diastereoselective addition of α-metalated sulfoxides to imines revisited: mechanism, computational...

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2003 Sulfoxides Sulfoxides Q 0600 Diastereoselective Addition of α-Metalated Sulfoxides to Imines Revisited: Mech- anism, Computational Studies, and the Effect of External Chiral Ligands. — On the basis of a computer modelling study, the mechanistical aspects are discussed in detail. The structure of compound (IIIe) is determined by X-ray analysis. — (PEDERSEN, B.; REIN, T.; SOETEFTE, I.; NORRBY*, P.-O.; TANNER, D.; Collect. Czech. Chem. Commun. 68 (2003) 5, 885-898; Dep. Chem., Tech. Univ. Den., DK-2800 Lyngby, Den.; Eng.) — K. Schneider 34- 077

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Page 1: Diastereoselective Addition of α-Metalated Sulfoxides to Imines Revisited: Mechanism, Computational Studies, and the Effect of External Chiral Ligands

2003 Sulfoxides

SulfoxidesQ 0600 Diastereoselective Addition of α-Metalated Sulfoxides to Imines Revisited: Mech-

anism, Computational Studies, and the Effect of External Chiral Ligands. — On the basis of a computer modelling study, the mechanistical aspects are discussed in detail. The structure of compound (IIIe) is determined by X-ray analysis. — (PEDERSEN, B.; REIN, T.; SOETEFTE, I.; NORRBY*, P.-O.; TANNER, D.; Collect. Czech. Chem. Commun. 68 (2003) 5, 885-898; Dep. Chem., Tech. Univ. Den., DK-2800 Lyngby, Den.; Eng.) — K. Schneider

34- 077

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