJ/kg.K
0.60890216686 W/m.K
Linear velocity, u
Reynold number, Re
Prandtl number, Pr
E.G. linear velocity, u (m/s) 21.0028Reynold number, Re 489687.564Prandtl number, Pr 3.0963
164.5314
From figure 12.23, Chemical Engineering, Vol. 6
0.0030
( eqn. 12.15 )
87584( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
d) Tube side pressure drop
From figure 12.24 'Chemical Engineering'. Vol. 6
0.0021
( eqn. 12.20 )
Methanol density, rt kg/m3
Viscosity of Methanol, mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi (W/m2.C)
friction factor, jf
Tube side pressure drop, DPt
u=v f / ρ
Re=ρuDti
μ
Pr=Cp μ
k f
hi=k f jh RePr0 . 33
Dti ( μμw )
0 .14
ΔPs=N p [ 8 jf ( L/ Dti )(μ
μw)−m+2. 5 ]
ρus2
2
Appendix F -83
Production of 100,000 MTA Hydrogen
where m = 0.25 for laminar flow, Re<2100 m = 0.14 for turbulent flow, Re>2100
1865.5276 kPa (acceptable)
e) Shell side coefficient0.4474 m
Baffle diameter
0.4026 mBaffle Diameter 0.4458 m
23.8125 mm
( eqn. 12.21 )
0.0360
204584.6683 kg/hr
1577.4795
( eqn. 12.23 )
13.5265 mm
Mean temperature (C)
Np = number of tube side passes
Tube side pressure drop,
DPt
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As m2
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs kg/s.m2
Shell side equivalent diameter, De
Shell side equivalent diameter, De
Tmean = (Tshell.in +Tshell.out)/2
ΔPs=N p [ 8 jf ( L/ Dti )(μ
μw)−m+2. 5 ]
ρus2
2
Baffle Diameter=D s−0 . 0016
Baffle Spacing , lB=0 . 9∗Ds
As=( p t−Dto )D s lB
pt
sss AwG /
De=1 .1Dto
( pz2−0. 971 Dto
2 )
Appendix F -84
Production of 100,000 MTA Hydrogen
Mean temperature (C) 561.0600
Physical properties of shell fluid (light hydrocarbon)
Physical properties
8.3574
1.2178E-052.95453136063117 kJ/kg.K
0.1169 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 41756.754Prandtl number, Pr 0.3079
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0040
( eqn. 12.25 )
978.2222
f) Shell side pressure drop
188.7524 m/sFrom figure 12.30 'Chemical Engineering'. Vol. 6
0.0590
( eqn. 12.26 )
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs (W/m2.C)
Linear velocity, us
Linear velocity, us
friction factor, jf
Shell side presure drop, DPs
Re=Gs De /μ
hs=k f jh RePr1/3
De ( μμw )
0 .14
us=Gs / ρ
hs=k f jh RePr1/3
De ( μμw )
0 .14
Appendix F -85
Production of 100,000 MTA Hydrogen
Shell side presure drop, 1794482930.0673 Pa (acceptable)
1794482.9301 kPa
g) Overall Coefficient
978.2222
87584
5000
5000
16.30.01483
0.01905
Overall heat transfer coefficient can be calculated by using the formula
( eqn. 12.1 )Therefore,
0.00164017232653821
609.692032855247
5
Costing
Type Shell and tube
28.5295Material Carbon SteelFeed Pressure 24 bar
DPs
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (from Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
1/Uo =
Uo = W/m2.C (acceptable)
h) Number of baffle, Nb
Number of baffle, Nb
Nbaffle
Area (m2)
hs=k f jh RePr1/3
De ( μμw )
0 .14
1Uo
= 1hs
+ 1hod
+d to ln(d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Nb=( L/ lB)−1
Appendix F -86
Production of 100,000 MTA Hydrogen
With reference to costing method proposed by L.T. Biegler,Base Cost, C
For 100<S<10000 ft2,Co 5000
Bare Module Cost, BMC So 400a 0.65UF 3.219048
Materials and Pressure Correction Factor, MPF
Total area (ft2) 307.09Base cost, C ($) 4210.6888Modular factor, MF 3.29Design factor, Fd 1.0 (Floating head)Pressure factor, Fp 0Material factor, Fm 1 (CS/CS)MPF 1Bare module cost ($) $44,594Bare module cost (RM) 169,457
C=C0( S/ S0 )α
BMC=BC (C )×MF
MPF=Fm( F p+Fd )
Appendix F -87
Production of 100,000 MTA Hydrogen
Heat Exchanger, X-16
Heat exchanger type 1 shell and 2 tubesDesign type Split-ring floating headHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side WaterShell side light hydrocarbonHeat duty (kW) 12112.210
a) Equipment sizingshell tube
Stream Light HC Water548.97 364.25
453.15 373.15
R = ( eqn. 12.6 )R= 10.766
S= ( eqn. 12.7 )S= 0.048
Ft can be obtained from fig 12.19 ( vol. 6 ),
1.0000
( eqn. 12.4 )
Tin (K)
Tout (K)
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =
DTlm can be calculated from the equation,
ΔT lm=(T 1−t 2 )−(T2−t1 )
ln(T1−t 2 )(T2−t 1 )
T1 = inlet temperature to shellT2 = outlet temperature from shellt1 = inlet temperature to tubet2 = outlet temperature from tube
T2
T1
t2
t1
Appendix F -88
Production of 100,000 MTA Hydrogen
127.4583Therefore, the actual temperature difference is
127.4583
Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 500
Provisional area of heat exchanger, A can be obtained trough the formulae,
Provisional area, A 190.05762045.7633
b) Tube rating ( App.5.-2, Tranport Processes )Material Carbon steelBWG number 18
2.4419.0516.56
Material Thermal Conductivity ( W/m.K ) 16.3
0.1460
1.5718
Number of tube, Nt
1302
Tube pitch is the distance between tube centres and formulated as
23.8125
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition )
DTlm =
FtDTlm =
W/(C.m2)
m2
ft2
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)
Heat transfer area of a tube, At
Area of one tube, At (m2)
(ft2)
Number of tube, Nt
Tube pitch, Pt (mm)
Q=UA ΔTalignl ¿ lm ¿¿¿
A t=Lt πDalignl ¿ to ¿ ¿¿
A=Q
UΔT lm
N t=AA t
Pt=1 . 25×D to
Appendix F -89
Production of 100,000 MTA Hydrogen
0.249( 2 passes ) n 2.207
( eqn. 12.3b )
921.8256
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 70
For Split-ring floating head, Ds = Db + shell bundle clearance
0.9918
c) Tube side coefficient
Mean temperature (C)
Mean temperature (C) 368.7000
215.4105
325
0.0701
Mass flow rate (inside tube), m 326.2381 kg/s
Triangular pitch K1
The bundle diameter, Db
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(Tc.in +Tc,out)/2
Tube cross-sectional area, At
Tube cross-sectional area, At
Tube cross-sectional area, At mm2
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Db=D to( N t / K1 )1 /n
A t=πDti2
¿4 ¿¿
¿
AT=N t A t
Appendix F -90
Production of 100,000 MTA Hydrogen
4654.5408
Physical properties of the tube side fluidPhysical properties of Water
1015.2654
7.94E-044.1715617374329 kJ/kg.K
0.6155814452 W/m.K
Linear velocity, u
Reynold number, Re
Prandtl number, Pr
linear velocity, u (m/s) 4.5846Reynold number, Re 97040.408Prandtl number, Pr 5.3827
147.3430
From figure 12.23, Chemical Engineering, Vol. 6
0.0032
( eqn. 12.15 )
20116.7( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
Fluid velocity, nf
mass velocity, nf kg/m2.s
density, rt kg/m3
Viscosity, mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi (W/m2.C)
v f=m / AT
u=v f / ρ
Re=ρuDti
μ
Pr=Cp μ
k f
hi=k f jh RePr0 .33
Dti ( μμw )
0 .14
Appendix F -91
Production of 100,000 MTA Hydrogen
d) Tube side pressure drop
From figure 12.24 'Chemical Engineering'. Vol. 6
0.0028
( eqn. 12.20 )where m = 0.25 for laminar flow, Re<2100 m = 0.14 for turbulent flow, Re>2100
123.7765 kPa (acceptable)
e) Shell side coefficient0.9918 m
Baffle diameter
0.8926 mBaffle Diameter 0.9902 m
23.8125 mm
( eqn. 12.21 )
0.1771
206584.6683 kg/hr
324.0801
friction factor, jf
Tube side pressure drop, DPt
Np = number of tube side passes
Tube side pressure drop,
DPt
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As m2
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs kg/s.m2
Shell side equivalent diameter, De
ΔPs=N p [ 8 jf ( L/ Dti )(μμw
)−m+2.5 ]ρus
2
2
Baffle Diameter=D s−0 . 0016
Baffle Spacing , lB=0 .9∗Ds
As=( p t−Dto )D s lB
pt
sss AwG /
Appendix F -92
Production of 100,000 MTA Hydrogen
( eqn. 12.23 )
13.5265 mm
Mean temperature (C)
Mean temperature (C) 501.0600
Physical properties of shell fluid (light hydrocarbon)
Physical properties
8.2657
1.7348E-052.36028628549583 kJ/kg.K
0.0933 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 5518.890Prandtl number, Pr 0.4391
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0090
( eqn. 12.25 )
260.998
f) Shell side pressure drop
Shell side equivalent diameter, De
Tmean = (Tshell.in +Tshell.out)/2
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs (W/m2.C)
De=1 .1Dto
( pz2−0. 971 Dto
2 )
Re=Gs De /μ
hs=k f jh RePr1/3
De ( μμw )
0 .14
Appendix F -93
Production of 100,000 MTA Hydrogen
39.2078 m/s
From figure 12.30 'Chemical Engineering'. Vol. 6
0.0770
( eqn. 12.26 )
Shell side presure drop, 55360755.6653 Pa ((acceptable)
55360.7557 kPa
g) Overall Coefficient
260.998
20116.7
5000
5000
16.30.01656
0.01905
Overall heat transfer coefficient can be calculated by using the formula
( eqn. 12.1 )
Linear velocity, us
Linear velocity, us
friction factor, jf
Shell side presure drop, DPs
DPs
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (from Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
us=Gs / ρ
hs=k f jh RePr1/3
De ( μμw )
0 .14
1Uo
= 1hs
+ 1hod
+d to ln (d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Appendix F -94
Production of 100,000 MTA Hydrogen
Therefore,
0.00440056025829428
227.243791995616
2
Costing
Type Shell and tube
190.0576Material Carbon SteelFeed Pressure 24 bar
With reference to costing method proposed by L.T. Biegler,Base Cost, C
For 100<S<10000 ft2,Co 5000
Bare Module Cost, BMC So 400a 0.65UF 3.219048
Materials and Pressure Correction Factor, MPF
Total area (ft2) 2045.76Base cost, C ($) 14443.9845Modular factor, MF 3.29Design factor, Fd 1.0 (Floating head)Pressure factor, Fp 0Material factor, Fm 1 (CS/CS)MPF 1Bare module cost ($) $152,971Bare module cost (RM) 581,291
1/Uo =
Uo = W/m2.C
h) Number of baffle, Nb
Number of baffle, Nb
Nbaffle
Area (m2)
Nb=( L/ lB)−1
C=C 0(S/S0)α
BMC= BC(C)×MF
MPF= Fm(Fp+Fd)
C=C0( S/ S0 )α
BMC=BC(C )×MF
MPF=Fm( F p+Fd )
Appendix F -95
Production of 100,000 MTA Hydrogen
Heat Exchanger, X-18
Heat exchanger type 1 shell and 2 tubesDesign type Split-ring floating headHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side Light HydrocarbonShell side Light HydrocarbonHeat duty (kW) 333.960
a) Equipment sizingShell tube
Stream Light HC Light HC358.15 330.62
353.15 331.19
R = ( eqn. 12.6 )R= 8.772
S= ( eqn. 12.7 )S= 0.021
Ft can be obtained from fig 12.19 ( vol. 6 ),
0.9900
( eqn. 12.4 )
24.6788
Tin (K)
Tout (K)
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =DTlm can be calculated from the equation,
DTlm =
ΔT lm=(T 1−t 2 )−(T2−t1 )
ln(T1−t2 )(T2−t1 )
T1 = inlet temperature to shellT2 = outlet temperature from shellt1 = inlet temperature to tubet2 = outlet temperature from tube
T2
T1
t2
t1
Appendix F -96
Production of 100,000 MTA Hydrogen
Therefore, the actual temperature difference is
24.4320Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 300
Provisional area of heat exchanger, A can be obtained trough the formulae,
Provisional area, A 45.5632490.4386
b) Tube rating ( App.5.-2, Tranport Processes )Material Carbon steelBWG number 12
2.4419.0513.51
Material Thermal Conductivity ( W/m.K ) 16.3
0.1460
1.5718
Number of tube, Nt
312
Tube pitch is the distance between tube centres and formulated as
23.8125
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition )
0.249( 2 passes ) n 2.207
FtDTlm =
W/(C.m2)
m2
ft2
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)
Heat transfer area of a tube, At
Area of one tube, At (m2)
(ft2)
Number of tube, Nt
Tube pitch, Pt (mm)
Triangular pitch K1
Q=UA ΔTalignl¿ lm ¿¿¿
A t=Lt πDalignl ¿ to ¿ ¿¿
A=Q
UΔT lm
N t=AA t
Pt=1 . 25×D to
Appendix F -97
Production of 100,000 MTA Hydrogen
( eqn. 12.3b )
482.6161
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 58
For Split-ring floating head, Ds = Db + shell bundle clearance
0.5406
c) Tube side coefficient
Mean temperature (C)
Mean temperature (C) 330.9050
143.3695
78
0.0112
Mass flow rate (inside tube), m 165.3786 kg/s
14787.7565
The bundle diameter, Db
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(Tc.in +Tc,out)/2
Tube cross-sectional area, At
Tube cross-sectional area, At
Tube cross-sectional area, At mm2
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Fluid velocity, nf
mass velocity, nf kg/m2.s
Db=D to( N t / K1 )1 /n
A t=πDti2
¿4 ¿¿
¿
AT=N t A t
v f=m / AT
Appendix F -98
Production of 100,000 MTA Hydrogen
Physical properties of the tube side fluidPhysical properties
838.8251
5.16E-043.54274740819102 kJ/kg.K
0.58032666372 W/m.K
Linear velocity, u
Reynold number, Re
Prandtl number, Pr
linear velocity, u (m/s) 17.6291Reynold number, Re 387037.550Prandtl number, Pr 3.1512
180.6070
From figure 12.23, Chemical Engineering, Vol. 6
0.0030
( eqn. 12.15 )
72842.92( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
d) Tube side pressure drop
From figure 12.24 'Chemical Engineering'. Vol. 6
0.0020
( eqn. 12.20 )
density, rt kg/m3
Viscosity, mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi W/m2.C
friction factor, jf
Tube side pressure drop, DPt
u=v f / ρ
Re=ρuDti
μ
Pr=Cp μ
k f
hi=k f jh RePr0 .33
Dti ( μμw )
0 .14
ΔPs=N p [ 8 jf ( L/ Dti )(μ
μw)−m+2.5 ]
ρus2
2
Appendix F -99
Production of 100,000 MTA Hydrogen
where m = 0.25 for laminar flow, Re<2100 m = 0.14 for turbulent flow, Re>2100
1405.0723 kPa (acceptable)
e) Shell side coefficient0.5406 m Baffle
diameter
0.4866 mBaffle Diameter 0.5390 m
23.8125 mm
( eqn. 12.21 )
0.0526
95470.78911 kg/hr
504.1011
( eqn. 12.23 )
13.5265 mm
Mean temperature (C)
Mean temperature (C) 355.6500
Np = number of tube side passes
Tube side pressure drop,
DPt
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As m2
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs kg/s.m2
Shell side equivalent diameter, De
Shell side equivalent diameter, De
Tmean = (Tshell.in +Tshell.out)/2
ΔPs=N p [ 8 jf ( L/ Dti )(μ
μw)−m+2.5 ]
ρus2
2
Baffle Diameter=D s−0 . 0016
Baffle Spacing , lB=0 . 9∗Ds
A s=( p t−Dto )D s lB
pt
sss AwG /
De=1 .1Dto
( pz2−0. 971 Dto
2 )
Appendix F -100
Production of 100,000 MTA Hydrogen
Physical properties of shell fluid (light hydrocarbon)
Physical properties
8.3574
1.2178E-052.95453136063117 kJ/kg.K
0.1169 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 13209.823Prandtl number, Pr 0.3079
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0057
( eqn. 12.25 )
440.9838
f) Shell side pressure drop
60.3179 m/s
From figure 12.30 'Chemical Engineering'. Vol. 6
0.0660
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs W/m2.C
Linear velocity, us
Linear velocity, us
friction factor, jf
Re=Gs De /μ
hs=k f jh RePr1/3
De ( μμw )
0 .14
us=Gs / ρ
Appendix F -101
Production of 100,000 MTA Hydrogen
( eqn. 12.26 )
Shell side presure drop, 172611790.8049 Pa (acceptable)
172611.7908 kPa
g) Overall Coefficient
440.9838
72842.92
5000
5000
16.30.01351
0.01905
Overall heat transfer coefficient can be calculated by using the formula
( eqn. 12.1 )Therefore,
0.00296983413601567
336.719141272179
4
Costing
Type Shell and tube
45.5632Material Carbon SteelFeed Pressure 24 bar
Shell side presure drop, DPs
DPs
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (from Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
1/Uo =
Uo = W/m2.C
h) Number of baffle, Nb
Number of baffle, Nb
Nbaffle
Area (m2)
hs=k f jh RePr1/3
De ( μμw )
0 .14
1Uo
= 1hs
+ 1hod
+d to ln(d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Nb=( L/ lB)−1
C=C 0(S/S0)α
BMC= BC(C)×MF
MPF= Fm(Fp+Fd)
Appendix F -102
Production of 100,000 MTA Hydrogen
With reference to costing method proposed by L.T. Biegler,Base Cost, C
For 100<S<10000 ft2,Co 5000
Bare Module Cost, BMC So 400a 0.65UF 3.219048
Materials and Pressure Correction Factor, MPF
Total area (ft2) 490.44Base cost, C ($) 5708.3554Modular factor, MF 3.29Design factor, Fd 1.0 (Floating head)Pressure factor, Fp 0Material factor, Fm 1 (CS/CS)MPF 1Bare module cost ($) $60,455Bare module cost (RM) 229,730
C=C0( S/ S0 )α
BMC=BC (C )×MF
MPF=Fm( F p+Fd )
Appendix F -103
Production of 100,000 MTA Hydrogen
Heat Exchanger, X-21
Heat exchanger type 1 shell and 2 tubesDesign type Split-ring floating headHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side Organic SolventsShell side Light HydrocarbonHeat duty (kW) 18412.370
a) Equipment sizingshell tube
Stream Light HC organic solvent623.15 299.36
483.15 330.62
R = ( eqn. 12.6 )R= 4.479
S= ( eqn. 12.7 )S= 0.097
Ft can be obtained from fig 12.19 ( vol. 6 ),
0.9900
( eqn. 12.4 )
233.9635
Tin (K)
Tout (K)
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =DTlm can be calculated from the equation,
DTlm =
ΔT lm=(T 1−t 2 )−(T2−t1 )
ln(T1−t2 )(T2−t1 )
T1 = inlet temperature to shellT2 = outlet temperature from shellt1 = inlet temperature to tubet2 = outlet temperature from tube
T2
T1
t2
t1
Appendix F -104
Production of 100,000 MTA Hydrogen
Therefore, the actual temperature difference is
231.6238
Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 350
Provisional area of heat exchanger, A can be obtained trough the formulae,
Provisional area, A 227.12162444.7164
b) Tube rating ( App.5.-2, Tranport Processes )Material Carbon steelBWG number 14
2.4419.0514.83
Material Thermal Conductivity ( W/m.K ) 16.3
0.1460
1.5718
Number of tube, Nt
1555
Tube pitch is the distance between tube centres and formulated as
23.8125
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition )
0.249( 2 passes ) n 2.207
FtDTlm =
W/(C.m2)
m2
ft2
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)
Heat transfer area of a tube, At
Area of one tube, At (m2)
(ft2)
Number of tube, Nt
Tube pitch, Pt (mm)
Triangular pitch K1
Q=UA ΔTalignl¿ lm ¿¿¿
A t=Lt πDalignl ¿ to ¿ ¿¿
A=Q
UΔT lm
N t=AA t
Pt=1 . 25×D to
Appendix F -105
Production of 100,000 MTA Hydrogen
( eqn. 12.3b )
999.3252
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 72
For Split-ring floating head, Ds = Db + shell bundle clearance
1.0713
c) Tube side coefficient
Mean temperature (K)
Mean temperature (K) 314.9900
172.7542
389
0.0672
Mass flow rate (inside tube), m 166.1370 kg/s
2473.2820
The bundle diameter, Db
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(TK.in +TK,out)/2
Tube cross-sectional area, At
Tube cross-sectional area, At
Tube cross-sectional area, At mm2
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Fluid velocity, nf
mass velocity, nf kg/m2.s
Db=D to( N t / K1 )1 /n
A t=πDti2
¿4 ¿¿
¿
AT=N t A t
v f=m / AT
Appendix F -106
Production of 100,000 MTA Hydrogen
Physical properties of the tube side fluid Physical properties
838.4112
5.15E-043.5453121354088 kJ/kg.K
0.57972579598 W/m.K
Linear velocity, u
Reynold number, Re
Prandtl number, Pr
linear velocity, u (m/s) 2.9500Reynold number, Re 71252.324Prandtl number, Pr 3.1481
164.5314
From figure 12.23, Chemical Engineering, Vol. 6
0.0033
( eqn. 12.15 )
13419.93( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
d) Tube side pressure drop
From figure 12.24 'Chemical Engineering'. Vol. 6
0.0029
density, rt kg/m3
Viscosity, mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi W/m2.C
friction factor, jf
u=v f / ρ
Re=ρuDti
μ
Pr=Cp μ
k f
hi=k f jh RePr0 . 33
Dti ( μμw )
0 .14
Appendix F -107
Production of 100,000 MTA Hydrogen
( eqn. 12.20 )where m = 0.25 for laminar flow, Re<2100 m = 0.14 for turbulent flow, Re>2100
46.0903 kPa (acceptable)
e) Shell side coefficient1.0713 m Baffle
diameter
0.9642 mBaffle Diameter 1.0697 m
23.8125 mm
( eqn. 12.21 )
0.2066
204584.0255 kg/hr
275.0769
( eqn. 12.23 )
13.5265 mm
Tube side pressure drop, DPt
Np = number of tube side passes
Tube side pressure drop,
DPt
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As m2
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs kg/s.m2
Shell side equivalent diameter, De
Shell side equivalent diameter, De
ΔPs=N p [ 8 jf ( L/ Dti )(μ
μw)−m+2. 5 ]
ρus2
2
Baffle Diameter=D s−0 . 0016
Baffle Spacing , lB=0 . 9∗Ds
A s=( p t−Dto )D s lB
pt
sss AwG /
De=1 .1Dto
( pz2−0.971 Dto
2 )
Appendix F -108
Production of 100,000 MTA Hydrogen
Mean temperature (C)
Mean temperature (C) 553.1500
Physical properties of shell fluid (light hydrocarbon)
Physical properties
6.0172
2.3856E-052.41040091250368 kJ/kg.K
0.1416 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 7228.068Prandtl number, Pr 0.4062
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0070
( eqn. 12.25 )
393.3391
f) Shell side pressure drop
45.7151 m/s
From figure 12.30 'Chemical Engineering'. Vol. 6
0.0720
Tmean = (Tshell.in +Tshell.out)/2
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs W/m2.C
Linear velocity, us
Linear velocity, us
friction factor, jf
Re=Gs De /μ
hs=k f jhRePr1/3
De ( μμw )
0 .14
us=Gs / ρ
Appendix F -109
Production of 100,000 MTA Hydrogen
( eqn. 12.26 )
Shell side presure drop, 48784382.0918 Pa (acceptable)
48784.3821 kPa
g) Overall Coefficient
393.3391
13419.93
5000
5000
16.30.01483
0.01905
Overall heat transfer coefficient can be calculated by using the formula
( eqn. 12.1 )Therefore,
0.00324129909514685
308.518273274221
2
Shell side presure drop, DPs
DPs
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (from Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
1/Uo =
Uo = W/m2.C
h) Number of baffle, Nb
Number of baffle, Nb
Nbaffle
hs=k f jh RePr1/3
De ( μμw )
0 .14
1Uo
= 1hs
+ 1hod
+d to ln(d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Nb=( L/ lB)−1
C=C 0(S/S0)α
Appendix F -110
Production of 100,000 MTA Hydrogen
Costing
Type Shell and tube
227.1216Material Carbon SteelFeed Pressure 23 bar
With reference to costing method proposed by L.T. Biegler,Base Cost, C
For 100<S<10000 ft2,Co 5000
Bare Module Cost, BMC So 400a 0.65UF 3.219048
Materials and Pressure Correction Factor, MPF
Total area (ft2) 2444.72Base cost, C ($) 16217.3365Modular factor, MF 3.29Design factor, Fd 1.0 (Floating head)Pressure factor, Fp 0Material factor, Fm 1 (CS/CS)MPF 1Bare module cost ($) $171,752Bare module cost (RM) 652,659
Area (m2)
BMC= BC(C)×MF
MPF= Fm(Fp+Fd)
C=C0( S/ S0 )α
BMC=BC (C )×MF
MPF=Fm( F p+Fd )
Appendix F -111
Production of 100,000 MTA Hydrogen
Heat Exchanger, X-25
Heat exchanger type 1 shell and 2 tubesDesign type Split-ring floating headHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side MethanolShell side Natural GasesHeat duty (kW) 1088.150
a) Equipment sizingshell tube
Stream Natural Gases Methanol429.30 295.97
387.57 298.04
R = ( eqn. 12.6 )R= 20.159
S= ( eqn. 12.7 )S= 0.016
Ft can be obtained from fig 12.19 ( vol. 6 ),
1.0000
( eqn. 12.4 )
110.2436
Tin (K)
Tout (K)
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =DTlm can be calculated from the equation,
DTlm =
ΔT lm=(T 1−t2 )−(T2−t1 )
ln(T1−t2 )(T2−t1 )
T1 = inlet temperature to shellT2 = outlet temperature from shellt1 = inlet temperature to tubet2 = outlet temperature from tube
T2
T1
t2
t1
Appendix F -112
Production of 100,000 MTA Hydrogen
Therefore, the actual temperature difference is
110.2436
Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 300
Provisional area of heat exchanger, A can be obtained trough the formulae,
Provisional area, A 32.9014354.1476
b) Tube rating ( App.5.-2, Tranport Processes )Material Carbon steelBWG number 14
2.4419.0514.83
Material Thermal Conductivity ( W/m.K ) 16.3
0.1460
1.5718
Number of tube, Nt
225
Tube pitch is the distance between tube centres and formulated as
23.8125
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition )
0.249( 2 passes ) n 2.207
FtDTlm =
W/(C.m2)
m2
ft2
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)
Heat transfer area of a tube, At
Area of one tube, At (m2)
(ft2)
Number of tube, Nt
Tube pitch, Pt (mm)
Triangular pitch K1
Q=UA ΔTalignl¿ lm ¿¿¿
A t=Lt πDalignl ¿ to ¿ ¿¿
A=Q
UΔT lm
N t=AA t
Pt=1 . 25×D to
Appendix F -113
Production of 100,000 MTA Hydrogen
( eqn. 12.3b )
416.4211
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 55
For Split-ring floating head, Ds = Db + shell bundle clearance
0.4714
c) Tube side coefficient
Mean temperature (K)
Mean temperature (K) 297.0050
172.7542
56
0.0097
Mass flow rate (inside tube), m 143.4985 kg/s
14746.8378
The bundle diameter, Db
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(Tc.in +Tc,out)/2
Tube cross-sectional area, At
Tube cross-sectional area, At
Tube cross-sectional area, At mm2
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Fluid velocity, nf
mass velocity, nf kg/m2.s
Db=D to( N t / K1 )1 /n
A t=πDti2
¿4 ¿¿
¿
AT=N t A t
v f=m / AT
Appendix F -114
Production of 100,000 MTA Hydrogen
Physical properties of the tube side fluidPhysical properties
814.0675
5.30E-043.66328876558271 kJ/kg.K
0.60959368776 W/m.K
Linear velocity, u
Reynold number, Re
Prandtl number, Pr
linear velocity, u (m/s) 18.1150Reynold number, Re 412575.610Prandtl number, Pr 3.1854
164.5314
From figure 12.23, Chemical Engineering, Vol. 6
0.0028
( eqn. 12.15 )
69599.49( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
d) Tube side pressure drop
From figure 12.24 'Chemical Engineering'. Vol. 6
0.0019
density, rt kg/m3
Viscosity of E.G, mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi W/m2.C
friction factor, jf
u=v f / ρ
Re=ρuDti
μ
Pr=Cp μ
k f
hi=k f jh RePr0 . 33
Dti ( μμw )
0 .14
Appendix F -115
Production of 100,000 MTA Hydrogen
( eqn. 12.20 )where m = 0.25 for laminar flow, Re<2100 m = 0.14 for turbulent flow, Re>2100
1335.9295 kPa (acceptable)
e) Shell side coefficient0.4714 m Baffle
diameter
0.4243 mBaffle Diameter 0.4698 m
23.8125 mm
( eqn. 12.21 )
0.0400
40225.6368 kg/hr
279.3250
( eqn. 12.23 )
13.5265 mm
Tube side pressure drop, DPt
Np = number of tube side passes
Tube side pressure drop,
DPt
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As m2
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs kg/s.m2
Shell side equivalent diameter, De
Shell side equivalent diameter, De
ΔPs=N p [ 8 jf ( L/ Dti )(μ
μw)−m+2.5 ]
ρus2
2
Baffle Diameter=D s−0 . 0016
Baffle Spacing , lB=0 . 9∗Ds
As=( p t−Dto )D s lB
pt
sss AwG /
De=1 .1Dto
( pz2−0. 971 Dto
2 )
Appendix F -116
Production of 100,000 MTA Hydrogen
Mean temperature (C)
Mean temperature (C) 408.4350
Physical properties of shell fluid (light hydrocarbon)
Physical properties
1.9887
1.8326E-052.99569121652991 kJ/kg.K
0.0745 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 7127.829Prandtl number, Pr 0.7367
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0075
( eqn. 12.25 )
266.2769
f) Shell side pressure drop
140.4561 m/s
From figure 12.30 'Chemical Engineering'. Vol. 6
0.0730
Tmean = (Tshell.in +Tshell.out)/2
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs W/m2.C
Linear velocity, us
Linear velocity, us
friction factor, jf
Re=Gs De /μ
hs=k f jh RePr1/3
De ( μμw )
0 .14
us=Gs / ρ
Appendix F -117
Production of 100,000 MTA Hydrogen
( eqn. 12.26 )
Shell side presure drop, 267886243.7284 Pa (acceptable)
267886.2437 kPa
g) Overall Coefficient
266.2769
69599.49
5000
5000
16.30.01483
0.01905
Overall heat transfer coefficient can be calculated by using the formula
( eqn. 12.1 )Therefore,
0.0043771889231655
228.457125692628
5
Shell side presure drop, DPs
DPs
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (from Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
1/Uo =
Uo = W/m2.C
h) Number of baffle, Nb
Number of baffle, Nb
Nbaffle
hs=k f jh RePr1/3
De ( μμw )
0 .14
1Uo
= 1hs
+ 1hod
+d to ln (d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Nb=( L/ lB)−1
C=C 0(S/S0)α
Appendix F -118
Production of 100,000 MTA Hydrogen
Costing
Type Shell and tube
32.9014Material Carbon SteelFeed Pressure 24 bar
With reference to costing method proposed by L.T. Biegler,Base Cost, C
For 100<S<10000 ft2,Co 5000
Bare Module Cost, BMC So 400a 0.65UF 3.219048
Materials and Pressure Correction Factor, MPF
Total area (ft2) 354.15Base cost, C ($) 4619.5617Modular factor, MF 3.29Design factor, Fd 1.0 (Floating head)Pressure factor, Fp 0Material factor, Fm 1 (CS/CS)MPF 1Bare module cost ($) $48,924Bare module cost (RM) 185,912
Area (m2)
BMC=BC (C)×MF
MPF= Fm(Fp+Fd)
C=C0( S/ S0 )α
BMC=BC (C )×MF
MPF=Fm( F p+Fd )
Appendix F -119
Production of 100,000 MTA Hydrogen
Heat Exchanger, X-26
Heat exchanger type 1 shell and 2 tubesDesign type Split-ring floating headHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side MethanolShell side WaterHeat duty (kW) 1107.710
a) Equipment sizingshell tube
Stream Water Methanol358.15 298.04
349.12 300.15
R = ( eqn. 12.6 )R= 4.280
S= ( eqn. 12.7 )S= 0.035
Ft can be obtained from fig 12.19 ( vol. 6 ),
1.0000
( eqn. 12.4 )
54.4668
Tin (K)
Tout (K)
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =DTlm can be calculated from the equation,
DTlm =
ΔT lm=(T 1−t2 )−(T2−t1 )
ln(T1−t2 )(T2−t1 )
T1 = inlet temperature to shellT2 = outlet temperature from shellt1 = inlet temperature to tubet2 = outlet temperature from tube
T2
T1
t2
t1
Appendix F -120
Production of 100,000 MTA Hydrogen
Therefore, the actual temperature difference is
54.4668
Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 500
Provisional area of heat exchanger, A can be obtained trough the formulae,
Provisional area, A 40.6747437.8190
b) Tube rating ( App.5.-2, Tranport Processes )Material Carbon steelBWG number 14
2.4419.0514.83
Material Thermal Conductivity ( W/m.K ) 16.3
0.1460
1.5718
Number of tube, Nt
279
Tube pitch is the distance between tube centres and formulated as
23.8125
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition )
0.249( 2 passes ) n 2.207
FtDTlm =
W/(C.m2)
m2
ft2
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)
Heat transfer area of a tube, At
Area of one tube, At (m2)
(ft2)
Number of tube, Nt
Tube pitch, Pt (mm)
Triangular pitch K1
Q=UA ΔTalignl ¿ lm ¿¿¿
A t=Lt πDalignl ¿ to ¿ ¿¿
A=Q
UΔT lm
N t=AA t
Pt=1 . 25×D to
Appendix F -121
Production of 100,000 MTA Hydrogen
( eqn. 12.3b )
458.4250
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 72
For Split-ring floating head, Ds = Db + shell bundle clearance
0.5304
c) Tube side coefficient
Mean temperature (K)
Mean temperature (K) 299.0950
172.7542
70
0.0120
Mass flow rate (inside tube), m 143.3087 kg/s
The bundle diameter, Db
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(Tc.in +Tc,out)/2
Tube cross-sectional area, At
Tube cross-sectional area, At
Tube cross-sectional area, At mm2
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Db=D to( N t / K1 )1 /n
A t=πDti2
¿4 ¿¿
¿
AT=N t A t
Appendix F -122
Production of 100,000 MTA Hydrogen
11912.7959
Physical properties of the tube side fluid Physical properties
814.0675
5.30E-043.66328876558271 kJ/kg.K
0.60959368776 W/m.K
Linear velocity, u
Reynold number, Re
Prandtl number, Pr
linear velocity, u (m/s) 14.6337Reynold number, Re 333286.982Prandtl number, Pr 3.1854
164.5314
From figure 12.23, Chemical Engineering, Vol. 6
0.0029
( eqn. 12.15 )
58231.88( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
d) Tube side pressure drop
From figure 12.24 'Chemical Engineering'. Vol. 6
0.0020
Fluid velocity, nf
E.G mass velocity, nf kg/m2.s
density, rt kg/m3
Viscosity, mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi W/m2.C
friction factor, jf
v f=m / AT
u=v f / ρ
Re=ρuDti
μ
Pr=Cp μ
k f
hi=k f jh RePr0 . 33
Dti ( μμw )
0 .14
Appendix F -123
Production of 100,000 MTA Hydrogen
( eqn. 12.20 )where m = 0.25 for laminar flow, Re<2100 m = 0.14 for turbulent flow, Re>2100
894.7384 kPa (acceptable)
e) Shell side coefficient0.5304 m Baffle
diameter
0.4774 mBaffle Diameter 0.5288 m
23.8125 mm
( eqn. 12.21 )
0.0506
109113.8792 kg/hr
598.4902
( eqn. 12.23 )
13.5265 mm
Tube side pressure drop, DPt
Np = number of tube side passes
Tube side pressure drop,
DPt
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As m2
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs kg/s.m2
Shell side equivalent diameter, De
Shell side equivalent diameter, De
ΔPs=N p [ 8 jf ( L/ Dti )(μ
μw)−m+2.5 ]
ρus2
2
Baffle Diameter=D s−0 . 0016
Baffle Spacing , lB=0 .9∗Ds
A s=( p t−Dto )D s lB
pt
sss AwG /
De=1 .1Dto
( pz2−0.971 Dto
2 )
Appendix F -124
Production of 100,000 MTA Hydrogen
Mean temperature (C)
Mean temperature (C) 353.6350
Physical properties of shell fluid
Physical properties
965.3964
5.8331E-044.18173789157996 kJ/kg.K
1.1730 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 15272.299Prandtl number, Pr 2.0794
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0055
( eqn. 12.25 )
9275
f) Shell side pressure drop
0.6199 m/s
From figure 12.30 'Chemical Engineering'. Vol. 6
0.0650
Tmean = (Tshell.in +Tshell.out)/2
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs W/m2.C
Linear velocity, us
Linear velocity, us
friction factor, jf
Re=Gs De /μ
hs=k f jh RePr1/3
De ( μμw )
0 .14
us=Gs / ρ
Appendix F -125
Production of 100,000 MTA Hydrogen
( eqn. 12.26 )
Shell side presure drop, 2624542.4541 Pa (acceptable)
2624.5425 kPa
g) Overall Coefficient
9275
58231.88
5000
5000
16.30.01483
0.01905
Overall heat transfer coefficient can be calculated by using the formula
( eqn. 12.1 )Therefore,
0.000733119206563126
1364.03464954631
4
Costing
Type Shell and tube
40.6747Material Carbon SteelFeed Pressure 1.01325 bar
Shell side presure drop, DPs
DPs
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (from Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
1/Uo =
Uo = W/m2.C
h) Number of baffle, Nb
Number of baffle, Nb
Nbaffle
Area (m2)
hs=k f jh RePr1/3
De ( μμw )
0 .14
1Uo
= 1hs
+ 1hod
+d to ln (d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Nb=( L/ lB)−1
Appendix F -126
Production of 100,000 MTA Hydrogen
With reference to costing method proposed by L.T. Biegler,Base Cost, C
For 100<S<10000 ft2,Co 5000
Bare Module Cost, BMC So 400a 0.65UF 3.219048
Materials and Pressure Correction Factor, MPF
Total area (ft2) 437.82Base cost, C ($) 5302.4006Modular factor, MF 3.29Design factor, Fd 1.0 (Floating head)Pressure factor, Fp 0Material factor, Fm 1 (CS/CS)MPF 1Bare module cost ($) $56,156Bare module cost (RM) 213,393
C=C0( S/ S0 )α
BMC=BC (C )×MF
MPF=Fm( F p+Fd )
Appendix F -127
Production of 100,000 MTA Hydrogen
Heat Exchanger, X-28
Heat exchanger type 1 shell and 2 tubesDesign type Split-ring floating headHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side Organic SolventsShell side WaterHeat duty (kW) 5635.519
a) Equipment sizingshell tube
Stream Water organic solvent349.12 289.79
303.15 299.36
R = ( eqn. 12.6 )R= 4.804
S= ( eqn. 12.7 )S= 0.161
Ft can be obtained from fig 12.19 ( vol. 6 ),
0.9600
( eqn. 12.4 )
27.6817
Therefore, the actual temperature difference is
26.5745
Tin (K)
Tout (K)
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =DTlm can be calculated from the equation,
DTlm =
FtDTlm =
ΔT lm=(T 1−t 2 )−(T2−t 1 )
ln(T1−t2 )(T2−t1 )
T1 = inlet temperature to shellT2 = outlet temperature from shellt1 = inlet temperature to tubet2 = outlet temperature from tube
T2T1
t2
t1
Appendix F -128
Production of 100,000 MTA Hydrogen
Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 600
Provisional area of heat exchanger, A can be obtained trough the formulae,
Provisional area, A 353.44193804.4172
b) Tube rating ( App.5.-2, Tranport Processes )Material Carbon steelBWG number 16
2.4419.0515.75
Material Thermal Conductivity ( W/m.K ) 16.3
0.1460
1.5718
Number of tube, Nt
2420
Tube pitch is the distance between tube centres and formulated as
23.8125
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition )
0.249( 2 passes ) n 2.207
W/(C.m2)
m2
ft2
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)
Heat transfer area of a tube, At
Area of one tube, At (m2)
(ft2)
Number of tube, Nt
Tube pitch, Pt (mm)
Triangular pitch K1
Q=UA ΔTalignl¿ lm ¿¿¿
A t=Lt πDalignl ¿ to ¿ ¿¿
A=Q
UΔT lm
N t=AA t
Pt=1 .25×D to
Appendix F -129
Production of 100,000 MTA Hydrogen
( eqn. 12.3b )
1221.0397
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 78
For Split-ring floating head, Ds = Db + shell bundle clearance
1.2990
c) Tube side coefficient
Mean temperature (K)
Mean temperature (K) 294.5750
194.8531
605
0.1179
Mass flow rate (inside tube), m 166.2194 kg/hr
1409.7780
The bundle diameter, Db
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(Tc.in +Tc,out)/2
Tube cross-sectional area, At
Tube cross-sectional area, At
Tube cross-sectional area, At mm2
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Fluid velocity, nf
mass velocity, nf kg/m2.s
Db=D to( N t / K1 )1 /n
A t=πDti2
¿4 ¿¿
¿
AT=N t A t
v f=m / AT
Appendix F -130
Production of 100,000 MTA Hydrogen
Physical properties of the tube side fluid Physical properties
838.8215
5.16E-043.54274740819102 kJ/kg.K
0.58032666372 W/m.K
Linear velocity, u
Reynold number, Re
Prandtl number, Pr
linear velocity, u (m/s) 1.6807Reynold number, Re 43015.675Prandtl number, Pr 3.1512
154.9206
From figure 12.23, Chemical Engineering, Vol. 6
0.0036
( eqn. 12.15 )
8333.3( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
d) Tube side pressure drop
From figure 12.24 'Chemical Engineering'. Vol. 6
0.0033
( eqn. 12.20 )
where m = 0.25 for laminar flow, Re<2100 m = 0.14 for turbulent flow, Re>2100
density, rt kg/m3
Viscosity, mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi W/m2.C
friction factor, jf
Tube side pressure drop, DPt
Np = number of tube side passes
u=v f / ρ
Re=ρuDti
μ
Pr=Cp μ
k f
hi=k f jh RePr0 . 33
Dti ( μμw )
0 .14
ΔPs=N p [ 8 jf ( L/ Dti )(μ
μw)−m+2. 5 ]
ρus2
2
Appendix F -131
Production of 100,000 MTA Hydrogen
15.6139 kPa (acceptable)
e) Shell side coefficient1.2990 m Baffle
diameter
1.1691 mBaffle Diameter 1.2974 m
23.8125 mm
( eqn. 12.21 )
0.3038
109113.8792 kg/hr
99.7838
( eqn. 12.23 )
13.5265 mm
Mean temperature (C)
Mean temperature (C) 326.1350
Physical properties of shell fluid
Tube side pressure drop,
DPt
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As m2
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs kg/s.m2
Shell side equivalent diameter, De
Shell side equivalent diameter, De
Tmean = (Tshell.in +Tshell.out)/2
Baffle Diameter=D s−0 . 0016
Baffle Spacing , lB=0 . 9∗Ds
A s=( p t−Dto )D s lB
pt
sss AwG /
De=1 . 1Dto
( pz2−0.971 Dto
2 )
Appendix F -132
Production of 100,000 MTA Hydrogen
Physical properties
965.3964
5.8331E-044.18340762759332 kJ/kg.K
1.1730 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 2614.806Prandtl number, Pr 2.0803
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0130
( eqn. 12.25 )
3753.935
f) Shell side pressure drop
0.1034 m/s
From figure 12.30 'Chemical Engineering'. Vol. 6
0.0850
( eqn. 12.26 )
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs W/m2.C
Linear velocity, us
Linear velocity, us
friction factor, jf
Shell side presure drop, DPs
Re=Gs De /μ
hs=k f jh RePr1/3
De ( μμw )
0 .14
us=Gs / ρ
hs=k f jh RePr1/3
De ( μμw )
0 .14
Appendix F -133
Production of 100,000 MTA Hydrogen
Shell side presure drop, 42201.6211 Pa (acceptable)
42.2016 kPa
g) Overall Coefficient
3753.935
8333.3
5000
5500
16.30.01575
0.01905
Overall heat transfer coefficient can be calculated by using the formula
( eqn. 12.1 )Therefore,
0.000942604074700494
1060.89080966231
1
Costing
Type Shell and tube
353.4419Material Carbon SteelFeed Pressure 25.7 bar
With reference to costing method proposed by L.T. Biegler,Base Cost, C
DPs
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (from Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
1/Uo =
Uo = W/m2.C
h) Number of baffle, Nb
Number of baffle, Nb
Nbaffle
Area (m2)
1Uo
= 1hs
+ 1hod
+d to ln(d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Nb=( L/ lB)−1
C=C0( S/ S0 )α
Appendix F -134
Production of 100,000 MTA Hydrogen
Bare Module Cost, BMC For 100<S<10000 ft2,Co 5000So 400
Materials and Pressure Correction Factor, MPF a 0.65UF 3.219048
Total area (ft2) 3804.42Base cost, C ($) 21618.1387Modular factor, MF 3.29Design factor, Fd 1.0 (Floating head)Pressure factor, Fp 0Material factor, Fm 1 (CS/CS)MPF 1Bare module cost ($) $228,951Bare module cost (RM) 870,012
BMC=BC (C )×MF
MPF=Fm( F p+Fd )
Appendix F -135
Production of 100,000 MTA Hydrogen
Heat Exchanger, X-29
Heat exchanger type 1 shell and 2 tubesDesign type Split-ring floating headHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side light hydrocarbonShell side natural gasesHeat duty (kW) 2437.400
a) Equipment sizingshell tube
Stream Natural Gases Light Hydrocarbon387.57 284.15
294.15 333.15
R = ( eqn. 12.6 )R= 1.907
S= ( eqn. 12.7 )S= 0.474
Ft can be obtained from fig 12.19 ( vol. 6 ),
0.8000
( eqn. 12.4 )
26.2197
Tin (K)
Tout (K)
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =
DTlm can be calculated from the equation,
DTlm =
ΔT lm=(T 1−t 2 )−(T2−t1 )
ln(T1−t2 )(T2−t1 )
T1 = inlet temperature to shellT2 = outlet temperature from shellt1 = inlet temperature to tubet2 = outlet temperature from tube
T2
T1
t2
t1
Appendix F -136
Production of 100,000 MTA Hydrogen
Therefore, the actual temperature difference is
20.9758
Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 300
Provisional area of heat exchanger, A can be obtained trough the formulae,
Provisional area, A 387.33614169.2514
b) Tube rating ( App.5.-2, Tranport Processes )Material Carbon steelBWG number 16
2.4419.0515.75
Material Thermal Conductivity ( W/m.K ) 16.3
0.1460
1.5587
Number of tube, Nt
2652
Tube pitch is the distance between tube centres and formulated as
23.8125
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition )
0.249( 2 passes ) n 2.207
FtDTlm =
W/(C.m2)
m2
ft2
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)
Heat transfer area of a tube, At
Area of one tube, At (m2)
(ft2)
Number of tube, Nt
Tube pitch, Pt (mm)
Triangular pitch K1
Q=UA ΔTalignl¿ lm ¿¿¿
A t=Lt πDalignl ¿ to ¿ ¿¿
A=Q
UΔT lm
N t=AA t
Pt=1 . 25×D to
Appendix F -137
Production of 100,000 MTA Hydrogen
( eqn. 12.3b )
1272.7693
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 77
For Split-ring floating head, Ds = Db + shell bundle clearance
1.3498
c) Tube side coefficient
Mean temperature (K)
Mean temperature (K) 308.6500
194.8531
663
0.1292
Mass flow rate (inside tube), m 4.5877 kg/s
35.5055
The bundle diameter, Db
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(Tc.in +Tc,out)/2
Tube cross-sectional area, At
Tube cross-sectional area, At
Tube cross-sectional area, At mm2
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Fluid velocity, nf
mass velocity, nf kg/m2.s
Db=D to( N t / K1 )1 /n
A t=πDti2
¿4 ¿¿
¿
AT=N t A t
v f=m / AT
Appendix F -138
Production of 100,000 MTA Hydrogen
Physical properties of the tube side fluid Physical properties
2.6873
8.10E-0610.8426291635825 kJ/kg.K
0.14327499494 W/m.K
Linear velocity, u
Reynold number, Re
Prandtl number, Pr
linear velocity, u (m/s) 13.2123Reynold number, Re 69081.032Prandtl number, Pr 0.6126
154.9206
From figure 12.23, Chemical Engineering, Vol. 6
0.0038
( eqn. 12.15 )
2031.431( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
d) Tube side pressure drop
From figure 12.24 'Chemical Engineering'. Vol. 6
0.0035
density, rt kg/m3
Viscosity, mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi W/m2.C
friction factor, jf
u=v f / ρ
Re=ρuDti
μ
Pr=Cp μ
k f
hi=k f jh RePr0 . 33
Dti ( μμw )
0 .14
Appendix F -139
Production of 100,000 MTA Hydrogen
( eqn. 12.20 )where m = 0.25 for laminar flow, Re<2100 m = 0.14 for turbulent flow, Re>2100
3.2077 kPa (acceptable)
e) Shell side coefficient1.3498 m Baffle
diameter
1.2148 mBaffle Diameter 1.3482 m
23.8125 mm
( eqn. 12.21 )
0.3279
40225.6368 kg/hr
34.0729
( eqn. 12.23 )
13.5265 mm
Tube side pressure drop, DPt
Np = number of tube side passes
Tube side pressure drop,
DPt
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As m2
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs kg/s.m2
Shell side equivalent diameter, De
Shell side equivalent diameter, De
ΔPs=N p [ 8 jf ( L/ Dti )(μ
μw)−m+2.5 ]
ρus2
2
Baffle Diameter=D s−0 .0016
Baffle Spacing , lB=0 . 9∗Ds
A s=( p t−Dto )D s lB
pt
sss AwG /
De=1 .1Dto
( pz2−0. 971 Dto
2 )
Appendix F -140
Production of 100,000 MTA Hydrogen
Mean temperature (C)
Mean temperature (C) 340.8600
Physical properties of shell fluid (stream)
Physical properties
1.9887
1.8326E-052.99569121652991 kJ/kg.K
0.0745 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 56934.549Prandtl number, Pr 0.7367
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0025
( eqn. 12.25 )
708.9748
f) Shell side pressure drop
17.1332 m/s
From figure 12.30 'Chemical Engineering'. Vol. 6
0.0500
Tmean = (Tshell.in +Tshell.out)/2
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs W/m2.C
Linear velocity, us
Linear velocity, us
friction factor, jf
Re=Gs De /μ
hs=kf jh RePr1/3
De ( μμw )
0 .14
us=Gs / ρ
Appendix F -141
Production of 100,000 MTA Hydrogen
( eqn. 12.26 )
Shell side presure drop, 1334974.4710 Pa (acceptable)
1334.9745 kPa
g) Overall Coefficient
708.9748
2031.431
5000
5000
16.30.01575
0.01905
Overall heat transfer coefficient can be calculated by using the formula
( eqn. 12.1 )Therefore,
0.00255895713832139
390.784192913826
1
Shell side presure drop, DPs
DPs
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (from Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
1/Uo =
Uo = W/m2.C
h) Number of baffle, Nb
Number of baffle, Nb
Nbaffle
hs=k f jh RePr1/3
De ( μμw )
0 .14
1Uo
= 1hs
+ 1hod
+d to ln(d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Nb=( L/ lB)−1
Appendix F -142
Production of 100,000 MTA Hydrogen
Costing
Type Shell and tube
387.3361Material Carbon SteelFeed Pressure 5.07bar
With reference to costing method proposed by L.T. Biegler,Base Cost, C
For 100<S<10000 ft2,Co 5000
Bare Module Cost, BMC So 400a 0.65UF 3.219048
Materials and Pressure Correction Factor, MPF
Total area (ft2) 4169.25Base cost, C ($) 22943.9805Modular factor, MF 3.29Design factor, Fd 1.0 (Floating head)Pressure factor, Fp 0Material factor, Fm 1 (CS/CS)MPF 1Bare module cost ($) $242,992Bare module cost (RM) 923,370
Area (m2)
C=C0( S/ S0 )α
BMC=BC (C )×MF
MPF=Fm( F p+Fd )
Appendix F -143
Production of 100,000 MTA Hydrogen
Heat Exchanger, X-30
Heat exchanger type 1 shell and 2 tubesDesign type Split-ring floating headHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side Organic SolventShell side MethanolHeat duty (kW) 1044.601
a) Equipment sizingshell tube
Stream Methanol Organic Solvent294.15 263.15
292.26 284.15
R = ( eqn. 12.6 )R= 0.090
S= ( eqn. 12.7 )S= 0.677
Ft can be obtained from fig 12.19 ( vol. 6 ),
0.9800
( eqn. 12.4 )
17.8860
Therefore, the actual temperature difference is
17.5283
Tin (K)
Tout (K)
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =DTlm can be calculated from the equation,
DTlm =
FtDTlm =
ΔT lm=(T 1−t 2 )−(T2−t 1 )
ln(T1−t2 )(T2−t1 )
T1 = inlet temperature to shellT2 = outlet temperature from shellt1 = inlet temperature to tubet2 = outlet temperature from tube
T2
T1
t2
t1
Appendix F -144
Production of 100,000 MTA Hydrogen
Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 450
Provisional area of heat exchanger, A can be obtained trough the formulae,
Provisional area, A 132.43361425.5029
b) Tube rating ( App.5.-2, Tranport Processes )Material Carbon steelBWG number 16
2.4419.0515.75
Material Thermal Conductivity ( W/m.K ) 16.3
0.1460
1.5587Number of tube, Nt
907
Tube pitch is the distance between tube centres and formulated as
23.8125
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition )
0.249( 2 passes ) n 2.207
W/(C.m2)
m2
ft2
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)
Heat transfer area of a tube, At
Area of one tube, At (m2)
(ft2)
Number of tube, Nt
Tube pitch, Pt (mm)
Triangular pitch K1
The bundle diameter, Db
Q=UA ΔTalignl¿ lm ¿¿¿
A t=Lt πDalignl ¿ to ¿ ¿¿
A=Q
UΔT lm
N t=AA t
Pt=1 . 25×D to
Appendix F -145
Production of 100,000 MTA Hydrogen
( eqn. 12.3b )
782.6410
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 73
For Split-ring floating head, Ds = Db + shell bundle clearance
0.8556
c) Tube side coefficient
Mean temperature (K)
Mean temperature (K) 273.6500
194.8531
227
0.0442
Mass flow rate (inside tube), m 4.5877 kg/s
103.8450
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(Tc.in +Tc,out)/2
Tube cross-sectional area, At
Tube cross-sectional area, At
Tube cross-sectional area, At mm2
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Fluid velocity, nf
mass velocity, nf kg/m2.s
Db=D to( N t / K1 )1 /n
A t=πDti2
¿4 ¿¿
¿
AT=N t A t
v f=m / AT
Appendix F -146
Production of 100,000 MTA Hydrogen
Physical properties of the tube side fluid Physical properties
2.6873
8.10E-0610.8426291635825 kJ/kg.K
0.14327499494 W/m.K
Linear velocity, u
Reynold number, Re
Prandtl number, Pr
linear velocity, u (m/s) 38.6429Reynold number, Re 202045.508Prandtl number, Pr 0.6126
154.9206
From figure 12.23, Chemical Engineering, Vol. 6
0.0030
( eqn. 12.15 )
4690.617776129( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
d) Tube side pressure drop
From figure 12.24 'Chemical Engineering'. Vol. 6
0.0023
( eqn. 12.20 )where m = 0.25 for laminar flow, Re<2100
density, rt kg/m3
Viscosity, mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi (W/m2.C)
friction factor, jf
Tube side pressure drop, DPt
u=v f / ρ
Re=ρuDti
μ
Pr=Cp μ
k f
hi=k f jh RePr0 . 33
Dti ( μμw )
0 .14
ΔPs=N p [ 8 jf ( L/ Dti )(μμw
)−m+2. 5 ]ρus
2
2
Appendix F -147
Production of 100,000 MTA Hydrogen
m = 0.14 for turbulent flow, Re>2100
21.4710 kPa (acceptable)
e) Shell side coefficient0.8556 m
Baffle diameter
0.7701 mBaffle Diameter 0.8540 m
23.8125 mm
( eqn. 12.21 )
0.1318
720925.4752 kg/hr
1519.6103
( eqn. 12.23 )
13.5265 mm
Mean temperature (C)
Mean temperature (C) 293.2065
Np = number of tube side passes
Tube side pressure drop,
DPt
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As m2
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs kg/s.m2
Shell side equivalent diameter, De
Shell side equivalent diameter, De
Tmean = (Tshell.in +Tshell.out)/2
Baffle Diameter=D s−0 . 0016
Baffle Spacing , lB=0 . 9∗Ds
A s=( p t−Dto )D s lB
pt
sss AwG /
De=1 . 1Dto
( pz2−0.971 Dto
2 )
Appendix F -148
Production of 100,000 MTA Hydrogen
Physical properties of shell fluid (stream)
Physical properties
799.8603
5.1581E-043.69813443294356 kJ/kg.K
0.6155 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 2539213.908Prandtl number, Pr 3.0990
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0008
( eqn. 12.25 )
134265.25076058
f) Shell side pressure drop
1.8998 m/s
From figure 12.30 'Chemical Engineering'. Vol. 6
0.0320
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs (W/m2.C)
Linear velocity, us
Linear velocity, us
friction factor, jf
Re=Gs De /μ
hs=k f jh RePr1/3
De ( μμw )
0 .14
us=Gs / ρ
Appendix F -149
Production of 100,000 MTA Hydrogen
( eqn. 12.26 )
Shell side presure drop, 6319096.4457 Pa (acceptable)
6319.0964 kPa
g) Overall Coefficient
134265.25076058
4690.617776129
5000
5000
16.30.01575
0.01905
Overall heat transfer coefficient can be calculated by using the formula
( eqn. 12.1 )Therefore,
0.000818373044027
1221.93663060944
2
Costing
Type Shell and tube
132.4336Material Carbon SteelFeed Pressure 5.07bar
Shell side presure drop, DPs
DPs
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (from Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
1/Uo =
Uo = W/m2.C
h) Number of baffle, Nb
Number of baffle, Nb
Nbaffle
Area (m2)
hs=k f jh RePr1/3
De ( μμw )
0 .14
1Uo
= 1hs
+ 1hod
+d to ln (d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Nb=( L/ lB)−1
Appendix F -150
Production of 100,000 MTA Hydrogen
With reference to costing method proposed by L.T. Biegler,Base Cost, C
For 100<S<10000 ft2,Bare Module Cost, BMC Co 5000
So 400a 0.65
Materials and Pressure Correction Factor, MPF UF 3.21904761904762
Total area (ft2) 1425.50Base cost, C ($) 11421.1619Modular factor, MF 3.29Design factor, Fd 1.0 (Floating head)Pressure factor, Fp 0Material factor, Fm 1 (CS/CS)MPF 1Bare module cost ($) $120,958Bare module cost (RM) 459,639
C=C0( S/ S0)α
BMC=BC(C )×MF
MPF=Fm( F p+Fd )
Appendix F -151
Production of 100,000 MTA Hydrogen
Heater X-34
Heat exchanger type Split flow shell and 2 tubesDesign type Fixed and U-TubeHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side Organic solventShell side SteamHeat duty (kW) (Q) 12935.46000
a) Equipment sizingshell (t) tube (T)
Stream Steam523.15 331.19
423.15 353.15
R = ( eqn. 12.6 )R= 4.55373406193079
S= ( eqn. 12.7 )S= 0.1144
Ft can be obtained from eqn 12.8 ( vol. 6 ),
0.976
Organic solvent
Tin (K)
Tout (K)
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =
T1 = inlet temperature to tubeT2 = outlet temperature from tubet1 = inlet temperature to shellt2 = outlet temperature from shell
T2
T1
t2
t1
Appendix F -152
Production of 100,000 MTA Hydrogen
( eqn. 12.4 )
127.0090
Therefore, the actual temperature difference is
124.0151
Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 800
Provisional area of heat exchanger, A can be obtained trough the formula,
Provisional area, A = 130.3819
= 1403.4194
Material Stainless SteelBWG number 16
4.8819.0515.7544.0
0.2921
3.1437
DTlm can be calculated from the equation,
DTlm =
ΔTm = FtΔTlm =
W/(ºC.m2)
m2
ft2
b) Tube rating ( From App.5.-2, Tranport Processes by, Christie J. Geankoplis )
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)Material Thermal Conductivity ( W/m.K )
Heat transfer area of a tube, At
Area of one tube, At (m2) =
(ft2) =
ΔT lm=(T 1−t 2 )−(T2−t 1 )
ln(T1−t2 )(T2−t1 )
Q=UA ΔTalignl¿ lm ¿¿¿A=
QUΔT lm
A t=Lt πDalignl ¿ to ¿ ¿¿
Appendix F -153
Production of 100,000 MTA Hydrogen
Number of tube, Nt
446
Tube pitch is the distance between tube centres and formulated as
23.8125
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition ), page 523Triangular pitch K1 0.249( 2 passes ) n 2.207
( eqn. 12.3b )
567.6654
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 60
For Split-ring floating head, Ds = Db + shell bundle clearance
0.62767
c) Tube side coefficient
Mean temperature (C)
Mean temperature (C) 342.1700
Number of tube, Nt
Tube pitch, Pt (mm)
The bundle diameter, Db
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(TH.in +TH,out)/2
N t=AA t
Pt=1 . 25×D to
Pt
Db=D to( N t / K1 )1 /n
Appendix F -154
Production of 100,000 MTA Hydrogen
194.8531
223
0.0434941
Mass flow rate (inside tube), m 216.6034 kg/s
4980.0634
Physical properties of the tube side fluid (simulation result)Physical properties of organic solvent
838.4112
5.15E-043.5453121354088 kJ/kg.K
0.57972579598 W/m.K1 cp (Ns/m2) = 1.00E-03
Linear velocity, u
Reynold number, Re Prandtl number, Pr
Tube cross-sectional area, At
Tube cross-sectional area, At mm2
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Fluid velocity, nf
Fluid mass velocity, nf kg/m2.s
organic solvent density, rt kg/m3
Viscosity of , mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
A t=πDti2
¿4 ¿¿
¿
AT =N t A t
v f=m / AT
u=v f / ρ
Re=ρuDti
μPr=
Cp μk f
Appendix F -155
Production of 100,000 MTA Hydrogen
steam linear velocity, u (m/s) 5.9399Reynold number, Re 1.5237E+05Prandtl number, Pr 3.1481
309.8413
From figure 12.23, Chemical Engineering, Vol. 6
0.00320
( eqn. 12.15 )
26202.7833( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
d) Tube side pressure drop
From figure 12.24 'Chemical Engineering'. Vol. 6
0.00250
( eqn. 12.20 )where m = 0.25 for laminar flow, Re<2100 m = 0.14 for turbulent flow, Re>2100
257.2607 kPa
2.5389655289586
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi
friction factor, jf
Tube side pressure drop, DPt
Np = number of tube side passes
Tube side pressure drop,
DPt (atm)
hi=k f jh RePr0 .33
Dti ( μμw )
0 .14
ΔPs=N p [ 8 jf ( L/ Dti )(μμw
)−m+2. 5 ]ρus
2
2
Appendix F -156
Production of 100,000 MTA Hydrogen
e) Shell side coefficient0.6277 m
Baffle diameter
0.5649 mBaffle Diameter 0.6261 m
23.8125 mm
( eqn. 12.21 )
0.070913
65.102979 kg/s
918.0619
( eqn. 12.23 )13.5265 mm
Mean temperature (C)
Mean temperature (ºC) 473.1500
Physical properties of shell fluid (steam)
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As m2
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs kg/s.m2
Shell side equivalent diameter, De
Shell side equivalent diameter, De
Tmean = (Tshell.in +Tshell.out)/2
A s=( p t−Dto )D s lB
pt
sss AwG /
De=1 .1Dto
( pz2−0. 971 Dto
2 )
Baffle Spacing , lB=0 . 9∗Ds
Baffle Diameter=D s−0 .0016
Appendix F -157
Production of 100,000 MTA Hydrogen
Physical properties
0.4211
1.82E-051.98692E+00 kJ/kg.K
0.0381499 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 6.8153E+05Prandtl number, Pr 0.9490
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0009
( eqn. 12.25 )
1700.322135865
f) Shell side pressure drop
2179.9965 m/s
From figure 12.30 'Chemical Engineering'. Vol. 6
0.0340
( eqn. 12.26 )
Shell side presure drop, 109108878.2618 Pa
109108.8783 kPa 1076.820905618
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs (W/m2.C)
Linear velocity, us
Linear velocity, us
friction factor, jf
Shell side presure drop, DPs
DPs (atm)
m/Re es DG
hs=k f jh RePr1/3
De ( μμw )
0 .14
us=Gs / ρ
ΔPs=8 jf ( Ds /D e)( L/ lB )ρus
2
2( μ
μw)−0 . 14
Appendix F -158
Production of 100,000 MTA Hydrogen
g) Overall Coefficient
1700.322135865
26202.7833
5000
5000
44.00.01575
0.01905
Overall heat transfer coefficient can be calculated by using the formula
( eqn. 12.2 )Therefore,
0.001117368503781
894.959896055954
8
i) Costing (Guthrie's Modular Method)
Total area of the Heat Exchanger = 130.3819 = 1403.4180838
Operating Pressure = 4.75 bar405.6
126.00Update factor = 405.6
126.00
= 3.21904761904762
With reference to costing method proposed in Systematic Method of Chemical ProcessDesign by L.T. Biegler.
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
1/Uo =
Uo = W/m2.C
h) Number of baffle, Nb
Number of baffle, Nb
Nbaffle
m2
ft2
CE Plant Cost Index for 2003, CEI 03 =CE Plant Cost Index for 1968 1/2, CEI 68 =
1Uo
= 1hs
+ 1hod
+d to ln (d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Nb=( L/ lB)−1
Appendix F -159
Production of 100,000 MTA Hydrogen
Base Cost,
C0= 5000S0= 400
0.65Updated Bare Module Cost : BMC= (UF)(MPF+MF-1) (BC)
Materials and Pressure Correction Factor, MPF
Total area (ft2) 1,403.41808Base cost, C ($) 11,305.834Modular factor, MF 3.2900Design factor, Fd 0.8500Pressure factor, Fp 0.0000Material factor, Fm 2.5000MPF 2.1250
160,679.59Bare module cost (RM) 610,582.44
Utility cost:H (250C, 475 kPa,super) = 2961.85 kJ/kgH (150C, saturated) = 632.1 kJ/kgΔ H = 2329.75 kJ/kg
== 5.5523 kg/s= 5552.3 g/s= 308 gmol/s
The amout of water need to be heated to obtain the amount of steam;= 5.5523 kg/s= 19988 kg/hr= 19.9883= 172,698.5933
Assume the water will be flowed to the incinerator to generate steam before flowing to the heater, therefore, no extra heating cost is needed.
Assume water cost = RM 1.15Total cost of water RM/yr = 198,603.38
α=
Updated bare module cost ($)
Steam flow, mc Qmax/ΔH
m3/hrm3/yr
/m3
Appendix F -160
Production of 100,000 MTA Hydrogen
Cooler X-35
Heat exchanger type Split flow shell and 2 tubesDesign type Fixed and U-TubeHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side R-12Shell side waterHeat duty (kW) (Q) 68805.55600
a) Equipment sizingshell (t) tube (T)
Stream Methanol R-12299.82 479.75
324.82 368.15
R = ( eqn. 12.6 )R= 0.224014336917563
S= ( eqn. 12.7 )S= 0.6202
Ft can be obtained from fig 12.19 ( vol. 6 ),
0.950
( eqn. 12.4 )
105.7872
Tin (K)
Tout (K)
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =DTlm can be calculated from the equation,
DTlm =
T1 = inlet temperature to tubeT2 = outlet temperature from tubet1 = inlet temperature to shellt2 = outlet temperature from shell
T2
T1
t2
t1
ΔT lm=(T 1−t2 )−(T2−t 1)
ln(T1−t 2 )(T2−t 1 )
Appendix F -161
Production of 100,000 MTA Hydrogen
Therefore, the actual temperature difference is
100.4978
Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 454.264
Provisional area of heat exchanger, A can be obtained trough the formula,
Provisional area, A = 150.7157
= 1622.2900
b) Tube rating
Material Stainless SteelBWG number 16
4.8819.0515.7544.0
0.2921
3.1437
Number of tube, Nt
516
Tube pitch is the distance between tube centres and formulated as
ΔTm = FtΔTlm =
W/(ºC.m2)
m2
ft2
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)Material Thermal Conductivity ( W/m.K )
Heat transfer area of a tube, At
Area of one tube, At (m2) =
(ft2) =
Number of tube, Nt
Q=UA ΔTalignl¿ lm ¿¿¿A=
QUΔT lm
A t=Lt πDalignl ¿ to ¿ ¿¿
N t=AA t
Pt=1 . 25×D to
Appendix F -162
Production of 100,000 MTA Hydrogen
23.8125
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition ), page 523Triangular pitch K1 0.249( 2 passes ) n 2.207
( eqn. 12.3b )
606.1934
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 63
For Split-ring floating head, Ds = Db + shell bundle clearance
0.66919
c) Tube side coefficient
Mean temperature (C)
Mean temperature (C) 423.9500
194.8531
258
0.0502772
Tube pitch, Pt (mm)
The bundle diameter, Db
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(TH.in +TH,out)/2
Tube cross-sectional area, At
Tube cross-sectional area, At
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Pt
Db=D to( N t / K1 )1 /n
A t=πDti2
¿4 ¿¿
¿
AT=N t A t
Appendix F -163
Production of 100,000 MTA Hydrogen
Mass flow rate (inside tube), m -12.7199
-252.9944
Physical properties of the tube side fluid (simulation result)Physical properties of organic solvent
5.9838
1.06E-050.567650181120466 kJ/kg.K
0.00834125294 W/m.K1 cp =
Linear velocity, u
Reynold number, Re Prandtl number, Pr
steam linear velocity, u (m/s) -42.2799Reynold number, Re -3.7741E+05Prandtl number, Pr 0.7185
309.8413
From figure 12.23, Chemical Engineering, Vol. 6
0.00270
( eqn. 12.15 )
( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
d) Tube side pressure drop
Fluid velocity, nf
Fluid mass velocity, nf
organic solvent density, rt kg/m3
Viscosity of , mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi
v f=m / AT
u=v f / ρ
Re=ρuDti
μPr=
Cp μk f
hi=k f jh RePr0 . 33
Dti ( μμw )
0 .14
Appendix F -164
Production of 100,000 MTA Hydrogen
From figure 12.24 'Chemical Engineering'. Vol. 6
0.00170
where m = 0.25 for laminar flow, Re<2100 m = 0.14 for turbulent flow, Re>2100
71.8151 kPa
e) Shell side coefficient0.6692
0.6023Baffle Diameter 0.6676
23.8125
( eqn. 12.21 )
0.080608
200.257076
2484.3456
( eqn. 12.23 )
friction factor, jf
Tube side pressure drop, DPt
Np = number of tube side passes
Tube side pressure drop,
DPt
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs
Shell side equivalent diameter, De
ΔPs=N p [ 8 jf ( L/ Dti )(μμw
)−m+2. 5 ]ρus
2
2
A s=( p t−Dto )D s lB
pt
sss AwG /
De=1 .1Dto
( pz2−0.971 Dto
2 )
Baffle Spacing , lB=0 . 9∗Ds
Baffle Diameter=D s−0 . 0016
Appendix F -165
Production of 100,000 MTA Hydrogen
13.5265
Mean temperature (C)
Mean temperature (ºC) 312.3200
Physical properties of shell fluid (steam)
Physical properties
799.8603
5.16E-043.69813E+00 kJ/kg.K
0.6155396 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 6.5148E+04Prandtl number, Pr 3.0990
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0028
( eqn. 12.25 )
f) Shell side pressure drop
3.1060
From figure 12.30 'Chemical Engineering'. Vol. 6
Shell side equivalent diameter, De
Tmean = (Tshell.in +Tshell.out)/2
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs
Linear velocity, us
Linear velocity, us
De=1 .1Dto
( pz2−0.971 Dto
2 )
m/Re es DG
hs=k f jh RePr1/3
De ( μμw )
0 .14
us=Gs / ρ
Appendix F -166
Production of 100,000 MTA Hydrogen
0.0500
Shell side presure drop, 618633.2884 Pa
618.6333 kPa
g) Overall Coefficient
Overall heat transfer coefficient can be calculated by using the formula
Therefore,
-0.0019335603433026
-517.180652501363
7
friction factor, jf
Shell side presure drop, DPs
DPs
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
1/Uo =
Uo = W/m2.C
h) Number of baffle, Nb
Number of baffle, Nb
Nbaffle
ΔPs=8 jf ( Ds /D e)( L/ lB )ρus
2
2( μ
μw)−0 .14
1Uo
= 1hs
+ 1hod
+d to ln (d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Nb=( L/ lB)−1
Appendix F -167
Production of 100,000 MTA Hydrogen
i) Costing (Guthrie's Modular Method)
Total area of the Heat Exchanger = 150.7157 = 1622.28846242856
Operating Pressure = 4.75
405.6126.00
Update factor = 405.6126.00
= 3.21904761904762
With reference costing method proposed in Systematic Method of Chemical ProcessDesign by L.T. Biegler.
Base Cost,
C0= 5000S0= 400
0.65Updated Bare Module Cost : BMC= (UF)(MPF+MF-1) (BC)
Materials and Pressure Correction Factor, MPF
Total area (ft2) 1,622.28846Base cost, C ($) 12,422.650Modular factor, MF 3.2900Design factor, Fd 0.8500Pressure factor, Fp 0.0000Material factor, Fm 2.5000MPF 2.1250
176,551.89Bare module cost (RM) 670,897.18
CE Plant Cost Index for 2003, CEI 03 =CE Plant Cost Index for 1968 1/2, CEI 68 =
α=
Updated bare module cost ($)
Appendix F -168
Production of 100,000 MTA Hydrogen
Cost of Coolant:Mass flowrate of R-12 needed = -12.7199Assume that the coolant R-12 will be recycled in a cycle in 10 minutes, which equal to 600s.Total of coolant needed = -7631.9152From the website, we obtained 50 pound of R-12a is sold at US 160;Price for coolant = US 3.2 /pound = RM 27.02 /kgThe cost for coolant = RM -206231.309417173
Cost of Mechanical Refrigeration Unit:For the coolant/refrigerate to cold down to its initial temperature for recycling to the cooler X-35,an air cooled mechanical refrigeration unit is installed. From Ulrich (1984);The rate of heat absorbtion, Q = 68805.55600The temperature of coolant = 479.75000
= 206.60000From Figure 5-11, Ulrich (1984);Bare module cost for the air-cooled refrigeration unit = US $Updated factor = 1.29Updated module cost, BMC = US $ 1,935,000.00
= RM 7,353,000.00
Appendix F -169
Production of 100,000 MTA Hydrogen
Split flow shell and 2 tubesFixed and U-Tube
HorizontalHorizontal
11
R-12water
68805.55600
T1 = inlet temperature to tubeT2 = outlet temperature from tubet1 = inlet temperature to shellt2 = outlet temperature from shell
Appendix F -170
Production of 100,000 MTA Hydrogen
(standard length of tubes are 8, 12, or 16 ft, pg 520, Vol6 )
(A.3-16)
Appendix F -171
Production of 100,000 MTA Hydrogen
mm2
Appendix F -172
Production of 100,000 MTA Hydrogen
kg/s
1.00E-03
Prandtl number, Pr
-483.8899
kg/m2.s
Ns/m2
W/m2.C
Pr=Cp μ
k f
Appendix F -173
Production of 100,000 MTA Hydrogen
( eqn. 12.20 )
0.708759851386908 atm
Baffle
m diameter
mm
mm
kg/s
m2
kg/s.m2
Appendix F -174
Production of 100,000 MTA Hydrogen
mm
12056.9102221634
m/s
W/m2.C
Appendix F -175
Production of 100,000 MTA Hydrogen
( eqn. 12.26 )
6.10543585855115 atm
12056.9102221634
-483.8899
5000
5000
44.00.01575
0.01905
( eqn. 12.2 )
Appendix F -176
Production of 100,000 MTA Hydrogen
bar
With reference costing method proposed in Systematic Method of Chemical Process
m2
ft2
Appendix F -177
Production of 100,000 MTA Hydrogen
kg/sAssume that the coolant R-12 will be recycled in a cycle in 10 minutes, which equal to 600s.
kg
For the coolant/refrigerate to cold down to its initial temperature for recycling to the cooler X-35,
KWKoC
1,500,000
Appendix F -169
Production of 100,000 MTA Hydrogen
Cooler X-35
Heat exchanger type Split flow shell and 2 tubesDesign type Fixed and U-TubeHeat exchanger orientation HorizontalTube inlet direction HorizontalNumber of parallel plate 1Tube side stream feed 1Tube side R-12Shell side methanolHeat duty (kW) (Q) 26.08619
a) Equipment sizingshell (t) tube (T)
Stream Methanol R-12294.15 263.15
293.15 278.15
R = ( eqn. 12.6 )R= 0.0666666666666667
S= ( eqn. 12.7 )S= 0.4839
Ft can be obtained from fig 12.19 ( vol. 6 ),
0.980
( eqn. 12.4 )
22.2714
Therefore, the actual temperature difference is
21.8260
Tin (K)
Tout (K)
(T1-T2)/(t2-t1)
(t2-t1)/(T1-t1)
Ft =DTlm can be calculated from the equation,
DTlm =
ΔTm = FtΔTlm =
T1 = inlet temperature to tubeT2 = outlet temperature from tubet1 = inlet temperature to shellt2 = outlet temperature from shell
T2
T1
t2
t1
ΔT lm=(T 1−t2 )−(T2−t1 )
ln(T1−t2 )(T2−t1 )
Appendix F -170
Production of 100,000 MTA Hydrogen
Assumption: (Table 12.1, 'Chem. Eng', Vol. 6)
U 800
Provisional area of heat exchanger, A can be obtained trough the formula,
Provisional area, A = 1.4940
= 16.0811
Material Stainless SteelBWG number 16
4.8819.0515.7544.0
0.2921
3.1437
Number of tube, Nt
5
Tube pitch is the distance between tube centres and formulated as
23.8125
W/(ºC.m2)
m2
ft2
b) Tube rating ( From App.5.-2, Tranport Processes by, Christie J. Geankoplis )
Length of tube Lt (m)Outer diameter, Dto (mm)Inner diameter, Dti (mm)Material Thermal Conductivity ( W/m.K )
Heat transfer area of a tube, At
Area of one tube, At (m2) =
(ft2) =
Number of tube, Nt
Tube pitch, Pt (mm)
Q=UA ΔTalignl ¿ lm ¿¿¿A=
QUΔT lm
A t=Lt πDalignl ¿ to ¿ ¿¿
N t=AA t
Pt=1 . 25×D to
Appendix F -171
Production of 100,000 MTA Hydrogen
From Table 12.4, Chemical Engineering , Vol. 6 ( 1st Edition ), page 523Triangular pitch K1 0.249( 2 passes ) n 2.207
( eqn. 12.3b )
74.9336
From Chemical Engineering , Vol. 6 (figure 12.10)Shell bundle clearance (mm) 50
For Split-ring floating head, Ds = Db + shell bundle clearance
0.12493
c) Tube side coefficientMean temperature (C)
Mean temperature (C) 270.6500
194.8531
3
0.0004984
Mass flow rate (inside tube), m 2.8719 kg/s
The bundle diameter, Db
Bundle diameter, Db (mm)
Shell internal diameter, Ds (m)
Tmean =(TH.in +TH,out)/2
Tube cross-sectional area, At
Tube cross-sectional area, At mm2
Tube per pass = Nt
Total flow area (m2), AT
Total flow area (m2), AT
Pt
Db=D to( N t / K1 )1 /n
A t=πDti2
¿4 ¿¿
¿
AT=N t A t
Appendix F -172
Production of 100,000 MTA Hydrogen
5762.4214
Physical properties of the tube side fluid (simulation result)Physical properties of organic solvent
5.9838
1.26E-050.605556213507121 kJ/kg.K
0.0106691796 W/m.K1 cp = 1.00E-03
Linear velocity, u
Reynold number, Re Prandtl number, Pr
steam linear velocity, u (m/s) 963.0037Reynold number, Re 7.2007E+06Prandtl number, Pr 0.7154
309.8413
From figure 12.23, Chemical Engineering, Vol. 6
0.00270
( eqn. 12.15 )
11791.9849( assuming viscosity of the fluid is identical at the wall and of the bulk fluid )
Fluid velocity, nf
Fluid mass velocity, nf kg/m2.s
organic solvent density, rt kg/m3
Viscosity of , mtL Ns/m2
Heat capacity, Ctp
Thermal conductivity, ktf
Ns/m2
L/Dti
Heat transfer factor, jh
Tube side heat transfer coefficient, hi
Tube side heat transfer coefficient, hi W/m2.C
v f=m / AT
u=v f / ρ
Re=ρuDti
μPr=
Cp μk f
hi=kf jh RePr0 . 33
Dti ( μμw )
0 .14
Appendix F -173
Production of 100,000 MTA Hydrogen
d) Tube side pressure drop
From figure 12.24 'Chemical Engineering'. Vol. 6
0.00170
( eqn. 12.20 )where m = 0.25 for laminar flow, Re<2100 m = 0.14 for turbulent flow, Re>2100
37256.6692 kPa
367.6947371 atm
e) Shell side coefficient Baffle
0.1249 m diameter
0.1124 mBaffle Diameter 0.1233 m
23.8125 mm
( eqn. 12.21 )
0.002810
11.173788 kg/s
3977.1254
friction factor, jf
Tube side pressure drop, DPt
Np = number of tube side passes
Tube side pressure drop,
DPt
Shell diameter, Ds
Baffle spacing, lB
Tube pitch, Pt
Cross flow area, As
Cross flow area, As m2
Shell side mass velocity, Gs
Mass flow (inside shell), Ws
Shell side mass velocity, Gs kg/s.m2
ΔPs=N p [ 8 jf ( L/ Dti )(μ
μw)−m+2. 5 ]
ρus2
2
A s=( p t−Dto )D s lB
pt
sss AwG /
Baffle Spacing , lB=0 .9∗Ds
Baffle Diameter=D s−0 .0016
Appendix F -174
Production of 100,000 MTA Hydrogen
( eqn. 12.23 )13.5265 mm
Mean temperature (C)
Mean temperature (ºC) 293.6500
Physical properties of shell fluid (steam)
Physical properties
1.9887
1.83E-052.99569E+00 kJ/kg.K
0.0745250 W/m.K
Reynold number, Re( eqn. 12.24 )
Reynold number, Re 2.9355E+06Prandtl number, Pr 0.7367
Selecting 15% for baffle cutFrom figure 12.29, Chemical Engineering, Vol. 6
0.0008
( eqn. 12.25 )
11697.42886
Shell side equivalent diameter, De
Shell side equivalent diameter, De
Tmean = (Tshell.in +Tshell.out)/2
Fluid density, rs kg/m3
Viscosity, msL Ns/m2
Heat capacity, Csp
Thermal conductivity, ksf
Heat Transfer Factor, jh
Shell side heat transfer coefficient, hs
Shell side heat transfer coefficient, hs W/m2.C
De=1 .1Dto
( pz2−0. 971 Dto
2 )
m/Re es DG
hs=k f jh RePr1/3
De ( μμw )
0 .14
Appendix F -175
Production of 100,000 MTA Hydrogen
f) Shell side pressure drop
1999.8619 m/s
From figure 12.30 'Chemical Engineering'. Vol. 6
0.0320
( eqn. 12.26 )
Shell side presure drop, 408105712.7656 Pa
408105.7128 kPa 4027.690232 atm
g) Overall Coefficient
11697.42886
11791.9849
5000
5000
44.00.01575
0.01905
Overall heat transfer coefficient can be calculated by using the formula
( eqn. 12.2 )
Therefore,
0.000671145088401414
1489.99078929696
Linear velocity, us
Linear velocity, us
friction factor, jf
Shell side presure drop, DPs
DPs
Outside fluid film coefficient, hs, W/m2.oC
Inside fluid film coefficient, hi, W/m2.oC
Outside dirt coefficient (fouling factor), hod, W/m2.oC
Inside dirt coefficient, hid, W/m2.oC (Table 12.2, vol. Six )
Thermal conductivity of the tube wall material, kw, W/m.oCTube inside diameter, Dti, m
Tube outside diameter, Dto, m
1/Uo =
Uo = W/m2.C
h) Number of baffle, Nb
Number of baffle, Nb
us=Gs / ρ
ΔPs=8 jf ( Ds /D e)( L/ lB )ρus
2
2( μ
μw)−0 .14
1Uo
= 1hs
+ 1hod
+d to ln(d to /d ti)
2k w+
d to
d ti× 1
hid+
d to
dti× 1
hi
Nb=( L/ lB)−1
Appendix F -176
Production of 100,000 MTA Hydrogen
42
i) Costing (Guthrie's Modular Method)
Total area of the Heat Exchanger = 1.4940 = 16.0811302128
Operating Pressure = 4.75 bar405.6
126.00Update factor = 405.6
126.00
= 3.21904761904762
With reference to costing method proposed in Systematic Method of Chemical ProcessDesign by L.T. Biegler.
Base Cost,
C0= 5000S0= 400
0.65Updated Bare Module Cost : BMC= (UF)(MPF+MF-1) (BC)
Materials and Pressure Correction Factor, MPF
Total area (ft2) 16.08113Base cost, C ($) 619.066Modular factor, MF 3.2900Design factor, Fd 0.8500Pressure factor, Fp 0.0000Material factor, Fm 2.5000MPF 2.1250
8,798.22Bare module cost (RM) 33,433.24
Nbaffle
m2
ft2
CE Plant Cost Index for 2003, CEI 03 =CE Plant Cost Index for 1968 1/2, CEI 68 =
α=
Updated bare module cost ($)
Appendix F -177
Production of 100,000 MTA Hydrogen
Utility cost:
Cost of Coolant R-12:Mass flowrate of R-12 needed = 2.8719 kg/sAssume that the coolant R-12 will be recycled in a cycle in 10 minutes, which equal to 600s.Total of coolant needed = 1723.1226 kgFrom the website, we obtained 50 pound of R-12a is sold at US 160;Price for coolant = US 3.2 /pound = RM 27.02 /kgThe cost for coolant = RM 46562.6019443245
Cost of Mechanical Refrigeration Unit:For the coolant/refrigerate to cold down to its initial temperature for recycling to the cooler X-36, an air cooled mechanical refrigeration unit is installed. From Ulrich (1984);The rate of heat absorbtion, Q = 26.08619 KWThe temperature of coolant = 263.15000 K
= -10.00000 oCFrom Figure 5-11, Ulrich (1984);Bare module cost for the air-cooled refrigeration unit = US $ 15,000Updated factor = 1.29
19,350.00 = RM 73,530.00
Updated module cost, BMC = US $