development of a “capable plant model” for · solar/thermal drying beds anaerobic digestion...

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Development of a “Capable Plant Model” for Anaerobic Digestion Marlene vd Merwe-Botha 3 rd National Biogas Conference, DBSA, 1-3 November 2017

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• The status of anaerobic digestion in South Africa

• A Capable Plant Model for Anaerobic Digesters

• Development of a Guideline Manual

• Modules 1 – 10

• Self Assessment / Masterclass

• Inspection Guideline for Process Controllers

• PFD - Councillors

• Way forward

Presentation Outline

3

0 100 200 300 400

Solar/Thermal Drying Beds

Anaerobic Digestion

Sludge Lagoon/Pond

Belt Press Dewatering

Other

Gravity Thickening

Composting

Dissolved Air Flotation…

Screw Press Dewatering

Centrifugal Dewatering

Thermo-Chemical Treatment

Centrifugal Thickening

Plate Filter Press Dewatering

Rotary Drum Sludge Thickening

Incineration

Lime or Other Chemical…

Pelletisation

NUMBER OF SYSTEMS

Wastewater sludge treatment technologies at municipal treatment plants

217 WWTWs identified with ADs108 = functional Ads = 46 munics

Solids treatment technology: status 2015/16

4

5

2016-17: DoE&GIZ Scoping Studies

6

MIX 54%HEAT 34%COLLECT 95%USE BIOGAS <15% PLAN to USE >80%FLARE <2%

Most plants do: Hydraulic loading Organic loading – COD, SS, P and N Electricity demand Electricity projection Liquids treatment performance

Most plants don’t:ꭕ Settled COD and SSꭕ TS, VS, VS reductionꭕ Temperatureꭕ HRT, VS loadingꭕ Alkalinity, VA, VFA/Alkꭕ Biogas production rateꭕ Biogas compositionꭕ Sludge treatment performance

108 ADs - Operational status

7

7-Nov-17 8

• Process Controllers

• Managers

• Decision makers

• Wastewater Practitioners

Development of Guideline

7-Nov-17 9

Raise the capacity of Process Controllers who are responsible for the sustainable operation of anaerobic digesters and optimised performance of biogas production

Create awareness within the municipal sector that wastewater sludge and biogas are valuable resources

Promote sustainable sludge management & energy recovery in municipalities

Build competency in the water sector to manage and operate sludge treatment processes

Identify opportunities for municipal uptake and private sector involvement

Objective of Guideline

10

7-Nov-17 11

Module 1: Anaerobic Digestion

7-Nov-17 12

Module 2: Upstream raw sludge mngt

7-Nov-17 13

Indicators

The ratio of volatile acids toalkalinity should be < 0.3

14

Module 3: Co-digestion

Chickenslaughter

waste

Porkslaughter

waste

Chickenlitter

Beefslaughter

waste

Fruit effluent

Bagasse Solidwaste

Waste-waste

Cattleslurry

Pigslurry

Municipal waste

Sugar Production

Fruit processing

Agriculture

Abattoir

0.54GJ/ton

1.14GJ/ton

1.55GJ/ton

1.69GJ/ton

2.21GJ/ton

2.32GJ/ton

4.25GJ/ton

3.07GJ/ton

0.64GJ/ton

1.07GJ/ton

15

Module 4: Down stream sludge mgnt

16

Module 5: Biogas to CHP

17

Module 6: Operations & Process Control

18

Module 6: Operations & Process Control

7-Nov-17 19

Module 6: Graphical recordings0

1000

2000

3000

4000

Dig

este

r VS

Load

ing

(kgV

S/d)

0

500

1000

1500

2000

2500

3000

3500

Tota

l Alk

alin

ity

& V

FA A

lkal

init

y (m

g/l

CaCO

3)

Total Alkalinity

0

0.2

0.4

0.6

0.8

VFA

/Alk

alin

ity

Rati

o

6.3

6.4

6.5

6.6

6.7

6.8

6.9

7

7.1

7.2

Slud

ge p

H V

alue

0

200

400

600

800

1000

1200

Gas

Vol

ume

(m3/

d)

20

25

30

35

40

45

% C

O2

in G

as

25

30

35

40

Dig

este

r Tem

p(C)

40

45

50

55

60

65

% V

S Re

mov

al

Average Loading rate = 1,800kgVS/d

Peak V Load on Day 5Feed reduced to 1/3 daily load untilDay 11

Increase in VFA due to feedoverload on Day 5

Increase in ratio due to lossin buffering capacity

Maximum permissable ratio = 0.3

Slaked lime added in day 10Minimum permissable pH = 6.8

Average gas production = 600m3/d

Rapid drop in gas due to overload on day 5

Average CO2 = 30%

High CO2 values due to non-optimum conditionsfor methanogens

Desirable digester temperature= 35°C

Heating malfunction of digesterheating systemIncreased overload on day 5

Average removal efficiency

Inadequate digestion duringoverload

Day 5

20

Parameters Typical Concentration or Range

Feed Sludge: Total solids 5%

Volatile solids 4.2%

% volatile solids of TS 84%

Digested Sludge: Total solids 2.5%

Volatile solids 1.7%

% volatile solids of TS 68%

Volatile Solids reduction 40 – 60%

Digester Loading: Highrate

1.5 – 3.0 kgVS/m3/d

Standard rate 0.5 – 1.4 kgVS/m3/d

Hydraulic Retention Time: Highrate

15 – 25 days

Standard rate 30 – 60 days

Temperature of Digester:Mesophilic

32 - 37°C

Thermophilic 55 - 65°C

Mixing of Digester:Turnover rate

Once per 24 hours

Power input 5 – 10 w/m3

Biogas Production Rate 1m3 biogas/kgVS destroyed

Biogas Composition:Methane

50 – 75%

Carbon dioxide 25 – 40%

Colour of flame Yellow flame with blue at base

Volatile Fatty Acid: Digesterliquor

50 – 300 mg/l

Total Alkalinity: Digester liquor 2,000 – 3,000 mg/l

Ratio VFA:Total Alkalinity: Digesterliquor

Less than 0.3

pH Value: Digester liquor 7.0 – 7.5

C:N:P:S ratio Digester liquor 500 – 600:15:5:3

Problem Probable Cause Action

A rise in the volatile toalkalinity ratio to 0.3

a) Hydraulic overload causedby accidental pumping

b) Organic overload due toseptic tank sludgedischarged to plant

c) Discharge of toxic materialsdue to industrial wastes

a) Decrease sludgewithdrawal rate tokeep sludge in digester

b) Decrease feeding

c) Add seed sludge fromsecondary digester

d) Liquid dilution

pH value starts to dropand CO2 increases above45% so no burnable gas isobtained

Severe organic overload over aperiod of time so that the VA:ALKratio has increased above 0.8

a) Add alkalinity byaddition of chemicals

b) Decrease digesterloading

Supernatant has a sourodour

Digester pH is too low a) Add alkalinity byaddition of chemicals

b) Decrease digesterloading

Digester temperature isfalling and cannot bemaintained above normal

level

a) Sludge is blocking externalheat exchanger

b) Feed solids concentration istoo low and not sufficientbiogas is being generated

a) Open heat exchangerand clean

b) B) Thicken feed solids

Scum blanket is too thick a) Lack of mixing

b) High grease content

a) Break up blanket byusing mixers

b) B) Check greaseremoval mechanism atPST and gravitythickener

Gas is leaking throughpressure relief valve ondigester roof

Valve is not seating properly or isstuck open

Remove valve cover and rotateweight holder until it seatsproperly; Install new ring isneeded

Flare is not firing on biogas a)Low gas pressure

b) Low methane content

c) Pilot flame out

d) Excess water in lines

a) Check for leaks in system andrepair

b) Check methane content ofgas

c) Relight according to standardprocedure

d) Drain lines and water traps

Excessive noise in gearboxof mechanical mixer

a) Lack of proper lubrication

b) Misalignment of equipment

c) Unit worn

a) Lubricate as permanual

b) B) Check alignment

c) C) Check for wear

7-Nov-17 21

Module 7: Design & Technology

22

Module 8: Asset management (Maint)

Planning

Design Procure Construct

Operate Maintain Refurbish

0.2% 2% 17% 44%

Ongoing

Total Life Cycle Cost

7-Nov-17 23

Module 9: Management

7-Nov-17 24

Module 10: BtEnergy Opportunities

7-Nov-17 25

Annexures

28

Inspection Guide

AGRICULTURE

INDUSTRY

COMPOSTING

ELECTRICITY GRID

RIVERS

AGRICULTURE

INDUSTRY

FACTORIES

FLATS

HOUSES

PUMPSTATION

WASTEWATER TREATMENT WORKS

BIOGASTREATED SOLIDS

ANAEROBIC DIGESTERS

Designed by Shawn Moorgas

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Way Forward

[email protected]